Pentapotassium dicitrato(4-)­manganate(III) pentahydrate

The centrosymmetric crystal structure pentapotassium dicitrato(4-)­manganate(III) pentahydrate, K₅[Mn(C₆H₄O₇)₂]·5H₂O, has two independent anions, both of which lie at inversion centers in the triclinic unit cell. The Mn atoms are O,O',O''-chelated by the citrate entity and the six O atoms surrounding each Mn atom constitute an octahedron. The K atoms interact with the anions and the water mol­ecules, leading to the formation of a network structure that also features extensive hydrogen bonding.

Key indicators

• Single-crystal X-ray study
• T = 298 K
• Mean [sigma](C-C) = 0.007 Å
• R factor = 0.062
• wR factor = 0.161
• Data-to-parameter ratio = 12.4

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level B:



PLAT_420  Alert B D-H Without Acceptor       O1W    -   H1W1   ...          ?

PLAT_420  Alert B D-H Without Acceptor       O4W    -   H4W2   ...          ?


 Alert Level C:



PLAT_710  Alert C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        179
                   O4W -K4  -O13 -C12    66.00  1.50   1.555   1.555   1.555   1.555

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        186
                   O4W -K4  -O13 -K3    -52.00  1.00   1.555   1.555   1.555   2.667

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        193
                   O4W -K4  -O13 -K4   -139.00  1.00   1.555   1.555   1.555   2.667

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        200
                   O4W -K4  -O13 -K3     45.00  1.00   1.555   1.555   1.555   1.655

PLAT_710  Alert C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #        215
                   O13 -K4  -O4W -K5     -8.00  1.00   1.555   1.555   1.555   1.655


 0 Alert Level A = Potentially serious problem

 2 Alert Level B = Potential problem

 5 Alert Level C = Please check

---

Computing details

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Pentapotassium dicitrato(4-)manganate(III) pentahydrate

Crystal data

K5[Mn(C6H4O7)2]·5H2O	Z = 2
Mr = 716.70	F(000) = 724
Triclinic, P1	Dx = 1.984 Mg m^−3
a = 6.8304 (4) Å	Mo Kα radiation, λ = 0.71073 Å
b = 9.2270 (5) Å	Cell parameters from 3636 reflections
c = 20.197 (1) Å	θ = 2.3–28.3°
α = 78.294 (1)°	µ = 1.51 mm^−1
β = 82.734 (1)°	T = 298 K
γ = 74.892 (1)°	Plate, brown
V = 1199.7 (1) Å^3	0.19 × 0.19 × 0.04 mm

Data collection

Bruker APEX area-detector diffractometer	4168 independent reflections
Radiation source: fine-focus sealed tube	3444 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.024
φ and ω scans	θmax = 25.0°, θmin = 1.0°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −8→8
Tmin = 0.711, Tmax = 0.942	k = −10→8
7084 measured reflections	l = −24→22

