Organosilver(I) framework assembly with trifluoroacetate and enediyne-functionalized alicycles

Eight new silver(I) trifluoroacetate complexes based on a series of designed ligands, each featuring an alicyclic ring with enediyne functionality, have been synthesized and characterized by single-crystal X-ray diffraction. Each ethynide terminal is inserted into an Ag_n (n = 4–5) basket, leading to the generation of coordination chain or layer structures, but the well shielded ethenyl group does not take part in silver-olefin bonding. Variation in ring size of the alicycles is shown to influence the construction of the organosilver(I) coordination networks, which are consolidated by weak intermolecular interactions in the crystal structures. The effect of adding ancillary N-donor ligands to the reaction system on the coordination and supramolecular network assembly is also investigated.

Computing details

For all compounds, data collection: APEX2 (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2009); software used to prepare material for publication: SHELXL2013.

Figures

(I)

Crystal data

22(Ag^+)·3(C10H8^2^−)·16(C2F3O2^−)·12(C2H6SO)	Z = 4
Mr = 5503.48	F(000) = 10488
Monoclinic, C2/c	Dx = 2.445 Mg m^−3
a = 22.076 (3) Å	Mo Kα radiation, λ = 0.71073 Å
b = 14.7930 (18) Å	µ = 3.11 mm^−1
c = 45.863 (6) Å	T = 173 K
β = 93.501 (3)°	Block, yellow
V = 14950 (3) Å^3	0.50 × 0.50 × 0.40 mm

Data collection

Bruker APEX-II CCD diffractometer	9700 reflections with I > 2σ(I)
φ and ω scan	Rint = 0.158
Absorption correction: multi-scan SADABS (Bruker, 2003)	θmax = 25.3°, θmin = 1.7°
Tmin = 0.306, Tmax = 0.370	h = −26→26
102163 measured reflections	k = −17→17
13534 independent reflections	l = −55→54

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.076	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.200	H-atom parameters constrained
S = 1.08	w = 1/[σ^2(Fo^2) + (0.096P)^2 + 292.8881P] where P = (Fo^2 + 2Fc^2)/3
13534 reflections	(Δ/σ)max = 0.001
967 parameters	Δρmax = 3.61 e Å^−3
606 restraints	Δρmin = −1.64 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.79033 (4)	0.31570 (6)	0.49150 (2)	0.0245 (2)
Ag2	0.78628 (5)	0.17130 (7)	0.44545 (3)	0.0418 (3)
Ag3	0.76039 (5)	0.36734 (6)	0.43049 (2)	0.0295 (2)
Ag4	0.66712 (5)	0.38185 (6)	0.48665 (2)	0.0298 (2)
Ag5	0.55130 (5)	0.38358 (6)	0.34034 (2)	0.0278 (2)
Ag6	0.59620 (6)	0.43755 (7)	0.40950 (2)	0.0387 (3)
Ag7	0.67050 (5)	0.44516 (6)	0.35846 (2)	0.0263 (2)
Ag8	0.66188 (5)	0.26565 (6)	0.33484 (2)	0.0363 (3)
Ag9	0.54827 (5)	0.27076 (6)	0.28916 (2)	0.0364 (3)
Ag10	0.63744 (5)	0.42288 (6)	0.29427 (2)	0.0308 (3)
Ag11	0.43231 (6)	0.38098 (9)	0.29400 (3)	0.0475 (3)
C1	0.7108 (5)	0.2672 (7)	0.4616 (2)	0.018 (2)
C2	0.6746 (5)	0.2425 (7)	0.4419 (2)	0.014 (2)
C3	0.6308 (5)	0.2149 (8)	0.4194 (3)	0.022 (3)
C4	0.6242 (5)	0.2795 (7)	0.3950 (2)	0.019 (2)
C5	0.6208 (6)	0.3299 (8)	0.3740 (2)	0.023 (3)
C6	0.6003 (6)	0.1366 (8)	0.4188 (3)	0.024 (3)
C7	0.6058 (7)	0.0635 (8)	0.4411 (3)	0.037 (3)
H7A	0.5831	0.0794	0.4584	0.045*
H7B	0.6488	0.0531	0.4475	0.045*
C8	0.5788 (8)	−0.0195 (11)	0.4260 (4)	0.059 (5)
H8A	0.6096	−0.0519	0.4152	0.071*
H8B	0.5619	−0.0614	0.4403	0.071*
C9	0.5294 (8)	0.0183 (11)	0.4055 (4)	0.053 (4)
H9A	0.4921	0.0292	0.4158	0.064*
H9B	0.5199	−0.0241	0.3891	0.064*
C10	0.5544 (7)	0.1069 (9)	0.3942 (3)	0.039 (3)
H10A	0.5218	0.1523	0.3909	0.047*
H10B	0.5746	0.0975	0.3757	0.047*
C11	0.5363 (6)	0.4162 (9)	0.2925 (3)	0.033 (3)
C12	0.5173 (6)	0.4728 (8)	0.2753 (3)	0.026 (3)
C13	0.5000	0.5259 (11)	0.2500	0.024 (4)
C14	0.5000	0.6183 (11)	0.2500	0.028 (4)
C15	0.5178 (7)	0.6751 (9)	0.2762 (3)	0.040 (3)
H15A	0.5600	0.6625	0.2837	0.048*
H15B	0.4901	0.6654	0.2921	0.048*
C16	0.5115 (11)	0.7697 (12)	0.2637 (4)	0.078 (6)
H16A	0.4850	0.8058	0.2759	0.093*
H16B	0.5519	0.7989	0.2645	0.093*
S1	0.7834 (3)	0.1041 (3)	0.37065 (10)	0.0648 (13)
O17	0.7644 (6)	0.1757 (8)	0.3910 (3)	0.070 (4)
C33	0.7396 (10)	0.0091 (15)	0.3777 (5)	0.085 (7)
H33A	0.6974	0.0198	0.3706	0.128*
H33B	0.7413	−0.0023	0.3988	0.128*
H33C	0.7555	−0.0436	0.3677	0.128*
C34	0.8542 (10)	0.0650 (14)	0.3854 (5)	0.078 (6)
H34A	0.8851	0.1115	0.3830	0.118*
H34B	0.8655	0.0099	0.3751	0.118*
H34C	0.8515	0.0516	0.4062	0.118*
S2	0.82363 (18)	0.4145 (3)	0.36429 (8)	0.0441 (9)
O18	0.7685 (4)	0.4105 (6)	0.38215 (19)	0.033 (2)
C35	0.8789 (9)	0.3462 (12)	0.3833 (5)	0.071 (6)
H35A	0.8677	0.2824	0.3809	0.106*
H35B	0.8810	0.3620	0.4041	0.106*
H35C	0.9186	0.3565	0.3754	0.106*
C36	0.8576 (9)	0.5228 (12)	0.3733 (4)	0.068 (5)
H36A	0.8326	0.5711	0.3642	0.102*
H36B	0.8984	0.5253	0.3660	0.102*
H36C	0.8603	0.5308	0.3945	0.102*
S3	0.70907 (17)	0.5873 (2)	0.44468 (8)	0.0356 (8)
O19	0.6878 (4)	0.4922 (6)	0.4353 (2)	0.043 (2)
C37	0.7223 (10)	0.6420 (11)	0.4116 (4)	0.068 (5)
H37A	0.7591	0.6175	0.4037	0.101*
H37B	0.7274	0.7070	0.4151	0.101*
H37C	0.6876	0.6320	0.3976	0.101*
C38	0.6416 (7)	0.6438 (9)	0.4534 (3)	0.040 (4)
H38A	0.6280	0.6203	0.4719	0.061*
H38B	0.6100	0.6337	0.4379	0.061*
H38C	0.6496	0.7088	0.4554	0.061*
S4	0.51124 (18)	0.4043 (3)	0.47009 (9)	0.0425 (9)
O20	0.5716 (4)	0.4224 (6)	0.45803 (19)	0.034 (2)
C39	0.4597 (8)	0.4772 (13)	0.4490 (4)	0.070 (5)
H39A	0.4671	0.5402	0.4547	0.105*
H39B	0.4178	0.4609	0.4526	0.105*
H39C	0.4661	0.4699	0.4281	0.105*
C40	0.4865 (8)	0.2971 (10)	0.4553 (4)	0.060 (5)
H40A	0.5108	0.2486	0.4647	0.090*
H40B	0.4916	0.2962	0.4342	0.090*
H40C	0.4436	0.2879	0.4588	0.090*
S5	0.3088 (2)	0.5051 (3)	0.27010 (8)	0.0454 (10)
O21	0.3551 (5)	0.4355 (7)	0.2618 (2)	0.046 (3)
C41	0.3514 (10)	0.5748 (13)	0.2961 (5)	0.083 (6)
H41A	0.3811	0.6105	0.2860	0.125*
H41B	0.3725	0.5365	0.3108	0.125*
H41C	0.3237	0.6156	0.3056	0.125*
C42	0.2631 (8)	0.4540 (12)	0.2951 (4)	0.059 (5)
H42A	0.2349	0.4120	0.2848	0.088*
H42B	0.2400	0.5006	0.3049	0.088*
H42C	0.2887	0.4209	0.3097	0.088*
S6	0.4067 (3)	0.1429 (5)	0.2665 (2)	0.051 (3)	0.80 (2)
O22	0.4347 (5)	0.2377 (6)	0.2630 (2)	0.040 (2)	0.80 (2)
C43	0.3977 (11)	0.1294 (14)	0.3043 (4)	0.080 (6)	0.80 (2)
H43A	0.4373	0.1174	0.3144	0.120*	0.80 (2)
H43B	0.3703	0.0785	0.3073	0.120*	0.80 (2)
H43C	0.3804	0.1848	0.3121	0.120*	0.80 (2)
C44	0.3282 (11)	0.1635 (17)	0.2543 (5)	0.094 (7)	0.80 (2)
H44A	0.3252	0.1719	0.2331	0.141*	0.80 (2)
H44B	0.3136	0.2179	0.2638	0.141*	0.80 (2)
H44C	0.3033	0.1116	0.2594	0.141*	0.80 (2)
S6'	0.3876 (12)	0.183 (2)	0.2793 (5)	0.043 (11)	0.20 (2)
O22'	0.4347 (5)	0.2377 (6)	0.2630 (2)	0.040 (2)	0.20 (2)
C43'	0.3977 (11)	0.1294 (14)	0.3043 (4)	0.080 (6)	0.20 (2)
H43D	0.4336	0.1515	0.3158	0.120*	0.20 (2)
H43E	0.4043	0.0666	0.2985	0.120*	0.20 (2)
H43F	0.3622	0.1325	0.3161	0.120*	0.20 (2)
C44'	0.3282 (11)	0.1635 (17)	0.2543 (5)	0.094 (7)	0.20 (2)
H44D	0.3289	0.2081	0.2385	0.141*	0.20 (2)
H44E	0.2898	0.1685	0.2639	0.141*	0.20 (2)
H44F	0.3318	0.1026	0.2462	0.141*	0.20 (2)
O1	0.8358 (5)	0.4502 (6)	0.4931 (2)	0.041 (2)
O2	0.8421 (5)	0.4603 (6)	0.4445 (2)	0.039 (2)
C17	0.8513 (7)	0.4860 (9)	0.4706 (3)	0.032 (3)
C18	0.8906 (5)	0.5717 (7)	0.4748 (2)	0.047 (4)
F1	0.8779 (7)	0.6305 (7)	0.4542 (2)	0.131 (6)
F2	0.9470 (4)	0.5522 (7)	0.4736 (3)	0.112 (5)
F3	0.8830 (5)	0.6127 (7)	0.4992 (2)	0.095 (4)
O3	0.7305 (5)	0.4797 (6)	0.5506 (2)	0.041 (2)
O4	0.6765 (5)	0.5152 (5)	0.5090 (2)	0.036 (2)
C19	0.7088 (6)	0.5299 (8)	0.5318 (3)	0.028 (3)
C20	0.7266 (5)	0.6312 (8)	0.5361 (2)	0.043 (4)
F4	0.7642 (7)	0.6451 (8)	0.5580 (2)	0.127 (6)
F5	0.6781 (5)	0.6773 (8)	0.5400 (3)	0.141 (6)
F6	0.7498 (6)	0.6657 (7)	0.5133 (2)	0.103 (4)
O5	0.6034 (5)	0.2585 (7)	0.5098 (2)	0.049 (3)
O6	0.6144 (5)	0.2934 (7)	0.5579 (2)	0.052 (3)
C21	0.5864 (7)	0.2642 (8)	0.5350 (3)	0.034 (3)
C22	0.5244 (6)	0.2205 (8)	0.5387 (3)	0.054 (4)
F7	0.4820 (7)	0.2768 (11)	0.5322 (4)	0.179 (8)
F8	0.5152 (7)	0.1517 (11)	0.5212 (3)	0.167 (8)
F9	0.5180 (6)	0.1891 (10)	0.5644 (2)	0.120 (5)
O7	0.5077 (6)	0.5260 (9)	0.3533 (3)	0.077 (4)
O8	0.5634 (6)	0.5731 (8)	0.3921 (3)	0.065 (3)
C23	0.5306 (8)	0.5817 (10)	0.3701 (3)	0.043 (4)
C24	0.5156 (5)	0.6815 (9)	0.3613 (2)	0.065 (5)
F10	0.4639 (4)	0.6895 (8)	0.3468 (2)	0.095 (4)
F11	0.5150 (7)	0.7343 (8)	0.3838 (2)	0.127 (6)
F12	0.5571 (5)	0.7110 (8)	0.3450 (2)	0.097 (4)
O9	0.4691 (6)	0.3061 (9)	0.3605 (3)	0.070 (4)
O10	0.3852 (5)	0.3534 (7)	0.3355 (2)	0.046 (3)
C25	0.4143 (7)	0.3162 (9)	0.3571 (3)	0.038 (3)
C26	0.3771 (5)	0.2873 (7)	0.3825 (3)	0.046 (4)
F13	0.3775 (7)	0.3520 (7)	0.4018 (3)	0.127 (5)
F14	0.3994 (5)	0.2170 (6)	0.3958 (2)	0.084 (4)
F15	0.3218 (5)	0.2709 (10)	0.3745 (3)	0.132 (6)
O11	0.7035 (5)	0.5743 (6)	0.3443 (2)	0.040 (2)
O12	0.6556 (5)	0.5806 (6)	0.2995 (2)	0.043 (3)
C27	0.6845 (6)	0.6136 (8)	0.3205 (3)	0.028 (3)
C28	0.7020 (5)	0.7143 (8)	0.3196 (2)	0.041 (4)
F16	0.6700 (5)	0.7583 (6)	0.3000 (2)	0.089 (4)
F17	0.6965 (5)	0.7559 (5)	0.34445 (17)	0.068 (3)
F18	0.7586 (4)	0.7211 (7)	0.3138 (3)	0.093 (4)
O13	0.7485 (5)	0.2641 (7)	0.3109 (3)	0.053 (3)
O14	0.7372 (5)	0.4017 (7)	0.2922 (3)	0.054 (3)
C29	0.7647 (7)	0.3312 (9)	0.2978 (3)	0.040 (3)
C30	0.8298 (6)	0.3294 (8)	0.2869 (2)	0.059 (5)
F19	0.8502 (6)	0.4081 (7)	0.2805 (3)	0.139 (6)
F20	0.8288 (6)	0.2806 (10)	0.2635 (2)	0.121 (5)
F21	0.8688 (4)	0.2935 (7)	0.3056 (2)	0.069 (3)
O15	0.6403 (5)	0.1136 (6)	0.3253 (2)	0.048 (3)
O16	0.5505 (5)	0.1268 (6)	0.3006 (2)	0.050 (3)
C31	0.5912 (7)	0.0866 (9)	0.3143 (3)	0.036 (3)
C32	0.5811 (5)	−0.0179 (7)	0.3160 (2)	0.042 (4)
F22	0.5981 (5)	−0.0565 (7)	0.2924 (2)	0.096 (4)
F23	0.5249 (4)	−0.0376 (6)	0.3187 (3)	0.087 (4)
F24	0.6119 (5)	−0.0553 (6)	0.3377 (2)	0.096 (4)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0249 (5)	0.0271 (4)	0.0210 (5)	−0.0101 (4)	−0.0024 (4)	0.0049 (4)
Ag2	0.0314 (6)	0.0283 (5)	0.0662 (8)	−0.0006 (4)	0.0080 (6)	−0.0119 (5)
Ag3	0.0333 (6)	0.0311 (5)	0.0237 (5)	−0.0052 (4)	−0.0013 (4)	0.0109 (4)
Ag4	0.0348 (6)	0.0268 (5)	0.0271 (5)	0.0032 (4)	−0.0025 (4)	−0.0047 (4)
Ag5	0.0298 (6)	0.0360 (5)	0.0167 (5)	−0.0012 (4)	−0.0073 (4)	0.0064 (4)
Ag6	0.0527 (8)	0.0388 (6)	0.0246 (6)	0.0067 (5)	0.0031 (5)	0.0005 (4)
Ag7	0.0317 (6)	0.0252 (4)	0.0213 (5)	−0.0052 (4)	−0.0037 (4)	0.0061 (4)
Ag8	0.0471 (7)	0.0270 (5)	0.0358 (6)	−0.0024 (5)	0.0100 (5)	−0.0037 (4)
Ag9	0.0454 (7)	0.0256 (5)	0.0365 (6)	0.0002 (4)	−0.0110 (5)	−0.0009 (4)
Ag10	0.0369 (6)	0.0343 (5)	0.0209 (5)	−0.0023 (4)	−0.0015 (4)	0.0020 (4)
Ag11	0.0414 (7)	0.0674 (8)	0.0335 (6)	0.0065 (6)	0.0010 (5)	0.0164 (6)
C1	0.015 (5)	0.024 (5)	0.014 (5)	−0.003 (4)	0.002 (4)	0.000 (4)
C2	0.010 (5)	0.017 (4)	0.015 (5)	−0.003 (4)	0.005 (4)	0.008 (4)
C3	0.016 (6)	0.027 (5)	0.021 (5)	0.004 (4)	−0.002 (5)	0.002 (4)
C4	0.019 (6)	0.023 (5)	0.016 (5)	−0.007 (4)	−0.004 (4)	0.003 (4)
C5	0.029 (6)	0.027 (5)	0.013 (5)	0.003 (5)	−0.005 (5)	−0.008 (4)
C6	0.018 (6)	0.034 (5)	0.020 (5)	−0.005 (5)	0.000 (5)	−0.003 (5)
C7	0.039 (7)	0.029 (6)	0.043 (7)	−0.012 (5)	0.002 (6)	0.017 (5)
C8	0.065 (8)	0.053 (7)	0.058 (8)	−0.018 (7)	−0.012 (7)	0.018 (6)
C9	0.045 (8)	0.059 (7)	0.055 (8)	−0.028 (6)	−0.007 (6)	0.007 (6)
C10	0.035 (7)	0.042 (6)	0.040 (7)	−0.005 (6)	−0.001 (6)	0.002 (5)
C11	0.034 (7)	0.033 (6)	0.030 (6)	−0.001 (5)	−0.002 (5)	0.001 (5)
C12	0.029 (6)	0.026 (5)	0.022 (6)	−0.003 (5)	0.000 (5)	−0.004 (5)
C13	0.029 (8)	0.024 (6)	0.020 (7)	0.000	0.000 (6)	0.000
C14	0.033 (8)	0.027 (7)	0.024 (7)	0.000	−0.001 (6)	0.000
C15	0.045 (7)	0.033 (6)	0.041 (7)	0.000 (5)	−0.001 (6)	−0.017 (5)
C16	0.091 (10)	0.059 (8)	0.083 (9)	0.000 (8)	0.003 (8)	−0.011 (7)
S1	0.077 (4)	0.071 (3)	0.048 (3)	0.026 (3)	0.014 (2)	0.017 (2)
O17	0.069 (7)	0.067 (6)	0.074 (7)	0.015 (6)	0.015 (6)	0.013 (6)
C33	0.084 (13)	0.087 (12)	0.081 (13)	−0.003 (11)	−0.022 (11)	−0.008 (10)
C34	0.076 (13)	0.076 (11)	0.085 (13)	0.022 (10)	0.020 (11)	−0.007 (10)
S2	0.035 (2)	0.073 (3)	0.0245 (19)	−0.0011 (19)	0.0019 (16)	0.0006 (17)
O18	0.029 (5)	0.041 (4)	0.030 (5)	−0.006 (4)	−0.001 (4)	0.005 (4)
C35	0.050 (10)	0.063 (10)	0.101 (13)	0.021 (8)	0.017 (10)	0.021 (9)
C36	0.059 (11)	0.070 (10)	0.077 (12)	−0.009 (9)	0.018 (9)	0.019 (9)
S3	0.035 (2)	0.0343 (17)	0.038 (2)	−0.0040 (15)	0.0066 (17)	−0.0047 (15)
O19	0.033 (5)	0.031 (4)	0.065 (6)	−0.004 (4)	0.003 (5)	−0.001 (4)
C37	0.104 (13)	0.054 (9)	0.048 (9)	−0.041 (9)	0.027 (9)	−0.003 (7)
C38	0.037 (8)	0.042 (7)	0.042 (8)	0.009 (6)	0.001 (7)	−0.004 (6)
S4	0.035 (2)	0.048 (2)	0.046 (2)	−0.0058 (17)	0.0084 (18)	−0.0016 (17)
O20	0.026 (5)	0.048 (5)	0.028 (5)	−0.004 (4)	0.002 (4)	0.006 (4)
C39	0.043 (10)	0.081 (11)	0.088 (12)	0.013 (9)	0.015 (9)	0.025 (10)
C40	0.058 (10)	0.043 (8)	0.075 (11)	−0.023 (7)	−0.029 (9)	0.002 (8)
S5	0.056 (3)	0.046 (2)	0.035 (2)	0.0217 (19)	0.0122 (19)	0.0084 (16)
O21	0.048 (6)	0.061 (5)	0.029 (5)	0.021 (5)	0.005 (4)	0.000 (4)
C41	0.074 (12)	0.064 (10)	0.113 (14)	−0.018 (9)	0.021 (11)	−0.027 (10)
C42	0.060 (11)	0.060 (9)	0.056 (10)	−0.005 (8)	0.001 (9)	0.008 (8)
S6	0.068 (4)	0.044 (3)	0.043 (5)	−0.013 (3)	0.008 (3)	−0.002 (3)
O22	0.041 (5)	0.039 (4)	0.039 (5)	−0.003 (4)	−0.002 (4)	0.001 (4)
C43	0.091 (12)	0.080 (10)	0.070 (10)	−0.015 (9)	0.004 (9)	0.014 (9)
C44	0.088 (12)	0.118 (13)	0.074 (11)	−0.021 (10)	−0.007 (10)	0.000 (10)
S6'	0.047 (16)	0.071 (19)	0.010 (11)	−0.027 (13)	0.001 (9)	−0.007 (11)
O22'	0.041 (5)	0.039 (4)	0.039 (5)	−0.003 (4)	−0.002 (4)	0.001 (4)
C43'	0.091 (12)	0.080 (10)	0.070 (10)	−0.015 (9)	0.004 (9)	0.014 (9)
C44'	0.088 (12)	0.118 (13)	0.074 (11)	−0.021 (10)	−0.007 (10)	0.000 (10)
O1	0.054 (6)	0.043 (5)	0.025 (5)	−0.026 (4)	−0.006 (4)	0.010 (4)
O2	0.039 (5)	0.045 (5)	0.032 (5)	−0.021 (4)	0.007 (4)	0.004 (4)
C17	0.042 (7)	0.036 (6)	0.019 (6)	−0.007 (5)	0.003 (5)	0.000 (5)
C18	0.050 (8)	0.043 (6)	0.047 (7)	−0.015 (6)	0.004 (6)	−0.001 (6)
F1	0.201 (14)	0.070 (7)	0.115 (10)	−0.071 (8)	−0.036 (10)	0.046 (7)
F2	0.056 (7)	0.087 (8)	0.195 (13)	−0.035 (6)	0.016 (8)	−0.043 (8)
F3	0.112 (9)	0.080 (7)	0.097 (8)	−0.072 (7)	0.035 (7)	−0.049 (6)
O3	0.056 (6)	0.029 (4)	0.037 (5)	−0.012 (4)	−0.003 (5)	0.005 (4)
O4	0.051 (6)	0.019 (4)	0.036 (5)	0.002 (4)	−0.011 (4)	−0.005 (3)
C19	0.033 (6)	0.024 (5)	0.027 (6)	−0.003 (5)	0.011 (5)	−0.002 (5)
C20	0.057 (8)	0.034 (6)	0.039 (7)	−0.006 (6)	0.006 (6)	−0.003 (6)
F4	0.194 (13)	0.062 (7)	0.118 (10)	−0.057 (8)	−0.054 (10)	0.005 (7)
F5	0.144 (12)	0.054 (7)	0.233 (15)	0.009 (7)	0.072 (11)	−0.036 (8)
F6	0.160 (12)	0.059 (6)	0.092 (8)	−0.050 (7)	0.029 (8)	−0.002 (6)
O5	0.039 (6)	0.066 (6)	0.042 (5)	−0.018 (5)	0.000 (5)	0.010 (5)
O6	0.040 (6)	0.061 (6)	0.056 (6)	−0.011 (5)	0.011 (5)	−0.009 (5)
C21	0.034 (7)	0.030 (6)	0.038 (7)	−0.008 (5)	0.013 (6)	0.001 (5)
C22	0.046 (8)	0.061 (8)	0.056 (8)	−0.015 (7)	0.008 (7)	−0.003 (7)
F7	0.074 (9)	0.184 (14)	0.284 (17)	0.021 (10)	0.040 (11)	0.109 (13)
F8	0.125 (12)	0.205 (14)	0.172 (14)	−0.104 (11)	0.020 (10)	−0.056 (12)
F9	0.094 (9)	0.183 (12)	0.084 (8)	−0.081 (9)	0.015 (7)	0.028 (8)
O7	0.075 (7)	0.069 (6)	0.084 (7)	0.020 (6)	−0.015 (6)	−0.023 (6)
O8	0.088 (7)	0.056 (6)	0.046 (6)	0.010 (5)	−0.021 (6)	0.002 (5)
C23	0.055 (8)	0.043 (6)	0.033 (7)	0.013 (6)	0.009 (6)	−0.007 (6)
C24	0.070 (9)	0.073 (8)	0.051 (8)	0.022 (7)	−0.001 (7)	−0.003 (7)
F10	0.079 (8)	0.121 (9)	0.084 (8)	0.053 (7)	0.005 (7)	0.030 (7)
F11	0.216 (14)	0.088 (8)	0.074 (8)	0.080 (9)	−0.016 (9)	−0.027 (6)
F12	0.095 (9)	0.082 (8)	0.110 (9)	−0.006 (7)	−0.014 (8)	0.015 (7)
O9	0.054 (7)	0.078 (7)	0.079 (7)	−0.006 (6)	0.007 (6)	0.044 (6)
O10	0.043 (6)	0.065 (6)	0.030 (5)	0.000 (5)	−0.002 (4)	0.015 (4)
C25	0.030 (7)	0.041 (6)	0.042 (7)	−0.003 (5)	−0.008 (6)	0.007 (5)
C26	0.041 (7)	0.046 (7)	0.051 (7)	−0.014 (6)	−0.010 (6)	0.008 (6)
F13	0.185 (14)	0.120 (10)	0.084 (9)	−0.001 (10)	0.059 (9)	0.006 (8)
F14	0.097 (9)	0.083 (7)	0.074 (7)	−0.021 (6)	0.013 (6)	0.037 (6)
F15	0.075 (9)	0.230 (14)	0.088 (9)	−0.062 (9)	−0.007 (7)	0.072 (9)
O11	0.048 (6)	0.039 (4)	0.031 (5)	−0.011 (4)	−0.012 (4)	0.014 (4)
O12	0.057 (6)	0.032 (4)	0.039 (5)	−0.004 (4)	−0.011 (5)	0.001 (4)
C27	0.031 (6)	0.025 (5)	0.029 (6)	−0.006 (5)	0.003 (5)	−0.004 (5)
C28	0.043 (7)	0.045 (6)	0.035 (7)	−0.003 (6)	0.004 (6)	0.011 (6)
F16	0.133 (10)	0.048 (5)	0.079 (7)	−0.024 (6)	−0.056 (7)	0.036 (5)
F17	0.103 (8)	0.033 (4)	0.067 (6)	−0.008 (5)	−0.001 (6)	−0.010 (4)
F18	0.074 (8)	0.075 (7)	0.133 (10)	−0.028 (6)	0.045 (7)	−0.004 (7)
O13	0.054 (6)	0.046 (5)	0.061 (6)	0.008 (5)	0.017 (5)	0.003 (5)
O14	0.048 (6)	0.047 (5)	0.069 (6)	0.006 (5)	0.006 (5)	0.012 (5)
C29	0.044 (7)	0.039 (6)	0.037 (7)	0.007 (6)	−0.008 (6)	0.005 (5)
C30	0.066 (9)	0.060 (8)	0.051 (8)	0.004 (7)	0.011 (7)	0.010 (7)
F19	0.078 (9)	0.124 (10)	0.222 (15)	0.001 (8)	0.060 (10)	0.066 (10)
F20	0.087 (9)	0.220 (14)	0.059 (7)	0.026 (9)	0.027 (7)	−0.029 (9)
F21	0.038 (6)	0.092 (7)	0.076 (7)	0.010 (5)	0.001 (5)	−0.018 (6)
O15	0.055 (6)	0.031 (4)	0.058 (6)	−0.002 (4)	−0.009 (5)	−0.005 (4)
O16	0.058 (6)	0.038 (5)	0.053 (6)	0.001 (5)	−0.009 (5)	0.004 (4)
C31	0.040 (7)	0.025 (5)	0.043 (7)	−0.002 (5)	−0.005 (6)	0.002 (5)
C32	0.039 (7)	0.032 (6)	0.055 (8)	0.003 (6)	−0.010 (6)	0.000 (6)
F22	0.143 (11)	0.043 (5)	0.102 (9)	0.001 (6)	0.005 (8)	−0.035 (6)
F23	0.072 (8)	0.048 (5)	0.140 (10)	−0.016 (5)	0.004 (7)	0.025 (6)
F24	0.124 (10)	0.039 (5)	0.116 (9)	−0.014 (6)	−0.063 (8)	0.025 (5)

Geometric parameters (Å, º)

