Di-μ-iodo-bis­[pyridine­(tri-p-tolyl­phosphine)silver(I)]

The title compound, [Ag₂I₂(C₅H₅N)₂(C₂₁H₂₁P)₂], has C_i mol­ecular symmetry. Each Ag atom is surrounded by a phosphine ligand, a pyridine ligand and two iodide anions in a distorted tetra­hedral coordination. The Ag...Ag separation in the binuclear species is 3.1130 (18) Å. The Ag—P distance is 2.4489 (12) Å, the Ag—N distance is 2.392 (3) Å, and the Ag—I distances are 2.8402 (14) and 2.8644 (8) Å.

Key indicators

• Single-crystal X-ray study
• T = 298 K
• Mean [sigma](C-C) = 0.007 Å
• Disorder in main residue
• R factor = 0.030
• wR factor = 0.078
• Data-to-parameter ratio = 14.9

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.06
PLAT301_ALERT_3_C Main Residue  Disorder .........................      12.00 Perc.
PLAT432_ALERT_2_C Short Inter X...Y Contact  C22B   ..  C23B    ..       3.11 Ang.

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: SMART-NT (Bruker, 1999); cell refinement: SAINT-Plus (Bruker, 1999); data reduction: SAINT-Plus and XPREP (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

Di-µ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]

Crystal data

C52H52Ag2I2N2P2	Z = 1
Mr = 1236.44	F(000) = 608
Triclinic, P1	Dx = 1.632 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.006 (2) Å	Cell parameters from 946 reflections
b = 11.957 (2) Å	θ = 3.4–27.8°
c = 12.184 (2) Å	µ = 2.10 mm^−1
α = 104.67 (3)°	T = 298 K
β = 113.24 (3)°	Cuboid, colourless
γ = 96.44 (3)°	0.44 × 0.24 × 0.22 mm
V = 1258.4 (6) Å^3

Data collection

Bruker SMART CCD area-detector diffractometer	4400 independent reflections
Radiation source: fine-focus sealed tube	3631 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.015
Detector resolution: 512 pixels mm^-1	θmax = 25°, θmin = 1.8°
φ and ω scans	h = −11→11
Absorption correction: multi-scan (SADABS; Bruker, 2004)	k = −12→14
Tmin = 0.440, Tmax = 0.629	l = −11→14
6862 measured reflections

Refinement

Refinement on F^2	8 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.03	w = 1/[σ^2(Fo^2) + (0.0385P)^2 + 0.8633P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.078	(Δ/σ)max < 0.001
S = 1.03	Δρmax = 1.05 e Å^−3
4400 reflections	Δρmin = −0.51 e Å^−3
295 parameters