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.062	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.161	H-atom parameters constrained
S = 1.15	w = 1/[σ^2(Fo^2) + (0.0736P)^2 + 0.8327P] where P = (Fo^2 + 2Fc^2)/3
4168 reflections	(Δ/σ)max = 0.001
337 parameters	Δρmax = 0.68 e Å^−3
0 restraints	Δρmin = −0.53 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Mn1	0.5000	0.5000	0.5000	0.0125 (3)
Mn2	0.5000	1.0000	1.0000	0.0128 (3)
K1	0.0148 (2)	0.2456 (1)	0.48527 (6)	0.0246 (3)
K2	0.6141 (2)	0.1263 (1)	0.41473 (6)	0.0299 (3)
K3	0.0223 (2)	0.7351 (1)	0.99095 (6)	0.0230 (3)
K4	0.6042 (2)	0.6350 (1)	0.91827 (6)	0.0248 (3)
K5	−0.0623 (2)	0.7180 (2)	0.74286 (7)	0.0339 (4)
O1	0.3467 (5)	0.3396 (4)	0.5165 (2)	0.020 (1)
O2	0.2684 (5)	0.1699 (4)	0.6034 (2)	0.026 (1)
O3	0.3165 (5)	0.5940 (4)	0.5845 (2)	0.019 (1)
O4	0.3129 (5)	0.6274 (4)	0.6901 (2)	0.025 (1)
O5	0.6660 (4)	0.3660 (4)	0.5646 (2)	0.016 (1)
O6	0.7124 (6)	0.0267 (4)	0.5438 (2)	0.029 (1)
O7	0.9521 (6)	−0.0674 (5)	0.6161 (2)	0.037 (1)
O8	0.3637 (5)	0.8303 (4)	1.0157 (2)	0.021 (1)
O9	0.2892 (5)	0.6596 (4)	1.1023 (2)	0.024 (1)
O10	0.2946 (5)	1.0862 (4)	1.0850 (2)	0.021 (1)
O11	0.1263 (5)	1.0541 (4)	1.1858 (2)	0.030 (1)
O12	0.6667 (5)	0.8751 (4)	1.0664 (2)	0.015 (1)
O13	0.7256 (6)	0.5305 (4)	1.0450 (2)	0.029 (1)
O14	0.9684 (5)	0.4361 (5)	1.1155 (2)	0.033 (1)
O1w	0.1989 (8)	0.4192 (6)	0.3745 (2)	0.057 (1)
O2w	0.1306 (7)	0.5843 (6)	0.2419 (2)	0.046 (1)
O3w	0.2448 (6)	0.8773 (5)	0.8755 (2)	0.035 (1)
O4w	0.5237 (6)	0.7440 (6)	0.7708 (3)	0.062 (2)
O5w	0.1177 (8)	0.1365 (6)	0.7393 (2)	0.057 (2)
C1	0.3738 (7)	0.2580 (6)	0.5757 (3)	0.019 (1)
C2	0.5443 (7)	0.2830 (6)	0.6125 (2)	0.015 (1)
C3	0.4487 (7)	0.3755 (5)	0.6692 (2)	0.017 (1)
C4	0.3506 (7)	0.5431 (6)	0.6462 (2)	0.016 (1)
C5	0.6788 (8)	0.1327 (6)	0.6445 (3)	0.021 (1)
C6	0.7889 (7)	0.0233 (6)	0.5972 (3)	0.020 (1)
C7	0.3925 (7)	0.7478 (6)	1.0758 (2)	0.016 (1)
C8	0.5535 (7)	0.7823 (6)	1.1133 (2)	0.016 (1)
C9	0.4351 (7)	0.8705 (6)	1.1688 (2)	0.019 (1)
C10	0.2750 (7)	1.0141 (6)	1.1448 (3)	0.017 (1)
C11	0.6965 (8)	0.6359 (6)	1.1459 (3)	0.021 (1)
C12	0.8065 (7)	0.5261 (6)	1.0985 (2)	0.019 (1)
H1w1	0.3011	0.3204	0.3824	0.068*
H1w2	0.2245	0.4787	0.4060	0.068*
H2w1	0.1969	0.5912	0.1959	0.055*
H2w2	0.1988	0.4830	0.2665	0.055*
H3w1	0.2531	0.9790	0.8782	0.042*
H3w2	0.2012	0.8738	0.8320	0.042*
H4w1	0.4724	0.6743	0.7512	0.074*
H4w2	0.4415	0.8472	0.7607	0.074*
H5w1	0.1787	0.1554	0.6929	0.069*
H5w2	0.0250	0.0716	0.7392	0.069*
H3a	0.3466	0.3279	0.6961	0.020*
H3b	0.5538	0.3680	0.6987	0.020*
H5a	0.5954	0.0804	0.6786	0.025*
H5b	0.7801	0.1553	0.6678	0.025*
H9a	0.3691	0.8025	1.2017	0.023*
H9b	0.5319	0.8982	1.1921	0.023*
H11a	0.7978	0.6634	1.1673	0.025*
H11b	0.6185	0.5823	1.1815	0.025*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mn1	0.0131 (5)	0.0116 (6)	0.0125 (5)	−0.0013 (4)	−0.0029 (4)	−0.0020 (4)
Mn2	0.0122 (5)	0.0119 (6)	0.0132 (6)	−0.0010 (4)	−0.0029 (4)	−0.0011 (4)
K1	0.0187 (6)	0.0269 (7)	0.0289 (7)	−0.0025 (5)	−0.0027 (5)	−0.0100 (5)
K2	0.0382 (7)	0.0224 (7)	0.0324 (7)	−0.0119 (6)	−0.0056 (6)	−0.0048 (6)
K3	0.0177 (6)	0.0223 (7)	0.0287 (7)	−0.0018 (5)	−0.0018 (5)	−0.0080 (5)
K4	0.0295 (6)	0.0206 (7)	0.0256 (7)	−0.0050 (5)	−0.0058 (5)	−0.0065 (5)
K5	0.0281 (6)	0.0319 (8)	0.0409 (8)	−0.0026 (6)	0.0050 (5)	−0.0153 (6)
O1	0.022 (2)	0.022 (2)	0.017 (2)	−0.009 (2)	−0.006 (1)	−0.001 (2)
O2	0.032 (2)	0.025 (2)	0.026 (2)	−0.017 (2)	−0.001 (2)	−0.002 (2)
O3	0.021 (2)	0.015 (2)	0.018 (2)	0.003 (2)	−0.004 (2)	−0.006 (2)
O4	0.030 (2)	0.023 (2)	0.023 (2)	−0.001 (2)	−0.002 (2)	−0.013 (2)
O5	0.012 (2)	0.018 (2)	0.016 (2)	−0.001 (1)	−0.004 (1)	0.000 (2)
O6	0.036 (2)	0.025 (2)	0.023 (2)	0.004 (2)	−0.008 (2)	−0.010 (2)
O7	0.028 (2)	0.032 (3)	0.045 (3)	0.011 (2)	−0.011 (2)	−0.015 (2)
O8	0.023 (2)	0.020 (2)	0.019 (2)	−0.007 (2)	−0.009 (2)	0.002 (2)
O9	0.028 (2)	0.020 (2)	0.026 (2)	−0.014 (2)	−0.001 (2)	0.000 (2)
O10	0.023 (2)	0.013 (2)	0.020 (2)	0.001 (2)	0.002 (2)	0.002 (2)
O11	0.024 (2)	0.034 (3)	0.024 (2)	0.001 (2)	0.004 (2)	−0.004 (2)
O12	0.015 (2)	0.016 (2)	0.015 (2)	−0.002 (1)	−0.003 (1)	−0.002 (1)
O13	0.031 (2)	0.027 (2)	0.025 (2)	0.005 (2)	−0.003 (2)	−0.011 (2)
O14	0.021 (2)	0.031 (2)	0.046 (3)	0.007 (2)	−0.012 (2)	−0.015 (2)
O1w	0.070 (3)	0.070 (4)	0.046 (3)	−0.044 (3)	−0.009 (2)	−0.007 (3)
O2w	0.059 (3)	0.058 (3)	0.022 (2)	−0.023 (2)	−0.010 (2)	0.003 (2)
O3w	0.038 (2)	0.038 (3)	0.029 (2)	−0.008 (2)	−0.010 (2)	−0.003 (2)
O4w	0.034 (3)	0.077 (4)	0.088 (4)	−0.009 (3)	−0.005 (3)	−0.051 (3)
O5w	0.067 (3)	0.084 (4)	0.031 (3)	−0.045 (3)	−0.002 (2)	−0.001 (3)
C1	0.015 (2)	0.018 (3)	0.022 (3)	−0.001 (2)	0.002 (2)	−0.008 (2)
C2	0.019 (2)	0.013 (3)	0.013 (3)	−0.002 (2)	−0.001 (2)	−0.003 (2)
C3	0.022 (2)	0.011 (3)	0.014 (3)	0.000 (2)	−0.001 (2)	−0.001 (2)
C4	0.008 (2)	0.023 (3)	0.018 (3)	−0.002 (2)	0.000 (2)	−0.008 (2)
C5	0.028 (3)	0.016 (3)	0.016 (3)	0.001 (2)	−0.006 (2)	−0.002 (2)
C6	0.020 (3)	0.012 (3)	0.024 (3)	−0.003 (2)	−0.002 (2)	0.001 (2)
C7	0.015 (2)	0.008 (3)	0.021 (3)	0.005 (2)	−0.001 (2)	−0.007 (2)
C8	0.018 (2)	0.016 (3)	0.012 (3)	−0.002 (2)	−0.001 (2)	−0.004 (2)
C9	0.023 (3)	0.023 (3)	0.010 (3)	−0.006 (2)	0.001 (2)	−0.003 (2)
C10	0.014 (2)	0.020 (3)	0.022 (3)	−0.006 (2)	−0.002 (2)	−0.014 (2)
C11	0.028 (3)	0.014 (3)	0.016 (3)	0.001 (2)	−0.008 (2)	0.003 (2)
C12	0.021 (3)	0.021 (3)	0.015 (3)	−0.006 (2)	−0.001 (2)	0.000 (2)

