In the title complex, (C24H20P)2[Cu(C3S5)2], the CuII ion is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands in a distorted planar geometry. The anion possesses C2 symmetry with the metal ion lying on a twofold axis.
Supporting information
CCDC reference: 630010
Key indicators
- Single-crystal X-ray study
- T = 295 K
- Mean (C-C) = 0.007 Å
- R factor = 0.047
- wR factor = 0.137
- Data-to-parameter ratio = 17.0
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
1 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
0 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
0 ALERT type 5 Informative message, check
Data collection: XSCANS (Bruker,1996); cell refinement: XSCANS; data reduction: SHELXTL (Bruker, 1997); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: WinGX (Farrugia,1999).
bis(tetraphenylphosphonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)
top
Crystal data top
(C24H20P)2[Cu(C3S5)2] | F(000) = 2332 |
Mr = 1134.94 | Dx = 1.436 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 38 reflections |
a = 20.255 (3) Å | θ = 4.7–12.5° |
b = 12.6669 (17) Å | µ = 0.91 mm−1 |
c = 20.499 (2) Å | T = 295 K |
β = 93.772 (10)° | Prism, dark red |
V = 5248.2 (12) Å3 | 0.36 × 0.34 × 0.30 mm |
Z = 4 | |
Data collection top
Bruker P4 diffractometer | 3172 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.031 |
Graphite monochromator | θmax = 26.0°, θmin = 1.9° |
ω scans | h = −24→1 |
Absorption correction: ψ scan (XSCANS; Bruker,1996) | k = −15→1 |
Tmin = 0.710, Tmax = 0.765 | l = −25→25 |
6171 measured reflections | 3 standard reflections every 97 reflections |
5167 independent reflections | intensity decay: 1% |
Refinement top
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.047 | H-atom parameters constrained |
wR(F2) = 0.137 | w = 1/[σ2(Fo2) + (0.0617P)2 + 1.9578P] where P = (Fo2 + 2Fc2)/3 |
S = 1.03 | (Δ/σ)max = 0.001 |
5167 reflections | Δρmax = 0.41 e Å−3 |
304 parameters | Δρmin = −0.56 e Å−3 |
1 restraint | Extinction correction: SHELXTL, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.0036 (2) |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
C1 | 0.6646 (2) | 0.4692 (3) | 0.9726 (2) | 0.0538 (11) | |
C2 | 0.56219 (19) | 0.5035 (3) | 0.88999 (19) | 0.0454 (10) | |