Ag1—O1	2.228 (9)	C33—H33C	0.9800
Ag1—C1	2.277 (11)	C34—H34A	0.9800
Ag1—C1^i	2.478 (11)	C34—H34B	0.9800
Ag1—O5^i	2.594 (11)	C34—H34C	0.9800
Ag1—Ag1^i	2.7796 (18)	S2—O18	1.509 (10)
Ag1—Ag4	2.8863 (15)	S2—C35	1.772 (17)
Ag1—Ag3	2.9366 (13)	S2—C36	1.806 (19)
Ag1—Ag2	3.0012 (14)	C35—H35A	0.9800
Ag1—Ag4^i	3.2113 (13)	C35—H35B	0.9800
Ag2—O6^i	2.268 (11)	C35—H35C	0.9800
Ag2—O3^i	2.272 (9)	C36—H36A	0.9800
Ag2—C1	2.343 (11)	C36—H36B	0.9800
Ag2—O17	2.514 (13)	C36—H36C	0.9800
Ag2—C2	2.678 (11)	S3—O19	1.536 (9)
Ag2—Ag3	3.0265 (14)	S3—C37	1.760 (16)
Ag2—Ag4^i	3.3140 (17)	S3—C38	1.775 (14)
Ag3—O18	2.324 (9)	C37—H37A	0.9800
Ag3—O2	2.327 (9)	C37—H37B	0.9800
Ag3—C1	2.371 (11)	C37—H37C	0.9800
Ag3—O19	2.465 (10)	C38—H38A	0.9800
Ag4—O4	2.227 (8)	C38—H38B	0.9800
Ag4—C1	2.294 (11)	C38—H38C	0.9800
Ag4—O20	2.489 (9)	S4—O20	1.497 (10)
Ag4—O5	2.572 (10)	S4—C40	1.798 (15)
Ag4—Ag1^i	3.2113 (13)	S4—C39	1.806 (18)
Ag4—Ag2^i	3.3141 (16)	C39—H39A	0.9800
Ag5—C11	2.253 (13)	C39—H39B	0.9800
Ag5—C5	2.253 (12)	C39—H39C	0.9800
Ag5—O9	2.381 (12)	C40—H40A	0.9800
Ag5—O7	2.407 (12)	C40—H40B	0.9800
Ag5—Ag7	2.8597 (14)	C40—H40C	0.9800
Ag5—Ag9	2.8776 (14)	S5—O21	1.516 (10)
Ag5—Ag10	2.9849 (15)	S5—C42	1.745 (18)
Ag5—Ag8	3.0235 (15)	S5—C41	1.80 (2)
Ag5—Ag11	3.2766 (15)	O21—Ag10^ii	2.595 (10)
Ag5—Ag6	3.3611 (14)	C41—H41A	0.9800
Ag6—O8	2.260 (11)	C41—H41B	0.9800
Ag6—O20	2.334 (9)	C41—H41C	0.9800
Ag6—C5	2.363 (11)	C42—H42A	0.9800
Ag6—O19	2.419 (10)	C42—H42B	0.9800
Ag6—C4	2.518 (11)	C42—H42C	0.9800
Ag6—Ag7	2.9412 (15)	S6—O22	1.546 (11)
Ag7—O11	2.158 (9)	S6—C43	1.77 (2)
Ag7—C5	2.172 (12)	S6—C44	1.82 (2)
Ag7—O18	2.416 (9)	O22—Ag9^ii	2.492 (10)
Ag7—Ag8	2.8699 (13)	C43—H43A	0.9800
Ag7—Ag10	3.0080 (14)	C43—H43B	0.9800
Ag8—O13	2.263 (11)	C43—H43C	0.9800
Ag8—C5	2.271 (12)	C44—H44A	0.9800
Ag8—O15	2.335 (9)	C44—H44B	0.9800
Ag8—Ag10	3.0069 (14)	C44—H44C	0.9800
Ag8—Ag9	3.1693 (16)	O1—C17	1.230 (15)
Ag9—C11	2.175 (13)	O2—C17	1.257 (15)
Ag9—O16	2.193 (10)	C17—C18	1.541 (17)
Ag9—O22'^ii	2.492 (10)	C18—F2	1.283 (9)
Ag9—O22^ii	2.492 (10)	C18—F3	1.291 (9)
Ag9—Ag10	2.9894 (15)	C18—F1	1.301 (9)
Ag9—Ag11	3.0545 (17)	O3—C19	1.216 (15)
Ag10—O14	2.232 (11)	O3—Ag2^i	2.272 (9)
Ag10—C11	2.231 (14)	O4—C19	1.246 (15)
Ag10—O12	2.377 (9)	C19—C20	1.559 (16)
Ag10—O21^ii	2.595 (10)	C20—F4	1.281 (9)
Ag11—O10	2.263 (10)	C20—F5	1.291 (9)
Ag11—O21	2.330 (10)	C20—F6	1.298 (9)
Ag11—C11	2.359 (14)	O5—C21	1.240 (17)
Ag11—C12	2.510 (13)	O5—Ag1^i	2.594 (11)
Ag11—O22	2.555 (9)	O6—C21	1.263 (17)
C1—C2	1.226 (15)	O6—Ag2^i	2.268 (11)
C1—Ag1^i	2.478 (11)	C21—C22	1.532 (19)
C2—C3	1.428 (16)	C22—F7	1.273 (9)
C3—C6	1.341 (16)	C22—F9	1.282 (9)
C3—C4	1.472 (15)	C22—F8	1.303 (9)
C4—C5	1.216 (16)	O7—C23	1.217 (19)
C6—C7	1.489 (17)	O8—C23	1.212 (18)
C6—C10	1.534 (17)	C23—C24	1.56 (2)
C7—C8	1.51 (2)	C24—F10	1.291 (9)
C7—H7A	0.9900	C24—F11	1.293 (9)
C7—H7B	0.9900	C24—F12	1.295 (10)
C8—C9	1.50 (2)	O9—C25	1.218 (18)
C8—H8A	0.9900	O10—C25	1.270 (16)
C8—H8B	0.9900	C25—C26	1.53 (2)
C9—C10	1.53 (2)	C26—F15	1.276 (9)
C9—H9A	0.9900	C26—F14	1.290 (9)
C9—H9B	0.9900	C26—F13	1.304 (9)
C10—H10A	0.9900	O11—C27	1.288 (15)
C10—H10B	0.9900	O12—C27	1.223 (15)
C11—C12	1.208 (17)	C27—C28	1.540 (16)
C12—C13	1.432 (15)	C28—F16	1.287 (9)
C13—C14	1.37 (2)	C28—F18	1.297 (9)
C13—C12^ii	1.432 (15)	C28—F17	1.306 (9)
C14—C15^ii	1.500 (15)	O13—C29	1.226 (17)
C14—C15	1.500 (15)	O14—C29	1.226 (17)
C15—C16	1.52 (2)	C29—C30	1.55 (2)
C15—H15A	0.9900	C30—F19	1.289 (9)
C15—H15B	0.9900	C30—F21	1.292 (9)
C16—C16^ii	1.33 (4)	C30—F20	1.293 (9)
C16—H16A	0.9900	O15—C31	1.234 (17)
C16—H16B	0.9900	O16—C31	1.219 (17)
S1—O17	1.490 (14)	C31—C32	1.564 (16)
S1—C33	1.75 (2)	C32—F23	1.288 (9)
S1—C34	1.76 (2)	C32—F24	1.292 (9)
C33—H33A	0.9800	C32—F22	1.300 (9)
C33—H33B	0.9800
O1—Ag1—C1	129.1 (4)	Ag1—C1—Ag4	78.3 (3)
O1—Ag1—C1^i	116.2 (3)	C2—C1—Ag2	91.8 (8)
C1—Ag1—C1^i	108.6 (3)	Ag1—C1—Ag2	81.0 (4)
O1—Ag1—O5^i	88.4 (4)	Ag4—C1—Ag2	159.2 (5)
C1—Ag1—O5^i	121.3 (4)	C2—C1—Ag3	92.7 (7)
C1^i—Ag1—O5^i	82.3 (4)	Ag1—C1—Ag3	78.4 (3)
O1—Ag1—Ag1^i	155.5 (3)	Ag4—C1—Ag3	93.6 (4)
C1—Ag1—Ag1^i	57.7 (3)	Ag2—C1—Ag3	79.9 (4)
C1^i—Ag1—Ag1^i	50.9 (3)	C2—C1—Ag1^i	116.9 (8)
O5^i—Ag1—Ag1^i	107.8 (2)	Ag1—C1—Ag1^i	71.4 (3)
O1—Ag1—Ag4	96.9 (3)	Ag4—C1—Ag1^i	84.5 (4)
C1—Ag1—Ag4	51.1 (3)	Ag2—C1—Ag1^i	91.1 (4)
C1^i—Ag1—Ag4	100.1 (3)	Ag3—C1—Ag1^i	149.5 (5)
O5^i—Ag1—Ag4	172.3 (2)	C1—C2—C3	178.2 (12)
Ag1^i—Ag1—Ag4	69.02 (4)	C1—C2—Ag2	61.0 (7)
O1—Ag1—Ag3	82.8 (2)	C3—C2—Ag2	120.8 (8)
C1—Ag1—Ag3	52.2 (3)	C6—C3—C2	125.4 (10)
C1^i—Ag1—Ag3	160.5 (3)	C6—C3—C4	121.2 (10)
O5^i—Ag1—Ag3	103.9 (2)	C2—C3—C4	113.3 (10)
Ag1^i—Ag1—Ag3	109.79 (5)	C5—C4—C3	176.5 (13)
Ag4—Ag1—Ag3	71.47 (4)	C5—C4—Ag6	68.6 (7)
O1—Ag1—Ag2	130.8 (3)	C3—C4—Ag6	114.6 (8)
C1—Ag1—Ag2	50.5 (3)	C4—C5—Ag7	137.2 (10)
C1^i—Ag1—Ag2	104.9 (3)	C4—C5—Ag5	139.9 (10)
O5^i—Ag1—Ag2	70.8 (2)	Ag7—C5—Ag5	80.5 (4)
Ag1^i—Ag1—Ag2	73.00 (4)	C4—C5—Ag8	111.1 (9)
Ag4—Ag1—Ag2	101.52 (4)	Ag7—C5—Ag8	80.5 (4)
Ag3—Ag1—Ag2	61.28 (4)	Ag5—C5—Ag8	83.9 (4)
O1—Ag1—Ag4^i	132.8 (3)	C4—C5—Ag6	82.8 (8)
C1—Ag1—Ag4^i	95.8 (3)	Ag7—C5—Ag6	80.8 (4)
C1^i—Ag1—Ag4^i	45.3 (3)	Ag5—C5—Ag6	93.4 (4)
O5^i—Ag1—Ag4^i	51.3 (2)	Ag8—C5—Ag6	161.2 (6)
Ag1^i—Ag1—Ag4^i	57.06 (4)	C3—C6—C7	126.4 (11)
Ag4—Ag1—Ag4^i	126.08 (3)	C3—C6—C10	124.8 (11)
Ag3—Ag1—Ag4^i	125.35 (4)	C7—C6—C10	108.7 (11)
Ag2—Ag1—Ag4^i	64.37 (3)	C6—C7—C8	105.2 (12)
O6^i—Ag2—O3^i	113.2 (4)	C6—C7—H7A	110.7
O6^i—Ag2—C1	126.2 (4)	C8—C7—H7A	110.7
O3^i—Ag2—C1	116.6 (4)	C6—C7—H7B	110.7
O6^i—Ag2—O17	93.1 (4)	C8—C7—H7B	110.7
O3^i—Ag2—O17	94.7 (4)	H7A—C7—H7B	108.8
C1—Ag2—O17	101.6 (4)	C9—C8—C7	103.5 (13)
O6^i—Ag2—C2	142.7 (4)	C9—C8—H8A	111.1
O3^i—Ag2—C2	103.7 (3)	C7—C8—H8A	111.1
C1—Ag2—C2	27.2 (4)	C9—C8—H8B	111.1
O17—Ag2—C2	79.0 (4)	C7—C8—H8B	111.1
O6^i—Ag2—Ag1	84.0 (3)	H8A—C8—H8B	109.0
O3^i—Ag2—Ag1	129.9 (3)	C8—C9—C10	105.6 (12)
C1—Ag2—Ag1	48.5 (3)	C8—C9—H9A	110.6
O17—Ag2—Ag1	132.5 (3)	C10—C9—H9A	110.6
C2—Ag2—Ag1	75.6 (2)	C8—C9—H9B	110.6
O6^i—Ag2—Ag3	86.2 (3)	C10—C9—H9B	110.6
O3^i—Ag2—Ag3	158.5 (3)	H9A—C9—H9B	108.7
C1—Ag2—Ag3	50.5 (3)	C9—C10—C6	103.4 (11)
O17—Ag2—Ag3	74.2 (3)	C9—C10—H10A	111.1
C2—Ag2—Ag3	56.6 (2)	C6—C10—H10A	111.1
Ag1—Ag2—Ag3	58.31 (3)	C9—C10—H10B	111.1
O6^i—Ag2—Ag4^i	82.7 (3)	C6—C10—H10B	111.1
O3^i—Ag2—Ag4^i	74.7 (2)	H10A—C10—H10B	109.0
C1—Ag2—Ag4^i	91.9 (3)	C12—C11—Ag9	132.8 (11)
O17—Ag2—Ag4^i	165.7 (3)	C12—C11—Ag10	107.5 (11)
C2—Ag2—Ag4^i	112.5 (2)	Ag9—C11—Ag10	85.4 (5)
Ag1—Ag2—Ag4^i	60.89 (3)	C12—C11—Ag5	144.1 (11)
Ag3—Ag2—Ag4^i	118.94 (4)	Ag9—C11—Ag5	81.0 (4)
O18—Ag3—O2	89.9 (3)	Ag10—C11—Ag5	83.5 (5)
O18—Ag3—C1	144.2 (3)	C12—C11—Ag11	82.7 (9)
O2—Ag3—C1	125.5 (3)	Ag9—C11—Ag11	84.6 (5)
O18—Ag3—O19	88.2 (3)	Ag10—C11—Ag11	169.0 (6)
O2—Ag3—O19	91.7 (3)	Ag5—C11—Ag11	90.5 (5)
C1—Ag3—O19	95.0 (4)	C11—C12—C13	166.7 (13)
O18—Ag3—Ag1	162.6 (2)	C11—C12—Ag11	68.8 (9)
O2—Ag3—Ag1	76.4 (2)	C13—C12—Ag11	114.0 (7)
C1—Ag3—Ag1	49.4 (3)	C14—C13—C12	123.2 (7)
O19—Ag3—Ag1	102.7 (3)	C14—C13—C12^ii	123.2 (7)
O18—Ag3—Ag2	117.1 (2)	C12—C13—C12^ii	113.5 (14)
O2—Ag3—Ag2	111.8 (3)	C13—C14—C15^ii	124.0 (8)
C1—Ag3—Ag2	49.7 (3)	C13—C14—C15	124.0 (8)
O19—Ag3—Ag2	144.4 (2)	C15^ii—C14—C15	111.9 (16)
Ag1—Ag3—Ag2	60.42 (3)	C14—C15—C16	101.5 (13)
O4—Ag4—C1	148.8 (4)	C14—C15—H15A	111.5
O4—Ag4—O20	94.7 (3)	C16—C15—H15A	111.5
C1—Ag4—O20	106.4 (4)	C14—C15—H15B	111.5
O4—Ag4—O5	118.4 (4)	C16—C15—H15B	111.5
C1—Ag4—O5	86.5 (4)	H15A—C15—H15B	109.3
O20—Ag4—O5	85.5 (3)	C16^ii—C16—C15	112.3 (9)
O4—Ag4—Ag1	101.8 (3)	C16^ii—C16—H16A	109.1
C1—Ag4—Ag1	50.6 (3)	C15—C16—H16A	109.1
O20—Ag4—Ag1	152.5 (2)	C16^ii—C16—H16B	109.1
O5—Ag4—Ag1	105.3 (3)	C15—C16—H16B	109.1
O4—Ag4—Ag1^i	130.1 (2)	H16A—C16—H16B	107.9
C1—Ag4—Ag1^i	50.2 (3)	O17—S1—C33	105.9 (10)
O20—Ag4—Ag1^i	127.3 (2)	O17—S1—C34	105.7 (9)
O5—Ag4—Ag1^i	51.9 (3)	C33—S1—C34	98.7 (10)
Ag1—Ag4—Ag1^i	53.92 (3)	S1—O17—Ag2	124.1 (7)
O4—Ag4—Ag2^i	76.2 (2)	S1—C33—H33A	109.5
C1—Ag4—Ag2^i	100.3 (3)	S1—C33—H33B	109.5
O20—Ag4—Ag2^i	139.2 (2)	H33A—C33—H33B	109.5
O5—Ag4—Ag2^i	65.8 (2)	S1—C33—H33C	109.5
Ag1—Ag4—Ag2^i	67.06 (3)	H33A—C33—H33C	109.5
Ag1^i—Ag4—Ag2^i	54.74 (3)	H33B—C33—H33C	109.5
C11—Ag5—C5	142.8 (5)	S1—C34—H34A	109.5
C11—Ag5—O9	114.3 (5)	S1—C34—H34B	109.5
C5—Ag5—O9	93.9 (4)	H34A—C34—H34B	109.5
C11—Ag5—O7	90.9 (5)	S1—C34—H34C	109.5
C5—Ag5—O7	113.9 (4)	H34A—C34—H34C	109.5
O9—Ag5—O7	89.9 (5)	H34B—C34—H34C	109.5
C11—Ag5—Ag7	107.0 (4)	O18—S2—C35	105.3 (8)
C5—Ag5—Ag7	48.5 (3)	O18—S2—C36	104.4 (8)
O9—Ag5—Ag7	138.6 (3)	C35—S2—C36	97.4 (10)
O7—Ag5—Ag7	91.4 (3)	S2—O18—Ag3	129.8 (5)
C11—Ag5—Ag9	48.3 (3)	S2—O18—Ag7	118.5 (5)
C5—Ag5—Ag9	109.6 (3)	Ag3—O18—Ag7	111.6 (4)
O9—Ag5—Ag9	93.3 (4)	S2—C35—H35A	109.5
O7—Ag5—Ag9	136.1 (3)	S2—C35—H35B	109.5
Ag7—Ag5—Ag9	113.39 (5)	H35A—C35—H35B	109.5
C11—Ag5—Ag10	48.0 (4)	S2—C35—H35C	109.5
C5—Ag5—Ag10	96.8 (3)	H35A—C35—H35C	109.5
O9—Ag5—Ag10	154.5 (4)	H35B—C35—H35C	109.5
O7—Ag5—Ag10	106.7 (4)	S2—C36—H36A	109.5
Ag7—Ag5—Ag10	61.91 (4)	S2—C36—H36B	109.5
Ag9—Ag5—Ag10	61.28 (4)	H36A—C36—H36B	109.5
C11—Ag5—Ag8	96.5 (4)	S2—C36—H36C	109.5
C5—Ag5—Ag8	48.3 (3)	H36A—C36—H36C	109.5
O9—Ag5—Ag8	113.2 (3)	H36B—C36—H36C	109.5
O7—Ag5—Ag8	149.7 (3)	O19—S3—C37	104.1 (7)
Ag7—Ag5—Ag8	58.31 (3)	O19—S3—C38	104.3 (6)
Ag9—Ag5—Ag8	64.91 (4)	C37—S3—C38	99.4 (9)
Ag10—Ag5—Ag8	60.05 (3)	S3—O19—Ag6	132.5 (6)
C11—Ag5—Ag11	46.1 (4)	S3—O19—Ag3	121.5 (5)
C5—Ag5—Ag11	157.7 (3)	Ag6—O19—Ag3	103.5 (3)
O9—Ag5—Ag11	69.3 (3)	S3—C37—H37A	109.5
O7—Ag5—Ag11	81.6 (3)	S3—C37—H37B	109.5
Ag7—Ag5—Ag11	151.55 (4)	H37A—C37—H37B	109.5
Ag9—Ag5—Ag11	59.09 (4)	S3—C37—H37C	109.5
Ag10—Ag5—Ag11	93.63 (4)	H37A—C37—H37C	109.5
Ag8—Ag5—Ag11	123.95 (4)	H37B—C37—H37C	109.5
C11—Ag5—Ag6	152.4 (3)	S3—C38—H38A	109.5
C5—Ag5—Ag6	44.6 (3)	S3—C38—H38B	109.5
O9—Ag5—Ag6	86.3 (3)	H38A—C38—H38B	109.5
O7—Ag5—Ag6	70.0 (3)	S3—C38—H38C	109.5
Ag7—Ag5—Ag6	55.73 (3)	H38A—C38—H38C	109.5
Ag9—Ag5—Ag6	153.95 (4)	H38B—C38—H38C	109.5
Ag10—Ag5—Ag6	117.25 (4)	O20—S4—C40	106.0 (8)
Ag8—Ag5—Ag6	91.30 (4)	O20—S4—C39	103.9 (7)
Ag11—Ag5—Ag6	142.51 (5)	C40—S4—C39	99.0 (9)
O8—Ag6—O20	109.5 (4)	S4—O20—Ag6	129.3 (5)
O8—Ag6—C5	115.9 (4)	S4—O20—Ag4	120.4 (5)
O20—Ag6—C5	132.0 (4)	Ag6—O20—Ag4	106.7 (4)
O8—Ag6—O19	96.7 (4)	S4—C39—H39A	109.5
O20—Ag6—O19	78.6 (3)	S4—C39—H39B	109.5
C5—Ag6—O19	110.0 (4)	H39A—C39—H39B	109.5
O8—Ag6—C4	144.0 (4)	S4—C39—H39C	109.5
O20—Ag6—C4	103.8 (3)	H39A—C39—H39C	109.5
C5—Ag6—C4	28.6 (4)	H39B—C39—H39C	109.5
O19—Ag6—C4	103.2 (3)	S4—C40—H40A	109.5
O8—Ag6—Ag7	82.4 (3)	S4—C40—H40B	109.5
O20—Ag6—Ag7	159.4 (2)	H40A—C40—H40B	109.5
C5—Ag6—Ag7	46.8 (3)	S4—C40—H40C	109.5
O19—Ag6—Ag7	83.5 (3)	H40A—C40—H40C	109.5
C4—Ag6—Ag7	70.6 (3)	H40B—C40—H40C	109.5
O8—Ag6—Ag5	78.9 (3)	O21—S5—C42	107.2 (8)
O20—Ag6—Ag5	143.6 (2)	O21—S5—C41	102.8 (9)
C5—Ag6—Ag5	42.0 (3)	C42—S5—C41	96.5 (10)
O19—Ag6—Ag5	137.0 (3)	S5—O21—Ag11	123.7 (6)
C4—Ag6—Ag5	66.0 (2)	S5—O21—Ag10^ii	112.5 (5)
Ag7—Ag6—Ag5	53.47 (3)	Ag11—O21—Ag10^ii	121.0 (4)
O11—Ag7—C5	168.6 (4)	S5—C41—H41A	109.5
O11—Ag7—O18	90.8 (3)	S5—C41—H41B	109.5
C5—Ag7—O18	98.2 (4)	H41A—C41—H41B	109.5
O11—Ag7—Ag5	121.1 (3)	S5—C41—H41C	109.5
C5—Ag7—Ag5	51.0 (3)	H41A—C41—H41C	109.5
O18—Ag7—Ag5	147.8 (2)	H41B—C41—H41C	109.5
O11—Ag7—Ag8	136.2 (3)	S5—C42—H42A	109.5
C5—Ag7—Ag8	51.3 (3)	S5—C42—H42B	109.5
O18—Ag7—Ag8	90.6 (2)	H42A—C42—H42B	109.5
Ag5—Ag7—Ag8	63.70 (4)	S5—C42—H42C	109.5
O11—Ag7—Ag6	119.2 (3)	H42A—C42—H42C	109.5
C5—Ag7—Ag6	52.5 (3)	H42B—C42—H42C	109.5
O18—Ag7—Ag6	99.3 (2)	O22—S6—C43	106.0 (9)
Ag5—Ag7—Ag6	70.80 (4)	O22—S6—C44	101.3 (9)
Ag8—Ag7—Ag6	103.75 (4)	C43—S6—C44	99.2 (12)
O11—Ag7—Ag10	82.5 (2)	S6—O22—Ag9^ii	111.3 (6)
C5—Ag7—Ag10	97.9 (3)	S6—O22—Ag11	132.2 (7)
O18—Ag7—Ag10	125.0 (2)	Ag9^ii—O22—Ag11	112.4 (3)
Ag5—Ag7—Ag10	61.09 (3)	S6—C43—H43A	109.5
Ag8—Ag7—Ag10	61.48 (3)	S6—C43—H43B	109.5
Ag6—Ag7—Ag10	131.38 (5)	H43A—C43—H43B	109.5
O13—Ag8—C5	141.1 (4)	S6—C43—H43C	109.5
O13—Ag8—O15	93.9 (4)	H43A—C43—H43C	109.5
C5—Ag8—O15	117.7 (4)	H43B—C43—H43C	109.5
O13—Ag8—Ag7	98.9 (3)	S6—C44—H44A	109.5
C5—Ag8—Ag7	48.3 (3)	S6—C44—H44B	109.5
O15—Ag8—Ag7	166.0 (3)	H44A—C44—H44B	109.5
O13—Ag8—Ag10	80.4 (3)	S6—C44—H44C	109.5
C5—Ag8—Ag10	95.8 (3)	H44A—C44—H44C	109.5
O15—Ag8—Ag10	127.0 (3)	H44B—C44—H44C	109.5
Ag7—Ag8—Ag10	61.52 (3)	C17—O1—Ag1	120.3 (8)
O13—Ag8—Ag5	139.2 (3)	C17—O2—Ag3	121.4 (9)
C5—Ag8—Ag5	47.8 (3)	O1—C17—O2	129.1 (12)
O15—Ag8—Ag5	114.5 (3)	O1—C17—C18	115.5 (11)
Ag7—Ag8—Ag5	57.99 (3)	O2—C17—C18	115.3 (11)
Ag10—Ag8—Ag5	59.34 (3)	F2—C18—F3	108.6 (9)
O13—Ag8—Ag9	109.8 (3)	F2—C18—F1	106.6 (9)
C5—Ag8—Ag9	100.1 (3)	F3—C18—F1	106.3 (9)
O15—Ag8—Ag9	75.8 (3)	F2—C18—C17	110.4 (10)
Ag7—Ag8—Ag9	105.01 (4)	F3—C18—C17	113.3 (10)
Ag10—Ag8—Ag9	57.83 (3)	F1—C18—C17	111.4 (10)
Ag5—Ag8—Ag9	55.32 (3)	C19—O3—Ag2^i	126.7 (8)
C11—Ag9—O16	161.0 (5)	C19—O4—Ag4	125.0 (8)
C11—Ag9—O22'^ii	106.7 (4)	O3—C19—O4	132.0 (11)
O16—Ag9—O22'^ii	92.1 (4)	O3—C19—C20	114.4 (11)
C11—Ag9—O22^ii	106.7 (4)	O4—C19—C20	113.6 (10)
O16—Ag9—O22^ii	92.1 (4)	F4—C20—F5	108.0 (9)
C11—Ag9—Ag5	50.7 (3)	F4—C20—F6	107.5 (9)
O16—Ag9—Ag5	111.6 (3)	F5—C20—F6	106.1 (9)
O22'^ii—Ag9—Ag5	154.1 (2)	F4—C20—C19	113.5 (10)
O22^ii—Ag9—Ag5	154.1 (2)	F5—C20—C19	108.8 (10)
C11—Ag9—Ag10	48.1 (4)	F6—C20—C19	112.6 (10)
O16—Ag9—Ag10	135.0 (3)	C21—O5—Ag4	122.7 (9)
O22'^ii—Ag9—Ag10	94.9 (2)	C21—O5—Ag1^i	112.0 (9)
O22^ii—Ag9—Ag10	94.9 (2)	Ag4—O5—Ag1^i	76.9 (3)
Ag5—Ag9—Ag10	61.13 (3)	C21—O6—Ag2^i	116.7 (9)
C11—Ag9—Ag11	50.3 (4)	O5—C21—O6	129.7 (14)
O16—Ag9—Ag11	120.5 (3)	O5—C21—C22	113.4 (12)
O22'^ii—Ag9—Ag11	110.5 (2)	O6—C21—C22	116.6 (12)
O22^ii—Ag9—Ag11	110.5 (2)	F7—C22—F9	109.3 (10)
Ag5—Ag9—Ag11	66.98 (4)	F7—C22—F8	106.4 (10)
Ag10—Ag9—Ag11	98.24 (4)	F9—C22—F8	105.1 (9)
C11—Ag9—Ag8	94.1 (4)	F7—C22—C21	110.3 (12)
O16—Ag9—Ag8	79.2 (3)	F9—C22—C21	113.8 (11)
O22'^ii—Ag9—Ag8	118.0 (2)	F8—C22—C21	111.6 (12)
O22^ii—Ag9—Ag8	118.0 (2)	C23—O7—Ag5	126.4 (11)
Ag5—Ag9—Ag8	59.77 (3)	C23—O8—Ag6	123.3 (10)
Ag10—Ag9—Ag8	58.36 (3)	O8—C23—O7	131.3 (15)
Ag11—Ag9—Ag8	126.70 (5)	O8—C23—C24	114.9 (13)
O14—Ag10—C11	168.5 (4)	O7—C23—C24	113.8 (14)
O14—Ag10—O12	88.9 (4)	F10—C24—F11	107.6 (9)
C11—Ag10—O12	102.1 (4)	F10—C24—F12	107.8 (9)
O14—Ag10—O21^ii	81.1 (4)	F11—C24—F12	107.4 (10)
C11—Ag10—O21^ii	95.2 (4)	F10—C24—C23	112.7 (12)
O12—Ag10—O21^ii	90.5 (3)	F11—C24—C23	112.2 (11)
O14—Ag10—Ag5	132.5 (3)	F12—C24—C23	108.9 (11)
C11—Ag10—Ag5	48.6 (3)	C25—O9—Ag5	131.7 (10)
O12—Ag10—Ag5	103.4 (3)	C25—O10—Ag11	119.7 (10)
O21^ii—Ag10—Ag5	142.9 (2)	O9—C25—O10	127.2 (15)
O14—Ag10—Ag9	122.5 (3)	O9—C25—C26	116.3 (12)
C11—Ag10—Ag9	46.5 (3)	O10—C25—C26	116.3 (12)
O12—Ag10—Ag9	148.6 (3)	F15—C26—F14	108.2 (9)
O21^ii—Ag10—Ag9	93.3 (2)	F15—C26—F13	107.5 (10)
Ag5—Ag10—Ag9	57.59 (3)	F14—C26—F13	106.4 (9)
O14—Ag10—Ag8	77.2 (3)	F15—C26—C25	112.7 (11)
C11—Ag10—Ag8	97.5 (3)	F14—C26—C25	112.4 (11)
O12—Ag10—Ag8	132.4 (2)	F13—C26—C25	109.3 (11)
O21^ii—Ag10—Ag8	130.5 (2)	C27—O11—Ag7	123.8 (8)
Ag5—Ag10—Ag8	60.61 (3)	C27—O12—Ag10	123.2 (8)
Ag9—Ag10—Ag8	63.81 (4)	O12—C27—O11	128.0 (11)
O14—Ag10—Ag7	82.9 (3)	O12—C27—C28	119.1 (11)
C11—Ag10—Ag7	102.9 (3)	O11—C27—C28	112.9 (10)
O12—Ag10—Ag7	76.4 (2)	F16—C28—F18	108.1 (9)
O21^ii—Ag10—Ag7	159.4 (2)	F16—C28—F17	107.2 (9)
Ag5—Ag10—Ag7	57.00 (3)	F18—C28—F17	106.6 (9)
Ag9—Ag10—Ag7	106.17 (4)	F16—C28—C27	112.2 (9)
Ag8—Ag10—Ag7	57.00 (3)	F18—C28—C27	109.0 (10)
O10—Ag11—O21	103.8 (4)	F17—C28—C27	113.4 (9)
O10—Ag11—C11	124.3 (4)	C29—O13—Ag8	120.6 (10)
O21—Ag11—C11	125.4 (4)	C29—O14—Ag10	126.0 (11)
O10—Ag11—C12	141.1 (4)	O13—C29—O14	129.6 (16)
O21—Ag11—C12	97.4 (4)	O13—C29—C30	116.5 (12)
C11—Ag11—C12	28.5 (4)	O14—C29—C30	113.9 (13)
O10—Ag11—O22	110.2 (4)	F19—C30—F21	107.2 (10)
O21—Ag11—O22	88.5 (3)	F19—C30—F20	107.6 (10)
C11—Ag11—O22	96.5 (4)	F21—C30—F20	107.4 (9)
C12—Ag11—O22	102.5 (4)	F19—C30—C29	113.6 (11)
O10—Ag11—Ag9	113.3 (3)	F21—C30—C29	112.8 (10)
O21—Ag11—Ag9	136.3 (2)	F20—C30—C29	107.9 (11)
C11—Ag11—Ag9	45.1 (3)	C31—O15—Ag8	123.5 (9)
C12—Ag11—Ag9	67.5 (3)	C31—O16—Ag9	127.1 (10)
O22—Ag11—Ag9	58.1 (2)	O16—C31—O15	130.8 (13)
O10—Ag11—Ag5	81.3 (3)	O16—C31—C32	113.9 (12)
O21—Ag11—Ag5	159.0 (3)	O15—C31—C32	115.0 (11)
C11—Ag11—Ag5	43.4 (3)	F23—C32—F24	107.0 (9)
C12—Ag11—Ag5	68.3 (3)	F23—C32—F22	108.0 (9)
O22—Ag11—Ag5	109.2 (2)	F24—C32—F22	106.8 (9)
Ag9—Ag11—Ag5	53.93 (3)	F23—C32—C31	111.7 (10)
C2—C1—Ag1	169.3 (10)	F24—C32—C31	113.1 (10)
C2—C1—Ag4	108.4 (8)	F22—C32—C31	110.1 (10)
Ag1—C1—C2—Ag2	47 (5)	Ag2^i—O3—C19—O4	−6 (2)
Ag4—C1—C2—Ag2	174.7 (8)	Ag2^i—O3—C19—C20	176.9 (8)
Ag3—C1—C2—Ag2	80.0 (4)	Ag4—O4—C19—O3	−19 (2)
Ag1^i—C1—C2—Ag2	−92.1 (7)	Ag4—O4—C19—C20	157.9 (8)
Ag2—C2—C3—C6	75.6 (14)	O3—C19—C20—F4	3.7 (16)
Ag2—C2—C3—C4	−100.8 (10)	O4—C19—C20—F4	−174.0 (12)
C6—C3—C4—Ag6	126.4 (11)	O3—C19—C20—F5	−116.5 (13)
C2—C3—C4—Ag6	−57.0 (12)	O4—C19—C20—F5	65.8 (14)
Ag6—C4—C5—Ag7	68.0 (12)	O3—C19—C20—F6	126.2 (13)
Ag6—C4—C5—Ag5	−86.8 (13)	O4—C19—C20—F6	−51.5 (15)
Ag6—C4—C5—Ag8	166.9 (8)	Ag4—O5—C21—O6	−40 (2)
C2—C3—C6—C7	0 (2)	Ag1^i—O5—C21—O6	48.3 (18)
C4—C3—C6—C7	176.1 (13)	Ag4—O5—C21—C22	146.6 (9)
C2—C3—C6—C10	−178.6 (12)	Ag1^i—O5—C21—C22	−125.2 (10)
C4—C3—C6—C10	−2 (2)	Ag2^i—O6—C21—O5	−7 (2)
C3—C6—C7—C8	−162.1 (14)	Ag2^i—O6—C21—C22	166.6 (9)
C10—C6—C7—C8	16.6 (16)	O5—C21—C22—F7	−86.7 (15)
C6—C7—C8—C9	−32.9 (18)	O6—C21—C22—F7	98.9 (15)
C7—C8—C9—C10	37.2 (19)	O5—C21—C22—F9	150.1 (13)
C8—C9—C10—C6	−26.6 (18)	O6—C21—C22—F9	−24.3 (17)
C3—C6—C10—C9	−175.3 (14)	O5—C21—C22—F8	31.4 (16)
C7—C6—C10—C9	6.0 (16)	O6—C21—C22—F8	−143.0 (14)
Ag9—C11—C12—C13	−29 (7)	Ag6—O8—C23—O7	1 (3)
Ag10—C11—C12—C13	71 (6)	Ag6—O8—C23—C24	−177.5 (9)
Ag5—C11—C12—C13	175 (4)	Ag5—O7—C23—O8	−33 (3)
Ag11—C11—C12—C13	−105 (6)	Ag5—O7—C23—C24	145.4 (11)
Ag9—C11—C12—Ag11	75.6 (13)	O8—C23—C24—F10	−152.3 (14)
Ag10—C11—C12—Ag11	175.9 (8)	O7—C23—C24—F10	28.7 (18)
Ag5—C11—C12—Ag11	−80.7 (18)	O8—C23—C24—F11	−30.5 (19)
C11—C12—C13—C14	−146 (6)	O7—C23—C24—F11	150.4 (14)
Ag11—C12—C13—C14	114.6 (5)	O8—C23—C24—F12	88.2 (16)
C11—C12—C13—C12^ii	34 (6)	O7—C23—C24—F12	−90.8 (16)
Ag11—C12—C13—C12^ii	−65.4 (5)	Ag5—O9—C25—O10	22 (3)
C12—C13—C14—C15^ii	179.9 (10)	Ag5—O9—C25—C26	−152.7 (10)
C12^ii—C13—C14—C15^ii	−0.1 (10)	Ag11—O10—C25—O9	14 (2)
C12—C13—C14—C15	−0.1 (10)	Ag11—O10—C25—C26	−171.3 (8)
C12^ii—C13—C14—C15	179.9 (10)	O9—C25—C26—F15	−158.1 (14)
C13—C14—C15—C16	178.2 (10)	O10—C25—C26—F15	26.4 (17)
C15^ii—C14—C15—C16	−1.8 (10)	O9—C25—C26—F14	−35.4 (17)
C14—C15—C16—C16^ii	6 (3)	O10—C25—C26—F14	149.0 (12)
C33—S1—O17—Ag2	69.1 (11)	O9—C25—C26—F13	82.5 (16)
C34—S1—O17—Ag2	−35.0 (12)	O10—C25—C26—F13	−93.1 (14)
C35—S2—O18—Ag3	18.1 (10)	Ag10—O12—C27—O11	−9 (2)
C36—S2—O18—Ag3	−83.9 (9)	Ag10—O12—C27—C28	170.9 (8)
C35—S2—O18—Ag7	−158.2 (8)	Ag7—O11—C27—O12	−16 (2)
C36—S2—O18—Ag7	99.7 (8)	Ag7—O11—C27—C28	164.3 (8)
C37—S3—O19—Ag6	−69.0 (11)	O12—C27—C28—F16	17.8 (16)
C38—S3—O19—Ag6	34.8 (10)	O11—C27—C28—F16	−162.5 (11)
C37—S3—O19—Ag3	89.8 (10)	O12—C27—C28—F18	−101.9 (14)
C38—S3—O19—Ag3	−166.4 (7)	O11—C27—C28—F18	77.8 (13)
C40—S4—O20—Ag6	60.5 (9)	O12—C27—C28—F17	139.4 (12)
C39—S4—O20—Ag6	−43.4 (10)	O11—C27—C28—F17	−40.8 (15)
C40—S4—O20—Ag4	−95.2 (8)	Ag8—O13—C29—O14	−9 (2)
C39—S4—O20—Ag4	160.9 (8)	Ag8—O13—C29—C30	169.3 (8)
C42—S5—O21—Ag11	−67.7 (10)	Ag10—O14—C29—O13	−16 (2)
C41—S5—O21—Ag11	33.4 (11)	Ag10—O14—C29—C30	165.2 (8)
C42—S5—O21—Ag10^ii	131.2 (7)	O13—C29—C30—F19	−162.5 (13)
C41—S5—O21—Ag10^ii	−127.7 (9)	O14—C29—C30—F19	16.4 (17)
C43—S6—O22—Ag9^ii	179.8 (9)	O13—C29—C30—F21	−40.2 (17)
C44—S6—O22—Ag9^ii	−77.1 (10)	O14—C29—C30—F21	138.7 (12)
C43—S6—O22—Ag11	−25.0 (12)	O13—C29—C30—F20	78.3 (15)
C44—S6—O22—Ag11	78.1 (11)	O14—C29—C30—F20	−102.8 (14)
Ag1—O1—C17—O2	5 (2)	Ag9—O16—C31—O15	0 (3)
Ag1—O1—C17—C18	−171.3 (8)	Ag9—O16—C31—C32	−174.3 (8)
Ag3—O2—C17—O1	25 (2)	Ag8—O15—C31—O16	18 (2)
Ag3—O2—C17—C18	−158.6 (8)	Ag8—O15—C31—C32	−167.3 (8)
O1—C17—C18—F2	97.6 (14)	O16—C31—C32—F23	−37.6 (16)
O2—C17—C18—F2	−79.4 (14)	O15—C31—C32—F23	146.9 (13)
O1—C17—C18—F3	−24.6 (17)	O16—C31—C32—F24	−158.4 (12)
O2—C17—C18—F3	158.4 (12)	O15—C31—C32—F24	26.1 (17)
O1—C17—C18—F1	−144.2 (13)	O16—C31—C32—F22	82.3 (15)
O2—C17—C18—F1	38.8 (16)	O15—C31—C32—F22	−93.2 (14)

Symmetry codes: (i) −x+3/2, −y+1/2, −z+1; (ii) −x+1, y, −z+1/2.

(II)

Crystal data

22(Ag^+)·3(C11H10^2^−)·16(C2F3O2^−)·12(C2H6SO)	Z = 4
Mr = 5545.56	F(000) = 10584
Monoclinic, C2/c	Dx = 2.469 Mg m^−3
a = 21.9927 (13) Å	Mo Kα radiation, λ = 0.71073 Å
b = 14.8488 (13) Å	µ = 3.11 mm^−1
c = 45.797 (3) Å	T = 173 K
β = 93.937 (2)°	Block, yellow
V = 14920.4 (19) Å^3	0.50 × 0.50 × 0.40 mm

Data collection

Bruker APEX-II CCD diffractometer	12140 reflections with I > 2σ(I)
φ and ω scan	Rint = 0.131
Absorption correction: multi-scan SADABS (Bruker, 2003)	θmax = 25.3°, θmin = 1.7°
Tmin = 0.305, Tmax = 0.369	h = −26→26
164822 measured reflections	k = −17→17
13506 independent reflections	l = −54→54

