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The title compound, [Ag(P(p-tol)3}4]PF6 or [Ag(C21H21P)4]PF6, crystallizes with parts of two independent formula units in the asymmetric unit. The Ag—P distances range between 2.5665 (13) and 2.6142 (7) Å, and the P—Ag—P angles between 109.310 (18) and 109.632 (18)°, indicating a distorted tetra­hedral geometry. Both Ag atoms and both PF6 anions lie on threefold rotation axes.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680604760X/ng2149sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S160053680604760X/ng2149Isup2.hkl
Contains datablock I

CCDC reference: 630186

Key indicators

  • Single-crystal X-ray study
  • T = 101 K
  • Mean [sigma](Wave) = 0.000 Å
  • R factor = 0.038
  • wR factor = 0.102
  • Data-to-parameter ratio = 21.3

checkCIF/PLATON results

No syntax errors found



Alert level G REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF. From the CIF: _diffrn_reflns_theta_max 28.35 From the CIF: _reflns_number_total 12538 Count of symmetry unique reflns 6684 Completeness (_total/calc) 187.58% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 5854 Fraction of Friedel pairs measured 0.876 Are heavy atom types Z>Si present yes
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 0 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker, 2004); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

Tetrakis(tri-p-tolylphosphine-κP)silver(I) hexafluorophosphate top
Crystal data top
[Ag(C21H21P)4]PF6Dx = 1.299 Mg m3
Mr = 1470.23Mo Kα radiation, λ = 0.71073 Å
Cubic, P213Cell parameters from 8586 reflections
Hall symbol: P 2ac 2ab 3θ = 2.3–25.7°
a = 24.6842 (4) ŵ = 0.43 mm1
V = 15040.3 (4) Å3T = 101 K
Z = 8Cuboid, colourless
F(000) = 61120.40 × 0.37 × 0.36 mm
Data collection top
Bruker X8 APEX0II 4K KappaCCD
diffractometer
12538 independent reflections
Radiation source: sealed tube10906 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.064
Detector resolution: 512 pixels mm-1θmax = 28.4°, θmin = 1.2°
ω and φ scansh = 3232
Absorption correction: multi-scan
(SADABS; Bruker, 2004)
k = 3232
Tmin = 0.846, Tmax = 0.860l = 3232
122435 measured reflections
Refinement top
Refinement on F2H-atom parameters constrained
Least-squares matrix: full w = 1/[σ2(Fo2) + (0.0501P)2 + 9.1168P]
where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.038(Δ/σ)max = 0.003
wR(F2) = 0.102Δρmax = 1.58 e Å3
S = 1.09Δρmin = 0.55 e Å3
12538 reflectionsAbsolute structure: Flack (1983), 5852 Friedel pairs
588 parametersAbsolute structure parameter: 0.024 (17)
0 restraints
Special details top

Experimental. The intensity data was collected on a Bruker X8 ApexII 4 K Kappa CCD diffractometer using an exposure time of 15 s/frame. A total of 809 frames were collected with a frame width of 0.5° covering up to θ = 25.65° with 100% completeness accomplished.

IR νPF6: 839.67 cm-1; 31P NMR (121.495 MHz, 298 K, CD2Cl2): δ 4.80 p.p.m.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.732149 (8)0.732149 (8)0.732149 (8)0.01623 (8)
Ag20.255160 (8)0.755160 (8)0.744840 (8)0.01793 (8)
P011.00470 (6)0.50470 (6)0.99530 (6)0.0481 (5)
P020.48752 (6)0.51248 (6)1.01248 (6)0.0416 (4)
P110.79225 (3)0.79225 (3)0.79225 (3)0.0199 (3)
P120.63752 (3)0.77517 (3)0.72403 (3)0.01849 (15)
P230.19513 (3)0.69513 (3)0.80487 (3)0.0230 (3)
P240.34121 (3)0.78461 (3)0.79910 (3)0.01731 (14)
F11A1.0014 (7)0.5327 (5)0.9360 (4)0.134 (4)0.5