C3 | 0.61538 (19) | 0.5208 (3) | 0.85513 (19) | 0.0448 (10) | |
C4 | 0.6268 (2) | 0.1882 (5) | 0.8584 (3) | 0.0752 (15) | |
H4 | 0.6712 | 0.2035 | 0.8543 | 0.090* | |
C5 | 0.5802 (2) | 0.2542 (4) | 0.8311 (3) | 0.0696 (14) | |
H5 | 0.5926 | 0.3124 | 0.8071 | 0.083* | |
C6 | 0.5131 (2) | 0.2344 (4) | 0.8393 (2) | 0.0590 (12) | |
H6 | 0.4808 | 0.2796 | 0.8210 | 0.071* | |
C7 | 0.4955 (2) | 0.1473 (3) | 0.8745 (2) | 0.0501 (10) | |
C8 | 0.5438 (2) | 0.0788 (4) | 0.8997 (3) | 0.0749 (15) | |
H8 | 0.5319 | 0.0184 | 0.9220 | 0.090* | |
C9 | 0.6103 (2) | 0.0999 (5) | 0.8918 (3) | 0.0824 (17) | |
H9 | 0.6430 | 0.0545 | 0.9090 | 0.099* | |
C10 | 0.4001 (2) | 0.1600 (3) | 0.9755 (2) | 0.0479 (10) | |
C11 | 0.4520 (2) | 0.1991 (4) | 1.0166 (2) | 0.0603 (12) | |
H11 | 0.4946 | 0.2036 | 1.0024 | 0.072* | |
C12 | 0.4388 (3) | 0.2313 (4) | 1.0795 (2) | 0.0724 (14) | |
H12 | 0.4729 | 0.2580 | 1.1073 | 0.087* | |
C13 | 0.3769 (3) | 0.2243 (4) | 1.1006 (2) | 0.0717 (14) | |
H13 | 0.3691 | 0.2444 | 1.1430 | 0.086* | |
C14 | 0.3258 (3) | 0.1879 (4) | 1.0596 (3) | 0.0720 (14) | |
H14 | 0.2833 | 0.1847 | 1.0741 | 0.086* | |
C15 | 0.3368 (2) | 0.1562 (4) | 0.9977 (2) | 0.0595 (12) | |
H15 | 0.3018 | 0.1319 | 0.9702 | 0.071* | |
C16 | 0.39723 (19) | −0.0171 (3) | 0.8806 (2) | 0.0491 (10) | |
C17 | 0.3675 (2) | −0.0773 (4) | 0.9259 (2) | 0.0607 (12) | |
H17 | 0.3527 | −0.0458 | 0.9632 | 0.073* | |
C18 | 0.3593 (3) | −0.1852 (4) | 0.9161 (3) | 0.0717 (15) | |
H18 | 0.3405 | −0.2261 | 0.9477 | 0.086* | |
C19 | 0.3783 (3) | −0.2305 (4) | 0.8615 (3) | 0.0825 (17) | |
H19 | 0.3715 | −0.3025 | 0.8549 | 0.099* | |
C20 | 0.4076 (3) | −0.1720 (5) | 0.8149 (3) | 0.0813 (17) | |
H20 | 0.4204 | −0.2044 | 0.7771 | 0.098* | |
C21 | 0.4181 (2) | −0.0639 (4) | 0.8242 (2) | 0.0694 (14) | |
H21 | 0.4387 | −0.0241 | 0.7932 | 0.083* | |
C22 | 0.3529 (2) | 0.1981 (4) | 0.8436 (2) | 0.0508 (11) | |
C23 | 0.3504 (2) | 0.3067 (4) | 0.8533 (2) | 0.0612 (12) | |
H23 | 0.3796 | 0.3387 | 0.8841 | 0.073* | |
C24 | 0.3047 (2) | 0.3664 (4) | 0.8173 (3) | 0.0762 (16) | |
H24 | 0.3032 | 0.4391 | 0.8232 | 0.091* | |
C25 | 0.2609 (2) | 0.3176 (6) | 0.7724 (3) | 0.0845 (18) | |
H25 | 0.2301 | 0.3583 | 0.7479 | 0.101* | |
C26 | 0.2619 (2) | 0.2117 (5) | 0.7632 (3) | 0.0764 (16) | |
