Zn₃TeO₆

Single crystals of trizinc(II) hexa­oxotellurate(VI), Zn₃TeO₆, were grown by chemical transport reactions. The compound crystallizes in the β-Li₃VF₆ structure type and is isotypic with Co₃TeO₆. It can be derived from a close packing of strongly distorted oxygen layers in an hhchhc sequence parallel to (100), with two distinct Te atoms in the octa­hedral, four Zn atoms in the octa­hedral and one Zn atom in the tetra­hedral inter­stices. Except for one Te atom and one Zn atom which are located on an inversion centre and on a twofold axis, respectively, all atoms are in general positions.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](n-O) = 0.004 Å
• R factor = 0.036
• wR factor = 0.078
• Data-to-parameter ratio = 16.7

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.33 Ratio
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       0.88

Alert level G
ABSTM02_ALERT_3_G  When printed, the submitted absorption T values will be
            replaced by the scaled T values. Since the ratio of scaled T's
            is identical to the ratio of reported T values, the scaling
            does not imply a change to the absorption corrections used in
            the study.
            Ratio of Tmax expected/reported      0.876
            Tmax scaled      0.414 Tmin scaled      0.096
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ATOMS (Dowty, 2004); software used to prepare material for publication: SHELXL97.

Trizinc hexaoxotellurate(VI)

Crystal data

Zn3TeO6	F(000) = 2280
Mr = 419.71	Dx = 6.154 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 8104 reflections
a = 14.8898 (8) Å	θ = 2.7–32.0°
b = 8.8341 (5) Å	µ = 22.02 mm^−1
c = 10.3457 (5) Å	T = 293 K
β = 92.990 (1)°	Lath, colourless
V = 1359.00 (12) Å^3	0.18 × 0.05 × 0.04 mm
Z = 12

Data collection

Bruker SMART APEX CCD diffractometer	2326 independent reflections
Radiation source: fine-focus sealed tube	2301 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.029
ω scans	θmax = 32.0°, θmin = 2.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 2002)	h = −21→22
Tmin = 0.110, Tmax = 0.473	k = −13→12
10616 measured reflections	l = −15→15