F11B0.9719 (7)0.5089 (5)0.9448 (4)0.134 (4)0.5
F120.95130 (19)0.5287 (3)1.0141 (2)0.147 (2)
F210.46885 (13)0.48476 (16)0.95873 (12)0.0778 (10)
F220.43170 (16)0.4946 (2)1.03813 (18)0.1103 (15)
C1110.83210 (12)0.75585 (13)0.84283 (12)0.0242 (6)
C1120.83388 (14)0.77050 (16)0.89717 (14)0.0346 (8)
H1120.81410.80110.90950.042*
C1130.86446 (16)0.74040 (18)0.93330 (15)0.0462 (10)
H1130.86450.75010.97050.055*
C1140.89500 (16)0.69643 (16)0.91634 (16)0.0400 (9)
C1150.89311 (14)0.68244 (13)0.86203 (15)0.0301 (7)
H1150.91410.65270.84940.036*
C1160.86119 (13)0.71105 (13)0.82580 (13)0.0256 (7)
H1160.85930.69980.7890.031*
C1170.9306 (2)0.6650 (2)0.95448 (19)0.0590 (13)
H11A0.96860.67430.94790.088*
H11B0.92520.62610.94850.088*
H11C0.9210.6740.99190.088*
C2110.63916 (12)0.84253 (12)0.69368 (12)0.0212 (6)
C2120.60280 (13)0.85967 (13)0.65422 (13)0.0261 (7)
H2120.57430.83630.6430.031*
C2130.60785 (15)0.91087 (14)0.63106 (14)0.0324 (7)
H2130.58290.92190.60390.039*
C2140.64855 (15)0.94588 (13)0.64691 (15)0.0332 (8)
C2150.68394 (14)0.92876 (13)0.68703 (14)0.0306 (7)
H2150.7120.95240.69870.037*
C2160.67936 (13)0.87784 (13)0.71053 (13)0.0247 (6)
H2160.70390.86720.73820.03*
C2170.6540 (2)1.00130 (15)0.62221 (18)0.0494 (11)
H21A0.64711.02890.64990.074*
H21B0.62761.00530.59270.074*
H21C0.69071.00590.60790.074*
C2210.59100 (11)0.73933 (12)0.67921 (12)0.0195 (6)
C2220.53804 (12)0.72571 (12)0.69226 (13)0.0236 (6)
H2220.52380.73470.72690.028*
C2230.50605 (12)0.69900 (13)0.65465 (13)0.0256 (7)
H2230.47010.68920.66430.031*
C2240.52499 (13)0.68608 (13)0.60307 (13)0.0251 (6)
C2250.57819 (13)0.69914 (14)0.59142 (14)0.0281 (7)
H2250.59270.690.55690.034*
C2260.61085 (12)0.72517 (13)0.62887 (13)0.0259 (7)
H2260.64730.73340.61980.031*
C2270.48939 (14)0.65850 (16)0.56239 (15)0.0346 (8)
H22A0.51080.64920.53030.052*
H22B0.45980.68290.5520.052*
H22C0.47430.62540.57830.052*
C2310.59986 (11)0.78528 (12)0.78650 (12)0.0199 (6)
C2320.59169 (12)0.74153 (13)0.82122 (13)0.0275 (7)
H2320.60450.70670.81120.033*
C2330.56511 (13)0.74825 (15)0.87006 (13)0.0320 (7)
H2330.55990.71790.89320.038*
C2340.54599 (13)0.79866 (15)0.88569 (13)0.0291 (7)
C2350.55378 (13)0.84216 (14)0.85117 (14)0.0284 (7)
H2350.54060.87690.86120.034*
C2360.58050 (12)0.83571 (13)0.80229 (13)0.0225 (6)
H2360.58570.86610.77930.027*
C2370.51783 (17)0.80629 (18)0.93925 (16)0.0453 (10)
H23A0.53050.77880.96490.068*
H23B0.47860.80260.93420.068*
H23C0.5260.84240.95350.068*
C3110.22806 (13)0.66930 (12)0.86549 (12)0.0245 (6)
C3120.28104 (13)0.65113 (12)0.86081 (13)0.0247 (6)
H3120.29860.65240.82660.03*
C3130.30859 (14)0.63113 (13)0.90541 (14)0.0275 (7)
H3130.34490.6190.90130.033*
C3140.28422 (16)0.62852 (16)0.95586 (15)0.0381 (9)
C3150.23161 (18)0.64773 (18)0.96049 (15)0.0480 (11)
H3150.21430.6470.99490.058*
C3160.20348 (16)0.66816 (17)0.91586 (14)0.0390 (9)
H3160.16750.68120.92010.047*
C3170.3142 (2)0.6063 (2)1.00342 (16)0.0575 (13)
H31A0.320.56740.99840.086*
H31B0.2930.61241.03640.086*
H31C0.34930.62461.00670.086*
C4110.32941 (12)0.81954 (12)0.86334 (12)0.0205 (6)
C4120.28900 (13)0.80129 (14)0.89755 (13)0.0279 (7)
H4120.26810.77060.88760.034*
C4130.27875 (15)0.82732 (15)0.94607 (14)0.0344 (8)
H4130.25070.81430.9690.041*
C4140.30859 (16)0.87188 (14)0.96173 (14)0.0332 (8)
C4150.34967 (16)0.88970 (14)0.92806 (14)0.0359 (8)
H4150.37090.920.93840.043*
C4160.36020 (14)0.86383 (13)0.87937 (13)0.0273 (7)
H4160.38870.87650.85680.033*
C4170.2971 (2)0.89997 (17)1.01489 (16)0.0511 (12)
H41A0.26080.91611.01380.077*