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.064	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.164	H-atom parameters constrained
S = 1.14	w = 1/[σ^2(Fo^2) + (0.0621P)^2 + 504.2735P] where P = (Fo^2 + 2Fc^2)/3
13506 reflections	(Δ/σ)max = 0.001
998 parameters	Δρmax = 2.34 e Å^−3
508 restraints	Δρmin = −2.24 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.78934 (3)	0.68328 (5)	0.49160 (2)	0.02263 (16)
Ag2	0.78734 (4)	0.82858 (6)	0.44754 (2)	0.0398 (2)
Ag3	0.75820 (3)	0.63562 (5)	0.42987 (2)	0.02748 (18)
Ag4	0.66586 (3)	0.61903 (5)	0.48612 (2)	0.02833 (18)
Ag5	0.55050 (3)	0.61107 (5)	0.34015 (2)	0.02221 (16)
Ag6	0.59408 (4)	0.55934 (5)	0.40930 (2)	0.03211 (19)
Ag7	0.66991 (3)	0.55186 (5)	0.35906 (2)	0.02186 (16)
Ag8	0.66011 (4)	0.72902 (5)	0.33473 (2)	0.02775 (18)
Ag9	0.63728 (3)	0.57202 (5)	0.29451 (2)	0.02596 (17)
Ag10	0.54797 (4)	0.72234 (5)	0.28909 (2)	0.02852 (18)
Ag11	0.43225 (4)	0.61153 (7)	0.29338 (2)	0.0451 (2)
C1	0.7103 (4)	0.7344 (6)	0.46118 (19)	0.0215 (19)
C2	0.6709 (4)	0.7559 (6)	0.44217 (19)	0.0168 (17)
C3	0.6234 (4)	0.7759 (6)	0.42031 (18)	0.0196 (18)
C4	0.6203 (4)	0.7146 (6)	0.39587 (18)	0.0155 (17)
C5	0.6209 (4)	0.6668 (6)	0.37422 (19)	0.0195 (18)
C6	0.5850 (4)	0.8460 (6)	0.4211 (2)	0.0240 (19)
C7	0.5346 (5)	0.8637 (7)	0.3981 (2)	0.031 (2)
H7A	0.4948	0.8596	0.4069	0.037*
H7B	0.5355	0.8180	0.3825	0.037*
C8	0.5423 (5)	0.9557 (8)	0.3855 (2)	0.038 (3)
H8A	0.5078	0.9682	0.3711	0.046*
H8B	0.5802	0.9572	0.3751	0.046*
C9	0.5450 (6)	1.0280 (8)	0.4085 (3)	0.048 (3)
H9A	0.5054	1.0314	0.4175	0.058*
H9B	0.5526	1.0869	0.3993	0.058*
C10	0.5953 (6)	1.0082 (8)	0.4320 (3)	0.042 (3)
H10A	0.5941	1.0539	0.4477	0.050*
H10B	0.6352	1.0132	0.4234	0.050*
C11	0.5894 (5)	0.9149 (7)	0.4452 (2)	0.036 (2)
H11A	0.6253	0.9021	0.4588	0.044*
H11B	0.5525	0.9121	0.4564	0.044*
C12	0.5352 (4)	0.5795 (6)	0.29225 (19)	0.0210 (18)
C13	0.5178 (4)	0.5226 (6)	0.2747 (2)	0.0238 (19)
C14	0.5000	0.4662 (9)	0.2500	0.024 (3)
C15	0.5000	0.3755 (12)	0.2500	0.053 (4)	0.5
C16	0.5015 (10)	0.3245 (11)	0.2799 (3)	0.027 (4)	0.5
H16A	0.5212	0.3611	0.2960	0.032*	0.5
H16B	0.4601	0.3071	0.2850	0.032*	0.5
C17	0.5396 (10)	0.2429 (11)	0.2733 (4)	0.032 (5)	0.5
H17A	0.5491	0.2072	0.2913	0.038*	0.5
H17B	0.5783	0.2616	0.2653	0.038*	0.5
C18	0.5000	0.1858 (13)	0.2500	0.056 (5)	0.5
H18A	0.4724	0.1464	0.2605	0.068*	0.25
H18B	0.5276	0.1464	0.2395	0.068*	0.25
C15'	0.5000	0.3755 (12)	0.2500	0.053 (4)	0.5
C16'	0.4605 (9)	0.3228 (10)	0.2262 (4)	0.028 (4)	0.5
H16C	0.4210	0.3041	0.2335	0.033*	0.5
H16D	0.4529	0.3589	0.2082	0.033*	0.5
C17'	0.4993 (11)	0.2424 (11)	0.2789 (3)	0.034 (5)	0.5
H17C	0.4574	0.2619	0.2824	0.041*	0.5
H17D	0.5159	0.2069	0.2960	0.041*	0.5
C18'	0.5000	0.1858 (13)	0.2500	0.056 (5)	0.5
H18C	0.5364	0.1464	0.2514	0.068*	0.25
H18D	0.4636	0.1464	0.2486	0.068*	0.25
S1	0.78487 (19)	0.8805 (3)	0.37164 (8)	0.0651 (11)
O17	0.7667 (5)	0.8145 (7)	0.3937 (2)	0.068 (3)
C35	0.8556 (7)	0.9243 (11)	0.3852 (4)	0.074 (5)
H35A	0.8869	0.8775	0.3845	0.111*
H35B	0.8528	0.9441	0.4054	0.111*
H35C	0.8664	0.9756	0.3731	0.111*
C36	0.7402 (8)	0.9786 (12)	0.3757 (4)	0.073 (5)
H36A	0.6978	0.9662	0.3688	0.110*
H36B	0.7561	1.0276	0.3640	0.110*
H36C	0.7420	0.9963	0.3963	0.110*
S2	0.82444 (12)	0.5793 (2)	0.36512 (6)	0.0398 (7)
O18	0.7689 (3)	0.5882 (5)	0.38247 (15)	0.0322 (16)
C37	0.8542 (7)	0.4724 (10)	0.3749 (4)	0.062 (4)
H37A	0.8281	0.4255	0.3657	0.093*
H37B	0.8558	0.4655	0.3962	0.093*
H37C	0.8954	0.4667	0.3682	0.093*
C38	0.8819 (6)	0.6452 (10)	0.3848 (3)	0.058 (4)
H38A	0.8730	0.7093	0.3819	0.087*
H38B	0.9218	0.6314	0.3776	0.087*
H38C	0.8825	0.6308	0.4057	0.087*
S3	0.70851 (12)	0.41414 (18)	0.44499 (6)	0.0353 (6)
O19	0.6875 (3)	0.5077 (5)	0.4360 (2)	0.0408 (19)
C39	0.6412 (5)	0.3566 (8)	0.4541 (3)	0.038 (3)
H39A	0.6278	0.3803	0.4726	0.057*
H39B	0.6498	0.2921	0.4562	0.057*
H39C	0.6089	0.3660	0.4385	0.057*
C40	0.7198 (8)	0.3579 (10)	0.4124 (3)	0.062 (4)
H40A	0.7563	0.3816	0.4039	0.092*
H40B	0.6843	0.3670	0.3985	0.092*
H40C	0.7251	0.2934	0.4163	0.092*
S4	0.50992 (12)	0.58936 (19)	0.47015 (6)	0.0326 (6)
O20	0.5711 (3)	0.5753 (5)	0.45823 (15)	0.0326 (16)
C41	0.4837 (6)	0.6919 (8)	0.4543 (3)	0.049 (3)
H41A	0.5068	0.7420	0.4635	0.073*
H41B	0.4403	0.6995	0.4574	0.073*
H41C	0.4893	0.6911	0.4333	0.073*
C42	0.4608 (6)	0.5155 (9)	0.4499 (3)	0.052 (3)
H42A	0.4693	0.4534	0.4562	0.077*
H42B	0.4673	0.5213	0.4290	0.077*
H42C	0.4184	0.5305	0.4532	0.077*
S5	0.30698 (15)	0.4898 (2)	0.26928 (6)	0.0444 (7)
O21	0.3549 (4)	0.5579 (6)	0.26106 (16)	0.045 (2)
C43	0.2612 (6)	0.5447 (9)	0.2933 (3)	0.051 (3)
H43A	0.2345	0.5876	0.2824	0.077*
H43B	0.2871	0.5770	0.3081	0.077*
H43C	0.2363	0.5003	0.3029	0.077*
C44	0.3463 (9)	0.4194 (13)	0.2956 (4)	0.086 (6)
H44A	0.3755	0.3817	0.2860	0.130*
H44B	0.3169	0.3809	0.3049	0.130*
H44C	0.3681	0.4568	0.3106	0.130*
S6	0.59192 (19)	0.8495 (2)	0.23326 (8)	0.0426 (9)	0.8
O22	0.5638 (3)	0.7548 (5)	0.23687 (17)	0.0364 (17)	0.8
C45	0.5982 (7)	0.8621 (11)	0.1948 (3)	0.061 (4)	0.8
H45A	0.5580	0.8755	0.1852	0.092*	0.8
H45B	0.6138	0.8061	0.1868	0.092*	0.8
H45C	0.6263	0.9115	0.1913	0.092*	0.8
C46	0.6716 (7)	0.8270 (14)	0.2433 (4)	0.078 (5)	0.8
H46A	0.6773	0.8178	0.2645	0.117*	0.8
H46B	0.6963	0.8782	0.2377	0.117*	0.8
H46C	0.6842	0.7727	0.2332	0.117*	0.8
S6'	0.6140 (7)	0.8004 (11)	0.2195 (3)	0.041 (3)	0.2
O22'	0.5638 (3)	0.7548 (5)	0.23687 (17)	0.0364 (17)	0.2
C45'	0.5982 (7)	0.8621 (11)	0.1948 (3)	0.061 (4)	0.2
H45D	0.5634	0.8378	0.1829	0.092*	0.2
H45E	0.6332	0.8680	0.1828	0.092*	0.2
H45F	0.5877	0.9214	0.2024	0.092*	0.2
C46'	0.6716 (7)	0.8270 (14)	0.2433 (4)	0.078 (5)	0.2
H46D	0.6768	0.7796	0.2582	0.117*	0.2
H46E	0.6629	0.8843	0.2528	0.117*	0.2
H46F	0.7090	0.8326	0.2330	0.117*	0.2
O1	0.8974 (4)	0.7578 (6)	0.49184 (18)	0.045 (2)
O2	0.8873 (4)	0.7930 (6)	0.4443 (2)	0.049 (2)
C19	0.9152 (5)	0.7633 (7)	0.4672 (2)	0.027 (2)
C20	0.9780 (4)	0.7220 (6)	0.46322 (19)	0.038 (3)
F1	0.9905 (5)	0.7125 (9)	0.43640 (18)	0.132 (5)
F2	1.0199 (4)	0.7694 (8)	0.4765 (3)	0.133 (5)
F3	0.9826 (5)	0.6416 (7)	0.4748 (3)	0.141 (6)
O3	0.8332 (4)	0.5483 (5)	0.49281 (14)	0.0355 (18)
O4	0.8401 (4)	0.5427 (6)	0.44397 (16)	0.0396 (18)
C21	0.8495 (4)	0.5157 (6)	0.4696 (2)	0.025 (2)
C22	0.8884 (4)	0.4292 (6)	0.47365 (19)	0.042 (3)
F4	0.8742 (5)	0.3781 (6)	0.4951 (2)	0.090 (3)
F5	0.9447 (4)	0.4512 (7)	0.4790 (3)	0.133 (5)
F6	0.8847 (7)	0.3806 (8)	0.4503 (2)	0.149 (6)
O5	0.7685 (4)	0.9781 (5)	0.44922 (17)	0.045 (2)
O6	0.8220 (4)	1.0117 (5)	0.49086 (17)	0.0387 (18)
C23	0.7898 (5)	1.0291 (6)	0.4684 (2)	0.026 (2)
C24	0.7746 (4)	1.1289 (7)	0.46358 (19)	0.040 (3)
F7	0.7487 (5)	1.1624 (7)	0.4857 (2)	0.106 (4)
F8	0.7382 (5)	1.1436 (6)	0.4406 (2)	0.117 (5)
F9	0.8235 (4)	1.1746 (6)	0.4608 (3)	0.117 (4)
O7	0.5097 (5)	0.4688 (7)	0.3523 (3)	0.075 (3)
O8	0.5608 (5)	0.4239 (6)	0.39316 (18)	0.059 (3)
C25	0.5296 (6)	0.4136 (8)	0.3699 (2)	0.038 (3)
C26	0.5147 (4)	0.3148 (8)	0.3618 (2)	0.057 (3)
F10	0.4633 (4)	0.3066 (7)	0.3464 (2)	0.085 (3)
F11	0.5575 (4)	0.2834 (6)	0.3466 (2)	0.083 (3)
F12	0.5119 (6)	0.2648 (7)	0.38477 (17)	0.122 (5)
O9	0.4657 (4)	0.6813 (8)	0.3609 (3)	0.075 (4)
O10	0.3830 (4)	0.6358 (7)	0.33428 (18)	0.047 (2)
C27	0.4115 (5)	0.6686 (7)	0.3560 (2)	0.034 (2)
C28	0.3717 (4)	0.6925 (6)	0.3817 (2)	0.040 (3)
F13	0.3141 (3)	0.6898 (8)	0.37499 (18)	0.088 (3)
F14	0.3864 (4)	0.7704 (5)	0.3924 (2)	0.102 (4)
F15	0.3823 (5)	0.6342 (6)	0.40308 (19)	0.096 (3)
O11	0.7030 (4)	0.4237 (5)	0.34511 (16)	0.0377 (18)
O12	0.6579 (4)	0.4157 (5)	0.29988 (18)	0.046 (2)
C29	0.6873 (4)	0.3861 (7)	0.3217 (2)	0.027 (2)
C30	0.7088 (4)	0.2874 (6)	0.32048 (18)	0.040 (3)
F16	0.7684 (3)	0.2844 (6)	0.3206 (2)	0.073 (3)
F17	0.6945 (4)	0.2410 (5)	0.34302 (18)	0.071 (2)
F18	0.6872 (5)	0.2470 (6)	0.29714 (18)	0.115 (5)
O13	0.7464 (4)	0.7305 (5)	0.3108 (2)	0.046 (2)
O14	0.7368 (4)	0.5905 (6)	0.2931 (2)	0.050 (2)
C31	0.7641 (5)	0.6607 (7)	0.2992 (2)	0.032 (2)
C32	0.8312 (5)	0.6627 (6)	0.28966 (19)	0.047 (3)
F19	0.8680 (3)	0.7030 (5)	0.30863 (15)	0.059 (2)
F20	0.8316 (4)	0.7065 (7)	0.26516 (16)	0.091 (3)
F21	0.8523 (4)	0.5828 (5)	0.2855 (3)	0.105 (4)
O15	0.6420 (4)	0.8787 (5)	0.32315 (19)	0.0419 (19)
O16	0.5514 (4)	0.8659 (5)	0.29905 (18)	0.041 (2)
C33	0.5951 (4)	0.9071 (6)	0.3113 (2)	0.024 (2)
C34	0.5868 (4)	1.0114 (6)	0.30942 (17)	0.032 (2)
F22	0.5309 (3)	1.0358 (4)	0.31170 (17)	0.056 (2)
F23	0.6211 (3)	1.0534 (4)	0.32930 (14)	0.0502 (18)
F24	0.6036 (3)	1.0383 (4)	0.28404 (13)	0.0528 (19)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0223 (3)	0.0238 (4)	0.0211 (3)	0.0089 (3)	−0.0032 (3)	−0.0036 (3)
Ag2	0.0338 (4)	0.0264 (4)	0.0597 (6)	−0.0024 (3)	0.0076 (4)	0.0101 (4)
Ag3	0.0297 (4)	0.0269 (4)	0.0255 (4)	0.0060 (3)	−0.0008 (3)	−0.0101 (3)
Ag4	0.0324 (4)	0.0248 (4)	0.0273 (4)	−0.0039 (3)	−0.0018 (3)	0.0033 (3)
Ag5	0.0245 (3)	0.0252 (4)	0.0159 (3)	0.0007 (3)	−0.0063 (3)	−0.0053 (3)
Ag6	0.0468 (5)	0.0262 (4)	0.0238 (4)	−0.0052 (3)	0.0055 (3)	−0.0020 (3)
Ag7	0.0262 (4)	0.0195 (3)	0.0194 (3)	0.0065 (3)	−0.0026 (3)	−0.0044 (3)
Ag8	0.0342 (4)	0.0205 (4)	0.0292 (4)	0.0018 (3)	0.0070 (3)	0.0031 (3)
Ag9	0.0295 (4)	0.0280 (4)	0.0201 (3)	0.0026 (3)	−0.0005 (3)	−0.0030 (3)
Ag10	0.0354 (4)	0.0161 (3)	0.0321 (4)	−0.0012 (3)	−0.0114 (3)	0.0013 (3)
Ag11	0.0337 (5)	0.0664 (6)	0.0348 (5)	−0.0089 (4)	−0.0007 (4)	−0.0141 (4)
C1	0.021 (4)	0.024 (4)	0.019 (4)	0.003 (3)	0.001 (3)	−0.005 (3)
C2	0.016 (4)	0.014 (4)	0.019 (4)	−0.001 (3)	−0.005 (3)	−0.003 (3)
C3	0.020 (4)	0.024 (4)	0.014 (4)	0.006 (3)	−0.007 (3)	−0.005 (3)
C4	0.017 (4)	0.016 (4)	0.012 (4)	0.001 (3)	−0.006 (3)	0.000 (3)
C5	0.024 (4)	0.018 (4)	0.016 (4)	0.001 (3)	−0.005 (3)	0.002 (3)
C6	0.028 (4)	0.024 (4)	0.019 (4)	0.001 (4)	−0.005 (3)	−0.006 (3)
C7	0.030 (5)	0.030 (5)	0.031 (5)	0.012 (4)	−0.006 (4)	−0.006 (4)
C8	0.040 (5)	0.040 (5)	0.032 (5)	0.013 (5)	−0.011 (4)	0.001 (4)
C9	0.060 (6)	0.033 (5)	0.051 (6)	0.013 (5)	−0.003 (5)	−0.002 (5)
C10	0.047 (6)	0.034 (5)	0.044 (6)	0.008 (5)	−0.001 (5)	−0.013 (5)
C11	0.046 (5)	0.036 (5)	0.025 (5)	0.013 (4)	−0.010 (4)	−0.013 (4)
C12	0.028 (4)	0.018 (4)	0.016 (4)	−0.002 (3)	−0.008 (3)	−0.001 (3)
C13	0.035 (5)	0.018 (4)	0.017 (4)	0.000 (4)	−0.007 (4)	0.004 (3)
C14	0.040 (6)	0.016 (5)	0.015 (5)	0.000	−0.011 (5)	0.000
C15	0.073 (7)	0.038 (6)	0.044 (7)	0.000	−0.017 (6)	0.000
C16	0.030 (8)	0.029 (8)	0.020 (7)	0.000 (7)	−0.007 (6)	0.013 (6)
C17	0.036 (8)	0.024 (8)	0.035 (8)	0.004 (7)	−0.004 (7)	−0.007 (7)
C18	0.070 (7)	0.046 (7)	0.053 (7)	0.000	0.001 (6)	0.000
C15'	0.073 (7)	0.038 (6)	0.044 (7)	0.000	−0.017 (6)	0.000
C16'	0.027 (8)	0.027 (8)	0.028 (8)	−0.003 (7)	−0.004 (7)	−0.002 (6)
C17'	0.039 (9)	0.025 (8)	0.038 (8)	−0.003 (7)	0.003 (7)	0.004 (7)
C18'	0.070 (7)	0.046 (7)	0.053 (7)	0.000	0.001 (6)	0.000
S1	0.073 (2)	0.077 (3)	0.047 (2)	−0.029 (2)	0.0182 (17)	−0.0290 (18)
O17	0.072 (7)	0.054 (6)	0.081 (7)	−0.032 (5)	0.029 (6)	−0.023 (5)
C35	0.065 (9)	0.057 (8)	0.104 (12)	−0.016 (7)	0.030 (9)	−0.001 (8)
C36	0.068 (9)	0.082 (10)	0.065 (9)	0.010 (8)	−0.030 (7)	0.005 (8)
S2	0.0297 (14)	0.0650 (19)	0.0246 (13)	−0.0007 (13)	0.0012 (10)	0.0002 (13)
O18	0.024 (3)	0.044 (4)	0.028 (4)	−0.001 (3)	0.000 (3)	−0.016 (3)
C37	0.050 (7)	0.056 (8)	0.081 (10)	0.005 (6)	0.013 (7)	−0.019 (7)
C38	0.041 (7)	0.061 (8)	0.072 (9)	−0.025 (6)	0.004 (6)	−0.008 (7)
S3	0.0309 (13)	0.0304 (13)	0.0450 (16)	0.0046 (11)	0.0054 (11)	0.0044 (12)
O19	0.021 (4)	0.028 (4)	0.073 (6)	0.004 (3)	0.004 (4)	0.002 (4)
C39	0.034 (5)	0.036 (6)	0.045 (6)	−0.011 (5)	0.002 (5)	0.004 (5)
C40	0.087 (10)	0.048 (7)	0.053 (8)	0.029 (7)	0.024 (7)	0.014 (6)
S4	0.0288 (13)	0.0395 (14)	0.0297 (13)	0.0053 (11)	0.0041 (10)	0.0044 (11)
O20	0.022 (3)	0.049 (5)	0.027 (4)	−0.001 (3)	0.004 (3)	−0.003 (3)
C41	0.039 (6)	0.039 (6)	0.066 (8)	0.006 (5)	−0.008 (6)	0.004 (6)
C42	0.038 (6)	0.046 (7)	0.070 (8)	−0.013 (5)	0.002 (6)	−0.013 (6)
S5	0.0527 (18)	0.0508 (18)	0.0307 (14)	−0.0273 (15)	0.0094 (13)	−0.0064 (13)
O21	0.052 (5)	0.064 (6)	0.019 (4)	−0.032 (4)	−0.004 (3)	0.003 (4)
C43	0.055 (7)	0.049 (7)	0.050 (7)	0.003 (6)	0.003 (6)	−0.004 (6)
C44	0.094 (11)	0.073 (10)	0.094 (12)	0.011 (9)	0.020 (10)	0.039 (9)
S6	0.061 (2)	0.0316 (18)	0.0368 (19)	−0.0136 (17)	0.0128 (17)	−0.0066 (16)
O22	0.040 (4)	0.030 (4)	0.040 (4)	−0.003 (3)	0.003 (3)	0.004 (3)
C45	0.067 (8)	0.067 (8)	0.051 (7)	−0.010 (7)	0.008 (6)	0.008 (6)
C46	0.054 (8)	0.114 (11)	0.065 (8)	−0.028 (8)	−0.008 (7)	−0.009 (8)
S6'	0.051 (8)	0.052 (9)	0.018 (6)	−0.018 (7)	−0.002 (6)	0.001 (6)
O22'	0.040 (4)	0.030 (4)	0.040 (4)	−0.003 (3)	0.003 (3)	0.004 (3)
C45'	0.067 (8)	0.067 (8)	0.051 (7)	−0.010 (7)	0.008 (6)	0.008 (6)
C46'	0.054 (8)	0.114 (11)	0.065 (8)	−0.028 (8)	−0.008 (7)	−0.009 (8)
O1	0.041 (5)	0.059 (5)	0.036 (4)	0.013 (4)	0.011 (4)	−0.003 (4)
O2	0.035 (4)	0.060 (6)	0.055 (5)	0.009 (4)	0.014 (4)	0.016 (4)
C19	0.028 (5)	0.024 (4)	0.030 (5)	0.005 (4)	0.004 (4)	−0.003 (4)
C20	0.034 (5)	0.043 (6)	0.038 (5)	0.004 (5)	0.008 (4)	−0.003 (5)
F1	0.103 (8)	0.218 (13)	0.079 (7)	0.103 (9)	0.024 (6)	−0.018 (8)
F2	0.039 (5)	0.164 (11)	0.195 (12)	−0.004 (6)	0.009 (6)	−0.109 (10)
F3	0.091 (8)	0.121 (9)	0.216 (13)	0.060 (7)	0.046 (8)	0.071 (9)
O3	0.052 (5)	0.035 (4)	0.017 (3)	0.023 (4)	−0.011 (3)	−0.007 (3)
O4	0.041 (4)	0.049 (5)	0.030 (4)	0.016 (4)	0.006 (3)	0.002 (3)
C21	0.024 (4)	0.024 (4)	0.025 (5)	0.004 (4)	−0.001 (4)	0.001 (4)
C22	0.044 (6)	0.038 (5)	0.045 (6)	0.016 (5)	0.004 (5)	−0.004 (5)
F4	0.108 (7)	0.055 (5)	0.111 (8)	0.040 (5)	0.033 (6)	0.036 (5)
F5	0.053 (6)	0.090 (8)	0.254 (14)	0.033 (5)	0.007 (7)	0.052 (9)
F6	0.260 (15)	0.103 (8)	0.081 (7)	0.111 (9)	−0.013 (9)	−0.032 (6)
O5	0.069 (6)	0.028 (4)	0.036 (4)	0.010 (4)	−0.011 (4)	0.001 (3)
O6	0.051 (5)	0.022 (4)	0.041 (4)	0.001 (3)	−0.014 (4)	0.004 (3)
C23	0.037 (5)	0.019 (4)	0.024 (4)	0.003 (4)	0.012 (4)	−0.005 (4)
C24	0.045 (6)	0.032 (5)	0.042 (6)	0.009 (5)	0.006 (5)	0.006 (4)
F7	0.159 (10)	0.063 (6)	0.101 (8)	0.048 (6)	0.052 (7)	0.005 (5)
F8	0.179 (11)	0.051 (5)	0.109 (8)	0.034 (6)	−0.074 (8)	0.004 (5)
F9	0.099 (8)	0.045 (5)	0.212 (13)	−0.004 (5)	0.041 (8)	0.031 (7)
O7	0.070 (7)	0.050 (6)	0.098 (8)	−0.026 (5)	−0.031 (6)	0.031 (6)
O8	0.099 (8)	0.040 (5)	0.032 (5)	−0.015 (5)	−0.024 (5)	−0.001 (4)
C25	0.050 (6)	0.037 (5)	0.027 (5)	−0.016 (5)	0.007 (4)	0.004 (4)
C26	0.070 (7)	0.062 (7)	0.039 (6)	−0.016 (6)	−0.004 (6)	0.002 (5)
F10	0.083 (6)	0.089 (7)	0.083 (6)	−0.039 (5)	0.002 (5)	−0.030 (5)
F11	0.096 (7)	0.069 (6)	0.084 (6)	0.010 (5)	−0.006 (5)	−0.034 (5)
F12	0.237 (13)	0.065 (6)	0.063 (6)	−0.070 (8)	−0.003 (7)	0.010 (5)
O9	0.027 (5)	0.097 (8)	0.099 (8)	−0.005 (5)	0.004 (5)	−0.069 (7)
O10	0.033 (4)	0.071 (6)	0.038 (4)	0.001 (4)	−0.002 (3)	−0.016 (4)
C27	0.029 (5)	0.032 (5)	0.041 (5)	0.004 (4)	−0.005 (4)	−0.004 (4)
C28	0.036 (5)	0.046 (6)	0.037 (5)	0.004 (5)	−0.009 (4)	−0.004 (5)
F13	0.039 (4)	0.173 (10)	0.053 (5)	0.016 (5)	−0.001 (4)	−0.013 (6)
F14	0.109 (8)	0.068 (6)	0.136 (9)	−0.007 (6)	0.064 (7)	−0.048 (6)
F15	0.129 (9)	0.110 (8)	0.049 (5)	0.032 (7)	0.012 (5)	0.017 (5)
O11	0.052 (5)	0.031 (4)	0.029 (4)	0.012 (3)	−0.009 (3)	−0.012 (3)
O12	0.065 (6)	0.028 (4)	0.041 (5)	0.011 (4)	−0.028 (4)	−0.006 (3)
C29	0.022 (4)	0.024 (4)	0.033 (5)	0.003 (4)	−0.001 (4)	−0.003 (4)
C30	0.041 (5)	0.035 (5)	0.043 (6)	0.020 (5)	−0.005 (5)	−0.014 (5)
F16	0.047 (4)	0.077 (6)	0.097 (7)	0.035 (4)	0.011 (4)	0.008 (5)
F17	0.087 (6)	0.033 (4)	0.094 (6)	0.001 (4)	0.019 (5)	0.009 (4)
F18	0.168 (10)	0.068 (6)	0.095 (7)	0.065 (6)	−0.086 (7)	−0.064 (5)
O13	0.046 (5)	0.037 (5)	0.058 (5)	−0.006 (4)	0.026 (4)	−0.008 (4)
O14	0.038 (5)	0.049 (5)	0.065 (6)	−0.005 (4)	0.012 (4)	−0.018 (4)
C31	0.029 (5)	0.036 (5)	0.031 (5)	0.001 (4)	0.001 (4)	0.002 (4)
C32	0.046 (6)	0.056 (6)	0.042 (6)	0.003 (5)	0.011 (5)	−0.007 (5)
F19	0.031 (4)	0.088 (6)	0.059 (5)	−0.014 (4)	0.001 (3)	0.006 (4)
F20	0.056 (5)	0.166 (10)	0.051 (5)	−0.022 (6)	0.017 (4)	0.024 (6)
F21	0.068 (6)	0.086 (7)	0.168 (11)	0.010 (5)	0.049 (7)	−0.036 (7)
O15	0.041 (4)	0.022 (4)	0.061 (5)	−0.003 (3)	−0.011 (4)	0.003 (4)
O16	0.054 (5)	0.014 (3)	0.053 (5)	−0.005 (3)	−0.019 (4)	−0.001 (3)
C33	0.029 (5)	0.017 (4)	0.027 (4)	−0.002 (4)	0.003 (4)	−0.001 (3)
C34	0.040 (5)	0.017 (4)	0.040 (5)	−0.003 (4)	0.003 (4)	0.005 (4)
F22	0.049 (4)	0.024 (3)	0.095 (6)	0.011 (3)	−0.001 (4)	0.007 (4)
F23	0.068 (5)	0.020 (3)	0.060 (4)	−0.009 (3)	−0.017 (4)	−0.005 (3)
F24	0.078 (5)	0.032 (3)	0.048 (4)	−0.005 (3)	0.005 (4)	0.019 (3)

Geometric parameters (Å, º)

Ag1—O3	2.223 (7)	C17'—H17C	0.9900
Ag1—C1	2.281 (9)	C17'—H17D	0.9900
Ag1—C1^i	2.484 (9)	S1—O17	1.483 (11)
Ag1—Ag1^i	2.7742 (13)	S1—C35	1.758 (17)
Ag1—Ag4	2.8731 (11)	S1—C36	1.774 (17)
Ag1—Ag3	2.9487 (10)	C35—H35A	0.9800
Ag1—Ag2	2.9522 (11)	C35—H35B	0.9800
Ag1—Ag4^i	3.2391 (10)	C35—H35C	0.9800
Ag1—Ag2^i	3.3600 (12)	C36—H36A	0.9800
Ag2—O5	2.261 (8)	C36—H36B	0.9800
Ag2—O2	2.276 (8)	C36—H36C	0.9800
Ag2—C1	2.315 (9)	S2—O18	1.509 (7)
Ag2—O17	2.485 (11)	S2—C37	1.764 (15)
Ag2—Ag3	3.0337 (12)	S2—C38	1.792 (13)
Ag2—Ag4^i	3.2353 (13)	C37—H37A	0.9800
Ag2—Ag1^i	3.3601 (12)	C37—H37B	0.9800
Ag3—O18	2.310 (7)	C37—H37C	0.9800
Ag3—O4	2.324 (8)	C38—H38A	0.9800
Ag3—C1	2.350 (9)	C38—H38B	0.9800
Ag3—O19	2.482 (8)	C38—H38C	0.9800
Ag3—C2	2.709 (8)	S3—O19	1.513 (8)
Ag4—O6^i	2.217 (7)	S3—C40	1.744 (14)
Ag4—C1	2.313 (10)	S3—C39	1.783 (11)
Ag4—O20	2.455 (7)	C39—H39A	0.9800
Ag4—O1^i	2.547 (8)	C39—H39B	0.9800
Ag4—Ag2^i	3.2353 (13)	C39—H39C	0.9800
Ag4—Ag1^i	3.2392 (10)	C40—H40A	0.9800
Ag5—C12	2.246 (8)	C40—H40B	0.9800
Ag5—C5	2.277 (9)	C40—H40C	0.9800
Ag5—O7	2.376 (9)	S4—O20	1.502 (7)
Ag5—O9	2.391 (9)	S4—C42	1.759 (12)
Ag5—Ag7	2.8474 (10)	S4—C41	1.767 (12)
Ag5—Ag10	2.8606 (10)	C41—H41A	0.9800
Ag5—Ag9	2.9825 (10)	C41—H41B	0.9800
Ag5—Ag8	3.0038 (10)	C41—H41C	0.9800
Ag5—Ag11	3.2536 (11)	C42—H42A	0.9800
Ag5—Ag6	3.3347 (10)	C42—H42B	0.9800
Ag6—O8	2.248 (9)	C42—H42C	0.9800
Ag6—O20	2.342 (7)	S5—O21	1.526 (8)
Ag6—C5	2.368 (9)	S5—C43	1.743 (13)
Ag6—O19	2.442 (8)	S5—C44	1.775 (17)
Ag6—C4	2.464 (8)	O21—Ag9^ii	2.571 (7)
Ag6—Ag7	2.9349 (11)	C43—H43A	0.9800
Ag7—O11	2.151 (7)	C43—H43B	0.9800
Ag7—C5	2.159 (9)	C43—H43C	0.9800
Ag7—O18	2.420 (7)	C44—H44A	0.9800
Ag7—Ag8	2.8593 (10)	C44—H44B	0.9800
Ag7—Ag9	3.0087 (10)	C44—H44C	0.9800
Ag8—C5	2.254 (9)	S6—O22	1.549 (8)
Ag8—O13	2.257 (8)	S6—C45	1.785 (15)
Ag8—O15	2.314 (7)	S6—C46	1.812 (17)
Ag8—Ag9	2.9921 (11)	O22—Ag11^ii	2.544 (8)
Ag8—Ag10	3.1228 (11)	C45—H45A	0.9800
Ag9—O14	2.211 (8)	C45—H45B	0.9800
Ag9—C12	2.243 (9)	C45—H45C	0.9800
Ag9—O12	2.374 (8)	C46—H46A	0.9800
Ag9—O21^ii	2.571 (7)	C46—H46B	0.9800
Ag9—Ag10	2.9723 (11)	C46—H46C	0.9800
Ag10—C12	2.146 (9)	O1—C19	1.223 (13)
Ag10—O16	2.180 (7)	O1—Ag4^i	2.547 (8)
Ag10—O22	2.488 (8)	O2—C19	1.256 (13)
Ag10—Ag11	3.0483 (12)	C19—C20	1.533 (13)
Ag11—O10	2.256 (8)	C20—F2	1.280 (8)
Ag11—C12	2.317 (9)	C20—F1	1.285 (8)
Ag11—O21	2.318 (7)	C20—F3	1.306 (9)
Ag11—C13	2.497 (10)	O3—C21	1.242 (12)
Ag11—O22'^ii	2.544 (8)	O4—C21	1.245 (12)
Ag11—O22^ii	2.544 (8)	C21—C22	1.547 (13)
C1—C2	1.228 (13)	C22—F6	1.289 (8)
C1—Ag1^i	2.484 (9)	C22—F5	1.289 (9)
C2—C3	1.428 (12)	C22—F4	1.295 (8)
C3—C6	1.343 (13)	O5—C23	1.227 (13)
C3—C4	1.441 (12)	O6—C23	1.236 (12)
C4—C5	1.220 (12)	O6—Ag4^i	2.217 (7)
C6—C7	1.497 (13)	C23—C24	1.531 (13)
C6—C11	1.504 (13)	C24—F9	1.285 (9)
C7—C8	1.497 (16)	C24—F8	1.296 (8)
C7—H7A	0.9900	C24—F7	1.298 (8)
C7—H7B	0.9900	O7—C25	1.211 (15)
C8—C9	1.501 (16)	O8—C25	1.234 (14)
C8—H8A	0.9900	C25—C26	1.544 (16)
C8—H8B	0.9900	C26—F12	1.293 (9)
C9—C10	1.517 (17)	C26—F11	1.295 (9)
C9—H9A	0.9900	C26—F10	1.297 (9)
C9—H9B	0.9900	O9—C27	1.213 (13)
C10—C11	1.522 (17)	O10—C27	1.237 (13)
C10—H10A	0.9900	C27—C28	1.557 (15)
C10—H10B	0.9900	C28—F13	1.284 (8)
C11—H11A	0.9900	C28—F14	1.288 (8)
C11—H11B	0.9900	C28—F15	1.314 (8)
C12—C13	1.210 (13)	O11—C29	1.238 (12)
C13—C14	1.440 (12)	O12—C29	1.232 (12)
C14—C15	1.35 (2)	C29—C30	1.543 (13)
C14—C13^ii	1.440 (12)	C30—F18	1.288 (8)
C15—C16^ii	1.562 (15)	C30—F17	1.298 (8)
C15—C16	1.562 (15)	C30—F16	1.311 (8)
C16—C17	1.51 (3)	O13—C31	1.239 (13)
C16—H16A	0.9900	O14—C31	1.226 (14)
C16—H16B	0.9900	C31—C32	1.566 (15)
C17—C18	1.577 (18)	C32—F21	1.292 (8)
C17—H17A	0.9900	C32—F19	1.295 (8)
C17—H17B	0.9900	C32—F20	1.298 (8)
C18—C17^ii	1.577 (18)	O15—C33	1.207 (12)
C18—H18A	0.9900	O16—C33	1.242 (12)
C18—H18B	0.9900	C33—C34	1.563 (12)
C16'—C17'^ii	1.51 (3)	C34—F22	1.293 (8)
C16'—H16C	0.9900	C34—F23	1.301 (8)
C16'—H16D	0.9900	C34—F24	1.306 (8)
C17'—C16'^ii	1.51 (3)
O3—Ag1—C1	128.8 (3)	Ag1—C1—Ag3	79.1 (3)
O3—Ag1—C1^i	116.5 (3)	Ag4—C1—Ag3	93.5 (3)
C1—Ag1—C1^i	108.9 (2)	Ag2—C1—Ag3	81.1 (3)
O3—Ag1—Ag1^i	156.2 (2)	C2—C1—Ag1^i	116.7 (7)
C1—Ag1—Ag1^i	57.9 (2)	Ag1—C1—Ag1^i	71.1 (2)
C1^i—Ag1—Ag1^i	51.1 (2)	Ag4—C1—Ag1^i	84.9 (3)
O3—Ag1—Ag4	96.2 (2)	Ag2—C1—Ag1^i	88.8 (3)
C1—Ag1—Ag4	51.8 (2)	Ag3—C1—Ag1^i	149.8 (4)
C1^i—Ag1—Ag4	100.7 (2)	C1—C2—C3	176.6 (10)
Ag1^i—Ag1—Ag4	69.98 (3)	C1—C2—Ag3	60.0 (5)
O3—Ag1—Ag3	83.07 (17)	C3—C2—Ag3	119.1 (6)
C1—Ag1—Ag3	51.5 (2)	C6—C3—C2	125.1 (8)
C1^i—Ag1—Ag3	160.0 (2)	C6—C3—C4	120.9 (8)
Ag1^i—Ag1—Ag3	109.22 (4)	C2—C3—C4	114.0 (7)
Ag4—Ag1—Ag3	71.38 (3)	C5—C4—C3	175.0 (10)
O3—Ag1—Ag2	131.4 (2)	C5—C4—Ag6	71.0 (6)
C1—Ag1—Ag2	50.5 (2)	C3—C4—Ag6	113.4 (6)
C1^i—Ag1—Ag2	103.6 (2)	C4—C5—Ag7	139.0 (7)
Ag1^i—Ag1—Ag2	71.78 (3)	C4—C5—Ag8	116.1 (7)
Ag4—Ag1—Ag2	102.32 (3)	Ag7—C5—Ag8	80.7 (3)
Ag3—Ag1—Ag2	61.88 (3)	C4—C5—Ag5	136.4 (7)
O3—Ag1—Ag4^i	133.4 (2)	Ag7—C5—Ag5	79.8 (3)
C1—Ag1—Ag4^i	95.3 (2)	Ag8—C5—Ag5	83.0 (3)
C1^i—Ag1—Ag4^i	45.3 (2)	C4—C5—Ag6	79.8 (6)
Ag1^i—Ag1—Ag4^i	56.44 (3)	Ag7—C5—Ag6	80.7 (3)
Ag4—Ag1—Ag4^i	126.42 (3)	Ag8—C5—Ag6	161.3 (4)
Ag3—Ag1—Ag4^i	124.42 (3)	Ag5—C5—Ag6	91.8 (3)
Ag2—Ag1—Ag4^i	62.80 (3)	C3—C6—C7	123.8 (8)
O3—Ag1—Ag2^i	100.0 (2)	C3—C6—C11	122.5 (8)
C1—Ag1—Ag2^i	96.9 (2)	C7—C6—C11	113.7 (8)
C1^i—Ag1—Ag2^i	43.5 (2)	C6—C7—C8	109.5 (9)
Ag1^i—Ag1—Ag2^i	56.57 (3)	C6—C7—H7A	109.8
Ag4—Ag1—Ag2^i	61.96 (3)	C8—C7—H7A	109.8
Ag3—Ag1—Ag2^i	133.31 (3)	C6—C7—H7B	109.8
Ag2—Ag1—Ag2^i	128.35 (3)	C8—C7—H7B	109.8
Ag4^i—Ag1—Ag2^i	86.86 (3)	H7A—C7—H7B	108.2
O5—Ag2—O2	114.2 (3)	C7—C8—C9	112.5 (10)
O5—Ag2—C1	116.4 (3)	C7—C8—H8A	109.1
O2—Ag2—C1	127.2 (3)	C9—C8—H8A	109.1
O5—Ag2—O17	95.5 (3)	C7—C8—H8B	109.1
O2—Ag2—O17	91.6 (3)	C9—C8—H8B	109.1
C1—Ag2—O17	97.4 (3)	H8A—C8—H8B	107.8
O5—Ag2—Ag1	133.5 (2)	C8—C9—C10	110.5 (10)
O2—Ag2—Ag1	84.6 (2)	C8—C9—H9A	109.6
C1—Ag2—Ag1	49.5 (2)	C10—C9—H9A	109.6
O17—Ag2—Ag1	127.6 (2)	C8—C9—H9B	109.6
O5—Ag2—Ag3	154.2 (2)	C10—C9—H9B	109.6
O2—Ag2—Ag3	87.2 (3)	H9A—C9—H9B	108.1
C1—Ag2—Ag3	49.9 (2)	C9—C10—C11	112.3 (10)
O17—Ag2—Ag3	68.6 (2)	C9—C10—H10A	109.1
Ag1—Ag2—Ag3	59.01 (3)	C11—C10—H10A	109.1
O5—Ag2—Ag4^i	77.2 (2)	C9—C10—H10B	109.1
O2—Ag2—Ag4^i	82.5 (2)	C11—C10—H10B	109.1
C1—Ag2—Ag4^i	94.8 (2)	H10A—C10—H10B	107.9
O17—Ag2—Ag4^i	167.6 (2)	C6—C11—C10	109.3 (9)
Ag1—Ag2—Ag4^i	62.94 (3)	C6—C11—H11A	109.8
Ag3—Ag2—Ag4^i	121.69 (3)	C10—C11—H11A	109.8
O5—Ag2—Ag1^i	85.4 (2)	C6—C11—H11B	109.8
O2—Ag2—Ag1^i	125.7 (2)	C10—C11—H11B	109.8
C1—Ag2—Ag1^i	47.6 (2)	H11A—C11—H11B	108.3
O17—Ag2—Ag1^i	138.6 (2)	C13—C12—Ag10	133.0 (7)
Ag1—Ag2—Ag1^i	51.65 (3)	C13—C12—Ag9	105.4 (7)
Ag3—Ag2—Ag1^i	93.61 (3)	Ag10—C12—Ag9	85.2 (3)
Ag4^i—Ag2—Ag1^i	51.61 (2)	C13—C12—Ag5	144.5 (8)
O18—Ag3—O4	87.3 (3)	Ag10—C12—Ag5	81.3 (3)
O18—Ag3—C1	147.4 (3)	Ag9—C12—Ag5	83.3 (3)
O4—Ag3—C1	124.9 (3)	C13—C12—Ag11	83.9 (7)
O18—Ag3—O19	88.7 (3)	Ag10—C12—Ag11	86.1 (3)
O4—Ag3—O19	89.6 (3)	Ag9—C12—Ag11	170.2 (4)
C1—Ag3—O19	95.6 (3)	Ag5—C12—Ag11	90.9 (3)
O18—Ag3—C2	121.0 (3)	C12—C13—C14	170.0 (10)
O4—Ag3—C2	151.6 (3)	C12—C13—Ag11	67.3 (6)
C1—Ag3—C2	26.9 (3)	C14—C13—Ag11	114.0 (5)
O19—Ag3—C2	91.3 (2)	C15—C14—C13	125.6 (5)
O18—Ag3—Ag1	160.46 (17)	C15—C14—C13^ii	125.6 (5)
O4—Ag3—Ag1	75.61 (19)	C13—C14—C13^ii	108.8 (11)
C1—Ag3—Ag1	49.4 (2)	C14—C15—C16^ii	119.0 (9)
O19—Ag3—Ag1	100.4 (2)	C14—C15—C16	119.0 (9)
C2—Ag3—Ag1	76.33 (18)	C16^ii—C15—C16	122.1 (17)
O18—Ag3—Ag2	120.4 (2)	C17—C16—C15	101.1 (14)
O4—Ag3—Ag2	109.9 (2)	C17—C16—H16A	111.6
C1—Ag3—Ag2	48.9 (2)	C15—C16—H16A	111.6
O19—Ag3—Ag2	144.55 (19)	C17—C16—H16B	111.6
C2—Ag3—Ag2	57.42 (18)	C15—C16—H16B	111.6
Ag1—Ag3—Ag2	59.12 (3)	H16A—C16—H16B	109.4
O6^i—Ag4—C1	147.4 (3)	C16—C17—C18	106.2 (14)
O6^i—Ag4—O20	95.0 (3)	C16—C17—H17A	110.5
C1—Ag4—O20	108.2 (3)	C18—C17—H17A	110.5
O6^i—Ag4—O1^i	119.4 (3)	C16—C17—H17B	110.5
C1—Ag4—O1^i	85.7 (3)	C18—C17—H17B	110.5
O20—Ag4—O1^i	85.9 (3)	H17A—C17—H17B	108.7
O6^i—Ag4—Ag1	99.6 (2)	C17—C18—C17^ii	114.9 (17)
C1—Ag4—Ag1	50.8 (2)	C17—C18—H18A	108.5
O20—Ag4—Ag1	153.69 (17)	C17^ii—C18—H18A	108.5
O1^i—Ag4—Ag1	105.4 (2)	C17—C18—H18B	108.5
O6^i—Ag4—Ag2^i	75.1 (2)	C17^ii—C18—H18B	108.5
C1—Ag4—Ag2^i	99.6 (2)	H18A—C18—H18B	107.5
O20—Ag4—Ag2^i	139.12 (16)	C17'^ii—C16'—H16C	111.4
O1^i—Ag4—Ag2^i	66.56 (19)	C17'^ii—C16'—H16D	111.4
Ag1—Ag4—Ag2^i	66.44 (3)	H16C—C16'—H16D	109.3
O6^i—Ag4—Ag1^i	128.3 (2)	C16'^ii—C17'—H17C	110.8
C1—Ag4—Ag1^i	49.8 (2)	C16'^ii—C17'—H17D	110.8
O20—Ag4—Ag1^i	129.23 (19)	H17C—C17'—H17D	108.9
O1^i—Ag4—Ag1^i	52.2 (2)	O17—S1—C35	106.1 (8)
Ag1—Ag4—Ag1^i	53.58 (3)	O17—S1—C36	107.2 (8)
Ag2^i—Ag4—Ag1^i	54.25 (2)	C35—S1—C36	98.2 (8)
C12—Ag5—C5	142.6 (3)	S1—O17—Ag2	125.5 (5)
C12—Ag5—O7	90.6 (4)	S1—C35—H35A	109.5
C5—Ag5—O7	114.4 (3)	S1—C35—H35B	109.5
C12—Ag5—O9	114.3 (4)	H35A—C35—H35B	109.5
C5—Ag5—O9	94.6 (3)	S1—C35—H35C	109.5
O7—Ag5—O9	88.7 (4)	H35A—C35—H35C	109.5
C12—Ag5—Ag7	107.8 (2)	H35B—C35—H35C	109.5
C5—Ag5—Ag7	48.3 (2)	S1—C36—H36A	109.5
O7—Ag5—Ag7	90.5 (3)	S1—C36—H36B	109.5
O9—Ag5—Ag7	137.9 (3)	H36A—C36—H36B	109.5
C12—Ag5—Ag10	47.9 (2)	S1—C36—H36C	109.5
C5—Ag5—Ag10	108.9 (2)	H36A—C36—H36C	109.5
O7—Ag5—Ag10	136.0 (3)	H36B—C36—H36C	109.5
O9—Ag5—Ag10	95.8 (3)	O18—S2—C37	104.2 (6)
Ag7—Ag5—Ag10	113.12 (3)	O18—S2—C38	104.9 (6)
C12—Ag5—Ag9	48.3 (2)	C37—S2—C38	97.3 (7)
C5—Ag5—Ag9	96.5 (2)	S2—O18—Ag3	131.3 (4)
O7—Ag5—Ag9	105.2 (3)	S2—O18—Ag7	118.9 (4)
O9—Ag5—Ag9	156.6 (3)	Ag3—O18—Ag7	109.8 (3)
Ag7—Ag5—Ag9	62.09 (2)	S2—C37—H37A	109.5
Ag10—Ag5—Ag9	61.11 (3)	S2—C37—H37B	109.5
C12—Ag5—Ag8	96.2 (2)	H37A—C37—H37B	109.5
C5—Ag5—Ag8	48.2 (2)	S2—C37—H37C	109.5
O7—Ag5—Ag8	148.8 (3)	H37A—C37—H37C	109.5
O9—Ag5—Ag8	115.5 (3)	H37B—C37—H37C	109.5
Ag7—Ag5—Ag8	58.43 (2)	S2—C38—H38A	109.5
Ag10—Ag5—Ag8	64.30 (3)	S2—C38—H38B	109.5
Ag9—Ag5—Ag8	59.97 (2)	H38A—C38—H38B	109.5
C12—Ag5—Ag11	45.4 (2)	S2—C38—H38C	109.5
C5—Ag5—Ag11	157.7 (2)	H38A—C38—H38C	109.5
O7—Ag5—Ag11	81.9 (2)	H38B—C38—H38C	109.5
O9—Ag5—Ag11	69.6 (2)	O19—S3—C40	105.4 (6)
Ag7—Ag5—Ag11	151.61 (3)	O19—S3—C39	105.1 (5)
Ag10—Ag5—Ag11	59.40 (3)	C40—S3—C39	98.0 (7)
Ag9—Ag5—Ag11	93.45 (3)	S3—O19—Ag6	130.9 (4)
Ag8—Ag5—Ag11	123.65 (3)	S3—O19—Ag3	123.5 (4)
C12—Ag5—Ag6	153.3 (2)	Ag6—O19—Ag3	102.4 (3)
C5—Ag5—Ag6	45.2 (2)	S3—C39—H39A	109.5
O7—Ag5—Ag6	70.2 (3)	S3—C39—H39B	109.5
O9—Ag5—Ag6	84.5 (3)	H39A—C39—H39B	109.5
Ag7—Ag5—Ag6	56.02 (2)	S3—C39—H39C	109.5
Ag10—Ag5—Ag6	153.83 (3)	H39A—C39—H39C	109.5
Ag9—Ag5—Ag6	117.69 (3)	H39B—C39—H39C	109.5
Ag8—Ag5—Ag6	91.88 (3)	S3—C40—H40A	109.5
Ag11—Ag5—Ag6	142.21 (3)	S3—C40—H40B	109.5
O8—Ag6—O20	108.6 (3)	H40A—C40—H40B	109.5
O8—Ag6—C5	118.1 (3)	S3—C40—H40C	109.5
O20—Ag6—C5	131.3 (3)	H40A—C40—H40C	109.5
O8—Ag6—O19	97.4 (3)	H40B—C40—H40C	109.5
O20—Ag6—O19	77.4 (3)	O20—S4—C42	104.8 (5)
C5—Ag6—O19	108.2 (3)	O20—S4—C41	104.3 (6)
O8—Ag6—C4	146.2 (3)	C42—S4—C41	98.6 (7)
O20—Ag6—C4	102.3 (3)	S4—O20—Ag6	128.3 (4)
C5—Ag6—C4	29.2 (3)	S4—O20—Ag4	121.6 (4)
O19—Ag6—C4	102.4 (3)	Ag6—O20—Ag4	107.1 (3)
O8—Ag6—Ag7	84.2 (3)	S4—C41—H41A	109.5
O20—Ag6—Ag7	157.66 (17)	S4—C41—H41B	109.5
C5—Ag6—Ag7	46.6 (2)	H41A—C41—H41B	109.5
O19—Ag6—Ag7	82.9 (2)	S4—C41—H41C	109.5
C4—Ag6—Ag7	71.6 (2)	H41A—C41—H41C	109.5
O8—Ag6—Ag5	80.1 (2)	H41B—C41—H41C	109.5
O20—Ag6—Ag5	144.92 (18)	S4—C42—H42A	109.5
C5—Ag6—Ag5	43.0 (2)	S4—C42—H42B	109.5
O19—Ag6—Ag5	136.5 (2)	H42A—C42—H42B	109.5
C4—Ag6—Ag5	66.69 (18)	S4—C42—H42C	109.5
Ag7—Ag6—Ag5	53.56 (2)	H42A—C42—H42C	109.5
O11—Ag7—C5	169.1 (3)	H42B—C42—H42C	109.5
O11—Ag7—O18	90.9 (3)	O21—S5—C43	106.5 (6)
C5—Ag7—O18	97.8 (3)	O21—S5—C44	104.2 (7)
O11—Ag7—Ag5	120.5 (2)	C43—S5—C44	97.0 (8)
C5—Ag7—Ag5	51.9 (2)	S5—O21—Ag11	124.0 (4)
O18—Ag7—Ag5	148.06 (18)	S5—O21—Ag9^ii	113.1 (4)
O11—Ag7—Ag8	135.8 (2)	Ag11—O21—Ag9^ii	120.5 (3)
C5—Ag7—Ag8	51.1 (2)	S5—C43—H43A	109.5
O18—Ag7—Ag8	90.52 (19)	S5—C43—H43B	109.5
Ag5—Ag7—Ag8	63.52 (3)	H43A—C43—H43B	109.5
O11—Ag7—Ag6	119.2 (2)	S5—C43—H43C	109.5
C5—Ag7—Ag6	52.8 (2)	H43A—C43—H43C	109.5
O18—Ag7—Ag6	100.75 (17)	H43B—C43—H43C	109.5
Ag5—Ag7—Ag6	70.42 (3)	S5—C44—H44A	109.5
Ag8—Ag7—Ag6	103.83 (3)	S5—C44—H44B	109.5
O11—Ag7—Ag9	81.9 (2)	H44A—C44—H44B	109.5
C5—Ag7—Ag9	98.4 (2)	S5—C44—H44C	109.5
O18—Ag7—Ag9	124.03 (18)	H44A—C44—H44C	109.5
Ag5—Ag7—Ag9	61.16 (2)	H44B—C44—H44C	109.5
Ag8—Ag7—Ag9	61.25 (2)	O22—S6—C45	105.0 (6)
Ag6—Ag7—Ag9	131.03 (3)	O22—S6—C46	101.0 (7)
C5—Ag8—O13	140.8 (3)	C45—S6—C46	97.5 (8)
C5—Ag8—O15	120.5 (3)	S6—O22—Ag10	111.2 (4)
O13—Ag8—O15	90.9 (3)	S6—O22—Ag11^ii	132.3 (4)
C5—Ag8—Ag7	48.2 (2)	Ag10—O22—Ag11^ii	111.9 (3)
O13—Ag8—Ag7	98.9 (2)	S6—C45—H45A	109.5
O15—Ag8—Ag7	168.7 (2)	S6—C45—H45B	109.5
C5—Ag8—Ag9	96.7 (2)	H45A—C45—H45B	109.5
O13—Ag8—Ag9	79.6 (2)	S6—C45—H45C	109.5
O15—Ag8—Ag9	126.1 (2)	H45A—C45—H45C	109.5
Ag7—Ag8—Ag9	61.84 (2)	H45B—C45—H45C	109.5
C5—Ag8—Ag5	48.8 (2)	S6—C46—H46A	109.5
O13—Ag8—Ag5	138.8 (2)	S6—C46—H46B	109.5
O15—Ag8—Ag5	116.9 (2)	H46A—C46—H46B	109.5
Ag7—Ag8—Ag5	58.05 (2)	S6—C46—H46C	109.5
Ag9—Ag8—Ag5	59.66 (2)	H46A—C46—H46C	109.5
C5—Ag8—Ag10	101.3 (2)	H46B—C46—H46C	109.5
O13—Ag8—Ag10	109.1 (2)	C19—O1—Ag4^i	122.5 (7)
O15—Ag8—Ag10	76.2 (2)	C19—O2—Ag2	116.5 (7)
Ag7—Ag8—Ag10	105.46 (3)	O1—C19—O2	128.6 (10)
Ag9—Ag8—Ag10	58.12 (2)	O1—C19—C20	115.5 (9)
Ag5—Ag8—Ag10	55.63 (2)	O2—C19—C20	115.7 (9)
O14—Ag9—C12	169.2 (3)	F2—C20—F1	108.7 (8)
O14—Ag9—O12	86.7 (3)	F2—C20—F3	106.0 (8)
C12—Ag9—O12	103.7 (3)	F1—C20—F3	105.7 (8)
O14—Ag9—O21^ii	81.2 (3)	F2—C20—C19	110.5 (8)
C12—Ag9—O21^ii	95.3 (3)	F1—C20—C19	114.3 (8)
O12—Ag9—O21^ii	89.9 (3)	F3—C20—C19	111.3 (9)
O14—Ag9—Ag10	123.7 (2)	C21—O3—Ag1	118.7 (6)
C12—Ag9—Ag10	46.0 (2)	C21—O4—Ag3	121.9 (6)
O12—Ag9—Ag10	149.7 (2)	O3—C21—O4	129.9 (9)
O21^ii—Ag9—Ag10	93.86 (17)	O3—C21—C22	114.3 (8)
O14—Ag9—Ag5	132.8 (2)	O4—C21—C22	115.8 (8)
C12—Ag9—Ag5	48.4 (2)	F6—C22—F5	107.7 (8)
O12—Ag9—Ag5	104.1 (2)	F6—C22—F4	107.2 (8)
O21^ii—Ag9—Ag5	143.04 (18)	F5—C22—F4	106.5 (8)
Ag10—Ag9—Ag5	57.42 (2)	F6—C22—C21	111.3 (8)
O14—Ag9—Ag8	78.3 (2)	F5—C22—C21	109.3 (8)
C12—Ag9—Ag8	96.6 (2)	F4—C22—C21	114.6 (8)
O12—Ag9—Ag8	132.48 (18)	C23—O5—Ag2	124.6 (7)
O21^ii—Ag9—Ag8	130.8 (2)	C23—O6—Ag4^i	128.5 (7)
Ag10—Ag9—Ag8	63.14 (3)	O5—C23—O6	129.5 (9)
Ag5—Ag9—Ag8	60.37 (2)	O5—C23—C24	115.2 (9)
O14—Ag9—Ag7	82.6 (3)	O6—C23—C24	115.4 (8)
C12—Ag9—Ag7	102.8 (2)	F9—C24—F8	107.8 (8)
O12—Ag9—Ag7	76.71 (19)	F9—C24—F7	106.8 (8)
O21^ii—Ag9—Ag7	159.52 (17)	F8—C24—F7	106.8 (8)
Ag10—Ag9—Ag7	105.57 (3)	F9—C24—C23	110.5 (8)
Ag5—Ag9—Ag7	56.75 (2)	F8—C24—C23	113.4 (8)
Ag8—Ag9—Ag7	56.91 (2)	F7—C24—C23	111.3 (8)
C12—Ag10—O16	162.8 (3)	C25—O7—Ag5	129.3 (8)
C12—Ag10—O22	106.5 (3)	C25—O8—Ag6	122.9 (8)
O16—Ag10—O22	90.4 (3)	O7—C25—O8	130.1 (12)
C12—Ag10—Ag5	50.9 (2)	O7—C25—C26	114.9 (10)
O16—Ag10—Ag5	113.3 (2)	O8—C25—C26	115.0 (10)
O22—Ag10—Ag5	154.39 (18)	F12—C26—F11	108.0 (9)
C12—Ag10—Ag9	48.8 (2)	F12—C26—F10	107.4 (9)
O16—Ag10—Ag9	134.7 (2)	F11—C26—F10	108.2 (8)
O22—Ag10—Ag9	95.19 (18)	F12—C26—C25	111.7 (9)
Ag5—Ag10—Ag9	61.47 (2)	F11—C26—C25	108.8 (9)
C12—Ag10—Ag11	49.3 (3)	F10—C26—C25	112.6 (9)
O16—Ag10—Ag11	122.1 (2)	C27—O9—Ag5	129.9 (8)
O22—Ag10—Ag11	109.84 (18)	C27—O10—Ag11	118.9 (7)
Ag5—Ag10—Ag11	66.73 (3)	O9—C27—O10	130.5 (11)
Ag9—Ag10—Ag11	98.00 (3)	O9—C27—C28	114.7 (10)
C12—Ag10—Ag8	95.0 (2)	O10—C27—C28	114.7 (9)
O16—Ag10—Ag8	79.3 (2)	F13—C28—F14	109.7 (8)
O22—Ag10—Ag8	118.74 (18)	F13—C28—F15	106.2 (8)
Ag5—Ag10—Ag8	60.08 (2)	F14—C28—F15	106.4 (8)
Ag9—Ag10—Ag8	58.74 (2)	F13—C28—C27	114.0 (8)
Ag11—Ag10—Ag8	126.76 (3)	F14—C28—C27	110.7 (8)
O10—Ag11—C12	125.2 (3)	F15—C28—C27	109.5 (8)
O10—Ag11—O21	102.2 (3)	C29—O11—Ag7	125.2 (7)
C12—Ag11—O21	126.2 (3)	C29—O12—Ag9	121.2 (7)
O10—Ag11—C13	141.7 (3)	O12—C29—O11	130.0 (10)
C12—Ag11—C13	28.8 (3)	O12—C29—C30	117.1 (8)
O21—Ag11—C13	97.8 (3)	O11—C29—C30	113.0 (8)
O10—Ag11—O22'^ii	110.8 (3)	F18—C30—F17	108.4 (8)
C12—Ag11—O22'^ii	95.2 (3)	F18—C30—F16	107.3 (7)
O21—Ag11—O22'^ii	89.4 (3)	F17—C30—F16	106.0 (7)
C13—Ag11—O22'^ii	101.6 (3)	F18—C30—C29	112.1 (8)
O10—Ag11—O22^ii	110.8 (3)	F17—C30—C29	112.7 (8)
C12—Ag11—O22^ii	95.2 (3)	F16—C30—C29	110.0 (8)
O21—Ag11—O22^ii	89.4 (3)	C31—O13—Ag8	119.9 (7)
C13—Ag11—O22^ii	101.6 (3)	C31—O14—Ag9	124.7 (7)
O10—Ag11—Ag10	114.7 (2)	O14—C31—O13	130.2 (10)
C12—Ag11—Ag10	44.6 (2)	O14—C31—C32	114.1 (9)
O21—Ag11—Ag10	136.36 (19)	O13—C31—C32	115.7 (9)
C13—Ag11—Ag10	67.1 (2)	F21—C32—F19	108.0 (8)
O22'^ii—Ag11—Ag10	56.89 (18)	F21—C32—F20	108.0 (8)
O22^ii—Ag11—Ag10	56.89 (18)	F19—C32—F20	107.9 (8)
O10—Ag11—Ag5	82.0 (2)	F21—C32—C31	112.3 (9)
C12—Ag11—Ag5	43.6 (2)	F19—C32—C31	112.3 (8)
O21—Ag11—Ag5	159.7 (2)	F20—C32—C31	108.3 (8)
C13—Ag11—Ag5	68.8 (2)	C33—O15—Ag8	124.4 (7)
O22'^ii—Ag11—Ag5	107.75 (18)	C33—O16—Ag10	126.2 (7)
O22^ii—Ag11—Ag5	107.75 (18)	O15—C33—O16	130.1 (9)
Ag10—Ag11—Ag5	53.87 (2)	O15—C33—C34	117.6 (8)
C2—C1—Ag1	172.1 (7)	O16—C33—C34	112.3 (8)
C2—C1—Ag4	103.9 (7)	F22—C34—F23	108.6 (7)
Ag1—C1—Ag4	77.4 (3)	F22—C34—F24	108.3 (7)
C2—C1—Ag2	98.4 (7)	F23—C34—F24	106.9 (7)
Ag1—C1—Ag2	79.9 (3)	F22—C34—C33	112.4 (7)
Ag4—C1—Ag2	157.3 (4)	F23—C34—C33	112.1 (7)
C2—C1—Ag3	93.1 (6)	F24—C34—C33	108.3 (7)
Ag4—C1—C2—Ag3	−94.4 (4)	O2—C19—C20—F3	−128.3 (11)
Ag2—C1—C2—Ag3	81.5 (3)	Ag1—O3—C21—O4	−8.0 (15)
Ag1^i—C1—C2—Ag3	174.4 (7)	Ag1—O3—C21—C22	170.8 (6)
Ag3—C2—C3—C6	−165.8 (8)	Ag3—O4—C21—O3	−23.5 (16)
Ag3—C2—C3—C4	12.6 (10)	Ag3—O4—C21—C22	157.8 (6)
C6—C3—C4—Ag6	−116.9 (9)	O3—C21—C22—F6	155.6 (10)
C2—C3—C4—Ag6	64.6 (9)	O4—C21—C22—F6	−25.5 (13)
Ag6—C4—C5—Ag7	−62.8 (9)	O3—C21—C22—F5	−85.6 (11)
Ag6—C4—C5—Ag8	−169.6 (6)	O4—C21—C22—F5	93.3 (11)
Ag6—C4—C5—Ag5	81.8 (9)	O3—C21—C22—F4	33.8 (13)
C2—C3—C6—C7	−178.4 (9)	O4—C21—C22—F4	−147.3 (10)
C4—C3—C6—C7	3.3 (15)	Ag2—O5—C23—O6	−4.2 (17)
C2—C3—C6—C11	2.4 (16)	Ag2—O5—C23—C24	175.3 (6)
C4—C3—C6—C11	−175.9 (9)	Ag4^i—O6—C23—O5	−19.8 (17)
C3—C6—C7—C8	−122.7 (11)	Ag4^i—O6—C23—C24	160.6 (6)
C11—C6—C7—C8	56.6 (12)	O5—C23—C24—F9	−117.3 (11)
C6—C7—C8—C9	−56.2 (12)	O6—C23—C24—F9	62.3 (12)
C7—C8—C9—C10	55.7 (14)	O5—C23—C24—F8	3.8 (13)
C8—C9—C10—C11	−54.3 (14)	O6—C23—C24—F8	−176.5 (10)
C3—C6—C11—C10	124.2 (11)	O5—C23—C24—F7	124.3 (10)
C7—C6—C11—C10	−55.1 (13)	O6—C23—C24—F7	−56.1 (12)
C9—C10—C11—C6	53.3 (13)	Ag5—O7—C25—O8	30 (2)
Ag10—C12—C13—C14	21 (6)	Ag5—O7—C25—C26	−148.5 (9)
Ag9—C12—C13—C14	−77 (6)	Ag6—O8—C25—O7	−2 (2)
Ag5—C12—C13—C14	−177 (5)	Ag6—O8—C25—C26	176.3 (7)
Ag11—C12—C13—C14	100 (6)	O7—C25—C26—F12	−151.5 (12)
Ag10—C12—C13—Ag11	−78.8 (9)	O8—C25—C26—F12	29.7 (15)
Ag9—C12—C13—Ag11	−176.8 (5)	O7—C25—C26—F11	89.4 (13)
Ag5—C12—C13—Ag11	83.0 (12)	O8—C25—C26—F11	−89.4 (12)
C12—C13—C14—C15	151 (5)	O7—C25—C26—F10	−30.5 (14)
Ag11—C13—C14—C15	−113.1 (4)	O8—C25—C26—F10	150.7 (11)
C12—C13—C14—C13^ii	−29 (5)	Ag5—O9—C27—O10	−22 (2)
Ag11—C13—C14—C13^ii	66.9 (4)	Ag5—O9—C27—C28	154.1 (9)
C13—C14—C15—C16^ii	−161.9 (11)	Ag11—O10—C27—O9	−10.4 (19)
C13^ii—C14—C15—C16^ii	18.1 (11)	Ag11—O10—C27—C28	173.4 (6)
C13—C14—C15—C16	18.1 (11)	O9—C27—C28—F13	171.5 (11)
C13^ii—C14—C15—C16	−161.9 (11)	O10—C27—C28—F13	−11.7 (14)
C14—C15—C16—C17	−145.4 (9)	O9—C27—C28—F14	47.3 (14)
C16^ii—C15—C16—C17	34.6 (9)	O10—C27—C28—F14	−135.9 (11)
C15—C16—C17—C18	−67.3 (17)	O9—C27—C28—F15	−69.7 (13)
C16—C17—C18—C17^ii	36.6 (9)	O10—C27—C28—F15	107.1 (11)
C35—S1—O17—Ag2	35.2 (10)	Ag9—O12—C29—O11	11.4 (17)
C36—S1—O17—Ag2	−69.0 (9)	Ag9—O12—C29—C30	−168.5 (6)
C37—S2—O18—Ag3	84.9 (8)	Ag7—O11—C29—O12	11.5 (17)
C38—S2—O18—Ag3	−16.8 (9)	Ag7—O11—C29—C30	−168.6 (6)
C37—S2—O18—Ag7	−96.8 (7)	O12—C29—C30—F18	−6.2 (13)
C38—S2—O18—Ag7	161.5 (6)	O11—C29—C30—F18	173.8 (9)
C40—S3—O19—Ag6	66.6 (9)	O12—C29—C30—F17	−128.9 (10)
C39—S3—O19—Ag6	−36.4 (8)	O11—C29—C30—F17	51.2 (11)
C40—S3—O19—Ag3	−89.7 (8)	O12—C29—C30—F16	113.1 (10)
C39—S3—O19—Ag3	167.3 (6)	O11—C29—C30—F16	−66.9 (11)
C42—S4—O20—Ag6	42.4 (8)	Ag9—O14—C31—O13	10.8 (18)
C41—S4—O20—Ag6	−60.7 (7)	Ag9—O14—C31—C32	−166.8 (6)
C42—S4—O20—Ag4	−160.0 (6)	Ag8—O13—C31—O14	16.2 (17)
C41—S4—O20—Ag4	96.9 (6)	Ag8—O13—C31—C32	−166.3 (6)
C43—S5—O21—Ag11	68.5 (8)	O14—C31—C32—F21	−20.2 (13)
C44—S5—O21—Ag11	−33.4 (10)	O13—C31—C32—F21	161.9 (10)
C43—S5—O21—Ag9^ii	−129.1 (6)	O14—C31—C32—F19	−142.1 (10)
C44—S5—O21—Ag9^ii	129.1 (8)	O13—C31—C32—F19	40.0 (13)
C45—S6—O22—Ag10	−178.6 (6)	O14—C31—C32—F20	98.9 (11)
C46—S6—O22—Ag10	80.4 (7)	O13—C31—C32—F20	−79.0 (11)
C45—S6—O22—Ag11^ii	28.0 (9)	Ag8—O15—C33—O16	−11.9 (17)
C46—S6—O22—Ag11^ii	−72.9 (8)	Ag8—O15—C33—C34	170.8 (6)
Ag4^i—O1—C19—O2	−40.0 (16)	Ag10—O16—C33—O15	−8.7 (17)
Ag4^i—O1—C19—C20	144.9 (7)	Ag10—O16—C33—C34	168.7 (6)
Ag2—O2—C19—O1	−6.9 (16)	O15—C33—C34—F22	−145.2 (9)
Ag2—O2—C19—C20	168.1 (6)	O16—C33—C34—F22	37.1 (11)
O1—C19—C20—F2	−70.1 (13)	O15—C33—C34—F23	−22.5 (12)
O2—C19—C20—F2	114.2 (11)	O16—C33—C34—F23	159.8 (8)
O1—C19—C20—F1	167.0 (11)	O15—C33—C34—F24	95.1 (10)
O2—C19—C20—F1	−8.7 (14)	O16—C33—C34—F24	−82.6 (10)
O1—C19—C20—F3	47.4 (13)