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.036	w = 1/[σ^2(Fo^2) + 46.687P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.078	(Δ/σ)max < 0.001
S = 1.44	Δρmax = 1.34 e Å^−3
2326 reflections	Δρmin = −1.70 e Å^−3
139 parameters	Extinction correction: SHELXL97, Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.00100 (5)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Te1	0.16407 (2)	0.49786 (4)	0.30415 (3)	0.00538 (10)
Te2	0.0000	0.0000	0.0000	0.00529 (11)
Zn1	0.16274 (5)	0.26545 (9)	0.05829 (7)	0.01223 (16)
Zn2	0.20357 (5)	0.13798 (8)	0.42673 (7)	0.00906 (15)
Zn3	0.36213 (5)	0.36122 (8)	0.24260 (7)	0.00943 (15)
Zn4	0.52649 (5)	0.14948 (8)	0.05220 (7)	0.00868 (14)
Zn5	0.0000	0.20099 (12)	0.2500	0.00887 (19)
O1	0.0711 (3)	0.0209 (5)	0.1573 (4)	0.0107 (8)
O2	0.0730 (3)	0.1630 (5)	0.4388 (4)	0.0085 (7)
O3	0.1007 (3)	0.3440 (5)	0.2041 (4)	0.0092 (8)
O4	0.2368 (3)	0.3498 (5)	0.3977 (4)	0.0095 (8)
O5	0.2566 (3)	0.4805 (5)	0.1793 (4)	0.0088 (7)
O6	0.2755 (3)	0.1540 (5)	0.0985 (4)	0.0104 (8)
O7	0.3910 (3)	0.1573 (5)	0.2988 (4)	0.0087 (8)
O8	0.4256 (3)	0.0027 (5)	0.0717 (4)	0.0095 (8)
O9	0.4288 (3)	0.3404 (5)	0.0710 (4)	0.0091 (8)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Te1	0.00539 (16)	0.00435 (16)	0.00642 (17)	0.00006 (11)	0.00040 (11)	0.00002 (11)
Te2	0.0055 (2)	0.0042 (2)	0.0062 (2)	−0.00010 (15)	0.00055 (15)	−0.00012 (15)
Zn1	0.0078 (3)	0.0197 (4)	0.0093 (3)	0.0026 (3)	0.0011 (2)	−0.0028 (3)
Zn2	0.0085 (3)	0.0080 (3)	0.0108 (3)	−0.0001 (2)	0.0005 (2)	−0.0027 (2)
Zn3	0.0105 (3)	0.0068 (3)	0.0108 (3)	0.0016 (2)	−0.0011 (2)	0.0007 (2)
Zn4	0.0088 (3)	0.0072 (3)	0.0099 (3)	−0.0007 (2)	−0.0009 (2)	−0.0005 (2)
Zn5	0.0089 (4)	0.0087 (4)	0.0092 (4)	0.000	0.0018 (3)	0.000
O1	0.0128 (19)	0.0097 (19)	0.0091 (18)	0.0000 (16)	−0.0033 (15)	−0.0010 (15)
O2	0.0054 (17)	0.0093 (18)	0.0108 (18)	−0.0007 (14)	0.0002 (14)	0.0008 (15)
O3	0.0081 (18)	0.0107 (19)	0.0089 (18)	−0.0021 (15)	0.0020 (14)	−0.0034 (15)
O4	0.0108 (19)	0.0054 (17)	0.0120 (19)	0.0007 (14)	−0.0011 (15)	0.0037 (14)
O5	0.0067 (17)	0.0101 (18)	0.0099 (18)	−0.0002 (14)	0.0033 (14)	0.0025 (15)
O6	0.0102 (19)	0.0108 (19)	0.0103 (19)	0.0026 (15)	0.0008 (15)	0.0052 (15)
O7	0.015 (2)	0.0056 (17)	0.0053 (17)	−0.0019 (15)	−0.0049 (14)	0.0009 (13)
