Morphological control for hollow rod crystals of a photochromic di­aryl­ethene on spherulites by surface properties of substrates

Sublimation methods utilizing the surface properties of substrates can address the challenge of controlling hollow morphologies in rod crystals. Spherulites were formed on the hydro­philic surface of the (0001) planes of α-quartz and sapphire substrates by sublimation of 1,2-bis­(3,5-di­methyl-2-thienyl)perfluoro­cyclo­pentene (1a). Various types of hollow morphologies, distinguished by the size and shape of their cross sections and by the presence or absence of branching structures, were formed separately on α-quartz and sapphire substrates. Such precise control of the hollow morphologies was attributed to the wettability of each substrate, leading to the formation of spherulites of 1a. In addition, it was indicated that the formation process of the surface morphologies of spherulites was associated with the hollow morphologies of rod crystals of 1a.

Computing details

(I)

Crystal data

C17H14F6S2	F(000) = 1616
Mr = 396.40	Dx = 1.544 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71075 Å
a = 12.047 (3) Å	Cell parameters from 8153 reflections
b = 17.400 (5) Å	θ = 2.1–27.5°
c = 16.281 (5) Å	µ = 0.37 mm^−1
β = 92.306 (3)°	T = 110 K
V = 3410.0 (16) Å^3	Block, colorless
Z = 8	0.20 × 0.20 × 0.10 mm

Data collection

Rigaku AFC11 with Saturn 724+ CCD diffractometer	7774 independent reflections
Radiation source: Rotating Anode	5934 reflections with I > 2σ(I)
Confocal monochromator	Rint = 0.064
Detector resolution: 28.5714 pixels mm^-1	θmax = 27.5°, θmin = 2.4°
dtprofit.ref scans	h = −15→15
Absorption correction: multi-scan REQAB (Rigaku, 1998)	k = −22→21
Tmin = 0.935, Tmax = 1.000	l = −21→21
34668 measured reflections

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.042	H-atom parameters constrained
wR(F^2) = 0.113	w = 1/[σ^2(Fo^2) + (0.0649P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 1.00	(Δ/σ)max = 0.002
7774 reflections	Δρmax = 0.84 e Å^−3
459 parameters	Δρmin = −0.34 e Å^−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.21828 (16)	0.07522 (11)	0.49614 (12)	0.0229 (4)