Symmetry codes: (i) −x+3/2, −y+3/2, −z+1; (ii) −x+1, y, −z+1/2.

(III)

Crystal data

7(Ag^+)·(C12H12^2^−)·5(C2F3O2^−)·5(C2H6SO)	Z = 4
Mr = 1867.04	F(000) = 3592
Monoclinic, Cc	Dx = 2.329 Mg m^−3
a = 17.8567 (17) Å	Mo Kα radiation, λ = 0.71073 Å
b = 21.007 (2) Å	µ = 2.83 mm^−1
c = 16.044 (3) Å	T = 173 K
β = 117.802 (1)°	Block, yellow
V = 5323.6 (12) Å^3	0.50 × 0.40 × 0.40 mm

Data collection

Bruker APEX-II CCD diffractometer	5135 reflections with I > 2σ(I)
φ and ω scan	Rint = 0.102
Absorption correction: multi-scan SADABS (Bruker, 2003)	θmax = 25.3°, θmin = 2.4°
Tmin = 0.332, Tmax = 0.398	h = −20→21
19165 measured reflections	k = −25→25
6449 independent reflections	l = −19→19

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.066	w = 1/[σ^2(Fo^2) + (0.0867P)^2] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.165	(Δ/σ)max < 0.001
S = 1.05	Δρmax = 1.67 e Å^−3
6449 reflections	Δρmin = −1.38 e Å^−3
668 parameters	Absolute structure: Refined as an inversion twin.
184 restraints	Absolute structure parameter: 0.48 (12)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.05523 (11)	0.21197 (9)	0.41366 (11)	0.0285 (4)
Ag2	0.11214 (12)	0.33360 (9)	0.38233 (13)	0.0367 (5)
Ag3	0.04057 (10)	0.24222 (8)	0.22717 (11)	0.0228 (4)
Ag4	0.14247 (13)	0.12186 (9)	0.34269 (15)	0.0404 (5)
Ag5	0.40369 (11)	0.32840 (8)	0.72935 (12)	0.0299 (4)
Ag6	0.42058 (11)	0.19386 (9)	0.76250 (12)	0.0301 (4)
Ag7	0.25700 (11)	0.23919 (10)	0.61825 (13)	0.0386 (5)
C1	0.1493 (14)	0.2320 (11)	0.3680 (15)	0.029 (5)
C2	0.2257 (15)	0.2297 (12)	0.4068 (15)	0.031 (5)
C3	0.3177 (14)	0.2338 (14)	0.4484 (14)	0.037 (6)
C4	0.3576 (14)	0.2431 (12)	0.5497 (16)	0.033 (6)
C5	0.3974 (13)	0.2495 (12)	0.6349 (15)	0.032 (6)
C6	0.3601 (19)	0.2232 (16)	0.400 (2)	0.060 (9)	0.6667
C7	0.460 (2)	0.220 (2)	0.451 (3)	0.053 (4)*	0.6667
H7A	0.4833	0.2536	0.4997	0.064*	0.6667
H7B	0.4784	0.1781	0.4842	0.064*	0.6667
C8	0.496 (2)	0.227 (2)	0.386 (3)	0.053 (4)*	0.6667
H8A	0.4831	0.1879	0.3469	0.064*	0.6667
H8B	0.5588	0.2293	0.4237	0.064*	0.6667
C9	0.466 (3)	0.283 (2)	0.322 (3)	0.053 (4)*	0.6667
H9A	0.4643	0.3201	0.3599	0.064*	0.6667
H9B	0.5098	0.2933	0.3022	0.064*	0.6667
C10	0.384 (3)	0.279 (2)	0.238 (3)	0.053 (4)*	0.6667
H10A	0.3923	0.2493	0.1949	0.064*	0.6667
H10B	0.3744	0.3217	0.2072	0.064*	0.6667
C11	0.305 (3)	0.261 (2)	0.237 (3)	0.053 (4)*	0.6667
H11A	0.2848	0.2967	0.2622	0.064*	0.6667
H11B	0.2610	0.2534	0.1711	0.064*	0.6667
C12	0.314 (3)	0.204 (2)	0.293 (2)	0.053 (4)*	0.6667
H12A	0.3476	0.1712	0.2805	0.064*	0.6667
H12B	0.2577	0.1853	0.2769	0.064*	0.6667
C6'	0.3601 (19)	0.2232 (16)	0.400 (2)	0.060 (9)	0.3333
C7'	0.454 (3)	0.249 (3)	0.441 (4)	0.053 (4)*	0.3333
H7'1	0.4538	0.2915	0.4141	0.064*	0.3333
H7'2	0.4789	0.2538	0.5103	0.064*	0.3333
C8'	0.508 (3)	0.206 (4)	0.420 (4)	0.053 (4)*	0.3333
H8'1	0.4946	0.1614	0.4288	0.064*	0.3333
H8'2	0.5679	0.2138	0.4652	0.064*	0.3333
C9'	0.498 (4)	0.212 (4)	0.322 (4)	0.053 (4)*	0.3333
H9'1	0.5355	0.2468	0.3223	0.064*	0.3333
H9'2	0.5192	0.1721	0.3071	0.064*	0.3333
C10'	0.413 (4)	0.224 (4)	0.244 (4)	0.053 (4)*	0.3333
H10C	0.3857	0.1821	0.2242	0.064*	0.3333
H10D	0.4217	0.2405	0.1913	0.064*	0.3333
C11'	0.350 (5)	0.266 (3)	0.251 (4)	0.053 (4)*	0.3333
H11C	0.3799	0.3037	0.2901	0.064*	0.3333
H11D	0.3108	0.2819	0.1871	0.064*	0.3333
C12'	0.302 (3)	0.234 (4)	0.292 (3)	0.053 (4)*	0.3333
H12C	0.2804	0.1932	0.2597	0.064*	0.3333
H12D	0.2530	0.2611	0.2822	0.064*	0.3333
S1	0.1405 (4)	0.1037 (3)	0.6040 (5)	0.0442 (16)
O11	0.1697 (11)	0.1449 (9)	0.5468 (13)	0.045 (4)
C23	0.0815 (19)	0.0433 (14)	0.5270 (18)	0.060 (9)
H23A	0.0233	0.0580	0.4878	0.091*
H23B	0.0809	0.0059	0.5632	0.091*
H23C	0.1069	0.0319	0.4865	0.091*
C24	0.2318 (17)	0.0575 (15)	0.674 (2)	0.058 (8)
H24A	0.2565	0.0418	0.6349	0.086*
H24B	0.2159	0.0214	0.7012	0.086*
H24C	0.2734	0.0840	0.7250	0.086*
S2	0.3256 (7)	0.0485 (5)	0.4307 (7)	0.048 (3)	0.6667
O12	0.2326 (14)	0.0380 (10)	0.4092 (17)	0.108 (12)	0.6667
C25	0.370 (2)	−0.0299 (15)	0.448 (3)	0.110 (18)	0.6667
H25A	0.3714	−0.0488	0.5048	0.165*	0.6667
H25B	0.4282	−0.0272	0.4566	0.165*	0.6667
H25C	0.3359	−0.0564	0.3934	0.165*	0.6667
C26	0.372 (3)	0.0777 (19)	0.542 (3)	0.100 (15)	0.6667
H26A	0.3312	0.1025	0.5528	0.149*	0.6667
H26B	0.4200	0.1052	0.5510	0.149*	0.6667
H26C	0.3934	0.0424	0.5872	0.149*	0.6667
S2'	0.3112 (13)	0.0132 (10)	0.4949 (14)	0.060 (6)	0.3333
O12'	0.2326 (14)	0.0380 (10)	0.4092 (17)	0.108 (12)	0.3333
C25'	0.370 (2)	−0.0299 (15)	0.448 (3)	0.110 (18)	0.3333
H25D	0.3406	−0.0278	0.3794	0.165*	0.3333
H25E	0.3760	−0.0744	0.4686	0.165*	0.3333
H25F	0.4267	−0.0108	0.4718	0.165*	0.3333
C26'	0.372 (3)	0.0777 (19)	0.542 (3)	0.100 (15)	0.3333
H26D	0.4154	0.0802	0.5204	0.149*	0.3333
H26E	0.4005	0.0744	0.6111	0.149*	0.3333
H26F	0.3373	0.1161	0.5226	0.149*	0.3333
S3	0.2714 (4)	0.4024 (3)	0.5144 (4)	0.0405 (15)
O13	0.3128 (10)	0.4037 (8)	0.6203 (11)	0.035 (4)
C27	0.2331 (19)	0.4778 (11)	0.477 (2)	0.063 (9)
H27A	0.1902	0.4881	0.4966	0.094*
H27B	0.2077	0.4798	0.4081	0.094*
H27C	0.2796	0.5085	0.5047	0.094*
C28	0.358 (3)	0.4030 (17)	0.487 (3)	0.073 (10)
H28A	0.3746	0.4471	0.4833	0.110*
H28B	0.3412	0.3818	0.4263	0.110*
H28C	0.4067	0.3804	0.5364	0.110*
S4	0.4745 (4)	0.4813 (3)	0.7282 (4)	0.0389 (14)
O14	0.5033 (9)	0.4228 (8)	0.7893 (11)	0.035 (4)
C29	0.5619 (17)	0.5350 (14)	0.778 (2)	0.053 (7)
H29A	0.5843	0.5363	0.8466	0.080*
H29B	0.5431	0.5777	0.7519	0.080*
H29C	0.6063	0.5205	0.7628	0.080*
C30	0.411 (2)	0.5198 (14)	0.766 (3)	0.062 (8)
H30A	0.3588	0.4951	0.7473	0.092*
H30B	0.3962	0.5621	0.7370	0.092*
H30C	0.4408	0.5240	0.8346	0.092*
S5	0.0839 (6)	0.3477 (5)	0.5827 (7)	0.044 (2)	0.6667
O15	0.1280 (12)	0.2986 (9)	0.5517 (11)	0.049 (5)	0.6667
C31	0.168 (3)	0.385 (2)	0.688 (3)	0.061 (15)*	0.6667
H31A	0.2063	0.3521	0.7292	0.091*	0.6667
H31B	0.1430	0.4082	0.7219	0.091*	0.6667
H31C	0.2000	0.4147	0.6694	0.091*	0.6667
C32	0.033 (3)	0.294 (2)	0.631 (3)	0.061 (12)*	0.6667
H32A	−0.0054	0.2651	0.5816	0.092*	0.6667
H32B	0.0017	0.3186	0.6560	0.092*	0.6667
H32C	0.0769	0.2685	0.6823	0.092*	0.6667
S5'	0.0961 (11)	0.3024 (9)	0.6267 (12)	0.033 (4)	0.3333
O15'	0.1280 (12)	0.2986 (9)	0.5517 (11)	0.049 (5)	0.3333
C31'	0.164 (3)	0.365 (3)	0.706 (4)	0.027 (17)*	0.3333
H31D	0.2204	0.3622	0.7096	0.040*	0.3333
H31E	0.1695	0.3582	0.7692	0.040*	0.3333
H31F	0.1393	0.4064	0.6823	0.040*	0.3333
C32'	−0.002 (3)	0.347 (3)	0.557 (4)	0.024 (14)*	0.3333
H32D	0.0031	0.3719	0.5085	0.037*	0.3333
H32E	−0.0133	0.3755	0.5983	0.037*	0.3333
H32F	−0.0497	0.3169	0.5265	0.037*	0.3333
O1	0.1682 (14)	0.3887 (11)	0.2927 (12)	0.070 (7)
O2	0.0739 (13)	0.3357 (10)	0.1674 (12)	0.059 (6)
C13	0.1275 (14)	0.3779 (11)	0.2075 (16)	0.032 (5)
C14	0.1460 (12)	0.4217 (10)	0.1450 (13)	0.055 (8)
F1	0.168 (2)	0.3874 (12)	0.094 (2)	0.175 (14)
F2	0.2057 (15)	0.4624 (13)	0.1887 (17)	0.149 (11)
F3	0.0804 (13)	0.4543 (13)	0.0890 (17)	0.138 (11)
O3	0.0449 (12)	0.4248 (9)	0.3854 (14)	0.058 (5)
O4	−0.0666 (12)	0.4133 (8)	0.2481 (14)	0.063 (6)
C15	−0.0124 (16)	0.4448 (13)	0.3141 (18)	0.041 (6)
C16	−0.0154 (10)	0.5179 (9)	0.2985 (12)	0.052 (7)
F4	0.0272 (12)	0.5489 (9)	0.3757 (12)	0.109 (8)
F5	−0.0922 (10)	0.5377 (9)	0.2602 (14)	0.090 (6)
F6	0.0159 (14)	0.5314 (11)	0.2429 (16)	0.115 (9)
O5	0.0744 (14)	0.1829 (11)	0.1306 (12)	0.060 (6)
O6	0.1345 (17)	0.0909 (9)	0.1980 (15)	0.068 (7)
C17	0.1162 (17)	0.1374 (14)	0.1374 (17)	0.040 (6)
C18	0.1431 (10)	0.1278 (7)	0.0598 (12)	0.046 (7)
F7	0.2067 (10)	0.0910 (8)	0.0838 (13)	0.082 (6)
F8	0.0799 (10)	0.1051 (7)	−0.0134 (11)	0.073 (5)
F9	0.1611 (11)	0.1827 (6)	0.0373 (14)	0.074 (5)
O7	0.3642 (11)	0.3586 (9)	0.8370 (12)	0.042 (4)
O8	0.4700 (11)	0.3179 (9)	0.9668 (12)	0.041 (4)
C19	0.4033 (16)	0.3439 (11)	0.9230 (18)	0.033 (6)
C20	0.3588 (11)	0.3657 (9)	0.9832 (12)	0.051 (8)
F10	0.2800 (9)	0.3798 (9)	0.9324 (12)	0.082 (6)
F11	0.3631 (16)	0.3225 (11)	1.0419 (16)	0.132 (10)
F12	0.3974 (12)	0.4152 (11)	1.0302 (15)	0.119 (9)
O9	0.3629 (15)	0.1800 (11)	0.8611 (15)	0.065 (6)
O10	0.2374 (12)	0.2199 (12)	0.7479 (13)	0.061 (6)
C21	0.2898 (19)	0.2016 (14)	0.833 (2)	0.048 (7)
C22	0.2478 (11)	0.1923 (8)	0.8957 (12)	0.051 (7)
F13	0.2009 (12)	0.2400 (8)	0.8908 (13)	0.080 (6)
F14	0.3049 (10)	0.1852 (10)	0.9817 (12)	0.097 (7)
F15	0.2010 (12)	0.1418 (8)	0.8727 (14)	0.090 (6)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0239 (8)	0.0374 (10)	0.0222 (7)	−0.0042 (7)	0.0091 (7)	0.0028 (7)
Ag2	0.0384 (10)	0.0279 (9)	0.0333 (9)	−0.0004 (8)	0.0080 (8)	−0.0014 (8)
Ag3	0.0174 (7)	0.0303 (9)	0.0177 (7)	0.0011 (7)	0.0056 (6)	0.0007 (7)
Ag4	0.0410 (11)	0.0316 (10)	0.0515 (11)	−0.0018 (9)	0.0240 (9)	0.0001 (9)
Ag5	0.0268 (8)	0.0346 (10)	0.0242 (8)	0.0058 (7)	0.0083 (7)	−0.0007 (7)
Ag6	0.0285 (9)	0.0320 (10)	0.0308 (8)	0.0000 (8)	0.0146 (7)	0.0074 (7)
Ag7	0.0203 (9)	0.0668 (14)	0.0263 (8)	−0.0059 (9)	0.0088 (7)	0.0002 (9)
C1	0.033 (9)	0.031 (10)	0.028 (9)	0.010 (8)	0.018 (8)	0.011 (7)
C2	0.029 (9)	0.047 (10)	0.020 (8)	−0.005 (8)	0.015 (7)	−0.003 (8)
C3	0.016 (11)	0.074 (19)	0.016 (10)	−0.002 (11)	0.002 (9)	−0.009 (11)
C4	0.019 (11)	0.058 (17)	0.027 (12)	0.005 (11)	0.015 (10)	0.006 (11)
C5	0.013 (10)	0.065 (17)	0.014 (9)	−0.012 (10)	0.002 (8)	0.002 (10)
C6	0.046 (17)	0.09 (3)	0.039 (15)	−0.015 (17)	0.017 (13)	−0.011 (16)
C6'	0.046 (17)	0.09 (3)	0.039 (15)	−0.015 (17)	0.017 (13)	−0.011 (16)
S1	0.044 (4)	0.044 (4)	0.037 (3)	−0.003 (3)	0.013 (3)	0.005 (3)
O11	0.039 (10)	0.045 (11)	0.041 (10)	−0.009 (8)	0.009 (8)	0.015 (9)
C23	0.063 (19)	0.043 (17)	0.032 (13)	−0.013 (14)	−0.013 (13)	0.009 (12)
C24	0.030 (14)	0.050 (19)	0.07 (2)	0.004 (12)	0.007 (13)	0.014 (15)
S2	0.058 (6)	0.041 (6)	0.032 (5)	0.006 (5)	0.010 (4)	0.000 (4)
O12	0.063 (15)	0.047 (14)	0.13 (2)	0.034 (12)	−0.022 (15)	−0.020 (15)
C25	0.07 (2)	0.05 (2)	0.17 (4)	0.015 (19)	0.02 (3)	−0.05 (3)
C26	0.17 (4)	0.08 (3)	0.09 (3)	0.02 (3)	0.09 (3)	0.01 (2)
S2'	0.072 (16)	0.057 (15)	0.046 (12)	0.001 (12)	0.021 (11)	0.000 (11)
O12'	0.063 (15)	0.047 (14)	0.13 (2)	0.034 (12)	−0.022 (15)	−0.020 (15)
C25'	0.07 (2)	0.05 (2)	0.17 (4)	0.015 (19)	0.02 (3)	−0.05 (3)
C26'	0.17 (4)	0.08 (3)	0.09 (3)	0.02 (3)	0.09 (3)	0.01 (2)
S3	0.042 (3)	0.029 (3)	0.034 (3)	−0.003 (3)	0.003 (3)	0.003 (3)
O13	0.037 (9)	0.036 (10)	0.033 (8)	0.016 (8)	0.016 (7)	0.013 (7)
C27	0.054 (17)	0.013 (12)	0.08 (2)	−0.001 (12)	−0.006 (15)	0.006 (13)
C28	0.11 (3)	0.06 (2)	0.07 (2)	−0.01 (2)	0.05 (2)	−0.009 (17)
S4	0.040 (3)	0.034 (3)	0.037 (3)	0.001 (3)	0.013 (3)	0.000 (3)
O14	0.025 (8)	0.042 (10)	0.039 (9)	−0.012 (7)	0.017 (7)	−0.007 (8)
C29	0.040 (15)	0.040 (16)	0.068 (19)	−0.001 (13)	0.014 (14)	−0.001 (14)
C30	0.059 (19)	0.034 (16)	0.08 (2)	0.011 (14)	0.026 (17)	0.000 (15)
S5	0.040 (5)	0.057 (7)	0.039 (5)	0.016 (5)	0.022 (4)	0.006 (5)
O15	0.047 (11)	0.070 (13)	0.025 (8)	0.008 (10)	0.013 (8)	−0.003 (8)
S5'	0.034 (10)	0.041 (12)	0.033 (9)	0.008 (8)	0.022 (8)	0.001 (8)
O15'	0.047 (11)	0.070 (13)	0.025 (8)	0.008 (10)	0.013 (8)	−0.003 (8)
O1	0.080 (15)	0.070 (15)	0.026 (9)	−0.033 (12)	−0.004 (10)	0.006 (9)
O2	0.058 (12)	0.077 (15)	0.026 (9)	−0.023 (11)	0.007 (9)	0.020 (9)
C13	0.028 (12)	0.027 (13)	0.034 (13)	−0.006 (10)	0.008 (10)	−0.002 (10)
C14	0.051 (17)	0.08 (2)	0.019 (11)	−0.017 (16)	0.006 (12)	−0.005 (13)
F1	0.22 (2)	0.17 (2)	0.19 (2)	−0.015 (18)	0.145 (19)	0.043 (18)
F2	0.151 (19)	0.143 (18)	0.131 (18)	−0.087 (15)	0.048 (14)	0.021 (15)
F3	0.128 (17)	0.151 (19)	0.114 (16)	−0.010 (15)	0.041 (14)	0.081 (15)
O3	0.044 (11)	0.047 (12)	0.057 (12)	0.004 (9)	0.001 (10)	0.000 (10)
O4	0.041 (11)	0.031 (10)	0.066 (13)	−0.004 (9)	−0.017 (10)	0.014 (10)
C15	0.039 (14)	0.046 (17)	0.037 (13)	−0.006 (13)	0.018 (12)	0.007 (12)
C16	0.052 (17)	0.032 (16)	0.055 (17)	−0.005 (13)	0.010 (14)	−0.005 (14)
F4	0.128 (15)	0.036 (10)	0.092 (13)	0.000 (10)	−0.010 (11)	−0.002 (10)
F5	0.074 (12)	0.056 (11)	0.109 (14)	0.014 (9)	0.018 (11)	−0.013 (10)
F6	0.137 (17)	0.081 (14)	0.163 (19)	−0.012 (12)	0.099 (15)	0.031 (13)
O5	0.076 (14)	0.078 (15)	0.031 (9)	0.047 (12)	0.029 (10)	0.007 (9)
O6	0.14 (2)	0.020 (10)	0.058 (12)	0.003 (11)	0.052 (14)	−0.001 (9)
C17	0.041 (10)	0.054 (11)	0.036 (9)	−0.013 (9)	0.026 (8)	−0.005 (8)
C18	0.057 (11)	0.046 (11)	0.052 (11)	0.006 (9)	0.039 (9)	0.001 (9)
F7	0.096 (13)	0.077 (12)	0.082 (12)	0.029 (10)	0.048 (11)	0.017 (10)
F8	0.123 (14)	0.050 (10)	0.061 (10)	0.004 (10)	0.055 (10)	−0.002 (8)
F9	0.089 (12)	0.061 (11)	0.108 (13)	0.011 (9)	0.075 (11)	0.017 (10)
O7	0.036 (9)	0.053 (12)	0.034 (9)	0.012 (8)	0.015 (8)	−0.006 (8)
O8	0.044 (11)	0.050 (11)	0.033 (9)	0.021 (9)	0.020 (8)	0.004 (8)
C19	0.038 (14)	0.019 (12)	0.051 (15)	−0.003 (10)	0.029 (13)	−0.015 (11)
C20	0.047 (16)	0.08 (2)	0.025 (12)	0.018 (15)	0.019 (12)	0.002 (14)
F10	0.059 (10)	0.109 (14)	0.102 (13)	0.003 (10)	0.057 (10)	−0.021 (11)
F11	0.150 (18)	0.17 (2)	0.117 (17)	0.059 (15)	0.098 (15)	0.032 (15)
F12	0.102 (14)	0.155 (18)	0.113 (15)	−0.009 (13)	0.061 (12)	−0.095 (14)
O9	0.079 (16)	0.081 (16)	0.060 (13)	−0.005 (13)	0.054 (12)	0.022 (11)
O10	0.039 (11)	0.117 (18)	0.040 (10)	−0.014 (11)	0.029 (9)	0.010 (11)
C21	0.049 (11)	0.046 (12)	0.060 (11)	0.000 (9)	0.034 (9)	0.002 (9)
C22	0.061 (12)	0.052 (12)	0.040 (10)	−0.002 (10)	0.025 (9)	0.010 (9)
F13	0.097 (13)	0.085 (12)	0.085 (11)	0.033 (10)	0.064 (11)	0.013 (10)
F14	0.105 (15)	0.141 (17)	0.077 (12)	0.011 (12)	0.068 (12)	0.022 (12)
F15	0.104 (14)	0.093 (13)	0.098 (13)	−0.025 (12)	0.069 (12)	−0.004 (11)

Geometric parameters (Å, º)