Geometric parameters (Å, º)

Mn1—O1	1.979 (3)	K5—O2w^iii	2.896 (5)
Mn1—O1^i	1.979 (3)	K5—O4w^iv	2.770 (4)
Mn1—O3	2.174 (3)	O1—C1	1.285 (6)
Mn1—O3^i	2.174 (3)	O2—C1	1.228 (6)
Mn1—O5	1.872 (3)	O3—C4	1.268 (6)
Mn1—O5^i	1.872 (3)	O4—C4	1.255 (6)
Mn2—O8	1.976 (3)	O5—C2	1.429 (6)
Mn2—O8^ii	1.976 (3)	O6—C6	1.247 (6)
Mn2—O10	2.216 (3)	O7—C6	1.257 (6)
Mn2—O10^ii	2.216 (3)	O8—C7	1.303 (6)
Mn2—O12	1.870 (3)	O9—C7	1.214 (6)
Mn2—O12^ii	1.870 (3)	O10—C10	1.264 (6)
K1—O1	2.811 (3)	O11—C10	1.254 (6)
K1—O2	2.986 (4)	O12—C8	1.436 (6)
K1—O3^iii	2.740 (3)	O13—C12	1.263 (6)
K1—O5^iv	2.802 (3)	O14—C12	1.238 (6)
K1—O6^v	2.830 (4)	C1—C2	1.545 (7)
K1—O7^v	2.829 (4)	C2—C5	1.520 (7)
K1—O1w	2.835 (5)	C2—C3	1.544 (7)
K2—O2^v	2.727 (4)	C3—C4	1.518 (7)
K2—O3^i	2.747 (4)	C5—C6	1.521 (7)
K2—O4^i	2.875 (4)	C7—C8	1.542 (7)
K2—O7^vi	2.880 (4)	C8—C11	1.526 (7)
K2—O6	2.691 (4)	C8—C9	1.540 (7)
K2—O6^v	2.891 (4)	C9—C10	1.518 (7)
K3—O8	2.829 (3)	C11—C12	1.524 (7)
K3—O9	2.934 (4)	O1w—H1w1	0.99
K3—O10^vii	2.776 (3)	O1w—H1w2	0.98
K3—O12^iv	2.848 (3)	O2w—H2w1	0.98
K3—O13^viii	2.776 (4)	O2w—H2w2	0.99
K4—O13	2.700 (4)	O3w—H3w1	0.97
K3—O13^iv	3.076 (4)	O3w—H3w2	0.97
K3—O14^viii	2.900 (4)	O4w—H4w1	0.97
K3—O3w	2.893 (4)	O4w—H4w2	0.97
K4—O8	2.983 (4)	O5w—H5w1	0.98
K4—O9^viii	2.727 (4)	O5w—H5w2	0.98
K4—O10^ii	2.819 (4)	C3—H3a	0.97
K4—O13^viii	2.977 (4)	C3—H3b	0.97
K4—O14^ix	2.846 (4)	C5—H5a	0.97
K4—O3w	2.944 (4)	C5—H5b	0.97
K4—O4w	3.016 (6)	C9—H9a	0.97
K5—O4	2.637 (4)	C9—H9b	0.97
K5—O7^x	2.909 (5)	C11—H11a	0.97
K5—O11^vii	2.697 (4)	C11—H11b	0.97
K5—O14^viii	2.993 (4)
O1—Mn1—O1^i	180.0 (1)	C1—O2—K1	92.4 (3)
O1—Mn1—O3	88.5 (1)	K2^v—O2—K1	89.6 (1)
O1—Mn1—O3^i	91.5 (1)	C4—O3—Mn1	124.0 (3)
O1—Mn1—O5	84.2 (1)	C4—O3—K1^iii	136.1 (3)
O1—Mn1—O5^i	95.8 (1)	Mn1—O3—K1^iii	97.0 (1)
O1^i—Mn1—O3	91.5 (1)	C4—O3—K2^i	94.2 (3)
O1^i—Mn1—O3^i	88.5 (1)	Mn1—O3—K2^i	108.9 (1)
O1^i—Mn1—O5	95.8 (1)	K1^iii—O3—K2^i	85.7 (1)
O1^i—Mn1—O5^i	84.2 (1)	C4—O4—K5	120.4 (3)
O3—Mn1—O5	86.7 (1)	C4—O4—K2^i	88.6 (3)
O3—Mn1—O3^i	180.0 (1)	K5—O4—K2^i	106.5 (1)
O3—Mn1—O5^i	93.3 (1)	C2—O5—Mn1	108.8 (2)
O3^i—Mn1—O5	93.3 (1)	C2—O5—K1^xi	127.2 (3)
O3^i—Mn1—O5^i	86.7 (1)	Mn1—O5—K1^xi	102.8 (1)
O5—Mn1—O5^i	180.0 (2)	C6—O6—K2	157.7 (3)
O8—Mn2—O8^ii	180.0 (1)	C6—O6—K1^v	94.4 (3)
O8—Mn2—O10	87.0 (1)	K2—O6—K1^v	93.7 (1)
O8—Mn2—O10^ii	93.0 (1)	C6—O6—K2^v	105.4 (3)
O8—Mn2—O12	84.2 (1)	K2—O6—K2^v	95.2 (1)
O8—Mn2—O12^ii	95.8 (1)	K1^v—O6—K2^v	91.6 (1)
O8^ii—Mn2—O10	93.0 (1)	C6—O6—K1^xi	80.7 (3)
O8^ii—Mn2—O10^ii	87.0 (1)	K2—O6—K1^xi	77.8 (1)
O8^ii—Mn2—O12	95.8 (1)	K1^v—O6—K1^xi	96.1 (1)
O8^ii—Mn2—O12^ii	84.2 (1)	K2^v—O6—K1^xi	169.9 (1)
O10—Mn2—O10^ii	180.0 (1)	C6—O7—K1^v	94.2 (3)
O10—Mn2—O12	86.3 (1)	C6—O7—K2^vi	141.5 (4)
O10—Mn2—O12^ii	93.7 (1)	K1^v—O7—K2^vi	81.6 (1)
O10^ii—Mn2—O12^ii	86.3 (1)	C6—O7—K5^xii	118.4 (3)
O10^ii—Mn2—O12	93.7 (1)	K1^v—O7—K5^xii	104.2 (1)
O12—Mn2—O12^ii	180.0 (2)	K2^vi—O7—K5^xii	99.6 (1)