H41B0.3240.92851.02090.077*
H41C0.29890.87361.04450.077*
C4210.38335 (11)0.83292 (11)0.76242 (12)0.0185 (6)
C4220.43952 (12)0.83227 (12)0.76076 (12)0.0237 (6)
H4220.4590.80490.77960.028*
C4230.46718 (13)0.87121 (13)0.73187 (14)0.0297 (7)
H4230.50560.86980.73050.036*
C4240.44042 (13)0.91236 (14)0.70486 (14)0.0289 (7)
C4250.38436 (13)0.91334 (13)0.70683 (13)0.0268 (7)
H4250.3650.94140.68890.032*
C4260.35660 (12)0.87401 (12)0.73460 (13)0.0235 (6)
H4260.31810.87480.73490.028*
C4270.47038 (17)0.95621 (18)0.6741 (2)0.0533 (12)
H42A0.50740.95920.68810.08*
H42B0.45160.99090.67890.08*
H42C0.47150.94690.63560.08*
C4310.38786 (11)0.73038 (12)0.81748 (12)0.0201 (6)
C4320.40076 (14)0.69199 (13)0.77873 (14)0.0303 (7)
H4320.38590.69510.74340.036*
C4330.43488 (15)0.64917 (14)0.79067 (16)0.0356 (8)
H4330.4440.62390.76310.043*
C4340.45585 (14)0.64280 (14)0.84225 (17)0.0374 (9)
C4350.44320 (14)0.68078 (16)0.88057 (15)0.0361 (8)
H4350.45780.67730.9160.043*
C4360.40941 (12)0.72439 (14)0.86881 (13)0.0275 (7)
H4360.40110.75010.89620.033*
C4370.49226 (18)0.59554 (18)0.8555 (2)0.0542 (12)
H43A0.52910.60320.84270.081*
H43B0.47860.56290.83760.081*
H43C0.49280.58990.89480.081*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
F210.0662 (19)0.117 (3)0.0498 (17)0.0149 (18)0.0221 (15)0.0188 (17)
F220.081 (2)0.154 (4)0.095 (3)0.020 (3)0.038 (2)0.005 (3)
P020.0416 (4)0.0416 (4)0.0416 (4)0.0023 (5)0.0023 (5)0.0023 (5)
P110.0199 (3)0.0199 (3)0.0199 (3)0.0027 (3)0.0027 (3)0.0027 (3)
P120.0151 (3)0.0177 (3)0.0227 (4)0.0015 (3)0.0012 (3)0.0009 (3)
P230.0230 (3)0.0230 (3)0.0230 (3)0.0045 (3)0.0045 (3)0.0045 (3)
P240.0169 (3)0.0188 (4)0.0162 (3)0.0003 (3)0.0009 (3)0.0009 (3)
Ag10.01623 (8)0.01623 (8)0.01623 (8)0.00046 (7)0.00046 (7)0.00046 (7)
Ag20.01793 (8)0.01793 (8)0.01793 (8)0.00111 (7)0.00111 (7)0.00111 (7)
P010.0481 (5)0.0481 (5)0.0481 (5)0.0058 (5)0.0058 (5)0.0058 (5)
F11A0.219 (13)0.131 (10)0.052 (4)0.016 (7)0.010 (5)0.022 (4)
F11B0.219 (13)0.131 (10)0.052 (4)0.016 (7)0.010 (5)0.022 (4)
F120.095 (3)0.234 (6)0.112 (4)0.062 (4)0.034 (3)0.014 (4)
C1110.0240 (14)0.0269 (16)0.0217 (14)0.0051 (12)0.0054 (11)0.0004 (12)
C1120.0311 (17)0.043 (2)0.0295 (17)0.0005 (15)0.0093 (14)0.0082 (16)
C1130.046 (2)0.066 (3)0.0260 (18)0.003 (2)0.0143 (15)0.0053 (18)
C1140.036 (2)0.044 (2)0.039 (2)0.0051 (17)0.0170 (16)0.0051 (17)
C1150.0266 (17)0.0238 (16)0.0400 (19)0.0061 (13)0.0112 (14)0.0021 (14)
C1160.0264 (16)0.0239 (16)0.0266 (16)0.0043 (13)0.0056 (13)0.0026 (13)
C1170.055 (3)0.072 (3)0.050 (3)0.008 (2)0.026 (2)0.015 (2)
C2110.0234 (15)0.0189 (14)0.0213 (15)0.0029 (11)0.0028 (12)0.0007 (11)
C2120.0256 (16)0.0273 (16)0.0254 (16)0.0040 (13)0.0001 (12)0.0005 (13)
C2130.0377 (19)0.0284 (18)0.0310 (18)0.0086 (15)0.0006 (15)0.0039 (14)
C2140.046 (2)0.0212 (16)0.0326 (19)0.0045 (14)0.0097 (15)0.0041 (13)
C2150.0323 (18)0.0222 (16)0.0374 (19)0.0001 (13)0.0035 (14)0.0038 (14)
C2160.0213 (15)0.0255 (16)0.0274 (16)0.0030 (12)0.0013 (12)0.0025 (13)
C2170.076 (3)0.0261 (19)0.046 (3)0.0031 (19)0.000 (2)0.0104 (17)
C2210.0164 (13)0.0177 (14)0.0243 (14)0.0028 (11)0.0004 (10)0.0013 (11)
C2220.0216 (15)0.0215 (15)0.0276 (15)0.0045 (12)0.0038 (12)0.0033 (12)
C2230.0164 (14)0.0272 (17)0.0332 (17)0.0029 (12)0.0040 (12)0.0016 (13)
C2240.0226 (15)0.0214 (15)0.0313 (17)0.0009 (12)0.0031 (13)0.0011 (12)
C2250.0245 (16)0.0326 (18)0.0273 (17)0.0027 (13)0.0045 (13)0.0051 (13)
C2260.0184 (14)0.0299 (17)0.0294 (16)0.0007 (12)0.0051 (12)0.0032 (13)