H1	0.1841	0.1201	0.4689	0.034*
H2	0.2348	0.0363	0.4549	0.034*
H3	0.2873	0.0908	0.5255	0.034*
C2	0.13997 (15)	0.04244 (10)	0.55584 (11)	0.0187 (4)
C3	0.04360 (15)	0.07326 (10)	0.58251 (11)	0.0177 (4)
H25	0.0158	0.1217	0.5642	0.021*
C4	−0.01173 (15)	0.02668 (10)	0.64013 (11)	0.0160 (4)
C5	0.04548 (15)	−0.04083 (10)	0.65718 (11)	0.0162 (4)
C6	−0.12010 (15)	0.05001 (10)	0.67453 (12)	0.0201 (4)
H4	−0.1613	0.0040	0.6900	0.030*
H5	−0.1638	0.0789	0.6329	0.030*
H6	−0.1061	0.0824	0.7231	0.030*
C7	0.01585 (14)	−0.10320 (10)	0.71156 (12)	0.0169 (4)
C8	0.02571 (16)	−0.18540 (11)	0.68345 (12)	0.0215 (4)
C9	−0.00035 (15)	−0.23435 (11)	0.75875 (12)	0.0214 (4)
C10	−0.06383 (15)	−0.17937 (10)	0.81351 (12)	0.0184 (4)
C11	−0.02989 (14)	−0.10016 (10)	0.78663 (11)	0.0159 (4)
C12	0.13901 (15)	0.03353 (11)	0.82683 (12)	0.0216 (4)
H7	0.1673	−0.0169	0.8108	0.032*
H8	0.1887	0.0558	0.8696	0.032*
H9	0.1355	0.0676	0.7789	0.032*
C13	−0.04629 (15)	−0.03476 (10)	0.84053 (11)	0.0164 (4)
C14	0.02545 (15)	0.02454 (10)	0.85908 (11)	0.0175 (4)
C15	−0.01982 (16)	0.07685 (10)	0.91606 (11)	0.0209 (4)
H26	0.0188	0.1213	0.9356	0.025*
C16	−0.12342 (16)	0.05779 (11)	0.94029 (11)	0.0213 (4)
C17	−0.19523 (18)	0.09925 (12)	0.99867 (13)	0.0304 (5)
H10	−0.2028	0.0682	1.0483	0.046*
H11	−0.2688	0.1080	0.9724	0.046*
H12	−0.1612	0.1487	1.0135	0.046*
C18	0.65730 (15)	0.15706 (11)	0.79336 (11)	0.0201 (4)
H13	0.5986	0.1873	0.8179	0.030*
H14	0.7277	0.1853	0.7984	0.030*
H15	0.6651	0.1077	0.8220	0.030*
C19	0.57893 (14)	0.07733 (10)	0.67212 (10)	0.0134 (4)
C20	0.62764 (14)	0.14314 (10)	0.70444 (11)	0.0140 (4)
C21	0.65077 (14)	0.19706 (10)	0.64145 (11)	0.0163 (4)
H27	0.6840	0.2457	0.6525	0.020*
C22	0.62109 (15)	0.17289 (10)	0.56376 (11)	0.0171 (4)
C23	0.63396 (18)	0.21479 (11)	0.48412 (12)	0.0257 (4)
H16	0.6487	0.2693	0.4953	0.039*
H17	0.5655	0.2098	0.4500	0.039*
H18	0.6961	0.1927	0.4551	0.039*
C24	0.53688 (14)	0.01147 (9)	0.71670 (10)	0.0122 (3)
C25	0.56385 (15)	−0.06967 (10)	0.69205 (10)	0.0141 (4)
C26	0.49718 (15)	−0.12125 (11)	0.74847 (11)	0.0173 (4)
C27	0.46746 (15)	−0.06813 (10)	0.81907 (11)	0.0181 (4)