O3^iii—K1—O5^iv	64.3 (1)	C7—O8—Mn2	111.2 (3)
O3^iii—K1—O1	130.6 (1)	C7—O8—K3	97.6 (3)
O5^iv—K1—O1	109.4 (1)	Mn2—O8—K3	145.8 (2)
O3^iii—K1—O7^v	79.6 (1)	C7—O8—K4	105.6 (3)
O5^iv—K1—O7^v	128.1 (1)	Mn2—O8—K4	102.2 (1)
O1—K1—O7^v	122.5 (1)	K3—O8—K4	86.8 (1)
O3^iii—K1—O6^v	125.7 (1)	C7—O9—K4^viii	120.5 (3)
O1—K1—O6^v	88.8 (1)	C7—O9—K3	94.8 (3)
O7^v—K1—O6^v	46.1 (1)	K4^viii—O9—K3	88.5 (1)
O3^iii—K1—O1w	78.8 (1)	C10—O10—Mn2	126.5 (3)
O5^iv—K1—O1w	124.4 (1)	C10—O10—K3^vii	125.5 (3)
O1—K1—O1w	65.3 (1)	Mn2—O10—K3^vii	97.4 (1)
O7^v—K1—O1w	79.4 (1)	C10—O10—K4^ii	112.2 (3)
O6^v—K1—O1w	90.6 (1)	Mn2—O10—K4^ii	101.2 (1)
O3^iii—K1—O2	153.3 (1)	K3^vii—O10—K4^ii	84.5 (1)
O5^iv—K1—O2	91.4 (1)	C10—O11—K5^vii	127.2 (3)
O1—K1—O2	44.8 (1)	C8—O12—Mn2	109.7 (3)
O7^v—K1—O2	126.4 (1)	C8—O12—K3^xi	119.9 (3)
O6^v—K1—O2	80.4 (1)	Mn2—O12—K3^xi	104.1 (1)
O1w—K1—O2	109.3 (1)	C12—O13—K4	158.6 (3)
O2—K1—O6^iv	98.4 (1)	C12—O13—K3^viii	97.4 (3)
O6—K2—O2^v	87.8 (1)	K4—O13—K3^viii	92.4 (1)
O6—K2—O3^i	91.2 (1)	C12—O13—K4^viii	108.2 (3)
O2^v—K2—O3^i	153.4 (1)	K4—O13—K4^viii	91.1 (1)
O6—K2—O4^i	134.4 (1)	K3^viii—O13—K4^viii	87.9 (1)
O2^v—K2—O4^i	121.9 (1)	C12—O13—K3^xi	79.1 (3)
O3^i—K2—O4^i	46.3 (1)	K4—O13—K3^xi	81.0 (1)
O6—K2—O7^vi	84.0 (1)	K3^viii—O13—K3^xi	96.4 (1)
O2^v—K2—O7^vi	74.8 (1)	K4^viii—O13—K3^xi	171.1 (1)
O3^i—K2—O7^vi	78.6 (1)	C12—O14—K4^ix	143.2 (4)
O4^i—K2—O7^vi	73.4 (1)	C12—O14—K3^viii	92.1 (3)
O6—K2—O6^v	84.8 (1)	K4^ix—O14—K3^viii	81.8 (1)
O2^v—K2—O6^v	68.5 (1)	C12—O14—K5^viii	125.9 (3)
O3^i—K2—O6^v	137.8 (1)	K4^ix—O14—K5^viii	86.8 (1)
O4^i—K2—O6^v	135.8 (1)	K3^viii—O14—K5^viii	122.0 (1)
O7^vi—K2—O6^v	142.0 (1)	C12—O14—K3^xi	65.4 (3)
O13^viii—K3—O10^vii	122.5 (1)	K4^ix—O14—K3^xi	78.0 (1)
O13^viii—K3—O8	90.6 (1)	K3^viii—O14—K3^xi	87.4 (1)
O10^vii—K3—O8	125.5 (1)	K5^viii—O14—K3^xi	144.7 (1)
O13^viii—K3—O12^iv	148.2 (1)	K3—O3w—K4	86.4 (1)
O10^vii—K3—O12^iv	64.2 (1)	K5^xi—O4w—K4	87.7 (1)
O8—K3—O12^iv	110.7 (1)	O2—C1—O1	123.5 (5)
O13^viii—K3—O3w	82.6 (1)	O2—C1—C2	121.2 (5)
O10^vii—K3—O3w	79.1 (1)	O1—C1—C2	115.3 (4)
O8—K3—O3w	62.3 (1)	O5—C2—C5	109.2 (4)
O12^iv—K3—O3w	127.9 (1)	O5—C2—C3	109.4 (4)
O13^viii—K3—O14^viii	45.7 (1)	C5—C2—C3	108.1 (4)
O10^vii—K3—O14^viii	76.9 (1)	O5—C2—C1	108.9 (4)
O8—K3—O14^viii	122.7 (1)	C5—C2—C1	111.7 (4)
O3w—K3—O14^viii	75.0 (1)	C3—C2—C1	109.5 (4)
O13^viii—K3—O9	82.6 (1)	C4—C3—C2	116.2 (4)
O10^vii—K3—O9	154.8 (1)	O4—C4—O3	122.6 (5)
O8—K3—O9	45.0 (1)	O4—C4—C3	117.2 (4)
O12^iv—K3—O9	95.6 (1)	O3—C4—C3	120.2 (4)
O3w—K3—O9	105.2 (1)	C2—C5—C6	116.9 (4)
O14^viii—K3—O9	128.3 (1)	O6—C6—O7	124.6 (5)
O13^viii—K3—O13^iv	83.6 (1)	O6—C6—C5	119.2 (4)
O10^vii—K3—O13^iv	84.4 (1)	O7—C6—C5	116.2 (4)
O8—K3—O13^iv	146.5 (1)	O9—C7—O8	122.6 (4)
O12^iv—K3—O13^iv	65.5 (1)	O9—C7—C8	122.4 (4)
O3w—K3—O13^iv	148.1 (1)	O8—C7—C8	114.7 (4)
O9—K3—O13^iv	101.5 (1)	O12—C8—C11	110.3 (4)
O8—K3—O14^iv	107.5 (1)	O12—C8—C9	110.2 (4)