C2270.0266 (17)0.044 (2)0.0333 (19)0.0043 (15)0.0013 (14)0.0113 (16)
C2310.0133 (13)0.0232 (14)0.0232 (15)0.0011 (11)0.0027 (11)0.0010 (11)
C2320.0259 (15)0.0251 (17)0.0315 (17)0.0033 (13)0.0057 (12)0.0031 (13)
C2330.0311 (17)0.0342 (18)0.0307 (17)0.0009 (15)0.0034 (13)0.0049 (15)
C2340.0214 (15)0.0398 (19)0.0261 (17)0.0041 (14)0.0049 (12)0.0070 (14)
C2350.0222 (16)0.0318 (18)0.0313 (18)0.0014 (13)0.0006 (13)0.0089 (14)
C2360.0187 (14)0.0235 (15)0.0251 (15)0.0013 (12)0.0005 (12)0.0029 (12)
C2370.045 (2)0.058 (3)0.032 (2)0.0035 (19)0.0132 (17)0.0088 (18)
C3110.0257 (16)0.0251 (15)0.0226 (15)0.0050 (13)0.0036 (13)0.0029 (12)
C3120.0271 (16)0.0191 (15)0.0277 (16)0.0054 (12)0.0063 (13)0.0009 (12)
C3130.0283 (17)0.0191 (15)0.0351 (18)0.0025 (12)0.0013 (13)0.0028 (13)
C3140.047 (2)0.038 (2)0.0297 (18)0.0126 (16)0.0065 (16)0.0036 (15)
C3150.053 (2)0.068 (3)0.0226 (17)0.024 (2)0.0080 (17)0.0083 (17)
C3160.0338 (19)0.055 (2)0.0278 (18)0.0142 (17)0.0103 (15)0.0081 (16)
C3170.067 (3)0.076 (3)0.029 (2)0.030 (3)0.010 (2)0.004 (2)
C4110.0231 (15)0.0212 (14)0.0173 (14)0.0020 (11)0.0005 (11)0.0019 (11)
C4120.0292 (17)0.0310 (17)0.0237 (16)0.0057 (13)0.0025 (13)0.0055 (13)
C4130.035 (2)0.041 (2)0.0266 (17)0.0083 (16)0.0111 (14)0.0047 (14)
C4140.048 (2)0.0289 (18)0.0226 (17)0.0035 (15)0.0069 (15)0.0067 (13)
C4150.053 (2)0.0285 (18)0.0261 (17)0.0178 (16)0.0029 (16)0.0063 (14)
C4160.0351 (18)0.0267 (16)0.0200 (15)0.0086 (13)0.0043 (13)0.0025 (12)
C4170.076 (3)0.045 (2)0.033 (2)0.018 (2)0.021 (2)0.0194 (18)
C4210.0174 (13)0.0198 (13)0.0184 (14)0.0010 (10)0.0013 (11)0.0024 (11)
C4220.0206 (14)0.0261 (15)0.0245 (16)0.0028 (11)0.0021 (12)0.0048 (12)
C4230.0189 (15)0.0346 (17)0.0357 (18)0.0007 (12)0.0014 (13)0.0082 (15)
C4240.0260 (17)0.0314 (18)0.0293 (17)0.0031 (13)0.0022 (13)0.0064 (14)
C4250.0262 (16)0.0269 (16)0.0274 (17)0.0017 (13)0.0021 (13)0.0059 (13)
C4260.0188 (14)0.0261 (15)0.0254 (15)0.0005 (11)0.0009 (12)0.0008 (13)
C4270.033 (2)0.053 (3)0.074 (3)0.0062 (19)0.004 (2)0.035 (2)
C4310.0183 (13)0.0192 (14)0.0230 (14)0.0003 (11)0.0003 (11)0.0040 (12)
C4320.0325 (18)0.0261 (16)0.0321 (18)0.0064 (13)0.0042 (14)0.0004 (13)
C4330.0327 (19)0.0271 (18)0.047 (2)0.0071 (14)0.0020 (16)0.0050 (15)
C4340.0265 (17)0.0282 (18)0.057 (2)0.0028 (14)0.0011 (16)0.0146 (17)
C4350.0251 (18)0.046 (2)0.037 (2)0.0039 (15)0.0083 (14)0.0133 (16)
C4360.0214 (15)0.0353 (18)0.0259 (16)0.0005 (13)0.0052 (12)0.0030 (14)
C4370.040 (2)0.043 (3)0.079 (3)0.0132 (19)0.000 (2)0.013 (2)
Geometric parameters (Å, º) top
F21—P021.562 (3)C226—H2260.95
F22—P021.579 (4)C227—H22A0.98
P02—F21i1.562 (3)C227—H22B0.98
P02—F21ii1.562 (3)C227—H22C0.98
P02—F22ii1.579 (4)C231—C2361.389 (4)
P02—F22i1.579 (4)C231—C2321.393 (4)
P11—C111iii1.826 (3)C232—C2331.382 (4)
P11—C1111.826 (3)C232—H2320.95
P11—C111iv1.826 (3)C233—C2341.386 (5)
P11—Ag12.5695 (13)C233—H2330.95
P12—C2311.818 (3)C234—C2351.384 (5)
P12—C2211.824 (3)C234—C2371.506 (5)
P12—C2111.824 (3)C235—C2361.384 (4)
P12—Ag12.5737 (7)C235—H2350.95
P23—C311v1.818 (3)C236—H2360.95
P23—C3111.818 (3)C237—H23A0.98
P23—C311vi1.818 (3)C237—H23B0.98
P23—Ag22.5665 (13)C237—H23C0.98
P24—C4311.823 (3)C311—C3161.384 (4)
P24—C4211.823 (3)C311—C3121.387 (5)
P24—C4111.828 (3)C312—C3131.385 (5)
P24—Ag22.6142 (7)C312—H3120.95
Ag1—P12iv2.5737 (7)C313—C3141.385 (5)
Ag1—P12iii2.5737 (7)C313—H3130.95
Ag2—P24v2.6142 (7)C314—C3151.387 (6)
Ag2—P24vi2.6142 (7)C314—C3171.492 (5)