C28	0.47615 (14)	0.01203 (10)	0.78502 (10)	0.0136 (4)
C29	0.33915 (15)	0.14590 (10)	0.70009 (10)	0.0169 (4)
H19	0.3948	0.1781	0.6744	0.025*
H20	0.2658	0.1699	0.6928	0.025*
H21	0.3378	0.0950	0.6742	0.025*
C30	0.42558 (15)	0.07709 (10)	0.82560 (10)	0.0138 (4)
C31	0.36827 (14)	0.13776 (10)	0.79003 (10)	0.0139 (4)
C32	0.33309 (15)	0.19089 (10)	0.85064 (11)	0.0163 (4)
H28	0.2932	0.2366	0.8371	0.020*
C33	0.36165 (16)	0.17048 (10)	0.92953 (11)	0.0185 (4)
C34	0.33665 (18)	0.21240 (11)	1.00741 (12)	0.0269 (5)
H22	0.2979	0.2605	0.9938	0.040*
H23	0.4063	0.2238	1.0382	0.040*
H24	0.2895	0.1802	1.0410	0.040*
F1	0.12776 (10)	−0.20330 (6)	0.65642 (8)	0.0347 (3)
F2	−0.04755 (11)	−0.20221 (6)	0.62057 (7)	0.0354 (3)
F3	0.09549 (9)	−0.25546 (7)	0.79899 (7)	0.0309 (3)
F4	−0.05712 (10)	−0.29904 (6)	0.73966 (8)	0.0322 (3)
F5	−0.04148 (10)	−0.19394 (6)	0.89411 (7)	0.0274 (3)
F6	−0.17572 (9)	−0.19069 (6)	0.80091 (7)	0.0260 (3)
F7	0.67445 (9)	−0.08557 (6)	0.70346 (7)	0.0251 (3)
F8	0.53935 (10)	−0.08472 (6)	0.61183 (6)	0.0254 (3)
F9	0.55042 (11)	−0.18495 (6)	0.77269 (7)	0.0325 (3)
F10	0.40124 (10)	−0.14289 (7)	0.70797 (7)	0.0334 (3)
F11	0.54338 (11)	−0.07919 (6)	0.88306 (7)	0.0307 (3)
F12	0.36773 (10)	−0.08522 (6)	0.84865 (8)	0.0317 (3)
S1	0.16556 (4)	−0.04567 (3)	0.60099 (3)	0.01907 (12)
S2	−0.16833 (4)	−0.02635 (3)	0.89374 (3)	0.02004 (12)
S3	0.56440 (4)	0.08216 (2)	0.56572 (3)	0.01603 (11)
S4	0.43413 (4)	0.08489 (3)	0.93196 (3)	0.01751 (12)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.0236 (10)	0.0235 (10)	0.0219 (10)	−0.0036 (8)	0.0027 (8)	0.0027 (8)
C2	0.0199 (9)	0.0191 (9)	0.0169 (9)	−0.0043 (7)	−0.0022 (7)	0.0003 (7)
C3	0.0193 (9)	0.0141 (9)	0.0194 (9)	−0.0017 (7)	−0.0029 (7)	0.0000 (7)
C4	0.0154 (9)	0.0150 (9)	0.0175 (9)	−0.0011 (7)	−0.0004 (7)	−0.0011 (7)
C5	0.0158 (9)	0.0137 (9)	0.0194 (9)	0.0002 (7)	0.0026 (7)	−0.0012 (7)
C6	0.0172 (9)	0.0172 (9)	0.0260 (10)	0.0038 (7)	0.0026 (8)	0.0023 (8)
C7	0.0139 (9)	0.0140 (9)	0.0226 (10)	0.0018 (7)	−0.0001 (7)	−0.0015 (7)
C8	0.0227 (10)	0.0173 (9)	0.0247 (10)	0.0043 (8)	0.0027 (8)	−0.0011 (8)
C9	0.0186 (9)	0.0123 (9)	0.0333 (11)	0.0009 (7)	−0.0004 (8)	0.0014 (8)