O9—K3—O14^iv	63.0 (1)	C11—C8—C9	109.6 (4)
O13—K4—O9^viii	88.1 (1)	O12—C8—C7	109.2 (4)
O13—K4—O10^ii	91.0 (1)	C11—C8—C7	111.4 (4)
O9^viii—K4—O10^ii	150.4 (1)	C9—C8—C7	106.2 (4)
O13—K4—O14^ix	81.8 (1)	C10—C9—C8	115.9 (4)
O9^viii—K4—O14^ix	73.4 (1)	O11—C10—O10	123.0 (5)
O10^ii—K4—O14^ix	77.1 (1)	O11—C10—C9	117.4 (4)
O13—K4—O3w	127.7 (1)	O10—C10—C9	119.6 (4)
O9^viii—K4—O3w	128.6 (1)	C12—C11—C8	116.0 (4)
O10^ii—K4—O3w	73.7 (1)	O14—C12—O13	124.0 (5)
O14^ix—K4—O3w	138.0 (1)	O14—C12—C11	117.7 (4)
O13—K4—O13^viii	88.9 (1)	O13—C12—C11	118.2 (4)
O9^viii—K4—O13^viii	65.2 (1)	K1—O1w—H1w1	76.5
O10^ii—K4—O13^viii	144.4 (1)	K1—O1w—H1w2	88.8
O14^ix—K4—O13^viii	137.8 (1)	H1w1—O1w—H1w2	105.5
O3w—K4—O13^viii	78.4 (1)	K5^iii—O2w—H2w1	98.3
O13—K4—O8	68.4 (1)	K5^iii—O2w—H2w2	46.7
O9^viii—K4—O8	141.6 (1)	H2w1—O2w—H2w2	105.4
O10^ii—K4—O8	63.3 (1)	K3—O3w—H3w1	114.2
O14^ix—K4—O8	128.7 (1)	K4—O3w—H3w1	114.5
O3w—K4—O8	60.0 (1)	K3—O3w—H3w2	113.9
O13^viii—K4—O8	83.9 (1)	K4—O3w—H3w2	114.3
O13—K4—O4w	172.9 (1)	H3w1—O3w—H3w2	111.5
O9^viii—K4—O4w	90.0 (1)	K5^xi—O4w—H4w1	113.8
O10^ii—K4—O4w	87.4 (1)	K4—O4w—H4w1	113.9
O14^ix—K4—O4w	91.1 (1)	K5^xi—O4w—H4w2	114.2
O3w—K4—O4w	58.3 (1)	K4—O4w—H4w2	114.2
O13^viii—K4—O4w	96.4 (1)	H4w1—O4w—H4w2	111.2
O8—K4—O4w	116.7 (1)	H5w1—O5w—H5w2	106.5
O4—K5—O11^vii	115.7 (1)	C4—C3—H3a	108.2
O4—K5—O4w^iv	159.8 (1)	C2—C3—H3a	108.2
O11^vii—K5—O4w^iv	84.3 (1)	C4—C3—H3b	108.2
O4—K5—O2w^iii	91.8 (1)	C2—C3—H3b	108.2
O11^vii—K5—O2w^iii	139.5 (1)	H3a—C3—H3b	107.4
O4w^iv—K5—O2w^iii	72.6 (1)	C2—C5—H5a	108.1
O4—K5—O7^x	76.5 (1)	C6—C5—H5a	108.1
O11^vii—K5—O7^x	90.7 (1)	C2—C5—H5b	108.1
O4w^iv—K5—O7^x	102.0 (2)	C6—C5—H5b	108.1
O2w^iii—K5—O7^x	125.9 (1)	H5a—C5—H5b	107.3
O4—K5—O14^viii	94.7 (1)	C10—C9—H9a	108.3
O11^vii—K5—O14^viii	74.7 (1)	C8—C9—H9a	108.3
O4w^iv—K5—O14^viii	93.1 (1)	C10—C9—H9b	108.3
O2w^iii—K5—O14^viii	73.9 (1)	C8—C9—H9b	108.3
O7^x—K5—O14^viii	157.9 (1)	H9a—C9—H9b	107.4
O7^x—K5—O1w^iii	71.9 (1)	C12—C11—H11a	108.3
C1—O1—Mn1	110.6 (3)	C8—C11—H11a	108.3
C1—O1—K1	99.4 (3)	C12—C11—H11b	108.3
Mn1—O1—K1	147.2 (2)	C8—C11—H11b	108.3
K1—O1—K2	85.7 (1)	H11a—C11—H11b	107.4
C1—O2—K2^v	119.0 (3)
O5^i—Mn1—O1—C1	−155.4 (3)	O10—Mn2—O12—C8	56.9 (3)
O5—Mn1—O1—C1	24.6 (3)	O10^ii—Mn2—O12—C8	−123.1 (3)
O3^i—Mn1—O1—C1	117.8 (3)	O8—Mn2—O12—K3^xi	99.1 (1)
O3—Mn1—O1—C1	−62.2 (3)	O8^ii—Mn2—O12—K3^xi	−80.9 (1)
O5^i—Mn1—O1—K1	−0.5 (3)	O10—Mn2—O12—K3^xi	−173.6 (1)
O5—Mn1—O1—K1	179.5 (3)	O10^ii—Mn2—O12—K3^xi	6.4 (1)
O3^i—Mn1—O1—K1	−87.4 (3)	O9^viii—K4—O13—C12	140.3 (9)
O3—Mn1—O1—K1	92.6 (3)	O10^ii—K4—O13—C12	−10.1 (9)
O3^iii—K1—O1—C1	143.9 (3)	O14^ix—K4—O13—C12	66.7 (9)
O5^iv—K1—O1—C1	71.6 (3)	O3w—K4—O13—C12	−80.1 (9)
O7^v—K1—O1—C1	−110.8 (3)	O13^viii—K4—O13—C12	−155 (1)
O6^v—K1—O1—C1	−77.4 (3)	O8—K4—O13—C12	−70.7 (9)
O1w—K1—O1—C1	−168.6 (3)	O4w—K4—O13—C12	66.0 (15)
O2—K1—O1—C1	0.2 (3)	O9^viii—K4—O13—K3^viii	22.8 (1)
O3^iii—K1—O1—Mn1	−12.3 (4)	O10^ii—K4—O13—K3^viii	−127.6 (1)
