metal-organic compounds
The structure of bis(1,4,7-trithiacyclononane)palladium(II) bis(dibromoiodide), [Pd(C6H12S3)2](IBr2)2 comprises ribbons in which neighbouring cations are linked by pairs of anions through SBr contacts of 3.767 (5)–3.877 (5) Å. In (1,4,8,11-tetrathiacyclotetradecane)palladium(II) bis(dibromoiodide), [Pd(C10H20S4)2](IBr2)2, PdI, SBr and SI contacts link cations and anions into an infinite three-dimensional network.