C10	0.0159 (9)	0.0168 (9)	0.0227 (10)	−0.0029 (7)	0.0012 (8)	0.0029 (7)
C11	0.0118 (8)	0.0131 (9)	0.0227 (10)	0.0003 (7)	−0.0006 (7)	0.0017 (7)
C12	0.0193 (10)	0.0198 (10)	0.0256 (10)	−0.0033 (8)	0.0003 (8)	0.0006 (8)
C13	0.0134 (9)	0.0162 (9)	0.0196 (9)	0.0011 (7)	0.0015 (7)	0.0016 (7)
C14	0.0181 (9)	0.0146 (9)	0.0198 (9)	−0.0005 (7)	−0.0002 (7)	0.0030 (7)
C15	0.0264 (11)	0.0160 (9)	0.0201 (10)	0.0006 (8)	−0.0027 (8)	−0.0004 (7)
C16	0.0253 (10)	0.0217 (10)	0.0167 (9)	0.0080 (8)	0.0000 (8)	0.0019 (8)
C17	0.0343 (12)	0.0325 (12)	0.0245 (11)	0.0141 (10)	0.0029 (9)	−0.0018 (9)
C18	0.0205 (10)	0.0203 (10)	0.0193 (10)	−0.0048 (8)	−0.0023 (8)	−0.0030 (7)
C19	0.0140 (9)	0.0140 (9)	0.0121 (8)	0.0024 (7)	0.0018 (7)	−0.0007 (6)
C20	0.0111 (8)	0.0137 (8)	0.0171 (9)	0.0006 (7)	0.0015 (7)	−0.0015 (7)
C21	0.0144 (9)	0.0125 (9)	0.0220 (10)	−0.0014 (7)	0.0021 (7)	0.0011 (7)
C22	0.0173 (9)	0.0139 (9)	0.0204 (10)	−0.0027 (7)	0.0039 (7)	0.0018 (7)
C23	0.0379 (12)	0.0189 (10)	0.0205 (10)	−0.0073 (9)	0.0032 (9)	0.0042 (8)
C24	0.0118 (8)	0.0134 (8)	0.0113 (8)	0.0003 (7)	−0.0013 (7)	0.0000 (7)
C25	0.0163 (9)	0.0142 (8)	0.0120 (8)	0.0010 (7)	0.0026 (7)	−0.0012 (7)
C26	0.0222 (9)	0.0118 (9)	0.0182 (9)	−0.0008 (7)	0.0027 (8)	−0.0003 (7)
C27	0.0218 (10)	0.0173 (9)	0.0155 (9)	0.0032 (7)	0.0058 (8)	0.0048 (7)
C28	0.0143 (8)	0.0137 (9)	0.0125 (8)	0.0024 (7)	−0.0013 (7)	0.0004 (7)
C29	0.0175 (9)	0.0173 (9)	0.0157 (9)	0.0034 (7)	−0.0008 (7)	0.0012 (7)
C30	0.0159 (9)	0.0132 (8)	0.0124 (8)	0.0001 (7)	0.0017 (7)	−0.0003 (6)
C31	0.0124 (8)	0.0133 (8)	0.0161 (9)	−0.0011 (7)	0.0020 (7)	0.0012 (7)
C32	0.0166 (9)	0.0112 (8)	0.0213 (10)	0.0017 (7)	0.0043 (7)	−0.0001 (7)
C33	0.0205 (10)	0.0140 (9)	0.0214 (10)	0.0016 (7)	0.0057 (8)	−0.0009 (7)
C34	0.0395 (12)	0.0214 (10)	0.0203 (10)	0.0080 (9)	0.0058 (9)	−0.0041 (8)
F1	0.0365 (8)	0.0211 (6)	0.0482 (8)	0.0116 (5)	0.0222 (6)	0.0045 (5)
F2	0.0551 (9)	0.0202 (6)	0.0300 (7)	0.0016 (6)	−0.0114 (6)	−0.0051 (5)
F3	0.0233 (6)	0.0279 (7)	0.0414 (7)	0.0088 (5)	−0.0011 (5)	0.0087 (5)
F4	0.0382 (8)	0.0145 (6)	0.0443 (8)	−0.0067 (5)	0.0065 (6)	−0.0037 (5)
F5	0.0380 (7)	0.0201 (6)	0.0241 (6)	−0.0011 (5)	0.0006 (5)	0.0060 (5)