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag	0.40816 (3)	0.37172 (3)	0.41150 (3)	0.05861 (11)
I	0.32215 (3)	0.58235 (2)	0.36615 (3)	0.06131 (11)
P	0.42104 (10)	0.24610 (9)	0.22467 (9)	0.0445 (2)
C11	0.4627 (4)	0.1032 (3)	0.2325 (3)	0.0446 (8)
C12	0.5363 (4)	0.0896 (3)	0.3498 (4)	0.0536 (9)
H12	0.56	0.1524	0.4227	0.064*
C13	0.5748 (4)	−0.0160 (4)	0.3596 (4)	0.0580 (10)
H13	0.6261	−0.0224	0.4393	0.07*
C14	0.5388 (4)	−0.1125 (3)	0.2537 (4)	0.0525 (9)
C15	0.4610 (5)	−0.0997 (4)	0.1376 (4)	0.0570 (10)
H15	0.4322	−0.1642	0.0649	0.068*
C16	0.4249 (4)	0.0054 (4)	0.1259 (4)	0.0548 (10)
H16	0.3746	0.0114	0.0459	0.066*
C17	0.5786 (6)	−0.2283 (4)	0.2638 (5)	0.0759 (13)
H17A	0.6834	−0.2206	0.2861	0.114*
H17B	0.5209	−0.2901	0.184	0.114*
H17C	0.557	−0.248	0.3276	0.114*
C21	0.2517 (4)	0.2091 (3)	0.0767 (3)	0.0452 (8)
C24	−0.0192 (4)	0.1549 (3)	−0.1437 (4)	0.0551 (10)
C27	−0.1620 (5)	0.1300 (4)	−0.2610 (4)	0.0754 (13)
H27A	−0.1992	0.2007	−0.2591	0.113*
H27B	−0.235	0.0676	−0.2651	0.113*
H27C	−0.1433	0.1056	−0.3339	0.113*
C22	0.1162 (9)	0.2037 (12)	0.0813 (7)	0.065 (3)	0.81 (2)
H22	0.1133	0.2186	0.159	0.078*	0.81 (2)
C23	−0.0156 (7)	0.1766 (13)	−0.0270 (7)	0.073 (3)	0.81 (2)
H23	−0.1053	0.173	−0.0203	0.088*	0.81 (2)
C25	0.1185 (7)	0.1614 (11)	−0.1486 (6)	0.059 (2)	0.81 (2)
H25	0.121	0.148	−0.2263	0.07*	0.81 (2)
C26	0.2508 (7)	0.1870 (12)	−0.0409 (7)	0.059 (2)	0.81 (2)
H26	0.3406	0.1896	−0.0473	0.071*	0.81 (2)
C22B	0.123 (5)	0.147 (4)	0.073 (4)	0.074 (11)	0.19 (2)
H22B	0.1257	0.1241	0.1417	0.089*	0.19 (2)
C23B	−0.020 (4)	0.118 (3)	−0.044 (3)	0.071 (10)*	0.19 (2)
H23B	−0.1077	0.075	−0.0503	0.085*	0.19 (2)
C25B	0.109 (3)	0.210 (3)	−0.131 (3)	0.055 (9)*	0.19 (2)
H25B	0.111	0.2374	−0.1958	0.065*	0.19 (2)
C26B	0.243 (4)	0.230 (3)	−0.025 (3)	0.041 (8)*	0.19 (2)
H26B	0.3313	0.2603	−0.027	0.05*	0.19 (2)
C31	0.5664 (4)	0.3147 (3)	0.1909 (3)	0.0447 (8)
C32	0.5510 (4)	0.4149 (4)	0.1533 (4)	0.0609 (10)
H32	0.4688	0.4466	0.148	0.073*
C33	0.6558 (5)	0.4676 (4)	0.1238 (4)	0.0670 (11)
H33	0.6418	0.5337	0.0974	0.08*
C34	0.7813 (4)	0.4255 (4)	0.1323 (4)	0.0618 (11)
C35	0.8001 (4)	0.3300 (4)	0.1770 (4)	0.0626 (11)
H35	0.8864	0.3023	0.1889	0.075*
C36	0.6937 (4)	0.2748 (4)	0.2043 (4)	0.0534 (9)
H36	0.7085	0.2097	0.2322	0.064*
C37	0.8918 (6)	0.4806 (5)	0.0947 (6)	0.0922 (16)
H37A	0.9711	0.4396	0.1072	0.138*	0.5
H37B	0.9329	0.5629	0.1455	0.138*	0.5
H37C	0.8422	0.4744	0.0072	0.138*	0.5
H37D	0.8597	0.545	0.0661	0.138*	0.5
H37E	0.8979	0.4217	0.0278	0.138*	0.5
H37F	0.9886	0.5102	0.1661	0.138*	0.5
N	0.2038 (4)	0.3047 (3)	0.4527 (3)	0.0577 (8)