Ag1—O8^i	2.156 (16)	S1—O11	1.521 (19)
Ag1—C1	2.16 (2)	S1—C23	1.74 (3)
Ag1—O11	2.580 (17)	S1—C24	1.78 (3)
Ag1—Ag2	2.879 (3)	C23—H23A	0.9800
Ag1—Ag3	2.949 (2)	C23—H23B	0.9800
Ag1—Ag4	2.993 (3)	C23—H23C	0.9800
Ag1—Ag5^i	3.053 (2)	C24—H24A	0.9800
Ag1—Ag6^i	3.184 (2)	C24—H24B	0.9800
Ag2—O3	2.27 (2)	C24—H24C	0.9800
Ag2—C1	2.28 (2)	S2—O12	1.55 (2)
Ag2—O1	2.40 (2)	S2—C26	1.70 (4)
Ag2—Ag3	2.924 (2)	S2—C25	1.79 (3)
Ag2—Ag6^i	3.097 (2)	C25—H25A	0.9800
Ag3—C1	2.20 (2)	C25—H25B	0.9800
Ag3—O5	2.279 (17)	C25—H25C	0.9800
Ag3—C5^i	2.29 (2)	C26—H26A	0.9800
Ag3—O2	2.380 (19)	C26—H26B	0.9800
Ag3—Ag6^i	2.801 (2)	C26—H26C	0.9800
Ag3—Ag5^i	2.873 (2)	S3—O13	1.504 (17)
Ag3—Ag4	3.161 (3)	S3—C27	1.72 (2)
Ag4—O12	2.287 (19)	S3—C28	1.80 (4)
Ag4—C1	2.34 (2)	C27—H27A	0.9800
Ag4—O6	2.35 (2)	C27—H27B	0.9800
Ag4—O14^i	2.409 (16)	C27—H27C	0.9800
Ag4—C2	2.64 (2)	C28—H28A	0.9800
Ag5—C5	2.21 (3)	C28—H28B	0.9800
Ag5—O7	2.240 (17)	C28—H28C	0.9800
Ag5—O13	2.356 (15)	S4—O14	1.506 (18)
Ag5—O14	2.535 (15)	S4—C30	1.72 (3)
Ag5—Ag6	2.866 (2)	S4—C29	1.78 (3)
Ag5—Ag3^ii	2.873 (2)	O14—Ag4^ii	2.409 (16)
Ag5—Ag7	3.032 (3)	C29—H29A	0.9800
Ag5—Ag1^ii	3.053 (2)	C29—H29B	0.9800
Ag6—C5	2.22 (2)	C29—H29C	0.9800
Ag6—O9	2.274 (18)	C30—H30A	0.9800
Ag6—O4^ii	2.286 (18)	C30—H30B	0.9800
Ag6—Ag3^ii	2.801 (2)	C30—H30C	0.9800
Ag6—Ag7	2.914 (2)	S5—O15	1.51 (2)
Ag6—Ag2^ii	3.098 (2)	S5—C31	1.83 (4)
Ag6—Ag1^ii	3.184 (2)	S5—C32	1.84 (4)
Ag7—O10	2.300 (17)	C31—H31A	0.9800
Ag7—O15	2.389 (18)	C31—H31B	0.9800
Ag7—C5	2.40 (2)	C31—H31C	0.9800
Ag7—O11	2.449 (18)	C32—H32A	0.9800
Ag7—C4	2.51 (2)	C32—H32B	0.9800
C1—C2	1.21 (3)	C32—H32C	0.9800
C2—C3	1.46 (3)	S5'—C31'	1.83 (4)
C3—C6	1.34 (4)	S5'—C32'	1.84 (4)
C3—C4	1.45 (3)	C31'—H31D	0.9800
C4—C5	1.22 (3)	C31'—H31E	0.9800
C5—Ag3^ii	2.29 (2)	C31'—H31F	0.9800
C6—C12	1.57 (4)	C32'—H32D	0.9800
C6—C7	1.59 (5)	C32'—H32E	0.9800
C7—C8	1.47 (5)	C32'—H32F	0.9800
C7—H7A	0.9900	O1—C13	1.23 (3)
C7—H7B	0.9900	O2—C13	1.24 (3)
C8—C9	1.50 (6)	C13—C14	1.51 (3)
C8—H8A	0.9900	C14—F1	1.287 (13)
C8—H8B	0.9900	C14—F2	1.289 (13)
C9—C10	1.46 (5)	C14—F3	1.291 (13)
C9—H9A	0.9900	O3—C15	1.20 (3)
C9—H9B	0.9900	O4—C15	1.24 (3)
C10—C11	1.47 (6)	O4—Ag6^i	2.286 (18)
C10—H10A	0.9900	C15—C16	1.55 (3)
C10—H10B	0.9900	C16—F5	1.283 (13)
C11—C12	1.47 (5)	C16—F6	1.286 (13)
C11—H11A	0.9900	C16—F4	1.288 (13)
C11—H11B	0.9900	O5—C17	1.19 (3)
C12—H12A	0.9900	O6—C17	1.31 (3)
C12—H12B	0.9900	C17—C18	1.54 (3)
C7'—C8'	1.47 (5)	C18—F7	1.276 (12)
C7'—H7'1	0.9900	C18—F8	1.283 (13)
C7'—H7'2	0.9900	C18—F9	1.293 (12)
C8'—C9'	1.50 (6)	O7—C19	1.26 (3)
C8'—H8'1	0.9900	O8—C19	1.20 (3)
C8'—H8'2	0.9900	O8—Ag1^ii	2.156 (16)
C9'—C10'	1.46 (5)	C19—C20	1.58 (3)
C9'—H9'1	0.9900	C20—F12	1.281 (13)
C9'—H9'2	0.9900	C20—F11	1.285 (13)
C10'—C11'	1.47 (6)	C20—F10	1.289 (13)
C10'—H10C	0.9900	O9—C21	1.25 (4)
C10'—H10D	0.9900	O10—C21	1.30 (4)
C11'—C12'	1.47 (5)	C21—C22	1.52 (3)
C11'—H11C	0.9900	C22—F13	1.283 (13)
C11'—H11D	0.9900	C22—F14	1.286 (13)
C12'—H12C	0.9900	C22—F15	1.293 (13)
C12'—H12D	0.9900
O8^i—Ag1—C1	173.3 (8)	H7A—C7—H7B	107.8
O8^i—Ag1—O11	86.9 (6)	C7—C8—C9	116 (4)
C1—Ag1—O11	86.9 (7)	C7—C8—H8A	108.4
O8^i—Ag1—Ag2	134.4 (5)	C9—C8—H8A	108.4
C1—Ag1—Ag2	51.3 (6)	C7—C8—H8B	108.4
O11—Ag1—Ag2	114.9 (4)	C9—C8—H8B	108.4
O8^i—Ag1—Ag3	136.0 (5)	H8A—C8—H8B	107.4
C1—Ag1—Ag3	47.9 (6)	C10—C9—C8	118 (4)
O11—Ag1—Ag3	128.2 (5)	C10—C9—H9A	107.8
Ag2—Ag1—Ag3	60.20 (6)	C8—C9—H9A	107.8
O8^i—Ag1—Ag4	123.7 (5)	C10—C9—H9B	107.8
C1—Ag1—Ag4	51.0 (6)	C8—C9—H9B	107.8
O11—Ag1—Ag4	67.5 (5)	H9A—C9—H9B	107.1
Ag2—Ag1—Ag4	101.89 (7)	C9—C10—C11	125 (4)
Ag3—Ag1—Ag4	64.28 (6)	C9—C10—H10A	106.2
O8^i—Ag1—Ag5^i	80.3 (5)	C11—C10—H10A	106.2
C1—Ag1—Ag5^i	101.7 (6)	C9—C10—H10B	106.2
O11—Ag1—Ag5^i	130.7 (4)	C11—C10—H10B	106.2
Ag2—Ag1—Ag5^i	107.64 (7)	H10A—C10—H10B	106.3
Ag3—Ag1—Ag5^i	57.18 (5)	C12—C11—C10	112 (4)
Ag4—Ag1—Ag5^i	80.76 (7)	C12—C11—H11A	109.2
O8^i—Ag1—Ag6^i	93.5 (5)	C10—C11—H11A	109.2
C1—Ag1—Ag6^i	92.9 (5)	C12—C11—H11B	109.2
O11—Ag1—Ag6^i	174.5 (4)	C10—C11—H11B	109.2
Ag2—Ag1—Ag6^i	61.20 (6)	H11A—C11—H11B	107.9
Ag3—Ag1—Ag6^i	54.20 (5)	C11—C12—C6	108 (3)
Ag4—Ag1—Ag6^i	116.44 (7)	C11—C12—H12A	110.1
Ag5^i—Ag1—Ag6^i	54.66 (5)	C6—C12—H12A	110.1
O3—Ag2—C1	166.7 (8)	C11—C12—H12B	110.1
O3—Ag2—O1	88.8 (9)	C6—C12—H12B	110.1
C1—Ag2—O1	99.7 (8)	H12A—C12—H12B	108.5
O3—Ag2—Ag1	120.7 (6)	C8'—C7'—H7'1	109.3
C1—Ag2—Ag1	47.9 (6)	C8'—C7'—H7'2	109.3
O1—Ag2—Ag1	144.4 (6)	H7'1—C7'—H7'2	108.0
O3—Ag2—Ag3	123.1 (5)	C7'—C8'—C9'	115 (4)
C1—Ag2—Ag3	48.0 (5)	C7'—C8'—H8'1	108.6
O1—Ag2—Ag3	86.8 (5)	C9'—C8'—H8'1	108.6
Ag1—Ag2—Ag3	61.07 (6)	C7'—C8'—H8'2	108.6
O3—Ag2—Ag6^i	74.3 (5)	C9'—C8'—H8'2	108.6
C1—Ag2—Ag6^i	93.0 (6)	H8'1—C8'—H8'2	107.5
O1—Ag2—Ag6^i	111.5 (5)	C10'—C9'—C8'	118 (4)
Ag1—Ag2—Ag6^i	64.26 (6)	C10'—C9'—H9'1	107.7
Ag3—Ag2—Ag6^i	55.36 (5)	C8'—C9'—H9'1	107.7
C1—Ag3—O5	105.0 (7)	C10'—C9'—H9'2	107.7
C1—Ag3—C5^i	149.1 (8)	C8'—C9'—H9'2	107.7
O5—Ag3—C5^i	100.0 (8)	H9'1—C9'—H9'2	107.1
C1—Ag3—O2	103.1 (8)	C9'—C10'—C11'	124 (4)
O5—Ag3—O2	89.0 (8)	C9'—C10'—H10C	106.2
C5^i—Ag3—O2	95.2 (8)	C11'—C10'—H10C	106.2
C1—Ag3—Ag6^i	103.4 (6)	C9'—C10'—H10D	106.2
O5—Ag3—Ag6^i	150.5 (5)	C11'—C10'—H10D	106.2
C5^i—Ag3—Ag6^i	50.5 (6)	H10C—C10'—H10D	106.4
O2—Ag3—Ag6^i	92.5 (6)	C12'—C11'—C10'	113 (4)
C1—Ag3—Ag5^i	106.6 (6)	C12'—C11'—H11C	109.1
O5—Ag3—Ag5^i	102.9 (7)	C10'—C11'—H11C	109.1
C5^i—Ag3—Ag5^i	49.2 (7)	C12'—C11'—H11D	109.1
O2—Ag3—Ag5^i	143.6 (5)	C10'—C11'—H11D	109.1
Ag6^i—Ag3—Ag5^i	60.65 (6)	H11C—C11'—H11D	107.8
C1—Ag3—Ag2	50.4 (6)	C11'—C12'—H12C	109.7
O5—Ag3—Ag2	142.1 (6)	C11'—C12'—H12D	109.7
C5^i—Ag3—Ag2	114.4 (6)	H12C—C12'—H12D	108.2
O2—Ag3—Ag2	73.1 (5)	O11—S1—C23	104.5 (13)
Ag6^i—Ag3—Ag2	65.47 (6)	O11—S1—C24	102.7 (13)
Ag5^i—Ag3—Ag2	111.41 (7)	C23—S1—C24	97.2 (15)
C1—Ag3—Ag1	47.0 (6)	S1—O11—Ag7	120.0 (11)
O5—Ag3—Ag1	130.2 (5)	S1—O11—Ag1	116.6 (10)
C5^i—Ag3—Ag1	102.5 (6)	Ag7—O11—Ag1	91.8 (6)
O2—Ag3—Ag1	131.8 (5)	S1—C23—H23A	109.5
Ag6^i—Ag3—Ag1	67.19 (6)	S1—C23—H23B	109.5
Ag5^i—Ag3—Ag1	63.24 (5)	H23A—C23—H23B	109.5
Ag2—Ag3—Ag1	58.72 (6)	S1—C23—H23C	109.5
C1—Ag3—Ag4	47.8 (6)	H23A—C23—H23C	109.5
O5—Ag3—Ag4	72.4 (5)	H23B—C23—H23C	109.5
C5^i—Ag3—Ag4	127.2 (7)	S1—C24—H24A	109.5
O2—Ag3—Ag4	135.5 (5)	S1—C24—H24B	109.5
Ag6^i—Ag3—Ag4	123.38 (8)	H24A—C24—H24B	109.5
Ag5^i—Ag3—Ag4	80.80 (6)	S1—C24—H24C	109.5
Ag2—Ag3—Ag4	97.03 (7)	H24A—C24—H24C	109.5
Ag1—Ag3—Ag4	58.55 (6)	H24B—C24—H24C	109.5
O12—Ag4—C1	135.4 (8)	O12—S2—C26	103.7 (18)
O12—Ag4—O6	87.3 (8)	O12—S2—C25	104.9 (14)
C1—Ag4—O6	114.8 (7)	C26—S2—C25	101.6 (18)
O12—Ag4—O14^i	104.5 (7)	S2—O12—Ag4	116.3 (12)
C1—Ag4—O14^i	114.1 (7)	S2—C25—H25A	109.5
O6—Ag4—O14^i	88.0 (7)	S2—C25—H25B	109.5
O12—Ag4—C2	109.5 (8)	H25A—C25—H25B	109.5
C1—Ag4—C2	27.2 (7)	S2—C25—H25C	109.5
O6—Ag4—C2	112.7 (7)	H25A—C25—H25C	109.5
O14^i—Ag4—C2	140.6 (6)	H25B—C25—H25C	109.5
O12—Ag4—Ag1	133.4 (7)	S2—C26—H26A	109.5
C1—Ag4—Ag1	45.9 (5)	S2—C26—H26B	109.5
O6—Ag4—Ag1	138.4 (6)	H26A—C26—H26B	109.5
O14^i—Ag4—Ag1	75.4 (4)	S2—C26—H26C	109.5
C2—Ag4—Ag1	66.9 (5)	H26A—C26—H26C	109.5
O12—Ag4—Ag3	167.7 (7)	H26B—C26—H26C	109.5
C1—Ag4—Ag3	44.0 (5)	O13—S3—C27	106.5 (14)
O6—Ag4—Ag3	83.6 (5)	O13—S3—C28	104.4 (14)
O14^i—Ag4—Ag3	83.5 (4)	C27—S3—C28	98.9 (17)
C2—Ag4—Ag3	66.9 (5)	S3—O13—Ag5	129.2 (9)
Ag1—Ag4—Ag3	57.17 (5)	S3—C27—H27A	109.5
C5—Ag5—O7	143.7 (8)	S3—C27—H27B	109.5
C5—Ag5—O13	101.4 (7)	H27A—C27—H27B	109.5
O7—Ag5—O13	91.6 (6)	S3—C27—H27C	109.5
C5—Ag5—O14	130.4 (7)	H27A—C27—H27C	109.5
O7—Ag5—O14	84.5 (6)	H27B—C27—H27C	109.5
O13—Ag5—O14	82.8 (6)	S3—C28—H28A	109.5
C5—Ag5—Ag6	49.9 (6)	S3—C28—H28B	109.5
O7—Ag5—Ag6	100.3 (5)	H28A—C28—H28B	109.5
O13—Ag5—Ag6	141.0 (4)	S3—C28—H28C	109.5
O14—Ag5—Ag6	135.0 (4)	H28A—C28—H28C	109.5
C5—Ag5—Ag3^ii	51.4 (6)	H28B—C28—H28C	109.5
O7—Ag5—Ag3^ii	137.0 (4)	O14—S4—C30	103.6 (13)
O13—Ag5—Ag3^ii	129.3 (4)	O14—S4—C29	105.3 (12)
O14—Ag5—Ag3^ii	87.6 (4)	C30—S4—C29	97.5 (15)
Ag6—Ag5—Ag3^ii	58.43 (6)	S4—O14—Ag4^ii	122.1 (8)
C5—Ag5—Ag7	51.7 (6)	S4—O14—Ag5	115.2 (8)
O7—Ag5—Ag7	97.6 (5)	Ag4^ii—O14—Ag5	104.8 (6)
O13—Ag5—Ag7	82.6 (4)	S4—C29—H29A	109.5
O14—Ag5—Ag7	165.3 (4)	S4—C29—H29B	109.5
Ag6—Ag5—Ag7	59.13 (6)	H29A—C29—H29B	109.5
Ag3^ii—Ag5—Ag7	100.38 (7)	S4—C29—H29C	109.5
C5—Ag5—Ag1^ii	101.2 (6)	H29A—C29—H29C	109.5
O7—Ag5—Ag1^ii	77.7 (4)	H29B—C29—H29C	109.5
O13—Ag5—Ag1^ii	153.9 (4)	S4—C30—H30A	109.5
O14—Ag5—Ag1^ii	72.6 (4)	S4—C30—H30B	109.5
Ag6—Ag5—Ag1^ii	64.99 (6)	H30A—C30—H30B	109.5
Ag3^ii—Ag5—Ag1^ii	59.58 (5)	S4—C30—H30C	109.5
Ag7—Ag5—Ag1^ii	122.01 (8)	H30A—C30—H30C	109.5
C5—Ag6—O9	139.3 (9)	H30B—C30—H30C	109.5
C5—Ag6—O4^ii	114.2 (9)	O15—S5—C31	105.4 (17)
O9—Ag6—O4^ii	92.5 (9)	O15—S5—C32	98.8 (17)
C5—Ag6—Ag3^ii	52.6 (5)	C31—S5—C32	103 (2)
O9—Ag6—Ag3^ii	147.1 (6)	S5—O15—Ag7	138.6 (10)
O4^ii—Ag6—Ag3^ii	109.3 (6)	S5—C31—H31A	109.5
C5—Ag6—Ag5	49.6 (7)	S5—C31—H31B	109.5
O9—Ag6—Ag5	102.3 (6)	H31A—C31—H31B	109.5
O4^ii—Ag6—Ag5	163.7 (6)	S5—C31—H31C	109.5
Ag3^ii—Ag6—Ag5	60.92 (6)	H31A—C31—H31C	109.5
C5—Ag6—Ag7	53.8 (6)	H31B—C31—H31C	109.5
O9—Ag6—Ag7	89.0 (6)	S5—C32—H32A	109.5
O4^ii—Ag6—Ag7	110.6 (4)	S5—C32—H32B	109.5
Ag3^ii—Ag6—Ag7	105.11 (7)	H32A—C32—H32B	109.5
Ag5—Ag6—Ag7	63.29 (6)	S5—C32—H32C	109.5
C5—Ag6—Ag2^ii	110.3 (6)	H32A—C32—H32C	109.5
O9—Ag6—Ag2^ii	105.8 (6)	H32B—C32—H32C	109.5
O4^ii—Ag6—Ag2^ii	75.3 (4)	C31'—S5'—C32'	101 (2)
Ag3^ii—Ag6—Ag2^ii	59.17 (6)	S5'—C31'—H31D	109.5
Ag5—Ag6—Ag2^ii	106.80 (7)	S5'—C31'—H31E	109.5
Ag7—Ag6—Ag2^ii	164.07 (8)	H31D—C31'—H31E	109.5
C5—Ag6—Ag1^ii	97.2 (6)	S5'—C31'—H31F	109.5
O9—Ag6—Ag1^ii	88.6 (6)	H31D—C31'—H31F	109.5
O4^ii—Ag6—Ag1^ii	127.8 (4)	H31E—C31'—H31F	109.5
Ag3^ii—Ag6—Ag1^ii	58.61 (6)	S5'—C32'—H32D	109.5
Ag5—Ag6—Ag1^ii	60.35 (6)	S5'—C32'—H32E	109.5
Ag7—Ag6—Ag1^ii	121.54 (8)	H32D—C32'—H32E	109.5
Ag2^ii—Ag6—Ag1^ii	54.54 (5)	S5'—C32'—H32F	109.5
O10—Ag7—O15	88.5 (7)	H32D—C32'—H32F	109.5
O10—Ag7—C5	120.4 (7)	H32E—C32'—H32F	109.5
O15—Ag7—C5	137.8 (8)	C13—O1—Ag2	112.5 (17)
O10—Ag7—O11	87.1 (7)	C13—O2—Ag3	131.2 (15)
O15—Ag7—O11	86.8 (7)	O1—C13—O2	128 (2)
C5—Ag7—O11	121.8 (8)	O1—C13—C14	115 (2)
O10—Ag7—C4	147.6 (7)	O2—C13—C14	116.6 (19)
O15—Ag7—C4	121.7 (7)	F1—C14—F2	107.3 (13)
C5—Ag7—C4	28.6 (7)	F1—C14—F3	107.5 (12)
O11—Ag7—C4	104.5 (8)	F2—C14—F3	106.2 (13)
O10—Ag7—Ag6	75.1 (5)	F1—C14—C13	108 (2)
O15—Ag7—Ag6	157.8 (4)	F2—C14—C13	115.2 (18)
C5—Ag7—Ag6	48.2 (5)	F3—C14—C13	112.2 (18)
O11—Ag7—Ag6	106.9 (4)	C15—O3—Ag2	119.8 (19)
C4—Ag7—Ag6	72.6 (5)	C15—O4—Ag6^i	121.0 (16)
O10—Ag7—Ag5	91.8 (5)	O3—C15—O4	127 (3)
O15—Ag7—Ag5	109.1 (5)	O3—C15—C16	117 (2)
C5—Ag7—Ag5	46.3 (6)	O4—C15—C16	116 (2)
O11—Ag7—Ag5	164.0 (4)	F5—C16—F6	108.1 (13)
C4—Ag7—Ag5	68.8 (6)	F5—C16—F4	108.4 (12)
Ag6—Ag7—Ag5	57.59 (6)	F6—C16—F4	107.6 (12)
C2—C1—Ag1	133.3 (17)	F5—C16—C15	110.3 (17)
C2—C1—Ag3	141.0 (17)	F6—C16—C15	109.6 (18)
Ag1—C1—Ag3	85.1 (8)	F4—C16—C15	112.7 (17)
C2—C1—Ag2	107.4 (19)	C17—O5—Ag3	137.2 (17)
Ag1—C1—Ag2	80.8 (7)	C17—O6—Ag4	114.0 (16)
Ag3—C1—Ag2	81.6 (7)	O5—C17—O6	127 (2)
C2—C1—Ag4	90.2 (17)	O5—C17—C18	117 (2)
Ag1—C1—Ag4	83.1 (8)	O6—C17—C18	116 (2)
Ag3—C1—Ag4	88.2 (8)	F7—C18—F8	109.2 (12)
Ag2—C1—Ag4	161.6 (11)	F7—C18—F9	108.7 (12)
C1—C2—C3	173 (3)	F8—C18—F9	107.6 (12)
C1—C2—Ag4	62.6 (15)	F7—C18—C17	113.9 (18)
C3—C2—Ag4	122.6 (18)	F8—C18—C17	108.4 (16)
C6—C3—C4	124 (2)	F9—C18—C17	108.7 (17)
C6—C3—C2	123 (2)	C19—O7—Ag5	124.2 (15)
C4—C3—C2	112.4 (19)	C19—O8—Ag1^ii	126.5 (16)
C5—C4—C3	175 (2)	O8—C19—O7	130 (2)
C5—C4—Ag7	70.9 (14)	O8—C19—C20	115 (2)
C3—C4—Ag7	114.1 (15)	O7—C19—C20	115 (2)
C4—C5—Ag5	132 (2)	F12—C20—F11	108.1 (12)
C4—C5—Ag6	137 (2)	F12—C20—F10	108.4 (12)
Ag5—C5—Ag6	80.5 (8)	F11—C20—F10	107.4 (12)
C4—C5—Ag3^ii	128.6 (18)	F12—C20—C19	108.0 (16)
Ag5—C5—Ag3^ii	79.4 (7)	F11—C20—C19	111.6 (18)
Ag6—C5—Ag3^ii	76.8 (7)	F10—C20—C19	113.2 (16)
C4—C5—Ag7	80.4 (14)	C21—O9—Ag6	115.8 (19)
Ag5—C5—Ag7	82.0 (8)	C21—O10—Ag7	131.4 (18)
Ag6—C5—Ag7	78.0 (7)	O9—C21—O10	127 (3)
Ag3^ii—C5—Ag7	150.7 (10)	O9—C21—C22	118 (2)
C3—C6—C12	122 (3)	O10—C21—C22	113 (2)
C3—C6—C7	121 (3)	F13—C22—F14	108.9 (13)
C12—C6—C7	117 (3)	F13—C22—F15	107.9 (13)
C8—C7—C6	113 (3)	F14—C22—F15	107.1 (12)
C8—C7—H7A	109.1	F13—C22—C21	111.6 (18)
C6—C7—H7A	109.1	F14—C22—C21	109.6 (18)
C8—C7—H7B	109.1	F15—C22—C21	111.6 (18)
C6—C7—H7B	109.1
Ag1—C1—C2—Ag4	81 (2)	O2—C13—C14—F1	−56 (3)
Ag3—C1—C2—Ag4	−87 (3)	O1—C13—C14—F2	4 (3)
Ag2—C1—C2—Ag4	174.4 (14)	O2—C13—C14—F2	−176 (2)
Ag4—C2—C3—C6	65 (3)	O1—C13—C14—F3	−118 (3)
Ag4—C2—C3—C4	−108 (2)	O2—C13—C14—F3	63 (3)
C6—C3—C4—Ag7	−168 (3)	Ag2—O3—C15—O4	36 (4)
C2—C3—C4—Ag7	5 (3)	Ag2—O3—C15—C16	−139.0 (18)
Ag7—C4—C5—Ag5	−70.1 (19)	Ag6^i—O4—C15—O3	10 (4)
Ag7—C4—C5—Ag6	60 (2)	Ag6^i—O4—C15—C16	−174.9 (15)
Ag7—C4—C5—Ag3^ii	176 (2)	O3—C15—C16—F5	−142 (2)
C4—C3—C6—C12	171 (3)	O4—C15—C16—F5	43 (3)
C2—C3—C6—C12	−1 (5)	O3—C15—C16—F6	99 (3)
C4—C3—C6—C7	0 (5)	O4—C15—C16—F6	−76 (3)
C2—C3—C6—C7	−172 (3)	O3—C15—C16—F4	−21 (3)
C3—C6—C7—C8	−163 (4)	O4—C15—C16—F4	164 (2)
C12—C6—C7—C8	26 (5)	Ag3—O5—C17—O6	28 (5)
C6—C7—C8—C9	51 (5)	Ag3—O5—C17—C18	−160.2 (19)
C7—C8—C9—C10	−81 (5)	Ag4—O6—C17—O5	−31 (4)
C8—C9—C10—C11	53 (6)	Ag4—O6—C17—C18	157.2 (15)
C9—C10—C11—C12	−48 (6)	O5—C17—C18—F7	160 (2)
C10—C11—C12—C6	76 (4)	O6—C17—C18—F7	−27 (3)
C3—C6—C12—C11	99 (4)	O5—C17—C18—F8	−78 (3)
C7—C6—C12—C11	−90 (4)	O6—C17—C18—F8	95 (2)
C7'—C8'—C9'—C10'	−37 (8)	O5—C17—C18—F9	39 (3)
C8'—C9'—C10'—C11'	38 (10)	O6—C17—C18—F9	−148 (2)
C9'—C10'—C11'—C12'	−83 (7)	Ag1^ii—O8—C19—O7	3 (4)
C23—S1—O11—Ag7	−180.0 (13)	Ag1^ii—O8—C19—C20	−174.6 (13)
C24—S1—O11—Ag7	−79.0 (15)	Ag5—O7—C19—O8	8 (4)
C23—S1—O11—Ag1	70.7 (15)	Ag5—O7—C19—C20	−174.9 (13)
C24—S1—O11—Ag1	171.7 (14)	O8—C19—C20—F12	75 (2)
C26—S2—O12—Ag4	90.1 (17)	O7—C19—C20—F12	−103 (2)
C25—S2—O12—Ag4	−163.7 (16)	O8—C19—C20—F11	−44 (2)
C27—S3—O13—Ag5	−166.7 (15)	O7—C19—C20—F11	139 (2)
C28—S3—O13—Ag5	−62.6 (17)	O8—C19—C20—F10	−164.9 (19)
C30—S4—O14—Ag4^ii	−145.1 (13)	O7—C19—C20—F10	17 (3)
C29—S4—O14—Ag4^ii	−43.3 (15)	Ag6—O9—C21—O10	14 (4)
C30—S4—O14—Ag5	86.0 (14)	Ag6—O9—C21—C22	178.9 (16)
C29—S4—O14—Ag5	−172.2 (12)	Ag7—O10—C21—O9	−12 (5)
C31—S5—O15—Ag7	22 (3)	Ag7—O10—C21—C22	−177.7 (16)
C32—S5—O15—Ag7	−84 (2)	O9—C21—C22—F13	145 (2)
Ag2—O1—C13—O2	−14 (4)	O10—C21—C22—F13	−48 (3)
Ag2—O1—C13—C14	166.6 (16)	O9—C21—C22—F14	24 (3)
Ag3—O2—C13—O1	−14 (5)	O10—C21—C22—F14	−169 (2)
Ag3—O2—C13—C14	165.3 (17)	O9—C21—C22—F15	−94 (3)
O1—C13—C14—F1	124 (3)	O10—C21—C22—F15	73 (3)

Symmetry codes: (i) x−1/2, −y+1/2, z−1/2; (ii) x+1/2, −y+1/2, z+1/2.

(IV)

Crystal data

7(Ag^+)·(C13H14^2^−)·5(C2F3O2^−)·4(C2H6SO)	V = 2542.2 (5) Å^3
Mr = 1802.94	Z = 2
Triclinic, P1	F(000) = 1728
a = 13.4350 (15) Å	Dx = 2.355 Mg m^−3
b = 13.8806 (15) Å	Mo Kα radiation, λ = 0.71073 Å
c = 16.3609 (18) Å	µ = 2.92 mm^−1
α = 110.194 (2)°	T = 173 K
β = 106.492 (2)°	Block, yellow
γ = 104.003 (2)°	0.50 × 0.40 × 0.40 mm

Data collection

Bruker APEX-II CCD diffractometer	15708 reflections with I > 2σ(I)
φ and ω scan	Rint = 0.075
Absorption correction: multi-scan SADABS (Bruker, 2003)	θmax = 25.3°, θmin = 1.5°
Tmin = 0.324, Tmax = 0.389	h = −15→16
31854 measured reflections	k = −16→16
16780 independent reflections	l = −19→19