P01—F11Bvii1.489 (13)C315—C3161.397 (5)
P01—F11B1.489 (13)C315—H3150.95
P01—F11Bviii1.489 (13)C316—H3160.95
P01—F12vii1.518 (4)C317—H31A0.98
P01—F12viii1.518 (4)C317—H31B0.98
P01—F121.518 (4)C317—H31C0.98
P01—F11Avii1.622 (10)C411—C4121.382 (4)
P01—F11A1.622 (10)C411—C4161.389 (4)
P01—F11Aviii1.622 (10)C412—C4131.383 (5)
F11B—F12viii1.603 (13)C412—H4120.95
F12—F11Bvii1.603 (14)C413—C4141.379 (5)
C111—C1161.384 (5)C413—H4130.95
C111—C1121.390 (4)C414—C4151.383 (5)
C112—C1131.385 (5)C414—C4171.511 (5)
C112—H1120.95C415—C4161.386 (5)
C113—C1141.386 (6)C415—H4150.95
C113—H1130.95C416—H4160.95
C114—C1151.385 (5)C417—H41A0.98
C114—C1171.503 (5)C417—H41B0.98
C115—C1161.386 (4)C417—H41C0.98
C115—H1150.95C421—C4221.387 (4)
C116—H1160.95C421—C4261.391 (4)
C117—H11A0.98C422—C4231.378 (4)
C117—H11B0.98C422—H4220.95
C117—H11C0.98C423—C4241.383 (5)
C211—C2161.385 (4)C423—H4230.95
C211—C2121.390 (4)C424—C4251.385 (5)
C212—C2131.393 (5)C424—C4271.514 (5)
C212—H2120.95C425—C4261.372 (4)
C213—C2141.382 (5)C425—H4250.95
C213—H2130.95C426—H4260.95
C214—C2151.387 (5)C427—H42A0.98
C214—C2171.504 (5)C427—H42B0.98
C215—C2161.389 (5)C427—H42C0.98
C215—H2150.95C431—C4361.382 (4)
C216—H2160.95C431—C4321.383 (4)
C217—H21A0.98C432—C4331.383 (5)
C217—H21B0.98C432—H4320.95
C217—H21C0.98C433—C4341.383 (5)
C221—C2261.380 (4)C433—H4330.95
C221—C2221.388 (4)C434—C4351.368 (6)
C222—C2231.386 (4)C434—C4371.509 (5)
C222—H2220.95C435—C4361.393 (5)
C223—C2241.393 (5)C435—H4350.95
C223—H2230.95C436—H4360.95
C224—C2251.383 (5)C437—H43A0.98
C224—C2271.498 (5)C437—H43B0.98
C225—C2261.385 (5)C437—H43C0.98
C225—H2250.95
F21—P02—F21i90.4 (2)C223—C222—H222120.1
F21—P02—F21ii90.4 (2)C221—C222—H222120.1
F21i—P02—F21ii90.4 (2)C222—C223—C224122.0 (3)
F21—P02—F22ii91.5 (2)C222—C223—H223119
F21i—P02—F22ii177.3 (2)C224—C223—H223119
F21ii—P02—F22ii87.7 (2)C225—C224—C223117.1 (3)
F21—P02—F22i177.3 (2)C225—C224—C227121.6 (3)
F21i—P02—F22i87.7 (2)C223—C224—C227121.3 (3)
F21ii—P02—F22i91.5 (2)C224—C225—C226121.5 (3)
F22ii—P02—F22i90.3 (3)C224—C225—H225119.3
F21—P02—F2287.7 (2)C226—C225—H225119.3
F21i—P02—F2291.5 (2)C221—C226—C225120.8 (3)
F21ii—P02—F22177.3 (2)C221—C226—H226119.6
F22ii—P02—F2290.3 (3)C225—C226—H226119.6
F22i—P02—F2290.3 (3)C224—C227—H22A109.5
C111iii—P11—C111103.48 (12)C224—C227—H22B109.5
C111iii—P11—C111iv103.48 (12)H22A—C227—H22B109.5
C111—P11—C111iv103.48 (12)C224—C227—H22C109.5
C111iii—P11—Ag1114.95 (10)H22A—C227—H22C109.5
C111—P11—Ag1114.95 (10)H22B—C227—H22C109.5
C111iv—P11—Ag1114.95 (10)C236—C231—C232118.2 (3)
C231—P12—C221105.02 (13)C236—C231—P12122.5 (2)
C231—P12—C211103.57 (14)C232—C231—P12119.3 (2)
C221—P12—C211101.94 (14)C233—C232—C231120.8 (3)
C231—P12—Ag1117.05 (9)C233—C232—H232119.6
C221—P12—Ag1114.74 (9)C231—C232—H232119.6
C211—P12—Ag1112.83 (10)C232—C233—C234120.8 (3)
C311v—P23—C311103.66 (12)C232—C233—H233119.6
C311v—P23—C311vi103.66 (12)C234—C233—H233119.6
C311—P23—C311vi103.66 (12)C235—C234—C233118.6 (3)
C311v—P23—Ag2114.80 (10)C235—C234—C237120.5 (3)
C311—P23—Ag2114.80 (10)C233—C234—C237120.9 (3)
C311vi—P23—Ag2114.80 (10)C234—C235—C236120.9 (3)
C431—P24—C421104.09 (13)C234—C235—H235119.6
C431—P24—C411103.36 (14)C236—C235—H235119.6
C421—P24—C411102.30 (13)C235—C236—C231120.8 (3)
C431—P24—Ag2115.88 (10)C235—C236—H236119.6
C421—P24—Ag2113.02 (9)C231—C236—H236119.6
C411—P24—Ag2116.49 (10)C234—C237—H23A109.5
P11—Ag1—P12iv109.311 (18)C234—C237—H23B109.5
P11—Ag1—P12109.310 (18)H23A—C237—H23B109.5