C42	0.1603 (5)	0.3825 (4)	0.5214 (4)	0.0663 (11)
H42	0.2147	0.4613	0.5553	0.08*
C43	0.0411 (6)	0.3559 (6)	0.5466 (5)	0.0811 (14)
H43	0.0163	0.4147	0.5964	0.097*
C44	−0.0389 (6)	0.2430 (6)	0.4977 (5)	0.0896 (17)
H44	−0.1208	0.2221	0.5129	0.107*
C45	0.0005 (7)	0.1591 (5)	0.4257 (6)	0.0993 (18)
H45	−0.054	0.0803	0.3905	0.119*
C46	0.1239 (6)	0.1937 (4)	0.4059 (5)	0.0801 (14)
H46	0.1516	0.1361	0.3574	0.096*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag	0.0620 (2)	0.0649 (2)	0.05410 (19)	0.02197 (15)	0.03155 (15)	0.01485 (15)
I	0.05580 (17)	0.06029 (18)	0.06207 (18)	0.01919 (13)	0.01682 (13)	0.02327 (13)
P	0.0419 (5)	0.0534 (6)	0.0402 (5)	0.0159 (4)	0.0193 (4)	0.0144 (4)
C11	0.0412 (19)	0.054 (2)	0.0400 (19)	0.0126 (16)	0.0192 (15)	0.0146 (16)
C12	0.053 (2)	0.055 (2)	0.042 (2)	0.0081 (18)	0.0147 (17)	0.0111 (17)
C13	0.059 (2)	0.063 (3)	0.049 (2)	0.013 (2)	0.0160 (19)	0.027 (2)
C14	0.054 (2)	0.055 (2)	0.061 (2)	0.0151 (18)	0.0321 (19)	0.025 (2)
C15	0.069 (3)	0.053 (2)	0.052 (2)	0.020 (2)	0.031 (2)	0.0117 (18)
C16	0.063 (2)	0.063 (3)	0.041 (2)	0.025 (2)	0.0231 (18)	0.0164 (18)
C17	0.096 (4)	0.066 (3)	0.090 (3)	0.033 (3)	0.051 (3)	0.042 (3)
C21	0.0385 (19)	0.054 (2)	0.046 (2)	0.0150 (16)	0.0191 (16)	0.0178 (17)
C24	0.045 (2)	0.057 (2)	0.054 (2)	0.0131 (18)	0.0126 (18)	0.0173 (19)
C27	0.051 (2)	0.091 (3)	0.065 (3)	0.013 (2)	0.007 (2)	0.026 (3)
C22	0.045 (3)	0.114 (8)	0.047 (3)	0.031 (4)	0.027 (3)	0.030 (4)
C23	0.037 (3)	0.120 (9)	0.065 (4)	0.022 (4)	0.027 (3)	0.025 (4)
C25	0.051 (3)	0.081 (6)	0.039 (3)	0.012 (3)	0.019 (2)	0.014 (3)
C26	0.041 (3)	0.088 (7)	0.050 (3)	0.018 (3)	0.024 (2)	0.018 (4)
C22B	0.071 (18)	0.09 (3)	0.08 (2)	0.06 (2)	0.032 (15)	0.05 (2)
C31	0.0371 (18)	0.055 (2)	0.0389 (18)	0.0101 (16)	0.0146 (15)	0.0146 (16)
C32	0.050 (2)	0.060 (3)	0.078 (3)	0.0182 (19)	0.029 (2)	0.028 (2)
C33	0.059 (3)	0.062 (3)	0.081 (3)	0.011 (2)	0.027 (2)	0.034 (2)
C34	0.047 (2)	0.073 (3)	0.056 (2)	0.002 (2)	0.0179 (19)	0.019 (2)
C35	0.041 (2)	0.086 (3)	0.063 (3)	0.019 (2)	0.0226 (19)	0.026 (2)
C36	0.046 (2)	0.068 (3)	0.052 (2)	0.0204 (18)	0.0208 (17)	0.0259 (19)
C37	0.064 (3)	0.117 (4)	0.108 (4)	0.008 (3)	0.045 (3)	0.052 (4)
N	0.058 (2)	0.063 (2)	0.058 (2)	0.0165 (17)	0.0296 (17)	0.0208 (17)
C42	0.065 (3)	0.075 (3)	0.059 (3)	0.011 (2)	0.034 (2)	0.016 (2)
C43	0.071 (3)	0.113 (4)	0.067 (3)	0.022 (3)	0.040 (3)	0.028 (3)
C44	0.065 (3)	0.136 (5)	0.081 (4)	0.015 (3)	0.036 (3)	0.055 (4)
C45	0.090 (4)	0.086 (4)	0.108 (5)	−0.012 (3)	0.034 (4)	0.040 (4)
C46	0.099 (4)	0.065 (3)	0.082 (3)	0.015 (3)	0.046 (3)	0.026 (3)