O8	0.0114 (19)	0.0096 (19)	0.0082 (18)	−0.0019 (15)	0.0063 (15)	−0.0013 (14)
O9	0.0124 (19)	0.0056 (17)	0.0096 (18)	−0.0028 (15)	0.0031 (15)	0.0008 (14)

Geometric parameters (Å, º)

Te1—O8^i	1.900 (4)	Zn5—O2^iv	2.210 (4)
Te1—O6^i	1.906 (4)	Zn5—O2	2.210 (4)
Te1—O7^i	1.923 (4)	O1—Zn3^viii	1.986 (5)
Te1—O3	1.925 (4)	O1—Zn2^v	3.470 (5)
Te1—O4	1.927 (4)	O1—Zn4^vii	3.509 (5)
Te1—O5	1.943 (4)	O1—Zn3^vii	3.569 (5)
Te1—Zn3^i	3.2665 (8)	O1—Zn4^vi	3.868 (5)
Te1—Zn1	3.2681 (8)	O2—Te2^iv	1.931 (4)
Te1—Zn3	3.2794 (8)	O2—Zn4^xiii	2.165 (4)
Te1—Zn1^ii	3.3602 (9)	O2—Zn3^ix	3.393 (4)
Te1—Zn2^i	3.4077 (8)	O2—Zn3^viii	3.428 (4)
Te1—Zn2	3.4617 (8)	O2—Zn1^iv	3.626 (4)
Te2—O1^iii	1.904 (4)	O2—Zn2^ix	3.952 (4)
Te2—O1	1.904 (4)	O3—Zn4^vi	3.178 (4)
Te2—O2^iv	1.931 (4)	O3—Zn4^xiv	3.285 (5)
Te2—O2^v	1.931 (4)	O3—Zn4^xiii	3.822 (4)
Te2—O9^vi	1.932 (4)	O4—Zn2^ix	1.982 (4)
Te2—O9^vii	1.932 (4)	O4—Zn4^xiii	3.590 (5)
Te2—Zn5	3.1372 (6)	O4—Zn4^x	3.953 (4)
Te2—Zn5^iii	3.1372 (6)	O4—Zn1^ii	3.965 (5)
Te2—Zn4^vi	3.1644 (7)	O4—Zn1^i	3.982 (4)
Te2—Zn4^vii	3.1644 (7)	O5—Zn2^i	1.886 (4)
Te2—Zn2^iv	3.3894 (7)	O5—Zn1^vi	3.538 (4)
Te2—Zn2^v	3.3894 (7)	O5—Zn1^i	3.848 (5)
Zn1—O3	1.938 (4)	O5—Zn4^xiv	3.902 (4)
Zn1—O6	1.972 (4)	O5—Zn3^i	3.903 (4)
Zn1—O6^vi	2.034 (4)	O5—Zn5^xv	4.146 (4)
Zn1—O9^vi	2.081 (4)	O6—Te1^viii	1.906 (4)
Zn1—O5	2.635 (5)	O6—Zn1^vi	2.034 (4)
Zn1—O8^vi	2.747 (5)	O6—Zn2^v	3.281 (5)
Zn2—O5^viii	1.886 (4)	O6—Zn3^viii	3.734 (5)
Zn2—O4	1.963 (4)	O6—Zn3^vi	3.990 (4)
Zn2—O2	1.967 (4)	O7—Zn4^x	1.922 (4)
Zn2—O4^ix	1.982 (4)	O7—Te1^viii	1.923 (4)
Zn2—Zn2^ix	2.8123 (14)	O7—Zn2^ix	3.706 (4)
Zn2—Zn3^viii	3.1345 (10)	O7—Zn1^vi	3.801 (4)
Zn3—O7	1.935 (4)	O7—Zn1^viii	3.864 (4)
Zn3—O5	1.976 (4)	O7—Zn3^x	4.136 (4)
Zn3—O1^i	1.986 (5)	O8—Te1^viii	1.900 (4)
Zn3—O9	2.087 (4)	O8—Zn4^xi	2.014 (4)
Zn3—O4	2.525 (5)	O8—Zn1^vi	2.747 (5)
Zn3—O6	2.652 (5)	O8—Zn5^xvi	3.395 (5)
Zn4—O7^x	1.922 (4)	O8—Zn2^viii	3.753 (4)
Zn4—O8	2.003 (4)	O8—Zn2^v	3.769 (5)
Zn4—O8^xi	2.014 (4)	O8—Zn1^xvi	4.115 (5)
Zn4—O2^xii	2.165 (4)	O8—Zn4^x	4.128 (4)
Zn4—O9	2.243 (5)	O9—Te2^xv	1.932 (4)
Zn4—Zn4^xi	2.9453 (14)	O9—Zn1^vi	2.081 (4)
Zn4—O3^vi	3.178 (4)	O9—Zn2^i	3.286 (5)
Zn5—O3^iv	2.036 (4)	O9—Zn5^vi	3.557 (4)
Zn5—O3	2.036 (4)	O9—Zn3^x	3.581 (5)
Zn5—O1^iv	2.162 (5)	O9—Zn5^xv	3.808 (4)