P12iv—Ag1—P12109.631 (18)C234—C237—H23C109.5
P11—Ag1—P12iii109.310 (18)H23A—C237—H23C109.5
P12iv—Ag1—P12iii109.631 (18)H23B—C237—H23C109.5
P12—Ag1—P12iii109.632 (18)C316—C311—C312118.8 (3)
P23—Ag2—P24v109.502 (18)C316—C311—P23123.4 (3)
P23—Ag2—P24109.502 (18)C312—C311—P23117.8 (2)
P24v—Ag2—P24109.441 (18)C313—C312—C311120.8 (3)
P23—Ag2—P24vi109.502 (18)C313—C312—H312119.6
P24v—Ag2—P24vi109.441 (18)C311—C312—H312119.6
P24—Ag2—P24vi109.441 (18)C314—C313—C312121.2 (3)
F11Bvii—P01—F11B115.7 (3)C314—C313—H313119.4
F11Bvii—P01—F11Bviii115.7 (3)C312—C313—H313119.4
F11B—P01—F11Bviii115.7 (3)C313—C314—C315117.7 (3)
F11Bvii—P01—F12vii75.9 (6)C313—C314—C317120.6 (4)
F11B—P01—F12vii163.8 (5)C315—C314—C317121.7 (4)
F11Bviii—P01—F12vii64.4 (6)C314—C315—C316121.6 (4)
F11Bvii—P01—F12viii163.8 (5)C314—C315—H315119.2
F11B—P01—F12viii64.4 (6)C316—C315—H315119.2
F11Bviii—P01—F12viii75.9 (6)C311—C316—C315119.9 (3)
F12vii—P01—F12viii101.2 (3)C311—C316—H316120.1
F11Bvii—P01—F1264.4 (6)C315—C316—H316120.1
F11B—P01—F1275.9 (6)C314—C317—H31A109.5
F11Bviii—P01—F12163.8 (5)C314—C317—H31B109.5
F12vii—P01—F12101.2 (3)H31A—C317—H31B109.5
F12viii—P01—F12101.2 (3)C314—C317—H31C109.5
F11Bvii—P01—F11Avii35.6 (7)H31A—C317—H31C109.5
F11B—P01—F11Avii102.2 (9)H31B—C317—H31C109.5
F11Bviii—P01—F11Avii97.9 (9)C412—C411—C416118.5 (3)
F12vii—P01—F11Avii93.7 (6)C412—C411—P24119.4 (2)
F12viii—P01—F11Avii159.1 (6)C416—C411—P24122.1 (2)
F12—P01—F11Avii90.1 (5)C411—C412—C413120.6 (3)
F11Bvii—P01—F11A97.9 (9)C411—C412—H412119.7
F11B—P01—F11A35.6 (7)C413—C412—H412119.7
F11Bviii—P01—F11A102.2 (9)C414—C413—C412121.1 (3)
F12vii—P01—F11A159.1 (6)C414—C413—H413119.5
F12viii—P01—F11A90.1 (5)C412—C413—H413119.5
F12—P01—F11A93.7 (6)C413—C414—C415118.5 (3)
F11Avii—P01—F11A71.5 (9)C413—C414—C417120.6 (3)
F11Bvii—P01—F11Aviii102.2 (9)C415—C414—C417120.9 (3)
F11B—P01—F11Aviii97.9 (9)C414—C415—C416120.8 (3)
F11Bviii—P01—F11Aviii35.6 (7)C414—C415—H415119.6
F12vii—P01—F11Aviii90.1 (6)C416—C415—H415119.6
F12viii—P01—F11Aviii93.7 (6)C415—C416—C411120.5 (3)
F12—P01—F11Aviii159.1 (6)C415—C416—H416119.8
F11Avii—P01—F11Aviii71.5 (9)C411—C416—H416119.8
F11A—P01—F11Aviii71.5 (9)C414—C417—H41A109.5
P01—F11B—F12viii58.7 (5)C414—C417—H41B109.5
P01—F12—F11Bvii56.9 (5)H41A—C417—H41B109.5
C116—C111—C112119.0 (3)C414—C417—H41C109.5
C116—C111—P11117.7 (2)H41A—C417—H41C109.5
C112—C111—P11123.3 (3)H41B—C417—H41C109.5
C113—C112—C111120.0 (4)C422—C421—C426117.9 (3)
C113—C112—H112120C422—C421—P24125.3 (2)
C111—C112—H112120C426—C421—P24116.8 (2)
C112—C113—C114121.5 (3)C423—C422—C421120.2 (3)
C112—C113—H113119.3C423—C422—H422119.9
C114—C113—H113119.3C421—C422—H422119.9
C115—C114—C113118.0 (3)C422—C423—C424121.7 (3)
C115—C114—C117119.8 (4)C422—C423—H423119.2
C113—C114—C117122.2 (4)C424—C423—H423119.2
C114—C115—C116121.1 (3)C423—C424—C425118.2 (3)
C114—C115—H115119.4C423—C424—C427122.2 (3)
C116—C115—H115119.4C425—C424—C427119.5 (3)
C111—C116—C115120.4 (3)C426—C425—C424120.3 (3)
C111—C116—H116119.8C426—C425—H425119.9
C115—C116—H116119.8C424—C425—H425119.9
C114—C117—H11A109.5C425—C426—C421121.7 (3)
C114—C117—H11B109.5C425—C426—H426119.2
H11A—C117—H11B109.5C421—C426—H426119.2
C114—C117—H11C109.5C424—C427—H42A109.5
H11A—C117—H11C109.5C424—C427—H42B109.5
H11B—C117—H11C109.5H42A—C427—H42B109.5
C216—C211—C212118.8 (3)C424—C427—H42C109.5
C216—C211—P12117.8 (2)H42A—C427—H42C109.5
C212—C211—P12123.4 (2)H42B—C427—H42C109.5
C211—C212—C213120.4 (3)C436—C431—C432118.2 (3)
