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The structure of bis(1,4,7-trithiacyclononane)palladium(II) bis(dibromoiodide), [Pd(C6H12S3)2](IBr2)2 comprises ribbons in which neighbouring cations are linked by pairs of anions through S...Br contacts of 3.767 (5)–3.877 (5) Å. In (1,4,8,11-tetrathiacyclotetradecane)palladium(II) bis(dibromoiodide), [Pd(C10H20S4)2](IBr2)2, Pd...I, S...Br and S...I contacts link cations and anions into an infinite three-dimensional network.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1, 2, global

fcf

Structure factor file (CIF format)
Contains datablock 1

fcf

Structure factor file (CIF format)
Contains datablock 2

CCDC references: 129712; 129713

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