O5^iv—K1—O1—Mn1	−84.6 (3)	O14^ix—K4—O13—K3^viii	−50.8 (1)
O7^v—K1—O1—Mn1	93.0 (3)	O3w—K4—O13—K3^viii	162.4 (1)
O6^v—K1—O1—Mn1	126.4 (3)	O13^viii—K4—O13—K3^viii	88.0 (1)
O1w—K1—O1—Mn1	35.2 (3)	O8—K4—O13—K3^viii	171.8 (1)
O2—K1—O1—Mn1	−156.0 (4)	O4w—K4—O13—K3^viii	−52 (1)
O2—K1—O1—K2	104.2 (2)	O9^viii—K4—O13—K4^viii	−65.2 (1)
O6—K2—O1—Mn1	98.0 (1)	O10^ii—K4—O13—K4^viii	144.4 (1)
O6—K2—O1—K1	−114.7 (1)	O14^ix—K4—O13—K4^viii	−138.7 (1)
O3^iii—K1—O2—C1	−93.2 (4)	O3w—K4—O13—K4^viii	74.5 (2)
O5^iv—K1—O2—C1	−116.7 (3)	O13^viii—K4—O13—K4^viii	0.0
O1—K1—O2—C1	−0.2 (3)	O8—K4—O13—K4^viii	83.8 (1)
O7^v—K1—O2—C1	101.5 (3)	O4w—K4—O13—K4^viii	−139 (1)
O6^v—K1—O2—C1	97.9 (3)	O9^viii—K4—O13—K3^xi	118.9 (1)
O1w—K1—O2—C1	10.6 (3)	O10^ii—K4—O13—K3^xi	−31.5 (1)
O3^iii—K1—O2—K2^v	147.8 (2)	O14^ix—K4—O13—K3^xi	45.3 (1)
O5^iv—K1—O2—K2^v	124.3 (1)	O3w—K4—O13—K3^xi	−101.5 (1)
O1—K1—O2—K2^v	−119.2 (2)	O13^viii—K4—O13—K3^xi	−176.0 (1)
O7^v—K1—O2—K2^v	−17.4 (2)	O8—K4—O13—K3^xi	−92.2 (1)
O6^v—K1—O2—K2^v	−21.1 (1)	O4w—K4—O13—K3^xi	45 (1)
O1w—K1—O2—K2^v	−108.4 (1)	O13^viii—K3—O3w—K4	−37.3 (1)
O5^i—Mn1—O3—C4	177.3 (4)	O10^vii—K3—O3w—K4	−162.5 (1)
O5—Mn1—O3—C4	−2.7 (4)	O8—K3—O3w—K4	57.3 (1)
O1—Mn1—O3—C4	81.6 (4)	O12^iv—K3—O3w—K4	152.8 (1)
O1^i—Mn1—O3—C4	−98.4 (4)	O14^viii—K3—O3w—K4	−83.3 (1)
O5^i—Mn1—O3—K1^iii	14.0 (1)	O9—K3—O3w—K4	43.0 (1)
O5—Mn1—O3—K1^iii	−166.0 (1)	O13^iv—K3—O3w—K4	−102.4 (2)
O1—Mn1—O3—K1^iii	−81.7 (1)	O13—K4—O3w—K3	−44.7 (2)
O1^i—Mn1—O3—K1^iii	98.3 (1)	O9^viii—K4—O3w—K3	79.5 (2)
O5^i—Mn1—O3—K2^i	−73.8 (1)	O10^ii—K4—O3w—K3	−122.9 (1)
O5—Mn1—O3—K2^i	106.2 (1)	O14^ix—K4—O3w—K3	−170.7 (1)
O1—Mn1—O3—K2^i	−169.6 (1)	O13^viii—K4—O3w—K3	34.9 (1)
O1^i—Mn1—O3—K2^i	10.5 (1)	O8—K4—O3w—K3	−54.7 (1)
O11^vii—K5—O4—C4	−166.8 (4)	O4w—K4—O3w—K3	140.0 (2)
O4w^iv—K5—O4—C4	5.5 (7)	O13—K4—O4w—K5^xi	−8 (1)
O2w^iii—K5—O4—C4	43.9 (4)	O9^viii—K4—O4w—K5^xi	−82.2 (1)
O7^x—K5—O4—C4	−82.7 (4)	O10^ii—K4—O4w—K5^xi	68.3 (1)
O14^viii—K5—O4—C4	117.9 (4)	O14^ix—K4—O4w—K5^xi	−8.8 (1)
O11^vii—K5—O4—K2^i	−68.6 (2)	O3w—K4—O4w—K5^xi	140.7 (2)
O4w^iv—K5—O4—K2^i	103.8 (4)	O13^viii—K4—O4w—K5^xi	−147.2 (1)
O2w^iii—K5—O4—K2^i	142.2 (1)	O8—K4—O4w—K5^xi	126.5 (1)
O7^x—K5—O4—K2^i	15.6 (1)	K2^v—O2—C1—O1	91.1 (5)
O14^viii—K5—O4—K2^i	−143.8 (1)	K1—O2—C1—O1	0.3 (5)
O1—Mn1—O5—C2	−32.0 (3)	K2^v—O2—C1—C2	−91.8 (5)
O1^i—Mn1—O5—C2	148.0 (3)	K1—O2—C1—C2	177.4 (4)
O3^i—Mn1—O5—C2	−123.2 (3)	Mn1—O1—C1—O2	166.1 (4)
O3—Mn1—O5—C2	56.8 (3)	K1—O1—C1—O2	−0.4 (6)
O1—Mn1—O5—K1^xi	105.1 (1)	Mn1—O1—C1—C2	−11.1 (5)
O1^i—Mn1—O5—K1^xi	−74.9 (1)	K1—O1—C1—C2	−177.6 (3)
O3^i—Mn1—O5—K1^xi	14.0 (1)	Mn1—O5—C2—C5	155.2 (3)
O3—Mn1—O5—K1^xi	−166.0 (1)	K1^xi—O5—C2—C5	31.7 (5)
O2^v—K2—O6—C6	134.2 (9)	Mn1—O5—C2—C3	−86.6 (4)
O3^i—K2—O6—C6	−19.2 (9)	K1^xi—O5—C2—C3	149.8 (3)
O4^i—K2—O6—C6	−0.5 (10)	Mn1—O5—C2—C1	33.0 (4)
O7^vi—K2—O6—C6	59.2 (9)	K1^xi—O5—C2—C1	−90.5 (4)
O6^v—K2—O6—C6	−157 (1)	O2—C1—C2—O5	168.7 (5)