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.087	H-atom parameters constrained
wR(F^2) = 0.235	w = 1/[σ^2(Fo^2) + (0.1443P)^2 + 44.008P] where P = (Fo^2 + 2Fc^2)/3
S = 1.05	(Δ/σ)max = 0.002
16780 reflections	Δρmax = 3.89 e Å^−3
1276 parameters	Δρmin = −1.66 e Å^−3
615 restraints	Absolute structure: Refined as an inversion twin.
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.71 (8)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ag1	−0.38356 (18)	−1.04880 (17)	−0.29993 (16)	0.0296 (5)
Ag2	−0.39957 (15)	−0.95877 (15)	−0.43389 (14)	0.0227 (4)
Ag3	−0.18377 (17)	−0.97454 (18)	−0.33388 (18)	0.0345 (5)
Ag4	−0.2679 (3)	−0.8511 (2)	−0.11866 (19)	0.0525 (8)
Ag5	0.01505 (17)	−0.74041 (16)	0.06564 (14)	0.0246 (4)
Ag6	0.09451 (18)	−0.73854 (17)	−0.09833 (15)	0.0295 (5)
Ag7	0.17573 (17)	−0.53556 (16)	0.09545 (14)	0.0251 (4)
Ag8	−0.05579 (19)	−0.55442 (18)	0.10487 (15)	0.0308 (5)
Ag9	0.09364 (17)	−0.34284 (16)	0.30561 (15)	0.0267 (4)
Ag10	0.16204 (17)	−0.53232 (16)	0.26833 (14)	0.0243 (4)
Ag11	0.39091 (17)	−0.42528 (19)	0.27721 (16)	0.0332 (5)
Ag12	0.38647 (17)	−0.06238 (17)	0.58175 (15)	0.0270 (5)
Ag13	0.4225 (2)	−0.26637 (17)	0.53787 (16)	0.0313 (5)
Ag14	0.61891 (17)	−0.18002 (17)	0.50427 (15)	0.0272 (5)
C1	−0.282 (2)	−0.882 (2)	−0.2728 (19)	0.023 (5)
C2	−0.213 (2)	−0.782 (2)	−0.2325 (16)	0.017 (5)
C3	−0.135 (2)	−0.6717 (19)	−0.1801 (17)	0.018 (5)
C4	−0.061 (2)	−0.652 (2)	−0.092 (2)	0.023 (5)
C5	0.001 (2)	−0.636 (2)	−0.003 (2)	0.026 (5)
C6	−0.134 (2)	−0.587 (2)	−0.212 (2)	0.027 (6)
C7	−0.053 (2)	−0.470 (2)	−0.143 (2)	0.030 (6)
H7A	−0.0947	−0.4300	−0.1140	0.035*
H7B	0.0041	−0.4740	−0.0918	0.035*
C8	0.007 (3)	−0.404 (3)	−0.180 (2)	0.042 (7)
H8A	0.0449	−0.3258	−0.1305	0.050*
H8B	−0.0485	−0.4058	−0.2361	0.050*
C9	0.095 (4)	−0.447 (4)	−0.209 (4)	0.071 (12)
H9A	0.1327	−0.3977	−0.2316	0.085*
H9B	0.1533	−0.4371	−0.1499	0.085*
C10	0.058 (4)	−0.566 (4)	−0.283 (3)	0.058 (10)
H10A	0.0407	−0.6170	−0.2547	0.070*
H10B	0.1194	−0.5747	−0.3027	0.070*
C11	−0.050 (4)	−0.595 (4)	−0.373 (3)	0.064 (11)
H11A	−0.0561	−0.5247	−0.3713	0.077*
H11B	−0.0390	−0.6331	−0.4308	0.077*
C12	−0.152 (4)	−0.662 (4)	−0.379 (3)	0.064 (11)
H12A	−0.1422	−0.7286	−0.3743	0.077*
H12B	−0.2095	−0.6876	−0.4434	0.077*
C13	−0.202 (3)	−0.614 (3)	−0.307 (3)	0.050 (9)
H13A	−0.2115	−0.5467	−0.3095	0.060*
H13B	−0.2766	−0.6691	−0.3258	0.060*
C14	0.224 (2)	−0.395 (2)	0.2382 (18)	0.021 (5)
C15	0.265 (2)	−0.292 (2)	0.270 (2)	0.025 (5)
C16	0.326 (2)	−0.1780 (18)	0.3168 (16)	0.014 (4)
C17	0.408 (3)	−0.143 (2)	0.411 (2)	0.032 (6)
C18	0.465 (2)	−0.146 (2)	0.4811 (19)	0.021 (5)
C19	0.316 (3)	−0.104 (3)	0.280 (2)	0.032 (6)
C20	0.373 (3)	0.015 (3)	0.331 (2)	0.039 (7)
H20A	0.4403	0.0311	0.3864	0.046*
H20B	0.3231	0.0450	0.3561	0.046*
C21	0.413 (3)	0.081 (3)	0.279 (3)	0.045 (8)
H21A	0.4552	0.1602	0.3257	0.053*
H21B	0.3465	0.0763	0.2297	0.053*
C22	0.490 (4)	0.035 (4)	0.232 (4)	0.072 (12)
H22A	0.5093	0.0810	0.1999	0.086*
H22B	0.5603	0.0549	0.2858	0.086*
C23	0.464 (5)	−0.080 (5)	0.164 (4)	0.076 (13)
H23A	0.4721	−0.1258	0.1985	0.091*
H23B	0.5174	−0.0804	0.1329	0.091*
C24	0.347 (4)	−0.130 (4)	0.090 (3)	0.065 (11)
H24A	0.3501	−0.1700	0.0278	0.078*
H24B	0.3255	−0.0673	0.0864	0.078*
C25	0.246 (4)	−0.212 (4)	0.096 (3)	0.067 (11)
H25A	0.1786	−0.2436	0.0362	0.080*
H25B	0.2665	−0.2738	0.1022	0.080*
C26	0.221 (3)	−0.155 (3)	0.177 (2)	0.042 (7)
H26A	0.1547	−0.2086	0.1734	0.050*
H26B	0.2004	−0.0946	0.1682	0.050*
S1	0.0743 (5)	−0.9081 (5)	−0.3241 (5)	0.0257 (13)
O21	0.0129 (14)	−0.8547 (16)	−0.2695 (13)	0.027 (4)
C47	0.163 (3)	−0.801 (3)	−0.338 (3)	0.040 (7)
H47A	0.1169	−0.7801	−0.3821	0.061*
H47B	0.2138	−0.8279	−0.3641	0.061*
H47C	0.2073	−0.7359	−0.2763	0.061*
C48	0.172 (3)	−0.935 (4)	−0.243 (3)	0.046 (8)
H48A	0.1316	−0.9935	−0.2309	0.069*
H48B	0.2164	−0.8673	−0.1834	0.069*
H48C	0.2226	−0.9592	−0.2715	0.069*
S2	−0.2231 (7)	−0.8851 (7)	0.0884 (6)	0.0360 (17)
O22	−0.1846 (19)	−0.875 (2)	0.0112 (14)	0.038 (5)
C49	−0.337 (3)	−0.841 (3)	0.076 (3)	0.042 (8)
H49A	−0.3099	−0.7610	0.0979	0.062*
H49B	−0.3763	−0.8609	0.1135	0.062*
H49C	−0.3895	−0.8784	0.0085	0.062*
C50	−0.298 (5)	−1.030 (4)	0.044 (4)	0.073 (13)
H50A	−0.2448	−1.0677	0.0466	0.110*
H50B	−0.3509	−1.0601	−0.0224	0.110*
H50C	−0.3388	−1.0422	0.0825	0.110*
S3	−0.3680 (7)	−0.6334 (7)	−0.0477 (6)	0.0367 (17)
O23	−0.2800 (17)	−0.6826 (19)	−0.0259 (15)	0.036 (5)
C51	−0.507 (3)	−0.758 (3)	−0.130 (2)	0.047 (8)
H51A	−0.5314	−0.7945	−0.0940	0.070*
H51B	−0.4963	−0.8103	−0.1820	0.070*
H51C	−0.5641	−0.7320	−0.1572	0.070*
C52	−0.341 (2)	−0.581 (3)	−0.126 (2)	0.032 (6)
H52A	−0.2707	−0.5159	−0.0910	0.048*
H52B	−0.4026	−0.5596	−0.1519	0.048*
H52C	−0.3350	−0.6380	−0.1774	0.048*
S4	0.0300 (7)	−1.0024 (6)	−0.0916 (5)	0.0335 (15)
O24	0.015 (2)	−0.8956 (18)	−0.0740 (15)	0.040 (5)
C53	0.117 (4)	−0.989 (4)	0.017 (3)	0.061 (11)
H53A	0.1929	−0.9371	0.0368	0.092*
H53B	0.1192	−1.0618	0.0094	0.092*
H53C	0.0879	−0.9617	0.0649	0.092*
C54	−0.094 (3)	−1.099 (3)	−0.107 (3)	0.052 (9)
H54A	−0.1544	−1.1168	−0.1669	0.078*
H54B	−0.1148	−1.0671	−0.0539	0.078*
H54C	−0.0825	−1.1665	−0.1091	0.078*
S5	0.1171 (5)	−0.0987 (5)	0.4906 (4)	0.0219 (12)
O25	0.1783 (16)	−0.1792 (15)	0.4562 (13)	0.025 (4)
C55	0.109 (3)	−0.032 (3)	0.417 (3)	0.044 (8)
H55A	0.1842	0.0188	0.4334	0.066*
H55B	0.0606	0.0098	0.4258	0.066*
H55C	0.0777	−0.0875	0.3503	0.066*
C56	−0.030 (2)	−0.181 (2)	0.441 (2)	0.026 (6)
H56A	−0.0435	−0.2269	0.4741	0.039*
H56B	−0.0554	−0.2289	0.3733	0.039*
H56C	−0.0721	−0.1320	0.4496	0.039*
S6	0.1621 (6)	−0.4651 (6)	0.4917 (5)	0.0286 (14)
O26	0.2445 (18)	−0.4207 (17)	0.4514 (14)	0.035 (5)
C57	0.172 (4)	−0.345 (4)	0.586 (3)	0.056 (10)
H57A	0.1363	−0.3030	0.5590	0.084*
H57B	0.2514	−0.2990	0.6267	0.084*
H57C	0.1346	−0.3677	0.6231	0.084*
C58	0.232 (3)	−0.521 (3)	0.561 (2)	0.040 (7)
H58A	0.2337	−0.5898	0.5196	0.060*
H58B	0.1919	−0.5353	0.6001	0.060*
H58C	0.3087	−0.4673	0.6032	0.060*
S7	0.5048 (7)	−0.4923 (7)	0.4683 (6)	0.0392 (18)
O27	0.4769 (18)	−0.4092 (16)	0.4351 (16)	0.035 (5)
C59	0.605 (4)	−0.530 (4)	0.424 (4)	0.067 (12)
H59A	0.6776	−0.4676	0.4594	0.100*
H59B	0.5789	−0.5476	0.3563	0.100*
H59C	0.6127	−0.5946	0.4323	0.100*
C60	0.392 (3)	−0.617 (3)	0.391 (3)	0.056 (10)
H60A	0.3262	−0.6149	0.4046	0.084*
H60B	0.4112	−0.6780	0.4001	0.084*
H60C	0.3764	−0.6297	0.3253	0.084*
S8	0.6568 (8)	−0.2760 (7)	0.2900 (7)	0.045 (2)
O28	0.569 (2)	−0.282 (2)	0.3294 (19)	0.053 (7)
C61	0.702 (4)	−0.394 (4)	0.283 (4)	0.067 (12)
H61A	0.7491	−0.3807	0.3466	0.101*
H61B	0.7452	−0.4019	0.2429	0.101*
H61C	0.6360	−0.4628	0.2542	0.101*
C62	0.572 (4)	−0.327 (4)	0.161 (3)	0.067 (12)
H62A	0.5412	−0.2722	0.1522	0.100*
H62B	0.5100	−0.3974	0.1379	0.100*
H62C	0.6191	−0.3380	0.1259	0.100*
O1	−0.3524 (17)	−1.1860 (17)	−0.2667 (15)	0.032 (4)*
O2	−0.5322 (18)	−1.313 (2)	−0.3373 (16)	0.041 (6)
C27	−0.437 (2)	−1.268 (2)	−0.2820 (19)	0.024 (5)
C28	−0.4005 (18)	−1.3323 (17)	−0.2239 (17)	0.042 (8)
F1	−0.4853 (19)	−1.4177 (19)	−0.243 (2)	0.090 (10)
F2	−0.325 (2)	−1.368 (3)	−0.243 (3)	0.110 (12)
F3	−0.359 (3)	−1.267 (2)	−0.1334 (17)	0.141 (16)
O3	−0.482 (2)	−1.022 (3)	−0.1882 (19)	0.070 (11)
O4	−0.6593 (19)	−1.077 (2)	−0.2961 (17)	0.045 (6)
C29	−0.585 (3)	−1.063 (2)	−0.222 (2)	0.031 (6)
C30	−0.6359 (18)	−1.0936 (18)	−0.1531 (16)	0.042 (8)
F4	−0.594 (3)	−1.159 (3)	−0.128 (3)	0.127 (14)
F5	−0.7440 (17)	−1.142 (2)	−0.1946 (18)	0.089 (9)
F6	−0.608 (2)	−1.003 (2)	−0.0784 (18)	0.112 (13)
O5	−0.4731 (17)	−0.8220 (16)	−0.4242 (15)	0.030 (4)
O6	−0.6226 (18)	−0.8911 (16)	−0.3978 (16)	0.033 (5)
C31	−0.560 (2)	−0.820 (2)	−0.4064 (19)	0.022 (5)
C32	−0.5856 (13)	−0.7147 (15)	−0.3985 (11)	0.029 (6)
F7	−0.5087 (14)	−0.6424 (15)	−0.4044 (14)	0.050 (5)
F8	−0.6817 (14)	−0.7421 (15)	−0.4661 (13)	0.058 (6)
F9	−0.5909 (17)	−0.6673 (15)	−0.3166 (11)	0.053 (5)
O7	−0.3209 (17)	−0.9409 (19)	−0.5395 (16)	0.035 (5)
O8	−0.203 (3)	−1.023 (3)	−0.4960 (18)	0.066 (9)
C33	−0.243 (3)	−0.973 (3)	−0.541 (2)	0.037 (7)
C34	−0.167 (2)	−0.934 (2)	−0.588 (2)	0.081 (14)
F10	−0.206 (3)	−0.881 (3)	−0.632 (3)	0.113 (12)
F11	−0.068 (3)	−0.867 (3)	−0.522 (2)	0.137 (15)
F12	−0.155 (3)	−1.016 (2)	−0.648 (2)	0.115 (12)
O9	−0.1194 (18)	−1.109 (2)	−0.326 (2)	0.048 (6)
O10	−0.2549 (18)	−1.2516 (16)	−0.4568 (15)	0.037 (5)
C35	−0.165 (2)	−1.206 (2)	−0.385 (2)	0.029 (6)
C36	−0.1062 (18)	−1.2819 (18)	−0.3635 (15)	0.040 (7)
F13	−0.008 (2)	−1.231 (2)	−0.2935 (18)	0.109 (12)
F14	−0.097 (2)	−1.344 (2)	−0.4391 (15)	0.090 (10)
F15	−0.171 (3)	−1.347 (3)	−0.342 (3)	0.150 (18)
O11	−0.1077 (19)	−0.6042 (17)	0.2100 (14)	0.034 (5)
O12	−0.0333 (19)	−0.4442 (18)	0.3394 (15)	0.036 (5)
C37	−0.095 (2)	−0.545 (3)	0.289 (2)	0.031 (6)
C38	−0.1617 (16)	−0.6031 (17)	0.3361 (14)	0.046 (8)
F16	−0.2671 (14)	−0.625 (2)	0.2905 (16)	0.076 (8)
F17	−0.148 (2)	−0.6953 (16)	0.3254 (18)	0.076 (8)
F18	−0.133 (2)	−0.5418 (18)	0.4256 (12)	0.077 (8)
O13	−0.104 (2)	−0.4182 (18)	0.0773 (17)	0.049 (7)
O14	−0.025 (2)	−0.275 (2)	0.2222 (16)	0.046 (6)
C39	−0.080 (3)	−0.322 (2)	0.137 (2)	0.032 (6)
C40	−0.1383 (19)	−0.2506 (19)	0.0960 (16)	0.043 (8)
F19	−0.238 (2)	−0.313 (2)	0.0287 (17)	0.098 (10)
F20	−0.150 (3)	−0.173 (2)	0.1616 (17)	0.112 (12)
F21	−0.077 (2)	−0.204 (3)	0.062 (3)	0.129 (14)
O15	0.0417 (19)	−0.8175 (15)	0.1631 (15)	0.034 (5)
O16	0.124 (2)	−0.6664 (17)	0.3067 (16)	0.042 (6)
C41	0.077 (2)	−0.769 (2)	0.250 (2)	0.027 (6)
C42	0.0758 (16)	−0.8481 (16)	0.2994 (13)	0.036 (7)
F22	0.094 (2)	−0.7988 (16)	0.3891 (12)	0.066 (7)
F23	0.154 (2)	−0.887 (2)	0.295 (2)	0.096 (10)
F24	−0.0196 (18)	−0.9311 (17)	0.2564 (16)	0.087 (9)
O17	0.256 (2)	−0.634 (2)	−0.0957 (19)	0.054 (7)
O18	0.2842 (17)	−0.4720 (16)	0.0230 (16)	0.035 (5)
C43	0.298 (2)	−0.536 (3)	−0.048 (2)	0.028 (6)
C44	0.3802 (17)	−0.4695 (16)	−0.0800 (13)	0.042 (8)
F25	0.4730 (15)	−0.4860 (17)	−0.0541 (16)	0.067 (7)
F26	0.3384 (18)	−0.5054 (19)	−0.1719 (11)	0.065 (6)
F27	0.4050 (18)	−0.3626 (14)	−0.0412 (14)	0.057 (6)
O19	0.260 (2)	−0.6802 (19)	0.098 (2)	0.058 (8)
O20	0.4398 (17)	−0.5637 (18)	0.1967 (18)	0.045 (6)
C45	0.3612 (19)	−0.651 (2)	0.1285 (16)	0.015 (5)
C46	0.4076 (16)	−0.7424 (17)	0.0827 (13)	0.038 (7)
F28	0.3365 (19)	−0.811 (2)	−0.0039 (13)	0.083 (8)
F29	0.5039 (17)	−0.6974 (19)	0.0825 (18)	0.076 (8)
F30	0.419 (2)	−0.799 (2)	0.1321 (18)	0.088 (9)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0300 (11)	0.0247 (10)	0.0363 (12)	0.0064 (8)	0.0131 (9)	0.0187 (9)
Ag2	0.0189 (9)	0.0216 (9)	0.0258 (10)	0.0066 (7)	0.0066 (8)	0.0112 (8)
Ag3	0.0202 (10)	0.0273 (11)	0.0533 (14)	0.0117 (8)	0.0162 (10)	0.0120 (10)
Ag4	0.091 (2)	0.0387 (14)	0.0287 (13)	0.0187 (14)	0.0292 (14)	0.0160 (11)
Ag5	0.0298 (10)	0.0211 (9)	0.0224 (10)	0.0092 (8)	0.0074 (8)	0.0119 (8)
Ag6	0.0313 (11)	0.0231 (10)	0.0303 (11)	0.0076 (8)	0.0185 (9)	0.0049 (8)
Ag7	0.0241 (10)	0.0245 (10)	0.0189 (9)	0.0048 (8)	0.0071 (8)	0.0055 (8)
Ag8	0.0409 (12)	0.0333 (11)	0.0285 (11)	0.0216 (10)	0.0209 (10)	0.0143 (9)
Ag9	0.0278 (10)	0.0244 (10)	0.0326 (11)	0.0136 (8)	0.0163 (9)	0.0119 (9)
Ag10	0.0324 (10)	0.0224 (9)	0.0251 (10)	0.0119 (8)	0.0148 (8)	0.0148 (8)
Ag11	0.0222 (10)	0.0391 (12)	0.0306 (12)	0.0126 (9)	0.0078 (9)	0.0087 (10)
Ag12	0.0281 (10)	0.0260 (10)	0.0357 (11)	0.0143 (8)	0.0186 (9)	0.0159 (9)
Ag13	0.0459 (13)	0.0202 (10)	0.0365 (12)	0.0137 (9)	0.0236 (10)	0.0156 (9)
Ag14	0.0234 (10)	0.0293 (11)	0.0245 (10)	0.0130 (8)	0.0062 (8)	0.0079 (8)
C1	0.026 (10)	0.019 (9)	0.024 (10)	0.002 (8)	0.006 (8)	0.016 (8)
C2	0.020 (9)	0.016 (9)	0.006 (8)	−0.007 (7)	0.005 (7)	0.004 (7)
C3	0.016 (9)	0.013 (9)	0.018 (9)	0.005 (7)	0.008 (7)	0.000 (7)
C4	0.022 (10)	0.025 (10)	0.036 (11)	0.010 (8)	0.013 (8)	0.025 (9)
C5	0.026 (10)	0.024 (10)	0.048 (12)	0.015 (8)	0.030 (9)	0.022 (9)
C6	0.026 (10)	0.028 (10)	0.035 (11)	0.009 (8)	0.014 (8)	0.022 (9)
C7	0.024 (10)	0.023 (10)	0.029 (11)	0.001 (8)	0.005 (8)	0.008 (9)
C8	0.047 (13)	0.036 (12)	0.039 (12)	0.009 (9)	0.008 (9)	0.027 (10)
C9	0.071 (17)	0.075 (17)	0.066 (16)	0.017 (12)	0.035 (13)	0.031 (13)
C10	0.070 (16)	0.055 (14)	0.055 (14)	0.020 (11)	0.025 (11)	0.032 (12)
C11	0.069 (16)	0.064 (16)	0.057 (15)	0.015 (11)	0.025 (12)	0.031 (12)
C12	0.065 (16)	0.069 (15)	0.062 (15)	0.018 (11)	0.020 (11)	0.043 (13)
C13	0.060 (14)	0.039 (12)	0.055 (14)	0.014 (10)	0.016 (10)	0.035 (11)
C14	0.021 (5)	0.021 (5)	0.021 (5)	0.008 (2)	0.009 (2)	0.009 (3)
C15	0.022 (10)	0.020 (10)	0.029 (11)	0.002 (8)	0.008 (8)	0.013 (8)
C16	0.022 (9)	0.011 (8)	0.015 (9)	0.008 (7)	0.012 (7)	0.009 (7)
C17	0.036 (11)	0.023 (10)	0.037 (12)	0.009 (8)	0.005 (9)	0.021 (9)
C18	0.021 (10)	0.014 (9)	0.025 (10)	0.004 (7)	0.009 (8)	0.008 (8)
C19	0.041 (12)	0.039 (11)	0.027 (11)	0.015 (9)	0.024 (9)	0.020 (9)
C20	0.046 (12)	0.031 (11)	0.038 (12)	0.021 (9)	0.013 (9)	0.013 (9)
C21	0.044 (13)	0.047 (13)	0.048 (13)	0.015 (10)	0.020 (10)	0.027 (10)
C22	0.070 (17)	0.072 (17)	0.081 (17)	0.032 (12)	0.033 (12)	0.037 (13)
C23	0.085 (18)	0.079 (18)	0.074 (17)	0.027 (12)	0.039 (13)	0.042 (13)
C24	0.077 (16)	0.071 (16)	0.059 (15)	0.027 (12)	0.039 (12)	0.032 (12)
C25	0.079 (17)	0.067 (16)	0.056 (15)	0.022 (12)	0.021 (11)	0.037 (13)
C26	0.046 (13)	0.034 (12)	0.044 (13)	0.012 (9)	0.012 (9)	0.024 (10)
S1	0.021 (3)	0.023 (3)	0.019 (3)	0.004 (2)	0.009 (3)	−0.003 (2)
O21	0.009 (8)	0.028 (10)	0.026 (10)	0.002 (7)	0.005 (7)	−0.003 (8)
C47	0.037 (14)	0.032 (14)	0.049 (16)	0.002 (11)	0.033 (13)	0.009 (12)
C48	0.043 (16)	0.08 (2)	0.039 (15)	0.040 (14)	0.032 (13)	0.025 (14)
S2	0.038 (4)	0.046 (4)	0.034 (4)	0.016 (3)	0.019 (3)	0.025 (4)
O22	0.041 (12)	0.056 (14)	0.019 (10)	0.017 (11)	0.009 (9)	0.022 (10)
C49	0.024 (13)	0.049 (17)	0.054 (17)	0.018 (12)	0.023 (12)	0.016 (13)
C50	0.10 (3)	0.049 (18)	0.09 (2)	0.033 (17)	0.040 (19)	0.040 (17)
S3	0.037 (4)	0.038 (4)	0.038 (4)	0.016 (3)	0.016 (3)	0.017 (3)
O23	0.024 (10)	0.046 (12)	0.031 (11)	0.021 (9)	0.003 (8)	0.011 (10)
C51	0.074 (19)	0.049 (16)	0.026 (14)	0.047 (15)	0.023 (13)	0.007 (12)
C52	0.017 (11)	0.036 (14)	0.043 (15)	0.012 (10)	0.016 (11)	0.013 (12)
S4	0.038 (4)	0.026 (3)	0.028 (4)	0.010 (3)	0.010 (3)	0.008 (3)
O24	0.054 (14)	0.033 (11)	0.027 (11)	0.006 (10)	0.016 (10)	0.015 (9)
C53	0.06 (2)	0.07 (2)	0.06 (2)	0.026 (16)	0.014 (15)	0.031 (16)
C54	0.047 (17)	0.040 (16)	0.055 (18)	0.006 (13)	0.015 (14)	0.018 (14)
S5	0.021 (3)	0.022 (3)	0.019 (3)	0.009 (2)	0.009 (2)	0.005 (2)
O25	0.024 (9)	0.016 (8)	0.018 (9)	−0.004 (7)	0.007 (7)	−0.002 (7)
C55	0.055 (17)	0.024 (13)	0.055 (17)	0.005 (12)	0.017 (14)	0.030 (13)
C56	0.018 (11)	0.015 (11)	0.033 (13)	−0.001 (9)	0.004 (10)	0.008 (10)
S6	0.027 (3)	0.030 (3)	0.029 (3)	0.010 (3)	0.013 (3)	0.011 (3)
O26	0.035 (11)	0.032 (11)	0.022 (10)	0.000 (9)	0.007 (9)	0.009 (9)
C57	0.07 (2)	0.07 (2)	0.045 (17)	0.032 (16)	0.046 (16)	0.024 (15)
C58	0.031 (13)	0.046 (16)	0.040 (15)	0.008 (11)	0.009 (11)	0.025 (13)
S7	0.050 (5)	0.037 (4)	0.033 (4)	0.025 (4)	0.016 (4)	0.014 (3)
O27	0.034 (11)	0.021 (10)	0.043 (12)	0.010 (8)	0.009 (10)	0.012 (9)
C59	0.055 (19)	0.07 (2)	0.08 (2)	0.049 (17)	0.012 (15)	0.030 (17)
C60	0.052 (18)	0.045 (17)	0.08 (2)	0.021 (14)	0.021 (15)	0.040 (16)
S8	0.042 (4)	0.039 (4)	0.043 (5)	0.003 (3)	0.024 (4)	0.009 (4)
O28	0.036 (13)	0.055 (15)	0.052 (15)	−0.001 (11)	0.027 (12)	0.012 (13)
C61	0.043 (17)	0.08 (2)	0.07 (2)	0.023 (16)	0.023 (16)	0.023 (17)
C62	0.08 (2)	0.08 (2)	0.057 (19)	0.019 (17)	0.032 (16)	0.043 (17)
O2	0.027 (11)	0.056 (14)	0.036 (12)	0.003 (10)	0.003 (9)	0.032 (11)
C27	0.027 (11)	0.022 (10)	0.022 (10)	0.004 (8)	0.009 (8)	0.013 (8)
C28	0.039 (12)	0.041 (12)	0.042 (13)	0.009 (9)	0.012 (9)	0.023 (10)
F1	0.103 (18)	0.053 (13)	0.091 (17)	−0.005 (12)	0.010 (13)	0.054 (13)
F2	0.11 (2)	0.12 (2)	0.14 (2)	0.070 (17)	0.043 (16)	0.089 (18)
F3	0.19 (3)	0.12 (2)	0.10 (2)	0.05 (2)	0.018 (17)	0.08 (2)
O3	0.038 (14)	0.11 (3)	0.037 (14)	−0.020 (15)	0.001 (11)	0.050 (16)
O4	0.025 (11)	0.059 (16)	0.037 (12)	0.012 (10)	0.003 (10)	0.017 (12)
C29	0.032 (11)	0.031 (11)	0.029 (11)	0.013 (9)	0.008 (9)	0.014 (9)
C30	0.050 (13)	0.043 (12)	0.042 (12)	0.010 (9)	0.025 (10)	0.029 (10)
F4	0.17 (3)	0.15 (2)	0.13 (2)	0.061 (18)	0.104 (19)	0.108 (19)
F5	0.063 (14)	0.11 (2)	0.079 (16)	−0.001 (13)	0.045 (13)	0.043 (14)
F6	0.13 (2)	0.12 (2)	0.093 (18)	0.012 (15)	0.096 (18)	0.034 (15)
O5	0.033 (10)	0.021 (9)	0.042 (12)	0.018 (8)	0.022 (9)	0.010 (9)
O6	0.037 (11)	0.023 (10)	0.046 (12)	0.009 (9)	0.024 (10)	0.019 (9)
C31	0.015 (9)	0.026 (10)	0.031 (10)	0.015 (8)	0.004 (7)	0.018 (8)
C32	0.030 (11)	0.021 (10)	0.033 (11)	0.014 (8)	0.004 (8)	0.013 (9)
F7	0.061 (12)	0.033 (9)	0.074 (13)	0.026 (9)	0.035 (10)	0.030 (9)
F8	0.059 (12)	0.041 (10)	0.065 (13)	0.028 (9)	0.004 (10)	0.026 (10)
F9	0.063 (12)	0.035 (10)	0.056 (12)	0.023 (9)	0.033 (10)	0.004 (9)
O7	0.025 (10)	0.044 (12)	0.045 (13)	0.014 (9)	0.014 (9)	0.029 (11)
O8	0.10 (2)	0.10 (2)	0.033 (13)	0.09 (2)	0.033 (14)	0.032 (15)
C33	0.030 (11)	0.037 (12)	0.041 (12)	0.008 (9)	0.017 (9)	0.015 (9)
C34	0.084 (19)	0.079 (18)	0.082 (18)	0.022 (12)	0.044 (14)	0.037 (14)
F10	0.14 (2)	0.14 (2)	0.13 (2)	0.062 (17)	0.096 (18)	0.088 (18)
F11	0.09 (2)	0.14 (3)	0.16 (3)	0.019 (17)	0.07 (2)	0.05 (2)
F12	0.16 (2)	0.09 (2)	0.12 (2)	0.036 (16)	0.10 (2)	0.045 (16)
O9	0.026 (11)	0.042 (14)	0.071 (17)	0.014 (10)	0.004 (11)	0.030 (13)
O10	0.035 (11)	0.021 (10)	0.035 (12)	0.017 (9)	0.002 (9)	−0.004 (9)
C35	0.023 (10)	0.023 (10)	0.039 (12)	0.006 (8)	0.010 (9)	0.018 (9)
C36	0.039 (12)	0.039 (12)	0.042 (12)	0.025 (10)	0.015 (9)	0.013 (9)
F13	0.105 (19)	0.076 (16)	0.10 (2)	0.063 (15)	−0.010 (14)	0.017 (14)
F14	0.098 (17)	0.084 (16)	0.087 (17)	0.079 (15)	0.021 (13)	0.019 (12)
F15	0.18 (3)	0.14 (2)	0.17 (3)	0.064 (19)	0.043 (18)	0.13 (2)
O11	0.049 (13)	0.033 (11)	0.024 (10)	0.006 (9)	0.028 (10)	0.011 (9)
O12	0.036 (11)	0.030 (11)	0.030 (11)	−0.001 (9)	0.012 (9)	0.010 (9)
C37	0.023 (10)	0.037 (12)	0.038 (12)	0.013 (8)	0.020 (9)	0.014 (9)
C38	0.031 (12)	0.044 (13)	0.052 (14)	0.012 (10)	0.020 (10)	0.009 (10)
F16	0.036 (11)	0.106 (18)	0.068 (14)	0.006 (11)	0.029 (10)	0.028 (13)
F17	0.110 (18)	0.059 (13)	0.103 (17)	0.030 (12)	0.074 (15)	0.060 (13)
F18	0.093 (17)	0.088 (16)	0.056 (13)	0.014 (13)	0.049 (12)	0.037 (12)
O13	0.073 (17)	0.022 (11)	0.044 (13)	0.027 (11)	0.005 (12)	0.015 (10)
O14	0.072 (17)	0.043 (13)	0.034 (13)	0.038 (13)	0.017 (12)	0.021 (11)
C39	0.036 (11)	0.025 (10)	0.040 (12)	0.009 (8)	0.011 (9)	0.024 (9)
C40	0.044 (13)	0.042 (12)	0.046 (13)	0.017 (10)	0.010 (9)	0.028 (11)
F19	0.111 (19)	0.085 (17)	0.075 (16)	0.053 (15)	−0.007 (13)	0.036 (14)
F20	0.15 (2)	0.097 (18)	0.101 (19)	0.093 (18)	0.019 (15)	0.046 (15)
F21	0.14 (2)	0.15 (2)	0.16 (3)	0.087 (19)	0.054 (17)	0.12 (2)
O15	0.051 (12)	0.017 (9)	0.031 (11)	0.016 (9)	0.003 (9)	0.018 (9)
O16	0.074 (17)	0.022 (10)	0.033 (12)	0.018 (11)	0.022 (11)	0.016 (9)
C41	0.028 (10)	0.026 (10)	0.027 (11)	0.009 (8)	0.007 (8)	0.015 (9)
C42	0.043 (12)	0.033 (11)	0.032 (12)	0.012 (9)	0.015 (9)	0.017 (9)
F22	0.099 (16)	0.058 (13)	0.066 (13)	0.027 (11)	0.042 (12)	0.050 (11)
F23	0.12 (2)	0.096 (16)	0.14 (2)	0.078 (15)	0.058 (15)	0.093 (16)
F24	0.112 (19)	0.056 (14)	0.075 (16)	0.002 (12)	0.019 (13)	0.045 (13)
O17	0.038 (13)	0.060 (17)	0.054 (16)	0.004 (12)	0.041 (13)	0.008 (13)
O18	0.024 (10)	0.018 (9)	0.040 (12)	0.003 (8)	0.018 (9)	−0.013 (8)
C43	0.021 (10)	0.038 (12)	0.028 (11)	0.011 (8)	0.013 (8)	0.013 (9)
C44	0.039 (12)	0.038 (12)	0.044 (13)	0.016 (10)	0.021 (10)	0.009 (9)
F25	0.033 (10)	0.067 (14)	0.086 (16)	0.011 (9)	0.029 (11)	0.021 (12)
F26	0.062 (13)	0.091 (16)	0.041 (11)	0.020 (11)	0.024 (10)	0.030 (11)
F27	0.062 (13)	0.048 (11)	0.068 (13)	0.017 (9)	0.043 (11)	0.023 (10)
O19	0.067 (18)	0.023 (11)	0.056 (16)	0.029 (12)	0.004 (13)	−0.004 (11)
O20	0.021 (10)	0.026 (11)	0.051 (14)	−0.001 (8)	0.006 (10)	−0.011 (10)
C45	0.014 (9)	0.020 (9)	0.011 (9)	0.009 (7)	0.007 (7)	0.002 (7)
C46	0.041 (12)	0.039 (12)	0.036 (12)	0.017 (9)	0.020 (9)	0.013 (9)
F28	0.108 (18)	0.077 (16)	0.047 (13)	0.056 (14)	0.027 (12)	−0.003 (11)
F29	0.063 (13)	0.080 (16)	0.090 (17)	0.034 (12)	0.059 (13)	0.017 (12)
F30	0.12 (2)	0.090 (16)	0.101 (18)	0.080 (15)	0.052 (14)	0.064 (14)

Geometric parameters (Å, º)

Ag1—C1	2.21 (2)	C26—H26B	0.9900
Ag1—O1	2.25 (2)	S1—O21	1.51 (2)
Ag1—O3	2.53 (3)	S1—C48	1.79 (3)
Ag1—Ag2	2.857 (3)	S1—C47	1.80 (3)
Ag1—Ag4	2.906 (3)	C47—H47A	0.9800
Ag1—Ag3	2.912 (3)	C47—H47B	0.9800
Ag1—Ag12^i	3.066 (3)	C47—H47C	0.9800
Ag1—Ag14^i	3.105 (3)	C48—H48A	0.9800
Ag1—Ag13^i	3.112 (3)	C48—H48B	0.9800
Ag2—O7	2.32 (2)	C48—H48C	0.9800
Ag2—O5	2.323 (18)	S2—O22	1.53 (2)
Ag2—C1	2.34 (3)	S2—C49	1.77 (3)
Ag2—C18^i	2.40 (2)	S2—C50	1.78 (5)
Ag2—Ag14^i	2.980 (3)	C49—H49A	0.9800
Ag2—Ag3	2.999 (3)	C49—H49B	0.9800
Ag2—Ag12^i	3.011 (3)	C49—H49C	0.9800
Ag3—C1	2.25 (3)	C50—H50A	0.9800
Ag3—O9	2.27 (2)	C50—H50B	0.9800
Ag3—O8	2.42 (2)	C50—H50C	0.9800
Ag3—O21	2.438 (17)	S3—O23	1.52 (2)
Ag3—Ag14^i	3.052 (3)	S3—C52	1.75 (3)
Ag4—O22	2.276 (19)	S3—C51	1.92 (4)
Ag4—C1	2.35 (3)	C51—H51A	0.9800
Ag4—O23	2.38 (2)	C51—H51B	0.9800
Ag4—C2	2.57 (2)	C51—H51C	0.9800
Ag5—C5	2.13 (3)	C52—H52A	0.9800
Ag5—O15	2.203 (18)	C52—H52B	0.9800
Ag5—O24	2.54 (2)	C52—H52C	0.9800
Ag5—O22	2.56 (2)	S4—O24	1.48 (2)
Ag5—Ag8	2.894 (3)	S4—C53	1.74 (4)
Ag5—Ag7	2.908 (3)	S4—C54	1.76 (4)
Ag5—Ag6	3.162 (3)	C53—H53A	0.9800
Ag5—Ag10	3.186 (3)	C53—H53B	0.9800
Ag6—O17	2.28 (2)	C53—H53C	0.9800
Ag6—O24	2.40 (2)	C54—H54A	0.9800
Ag6—O21	2.435 (19)	C54—H54B	0.9800
Ag6—C5	2.54 (3)	C54—H54C	0.9800
Ag6—C4	2.66 (3)	S5—O25	1.59 (2)
Ag6—Ag7	3.092 (3)	S5—C55	1.75 (3)
Ag7—C5	2.18 (3)	S5—C56	1.80 (3)
Ag7—C14	2.25 (3)	C55—H55A	0.9800
Ag7—O18	2.32 (2)	C55—H55B	0.9800
Ag7—O19	2.54 (2)	C55—H55C	0.9800
Ag7—Ag10	2.872 (3)	C56—H56A	0.9800
Ag7—Ag11	3.062 (3)	C56—H56B	0.9800
Ag7—Ag8	3.110 (3)	C56—H56C	0.9800
Ag8—C5	2.19 (3)	S6—O26	1.55 (2)
Ag8—O11	2.277 (18)	S6—C58	1.77 (3)
Ag8—O13	2.28 (2)	S6—C57	1.78 (4)
Ag8—Ag9	3.191 (3)	C57—H57A	0.9800
Ag8—Ag10	3.220 (3)	C57—H57B	0.9800
Ag9—O12	2.26 (2)	C57—H57C	0.9800
Ag9—O14	2.38 (2)	C58—H58A	0.9800
Ag9—O25	2.412 (18)	C58—H58B	0.9800
Ag9—C14	2.45 (3)	C58—H58C	0.9800
Ag9—C15	2.52 (3)	S7—O27	1.51 (2)
Ag9—Ag10	2.918 (3)	S7—C60	1.74 (4)
Ag10—O16	2.16 (2)	S7—C59	1.80 (5)
Ag10—C14	2.16 (3)	C59—H59A	0.9800
Ag10—O26	2.58 (2)	C59—H59B	0.9800
Ag10—Ag11	3.012 (3)	C59—H59C	0.9800
Ag11—O20	2.28 (2)	C60—H60A	0.9800
Ag11—C14	2.33 (2)	C60—H60B	0.9800
Ag11—O28	2.41 (2)	C60—H60C	0.9800
Ag11—O27	2.42 (2)	S8—O28	1.49 (3)
Ag12—O4^ii	2.31 (3)	S8—C62	1.86 (5)
Ag12—O6^ii	2.322 (19)	S8—C61	1.86 (5)
Ag12—C18	2.33 (3)	C61—H61A	0.9800
Ag12—Ag13	2.868 (3)	C61—H61B	0.9800
Ag12—Ag2^ii	3.011 (3)	C61—H61C	0.9800
Ag12—Ag1^ii	3.066 (3)	C62—H62A	0.9800
Ag13—C18	2.21 (2)	C62—H62B	0.9800
Ag13—O2^ii	2.32 (2)	C62—H62C	0.9800
Ag13—O26	2.41 (2)	O1—C27	1.29 (3)
Ag13—O27	2.53 (2)	O2—C27	1.19 (3)
Ag13—Ag14	2.907 (3)	O2—Ag13^i	2.32 (2)
Ag13—Ag1^ii	3.112 (3)	C27—C28	1.57 (3)
Ag14—C18	2.19 (3)	C28—F1	1.299 (15)
Ag14—O10^ii	2.215 (19)	C28—F3	1.300 (15)
Ag14—O28	2.51 (3)	C28—F2	1.303 (15)
Ag14—Ag2^ii	2.980 (3)	O3—C29	1.23 (4)
Ag14—Ag3^ii	3.052 (3)	O4—C29	1.24 (4)
Ag14—Ag1^ii	3.105 (3)	O4—Ag12^i	2.31 (3)
C1—C2	1.26 (4)	C29—C30	1.60 (4)
C2—C3	1.41 (3)	C30—F6	1.290 (15)
C3—C4	1.39 (4)	C30—F5	1.294 (14)
C3—C6	1.44 (4)	C30—F4	1.295 (14)
C4—C5	1.36 (4)	O5—C31	1.29 (3)
C6—C13	1.42 (5)	O6—C31	1.20 (3)
C6—C7	1.51 (4)	O6—Ag12^i	2.323 (19)
C7—C8	1.46 (4)	C31—C32	1.56 (3)
C7—H7A	0.9900	C32—F8	1.302 (14)
C7—H7B	0.9900	C32—F9	1.304 (14)
C8—C9	1.57 (7)	C32—F7	1.305 (14)
C8—H8A	0.9900	O7—C33	1.23 (4)
C8—H8B	0.9900	O8—C33	1.27 (4)
C9—C10	1.52 (7)	C33—C34	1.56 (4)
C9—H9A	0.9900	C34—F10	1.295 (15)
C9—H9B	0.9900	C34—F12	1.296 (15)
C10—C11	1.59 (6)	C34—F11	1.305 (15)
C10—H10A	0.9900	O9—C35	1.21 (4)
C10—H10B	0.9900	O10—C35	1.25 (4)
C11—C12	1.42 (6)	O10—Ag14^i	2.215 (19)
C11—H11A	0.9900	C35—C36	1.53 (3)
C11—H11B	0.9900	C36—F13	1.298 (15)
C12—C13	1.54 (7)	C36—F14	1.301 (14)
C12—H12A	0.9900	C36—F15	1.307 (15)
C12—H12B	0.9900	O11—C37	1.20 (4)
C13—H13A	0.9900	O12—C37	1.26 (4)
C13—H13B	0.9900	C37—C38	1.59 (4)
C14—C15	1.25 (4)	C38—F17	1.295 (15)
C15—C16	1.40 (3)	C38—F18	1.297 (15)
C16—C19	1.37 (4)	C38—F16	1.300 (15)
C16—C17	1.45 (4)	O13—C39	1.25 (4)
C17—C18	1.20 (4)	O14—C39	1.21 (4)
C18—Ag2^ii	2.40 (2)	C39—C40	1.60 (3)
C19—C20	1.45 (4)	C40—F21	1.297 (15)
C19—C26	1.58 (4)	C40—F19	1.302 (15)
C20—C21	1.54 (5)	C40—F20	1.305 (15)
C20—H20A	0.9900	O15—C41	1.22 (4)
C20—H20B	0.9900	O16—C41	1.27 (4)
C21—C22	1.59 (6)	C41—C42	1.57 (3)
C21—H21A	0.9900	C42—F24	1.295 (14)
C21—H21B	0.9900	C42—F22	1.306 (14)
C22—C23	1.48 (7)	C42—F23	1.307 (14)
C22—H22A	0.9900	O17—C43	1.19 (4)
C22—H22B	0.9900	O18—C43	1.29 (4)
C23—C24	1.49 (7)	C43—C44	1.59 (4)
C23—H23A	0.9900	C44—F26	1.301 (15)
C23—H23B	0.9900	C44—F25	1.301 (15)
C24—C25	1.60 (7)	C44—F27	1.307 (15)
C24—H24A	0.9900	O19—C45	1.21 (4)
C24—H24B	0.9900	O20—C45	1.27 (3)
C25—C26	1.46 (6)	C45—C46	1.60 (3)
C25—H25A	0.9900	C46—F29	1.294 (14)
C25—H25B	0.9900	C46—F28	1.299 (15)
C26—H26A	0.9900	C46—F30	1.307 (15)
C1—Ag1—O1	136.7 (9)	H7A—C7—H7B	107.1
C1—Ag1—O3	106.5 (11)	C7—C8—C9	112 (3)
O1—Ag1—O3	88.1 (10)	C7—C8—H8A	109.2
C1—Ag1—Ag2	53.1 (7)	C9—C8—H8A	109.2
O1—Ag1—Ag2	145.0 (6)	C7—C8—H8B	109.2
O3—Ag1—Ag2	124.1 (8)	C9—C8—H8B	109.2
C1—Ag1—Ag4	52.7 (7)	H8A—C8—H8B	107.9
O1—Ag1—Ag4	104.9 (5)	C10—C9—C8	120 (4)
O3—Ag1—Ag4	63.1 (6)	C10—C9—H9A	107.4
Ag2—Ag1—Ag4	102.42 (9)	C8—C9—H9A	107.4
C1—Ag1—Ag3	49.8 (8)	C10—C9—H9B	107.4
O1—Ag1—Ag3	98.0 (6)	C8—C9—H9B	107.4
O3—Ag1—Ag3	148.6 (6)	H9A—C9—H9B	106.9
Ag2—Ag1—Ag3	62.62 (7)	C9—C10—C11	110 (4)
Ag4—Ag1—Ag3	85.68 (10)	C9—C10—H10A	109.6
C1—Ag1—Ag12^i	98.6 (7)	C11—C10—H10A	109.6
O1—Ag1—Ag12^i	124.6 (5)	C9—C10—H10B	109.6
O3—Ag1—Ag12^i	75.4 (6)	C11—C10—H10B	109.6
Ag2—Ag1—Ag12^i	60.99 (7)	H10A—C10—H10B	108.1
Ag4—Ag1—Ag12^i	112.80 (11)	C12—C11—C10	115 (4)
Ag3—Ag1—Ag12^i	123.12 (9)	C12—C11—H11A	108.5
C1—Ag1—Ag14^i	97.8 (7)	C10—C11—H11A	108.5
O1—Ag1—Ag14^i	85.5 (6)	C12—C11—H11B	108.5
O3—Ag1—Ag14^i	150.5 (6)	C10—C11—H11B	108.5
Ag2—Ag1—Ag14^i	59.81 (7)	H11A—C11—H11B	107.5
Ag4—Ag1—Ag14^i	146.24 (11)	C11—C12—C13	120 (4)
Ag3—Ag1—Ag14^i	60.86 (7)	C11—C12—H12A	107.4
Ag12^i—Ag1—Ag14^i	84.79 (8)	C13—C12—H12A	107.4
C1—Ag1—Ag13^i	141.1 (7)	C11—C12—H12B	107.4
O1—Ag1—Ag13^i	74.6 (5)	C13—C12—H12B	107.4
O3—Ag1—Ag13^i	94.8 (6)	H12A—C12—H12B	106.9
Ag2—Ag1—Ag13^i	88.00 (8)	C6—C13—C12	113 (3)
Ag4—Ag1—Ag13^i	157.77 (11)	C6—C13—H13A	108.9
Ag3—Ag1—Ag13^i	116.52 (10)	C12—C13—H13A	108.9
Ag12^i—Ag1—Ag13^i	55.31 (7)	C6—C13—H13B	108.9
Ag14^i—Ag1—Ag13^i	55.76 (7)	C12—C13—H13B	108.9
O7—Ag2—O5	97.3 (7)	H13A—C13—H13B	107.8
O7—Ag2—C1	118.5 (9)	C15—C14—Ag10	145 (2)
O5—Ag2—C1	97.5 (9)	C15—C14—Ag7	133 (2)
O7—Ag2—C18^i	103.5 (9)	Ag10—C14—Ag7	81.3 (9)
O5—Ag2—C18^i	115.3 (8)	C15—C14—Ag11	98.5 (19)
C1—Ag2—C18^i	122.3 (9)	Ag10—C14—Ag11	84.2 (8)
O7—Ag2—Ag1	139.7 (5)	Ag7—C14—Ag11	84.0 (9)
O5—Ag2—Ag1	120.8 (5)	C15—C14—Ag9	78.8 (18)
C1—Ag2—Ag1	49.0 (6)	Ag10—C14—Ag9	78.3 (8)
C18^i—Ag2—Ag1	73.3 (6)	Ag7—C14—Ag9	125.5 (11)
O7—Ag2—Ag14^i	84.2 (6)	Ag11—C14—Ag9	141.9 (12)
O5—Ag2—Ag14^i	161.1 (5)	C14—C15—C16	170 (3)
C1—Ag2—Ag14^i	98.3 (6)	C14—C15—Ag9	72.2 (17)
C18^i—Ag2—Ag14^i	46.6 (6)	C16—C15—Ag9	112.1 (18)
Ag1—Ag2—Ag14^i	64.23 (7)	C19—C16—C15	126 (2)
O7—Ag2—Ag3	84.0 (5)	C19—C16—C17	121 (2)
O5—Ag2—Ag3	137.5 (5)	C15—C16—C17	112 (2)
C1—Ag2—Ag3	47.9 (7)	C18—C17—C16	161 (3)
C18^i—Ag2—Ag3	105.4 (6)	C17—C18—Ag14	127 (2)
Ag1—Ag2—Ag3	59.57 (7)	C17—C18—Ag13	129 (2)
Ag14^i—Ag2—Ag3	61.39 (7)	Ag14—C18—Ag13	82.6 (8)
O7—Ag2—Ag12^i	144.2 (5)	C17—C18—Ag12	98 (2)
O5—Ag2—Ag12^i	79.8 (5)	Ag14—C18—Ag12	133.9 (12)
C1—Ag2—Ag12^i	97.2 (7)	Ag13—C18—Ag12	78.3 (8)
C18^i—Ag2—Ag12^i	49.3 (6)	C17—C18—Ag2^ii	99.9 (19)
Ag1—Ag2—Ag12^i	62.92 (7)	Ag14—C18—Ag2^ii	80.7 (8)
Ag14^i—Ag2—Ag12^i	87.96 (7)	Ag13—C18—Ag2^ii	128.1 (12)
Ag3—Ag2—Ag12^i	122.02 (9)	Ag12—C18—Ag2^ii	79.0 (8)
C1—Ag3—O9	139.8 (10)	C16—C19—C20	126 (3)
C1—Ag3—O8	121.1 (8)	C16—C19—C26	115 (3)
O9—Ag3—O8	93.2 (10)	C20—C19—C26	118 (3)
C1—Ag3—O21	111.0 (8)	C19—C20—C21	120 (3)
O9—Ag3—O21	85.8 (8)	C19—C20—H20A	107.4
O8—Ag3—O21	92.2 (10)	C21—C20—H20A	107.4
C1—Ag3—Ag1	48.5 (6)	C19—C20—H20B	107.4
O9—Ag3—Ag1	98.4 (7)	C21—C20—H20B	107.4
O8—Ag3—Ag1	118.7 (9)	H20A—C20—H20B	106.9
O21—Ag3—Ag1	148.3 (5)	C20—C21—C22	111 (3)
C1—Ag3—Ag2	50.5 (7)	C20—C21—H21A	109.4
O9—Ag3—Ag2	137.8 (6)	C22—C21—H21A	109.4
O8—Ag3—Ag2	73.9 (6)	C20—C21—H21B	109.4
O21—Ag3—Ag2	133.6 (5)	C22—C21—H21B	109.4
Ag1—Ag3—Ag2	57.80 (7)	H21A—C21—H21B	108.0
C1—Ag3—Ag14^i	98.3 (7)	C23—C22—C21	128 (5)
O9—Ag3—Ag14^i	79.5 (6)	C23—C22—H22A	105.3
O8—Ag3—Ag14^i	60.9 (9)	C21—C22—H22A	105.3
O21—Ag3—Ag14^i	148.0 (5)	C23—C22—H22B	105.3
Ag1—Ag3—Ag14^i	62.70 (7)	C21—C22—H22B	105.3
Ag2—Ag3—Ag14^i	59.01 (7)	H22A—C22—H22B	106.0
O22—Ag4—C1	144.9 (9)	C22—C23—C24	111 (5)
O22—Ag4—O23	93.2 (8)	C22—C23—H23A	109.5
C1—Ag4—O23	116.3 (8)	C24—C23—H23A	109.5
O22—Ag4—C2	139.0 (8)	C22—C23—H23B	109.5
C1—Ag4—C2	29.3 (8)	C24—C23—H23B	109.5
O23—Ag4—C2	94.6 (8)	H23A—C23—H23B	108.1
O22—Ag4—Ag1	116.6 (6)	C23—C24—C25	122 (4)
C1—Ag4—Ag1	48.2 (6)	C23—C24—H24A	106.9
O23—Ag4—Ag1	143.1 (5)	C25—C24—H24A	106.9
C2—Ag4—Ag1	77.5 (5)	C23—C24—H24B	106.9
C5—Ag5—O15	168.4 (10)	C25—C24—H24B	106.9
C5—Ag5—O24	95.0 (9)	H24A—C24—H24B	106.7
O15—Ag5—O24	95.9 (7)	C26—C25—C24	112 (4)
C5—Ag5—O22	106.3 (9)	C26—C25—H25A	109.3
O15—Ag5—O22	78.9 (7)	C24—C25—H25A	109.3
O24—Ag5—O22	83.1 (8)	C26—C25—H25B	109.3
C5—Ag5—Ag8	48.8 (7)	C24—C25—H25B	109.3
O15—Ag5—Ag8	121.9 (6)	H25A—C25—H25B	107.9
O24—Ag5—Ag8	139.9 (5)	C25—C26—C19	118 (3)
O22—Ag5—Ag8	91.0 (5)	C25—C26—H26A	107.9
C5—Ag5—Ag7	48.3 (8)	C19—C26—H26A	107.9
O15—Ag5—Ag7	124.1 (6)	C25—C26—H26B	107.9
O24—Ag5—Ag7	106.6 (5)	C19—C26—H26B	107.9
O22—Ag5—Ag7	152.6 (5)	H26A—C26—H26B	107.2
Ag8—Ag5—Ag7	64.83 (7)	O21—S1—C48	105.9 (13)
C5—Ag5—Ag6	53.3 (7)	O21—S1—C47	106.2 (14)
O15—Ag5—Ag6	134.3 (6)	C48—S1—C47	103.1 (19)
O24—Ag5—Ag6	48.3 (5)	S1—O21—Ag6	124.4 (10)
O22—Ag5—Ag6	115.7 (5)	S1—O21—Ag3	111.5 (10)
Ag8—Ag5—Ag6	101.77 (8)	Ag6—O21—Ag3	114.2 (8)
Ag7—Ag5—Ag6	61.08 (7)	S1—C47—H47A	109.5
C5—Ag5—Ag10	91.7 (8)	S1—C47—H47B	109.5
O15—Ag5—Ag10	77.1 (5)	H47A—C47—H47B	109.5
O24—Ag5—Ag10	146.4 (6)	S1—C47—H47C	109.5
O22—Ag5—Ag10	126.3 (5)	H47A—C47—H47C	109.5
Ag8—Ag5—Ag10	63.75 (7)	H47B—C47—H47C	109.5
Ag7—Ag5—Ag10	56.01 (6)	S1—C48—H48A	109.5
Ag6—Ag5—Ag10	115.45 (8)	S1—C48—H48B	109.5
O17—Ag6—O24	142.5 (10)	H48A—C48—H48B	109.5
O17—Ag6—O21	94.6 (8)	S1—C48—H48C	109.5
O24—Ag6—O21	90.3 (7)	H48A—C48—H48C	109.5
O17—Ag6—C5	117.1 (9)	H48B—C48—H48C	109.5
O24—Ag6—C5	88.6 (8)	O22—S2—C49	105.2 (15)
O21—Ag6—C5	126.3 (8)	O22—S2—C50	105 (2)
O17—Ag6—C4	117.5 (9)	C49—S2—C50	99 (2)
O24—Ag6—C4	98.6 (8)	S2—O22—Ag4	131.5 (13)
O21—Ag6—C4	97.6 (8)	S2—O22—Ag5	117.4 (11)
C5—Ag6—C4	30.2 (9)	Ag4—O22—Ag5	98.2 (8)
O17—Ag6—Ag7	80.8 (6)	S2—C49—H49A	109.5
O24—Ag6—Ag7	104.9 (5)	S2—C49—H49B	109.5
O21—Ag6—Ag7	160.6 (5)	H49A—C49—H49B	109.5
C5—Ag6—Ag7	44.2 (7)	S2—C49—H49C	109.5
C4—Ag6—Ag7	68.7 (6)	H49A—C49—H49C	109.5
O17—Ag6—Ag5	132.1 (7)	H49B—C49—H49C	109.5
O24—Ag6—Ag5	52.3 (6)	S2—C50—H50A	109.5
O21—Ag6—Ag5	133.2 (5)	S2—C50—H50B	109.5
C5—Ag6—Ag5	42.1 (6)	H50A—C50—H50B	109.5
C4—Ag6—Ag5	66.9 (6)	S2—C50—H50C	109.5
Ag7—Ag6—Ag5	55.40 (6)	H50A—C50—H50C	109.5
C5—Ag7—C14	122.3 (10)	H50B—C50—H50C	109.5
C5—Ag7—O18	112.7 (9)	O23—S3—C52	104.6 (14)
C14—Ag7—O18	107.7 (8)	O23—S3—C51	105.6 (13)
C5—Ag7—O19	102.9 (9)	C52—S3—C51	101.8 (15)
C14—Ag7—O19	115.6 (9)	S3—O23—Ag4	130.8 (12)
O18—Ag7—O19	91.6 (10)	S3—C51—H51A	109.5
C5—Ag7—Ag10	99.5 (7)	S3—C51—H51B	109.5
C14—Ag7—Ag10	48.1 (7)	H51A—C51—H51B	109.5
O18—Ag7—Ag10	147.7 (5)	S3—C51—H51C	109.5
O19—Ag7—Ag10	84.0 (7)	H51A—C51—H51C	109.5
C5—Ag7—Ag5	46.8 (7)	H51B—C51—H51C	109.5
C14—Ag7—Ag5	112.3 (7)	S3—C52—H52A	109.5
O18—Ag7—Ag5	139.8 (4)	S3—C52—H52B	109.5
O19—Ag7—Ag5	67.3 (7)	H52A—C52—H52B	109.5
Ag10—Ag7—Ag5	66.89 (7)	S3—C52—H52C	109.5
C5—Ag7—Ag11	159.9 (7)	H52A—C52—H52C	109.5
C14—Ag7—Ag11	49.1 (6)	H52B—C52—H52C	109.5
O18—Ag7—Ag11	87.2 (5)	O24—S4—C53	107.6 (18)
O19—Ag7—Ag11	72.4 (6)	O24—S4—C54	108.0 (17)
Ag10—Ag7—Ag11	60.89 (7)	C53—S4—C54	98 (2)
Ag5—Ag7—Ag11	115.66 (9)	S4—O24—Ag6	134.7 (15)
C5—Ag7—Ag6	54.5 (7)	S4—O24—Ag5	135.8 (12)
C14—Ag7—Ag6	175.7 (7)	Ag6—O24—Ag5	79.5 (7)
O18—Ag7—Ag6	76.6 (4)	S4—C53—H53A	109.5
O19—Ag7—Ag6	64.2 (6)	S4—C53—H53B	109.5
Ag10—Ag7—Ag6	128.24 (9)	H53A—C53—H53B	109.5
Ag5—Ag7—Ag6	63.51 (7)	S4—C53—H53C	109.5
Ag11—Ag7—Ag6	132.76 (9)	H53A—C53—H53C	109.5
C5—Ag7—Ag8	44.7 (7)	H53B—C53—H53C	109.5
C14—Ag7—Ag8	77.9 (7)	S4—C54—H54A	109.5
O18—Ag7—Ag8	139.1 (6)	S4—C54—H54B	109.5
O19—Ag7—Ag8	123.3 (8)	H54A—C54—H54B	109.5
Ag10—Ag7—Ag8	64.99 (7)	S4—C54—H54C	109.5
Ag5—Ag7—Ag8	57.37 (7)	H54A—C54—H54C	109.5
Ag11—Ag7—Ag8	121.05 (9)	H54B—C54—H54C	109.5
Ag6—Ag7—Ag8	98.58 (8)	O25—S5—C55	104.2 (16)
C5—Ag8—O11	131.8 (9)	O25—S5—C56	107.7 (11)
C5—Ag8—O13	108.9 (10)	C55—S5—C56	96.8 (15)
O11—Ag8—O13	117.8 (10)	S5—O25—Ag9	123.9 (10)
C5—Ag8—Ag5	47.0 (7)	S5—C55—H55A	109.5
O11—Ag8—Ag5	85.4 (6)	S5—C55—H55B	109.5
O13—Ag8—Ag5	155.8 (7)	H55A—C55—H55B	109.5
C5—Ag8—Ag7	44.5 (8)	S5—C55—H55C	109.5
O11—Ag8—Ag7	122.4 (6)	H55A—C55—H55C	109.5
O13—Ag8—Ag7	109.0 (8)	H55B—C55—H55C	109.5
Ag5—Ag8—Ag7	57.81 (7)	S5—C56—H56A	109.5
C5—Ag8—Ag9	127.1 (8)	S5—C56—H56B	109.5
O11—Ag8—Ag9	76.0 (5)	H56A—C56—H56B	109.5
O13—Ag8—Ag9	78.2 (6)	S5—C56—H56C	109.5
Ag5—Ag8—Ag9	116.67 (9)	H56A—C56—H56C	109.5
Ag7—Ag8—Ag9	82.96 (8)	H56B—C56—H56C	109.5
C5—Ag8—Ag10	89.7 (8)	O26—S6—C58	105.3 (14)
O11—Ag8—Ag10	70.5 (6)	O26—S6—C57	104.9 (16)
O13—Ag8—Ag10	129.2 (6)	C58—S6—C57	98.3 (19)
Ag5—Ag8—Ag10	62.54 (7)	S6—O26—Ag13	127.8 (11)
Ag7—Ag8—Ag10	53.93 (6)	S6—O26—Ag10	110.3 (10)
Ag9—Ag8—Ag10	54.15 (6)	Ag13—O26—Ag10	121.8 (9)
O12—Ag9—O14	98.2 (9)	S6—C57—H57A	109.5
O12—Ag9—O25	97.1 (7)	S6—C57—H57B	109.5
O14—Ag9—O25	96.0 (7)	H57A—C57—H57B	109.5
O12—Ag9—C14	129.1 (9)	S6—C57—H57C	109.5
O14—Ag9—C14	115.0 (9)	H57A—C57—H57C	109.5
O25—Ag9—C14	115.4 (8)	H57B—C57—H57C	109.5
O12—Ag9—C15	156.0 (9)	S6—C58—H58A	109.5
O14—Ag9—C15	102.8 (9)	S6—C58—H58B	109.5
O25—Ag9—C15	92.2 (8)	H58A—C58—H58B	109.5
C14—Ag9—C15	29.0 (9)	S6—C58—H58C	109.5
O12—Ag9—Ag10	83.1 (6)	H58A—C58—H58C	109.5
O14—Ag9—Ag10	139.6 (6)	H58B—C58—H58C	109.5
O25—Ag9—Ag10	124.1 (5)	O27—S7—C60	104.9 (15)
C14—Ag9—Ag10	46.5 (6)	O27—S7—C59	107.4 (18)
C15—Ag9—Ag10	73.4 (6)	C60—S7—C59	96 (2)
O12—Ag9—Ag8	77.7 (6)	S7—O27—Ag11	131.3 (13)
O14—Ag9—Ag8	77.3 (6)	S7—O27—Ag13	118.1 (13)
O25—Ag9—Ag8	170.7 (5)	Ag11—O27—Ag13	104.4 (7)
C14—Ag9—Ag8	73.7 (6)	S7—C59—H59A	109.5
C15—Ag9—Ag8	95.6 (6)	S7—C59—H59B	109.5
Ag10—Ag9—Ag8	63.42 (7)	H59A—C59—H59B	109.5
O16—Ag10—C14	172.1 (10)	S7—C59—H59C	109.5
O16—Ag10—O26	80.2 (8)	H59A—C59—H59C	109.5
C14—Ag10—O26	97.1 (8)	H59B—C59—H59C	109.5
O16—Ag10—Ag7	129.8 (6)	S7—C60—H60A	109.5
C14—Ag10—Ag7	50.7 (7)	S7—C60—H60B	109.5
O26—Ag10—Ag7	145.3 (5)	H60A—C60—H60B	109.5
O16—Ag10—Ag9	130.1 (7)	S7—C60—H60C	109.5
C14—Ag10—Ag9	55.2 (7)	H60A—C60—H60C	109.5
O26—Ag10—Ag9	74.1 (5)	H60B—C60—H60C	109.5
Ag7—Ag10—Ag9	92.26 (8)	O28—S8—C62	102.0 (19)
O16—Ag10—Ag11	122.0 (7)	O28—S8—C61	109 (2)
C14—Ag10—Ag11	50.2 (7)	C62—S8—C61	99 (2)
O26—Ag10—Ag11	87.7 (5)	S8—O28—Ag11	131.8 (16)
Ag7—Ag10—Ag11	62.68 (7)	S8—O28—Ag14	121.6 (14)
Ag9—Ag10—Ag11	99.13 (8)	Ag11—O28—Ag14	101.6 (9)
O16—Ag10—Ag5	78.0 (6)	S8—C61—H61A	109.5
C14—Ag10—Ag5	105.3 (7)	S8—C61—H61B	109.5
O26—Ag10—Ag5	157.3 (5)	H61A—C61—H61B	109.5
Ag7—Ag10—Ag5	57.10 (6)	S8—C61—H61C	109.5
Ag9—Ag10—Ag5	116.13 (8)	H61A—C61—H61C	109.5
Ag11—Ag10—Ag5	109.26 (8)	H61B—C61—H61C	109.5
O16—Ag10—Ag8	111.0 (7)	S8—C62—H62A	109.5
C14—Ag10—Ag8	76.5 (7)	S8—C62—H62B	109.5
O26—Ag10—Ag8	131.1 (5)	H62A—C62—H62B	109.5
Ag7—Ag10—Ag8	61.09 (7)	S8—C62—H62C	109.5
Ag9—Ag10—Ag8	62.43 (7)	H62A—C62—H62C	109.5
Ag11—Ag10—Ag8	119.13 (8)	H62B—C62—H62C	109.5
Ag5—Ag10—Ag8	53.71 (6)	C27—O1—Ag1	119.0 (17)
O20—Ag11—C14	131.0 (8)	C27—O2—Ag13^i	115.7 (18)
O20—Ag11—O28	93.8 (9)	O2—C27—O1	134 (3)
C14—Ag11—O28	121.9 (10)	O2—C27—C28	113 (2)
O20—Ag11—O27	98.4 (9)	O1—C27—C28	112 (2)
C14—Ag11—O27	117.6 (8)	F1—C28—F3	108.3 (15)
O28—Ag11—O27	81.5 (9)	F1—C28—F2	107.6 (14)
O20—Ag11—Ag10	107.4 (6)	F3—C28—F2	108.3 (15)
C14—Ag11—Ag10	45.6 (6)	F1—C28—C27	111.2 (19)
O28—Ag11—Ag10	158.2 (7)	F3—C28—C27	109 (2)
O27—Ag11—Ag10	90.3 (5)	F2—C28—C27	112 (2)
O20—Ag11—Ag7	84.5 (6)	C29—O3—Ag1	119 (2)
C14—Ag11—Ag7	46.9 (6)	C29—O4—Ag12^i	120 (2)
O28—Ag11—Ag7	132.9 (7)	O3—C29—O4	133 (3)
O27—Ag11—Ag7	145.4 (5)	O3—C29—C30	114 (2)
Ag10—Ag11—Ag7	56.43 (7)	O4—C29—C30	112 (3)
O4^ii—Ag12—O6^ii	99.4 (9)	F6—C30—F5	109.4 (15)
O4^ii—Ag12—C18	138.5 (9)	F6—C30—F4	109.5 (15)
O6^ii—Ag12—C18	120.5 (8)	F5—C30—F4	109.0 (14)
O4^ii—Ag12—Ag13	90.5 (7)	F6—C30—C29	108 (2)
O6^ii—Ag12—Ag13	169.5 (5)	F5—C30—C29	111 (2)
C18—Ag12—Ag13	49.1 (6)	F4—C30—C29	110 (2)
O4^ii—Ag12—Ag2^ii	134.8 (6)	C31—O5—Ag2	125.3 (16)
O6^ii—Ag12—Ag2^ii	80.7 (5)	C31—O6—Ag12^i	126.0 (18)
C18—Ag12—Ag2^ii	51.6 (6)	O6—C31—O5	127 (2)
Ag13—Ag12—Ag2^ii	89.80 (8)	O6—C31—C32	119 (2)
O4^ii—Ag12—Ag1^ii	84.3 (6)	O5—C31—C32	114 (2)
O6^ii—Ag12—Ag1^ii	114.0 (5)	F8—C32—F9	108.7 (14)
C18—Ag12—Ag1^ii	70.3 (6)	F8—C32—F7	108.6 (13)
Ag13—Ag12—Ag1^ii	63.17 (7)	F9—C32—F7	108.0 (13)
Ag2^ii—Ag12—Ag1^ii	56.09 (6)	F8—C32—C31	109.8 (16)
C18—Ag13—O2^ii	148.1 (9)	F9—C32—C31	109.2 (17)
C18—Ag13—O26	119.6 (8)	F7—C32—C31	112.6 (17)
O2^ii—Ag13—O26	91.9 (7)	C33—O7—Ag2	118 (2)
C18—Ag13—O27	95.8 (9)	C33—O8—Ag3	121 (2)
O2^ii—Ag13—O27	94.0 (8)	O7—C33—O8	129 (3)
O26—Ag13—O27	80.1 (7)	O7—C33—C34	120 (3)
C18—Ag13—Ag12	52.6 (7)	O8—C33—C34	110 (3)
O2^ii—Ag13—Ag12	115.3 (7)	F10—C34—F12	109.2 (16)
O26—Ag13—Ag12	109.7 (6)	F10—C34—F11	108.0 (16)
O27—Ag13—Ag12	148.1 (5)	F12—C34—F11	107.7 (16)
C18—Ag13—Ag14	48.5 (7)	F10—C34—C33	110 (3)
O2^ii—Ag13—Ag14	111.4 (6)	F12—C34—C33	113 (3)
O26—Ag13—Ag14	137.6 (5)	F11—C34—C33	109 (3)
O27—Ag13—Ag14	64.0 (5)	C35—O9—Ag3	124.8 (19)
Ag12—Ag13—Ag14	92.19 (8)	C35—O10—Ag14^i	127.6 (18)
C18—Ag13—Ag1^ii	70.6 (7)	O9—C35—O10	128 (3)
O2^ii—Ag13—Ag1^ii	77.9 (6)	O9—C35—C36	115 (2)
O26—Ag13—Ag1^ii	160.4 (5)	O10—C35—C36	117 (2)
O27—Ag13—Ag1^ii	117.0 (5)	F13—C36—F14	108.7 (14)
Ag12—Ag13—Ag1^ii	61.53 (7)	F13—C36—F15	108.0 (15)
Ag14—Ag13—Ag1^ii	62.00 (7)	F14—C36—F15	107.4 (15)
C18—Ag14—O10^ii	161.0 (9)	F13—C36—C35	115 (2)
C18—Ag14—O28	93.3 (10)	F14—C36—C35	110 (2)
O10^ii—Ag14—O28	93.0 (9)	F15—C36—C35	107 (2)
C18—Ag14—Ag13	49.0 (6)	C37—O11—Ag8	128 (2)
O10^ii—Ag14—Ag13	112.0 (7)	C37—O12—Ag9	126 (2)
O28—Ag14—Ag13	107.3 (5)	O11—C37—O12	128 (3)
C18—Ag14—Ag2^ii	52.7 (6)	O11—C37—C38	116 (2)
O10^ii—Ag14—Ag2^ii	138.2 (5)	O12—C37—C38	116 (2)
O28—Ag14—Ag2^ii	114.9 (7)	F17—C38—F18	109.3 (15)
Ag13—Ag14—Ag2^ii	89.65 (8)	F17—C38—F16	108.8 (15)
C18—Ag14—Ag3^ii	109.5 (7)	F18—C38—F16	108.2 (15)
O10^ii—Ag14—Ag3^ii	78.6 (5)	F17—C38—C37	109.9 (19)
O28—Ag14—Ag3^ii	133.2 (5)	F18—C38—C37	114 (2)
Ag13—Ag14—Ag3^ii	118.58 (10)	F16—C38—C37	106.6 (19)
Ag2^ii—Ag14—Ag3^ii	59.60 (7)	C39—O13—Ag8	127.7 (19)
C18—Ag14—Ag1^ii	70.9 (7)	C39—O14—Ag9	124 (2)
O10^ii—Ag14—Ag1^ii	101.9 (6)	O14—C39—O13	130 (3)
O28—Ag14—Ag1^ii	164.2 (6)	O14—C39—C40	114 (3)
Ag13—Ag14—Ag1^ii	62.24 (7)	O13—C39—C40	115 (2)
Ag2^ii—Ag14—Ag1^ii	55.96 (6)	F21—C40—F19	108.6 (15)
Ag3^ii—Ag14—Ag1^ii	56.44 (7)	F21—C40—F20	108.2 (15)
C2—C1—Ag1	163 (2)	F19—C40—F20	107.2 (14)
C2—C1—Ag3	102 (2)	F21—C40—C39	109 (2)
Ag1—C1—Ag3	81.6 (9)	F19—C40—C39	112 (2)
C2—C1—Ag2	118.8 (18)	F20—C40—C39	112 (2)
Ag1—C1—Ag2	77.9 (8)	C41—O15—Ag5	125.8 (17)
Ag3—C1—Ag2	81.6 (9)	C41—O16—Ag10	126.4 (19)
C2—C1—Ag4	84.8 (17)	O15—C41—O16	131 (3)
Ag1—C1—Ag4	79.1 (8)	O15—C41—C42	114 (2)
Ag3—C1—Ag4	118.5 (11)	O16—C41—C42	115 (2)
Ag2—C1—Ag4	146.6 (13)	F24—C42—F22	108.0 (14)
C1—C2—C3	175 (2)	F24—C42—F23	108.1 (14)
C1—C2—Ag4	65.9 (15)	F22—C42—F23	107.3 (14)
C3—C2—Ag4	109.4 (16)	F24—C42—C41	110.5 (18)
C4—C3—C2	112 (2)	F22—C42—C41	113.4 (18)
C4—C3—C6	123 (2)	F23—C42—C41	109.4 (19)
C2—C3—C6	124 (2)	C43—O17—Ag6	121 (2)
C5—C4—C3	174 (3)	C43—O18—Ag7	123.9 (18)
C5—C4—Ag6	70.1 (15)	O17—C43—O18	132 (3)
C3—C4—Ag6	114.3 (18)	O17—C43—C44	115 (2)
C4—C5—Ag5	135 (2)	O18—C43—C44	113 (2)
C4—C5—Ag7	133.1 (19)	F26—C44—F25	109.0 (14)
Ag5—C5—Ag7	84.9 (11)	F26—C44—F27	107.7 (14)
C4—C5—Ag8	113.2 (18)	F25—C44—F27	107.7 (14)
Ag5—C5—Ag8	84.2 (10)	F26—C44—C43	111.1 (19)
Ag7—C5—Ag8	90.8 (12)	F25—C44—C43	107.0 (19)
C4—C5—Ag6	79.7 (17)	F27—C44—C43	114.1 (19)
Ag5—C5—Ag6	84.7 (8)	C45—O19—Ag7	118.4 (19)
Ag7—C5—Ag6	81.3 (8)	C45—O20—Ag11	117.4 (17)
Ag8—C5—Ag6	166.9 (14)	O19—C45—O20	132 (2)
C13—C6—C3	121 (3)	O19—C45—C46	116 (2)
C13—C6—C7	121 (3)	O20—C45—C46	111.6 (19)
C3—C6—C7	118 (2)	F29—C46—F28	109.5 (14)
C8—C7—C6	118 (3)	F29—C46—F30	108.5 (14)
C8—C7—H7A	107.8	F28—C46—F30	108.3 (14)
C6—C7—H7A	107.8	F29—C46—C45	111.4 (18)
C8—C7—H7B	107.8	F28—C46—C45	109.8 (18)
C6—C7—H7B	107.8	F30—C46—C45	109.3 (18)
Ag1—C1—C2—Ag4	−17 (8)	Ag12^i—O4—C29—O3	16 (6)
Ag3—C1—C2—Ag4	−118.1 (12)	Ag12^i—O4—C29—C30	−171.5 (16)
Ag2—C1—C2—Ag4	155 (2)	O3—C29—C30—F6	63 (4)
Ag4—C2—C3—C4	37 (3)	O4—C29—C30—F6	−111 (3)
Ag4—C2—C3—C6	−142 (2)	O3—C29—C30—F5	−176 (3)
C2—C3—C4—Ag6	74 (2)	O4—C29—C30—F5	9 (3)
C6—C3—C4—Ag6	−108 (2)	O3—C29—C30—F4	−56 (4)
Ag6—C4—C5—Ag5	−72 (2)	O4—C29—C30—F4	130 (3)
Ag6—C4—C5—Ag7	68 (2)	Ag12^i—O6—C31—O5	−3 (4)
Ag6—C4—C5—Ag8	−177.4 (16)	Ag12^i—O6—C31—C32	174.7 (14)
C4—C3—C6—C13	172 (3)	Ag2—O5—C31—O6	−5 (4)
C2—C3—C6—C13	−10 (4)	Ag2—O5—C31—C32	176.6 (13)
C4—C3—C6—C7	−4 (4)	O6—C31—C32—F8	−62 (3)
C2—C3—C6—C7	174 (3)	O5—C31—C32—F8	116 (2)
C13—C6—C7—C8	−37 (4)	O6—C31—C32—F9	57 (3)
C3—C6—C7—C8	140 (3)	O5—C31—C32—F9	−125 (2)
C6—C7—C8—C9	−70 (4)	O6—C31—C32—F7	177 (2)
C7—C8—C9—C10	58 (5)	O5—C31—C32—F7	−5 (3)
C8—C9—C10—C11	47 (5)	Ag2—O7—C33—O8	6 (5)
C9—C10—C11—C12	−104 (5)	Ag2—O7—C33—C34	−163 (2)
C10—C11—C12—C13	69 (5)	Ag3—O8—C33—O7	−39 (5)
C3—C6—C13—C12	−80 (4)	Ag3—O8—C33—C34	131 (3)
C7—C6—C13—C12	97 (4)	O7—C33—C34—F10	−7 (4)
C11—C12—C13—C6	−65 (5)	O8—C33—C34—F10	−179 (3)
Ag10—C14—C15—Ag9	−49 (3)	O7—C33—C34—F12	−130 (3)
Ag7—C14—C15—Ag9	129 (2)	O8—C33—C34—F12	59 (3)
Ag11—C14—C15—Ag9	−141.4 (11)	O7—C33—C34—F11	111 (3)
Ag9—C15—C16—C19	−94 (3)	O8—C33—C34—F11	−60 (3)
Ag9—C15—C16—C17	88 (2)	Ag3—O9—C35—O10	−2 (5)
C19—C16—C17—C18	−175 (9)	Ag3—O9—C35—C36	−179.3 (18)
C15—C16—C17—C18	3 (11)	Ag14^i—O10—C35—O9	−10 (5)
C16—C17—C18—Ag14	83 (10)	Ag14^i—O10—C35—C36	166.5 (18)
C16—C17—C18—Ag13	−30 (12)	O9—C35—C36—F13	−9 (4)
C16—C17—C18—Ag12	−111 (10)	O10—C35—C36—F13	174 (3)
C16—C17—C18—Ag2^ii	168 (9)	O9—C35—C36—F14	−132 (3)
C15—C16—C19—C20	174 (3)	O10—C35—C36—F14	50 (3)
C17—C16—C19—C20	−8 (5)	O9—C35—C36—F15	111 (3)
C15—C16—C19—C26	3 (4)	O10—C35—C36—F15	−66 (3)
C17—C16—C19—C26	−179 (3)	Ag8—O11—C37—O12	−14 (5)
C16—C19—C20—C21	145 (3)	Ag8—O11—C37—C38	168.3 (16)
C26—C19—C20—C21	−45 (4)	Ag9—O12—C37—O11	−8 (5)
C19—C20—C21—C22	−55 (4)	Ag9—O12—C37—C38	169.5 (15)
C20—C21—C22—C23	55 (6)	O11—C37—C38—F17	47 (3)
C21—C22—C23—C24	43 (7)	O12—C37—C38—F17	−131 (3)
C22—C23—C24—C25	−100 (6)	O11—C37—C38—F18	170 (2)
C23—C24—C25—C26	67 (6)	O12—C37—C38—F18	−8 (3)
C24—C25—C26—C19	−62 (4)	O11—C37—C38—F16	−71 (3)
C16—C19—C26—C25	−81 (4)	O12—C37—C38—F16	112 (3)
C20—C19—C26—C25	107 (4)	Ag9—O14—C39—O13	14 (5)
C48—S1—O21—Ag6	31 (2)	Ag9—O14—C39—C40	−171.4 (18)
C47—S1—O21—Ag6	−78.3 (19)	Ag8—O13—C39—O14	1 (6)
C48—S1—O21—Ag3	−112.7 (16)	Ag8—O13—C39—C40	−173.2 (19)
C47—S1—O21—Ag3	138.1 (15)	O14—C39—C40—F21	98 (3)
C49—S2—O22—Ag4	−14 (2)	O13—C39—C40—F21	−87 (3)
C50—S2—O22—Ag4	90 (3)	O14—C39—C40—F19	−142 (3)
C49—S2—O22—Ag5	118.3 (16)	O13—C39—C40—F19	33 (4)
C50—S2—O22—Ag5	−138 (2)	O14—C39—C40—F20	−22 (4)
C52—S3—O23—Ag4	−76 (2)	O13—C39—C40—F20	154 (3)
C51—S3—O23—Ag4	31 (2)	Ag5—O15—C41—O16	−14 (5)
C53—S4—O24—Ag6	101 (2)	Ag5—O15—C41—C42	174.4 (16)
C54—S4—O24—Ag6	−154 (2)	Ag10—O16—C41—O15	0 (5)
C53—S4—O24—Ag5	−29 (3)	Ag10—O16—C41—C42	171.4 (17)
C54—S4—O24—Ag5	76 (2)	O15—C41—C42—F24	−47 (3)
C55—S5—O25—Ag9	−70.3 (16)	O16—C41—C42—F24	140 (3)
C56—S5—O25—Ag9	31.7 (16)	O15—C41—C42—F22	−169 (2)
C58—S6—O26—Ag13	−68 (2)	O16—C41—C42—F22	19 (3)
C57—S6—O26—Ag13	36 (2)	O15—C41—C42—F23	72 (3)
C58—S6—O26—Ag10	114.7 (15)	O16—C41—C42—F23	−101 (3)
C57—S6—O26—Ag10	−142.1 (17)	Ag6—O17—C43—O18	17 (5)
C60—S7—O27—Ag11	−39 (2)	Ag6—O17—C43—C44	−158.4 (17)
C59—S7—O27—Ag11	62 (2)	Ag7—O18—C43—O17	6 (5)
C60—S7—O27—Ag13	108.4 (19)	Ag7—O18—C43—C44	−177.7 (14)
C59—S7—O27—Ag13	−150.3 (18)	O17—C43—C44—F26	43 (3)
C62—S8—O28—Ag11	47 (3)	O18—C43—C44—F26	−133 (2)
C61—S8—O28—Ag11	−57 (3)	O17—C43—C44—F25	−75 (3)
C62—S8—O28—Ag14	−163 (2)	O18—C43—C44—F25	108 (2)
C61—S8—O28—Ag14	93 (2)	O17—C43—C44—F27	165 (2)
Ag13^i—O2—C27—O1	11 (5)	O18—C43—C44—F27	−11 (3)
Ag13^i—O2—C27—C28	−158.2 (17)	Ag7—O19—C45—O20	37 (5)
Ag1—O1—C27—O2	30 (5)	Ag7—O19—C45—C46	−149.5 (16)
Ag1—O1—C27—C28	−160.0 (16)	Ag11—O20—C45—O19	−4 (5)
O2—C27—C28—F1	−5 (3)	Ag11—O20—C45—C46	−177.1 (14)
O1—C27—C28—F1	−177 (2)	O19—C45—C46—F29	150 (3)
O2—C27—C28—F3	−125 (3)	O20—C45—C46—F29	−36 (3)
O1—C27—C28—F3	63 (3)	O19—C45—C46—F28	28 (3)
O2—C27—C28—F2	115 (3)	O20—C45—C46—F28	−157 (2)
O1—C27—C28—F2	−57 (3)	O19—C45—C46—F30	−90 (3)
Ag1—O3—C29—O4	−36 (6)	O20—C45—C46—F30	84 (3)
Ag1—O3—C29—C30	151.5 (18)