H26 | 0.2315 | 0.1803 | 0.7333 | 0.092* | |
C27 | 0.3080 (2) | 0.1506 (4) | 0.7983 (2) | 0.0632 (13) | |
H27 | 0.3090 | 0.0779 | 0.7918 | 0.076* | |
P1 | 0.41176 (5) | 0.12196 (9) | 0.89291 (5) | 0.0461 (3) | |
S1 | 0.71469 (6) | 0.44289 (12) | 1.03735 (7) | 0.0756 (4) | |
S2 | 0.57977 (5) | 0.46807 (11) | 0.97176 (5) | 0.0593 (3) | |
S3 | 0.69188 (5) | 0.50274 (10) | 0.89724 (6) | 0.0570 (3) | |
S4 | 0.48114 (5) | 0.50977 (10) | 0.85744 (5) | 0.0526 (3) | |
S5 | 0.61057 (5) | 0.55640 (10) | 0.77355 (5) | 0.0582 (3) | |
Cu1 | 0.5000 | 0.53565 (6) | 0.7500 | 0.0440 (2) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
C1 | 0.055 (3) | 0.048 (3) | 0.057 (3) | −0.007 (2) | −0.004 (2) | 0.003 (2) |
C2 | 0.042 (2) | 0.052 (3) | 0.042 (2) | −0.0049 (19) | 0.0000 (18) | 0.0052 (19) |
C3 | 0.042 (2) | 0.046 (2) | 0.045 (2) | −0.0084 (19) | −0.0018 (18) | −0.0023 (19) |
C4 | 0.048 (3) | 0.098 (4) | 0.080 (4) | −0.004 (3) | 0.011 (3) | 0.000 (3) |
C5 | 0.062 (3) | 0.066 (3) | 0.084 (4) | −0.015 (3) | 0.029 (3) | −0.004 (3) |
C6 | 0.063 (3) | 0.050 (3) | 0.063 (3) | −0.005 (2) | 0.003 (2) | 0.005 (2) |
C7 | 0.046 (2) | 0.051 (3) | 0.053 (2) | −0.006 (2) | 0.001 (2) | 0.004 (2) |
C8 | 0.064 (3) | 0.073 (4) | 0.088 (4) | 0.002 (3) | 0.007 (3) | 0.027 (3) |
C9 | 0.053 (3) | 0.111 (5) | 0.084 (4) | 0.007 (3) | 0.007 (3) | 0.017 (4) |
C10 | 0.052 (2) | 0.039 (2) | 0.052 (2) | −0.001 (2) | −0.003 (2) | −0.002 (2) |
C11 | 0.048 (3) | 0.057 (3) | 0.075 (3) | 0.002 (2) | −0.007 (2) | −0.006 (3) |
C12 | 0.086 (3) | 0.064 (3) | 0.064 (3) | −0.001 (3) | −0.021 (3) | −0.015 (3) |
C13 | 0.092 (4) | 0.064 (3) | 0.059 (3) | 0.006 (3) | 0.006 (3) | −0.009 (3) |
C14 | 0.073 (3) | 0.071 (4) | 0.073 (3) | −0.007 (3) | 0.018 (3) | −0.010 (3) |
C15 | 0.051 (3) | 0.065 (3) | 0.063 (3) | −0.007 (2) | 0.009 (2) | −0.009 (2) |
C16 | 0.042 (2) | 0.050 (3) | 0.054 (2) | 0.000 (2) | −0.0030 (19) | −0.004 (2) |
C17 | 0.072 (3) | 0.046 (3) | 0.064 (3) | −0.005 (2) | 0.000 (2) | 0.002 (2) |
C18 | 0.076 (4) | 0.050 (3) | 0.087 (4) | −0.014 (3) | −0.009 (3) | 0.006 (3) |
C19 | 0.080 (4) | 0.054 (3) | 0.108 (5) | 0.000 (3) | −0.032 (4) | −0.010 (3) |
C20 | 0.077 (4) | 0.077 (4) | 0.089 (4) | 0.010 (3) | −0.007 (3) | −0.038 (3) |
C21 | 0.068 (3) | 0.076 (4) | 0.064 (3) | −0.012 (3) | 0.006 (3) | −0.016 (3) |