F6	0.0158 (6)	0.0198 (6)	0.0426 (7)	−0.0048 (4)	0.0044 (5)	0.0006 (5)
F7	0.0177 (6)	0.0195 (6)	0.0385 (7)	0.0034 (4)	0.0065 (5)	0.0000 (5)
F8	0.0456 (8)	0.0187 (6)	0.0120 (5)	−0.0045 (5)	0.0007 (5)	−0.0024 (4)
F9	0.0502 (8)	0.0168 (6)	0.0317 (7)	0.0130 (6)	0.0171 (6)	0.0082 (5)
F10	0.0325 (7)	0.0382 (7)	0.0295 (7)	−0.0183 (6)	0.0029 (5)	−0.0057 (5)
F11	0.0509 (8)	0.0239 (6)	0.0167 (6)	0.0105 (5)	−0.0079 (5)	0.0026 (5)
F12	0.0342 (7)	0.0196 (6)	0.0432 (8)	0.0005 (5)	0.0242 (6)	0.0051 (5)
S1	0.0168 (2)	0.0184 (2)	0.0223 (3)	0.00277 (18)	0.00507 (19)	0.00129 (18)
S2	0.0162 (2)	0.0219 (2)	0.0223 (3)	0.00090 (18)	0.00453 (19)	0.00083 (19)
S3	0.0222 (2)	0.0141 (2)	0.0119 (2)	−0.00331 (17)	0.00166 (18)	0.00051 (16)
S4	0.0249 (3)	0.0161 (2)	0.0117 (2)	0.00440 (18)	0.00225 (18)	−0.00058 (16)

Geometric parameters (Å, º)

C1—C2	1.495 (3)	C18—C20	1.497 (2)
C2—C3	1.365 (3)	C19—C20	1.381 (2)
C2—S1	1.7227 (19)	C19—C24	1.458 (2)
C3—C4	1.425 (3)	C19—S3	1.7362 (18)
C4—C5	1.384 (2)	C20—C21	1.426 (2)
C4—C6	1.497 (2)	C21—C22	1.367 (3)
C5—C7	1.454 (2)	C22—C23	1.501 (3)
C5—S1	1.7445 (19)	C22—S3	1.7209 (18)
C7—C11	1.362 (3)	C24—C28	1.356 (3)
C7—C8	1.508 (2)	C24—C25	1.507 (2)
C8—F2	1.356 (2)	C25—F8	1.353 (2)
C8—F1	1.359 (2)	C25—F7	1.366 (2)
C8—C9	1.536 (3)	C25—C26	1.534 (2)
C9—F4	1.347 (2)	C26—F9	1.332 (2)
C9—F3	1.355 (2)	C26—F10	1.361 (2)
C9—C10	1.533 (3)	C26—C27	1.529 (3)
C10—F5	1.353 (2)	C27—F12	1.345 (2)
C10—F6	1.370 (2)	C27—F11	1.372 (2)
C10—C11	1.508 (2)	C27—C28	1.506 (2)
C11—C13	1.455 (2)	C28—C30	1.457 (2)
C12—C14	1.493 (3)	C29—C31	1.499 (2)
C13—C14	1.372 (2)	C30—C31	1.376 (2)
C13—S2	1.7424 (19)	C30—S4	1.7359 (18)
C14—C15	1.424 (3)	C31—C32	1.429 (2)
C15—C16	1.365 (3)	C32—C33	1.363 (3)
C16—C17	1.496 (3)	C33—C34	1.504 (3)
C16—S2	1.726 (2)	C33—S4	1.7260 (19)
C3—C2—C1	128.60 (17)	C24—C19—S3	120.77 (13)
C3—C2—S1	110.71 (14)	C19—C20—C21	111.34 (16)
C1—C2—S1	120.68 (14)	C19—C20—C18	125.72 (16)
C2—C3—C4	114.34 (17)	C21—C20—C18	122.90 (16)
C5—C4—C3	111.85 (16)	C22—C21—C20	114.32 (16)
C5—C4—C6	126.13 (16)	C21—C22—C23	128.15 (17)
C3—C4—C6	122.00 (16)	C21—C22—S3	110.75 (13)
C4—C5—C7	128.53 (17)	C23—C22—S3	121.10 (14)