O2^v—K2—O6—K1^v	23.3 (1)	O1—C1—C2—O5	−14.0 (6)
O3^i—K2—O6—K1^v	−130.2 (1)	O2—C1—C2—C5	48.1 (6)
O4^i—K2—O6—K1^v	−111.4 (2)	O1—C1—C2—C5	−134.7 (5)
O7^vi—K2—O6—K1^v	−51.7 (1)	O2—C1—C2—C3	−71.7 (6)
O6^v—K2—O6—K1^v	91.9 (1)	O1—C1—C2—C3	105.6 (5)
O3^i—K2—O6—K2^v	137.9 (1)	O5—C2—C3—C4	47.0 (5)
O4^i—K2—O6—K2^v	156.7 (1)	C5—C2—C3—C4	165.8 (4)
O7^vi—K2—O6—K2^v	−143.6 (1)	C1—C2—C3—C4	−72.3 (5)
O6^v—K2—O6—K2^v	0.0	K5—O4—C4—O3	78.8 (5)
O2^v—K2—O6—K1^xi	118.8 (1)	K2^i—O4—C4—O3	−29.6 (4)
O3^i—K2—O6—K1^xi	−34.7 (1)	K5—O4—C4—C3	−103.7 (4)
O4^i—K2—O6—K1^xi	−16.0 (2)	K2^i—O4—C4—C3	147.9 (4)
O7^vi—K2—O6—K1^xi	43.8 (1)	Mn1—O3—C4—O4	147.4 (4)
O6^v—K2—O6—K1^xi	−172.6 (1)	K1^iii—O3—C4—O4	−56.9 (7)
O12^ii—Mn2—O8—C7	−156.4 (3)	K2^i—O3—C4—O4	31.2 (5)
O12—Mn2—O8—C7	23.6 (3)	Mn1—O3—C4—C3	−30.1 (6)
O10—Mn2—O8—C7	−62.9 (3)	K1^iii—O3—C4—C3	125.6 (4)
O10^ii—Mn2—O8—C7	117.1 (3)	K2^i—O3—C4—C3	−146.3 (4)
O12^ii—Mn2—O8—K3	−11.2 (3)	K1^iii—O3—C4—K5	−14.2 (5)
O12—Mn2—O8—K3	168.8 (3)	C2—C3—C4—O4	−164.6 (4)
O10—Mn2—O8—K3	82.3 (3)	C2—C3—C4—O3	13.0 (6)
O10^ii—Mn2—O8—K3	−97.7 (3)	O5—C2—C5—C6	−61.0 (6)
O12^ii—Mn2—O8—K4	91.3 (1)	C3—C2—C5—C6	−179.9 (4)
O12—Mn2—O8—K4	−88.7 (1)	C1—C2—C5—C6	59.5 (6)
O10—Mn2—O8—K4	−175.2 (1)	K2—O6—C6—O7	−101.5 (9)
O10^ii—Mn2—O8—K4	4.8 (1)	K1^v—O6—C6—O7	9.3 (5)
O13^viii—K3—O8—C7	−80.1 (3)	K2^v—O6—C6—O7	102.1 (5)
O10^vii—K3—O8—C7	148.0 (3)	K1^xi—O6—C6—O7	−86.2 (5)
O12^iv—K3—O8—C7	75.6 (3)	K2—O6—C6—C5	80 (1)
O3w—K3—O8—C7	−161.5 (3)	K1^v—O6—C6—C5	−169.4 (4)
O14^viii—K3—O8—C7	−114.7 (3)	K2^v—O6—C6—C5	−76.6 (5)
O9—K3—O8—C7	−1.1 (3)	K1^xi—O6—C6—C5	95.1 (4)
O13^iv—K3—O8—C7	−0.9 (4)	K1^v—O7—C6—O6	−9.3 (5)
O13^viii—K3—O8—Mn2	132.4 (3)	K2^vi—O7—C6—O6	72.5 (8)
O10^vii—K3—O8—Mn2	0.5 (4)	K5^xii—O7—C6—O6	−117.9 (5)
O12^iv—K3—O8—Mn2	−71.9 (3)	K1^v—O7—C6—C5	169.5 (4)
O3w—K3—O8—Mn2	51.0 (3)	K2^vi—O7—C6—C5	−108.8 (6)
O14^viii—K3—O8—Mn2	97.8 (3)	K5^xii—O7—C6—C5	60.9 (5)
O9—K3—O8—Mn2	−148.6 (4)	C2—C5—C6—O6	−27.9 (7)
O13^iv—K3—O8—Mn2	−148.4 (2)	C2—C5—C6—O7	153.3 (5)
O13^viii—K3—O8—K4	25.3 (1)	K4^viii—O9—C7—O8	88.9 (5)
O10^vii—K3—O8—K4	−106.6 (1)	K3—O9—C7—O8	−2.2 (5)
O12^iv—K3—O8—K4	−179.0 (1)	K4^viii—O9—C7—C8	−97.3 (5)
O3w—K3—O8—K4	−56.1 (1)	K3—O9—C7—C8	171.6 (4)
O14^viii—K3—O8—K4	−9.3 (2)	Mn2—O8—C7—O9	163.4 (4)
O9—K3—O8—K4	104.2 (2)	K3—O8—C7—O9	2.3 (5)
O13^iv—K3—O8—K4	104.5 (2)	K4—O8—C7—O9	−86.5 (5)
O13—K4—O8—C7	−17.9 (3)	Mn2—O8—C7—C8	−10.9 (5)
O9^viii—K4—O8—C7	38.2 (4)	K3—O8—C7—C8	−172.0 (3)
O10^ii—K4—O8—C7	−120.6 (3)	K4—O8—C7—C8	99.2 (4)
O14^ix—K4—O8—C7	−76.9 (3)	Mn2—O12—C8—C11	154.0 (3)
O3w—K4—O8—C7	153.6 (3)	K3^xi—O12—C8—C11	33.6 (5)
O13^viii—K4—O8—C7	73.4 (3)	Mn2—O12—C8—C9	−85.0 (4)
O4w—K4—O8—C7	167.6 (3)	K3^xi—O12—C8—C9	154.7 (3)
O13—K4—O8—Mn2	98.5 (1)	Mn2—O12—C8—C7	31.3 (4)
O9^viii—K4—O8—Mn2	154.5 (1)	K3^xi—O12—C8—C7	−89.0 (4)
O10^ii—K4—O8—Mn2	−4.2 (1)	O9—C7—C8—O12	172.9 (4)
O14^ix—K4—O8—Mn2	39.5 (2)	O8—C7—C8—O12	−12.8 (6)
