metal-organic compounds
The centrosymmetric title compound, Na(H)[Rh2(C2H3O2)6], consists of dirhodium(II) tetraacetate with two additional axial acetate ligands. Charges are balanced by a sodium ion and a disordered proton. The sodium coordination sphere includes O atoms bound equatorially to the rhodium as well as O atoms from the axial acetates. The Rh-Rh distance is 2.3827 (5) Å, Rh-O(axial) is 2.279 (2) Å, and the average Rh-O(equatorial) distance is 2.040 (4) Å.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129708