Zn5—O1	2.162 (5)
O8^i—Te1—O6^i	87.43 (19)	Zn4^xiii—O4—Zn1^ii	62.85 (7)
O8^i—Te1—O7^i	93.64 (19)	Zn1—O4—Zn1^ii	119.62 (11)
O6^i—Te1—O7^i	86.46 (19)	Zn4^x—O4—Zn1^ii	126.48 (12)
O8^i—Te1—O3	92.16 (19)	Te1—O4—Zn1^i	68.24 (12)
O6^i—Te1—O3	178.5 (2)	Zn2—O4—Zn1^i	163.33 (19)
O7^i—Te1—O3	92.10 (18)	Zn2^ix—O4—Zn1^i	72.40 (13)
O8^i—Te1—O4	94.14 (19)	Zn3—O4—Zn1^i	75.54 (10)
O6^i—Te1—O4	89.34 (19)	Zn4^xiii—O4—Zn1^i	106.18 (11)
O7^i—Te1—O4	170.98 (19)	Zn1—O4—Zn1^i	112.68 (11)
O3—Te1—O4	92.16 (19)	Zn4^x—O4—Zn1^i	94.07 (9)
O8^i—Te1—O5	176.70 (19)	Te1—O4—Zn5	64.46 (12)
O6^i—Te1—O5	94.42 (19)	Zn2—O4—Zn5	61.29 (12)
O7^i—Te1—O5	89.20 (19)	Zn2^ix—O4—Zn5	135.48 (18)
O3—Te1—O5	86.06 (18)	Zn3—O4—Zn5	115.90 (14)
O4—Te1—O5	83.17 (19)	Zn4^xiii—O4—Zn5	52.93 (6)
O1^iii—Te2—O1	180.0 (4)	Zn4^x—O4—Zn5	131.79 (12)
O1^iii—Te2—O2^iv	93.19 (19)	Zn1^ii—O4—Zn5	100.55 (10)
O1—Te2—O2^iv	86.81 (19)	Zn1^i—O4—Zn5	131.78 (11)
O1^iii—Te2—O2^v	86.81 (19)	Zn2^i—O5—Te1	125.7 (2)
O1—Te2—O2^v	93.19 (19)	Zn2^i—O5—Zn3	108.5 (2)
O2^iv—Te2—O2^v	180.0 (3)	Te1—O5—Zn3	113.6 (2)
O1^iii—Te2—O9^vi	92.17 (19)	Zn2^i—O5—Zn1	115.5 (2)
O1—Te2—O9^vi	87.83 (19)	Te1—O5—Zn1	89.78 (16)
O2^iv—Te2—O9^vi	84.84 (19)	Zn3—O5—Zn1	99.55 (18)
O2^v—Te2—O9^vi	95.16 (19)	Zn2^i—O5—Zn1^vi	85.43 (14)
O1^iii—Te2—O9^vii	87.83 (19)	Te1—O5—Zn1^vi	142.07 (19)
O1—Te2—O9^vii	92.17 (19)	Zn3—O5—Zn1^vi	67.02 (12)
O2^iv—Te2—O9^vii	95.16 (19)	Zn2^i—O5—Zn1^i	80.31 (14)
O2^v—Te2—O9^vii	84.84 (19)	Te1—O5—Zn1^i	71.66 (13)
O9^vi—Te2—O9^vii	180.0 (3)	Zn3—O5—Zn1^i	84.33 (14)
O3—Zn1—O6	116.71 (19)	Zn1—O5—Zn1^i	160.89 (15)
O3—Zn1—O6^vi	138.51 (19)	Zn1^vi—O5—Zn1^i	141.91 (13)
O6—Zn1—O6^vi	85.84 (18)	Zn2^i—O5—Zn4^xiv	79.59 (14)
O3—Zn1—O9^vi	109.81 (18)	Te1—O5—Zn4^xiv	63.48 (12)
O6—Zn1—O9^vi	115.66 (19)	Zn3—O5—Zn4^xiv	170.14 (19)
O6^vi—Zn1—O9^vi	87.29 (18)	Zn1—O5—Zn4^xiv	71.42 (10)
O3—Zn1—O5	68.54 (16)	Zn1^vi—O5—Zn4^xiv	108.96 (11)
O6—Zn1—O5	80.51 (17)	Zn1^i—O5—Zn4^xiv	102.94 (10)
O6^vi—Zn1—O5	82.89 (16)	Zn2^i—O5—Zn3^i	69.18 (13)
O9^vi—Zn1—O5	160.47 (16)	Te1—O5—Zn3^i	56.64 (11)
O3—Zn1—O8^vi	83.05 (16)	Zn3—O5—Zn3^i	138.76 (19)
O6—Zn1—O8^vi	148.86 (16)	Zn1—O5—Zn3^i	119.01 (14)
O6^vi—Zn1—O8^vi	64.76 (15)	Zn1^vi—O5—Zn3^i	147.88 (13)
O9^vi—Zn1—O8^vi	74.92 (15)	Zn1^i—O5—Zn3^i	54.44 (6)
