Structural characteristics of Bi₂O₂CO₃ nanosheets synthesized by nano-pulsed discharges in water

A comprehensive analysis of Bi₂O₂CO₃ nanosheets, which were synthesized using nanosecond-pulsed discharges in water between bis­muth electrodes, was conducted in order to investigate the crystallographic features of this material. Electron diffraction, X-ray diffraction and electron energy-loss spectrometry techniques revealed the presence of a stoichiometric tetragonal Bi₂O₂CO₃ structure, labelled BOC in this study. It crystallizes in the body-centred tetragonal Bravais lattice and belongs to the I4/mmm space group (No. 139), with the following lattice parameters: a = 3.91, c = 13.77 Å. The nanosheets adopt square shapes. This shape is dictated by the symmetry elements of its point group (4/mmm) under the prevailing local conditions. From the energetic point of view, this shape, dictated by the 4/m2/m2/m point group and therefore a pinacoid, corresponds to an absolute extremum, an indicator of the stability of these BOC nanosheets. Most nanosheets are crossed by equal-inclination fringes or bend contours. These bend contours reflect the fact that the BOC nanosheets contain crystal defects and/or are so thin that they bend elastically, leading to rotation of the lattice planes towards the diffracting Bragg position. The diffraction patterns corresponding to bend contours intersecting along the [001] zone axis have been studied in detail. Extra reflections are superimposed on the diffraction pattern of the BOC crystallographic structure. These extra reflections are essentially attributed to two phenomena: multiple diffraction and local disorder–order transformations of the BOC crystal structure, passing from a body-centred tetragonal to a primitive Bravais lattice. A mechanism related to the ledge mechanism (kinks and jogs), explaining the formation of nanosheets in a metallic matrix, has been adapted and proposed for the formation of BOC nanosheets in water. When the nanosheets are removed from the water, they become carbonated once in the air, leading to the formation of BOC that inherits the nanosheet morphology.

Computing details

(I)

Crystal data

Bi2O5C	Z = 2
Mr = 509.97	Cell parameters from 1000 reflections
Tetragonal, I4/mmm	θ = 3.0–27.0°
a = 3.867 Å	T = 300 K
c = 13.689 Å	Plate, colorless
V = 204.7 Å^3

Data collection

Bruker AXS diffractometer	h = →
10000 measured reflections	k = →
Rint = 0.05	l = →

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Biso*/Beq	Occ. (<1)
O1	0.114	0.114	0.079		0.125
O2	0.197	0.197	0.046		0.125
O3	0.228	0.228	0		0.125
O4	0	0	0.091		0.250
Bi1	0	0	0.34
O5	0	0.5	0.25
C1	0	0	0

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Bi1	0.01	0.01	0.01	0.0	0.0	0.0

Geometric parameters (Å, º)

Bi1—O1	2.3
Bi1—O1—O2	109.5