C22 | 0.042 (2) | 0.060 (3) | 0.050 (2) | −0.009 (2) | 0.0017 (19) | 0.011 (2) |
C23 | 0.051 (3) | 0.061 (3) | 0.072 (3) | 0.001 (2) | 0.001 (2) | 0.011 (3) |
C24 | 0.057 (3) | 0.067 (4) | 0.106 (4) | 0.005 (3) | 0.020 (3) | 0.025 (3) |
C25 | 0.045 (3) | 0.110 (5) | 0.099 (4) | 0.009 (3) | 0.007 (3) | 0.045 (4) |
C26 | 0.039 (3) | 0.114 (5) | 0.074 (3) | −0.007 (3) | −0.009 (2) | 0.027 (3) |
C27 | 0.050 (3) | 0.076 (3) | 0.063 (3) | −0.010 (3) | 0.001 (2) | 0.010 (3) |
P1 | 0.0393 (6) | 0.0470 (6) | 0.0516 (6) | −0.0061 (5) | 0.0003 (5) | 0.0037 (5) |
S1 | 0.0562 (7) | 0.0977 (11) | 0.0699 (8) | −0.0153 (7) | −0.0189 (6) | 0.0261 (8) |
S2 | 0.0443 (6) | 0.0877 (9) | 0.0455 (6) | −0.0039 (6) | 0.0001 (5) | 0.0108 (6) |
S3 | 0.0389 (6) | 0.0737 (8) | 0.0581 (7) | −0.0078 (6) | 0.0001 (5) | 0.0057 (6) |
S4 | 0.0377 (5) | 0.0731 (8) | 0.0471 (6) | 0.0032 (5) | 0.0025 (4) | 0.0048 (6) |
S5 | 0.0510 (6) | 0.0801 (9) | 0.0434 (6) | −0.0155 (6) | 0.0035 (5) | 0.0053 (6) |
Cu1 | 0.0452 (4) | 0.0435 (4) | 0.0429 (4) | 0.000 | 0.0008 (3) | 0.000 |
Geometric parameters (Å, º) top
C1—S1 | 1.650 (4) | C14—H14 | 0.9300 |
C1—S2 | 1.717 (4) | C15—H15 | 0.9300 |
C1—S3 | 1.728 (4) | C16—C17 | 1.370 (6) |
C2—C3 | 1.349 (5) | C16—C21 | 1.391 (6) |
C2—S4 | 1.733 (4) | C16—P1 | 1.801 (4) |
C2—S2 | 1.749 (4) | C17—C18 | 1.390 (6) |
C3—S5 | 1.728 (4) | C17—H17 | 0.9300 |
C3—S3 | 1.739 (4) | C18—C19 | 1.336 (7) |
C4—C5 | 1.354 (7) | C18—H18 | 0.9300 |
C4—C9 | 1.364 (7) | C19—C20 | 1.374 (8) |
C4—H4 | 0.9300 | C19—H19 | 0.9300 |
C5—C6 | 1.402 (6) | C20—C21 | 1.396 (7) |
C5—H5 | 0.9300 | C20—H20 | 0.9300 |
C6—C7 | 1.378 (6) | C21—H21 | 0.9300 |
C6—H6 | 0.9300 | C22—C23 | 1.391 (6) |
C7—C8 | 1.383 (6) | C22—C27 | 1.393 (6) |
C7—P1 | 1.791 (4) | C22—P1 | 1.794 (4) |
C8—C9 | 1.393 (6) | C23—C24 | 1.372 (6) |
C8—H8 | 0.9300 | C23—H23 | 0.9300 |
C9—H9 | 0.9300 | C24—C25 | 1.382 (7) |
C10—C15 | 1.389 (6) | C24—H24 | 0.9300 |
C10—C11 | 1.394 (6) | C25—C26 | 1.355 (8) |
C10—P1 | 1.791 (4) | C25—H25 | 0.9300 |
C11—C12 | 1.394 (6) | C26—C27 | 1.379 (6) |
C11—H11 | 0.9300 | C26—H26 | 0.9300 |
C12—C13 | 1.356 (7) | C27—H27 | 0.9300 |
C12—H12 | 0.9300 | S4—Cu1 | 2.2837 (11) |
C13—C14 | 1.369 (7) | S5—Cu1 | 2.2751 (11) |