O5—Zn1—O8^vi	85.61 (13)	Zn2^i—O5—Zn2	172.68 (19)
O5^viii—Zn2—O4	121.64 (19)	Te1—O5—Zn2	58.18 (11)
O5^viii—Zn2—O2	117.50 (19)	Zn3—O5—Zn2	64.63 (11)
O4—Zn2—O2	99.25 (19)	Zn1—O5—Zn2	69.34 (9)
O5^viii—Zn2—O4^ix	115.69 (19)	Zn1^vi—O5—Zn2	93.69 (10)
O4—Zn2—O4^ix	89.06 (18)	Zn1^i—O5—Zn2	96.10 (9)
O2—Zn2—O4^ix	109.42 (19)	Zn4^xiv—O5—Zn2	107.52 (10)
O7—Zn3—O5	139.18 (19)	Zn3^i—O5—Zn2	113.95 (10)
O7—Zn3—O1^i	114.06 (18)	Zn2^i—O5—Zn5^xv	57.14 (11)
O5—Zn3—O1^i	99.32 (19)	Te1—O5—Zn5^xv	119.28 (17)
O7—Zn3—O9	93.77 (18)	Zn3—O5—Zn5^xv	61.25 (11)
O5—Zn3—O9	99.80 (18)	Zn1—O5—Zn5^xv	149.24 (15)
O1^i—Zn3—O9	105.00 (18)	Zn1^vi—O5—Zn5^xv	94.91 (9)
O7—Zn3—O4	86.08 (17)	Zn1^i—O5—Zn5^xv	47.96 (5)
O5—Zn3—O4	68.33 (15)	Zn4^xiv—O5—Zn5^xv	128.60 (11)
O1^i—Zn3—O4	93.64 (17)	Zn3^i—O5—Zn5^xv	87.70 (9)
O9—Zn3—O4	159.54 (16)	Zn2—O5—Zn5^xv	115.78 (10)
O7—Zn3—O6	67.67 (15)	Te1^viii—O6—Zn1	147.8 (3)
O5—Zn3—O6	80.01 (16)	Te1^viii—O6—Zn1^vi	117.0 (2)
O1^i—Zn3—O6	177.23 (16)	Zn1—O6—Zn1^vi	94.16 (18)
O9—Zn3—O6	72.53 (15)	Te1^viii—O6—Zn3	90.02 (17)
O4—Zn3—O6	88.63 (14)	Zn1—O6—Zn3	99.09 (18)
O7^x—Zn4—O8	113.21 (19)	Zn1^vi—O6—Zn3	88.87 (16)
O7^x—Zn4—O8^xi	107.54 (19)	Te1^viii—O6—Zn2^v	81.30 (15)
O8—Zn4—O8^xi	85.68 (18)	Zn1—O6—Zn2^v	91.59 (16)
O7^x—Zn4—O2^xii	101.44 (18)	Zn1^vi—O6—Zn2^v	89.50 (15)
O8—Zn4—O2^xii	144.38 (18)	Zn3—O6—Zn2^v	169.29 (17)
O8^xi—Zn4—O2^xii	91.83 (17)	Te1^viii—O6—Zn2	68.30 (12)
O7^x—Zn4—O9	107.11 (17)	Zn1—O6—Zn2	85.81 (15)
O8—Zn4—O9	89.11 (17)	Zn1^vi—O6—Zn2	158.6 (2)
O8^xi—Zn4—O9	144.13 (18)	Zn3—O6—Zn2	70.03 (10)
O2^xii—Zn4—O9	72.46 (16)	Zn2^v—O6—Zn2	111.93 (12)
O3^iv—Zn5—O3	103.3 (3)	Te1^viii—O6—Zn3^viii	61.36 (12)
O3^iv—Zn5—O1^iv	88.26 (18)	Zn1—O6—Zn3^viii	87.58 (15)
O3—Zn5—O1^iv	160.63 (17)	Zn1^vi—O6—Zn3^viii	151.0 (2)
O3^iv—Zn5—O1	160.63 (17)	Zn3—O6—Zn3^viii	119.50 (14)
O3—Zn5—O1	88.26 (18)	Zn2^v—O6—Zn3^viii	61.48 (8)
O1^iv—Zn5—O1	85.3 (2)	Te1^viii—O6—Zn4	67.55 (13)
O3^iv—Zn5—O2^iv	88.05 (17)	Zn1—O6—Zn4	144.34 (19)
O3—Zn5—O2^iv	102.85 (17)	Zn1^vi—O6—Zn4	54.10 (10)
O1^iv—Zn5—O2^iv	92.90 (16)	Zn3—O6—Zn4	67.97 (10)
O1—Zn5—O2^iv	74.09 (16)	Zn2^v—O6—Zn4	102.67 (12)
O3^iv—Zn5—O2	102.85 (17)	Zn2—O6—Zn4	117.41 (12)
O3—Zn5—O2	88.05 (17)	Zn3^viii—O6—Zn4	127.97 (12)
O1^iv—Zn5—O2	74.09 (16)	Te1^viii—O6—Zn3^vi	130.50 (19)