Geometric parameters (Å, º)

Ag—N	2.392 (3)	C25—C26	1.379 (9)
Ag—P	2.4489 (12)	C25—H25	0.93
Ag—I^i	2.8402 (14)	C26—H26	0.93
Ag—I	2.8644 (8)	C22B—C23B	1.49 (5)
Ag—Ag^i	3.1138 (8)	C22B—H22B	0.93
I—Ag^i	2.8402 (14)	C23B—H23B	0.93
P—C11	1.820 (4)	C25B—C26B	1.39 (4)
P—C21	1.825 (4)	C25B—H25B	0.93
P—C31	1.826 (4)	C26B—H26B	0.93
C11—C12	1.387 (5)	C31—C36	1.374 (5)
C11—C16	1.394 (5)	C31—C32	1.390 (5)
C12—C13	1.381 (5)	C32—C33	1.375 (6)
C12—H12	0.93	C32—H32	0.93
C13—C14	1.382 (6)	C33—C34	1.381 (6)
C13—H13	0.93	C33—H33	0.93
C14—C15	1.378 (5)	C34—C35	1.385 (6)
C14—C17	1.504 (6)	C34—C37	1.502 (6)
C15—C16	1.371 (5)	C35—C36	1.384 (5)
C15—H15	0.93	C35—H35	0.93
C16—H16	0.93	C36—H36	0.93
C17—H17A	0.96	C37—H37A	0.96
C17—H17B	0.96	C37—H37B	0.96
C17—H17C	0.96	C37—H37C	0.96
C21—C26B	1.30 (3)	C37—H37D	0.96
C21—C22	1.374 (9)	C37—H37E	0.96
C21—C26	1.386 (8)	C37—H37F	0.96
C21—C22B	1.40 (5)	N—C42	1.320 (5)
C24—C25B	1.31 (3)	N—C46	1.320 (6)
C24—C23	1.364 (7)	C42—C43	1.367 (6)
C24—C25	1.397 (8)	C42—H42	0.93
C24—C23B	1.40 (4)	C43—C44	1.339 (7)
C24—C27	1.500 (5)	C43—H43	0.93
C27—H27A	0.96	C44—C45	1.359 (8)
C27—H27B	0.96	C44—H44	0.93
C27—H27C	0.96	C45—C46	1.388 (7)
C22—C23	1.378 (10)	C45—H45	0.93
C22—H22	0.93	C46—H46	0.93
C23—H23	0.93
N—Ag—P	117.09 (9)	C21—C26—H26	119.5
N—Ag—I^i	107.99 (8)	C21—C22B—C23B	118 (3)
P—Ag—I^i	111.63 (4)	C21—C22B—H22B	121.1
N—Ag—I	96.24 (8)	C23B—C22B—H22B	121.1
P—Ag—I	109.32 (3)	C24—C23B—C22B	119 (3)
I^i—Ag—I	113.84 (4)	C24—C23B—H23B	120.4
N—Ag—Ag^i	112.44 (9)	C22B—C23B—H23B	120.4
P—Ag—Ag^i	129.83 (4)	C24—C25B—C26B	122 (3)
I^i—Ag—Ag^i	57.29 (4)	C24—C25B—H25B	118.8
I—Ag—Ag^i	56.54 (3)	C26B—C25B—H25B	118.8
Ag^i—I—Ag	66.16 (4)	C21—C26B—C25B	124 (3)
C11—P—C21	104.54 (17)	C21—C26B—H26B	118
C11—P—C31	103.59 (16)	C25B—C26B—H26B	118
C21—P—C31	103.37 (16)	C36—C31—C32	117.7 (3)
C11—P—Ag	115.47 (12)	C36—C31—P	123.5 (3)
C21—P—Ag	115.15 (12)	C32—C31—P	118.8 (3)
C31—P—Ag	113.29 (12)	C33—C32—C31	120.8 (4)
C12—C11—C16	117.5 (3)	C33—C32—H32	119.6
C12—C11—P	119.1 (3)	C31—C32—H32	119.6
C16—C11—P	123.3 (3)	C32—C33—C34	122.0 (4)
C13—C12—C11	120.8 (4)	C32—C33—H33	119
C13—C12—H12	119.6	C34—C33—H33	119
C11—C12—H12	119.6	C33—C34—C35	116.7 (4)
C12—C13—C14	121.5 (4)	C33—C34—C37	121.6 (4)
C12—C13—H13	119.2	C35—C34—C37	121.7 (4)
C14—C13—H13	119.2	C36—C35—C34	121.5 (4)