C211—C212—H212119.8C436—C431—P24123.3 (2)
C213—C212—H212119.8C432—C431—P24118.4 (2)
C214—C213—C212121.1 (3)C433—C432—C431121.1 (3)
C214—C213—H213119.5C433—C432—H432119.5
C212—C213—H213119.5C431—C432—H432119.5
C213—C214—C215118.0 (3)C434—C433—C432120.7 (4)
C213—C214—C217121.2 (4)C434—C433—H433119.6
C215—C214—C217120.7 (4)C432—C433—H433119.6
C214—C215—C216121.5 (3)C435—C434—C433118.3 (3)
C214—C215—H215119.2C435—C434—C437121.1 (4)
C216—C215—H215119.2C433—C434—C437120.7 (4)
C211—C216—C215120.2 (3)C434—C435—C436121.5 (3)
C211—C216—H216119.9C434—C435—H435119.3
C215—C216—H216119.9C436—C435—H435119.3
C214—C217—H21A109.5C431—C436—C435120.3 (3)
C214—C217—H21B109.5C431—C436—H436119.9
H21A—C217—H21B109.5C435—C436—H436119.9
C214—C217—H21C109.5C434—C437—H43A109.5
H21A—C217—H21C109.5C434—C437—H43B109.5
H21B—C217—H21C109.5H43A—C437—H43B109.5
C226—C221—C222118.8 (3)C434—C437—H43C109.5
C226—C221—P12116.4 (2)H43A—C437—H43C109.5
C222—C221—P12124.7 (2)H43B—C437—H43C109.5
C223—C222—C221119.8 (3)
C111iii—P11—Ag1—P12iv104.93 (11)P12—C221—C222—C223179.2 (2)
C111—P11—Ag1—P12iv15.07 (11)C221—C222—C223—C2241.3 (5)
C111iv—P11—Ag1—P12iv135.07 (11)C222—C223—C224—C2252.5 (5)
C111iii—P11—Ag1—P1215.07 (11)C222—C223—C224—C227178.4 (3)
C111—P11—Ag1—P12135.07 (11)C223—C224—C225—C2261.6 (5)
C111iv—P11—Ag1—P12104.93 (11)C227—C224—C225—C226179.3 (3)
C111iii—P11—Ag1—P12iii135.07 (11)C222—C221—C226—C2251.7 (5)
C111—P11—Ag1—P12iii104.93 (11)P12—C221—C226—C225178.3 (3)
C111iv—P11—Ag1—P12iii15.07 (11)C224—C225—C226—C2210.5 (5)
C231—P12—Ag1—P1159.70 (11)C221—P12—C231—C236107.8 (3)
C221—P12—Ag1—P11176.54 (10)C211—P12—C231—C2361.2 (3)
C211—P12—Ag1—P1160.36 (11)Ag1—P12—C231—C236123.6 (2)
C231—P12—Ag1—P12iv60.10 (12)C221—P12—C231—C23274.8 (3)
C221—P12—Ag1—P12iv63.65 (10)C211—P12—C231—C232178.6 (2)
C211—P12—Ag1—P12iv179.84 (11)Ag1—P12—C231—C23253.8 (3)
C231—P12—Ag1—P12iii179.50 (11)C236—C231—C232—C2330.1 (5)
C221—P12—Ag1—P12iii56.74 (11)P12—C231—C232—C233177.4 (3)
C211—P12—Ag1—P12iii59.44 (12)C231—C232—C233—C2340.1 (5)
C311v—P23—Ag2—P24v14.78 (11)C232—C233—C234—C2350.4 (5)
C311—P23—Ag2—P24v134.78 (11)C232—C233—C234—C237179.0 (3)
C311vi—P23—Ag2—P24v105.22 (11)C233—C234—C235—C2360.6 (5)
C311v—P23—Ag2—P24105.22 (11)C237—C234—C235—C236178.8 (3)
C311—P23—Ag2—P2414.78 (11)C234—C235—C236—C2310.5 (5)
C311vi—P23—Ag2—P24134.78 (11)C232—C231—C236—C2350.1 (4)
C311v—P23—Ag2—P24vi134.78 (11)P12—C231—C236—C235177.5 (2)
C311—P23—Ag2—P24vi105.22 (11)C311v—P23—C311—C31610.8 (4)
C311vi—P23—Ag2—P24vi14.78 (11)C311vi—P23—C311—C31697.2 (3)
C431—P24—Ag2—P2365.73 (10)Ag2—P23—C311—C316136.8 (3)
C421—P24—Ag2—P23174.26 (10)C311v—P23—C311—C312167.5 (2)
C411—P24—Ag2—P2356.20 (11)C311vi—P23—C311—C31284.5 (3)
C431—P24—Ag2—P24v174.24 (10)Ag2—P23—C311—C31241.5 (3)
C421—P24—Ag2—P24v54.23 (10)C316—C311—C312—C3131.3 (5)
C411—P24—Ag2—P24v63.84 (12)P23—C311—C312—C313179.8 (2)
C431—P24—Ag2—P24vi54.31 (11)C311—C312—C313—C3140.1 (5)
C421—P24—Ag2—P24vi65.70 (10)C312—C313—C314—C3151.4 (5)
C411—P24—Ag2—P24vi176.24 (11)C312—C313—C314—C317179.3 (4)
F11Bvii—P01—F11B—F12viii162.0 (6)C313—C314—C315—C3161.1 (6)
F11Bviii—P01—F11B—F12viii57.9 (10)C317—C314—C315—C316179.6 (4)
F12vii—P01—F11B—F12viii29 (2)C312—C311—C316—C3151.5 (6)
F12—P01—F11B—F12viii110.0 (6)P23—C311—C316—C315179.9 (3)
F11Avii—P01—F11B—F12viii163.0 (6)C314—C315—C316—C3110.3 (7)
F11A—P01—F11B—F12viii132.2 (18)C431—P24—C411—C41286.7 (3)
F11Aviii—P01—F11B—F12viii90.4 (6)C421—P24—C411—C412165.4 (3)
F11B—P01—F12—F11Bvii128.1 (9)Ag2—P24—C411—C41241.6 (3)