C13—H13 | 0.9300 | Cu1—S5i | 2.2751 (11) |
C14—C15 | 1.363 (6) | Cu1—S4i | 2.2837 (11) |
| | | |
S1—C1—S2 | 124.7 (3) | C16—C17—H17 | 119.9 |
S1—C1—S3 | 123.6 (3) | C18—C17—H17 | 119.9 |
S2—C1—S3 | 111.8 (2) | C19—C18—C17 | 120.4 (5) |
C3—C2—S4 | 123.9 (3) | C19—C18—H18 | 119.8 |
C3—C2—S2 | 115.5 (3) | C17—C18—H18 | 119.8 |
S4—C2—S2 | 120.6 (2) | C18—C19—C20 | 120.7 (5) |
C2—C3—S5 | 124.0 (3) | C18—C19—H19 | 119.7 |
C2—C3—S3 | 115.6 (3) | C20—C19—H19 | 119.7 |
S5—C3—S3 | 120.4 (2) | C19—C20—C21 | 120.3 (5) |
C5—C4—C9 | 121.7 (5) | C19—C20—H20 | 119.8 |
C5—C4—H4 | 119.1 | C21—C20—H20 | 119.8 |
C9—C4—H4 | 119.1 | C16—C21—C20 | 118.6 (5) |
C4—C5—C6 | 119.6 (5) | C16—C21—H21 | 120.7 |
C4—C5—H5 | 120.2 | C20—C21—H21 | 120.7 |
C6—C5—H5 | 120.2 | C23—C22—C27 | 119.6 (4) |
C7—C6—C5 | 119.5 (5) | C23—C22—P1 | 118.7 (3) |
C7—C6—H6 | 120.2 | C27—C22—P1 | 121.6 (4) |
C5—C6—H6 | 120.2 | C24—C23—C22 | 119.9 (5) |
C6—C7—C8 | 119.8 (4) | C24—C23—H23 | 120.1 |
C6—C7—P1 | 122.4 (3) | C22—C23—H23 | 120.1 |
C8—C7—P1 | 117.7 (3) | C23—C24—C25 | 119.5 (5) |
C7—C8—C9 | 120.1 (5) | C23—C24—H24 | 120.3 |
C7—C8—H8 | 120.0 | C25—C24—H24 | 120.3 |
C9—C8—H8 | 120.0 | C26—C25—C24 | 121.3 (5) |
C4—C9—C8 | 119.1 (5) | C26—C25—H25 | 119.3 |
C4—C9—H9 | 120.4 | C24—C25—H25 | 119.3 |
C8—C9—H9 | 120.4 | C25—C26—C27 | 120.0 (5) |
C15—C10—C11 | 119.4 (4) | C25—C26—H26 | 120.0 |
C15—C10—P1 | 118.8 (3) | C27—C26—H26 | 120.0 |
C11—C10—P1 | 121.7 (3) | C26—C27—C22 | 119.6 (5) |
C12—C11—C10 | 118.6 (4) | C26—C27—H27 | 120.2 |
C12—C11—H11 | 120.7 | C22—C27—H27 | 120.2 |
C10—C11—H11 | 120.7 | C7—P1—C10 | 109.7 (2) |
C13—C12—C11 | 121.0 (5) | C7—P1—C22 | 112.9 (2) |
C13—C12—H12 | 119.5 | C10—P1—C22 | 105.3 (2) |
C11—C12—H12 | 119.5 | C7—P1—C16 | 107.1 (2) |
C12—C13—C14 | 120.3 (5) | C10—P1—C16 | 111.4 (2) |
C12—C13—H13 | 119.9 | C22—P1—C16 | 110.5 (2) |
C14—C13—H13 | 119.9 | C1—S2—C2 | 98.5 (2) |
C15—C14—C13 | 120.4 (5) | C1—S3—C3 | 98.6 (2) |
C15—C14—H14 | 119.8 | C2—S4—Cu1 | 99.41 (14) |
C13—C14—H14 | 119.8 | C3—S5—Cu1 | 99.63 (13) |
C14—C15—C10 | 120.4 (4) | S5i—Cu1—S5 | 166.73 (7) |
C14—C15—H15 | 119.8 | S5i—Cu1—S4i | 92.10 (4) |
C10—C15—H15 | 119.8 | S5—Cu1—S4i | 89.80 (4) |
C17—C16—C21 | 119.8 (4) | S5i—Cu1—S4 | 89.80 (4) |
C17—C16—P1 | 121.6 (3) | S5—Cu1—S4 | 92.10 (4) |