O3w—K4—O8—Mn2	−90.0 (2)	O9—C7—C8—C11	50.9 (6)
O13^viii—K4—O8—Mn2	−170.2 (1)	O8—C7—C8—C11	−134.8 (4)
O4w—K4—O8—Mn2	−76.1 (2)	O9—C7—C8—C9	−68.4 (6)
O13—K4—O8—K3	−114.9 (1)	O8—C7—C8—C9	105.9 (5)
O9^viii—K4—O8—K3	−58.9 (2)	O12—C8—C9—C10	62.6 (5)
O10^ii—K4—O8—K3	142.4 (1)	C11—C8—C9—C10	−175.9 (4)
O14^ix—K4—O8—K3	−173.9 (1)	C7—C8—C9—C10	−55.5 (5)
O3w—K4—O8—K3	56.6 (1)	K5^vii—O11—C10—O10	−77.4 (6)
O13^viii—K4—O8—K3	−23.6 (1)	K5^vii—O11—C10—C9	103.6 (5)
O4w—K4—O8—K3	70.6 (1)	Mn2—O10—C10—O11	−163.0 (4)
O13^viii—K3—O9—C7	99.4 (3)	K3^vii—O10—C10—O11	−26.7 (7)
O10^vii—K3—O9—C7	−77.4 (4)	K4^ii—O10—C10—O11	72.7 (5)
O8—K3—O9—C7	1.2 (3)	Mn2—O10—C10—C9	15.9 (6)
O12^iv—K3—O9—C7	−112.6 (3)	K3^vii—O10—C10—C9	152.2 (3)
O3w—K3—O9—C7	19.2 (3)	K4^ii—O10—C10—C9	−108.4 (4)
O14^viii—K3—O9—C7	101.8 (3)	C8—C9—C10—O11	152.1 (4)
O13^iv—K3—O9—C7	−178.6 (3)	C8—C9—C10—O10	−26.9 (6)
O13^viii—K3—O9—K4^viii	−21.0 (1)	O12—C8—C11—C12	−65.6 (6)
O10^vii—K3—O9—K4^viii	162.1 (2)	C9—C8—C11—C12	173.0 (4)
O8—K3—O9—K4^viii	−119.3 (2)	C7—C8—C11—C12	55.8 (6)
O12^iv—K3—O9—K4^viii	127.0 (1)	K4^ix—O14—C12—O13	69.8 (8)
O3w—K3—O9—K4^viii	−101.3 (1)	K3^viii—O14—C12—O13	−9.2 (5)
O14^viii—K3—O9—K4^viii	−18.7 (2)	K5^viii—O14—C12—O13	−142.1 (4)
O13^iv—K3—O9—K4^viii	60.9 (1)	K3^xi—O14—C12—O13	76.9 (5)
O12^ii—Mn2—O10—C10	151.9 (4)	K4^ix—O14—C12—C11	−111.5 (6)
O12—Mn2—O10—C10	−28.1 (4)	K3^viii—O14—C12—C11	169.4 (4)
O8—Mn2—O10—C10	56.3 (4)	K5^viii—O14—C12—C11	36.5 (6)
O8^ii—Mn2—O10—C10	−123.7 (4)	K3^xi—O14—C12—C11	−104.4 (5)
O12^ii—Mn2—O10—K3^vii	6.4 (1)	K4—O13—C12—O14	−106.9 (9)
O12—Mn2—O10—K3^vii	−173.6 (1)	K3^viii—O13—C12—O14	9.7 (6)
O8—Mn2—O10—K3^vii	−89.2 (1)	K4^viii—O13—C12—O14	100.0 (5)
O8^ii—Mn2—O10—K3^vii	90.8 (1)	K3^xi—O13—C12—O14	−85.4 (5)
O12^ii—Mn2—O10—K4^ii	−79.4 (1)	K4—O13—C12—C11	74 (1)
O12—Mn2—O10—K4^ii	100.6 (1)	K3^viii—O13—C12—C11	−168.9 (4)
O8—Mn2—O10—K4^ii	−175.0 (1)	K4^viii—O13—C12—C11	−78.7 (5)
O8^ii—Mn2—O10—K4^ii	5.0 (1)	K3^xi—O13—C12—C11	96.0 (4)
O8—Mn2—O12—C8	−30.5 (3)	C8—C11—C12—O14	155.9 (5)
O8^ii—Mn2—O12—C8	149.5 (3)	C8—C11—C12—O13	−25.3 (7)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, −y+2, −z+2; (iii) −x, −y+1, −z+1; (iv) x−1, y, z; (v) −x+1, −y, −z+1; (vi) −x+2, −y, −z+1; (vii) −x, −y+2, −z+2; (viii) −x+1, −y+1, −z+2; (ix) −x+2, −y+1, −z+2; (x) x−1, y+1, z; (xi) x+1, y, z; (xii) x+1, y−1, z.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O1w—H1w2···O5^i	0.98	2.00	2.919 (6)	157
O2w—H2w1···O9^xiii	0.98	1.95	2.902 (5)	165
O2w—H2w2···O1w	0.99	2.14	2.830 (6)	125
O3w—H3w2···O11^vii	0.97	2.22	2.828 (5)	120
O3w—H3w1···O12^ii	0.97	2.13	2.992 (5)	148
O4w—H4w1···O4	0.97	1.92	2.828 (6)	153
O4w—H4w2···O3w	0.97	2.56	2.903 (7)	101
O5w—H5w1···O2	0.98	1.82	2.792 (6)	171
O5w—H5w2···O11^xiv	0.98	2.06	2.822 (6)	134

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, −y+2, −z+2; (vii) −x, −y+2, −z+2; (xiii) x, y, z−1; (xiv) −x, −y+1, −z+2.