O1—Zn5—O2	92.90 (16)	Zn1—O6—Zn3^vi	55.79 (11)
O2^iv—Zn5—O2	162.5 (2)	Zn1^vi—O6—Zn3^vi	62.56 (11)
Te2—O1—Zn3^viii	128.2 (2)	Zn3—O6—Zn3^vi	137.12 (15)
Te2—O1—Zn5	100.8 (2)	Zn2—O6—Zn3^vi	131.73 (12)
Zn3^viii—O1—Zn5	122.3 (2)	Zn3^viii—O6—Zn3^vi	95.60 (10)
Te2—O1—Zn1	91.27 (17)	Zn4—O6—Zn3^vi	110.61 (11)
Zn3^viii—O1—Zn1	120.1 (2)	Zn4^x—O7—Te1^viii	130.9 (2)
Zn5—O1—Zn1	81.53 (14)	Zn4^x—O7—Zn3	113.4 (2)
Te2—O1—Zn2^v	71.56 (13)	Te1^viii—O7—Zn3	115.7 (2)
Zn3^viii—O1—Zn2^v	77.52 (14)	Zn4^x—O7—Zn2	101.77 (17)
Zn5—O1—Zn2^v	155.69 (19)	Te1^viii—O7—Zn2	80.33 (14)
Zn1—O1—Zn2^v	75.72 (11)	Zn3—O7—Zn2	89.37 (16)
Te2—O1—Zn2	168.1 (2)	Zn4^x—O7—Zn4	103.05 (17)
Zn3^viii—O1—Zn2	63.05 (12)	Te1^viii—O7—Zn4	79.55 (14)
Zn5—O1—Zn2	72.36 (12)	Zn3—O7—Zn4	85.59 (14)
Zn1—O1—Zn2	78.23 (11)	Zn2—O7—Zn4	154.63 (14)
Zn2^v—O1—Zn2	110.57 (13)	Zn4^x—O7—Zn2^ix	69.84 (12)
Te2—O1—Zn4^vii	63.67 (12)	Te1^viii—O7—Zn2^ix	127.86 (19)
Zn3^viii—O1—Zn4^vii	65.09 (12)	Zn3—O7—Zn2^ix	71.84 (13)
Zn5—O1—Zn4^vii	137.40 (19)	Zn4—O7—Zn2^ix	149.93 (13)
Zn1—O1—Zn4^vii	134.52 (16)	Zn4^x—O7—Zn1^vi	151.6 (2)
Zn2^v—O1—Zn4^vii	60.92 (8)	Te1^viii—O7—Zn1^vi	62.05 (11)
Zn2—O1—Zn4^vii	127.96 (13)	Zn3—O7—Zn1^vi	60.56 (11)
Te2—O1—Zn3^vii	73.74 (14)	Zn2—O7—Zn1^vi	105.76 (11)
Zn3^viii—O1—Zn3^vii	90.55 (16)	Zn4—O7—Zn1^vi	50.59 (6)
Zn5—O1—Zn3^vii	74.21 (13)	Zn2^ix—O7—Zn1^vi	126.02 (12)
Zn1—O1—Zn3^vii	148.17 (16)	Zn4^x—O7—Zn1^viii	78.31 (13)
Zn2^v—O1—Zn3^vii	122.97 (13)	Te1^viii—O7—Zn1^viii	57.67 (11)
Zn2—O1—Zn3^vii	112.57 (12)	Zn3—O7—Zn1^viii	154.4 (2)
Zn4^vii—O1—Zn3^vii	63.49 (8)	Zn2—O7—Zn1^viii	65.53 (8)
Te2—O1—Zn4^vi	54.41 (11)	Zn4—O7—Zn1^viii	114.82 (12)
Zn3^viii—O1—Zn4^vi	172.0 (2)	Zn2^ix—O7—Zn1^viii	92.84 (10)
Zn5—O1—Zn4^vi	61.08 (11)	Zn1^vi—O7—Zn1^viii	119.71 (11)
Zn1—O1—Zn4^vi	52.09 (8)	Zn4^x—O7—Zn3^x	64.16 (12)
Zn2^v—O1—Zn4^vi	97.45 (11)	Te1^viii—O7—Zn3^x	128.11 (18)
Zn2—O1—Zn4^vi	113.90 (12)	Zn3—O7—Zn3^x	75.40 (13)
Zn4^vii—O1—Zn4^vi	118.09 (12)	Zn2—O7—Zn3^x	151.32 (13)
Zn3^vii—O1—Zn4^vi	97.43 (11)	Zn4—O7—Zn3^x	49.71 (6)
Te2^iv—O2—Zn2	120.8 (2)	Zn2^ix—O7—Zn3^x	104.00 (10)
Te2^iv—O2—Zn4^xiii	101.04 (19)	Zn1^vi—O7—Zn3^x	87.95 (9)
Zn2—O2—Zn4^xiii	117.7 (2)	Zn1^viii—O7—Zn3^x	129.24 (11)
Te2^iv—O2—Zn5	98.28 (18)	Te1^viii—O8—Zn4	129.8 (2)