F11Bviii—P01—F12—F11Bvii94.5 (18)C431—P24—C411—C41692.7 (3)
F12vii—P01—F12—F11Bvii68.3 (7)C421—P24—C411—C41615.2 (3)
F12viii—P01—F12—F11Bvii172.1 (7)Ag2—P24—C411—C416139.0 (2)
F11Avii—P01—F12—F11Bvii25.6 (10)C416—C411—C412—C4131.4 (5)
F11A—P01—F12—F11Bvii97.0 (9)P24—C411—C412—C413179.2 (3)
F11Aviii—P01—F12—F11Bvii53.2 (14)C411—C412—C413—C4140.3 (6)
C111iii—P11—C111—C116174.5 (2)C412—C413—C414—C4150.8 (6)
C111iv—P11—C111—C11677.8 (3)C412—C413—C414—C417179.9 (4)
Ag1—P11—C111—C11648.4 (3)C413—C414—C415—C4160.8 (6)
C111iii—P11—C111—C1124.5 (3)C417—C414—C415—C416179.9 (4)
C111iv—P11—C111—C112103.2 (2)C414—C415—C416—C4110.3 (6)
Ag1—P11—C111—C112130.7 (3)C412—C411—C416—C4151.4 (5)
C116—C111—C112—C1130.0 (5)P24—C411—C416—C415179.2 (3)
P11—C111—C112—C113179.1 (3)C431—P24—C421—C42212.5 (3)
C111—C112—C113—C1141.9 (6)C411—P24—C421—C42294.8 (3)
C112—C113—C114—C1151.5 (6)Ag2—P24—C421—C422139.1 (2)
C112—C113—C114—C117176.9 (4)C431—P24—C421—C426168.4 (2)
C113—C114—C115—C1160.8 (5)C411—P24—C421—C42684.2 (2)
C117—C114—C115—C116179.3 (4)Ag2—P24—C421—C42641.8 (2)
C112—C111—C116—C1152.3 (5)C426—C421—C422—C4230.5 (5)
P11—C111—C116—C115178.6 (3)P24—C421—C422—C423179.6 (2)
C114—C115—C116—C1112.7 (5)C421—C422—C423—C4241.4 (5)
C231—P12—C211—C21684.4 (3)C422—C423—C424—C4250.8 (5)
C221—P12—C211—C216166.7 (2)C422—C423—C424—C427178.4 (4)
Ag1—P12—C211—C21643.1 (3)C423—C424—C425—C4260.5 (5)
C231—P12—C211—C21296.6 (3)C427—C424—C425—C426179.8 (4)
C221—P12—C211—C21212.3 (3)C424—C425—C426—C4211.4 (5)
Ag1—P12—C211—C212135.9 (2)C422—C421—C426—C4250.9 (5)
C216—C211—C212—C2131.9 (5)P24—C421—C426—C425178.3 (3)
P12—C211—C212—C213177.2 (3)C421—P24—C431—C436102.2 (3)
C211—C212—C213—C2140.6 (5)C411—P24—C431—C4364.3 (3)
C212—C213—C214—C2150.7 (5)Ag2—P24—C431—C436133.0 (2)
C212—C213—C214—C217179.7 (3)C421—P24—C431—C43280.4 (3)
C213—C214—C215—C2160.6 (5)C411—P24—C431—C432173.0 (3)
C217—C214—C215—C216179.6 (3)Ag2—P24—C431—C43244.4 (3)
C212—C211—C216—C2151.9 (5)C436—C431—C432—C4330.9 (5)
P12—C211—C216—C215177.2 (2)P24—C431—C432—C433178.4 (3)
C214—C215—C216—C2110.7 (5)C431—C432—C433—C4341.8 (6)
C231—P12—C221—C226178.1 (2)C432—C433—C434—C4351.9 (6)
C211—P12—C221—C22674.2 (3)C432—C433—C434—C437178.9 (4)
Ag1—P12—C221—C22648.1 (3)C433—C434—C435—C4361.1 (5)
C231—P12—C221—C2222.0 (3)C437—C434—C435—C436179.7 (4)
C211—P12—C221—C222105.8 (3)C432—C431—C436—C4350.1 (5)
Ag1—P12—C221—C222131.9 (2)P24—C431—C436—C435177.5 (3)
C226—C221—C222—C2230.8 (5)C434—C435—C436—C4310.3 (5)
Symmetry codes: (i) y+1, z1/2, x+3/2; (ii) z+3/2, x+1, y+1/2; (iii) y, z, x; (iv) z, x, y; (v) z+1, x+1/2, y+3/2; (vi) y1/2, z+3/2, x+1; (vii) y+1/2, z+3/2, x+2; (viii) z+2, x1/2, y+3/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C213—H213···F21ix0.952.543.439 (4)159
Symmetry code: (ix) x+1, y+1/2, z+3/2.
Comparative geometrical parameters for similar [Ag(PR3)4]X structures (R = p-tol, Ph; X = PF6-, NO3-, ClO4-), indicated as X, R in column headings. top
ParametersPF6, p-toliPF6, PhiiNO3, PhiiiClO4, Phiv
Ag1-P112.570 (1)2.639 (2)2.642 (3)2.651 (3)
Ag1-P122.5737 (7)2.674 (1)2.671 (4)2.668 (6)
Ag2-P212.567 (1)---
Ag2-P222.6142 (7)---
P11-Ag1-P12109.31 (2)109.31 (3)109.52 (9)109.3 (2)
P12-Ag1-P12'109.63 (2)109.73 (3)109.42 (7)109.6 (2)
P23-Ag2-P24109.50 (2)---
P24-Ag2-P24'109.44 (2)---
(i) This work (ii) Bowmaker et al., 1990 (iii) Barron et al., 1986 (iv) Engelhardt et al., 1985
 

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