Symmetry codes: (i) x−1, y−1, z−1; (ii) x+1, y+1, z+1.

(V)

Crystal data

7(Ag^+)·(C10H8^2^−)·5(C2F3O2^−)·2(H2O)	Z = 4
Mr = 1484.39	F(000) = 2768
Monoclinic, C2/c	Dx = 2.864 Mg m^−3
a = 23.394 (2) Å	Mo Kα radiation, λ = 0.71073 Å
b = 13.9512 (12) Å	µ = 4.03 mm^−1
c = 10.7920 (9) Å	T = 173 K
β = 102.214 (1)°	Block, colourless
V = 3442.5 (5) Å^3	0.50 × 0.50 × 0.40 mm

Data collection

Bruker APEX-II CCD diffractometer	2897 reflections with I > 2σ(I)
φ and ω scan	Rint = 0.087
Absorption correction: multi-scan SADABS (Bruker, 2003)	θmax = 25.3°, θmin = 1.7°
Tmin = 0.238, Tmax = 0.295	h = −28→28
30572 measured reflections	k = −16→16
3109 independent reflections	l = −12→12

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.047	Hydrogen site location: mixed
wR(F^2) = 0.125	H-atom parameters constrained
S = 1.07	w = 1/[σ^2(Fo^2) + (0.0768P)^2 + 33.6886P] where P = (Fo^2 + 2Fc^2)/3
3109 reflections	(Δ/σ)max = 0.001
264 parameters	Δρmax = 1.26 e Å^−3
78 restraints	Δρmin = −1.77 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.37163 (2)	0.07147 (3)	0.68599 (5)	0.03003 (18)
Ag2	0.32516 (2)	0.20816 (4)	0.50198 (5)	0.03480 (19)
Ag3	0.42235 (2)	0.07770 (3)	0.47735 (5)	0.02865 (18)
Ag4	0.49357 (9)	0.11845 (6)	0.77319 (16)	0.0284 (4)	0.5
C1	0.4190 (3)	0.1923 (4)	0.6088 (6)	0.0232 (12)
C2	0.4473 (2)	0.2606 (4)	0.6565 (5)	0.0192 (11)
C3	0.4754 (2)	0.3485 (4)	0.7045 (5)	0.0191 (11)
C4	0.4452 (3)	0.4398 (5)	0.6504 (8)	0.0366 (16)
H4A	0.4380	0.4373	0.5566	0.044*
H4B	0.4069	0.4447	0.6749	0.044*
C5	0.4808 (6)	0.5258 (7)	0.6961 (14)	0.095 (4)
H5A	0.5021	0.5434	0.6293	0.114*
H5B	0.4530	0.5786	0.7006	0.114*
O1	0.2769 (2)	0.0418 (4)	0.6968 (5)	0.0379 (12)
O2	0.23691 (18)	0.1606 (3)	0.5673 (4)	0.0264 (9)
C6	0.2363 (3)	0.0940 (4)	0.6448 (6)	0.0235 (12)
C7	0.1773 (3)	0.0700 (4)	0.6810 (6)	0.0347 (16)
F1	0.13862 (18)	0.1399 (3)	0.6533 (5)	0.0562 (13)
F2	0.1845 (2)	0.0524 (5)	0.8030 (5)	0.0684 (16)
F3	0.1536 (2)	−0.0062 (3)	0.6191 (5)	0.0598 (13)
O3	0.3679 (2)	−0.0952 (3)	0.6017 (4)	0.0337 (11)
O4	0.3928 (2)	−0.0740 (3)	0.4154 (4)	0.0306 (10)
C8	0.3726 (3)	−0.1204 (5)	0.4959 (6)	0.0277 (14)
C9	0.3527 (3)	−0.2236 (5)	0.4548 (6)	0.049 (2)
F4	0.3091 (4)	−0.2224 (5)	0.3602 (8)	0.159 (5)
F5	0.3406 (3)	−0.2758 (4)	0.5456 (5)	0.0707 (17)
F6	0.3951 (4)	−0.2703 (5)	0.4163 (9)	0.137 (4)
O5	0.4813 (2)	0.0444 (3)	0.3346 (4)	0.0289 (10)
C10	0.5000	0.0852 (6)	0.2500	0.0236 (18)
C11	0.5000	0.1974 (6)	0.2500	0.046 (3)
F7	0.5495 (3)	0.2353 (7)	0.2783 (12)	0.061 (3)	0.5
F8	0.4800 (4)	0.2240 (6)	0.1214 (6)	0.050 (2)	0.5
F9	0.4600 (4)	0.2350 (7)	0.2986 (9)	0.048 (3)	0.5
O1W	0.3089 (3)	0.1396 (4)	0.2956 (6)	0.0619 (19)
H1W	0.2990	0.0812	0.2993	0.093*
H2W	0.3400	0.1434	0.2671	0.093*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0342 (3)	0.0305 (3)	0.0279 (3)	0.00341 (19)	0.0121 (2)	0.01018 (18)
Ag2	0.0205 (3)	0.0332 (3)	0.0470 (4)	0.00385 (19)	−0.0012 (2)	0.0172 (2)
Ag3	0.0362 (3)	0.0239 (3)	0.0296 (3)	−0.00335 (18)	0.0155 (2)	−0.00848 (18)
Ag4	0.0236 (9)	0.0121 (4)	0.0417 (13)	−0.0021 (4)	−0.0106 (6)	0.0028 (4)
C1	0.026 (3)	0.015 (3)	0.026 (3)	0.004 (2)	−0.001 (2)	−0.001 (2)
C2	0.019 (3)	0.017 (3)	0.020 (3)	0.008 (2)	0.001 (2)	0.002 (2)
C3	0.024 (3)	0.012 (3)	0.022 (3)	0.001 (2)	0.006 (2)	0.000 (2)
C4	0.038 (4)	0.017 (3)	0.050 (4)	0.011 (3)	−0.004 (3)	0.004 (3)
C5	0.105 (7)	0.030 (4)	0.122 (8)	0.005 (5)	−0.042 (6)	0.010 (5)
O1	0.027 (2)	0.033 (3)	0.054 (3)	0.007 (2)	0.008 (2)	0.024 (2)
O2	0.023 (2)	0.024 (2)	0.033 (2)	0.0064 (17)	0.0060 (17)	0.0121 (18)
C6	0.022 (3)	0.021 (3)	0.027 (3)	0.000 (2)	0.006 (2)	0.002 (2)
C7	0.028 (3)	0.035 (4)	0.043 (4)	0.001 (3)	0.012 (3)	0.011 (3)
F1	0.031 (2)	0.051 (3)	0.094 (4)	0.015 (2)	0.031 (2)	0.023 (3)
F2	0.051 (3)	0.106 (4)	0.055 (3)	−0.001 (3)	0.025 (2)	0.030 (3)
F3	0.041 (3)	0.045 (3)	0.093 (4)	−0.014 (2)	0.013 (2)	−0.007 (3)
O3	0.057 (3)	0.021 (2)	0.028 (2)	−0.003 (2)	0.020 (2)	−0.0012 (19)
O4	0.049 (3)	0.021 (2)	0.023 (2)	−0.0114 (19)	0.010 (2)	−0.0026 (16)
C8	0.034 (3)	0.022 (3)	0.027 (3)	−0.006 (3)	0.007 (3)	−0.001 (2)
C9	0.089 (7)	0.034 (4)	0.026 (4)	−0.030 (4)	0.017 (4)	−0.007 (3)
F4	0.233 (10)	0.070 (5)	0.121 (6)	−0.096 (6)	−0.085 (7)	0.025 (4)
F5	0.118 (5)	0.038 (3)	0.062 (3)	−0.035 (3)	0.034 (3)	0.005 (2)
F6	0.237 (10)	0.047 (4)	0.174 (8)	−0.040 (5)	0.150 (8)	−0.046 (4)
O5	0.035 (2)	0.022 (2)	0.036 (2)	0.0009 (19)	0.021 (2)	0.0015 (19)
C10	0.023 (4)	0.013 (4)	0.038 (5)	0.000	0.015 (4)	0.000
C11	0.047 (7)	0.018 (5)	0.079 (9)	0.000	0.028 (6)	0.000
F7	0.052 (5)	0.027 (4)	0.093 (7)	−0.011 (4)	−0.011 (6)	−0.001 (6)
F8	0.074 (6)	0.024 (4)	0.056 (5)	0.000 (4)	0.026 (5)	0.016 (4)
F9	0.071 (6)	0.027 (4)	0.056 (5)	0.021 (4)	0.036 (5)	0.002 (4)
O1W	0.106 (5)	0.045 (3)	0.047 (3)	−0.030 (3)	0.045 (4)	−0.026 (3)

Geometric parameters (Å, º)

Ag1—C1	2.270 (6)	C5—C5^ii	1.31 (2)
Ag1—O1	2.282 (5)	C5—H5A	0.9900
Ag1—O4^i	2.420 (5)	C5—H5B	0.9900
Ag1—O3	2.491 (5)	O1—C6	1.234 (8)
Ag1—Ag3	2.7597 (7)	O2—C6	1.251 (7)
Ag1—Ag2	2.8015 (7)	O2—Ag2^iii	2.359 (4)
Ag1—Ag4	2.884 (2)	C6—C7	1.548 (8)
Ag1—Ag4^ii	3.1592 (19)	C7—F2	1.315 (7)
Ag2—C1	2.264 (6)	C7—F3	1.315 (7)
Ag2—O2^iii	2.359 (4)	C7—F1	1.320 (6)
Ag2—O1W	2.379 (5)	O3—C8	1.222 (8)
Ag2—O2	2.412 (4)	O4—C8	1.254 (8)
Ag2—Ag3	2.9680 (7)	O4—Ag1^iv	2.420 (5)
Ag3—C1	2.150 (6)	C8—C9	1.549 (9)
Ag3—O4	2.281 (4)	C9—F4	1.282 (8)
Ag3—O5	2.321 (4)	C9—F5	1.299 (7)
Ag3—Ag4^ii	3.033 (2)	C9—F6	1.325 (8)
Ag3—Ag4	3.323 (2)	O5—C10	1.233 (6)
Ag4—Ag4^ii	0.636 (2)	O5—Ag4^iv	2.401 (5)
Ag4—O5^i	2.401 (5)	C10—O5^v	1.233 (6)
Ag4—C1^ii	2.401 (6)	C10—C11	1.566 (11)
Ag4—C1	2.438 (6)	C11—F7^v	1.250 (7)
Ag4—C2^ii	2.445 (5)	C11—F7	1.250 (7)
Ag4—C2	2.473 (6)	C11—F9^v	1.278 (7)
Ag4—Ag3^ii	3.033 (2)	C11—F9	1.278 (7)
Ag4—Ag1^ii	3.1592 (19)	C11—F8^v	1.417 (7)
C1—C2	1.212 (9)	C11—F8	1.417 (7)
C1—Ag4^ii	2.401 (6)	F7—F9^v	0.812 (12)
C2—C3	1.435 (8)	F7—F8^v	1.412 (14)
C2—Ag4^ii	2.445 (5)	F8—F7^v	1.412 (14)
C3—C3^ii	1.345 (12)	F8—F9^v	1.491 (13)
C3—C4	1.513 (8)	F9—F7^v	0.812 (12)
C4—C5	1.484 (13)	F9—F8^v	1.491 (13)
C4—H4A	0.9900	O1W—H1W	0.8503
C4—H4B	0.9900	O1W—H2W	0.8493
C1—Ag1—O1	135.09 (19)	C2—Ag4—Ag3	64.63 (14)
C1—Ag1—O4^i	110.76 (19)	Ag1—Ag4—Ag3	52.22 (4)
O1—Ag1—O4^i	86.65 (18)	Ag3^ii—Ag4—Ag3	156.91 (4)
C1—Ag1—O3	122.78 (18)	Ag1^ii—Ag4—Ag3	112.41 (3)
O1—Ag1—O3	83.65 (19)	C2—C1—Ag3	140.5 (5)
O4^i—Ag1—O3	111.76 (15)	C2—C1—Ag2	121.6 (4)
C1—Ag1—Ag3	49.45 (15)	Ag3—C1—Ag2	84.5 (2)
O1—Ag1—Ag3	129.58 (14)	C2—C1—Ag1	134.0 (5)
O4^i—Ag1—Ag3	143.50 (13)	Ag3—C1—Ag1	77.22 (19)
O3—Ag1—Ag3	73.71 (10)	Ag2—C1—Ag1	76.33 (19)
C1—Ag1—Ag2	51.74 (15)	C2—C1—Ag4^ii	77.6 (4)
O1—Ag1—Ag2	85.65 (11)	Ag3—C1—Ag4^ii	83.38 (19)
O4^i—Ag1—Ag2	132.86 (10)	Ag2—C1—Ag4^ii	159.6 (3)
O3—Ag1—Ag2	113.45 (11)	Ag1—C1—Ag4^ii	85.07 (19)
Ag3—Ag1—Ag2	64.505 (19)	C2—C1—Ag4	77.3 (4)
C1—Ag1—Ag4	54.91 (15)	Ag3—C1—Ag4	92.6 (2)
O1—Ag1—Ag4	158.29 (14)	Ag2—C1—Ag4	151.6 (3)
O4^i—Ag1—Ag4	71.85 (13)	Ag1—C1—Ag4	75.46 (18)
O3—Ag1—Ag4	106.70 (13)	Ag4^ii—C1—Ag4	15.09 (6)
Ag3—Ag1—Ag4	72.11 (3)	C1—C2—C3	173.2 (6)
Ag2—Ag1—Ag4	106.58 (3)	C1—C2—Ag4^ii	73.5 (4)
C1—Ag1—Ag4^ii	49.22 (15)	C3—C2—Ag4^ii	113.2 (4)
O1—Ag1—Ag4^ii	169.20 (14)	C1—C2—Ag4	74.1 (4)
O4^i—Ag1—Ag4^ii	82.65 (13)	C3—C2—Ag4	112.5 (4)
O3—Ag1—Ag4^ii	101.64 (13)	Ag4^ii—C2—Ag4	14.85 (6)
Ag3—Ag1—Ag4^ii	61.21 (3)	C3^ii—C3—C2	121.3 (3)
Ag2—Ag1—Ag4^ii	100.59 (3)	C3^ii—C3—C4	122.6 (4)
Ag4—Ag1—Ag4^ii	10.91 (5)	C2—C3—C4	116.0 (5)
C1—Ag2—O2^iii	134.67 (18)	C5—C4—C3	111.7 (7)
C1—Ag2—O1W	112.5 (2)	C5—C4—H4A	109.3
O2^iii—Ag2—O1W	92.8 (2)	C3—C4—H4A	109.3
C1—Ag2—O2	128.44 (19)	C5—C4—H4B	109.3
O2^iii—Ag2—O2	78.39 (16)	C3—C4—H4B	109.3
O1W—Ag2—O2	100.7 (2)	H4A—C4—H4B	107.9
C1—Ag2—Ag1	51.93 (15)	C5^ii—C5—C4	121.7 (9)
O2^iii—Ag2—Ag1	150.92 (11)	C5^ii—C5—H5A	106.9
O1W—Ag2—Ag1	110.54 (17)	C4—C5—H5A	106.9
O2—Ag2—Ag1	80.39 (10)	C5^ii—C5—H5B	106.9
C1—Ag2—Ag3	46.15 (15)	C4—C5—H5B	106.9
O2^iii—Ag2—Ag3	151.61 (11)	H5A—C5—H5B	106.7
O1W—Ag2—Ag3	69.10 (19)	C6—O1—Ag1	122.2 (4)
O2—Ag2—Ag3	125.22 (10)	C6—O2—Ag2^iii	134.0 (4)
Ag1—Ag2—Ag3	57.066 (17)	C6—O2—Ag2	122.1 (4)
C1—Ag3—O4	146.3 (2)	Ag2^iii—O2—Ag2	101.61 (16)
C1—Ag3—O5	134.2 (2)	O1—C6—O2	128.7 (6)
O4—Ag3—O5	78.78 (17)	O1—C6—C7	113.5 (5)
C1—Ag3—Ag1	53.33 (17)	O2—C6—C7	117.8 (5)
O4—Ag3—Ag1	93.11 (12)	F2—C7—F3	107.9 (5)
O5—Ag3—Ag1	162.44 (12)	F2—C7—F1	107.5 (5)
C1—Ag3—Ag2	49.39 (16)	F3—C7—F1	106.7 (5)
O4—Ag3—Ag2	113.87 (13)	F2—C7—C6	111.2 (5)
O5—Ag3—Ag2	139.11 (12)	F3—C7—C6	110.4 (5)
Ag1—Ag3—Ag2	58.429 (17)	F1—C7—C6	112.8 (5)
C1—Ag3—Ag4^ii	51.85 (16)	C8—O3—Ag1	127.4 (4)
O4—Ag3—Ag4^ii	122.23 (12)	C8—O4—Ag3	114.3 (4)
O5—Ag3—Ag4^ii	105.18 (12)	C8—O4—Ag1^iv	133.7 (4)
Ag1—Ag3—Ag4^ii	65.90 (3)	Ag3—O4—Ag1^iv	105.69 (17)
Ag2—Ag3—Ag4^ii	99.83 (3)	O3—C8—O4	128.4 (6)
C1—Ag3—Ag4	47.12 (15)	O3—C8—C9	117.0 (6)
O4—Ag3—Ag4	119.97 (12)	O4—C8—C9	114.6 (5)
O5—Ag3—Ag4	115.12 (12)	F4—C9—F5	110.1 (6)
Ag1—Ag3—Ag4	55.68 (3)	F4—C9—F6	106.2 (7)
Ag2—Ag3—Ag4	92.68 (3)	F5—C9—F6	105.0 (6)
Ag4^ii—Ag3—Ag4	10.24 (5)	F4—C9—C8	110.8 (6)
Ag4^ii—Ag4—O5^i	108.75 (11)	F5—C9—C8	113.9 (5)
Ag4^ii—Ag4—C1^ii	85.7 (4)	F6—C9—C8	110.4 (6)
O5^i—Ag4—C1^ii	113.45 (19)	C10—O5—Ag3	138.9 (4)
Ag4^ii—Ag4—C1	79.2 (4)	C10—O5—Ag4^iv	98.7 (4)
O5^i—Ag4—C1	119.5 (2)	Ag3—O5—Ag4^iv	119.69 (19)
C1^ii—Ag4—C1	127.1 (3)	O5^v—C10—O5	125.0 (8)
Ag4^ii—Ag4—C2^ii	85.0 (3)	O5^v—C10—C11	117.5 (4)
O5^i—Ag4—C2^ii	140.8 (2)	O5—C10—C11	117.5 (4)
C1^ii—Ag4—C2^ii	28.9 (2)	F7^v—C11—F7	130.1 (12)
C1—Ag4—C2^ii	98.85 (19)	F7^v—C11—F9^v	116.6 (7)
Ag4^ii—Ag4—C2	80.1 (3)	F7—C11—F9^v	37.5 (5)
O5^i—Ag4—C2	146.6 (2)	F7^v—C11—F9	37.5 (5)
C1^ii—Ag4—C2	99.08 (19)	F7—C11—F9	116.6 (7)
C1—Ag4—C2	28.6 (2)	F9^v—C11—F9	131.6 (11)
C2^ii—Ag4—C2	70.4 (3)	F7^v—C11—F8^v	103.0 (6)
Ag4^ii—Ag4—Ag1	110.1 (4)	F7—C11—F8^v	63.5 (6)
O5^i—Ag4—Ag1	72.97 (12)	F9^v—C11—F8^v	100.2 (6)
C1^ii—Ag4—Ag1	160.66 (15)	F9—C11—F8^v	67.0 (6)
C1—Ag4—Ag1	49.63 (15)	F7^v—C11—F8	63.5 (6)
C2^ii—Ag4—Ag1	137.83 (15)	F7—C11—F8	103.0 (6)
C2—Ag4—Ag1	73.74 (15)	F9^v—C11—F8	67.0 (6)
Ag4^ii—Ag4—Ag3^ii	111.9 (4)	F9—C11—F8	100.2 (6)
O5^i—Ag4—Ag3^ii	70.77 (12)	F8^v—C11—F8	149.7 (9)
C1^ii—Ag4—Ag3^ii	44.77 (14)	F7^v—C11—C10	115.0 (6)
C1—Ag4—Ag3^ii	162.75 (14)	F7—C11—C10	115.0 (6)
C2^ii—Ag4—Ag3^ii	70.04 (14)	F9^v—C11—C10	114.2 (6)
C2—Ag4—Ag3^ii	137.24 (14)	F9—C11—C10	114.2 (6)
Ag1—Ag4—Ag3^ii	131.15 (4)	F8^v—C11—C10	105.1 (5)
Ag4^ii—Ag4—Ag1^ii	59.0 (4)	F8—C11—C10	105.2 (5)
O5^i—Ag4—Ag1^ii	86.53 (12)	F9^v—F7—C11	73.1 (8)
C1^ii—Ag4—Ag1^ii	45.71 (15)	F9^v—F7—F8^v	135.2 (12)
C1—Ag4—Ag1^ii	136.79 (15)	C11—F7—F8^v	64.0 (5)
C2^ii—Ag4—Ag1^ii	69.06 (15)	F7^v—F8—C11	52.5 (4)
C2—Ag4—Ag1^ii	123.63 (14)	F7^v—F8—F9^v	95.6 (6)
Ag1—Ag4—Ag1^ii	152.58 (4)	C11—F8—F9^v	52.0 (4)
Ag3^ii—Ag4—Ag1^ii	52.88 (4)	F7^v—F9—C11	69.5 (8)
Ag4^ii—Ag4—Ag3	57.9 (4)	F7^v—F9—F8^v	127.8 (12)
O5^i—Ag4—Ag3	92.20 (12)	C11—F9—F8^v	61.0 (5)
C1^ii—Ag4—Ag3	141.31 (15)	Ag2—O1W—H1W	109.4
C1—Ag4—Ag3	40.27 (14)	Ag2—O1W—H2W	109.5
C2^ii—Ag4—Ag3	124.94 (14)	H1W—O1W—H2W	109.8
Ag3—C1—C2—Ag4^ii	−63.0 (6)	O5^v—C10—C11—F7^v	110.0 (7)
Ag2—C1—C2—Ag4^ii	172.4 (5)	O5—C10—C11—F7^v	−70.0 (7)
Ag1—C1—C2—Ag4^ii	70.4 (5)	O5^v—C10—C11—F7	−70.0 (7)
Ag4—C1—C2—Ag4^ii	15.46 (6)	O5—C10—C11—F7	110.0 (7)
Ag3—C1—C2—Ag4	−78.5 (6)	O5^v—C10—C11—F9^v	−28.6 (6)
Ag2—C1—C2—Ag4	156.9 (5)	O5—C10—C11—F9^v	151.4 (6)
Ag1—C1—C2—Ag4	55.0 (5)	O5^v—C10—C11—F9	151.4 (6)
Ag4^ii—C1—C2—Ag4	−15.46 (6)	O5—C10—C11—F9	−28.6 (6)
Ag4^ii—C2—C3—C3^ii	−10.5 (9)	O5^v—C10—C11—F8^v	−137.5 (5)
Ag4—C2—C3—C3^ii	5.6 (9)	O5—C10—C11—F8^v	42.5 (5)
Ag4^ii—C2—C3—C4	171.7 (5)	O5^v—C10—C11—F8	42.5 (5)
Ag4—C2—C3—C4	−172.2 (5)	O5—C10—C11—F8	−137.5 (5)
C3^ii—C3—C4—C5	8.1 (13)	F7^v—C11—F7—F9^v	−82.2 (12)
C2—C3—C4—C5	−174.1 (9)	F9—C11—F7—F9^v	−124.6 (15)
C3—C4—C5—C5^ii	−25 (3)	F8^v—C11—F7—F9^v	−167.0 (15)
Ag1—O1—C6—O2	10.3 (10)	F8—C11—F7—F9^v	−16.0 (14)
Ag1—O1—C6—C7	−171.1 (4)	C10—C11—F7—F9^v	97.8 (12)
Ag2^iii—O2—C6—O1	−161.3 (5)	F7^v—C11—F7—F8^v	84.8 (5)
Ag2—O2—C6—O1	−1.9 (10)	F9^v—C11—F7—F8^v	167.0 (15)
Ag2^iii—O2—C6—C7	20.2 (9)	F9—C11—F7—F8^v	42.5 (7)
Ag2—O2—C6—C7	179.5 (4)	F8—C11—F7—F8^v	151.0 (9)
O1—C6—C7—F2	42.2 (8)	C10—C11—F7—F8^v	−95.2 (5)
O2—C6—C7—F2	−139.0 (6)	F7—C11—F8—F7^v	−128.5 (12)
O1—C6—C7—F3	−77.5 (7)	F9^v—C11—F8—F7^v	−139.0 (8)
O2—C6—C7—F3	101.3 (7)	F9—C11—F8—F7^v	−8.0 (9)
O1—C6—C7—F1	163.2 (6)	F8^v—C11—F8—F7^v	−69.3 (6)
O2—C6—C7—F1	−18.1 (8)	C10—C11—F8—F7^v	110.7 (6)
Ag1—O3—C8—O4	17.3 (11)	F7^v—C11—F8—F9^v	139.0 (8)
Ag1—O3—C8—C9	−164.3 (5)	F7—C11—F8—F9^v	10.5 (9)
Ag3—O4—C8—O3	−1.3 (10)	F9—C11—F8—F9^v	131.0 (11)
Ag1^iv—O4—C8—O3	−148.5 (6)	F8^v—C11—F8—F9^v	69.7 (6)
Ag3—O4—C8—C9	−179.7 (4)	C10—C11—F8—F9^v	−110.3 (6)
Ag1^iv—O4—C8—C9	33.1 (9)	F7—C11—F9—F7^v	122.0 (15)
O3—C8—C9—F4	116.0 (8)	F9^v—C11—F9—F7^v	80.0 (12)
O4—C8—C9—F4	−65.4 (9)	F8^v—C11—F9—F7^v	163.1 (15)
O3—C8—C9—F5	−8.8 (10)	F8—C11—F9—F7^v	11.8 (14)
O4—C8—C9—F5	169.8 (7)	C10—C11—F9—F7^v	−100.0 (12)
O3—C8—C9—F6	−126.7 (8)	F7^v—C11—F9—F8^v	−163.1 (15)
O4—C8—C9—F6	51.9 (9)	F7—C11—F9—F8^v	−41.0 (7)
Ag3—O5—C10—O5^v	−160.0 (6)	F9^v—C11—F9—F8^v	−83.1 (5)
Ag4^iv—O5—C10—O5^v	−0.60 (6)	F8—C11—F9—F8^v	−151.3 (9)
Ag3—O5—C10—C11	20.0 (6)	C10—C11—F9—F8^v	96.9 (5)
Ag4^iv—O5—C10—C11	179.40 (6)