C15—C14—C13	117.3 (4)	C36—C35—H35	119.2
C15—C14—C17	120.9 (4)	C34—C35—H35	119.2
C13—C14—C17	121.8 (4)	C31—C36—C35	121.1 (4)
C16—C15—C14	121.9 (4)	C31—C36—H36	119.5
C16—C15—H15	119	C35—C36—H36	119.5
C14—C15—H15	119	C34—C37—H37A	109.5
C15—C16—C11	120.8 (4)	C34—C37—H37B	109.5
C15—C16—H16	119.6	H37A—C37—H37B	109.5
C11—C16—H16	119.6	C34—C37—H37C	109.5
C14—C17—H17A	109.5	H37A—C37—H37C	109.5
C14—C17—H17B	109.5	H37B—C37—H37C	109.5
H17A—C17—H17B	109.5	C34—C37—H37D	109.5
C14—C17—H17C	109.5	H37A—C37—H37D	141.1
H17A—C17—H17C	109.5	H37B—C37—H37D	56.3
H17B—C17—H17C	109.5	H37C—C37—H37D	56.3
C22—C21—C26	117.4 (5)	C34—C37—H37E	109.5
C26B—C21—C22B	118 (2)	H37A—C37—H37E	56.3
C26B—C21—P	126.3 (14)	H37B—C37—H37E	141.1
C22—C21—P	118.5 (4)	H37C—C37—H37E	56.3
C26—C21—P	124.1 (3)	H37D—C37—H37E	109.5
C22B—C21—P	115.5 (15)	C34—C37—H37F	109.5
C23—C24—C25	116.6 (4)	H37A—C37—H37F	56.3
C25B—C24—C23B	118 (2)	H37B—C37—H37F	56.3
C25B—C24—C27	122.0 (14)	H37C—C37—H37F	141.1
C23—C24—C27	122.3 (4)	H37D—C37—H37F	109.5
C25—C24—C27	121.1 (4)	H37E—C37—H37F	109.5
C23B—C24—C27	120.2 (16)	C42—N—C46	116.0 (4)
C24—C27—H27A	109.5	C42—N—Ag	119.5 (3)
C24—C27—H27B	109.5	C46—N—Ag	124.4 (3)
H27A—C27—H27B	109.5	N—C42—C43	124.9 (5)
C24—C27—H27C	109.5	N—C42—H42	117.6
H27A—C27—H27C	109.5	C43—C42—H42	117.6
H27B—C27—H27C	109.5	C44—C43—C42	118.2 (5)
C21—C22—C23	121.2 (6)	C44—C43—H43	120.9
C21—C22—H22	119.4	C42—C43—H43	120.9
C23—C22—H22	119.4	C43—C44—C45	119.5 (5)
C24—C23—C22	122.4 (5)	C43—C44—H44	120.3
C24—C23—H23	118.8	C45—C44—H44	120.3
C22—C23—H23	118.8	C44—C45—C46	118.5 (5)
C26—C25—C24	121.5 (5)	C44—C45—H45	120.7
C26—C25—H25	119.3	C46—C45—H45	120.7
C24—C25—H25	119.3	N—C46—C45	122.9 (5)
C25—C26—C21	120.9 (5)	N—C46—H46	118.5
C25—C26—H26	119.5	C45—C46—H46	118.5
N—Ag—I—Ag^i	112.83 (9)	C24—C25—C26—C21	−0.9 (12)
P—Ag—I—Ag^i	−125.58 (4)	C26B—C21—C26—C25	−76 (4)
I^i—Ag—I—Ag^i	0	C22—C21—C26—C25	0.3 (10)
N—Ag—P—C11	−68.25 (16)	C22B—C21—C26—C25	31.5 (15)
I^i—Ag—P—C11	56.92 (13)	P—C21—C26—C25	−179.0 (5)
I—Ag—P—C11	−176.23 (12)	C26B—C21—C22B—C23B	−5.1 (15)
Ag^i—Ag—P—C11	121.69 (13)	C22—C21—C22B—C23B	75 (3)
N—Ag—P—C21	53.82 (16)	C26—C21—C22B—C23B	−29.6 (13)
I^i—Ag—P—C21	178.99 (13)	P—C21—C22B—C23B	178.1 (6)
I—Ag—P—C21	−54.16 (14)	C25B—C24—C23B—C22B	2.7 (19)