C4—C5—S1	110.64 (13)	C28—C24—C19	127.77 (15)
C7—C5—S1	120.82 (13)	C28—C24—C25	110.76 (14)
C11—C7—C5	129.47 (16)	C19—C24—C25	121.39 (15)
C11—C7—C8	110.42 (15)	F8—C25—F7	105.41 (14)
C5—C7—C8	119.92 (16)	F8—C25—C24	113.42 (14)
F2—C8—F1	106.02 (15)	F7—C25—C24	111.91 (14)
F2—C8—C7	112.14 (15)	F8—C25—C26	111.44 (14)
F1—C8—C7	113.53 (16)	F7—C25—C26	109.35 (14)
F2—C8—C9	109.59 (16)	C24—C25—C26	105.37 (14)
F1—C8—C9	110.37 (15)	F9—C26—F10	107.62 (15)
C7—C8—C9	105.22 (16)	F9—C26—C27	113.90 (15)
F4—C9—F3	107.45 (15)	F10—C26—C27	108.16 (15)
F4—C9—C10	113.28 (15)	F9—C26—C25	113.99 (15)
F3—C9—C10	108.86 (16)	F10—C26—C25	109.06 (14)
F4—C9—C8	113.42 (16)	C27—C26—C25	103.92 (15)
F3—C9—C8	109.80 (15)	F12—C27—F11	105.94 (14)
C10—C9—C8	103.95 (15)	F12—C27—C28	114.38 (15)
F5—C10—F6	105.94 (14)	F11—C27—C28	110.81 (15)
F5—C10—C11	114.02 (15)	F12—C27—C26	112.03 (15)
F6—C10—C11	111.40 (15)	F11—C27—C26	108.48 (15)
F5—C10—C9	111.27 (15)	C28—C27—C26	105.15 (14)
F6—C10—C9	109.53 (15)	C24—C28—C30	128.84 (15)
C11—C10—C9	104.73 (15)	C24—C28—C27	110.07 (14)
C7—C11—C13	129.88 (16)	C30—C28—C27	121.08 (15)
C7—C11—C10	110.44 (15)	C31—C30—C28	128.11 (16)
C13—C11—C10	119.66 (16)	C31—C30—S4	111.61 (13)
C14—C13—C11	128.41 (17)	C28—C30—S4	120.28 (13)
C14—C13—S2	111.36 (14)	C30—C31—C32	111.31 (16)
C11—C13—S2	120.21 (13)	C30—C31—C29	125.26 (16)
C13—C14—C15	111.70 (17)	C32—C31—C29	123.33 (16)
C13—C14—C12	125.41 (17)	C33—C32—C31	114.30 (16)
C15—C14—C12	122.86 (17)	C32—C33—C34	128.07 (17)
C16—C15—C14	114.32 (17)	C32—C33—S4	110.77 (13)
C15—C16—C17	128.71 (19)	C34—C33—S4	121.16 (14)
C15—C16—S2	110.70 (14)	C2—S1—C5	92.45 (9)
C17—C16—S2	120.59 (16)	C16—S2—C13	91.93 (9)
C20—C19—C24	127.79 (16)	C22—S3—C19	92.22 (8)
C20—C19—S3	111.36 (13)	C33—S4—C30	92.00 (9)
C1—C2—C3—C4	−179.99 (18)	C20—C19—C24—C28	42.7 (3)
S1—C2—C3—C4	0.2 (2)	S3—C19—C24—C28	−133.65 (17)
C2—C3—C4—C5	0.3 (2)	C20—C19—C24—C25	−133.72 (19)
C2—C3—C4—C6	−178.37 (17)	S3—C19—C24—C25	49.9 (2)
C3—C4—C5—C7	−179.24 (18)	C28—C24—C25—F8	129.74 (16)
C6—C4—C5—C7	−0.7 (3)	C19—C24—C25—F8	−53.3 (2)
C3—C4—C5—S1	−0.6 (2)	C28—C24—C25—F7	−111.16 (17)
C6—C4—C5—S1	178.00 (15)	C19—C24—C25—F7	65.8 (2)