Zn2—O2—Zn5	113.8 (2)	Te1^viii—O8—Zn4^xi	134.4 (2)
Zn4^xiii—O2—Zn5	101.91 (18)	Zn4—O8—Zn4^xi	94.32 (18)
Te2^iv—O2—Zn3^ix	76.75 (13)	Te1^viii—O8—Zn1^vi	90.73 (17)
Zn2—O2—Zn3^ix	79.75 (13)	Zn4—O8—Zn1^vi	79.08 (14)
Zn4^xiii—O2—Zn3^ix	66.70 (11)	Zn4^xi—O8—Zn1^vi	111.26 (18)
Zn5—O2—Zn3^ix	165.90 (18)	Te1^viii—O8—Zn5^xvi	80.55 (14)
Te2^iv—O2—Zn3^viii	77.24 (14)	Zn4—O8—Zn5^xvi	109.73 (18)
Zn2—O2—Zn3^viii	64.55 (12)	Zn4^xi—O8—Zn5^xvi	72.84 (13)
Zn4^xiii—O2—Zn3^viii	177.71 (18)	Zn1^vi—O8—Zn5^xvi	170.32 (16)
Zn5—O2—Zn3^viii	76.94 (12)	Te1^viii—O8—Zn2^viii	66.39 (12)
Zn3^ix—O2—Zn3^viii	114.12 (12)	Zn4—O8—Zn2^viii	160.64 (19)
Te2^iv—O2—Zn1^iv	67.78 (12)	Zn4^xi—O8—Zn2^viii	68.17 (12)
Zn2—O2—Zn1^iv	171.4 (2)	Zn1^vi—O8—Zn2^viii	114.20 (14)
Zn4^xiii—O2—Zn1^iv	57.82 (10)	Zn5^xvi—O8—Zn2^viii	58.41 (7)
Zn5—O2—Zn1^iv	62.49 (10)	Te1^viii—O8—Zn2^v	68.23 (13)
Zn3^ix—O2—Zn1^iv	103.55 (11)	Zn4—O8—Zn2^v	145.13 (19)
Zn3^viii—O2—Zn1^iv	119.95 (12)	Zn4^xi—O8—Zn2^v	81.90 (14)
Te2^iv—O2—Zn2^ix	133.97 (18)	Zn1^vi—O8—Zn2^v	70.34 (10)
Zn4^xiii—O2—Zn2^ix	75.86 (12)	Zn5^xvi—O8—Zn2^v	102.24 (11)
Zn5—O2—Zn2^ix	127.56 (16)	Te1^viii—O8—Zn3	60.02 (11)
Zn3^ix—O2—Zn2^ix	59.61 (7)	Zn4—O8—Zn3	73.22 (13)
Zn3^viii—O2—Zn2^ix	106.41 (11)	Zn4^xi—O8—Zn3	164.76 (19)
Zn1^iv—O2—Zn2^ix	133.12 (12)	Zn1^vi—O8—Zn3	58.56 (8)
Te1—O3—Zn1	115.6 (2)	Zn5^xvi—O8—Zn3	119.17 (12)
Te1—O3—Zn5	131.2 (2)	Zn2^viii—O8—Zn3	125.32 (11)
Zn1—O3—Zn5	110.2 (2)	Zn2^v—O8—Zn3	103.16 (11)
Te1—O3—Zn4^vi	133.6 (2)	Te1^viii—O8—Zn1^xvi	130.20 (19)
Zn1—O3—Zn4^vi	69.16 (13)	Zn4—O8—Zn1^xvi	71.13 (12)
Zn5—O3—Zn4^vi	77.96 (13)	Zn1^vi—O8—Zn1^xvi	138.84 (14)
Te1—O3—Zn2	79.35 (14)	Zn5^xvi—O8—Zn1^xvi	50.35 (6)
Zn1—O3—Zn2	97.18 (17)	Zn2^viii—O8—Zn1^xvi	90.20 (9)
Zn5—O3—Zn2	79.23 (14)	Zn2^v—O8—Zn1^xvi	123.70 (11)
Zn4^vi—O3—Zn2	146.97 (15)	Zn3—O8—Zn1^xvi	132.84 (12)
Te1—O3—Zn4^xiv	79.66 (14)	Te1^viii—O8—Zn4^x	57.53 (11)
Zn1—O3—Zn4^xiv	94.81 (16)	Zn4—O8—Zn4^x	78.35 (13)
Zn5—O3—Zn4^xiv	112.81 (17)	Zn4^xi—O8—Zn4^x	139.46 (19)
Zn4^vi—O3—Zn4^xiv	54.19 (8)	Zn1^vi—O8—Zn4^x	106.39 (12)
Zn2—O3—Zn4^xiv	158.76 (15)	Zn5^xvi—O8—Zn4^x	72.48 (8)
Te1—O3—Zn4^xiii	68.94 (12)	Zn2^viii—O8—Zn4^x	109.21 (10)
Zn1—O3—Zn4^xiii	155.8 (2)	Zn2^v—O8—Zn4^x	125.71 (11)