Ag^i—Ag—P—C21	−116.24 (13)	C23—C24—C23B—C22B	−75 (3)
N—Ag—P—C31	172.51 (15)	C25—C24—C23B—C22B	30.0 (15)
I^i—Ag—P—C31	−62.32 (13)	C27—C24—C23B—C22B	−178.1 (6)
I—Ag—P—C31	64.53 (13)	C21—C22B—C23B—C24	−1.0 (12)
Ag^i—Ag—P—C31	2.46 (13)	C23—C24—C25B—C26B	31 (3)
C21—P—C11—C12	−150.9 (3)	C25—C24—C25B—C26B	−82 (4)
C31—P—C11—C12	101.1 (3)	C23B—C24—C25B—C26B	2 (3)
Ag—P—C11—C12	−23.3 (3)	C27—C24—C25B—C26B	−177.6 (17)
C21—P—C11—C16	29.4 (4)	C22—C21—C26B—C25B	−20 (2)
C31—P—C11—C16	−78.5 (3)	C26—C21—C26B—C25B	94 (5)
Ag—P—C11—C16	157.0 (3)	C22B—C21—C26B—C25B	10 (3)
C16—C11—C12—C13	2.1 (6)	P—C21—C26B—C25B	−173.7 (17)
P—C11—C12—C13	−177.5 (3)	C24—C25B—C26B—C21	−8 (4)
C11—C12—C13—C14	−1.4 (6)	C11—P—C31—C36	−15.0 (3)
C12—C13—C14—C15	−0.8 (6)	C21—P—C31—C36	−123.8 (3)
C12—C13—C14—C17	−179.2 (4)	Ag—P—C31—C36	110.9 (3)
C13—C14—C15—C16	2.4 (6)	C11—P—C31—C32	167.1 (3)
C17—C14—C15—C16	−179.2 (4)	C21—P—C31—C32	58.2 (3)
C14—C15—C16—C11	−1.7 (6)	Ag—P—C31—C32	−67.1 (3)
C12—C11—C16—C15	−0.6 (6)	C36—C31—C32—C33	3.6 (6)
P—C11—C16—C15	179.0 (3)	P—C31—C32—C33	−178.3 (3)
C11—P—C21—C26B	−109.0 (18)	C31—C32—C33—C34	−1.2 (7)
C31—P—C21—C26B	−0.9 (18)	C32—C33—C34—C35	−2.5 (7)
Ag—P—C21—C26B	123.2 (17)	C32—C33—C34—C37	177.4 (5)
C11—P—C21—C22	99.2 (7)	C33—C34—C35—C36	3.9 (6)
C31—P—C21—C22	−152.7 (7)	C37—C34—C35—C36	−176.0 (4)
Ag—P—C21—C22	−28.6 (7)	C32—C31—C36—C35	−2.2 (6)
C11—P—C21—C26	−81.6 (8)	P—C31—C36—C35	179.8 (3)
C31—P—C21—C26	26.6 (8)	C34—C35—C36—C31	−1.6 (6)
Ag—P—C21—C26	150.7 (7)	P—Ag—N—C42	−156.8 (3)
C11—P—C21—C22B	67.5 (17)	I^i—Ag—N—C42	76.2 (3)
C31—P—C21—C22B	175.6 (17)	I—Ag—N—C42	−41.3 (3)
Ag—P—C21—C22B	−60.3 (17)	Ag^i—Ag—N—C42	15.0 (3)
C26B—C21—C22—C23	23.7 (14)	P—Ag—N—C46	19.7 (4)
C26—C21—C22—C23	0.5 (8)	I^i—Ag—N—C46	−107.3 (4)
C22B—C21—C22—C23	−89 (4)	I—Ag—N—C46	135.2 (3)
P—C21—C22—C23	179.8 (5)	Ag^i—Ag—N—C46	−168.5 (3)
C25B—C24—C23—C22	−26.2 (16)	C46—N—C42—C43	0.1 (7)
C25—C24—C23—C22	0.1 (9)	Ag—N—C42—C43	176.9 (4)
C23B—C24—C23—C22	88 (3)	N—C42—C43—C44	−0.5 (8)
C27—C24—C23—C22	−177.7 (5)	C42—C43—C44—C45	0.2 (8)
C21—C22—C23—C24	−0.7 (9)	C43—C44—C45—C46	0.4 (9)
C25B—C24—C25—C26	78 (4)	C42—N—C46—C45	0.5 (7)
C23—C24—C25—C26	0.7 (10)	Ag—N—C46—C45	−176.1 (4)
C23B—C24—C25—C26	−30.0 (17)	C44—C45—C46—N	−0.8 (9)
C27—C24—C25—C26	178.5 (6)

Symmetry code: (i) −x+1, −y+1, −z+1.