C21—C16—P1 | 118.5 (4) | S4i—Cu1—S4 | 163.49 (7) |
C16—C17—C18 | 120.2 (5) | | |
| | | |
S4—C2—C3—S5 | 2.3 (6) | C8—C7—P1—C22 | −167.3 (4) |
S2—C2—C3—S5 | 179.9 (2) | C6—C7—P1—C16 | 137.8 (4) |
S4—C2—C3—S3 | −176.5 (2) | C8—C7—P1—C16 | −45.4 (4) |
S2—C2—C3—S3 | 1.1 (5) | C15—C10—P1—C7 | 173.9 (4) |
C9—C4—C5—C6 | 2.6 (8) | C11—C10—P1—C7 | −2.2 (4) |
C4—C5—C6—C7 | −0.6 (7) | C15—C10—P1—C22 | 52.2 (4) |
C5—C6—C7—C8 | −2.0 (7) | C11—C10—P1—C22 | −123.9 (4) |
C5—C6—C7—P1 | 174.8 (4) | C15—C10—P1—C16 | −67.7 (4) |
C6—C7—C8—C9 | 2.6 (8) | C11—C10—P1—C16 | 116.2 (4) |
P1—C7—C8—C9 | −174.3 (4) | C23—C22—P1—C7 | −69.0 (4) |
C5—C4—C9—C8 | −2.0 (9) | C27—C22—P1—C7 | 114.1 (4) |
C7—C8—C9—C4 | −0.7 (8) | C23—C22—P1—C10 | 50.6 (4) |
C15—C10—C11—C12 | 1.2 (7) | C27—C22—P1—C10 | −126.3 (4) |
P1—C10—C11—C12 | 177.3 (4) | C23—C22—P1—C16 | 171.1 (3) |
C10—C11—C12—C13 | 0.4 (8) | C27—C22—P1—C16 | −5.9 (4) |
C11—C12—C13—C14 | −1.7 (8) | C17—C16—P1—C7 | 132.8 (4) |
C12—C13—C14—C15 | 1.3 (8) | C21—C16—P1—C7 | −46.0 (4) |
C13—C14—C15—C10 | 0.4 (8) | C17—C16—P1—C10 | 12.9 (4) |
C11—C10—C15—C14 | −1.6 (7) | C21—C16—P1—C10 | −165.9 (4) |
P1—C10—C15—C14 | −177.8 (4) | C17—C16—P1—C22 | −103.8 (4) |
C21—C16—C17—C18 | 1.3 (7) | C21—C16—P1—C22 | 77.4 (4) |
P1—C16—C17—C18 | −177.5 (4) | S1—C1—S2—C2 | 179.4 (3) |
C16—C17—C18—C19 | −2.4 (8) | S3—C1—S2—C2 | 0.0 (3) |
C17—C18—C19—C20 | 1.6 (8) | C3—C2—S2—C1 | −0.7 (4) |
C18—C19—C20—C21 | 0.2 (8) | S4—C2—S2—C1 | 176.9 (3) |
C17—C16—C21—C20 | 0.5 (7) | S1—C1—S3—C3 | −179.0 (3) |
P1—C16—C21—C20 | 179.3 (4) | S2—C1—S3—C3 | 0.4 (3) |
C19—C20—C21—C16 | −1.2 (8) | C2—C3—S3—C1 | −0.9 (4) |
C27—C22—C23—C24 | −1.3 (7) | S5—C3—S3—C1 | −179.8 (3) |
P1—C22—C23—C24 | −178.4 (3) | C3—C2—S4—Cu1 | 5.2 (4) |
C22—C23—C24—C25 | 0.9 (7) | S2—C2—S4—Cu1 | −172.2 (2) |
C23—C24—C25—C26 | 0.3 (8) | C2—C3—S5—Cu1 | −8.4 (4) |
C24—C25—C26—C27 | −1.1 (8) | S3—C3—S5—Cu1 | 170.4 (2) |
C25—C26—C27—C22 | 0.6 (7) | C3—S5—Cu1—S5i | 106.61 (14) |
C23—C22—C27—C26 | 0.6 (7) | C3—S5—Cu1—S4i | −155.06 (15) |
P1—C22—C27—C26 | 177.5 (3) | C3—S5—Cu1—S4 | 8.54 (15) |
C6—C7—P1—C10 | −101.2 (4) | C2—S4—Cu1—S5i | −174.58 (15) |
C8—C7—P1—C10 | 75.6 (4) | C2—S4—Cu1—S5 | −7.71 (15) |
C6—C7—P1—C22 | 15.9 (5) | C2—S4—Cu1—S4i | 88.69 (14) |
Symmetry code: (i) −x+1, y, −z+3/2. |