Zn5—O3—Zn4^xiii	62.41 (11)	Zn1^xvi—O8—Zn4^x	94.89 (10)
Zn4^vi—O3—Zn4^xiii	126.64 (13)	Te2^xv—O9—Zn1^vi	116.0 (2)
Zn2—O3—Zn4^xiii	59.35 (7)	Te2^xv—O9—Zn3	123.6 (2)
Zn4^xiv—O3—Zn4^xiii	109.38 (12)	Zn1^vi—O9—Zn3	105.19 (19)
Te1—O3—Zn3	57.22 (11)	Te2^xv—O9—Zn4	98.30 (19)
Zn1—O3—Zn3	65.13 (12)	Zn1^vi—O9—Zn4	90.70 (17)
Zn5—O3—Zn3	138.14 (18)	Zn3—O9—Zn4	118.6 (2)
Zn4^vi—O3—Zn3	129.32 (13)	Te2^xv—O9—Zn2^i	76.14 (14)
Zn2—O3—Zn3	61.23 (8)	Zn1^vi—O9—Zn2^i	89.52 (15)
Zn4^xiv—O3—Zn3	109.05 (12)	Zn3—O9—Zn2^i	67.14 (12)
Zn4^xiii—O3—Zn3	103.87 (10)	Zn4—O9—Zn2^i	173.88 (18)
Te1—O4—Zn2	125.7 (2)	Te2^xv—O9—Zn5^vi	61.57 (11)
Te1—O4—Zn2^ix	129.5 (2)	Zn1^vi—O9—Zn5^vi	64.59 (11)
Zn2—O4—Zn2^ix	90.94 (18)	Zn3—O9—Zn5^vi	169.0 (2)
Te1—O4—Zn3	93.91 (17)	Zn4—O9—Zn5^vi	67.38 (11)
Zn2—O4—Zn3	109.63 (19)	Zn2^i—O9—Zn5^vi	107.29 (12)
Zn2^ix—O4—Zn3	105.66 (18)	Te2^xv—O9—Zn3^x	71.82 (13)
Te1—O4—Zn4^xiii	75.03 (14)	Zn1^vi—O9—Zn3^x	153.01 (19)
Zn2—O4—Zn4^xiii	72.58 (13)	Zn3—O9—Zn3^x	88.61 (14)
Zn2^ix—O4—Zn4^xiii	87.21 (15)	Zn4—O9—Zn3^x	62.31 (11)
Zn3—O4—Zn4^xiii	166.75 (17)	Zn2^i—O9—Zn3^x	117.38 (12)
Te1—O4—Zn1	61.83 (12)	Zn5^vi—O9—Zn3^x	102.40 (11)
Zn2—O4—Zn1	83.57 (14)	Te2^xv—O9—Zn5^xv	55.24 (11)
Zn2^ix—O4—Zn1	167.8 (2)	Zn1^vi—O9—Zn5^xv	147.70 (19)
Zn3—O4—Zn1	66.34 (10)	Zn3—O9—Zn5^xv	69.22 (12)
Zn4^xiii—O4—Zn1	101.47 (11)	Zn4—O9—Zn5^xv	120.38 (16)
Te1—O4—Zn4^x	147.54 (19)	Zn2^i—O9—Zn5^xv	58.61 (7)
Zn2—O4—Zn4^x	77.50 (13)	Zn5^vi—O9—Zn5^xv	116.81 (11)
Zn2^ix—O4—Zn4^x	63.32 (11)	Zn3^x—O9—Zn5^xv	58.85 (7)
Zn3—O4—Zn4^x	54.43 (8)	Te2^xv—O9—Zn1	131.98 (18)
Zn4^xiii—O4—Zn4^x	137.31 (12)	Zn3—O9—Zn1	61.96 (11)
Zn1—O4—Zn4^x	104.70 (11)	Zn4—O9—Zn1	121.13 (15)
Te1—O4—Zn1^ii	57.80 (11)	Zn2^i—O9—Zn1	62.67 (8)
Zn2—O4—Zn1^ii	132.47 (18)	Zn5^vi—O9—Zn1	107.13 (11)
Zn2^ix—O4—Zn1^ii	71.97 (13)	Zn3^x—O9—Zn1	148.81 (13)
Zn3—O4—Zn1^ii	117.57 (14)	Zn5^xv—O9—Zn1	113.80 (11)

Symmetry codes: (i) −x+1/2, y+1/2, −z+1/2; (ii) x, −y+1, z+1/2; (iii) −x, −y, −z; (iv) −x, y, −z+1/2; (v) x, −y, z−1/2; (vi) −x+1/2, −y+1/2, −z; (vii) x−1/2, y−1/2, z; (viii) −x+1/2, y−1/2, −z+1/2; (ix) −x+1/2, −y+1/2, −z+1; (x) −x+1, y, −z+1/2; (xi) −x+1, −y, −z; (xii) x+1/2, −y+1/2, z−1/2; (xiii) x−1/2, −y+1/2, z+1/2; (xiv) x−1/2, y+1/2, z; (xv) x+1/2, y+1/2, z; (xvi) x+1/2, y−1/2, z.