Symmetry codes: (i) x, −y, z+1/2; (ii) −x+1, y, −z+3/2; (iii) −x+1/2, −y+1/2, −z+1; (iv) x, −y, z−1/2; (v) −x+1, y, −z+1/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W···O1^iv	0.85	2.05	2.786 (7)	144.8
O1W—H2W···O3^iv	0.85	2.13	2.808 (7)	136.0

Symmetry code: (iv) x, −y, z−1/2.

(VI)

Crystal data

9(Ag^+)·C10H8^2^−·9(C2F3O2^−)·C5H5N·2(C5H6N^+)	Z = 2
Mr = 2355.49	F(000) = 2224
Monoclinic, P21	Dx = 2.518 Mg m^−3
a = 8.9453 (9) Å	Mo Kα radiation, λ = 0.71073 Å
b = 24.902 (3) Å	µ = 2.93 mm^−1
c = 14.4248 (16) Å	T = 173 K
β = 105.016 (2)°	Block, yellow
V = 3103.5 (6) Å^3	0.50 × 0.50 × 0.40 mm

Data collection

Bruker APEX-II CCD diffractometer	10668 reflections with I > 2σ(I)
φ and ω scan	Rint = 0.077
Absorption correction: multi-scan SADABS (Bruker, 2003)	θmax = 25.3°, θmin = 1.7°
Tmin = 0.323, Tmax = 0.388	h = −10→10
68475 measured reflections	k = −29→29
11211 independent reflections	l = −17→17

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: mixed
R[F^2 > 2σ(F^2)] = 0.036	H-atom parameters constrained
wR(F^2) = 0.098	w = 1/[σ^2(Fo^2) + (0.0648P)^2 + 2.1022P] where P = (Fo^2 + 2Fc^2)/3
S = 1.03	(Δ/σ)max = 0.001
11211 reflections	Δρmax = 1.39 e Å^−3
873 parameters	Δρmin = −0.71 e Å^−3
283 restraints	Absolute structure: Refined as an inversion twin.
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.48 (4)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.26306 (8)	0.51006 (3)	0.29525 (5)	0.02586 (16)
Ag2	0.08014 (8)	0.41637 (3)	0.32873 (5)	0.02328 (16)
Ag3	0.32482 (8)	0.46660 (4)	0.48591 (5)	0.03095 (18)
Ag4	0.59817 (8)	0.47469 (3)	0.37339 (5)	0.02662 (17)
Ag5	0.31599 (9)	0.41789 (4)	0.17934 (5)	0.03128 (19)
Ag6	0.66712 (10)	0.43281 (3)	0.18543 (6)	0.03162 (19)
Ag7	0.88279 (9)	0.51015 (3)	0.30338 (6)	0.03278 (19)
Ag8	0.98831 (9)	0.46345 (3)	0.49325 (5)	0.02847 (18)
Ag9	0.7961 (3)	0.56467 (19)	0.56632 (13)	0.0576 (10)	0.699 (11)
N1	0.8037 (14)	0.6264 (5)	0.6766 (7)	0.037 (3)*	0.699 (11)
C29	0.7333 (16)	0.6171 (5)	0.7505 (9)	0.050 (5)*	0.699 (11)
H29	0.6752	0.5852	0.7508	0.060*	0.699 (11)
C30	0.748 (2)	0.6545 (6)	0.8239 (9)	0.071 (7)*	0.699 (11)
H30	0.6998	0.6481	0.8743	0.085*	0.699 (11)
C31	0.833 (2)	0.7012 (6)	0.8234 (10)	0.077 (7)*	0.699 (11)
H31	0.8430	0.7267	0.8736	0.093*	0.699 (11)
C32	0.9034 (19)	0.7105 (5)	0.7496 (11)	0.070 (6)*	0.699 (11)
H32	0.9615	0.7424	0.7493	0.084*	0.699 (11)
C33	0.8888 (16)	0.6731 (6)	0.6762 (9)	0.064 (6)*	0.699 (11)
H33	0.9369	0.6795	0.6257	0.076*	0.699 (11)
Ag9'	0.8395 (8)	0.5950 (4)	0.5745 (4)	0.057 (2)	0.301 (11)
N1'	0.857 (3)	0.6561 (10)	0.6927 (14)	0.038 (8)*	0.301 (11)
C29'	0.798 (3)	0.6385 (9)	0.7676 (17)	0.038 (9)*	0.301 (11)
H29'	0.7547	0.6036	0.7655	0.046*	0.301 (11)
C30'	0.804 (3)	0.6719 (11)	0.8455 (15)	0.032 (8)*	0.301 (11)
H30'	0.7633	0.6599	0.8967	0.038*	0.301 (11)
C31'	0.868 (4)	0.7230 (11)	0.8485 (18)	0.073 (16)*	0.301 (11)
H31'	0.8710	0.7458	0.9018	0.087*	0.301 (11)
C32'	0.926 (4)	0.7406 (9)	0.774 (2)	0.057 (12)*	0.301 (11)
H32'	0.9701	0.7755	0.7757	0.069*	0.301 (11)
C33'	0.921 (3)	0.7072 (11)	0.6957 (17)	0.038 (9)*	0.301 (11)
H33'	0.9615	0.7192	0.6445	0.046*	0.301 (11)
O1	0.0746 (8)	0.5761 (3)	0.3373 (5)	0.0266 (15)
O2	−0.0314 (11)	0.5810 (4)	0.4587 (7)	0.051 (2)
C11	0.0579 (12)	0.5957 (4)	0.4133 (7)	0.027 (2)
C12	0.1602 (12)	0.6451 (4)	0.4505 (7)	0.038 (3)
F1	0.1227 (12)	0.6687 (4)	0.5227 (6)	0.079 (3)
F2	0.3054 (8)	0.6311 (4)	0.4778 (7)	0.071 (3)
F3	0.1468 (13)	0.6816 (3)	0.3835 (5)	0.081 (3)
O3	0.4124 (9)	0.5863 (3)	0.2861 (6)	0.0349 (17)
O4	0.6178 (9)	0.5615 (3)	0.4048 (6)	0.0350 (17)
C13	0.5287 (12)	0.5947 (4)	0.3494 (8)	0.030 (2)
C14	0.5852 (11)	0.6548 (4)	0.3662 (7)	0.038 (3)
F4	0.6157 (10)	0.6668 (3)	0.4573 (5)	0.055 (2)
F5	0.4818 (9)	0.6877 (3)	0.3193 (7)	0.071 (3)
F6	0.7134 (9)	0.6615 (3)	0.3393 (6)	0.061 (2)
O5	0.0985 (9)	0.5370 (3)	0.1518 (5)	0.0328 (17)
O6	0.1723 (8)	0.4737 (3)	0.0632 (5)	0.0307 (15)
C15	0.0958 (11)	0.5129 (5)	0.0771 (7)	0.028 (2)
C16	−0.0235 (12)	0.5347 (4)	−0.0121 (8)	0.043 (3)
F7	−0.1569 (9)	0.5482 (4)	0.0039 (6)	0.072 (3)
F8	−0.0587 (11)	0.5009 (4)	−0.0842 (6)	0.087 (4)
F9	0.0313 (10)	0.5786 (4)	−0.0411 (8)	0.095 (4)
O7	0.1234 (9)	0.3402 (3)	0.4288 (5)	0.0319 (16)
O8	0.1889 (10)	0.3929 (3)	0.5593 (6)	0.0378 (18)
C17	0.1676 (12)	0.3491 (4)	0.5164 (8)	0.029 (2)
C18	0.2079 (13)	0.2984 (4)	0.5799 (8)	0.046 (3)
F10	0.1291 (16)	0.2565 (4)	0.5444 (8)	0.116 (6)
F11	0.1964 (18)	0.3064 (4)	0.6669 (6)	0.122 (6)
F12	0.3542 (12)	0.2865 (5)	0.5896 (11)	0.134 (6)
O9	0.3176 (12)	0.5258 (4)	0.5968 (7)	0.051 (2)
O10	0.0871 (10)	0.5094 (4)	0.6282 (6)	0.0443 (19)
C19	0.2194 (16)	0.5309 (4)	0.6422 (8)	0.039 (3)
C20	0.2604 (13)	0.5673 (4)	0.7318 (7)	0.044 (3)
F13	0.253 (2)	0.6160 (4)	0.7092 (7)	0.191 (12)
F14	0.1732 (17)	0.5596 (7)	0.7926 (9)	0.160 (8)
F15	0.3977 (14)	0.5557 (6)	0.7840 (9)	0.146 (7)
O11	0.0437 (9)	0.3753 (3)	0.1802 (5)	0.0342 (17)
O12	−0.1369 (9)	0.4324 (4)	0.0999 (6)	0.0414 (19)
C21	−0.0549 (12)	0.3909 (5)	0.1083 (7)	0.029 (2)
C22	−0.0739 (11)	0.3550 (5)	0.0190 (7)	0.043 (3)
F16	0.0321 (11)	0.3654 (5)	−0.0255 (8)	0.097 (4)
F17	−0.0629 (17)	0.3041 (4)	0.0417 (7)	0.108 (5)
F18	−0.2087 (10)	0.3599 (5)	−0.0426 (6)	0.090 (4)
O13	0.3643 (13)	0.3544 (6)	0.0817 (10)	0.080 (4)
O14	0.6198 (12)	0.3490 (4)	0.1223 (8)	0.057 (3)
C23	0.4862 (15)	0.3354 (5)	0.0806 (9)	0.038 (3)
C24	0.4756 (12)	0.2843 (5)	0.0166 (8)	0.047 (3)
F19	0.4424 (15)	0.2979 (4)	−0.0737 (6)	0.097 (4)
F20	0.3681 (12)	0.2510 (4)	0.0270 (9)	0.092 (4)
F21	0.6043 (11)	0.2563 (4)	0.0333 (9)	0.099 (4)
O15	0.5360 (9)	0.5063 (3)	0.1190 (6)	0.0369 (17)
O16	0.7191 (8)	0.5649 (3)	0.1932 (5)	0.0320 (16)
C25	0.5966 (12)	0.5522 (5)	0.1358 (8)	0.032 (2)
C26	0.5095 (11)	0.5982 (4)	0.0722 (7)	0.035 (2)
F22	0.3589 (7)	0.5906 (3)	0.0480 (7)	0.065 (2)
F23	0.5335 (10)	0.6450 (3)	0.1135 (6)	0.062 (2)
F24	0.5541 (12)	0.6000 (5)	−0.0073 (6)	0.090 (4)
O17	0.5447 (14)	0.4270 (5)	0.5933 (9)	0.074 (3)*
O18	0.7438 (12)	0.4657 (7)	0.5522 (6)	0.073 (3)
C27	0.6832 (14)	0.4330 (7)	0.5936 (9)	0.054 (4)
C28	0.7894 (19)	0.3919 (7)	0.6523 (12)	0.093 (6)*
F25	0.7201 (16)	0.3529 (7)	0.6863 (13)	0.197 (12)
F26	0.8809 (18)	0.4142 (9)	0.7292 (11)	0.222 (13)
F27	0.8815 (16)	0.3686 (8)	0.6069 (10)	0.208 (13)
C1	0.3506 (10)	0.4309 (4)	0.3512 (7)	0.0225 (19)
C2	0.4353 (11)	0.3925 (4)	0.3448 (7)	0.026 (2)
C3	0.5172 (11)	0.3432 (4)	0.3492 (7)	0.023 (2)
C4	0.4246 (13)	0.2919 (4)	0.3431 (9)	0.035 (2)
H4A	0.3566	0.2879	0.2774	0.042*
H4B	0.3581	0.2939	0.3882	0.042*
C5	0.5300 (15)	0.2428 (4)	0.3675 (9)	0.038 (3)
H5A	0.5791	0.2419	0.4374	0.045*
H5B	0.4679	0.2096	0.3500	0.045*
C6	0.6532 (14)	0.2451 (4)	0.3133 (9)	0.036 (2)
H6A	0.6036	0.2477	0.2437	0.043*
H6B	0.7150	0.2116	0.3248	0.043*
C7	0.7587 (13)	0.2928 (4)	0.3449 (9)	0.035 (2)
H7A	0.8217	0.2984	0.2985	0.042*
H7B	0.8302	0.2850	0.4083	0.042*
C8	0.6694 (11)	0.3438 (4)	0.3518 (7)	0.0229 (19)
C9	0.7474 (11)	0.3925 (4)	0.3508 (7)	0.024 (2)
C10	0.8375 (11)	0.4312 (4)	0.3554 (7)	0.0232 (19)
N2	0.0533 (15)	0.6496 (4)	0.1685 (7)	0.046 (3)
H2	0.0657	0.6146	0.1662	0.056*
C34	0.1674 (18)	0.6803 (7)	0.1632 (10)	0.058 (4)
H34A	0.2632	0.6651	0.1597	0.070*
C35	0.148 (2)	0.7362 (7)	0.1625 (11)	0.062 (4)
H35A	0.2289	0.7598	0.1569	0.075*
C36	0.014 (2)	0.7545 (6)	0.1700 (11)	0.058 (4)
H36A	−0.0018	0.7922	0.1701	0.070*
C37	−0.0983 (17)	0.7218 (7)	0.1775 (11)	0.056 (4)
H37A	−0.1938	0.7364	0.1832	0.067*
C38	−0.0792 (16)	0.6677 (6)	0.1773 (10)	0.048 (3)
H38A	−0.1593	0.6440	0.1832	0.058*
N3	0.4065 (15)	0.4149 (6)	0.7639 (8)	0.052 (3)	0.5
H3	0.4120	0.4025	0.7077	0.062*	0.5
C42	0.3911 (13)	0.4539 (5)	0.9361 (7)	0.038 (2)	0.5
H42A	0.3841	0.4670	0.9967	0.045*	0.5
N3'	0.3911 (13)	0.4539 (5)	0.9361 (7)	0.038 (2)	0.5
H3'	0.3846	0.4661	0.9922	0.045*	0.5
C42'	0.4065 (15)	0.4149 (6)	0.7639 (8)	0.052 (3)	0.5
H42B	0.4124	0.4024	0.7029	0.062*	0.5
C39	0.2704 (14)	0.4167 (6)	0.7868 (8)	0.043 (3)
H39	0.1798	0.4038	0.7423	0.051*
C40	0.5387 (16)	0.4333 (7)	0.8304 (10)	0.054 (3)
H40A	0.6360	0.4317	0.8155	0.064*
C41	0.5298 (16)	0.4532 (6)	0.9168 (9)	0.050 (3)
H41A	0.6192	0.4663	0.9621	0.060*
C43	0.2598 (15)	0.4365 (6)	0.8724 (9)	0.044 (3)
H43A	0.1628	0.4382	0.8875	0.053*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.0254 (4)	0.0218 (3)	0.0285 (4)	0.0007 (3)	0.0037 (3)	0.0018 (3)
Ag2	0.0182 (3)	0.0268 (4)	0.0254 (3)	0.0000 (3)	0.0065 (3)	−0.0009 (3)
Ag3	0.0253 (4)	0.0437 (5)	0.0234 (3)	−0.0007 (3)	0.0056 (3)	−0.0023 (4)
Ag4	0.0210 (3)	0.0213 (4)	0.0373 (4)	0.0011 (3)	0.0071 (3)	−0.0011 (3)
Ag5	0.0292 (4)	0.0388 (4)	0.0259 (4)	0.0091 (3)	0.0071 (3)	0.0000 (3)
Ag6	0.0377 (4)	0.0282 (4)	0.0284 (4)	−0.0030 (3)	0.0075 (3)	−0.0041 (3)
Ag7	0.0265 (4)	0.0235 (4)	0.0436 (5)	−0.0036 (3)	0.0007 (3)	0.0059 (3)
Ag8	0.0271 (4)	0.0313 (4)	0.0251 (3)	−0.0006 (3)	0.0034 (3)	−0.0046 (3)
Ag9	0.0605 (12)	0.062 (2)	0.0485 (9)	0.0069 (13)	0.0102 (8)	−0.0233 (9)
Ag9'	0.065 (3)	0.061 (5)	0.056 (3)	0.006 (3)	0.033 (2)	−0.005 (3)
O1	0.024 (4)	0.031 (4)	0.025 (4)	−0.001 (3)	0.007 (3)	−0.003 (3)
O2	0.048 (5)	0.063 (6)	0.050 (5)	−0.005 (4)	0.029 (4)	0.000 (5)
C11	0.024 (5)	0.026 (5)	0.027 (5)	0.003 (4)	0.002 (4)	−0.001 (4)
C12	0.047 (6)	0.028 (5)	0.035 (5)	−0.007 (5)	0.004 (5)	−0.001 (4)
F1	0.110 (8)	0.071 (6)	0.064 (6)	−0.022 (6)	0.038 (6)	−0.039 (5)
F2	0.041 (5)	0.062 (6)	0.100 (7)	−0.019 (4)	−0.002 (4)	−0.005 (5)
F3	0.140 (9)	0.044 (5)	0.046 (5)	−0.045 (6)	−0.001 (5)	0.009 (4)
O3	0.037 (4)	0.027 (4)	0.037 (4)	−0.007 (3)	0.003 (4)	0.004 (3)
O4	0.032 (4)	0.025 (4)	0.043 (4)	0.001 (3)	0.002 (3)	−0.001 (3)
C13	0.027 (5)	0.025 (5)	0.036 (5)	−0.001 (4)	0.005 (4)	−0.002 (4)
C14	0.032 (5)	0.023 (5)	0.054 (7)	0.000 (4)	0.001 (5)	−0.003 (5)
F4	0.078 (6)	0.041 (4)	0.050 (4)	−0.014 (4)	0.024 (4)	−0.021 (3)
F5	0.061 (5)	0.023 (4)	0.104 (7)	−0.001 (4)	−0.026 (5)	0.006 (4)
F6	0.072 (6)	0.038 (4)	0.088 (6)	−0.027 (4)	0.047 (5)	−0.015 (4)
O5	0.033 (4)	0.031 (4)	0.030 (4)	0.007 (3)	−0.001 (3)	−0.002 (3)
O6	0.029 (4)	0.035 (4)	0.026 (3)	0.006 (3)	0.004 (3)	−0.002 (3)
C15	0.022 (4)	0.037 (5)	0.024 (5)	0.000 (4)	0.007 (4)	0.006 (4)
C16	0.041 (6)	0.051 (7)	0.037 (6)	0.012 (5)	0.008 (5)	0.003 (5)
F7	0.051 (5)	0.110 (8)	0.050 (5)	0.039 (5)	0.003 (4)	0.013 (5)
F8	0.084 (7)	0.109 (9)	0.045 (5)	0.040 (6)	−0.026 (4)	−0.029 (5)
F9	0.065 (6)	0.114 (9)	0.086 (7)	−0.002 (6)	−0.014 (5)	0.068 (7)
O7	0.034 (4)	0.031 (4)	0.029 (4)	0.001 (3)	0.006 (3)	−0.003 (3)
O8	0.044 (5)	0.030 (4)	0.041 (5)	0.006 (3)	0.015 (4)	0.005 (3)
C17	0.027 (5)	0.029 (5)	0.032 (5)	0.004 (4)	0.011 (4)	0.006 (4)
C18	0.058 (7)	0.037 (6)	0.041 (6)	0.014 (6)	0.010 (5)	0.010 (5)
F10	0.166 (13)	0.043 (6)	0.097 (9)	−0.032 (7)	−0.040 (8)	0.035 (6)
F11	0.249 (18)	0.066 (7)	0.059 (6)	0.037 (9)	0.054 (9)	0.037 (6)
F12	0.101 (9)	0.109 (11)	0.196 (16)	0.073 (9)	0.048 (10)	0.094 (11)
O9	0.061 (6)	0.049 (6)	0.042 (5)	−0.012 (4)	0.012 (4)	−0.014 (4)
O10	0.056 (5)	0.045 (5)	0.031 (4)	−0.003 (4)	0.010 (4)	−0.008 (4)
C19	0.059 (7)	0.020 (5)	0.033 (5)	0.010 (5)	0.004 (5)	−0.004 (4)
C20	0.059 (7)	0.036 (6)	0.029 (5)	0.017 (5)	−0.001 (5)	−0.005 (5)
F13	0.45 (4)	0.030 (5)	0.050 (6)	−0.004 (10)	−0.017 (11)	−0.013 (5)
F14	0.209 (19)	0.191 (18)	0.096 (10)	−0.075 (15)	0.067 (11)	−0.104 (12)
F15	0.137 (12)	0.164 (14)	0.089 (8)	0.053 (11)	−0.054 (8)	−0.084 (9)
O11	0.030 (4)	0.041 (5)	0.032 (4)	0.000 (3)	0.010 (3)	−0.009 (3)
O12	0.029 (4)	0.042 (5)	0.057 (5)	−0.003 (4)	0.018 (4)	0.006 (4)
C21	0.024 (5)	0.037 (6)	0.027 (5)	−0.004 (4)	0.009 (4)	−0.008 (4)
C22	0.038 (6)	0.055 (7)	0.033 (6)	0.001 (5)	0.005 (5)	−0.007 (5)
F16	0.089 (7)	0.129 (10)	0.098 (8)	−0.053 (7)	0.068 (6)	−0.077 (8)
F17	0.188 (14)	0.059 (7)	0.063 (6)	−0.007 (8)	0.006 (7)	−0.026 (5)
F18	0.063 (6)	0.147 (11)	0.049 (5)	−0.002 (6)	−0.007 (4)	−0.038 (6)
O13	0.051 (6)	0.096 (9)	0.086 (8)	0.023 (6)	0.007 (6)	−0.053 (7)
O14	0.061 (6)	0.044 (5)	0.074 (7)	−0.017 (5)	0.033 (5)	−0.031 (5)
C23	0.044 (7)	0.034 (6)	0.037 (6)	0.001 (5)	0.014 (5)	−0.005 (5)
C24	0.051 (7)	0.045 (7)	0.050 (7)	−0.012 (6)	0.019 (5)	−0.015 (5)
F19	0.180 (13)	0.073 (7)	0.043 (5)	−0.029 (8)	0.037 (7)	−0.021 (5)
F20	0.099 (8)	0.077 (7)	0.111 (9)	−0.049 (6)	0.049 (7)	−0.034 (6)
F21	0.084 (8)	0.068 (7)	0.143 (11)	0.007 (6)	0.028 (7)	−0.060 (7)
O15	0.034 (4)	0.029 (4)	0.041 (4)	0.001 (3)	−0.003 (3)	0.003 (4)
O16	0.026 (4)	0.032 (4)	0.034 (4)	0.002 (3)	0.000 (3)	0.002 (3)
C25	0.027 (5)	0.034 (6)	0.033 (5)	0.003 (4)	0.005 (4)	−0.003 (4)
C26	0.038 (6)	0.035 (6)	0.031 (5)	0.010 (5)	0.004 (4)	0.007 (4)
F22	0.030 (4)	0.060 (5)	0.094 (7)	0.011 (3)	−0.004 (4)	0.022 (5)
F23	0.068 (6)	0.035 (4)	0.072 (5)	0.009 (4)	−0.002 (4)	0.008 (4)
F24	0.102 (8)	0.130 (10)	0.052 (5)	0.059 (7)	0.043 (5)	0.040 (6)
O18	0.053 (6)	0.134 (11)	0.031 (4)	0.012 (7)	0.010 (4)	−0.004 (6)
C27	0.028 (5)	0.098 (10)	0.038 (6)	0.006 (6)	0.012 (5)	0.012 (6)
F25	0.101 (11)	0.24 (2)	0.27 (2)	0.076 (13)	0.097 (14)	0.20 (2)
F26	0.094 (11)	0.43 (4)	0.110 (12)	0.031 (18)	−0.035 (9)	0.07 (2)
F27	0.136 (13)	0.36 (3)	0.175 (16)	0.168 (18)	0.121 (13)	0.18 (2)
C1	0.016 (4)	0.025 (5)	0.026 (4)	−0.003 (4)	0.004 (3)	0.004 (4)
C2	0.018 (4)	0.037 (5)	0.023 (4)	−0.001 (4)	0.007 (4)	0.000 (4)
C3	0.016 (4)	0.026 (5)	0.026 (5)	−0.003 (4)	0.003 (4)	−0.001 (4)
C4	0.027 (5)	0.025 (5)	0.054 (6)	−0.005 (4)	0.014 (5)	−0.004 (5)
C5	0.045 (6)	0.020 (5)	0.048 (6)	−0.007 (4)	0.012 (5)	0.004 (4)
C6	0.034 (5)	0.025 (5)	0.049 (6)	0.000 (4)	0.010 (5)	−0.002 (5)
C7	0.031 (5)	0.021 (5)	0.053 (6)	0.004 (4)	0.009 (5)	−0.001 (5)
C8	0.023 (5)	0.022 (5)	0.023 (4)	−0.002 (4)	0.005 (4)	0.000 (4)
C9	0.023 (5)	0.028 (5)	0.021 (4)	0.006 (4)	0.005 (4)	−0.005 (4)
C10	0.019 (4)	0.022 (5)	0.029 (5)	0.001 (4)	0.007 (4)	−0.001 (4)
N2	0.078 (8)	0.025 (5)	0.033 (5)	0.013 (5)	0.009 (5)	0.001 (4)
C34	0.052 (8)	0.076 (9)	0.048 (7)	0.014 (7)	0.015 (6)	0.001 (7)
C35	0.074 (9)	0.056 (8)	0.059 (8)	−0.028 (7)	0.021 (7)	0.009 (7)
C36	0.087 (10)	0.033 (6)	0.051 (7)	0.010 (6)	0.011 (7)	0.010 (5)
C37	0.047 (7)	0.061 (8)	0.053 (7)	0.014 (6)	0.003 (6)	0.007 (6)
C38	0.047 (7)	0.054 (7)	0.045 (6)	−0.012 (6)	0.014 (5)	0.008 (6)
N3	0.054 (6)	0.064 (7)	0.040 (5)	−0.002 (6)	0.017 (5)	−0.013 (6)
C42	0.043 (5)	0.048 (6)	0.021 (4)	0.002 (5)	0.008 (4)	−0.005 (4)
N3'	0.043 (5)	0.048 (6)	0.021 (4)	0.002 (5)	0.008 (4)	−0.005 (4)
C42'	0.054 (6)	0.064 (7)	0.040 (5)	−0.002 (6)	0.017 (5)	−0.013 (6)
C39	0.045 (6)	0.045 (6)	0.036 (5)	−0.002 (5)	0.006 (5)	−0.003 (5)
C40	0.040 (6)	0.067 (8)	0.055 (7)	0.002 (6)	0.014 (6)	−0.008 (6)
C41	0.043 (6)	0.070 (8)	0.032 (5)	0.005 (6)	0.003 (5)	0.003 (6)
C43	0.040 (6)	0.055 (7)	0.038 (6)	0.004 (5)	0.009 (5)	0.009 (5)

Geometric parameters (Å, º)

Ag1—C1	2.196 (10)	C14—F5	1.289 (10)
Ag1—O5	2.306 (7)	C14—F4	1.306 (10)
Ag1—O3	2.345 (7)	C14—F6	1.313 (10)
Ag1—O1	2.538 (7)	O5—C15	1.229 (13)
Ag1—Ag3	2.8728 (11)	O6—C15	1.237 (14)
Ag1—Ag5	2.9494 (12)	C15—C16	1.542 (14)
Ag1—Ag2	2.9603 (11)	C16—F9	1.309 (11)
Ag1—Ag4	3.0466 (10)	C16—F8	1.311 (11)
Ag2—O11	2.319 (7)	C16—F7	1.315 (11)
Ag2—C10^i	2.330 (9)	O7—C17	1.242 (14)
Ag2—O7	2.355 (8)	O8—C17	1.244 (14)
Ag2—C1	2.384 (9)	O8—Ag8^i	2.516 (8)
Ag2—Ag7^i	2.8929 (11)	C17—C18	1.547 (15)
Ag2—Ag8^i	2.9481 (10)	C18—F10	1.289 (11)
Ag2—Ag3	2.9874 (10)	C18—F11	1.300 (11)
Ag3—O9	2.189 (9)	C18—F12	1.313 (11)
Ag3—C1	2.202 (10)	O9—C19	1.231 (16)
Ag3—O17	2.379 (13)	O10—C19	1.266 (17)
Ag3—O8	2.577 (8)	O10—Ag8^i	2.233 (8)
Ag3—Ag8^i	3.0405 (11)	C19—C20	1.544 (15)
Ag3—Ag4	3.2727 (10)	C20—F13	1.251 (11)
Ag4—O4	2.206 (8)	C20—F15	1.297 (11)
Ag4—C1	2.414 (9)	C20—F14	1.330 (11)
Ag4—C10	2.472 (9)	O11—C21	1.237 (14)
Ag4—C2	2.484 (11)	O12—C21	1.255 (14)
Ag4—C9	2.511 (10)	O12—Ag6^i	2.391 (7)
Ag4—O18	2.581 (9)	C21—C22	1.541 (15)
Ag4—Ag7	3.1006 (11)	C22—F16	1.302 (10)
Ag4—Ag6	3.1120 (11)	C22—F18	1.304 (11)
Ag5—O13	2.233 (10)	C22—F17	1.306 (11)
Ag5—O6	2.297 (7)	O13—C23	1.192 (16)
Ag5—C2	2.432 (10)	O14—C23	1.238 (16)
Ag5—C1	2.439 (9)	C23—C24	1.560 (16)
Ag5—Ag6	3.1414 (11)	C24—F19	1.303 (11)
Ag6—O15	2.249 (8)	C24—F20	1.308 (11)
Ag6—O14	2.274 (9)	C24—F21	1.314 (11)
Ag6—O12^ii	2.391 (7)	O15—C25	1.261 (14)
Ag6—C9	2.515 (10)	O16—C25	1.232 (13)
Ag6—C10	2.530 (10)	C25—C26	1.547 (15)
Ag6—Ag7	2.9368 (12)	C26—F23	1.300 (10)
Ag7—C10	2.180 (10)	C26—F24	1.309 (10)
Ag7—O16	2.308 (7)	C26—F22	1.315 (10)
Ag7—O1^ii	2.333 (7)	O17—C27	1.247 (17)
Ag7—Ag2^ii	2.8929 (11)	O18—C27	1.22 (2)
Ag7—Ag8	2.8992 (12)	C27—C28	1.50 (2)
Ag8—O10^ii	2.233 (8)	C28—F27	1.312 (13)
Ag8—C10	2.242 (10)	C28—F25	1.313 (13)
Ag8—O8^ii	2.516 (8)	C28—F26	1.318 (13)
Ag8—O18	2.544 (10)	C1—C2	1.239 (14)
Ag8—Ag2^ii	2.9480 (10)	C2—C3	1.421 (15)
Ag8—Ag3^ii	3.0404 (11)	C3—C8	1.353 (14)
Ag8—Ag9	3.371 (3)	C3—C4	1.513 (14)
Ag9—N1	2.201 (10)	C4—C5	1.528 (16)
Ag9—O4	2.460 (8)	C4—H4A	0.9900
Ag9—O2^ii	2.490 (9)	C4—H4B	0.9900
Ag9—O18	2.508 (17)	C5—C6	1.508 (17)
N1—C29	1.3900	C5—H5A	0.9900
N1—C33	1.3900	C5—H5B	0.9900
C29—C30	1.3900	C6—C7	1.513 (15)
C29—H29	0.9500	C6—H6A	0.9900
C30—C31	1.3900	C6—H6B	0.9900
C30—H30	0.9500	C7—C8	1.517 (14)
C31—C32	1.3900	C7—H7A	0.9900
C31—H31	0.9500	C7—H7B	0.9900
C32—C33	1.3900	C8—C9	1.400 (15)
C32—H32	0.9500	C9—C10	1.247 (14)
C33—H33	0.9500	C10—Ag2^ii	2.330 (9)
Ag9'—N1'	2.26 (2)	N2—C34	1.29 (2)
Ag9'—O2^ii	2.291 (9)	N2—C38	1.304 (19)
N1'—C29'	1.3900	N2—H2	0.8800
N1'—C33'	1.3900	C34—C35	1.40 (2)
C29'—C30'	1.3900	C34—H34A	0.9500
C29'—H29'	0.9500	C35—C36	1.31 (2)
C30'—C31'	1.3900	C35—H35A	0.9500
C30'—H30'	0.9500	C36—C37	1.32 (2)
C31'—C32'	1.3900	C36—H36A	0.9500
C31'—H31'	0.9500	C37—C38	1.36 (2)
C32'—C33'	1.3900	C37—H37A	0.9500
C32'—H32'	0.9500	C38—H38A	0.9500
C33'—H33'	0.9500	N3—C39	1.343 (17)
O1—C11	1.244 (13)	N3—C40	1.393 (19)
O1—Ag7^i	2.333 (7)	N3—H3	0.8799
O2—C11	1.213 (14)	C42—C41	1.340 (18)
O2—Ag9'^i	2.291 (9)	C42—C43	1.361 (17)
O2—Ag9^i	2.490 (9)	C42—H42A	0.9500
C11—C12	1.545 (15)	C39—C43	1.354 (18)
C12—F2	1.304 (11)	C39—H39	0.9500
C12—F3	1.309 (10)	C40—C41	1.364 (19)
C12—F1	1.312 (10)	C40—H40A	0.9500
O3—C13	1.212 (14)	C41—H41A	0.9501
O4—C13	1.276 (14)	C43—H43A	0.9487
C13—C14	1.577 (15)
C1—Ag1—O5	132.4 (3)	C33—C32—H32	120.0
C1—Ag1—O3	126.4 (3)	C31—C32—H32	120.0
O5—Ag1—O3	87.4 (3)	C32—C33—N1	120.0
C1—Ag1—O1	133.6 (3)	C32—C33—H33	120.0
O5—Ag1—O1	73.5 (2)	N1—C33—H33	120.0
O3—Ag1—O1	85.0 (3)	N1'—Ag9'—O2^ii	134.6 (8)
C1—Ag1—Ag3	49.3 (2)	C29'—N1'—C33'	120.0
O5—Ag1—Ag3	152.6 (2)	C29'—N1'—Ag9'	114.0 (13)
O3—Ag1—Ag3	112.82 (19)	C33'—N1'—Ag9'	126.0 (13)
O1—Ag1—Ag3	89.44 (16)	N1'—C29'—C30'	120.0
C1—Ag1—Ag5	54.2 (2)	N1'—C29'—H29'	120.0
O5—Ag1—Ag5	82.93 (19)	C30'—C29'—H29'	120.0
O3—Ag1—Ag5	114.9 (2)	C31'—C30'—C29'	120.0
O1—Ag1—Ag5	148.60 (16)	C31'—C30'—H30'	120.0
Ag3—Ag1—Ag5	103.31 (3)	C29'—C30'—H30'	120.0
C1—Ag1—Ag2	52.6 (2)	C30'—C31'—C32'	120.0
O5—Ag1—Ag2	97.1 (2)	C30'—C31'—H31'	120.0
O3—Ag1—Ag2	173.9 (2)	C32'—C31'—H31'	120.0
O1—Ag1—Ag2	92.41 (16)	C31'—C32'—C33'	120.0
Ag3—Ag1—Ag2	61.59 (3)	C31'—C32'—H32'	120.0
Ag5—Ag1—Ag2	69.87 (3)	C33'—C32'—H32'	120.0
C1—Ag1—Ag4	51.8 (2)	C32'—C33'—N1'	120.0
O5—Ag1—Ag4	139.0 (2)	C32'—C33'—H33'	120.0
O3—Ag1—Ag4	74.6 (2)	N1'—C33'—H33'	120.0
O1—Ag1—Ag4	138.57 (16)	C11—O1—Ag7^i	102.2 (6)
Ag3—Ag1—Ag4	67.06 (3)	C11—O1—Ag1	134.7 (6)
Ag5—Ag1—Ag4	72.40 (3