C4—C5—C7—C11	−39.6 (3)	C28—C24—C25—C26	7.58 (19)
S1—C5—C7—C11	141.79 (18)	C19—C24—C25—C26	−175.40 (15)
C4—C5—C7—C8	134.8 (2)	F8—C25—C26—F9	94.02 (18)
S1—C5—C7—C8	−43.8 (2)	F7—C25—C26—F9	−22.1 (2)
C11—C7—C8—F2	108.81 (19)	C24—C25—C26—F9	−142.55 (15)
C5—C7—C8—F2	−66.6 (2)	F8—C25—C26—F10	−26.3 (2)
C11—C7—C8—F1	−131.06 (17)	F7—C25—C26—F10	−142.39 (14)
C5—C7—C8—F1	53.5 (2)	C24—C25—C26—F10	97.16 (16)
C11—C7—C8—C9	−10.3 (2)	F8—C25—C26—C27	−141.43 (15)
C5—C7—C8—C9	174.30 (16)	F7—C25—C26—C27	102.44 (16)
F2—C8—C9—F4	22.9 (2)	C24—C25—C26—C27	−18.01 (17)
F1—C8—C9—F4	−93.53 (19)	F9—C26—C27—F12	−88.94 (19)
C7—C8—C9—F4	143.62 (15)	F10—C26—C27—F12	30.6 (2)
F2—C8—C9—F3	143.08 (15)	C25—C26—C27—F12	146.45 (14)
F1—C8—C9—F3	26.7 (2)	F9—C26—C27—F11	27.6 (2)
C7—C8—C9—F3	−96.16 (17)	F10—C26—C27—F11	147.24 (15)
F2—C8—C9—C10	−100.59 (17)	C25—C26—C27—F11	−96.95 (16)
F1—C8—C9—C10	143.01 (15)	F9—C26—C27—C28	146.24 (15)
C7—C8—C9—C10	20.17 (19)	F10—C26—C27—C28	−94.17 (17)
F4—C9—C10—F5	90.22 (18)	C25—C26—C27—C28	21.64 (18)
F3—C9—C10—F5	−29.2 (2)	C19—C24—C28—C30	8.4 (3)
C8—C9—C10—F5	−146.23 (15)	C25—C24—C28—C30	−174.79 (17)
F4—C9—C10—F6	−26.6 (2)	C19—C24—C28—C27	−170.15 (16)
F3—C9—C10—F6	−146.03 (14)	C25—C24—C28—C27	6.6 (2)
C8—C9—C10—F6	96.98 (17)	F12—C27—C28—C24	−141.51 (16)
F4—C9—C10—C11	−146.13 (15)	F11—C27—C28—C24	98.83 (18)
F3—C9—C10—C11	94.40 (17)	C26—C27—C28—C24	−18.2 (2)
C8—C9—C10—C11	−22.58 (18)	F12—C27—C28—C30	39.8 (2)
C5—C7—C11—C13	−11.1 (3)	F11—C27—C28—C30	−79.9 (2)
C8—C7—C11—C13	174.03 (17)	C26—C27—C28—C30	163.10 (15)
C5—C7—C11—C10	170.34 (18)	C24—C28—C30—C31	43.0 (3)
C8—C7—C11—C10	−4.5 (2)	C27—C28—C30—C31	−138.60 (19)
F5—C10—C11—C7	139.33 (17)	C24—C28—C30—S4	−136.82 (17)
F6—C10—C11—C7	−100.83 (18)	C27—C28—C30—S4	41.6 (2)
C9—C10—C11—C7	17.5 (2)	C28—C30—C31—C32	−178.97 (17)
F5—C10—C11—C13	−39.4 (2)	S4—C30—C31—C32	0.82 (19)
F6—C10—C11—C13	80.4 (2)	C28—C30—C31—C29	4.7 (3)
C9—C10—C11—C13	−161.26 (16)	S4—C30—C31—C29	−175.54 (14)
C7—C11—C13—C14	−42.2 (3)	C30—C31—C32—C33	−0.8 (2)
C10—C11—C13—C14	136.29 (19)	C29—C31—C32—C33	175.64 (16)
C7—C11—C13—S2	139.84 (18)	C31—C32—C33—C34	−179.15 (19)
C10—C11—C13—S2	−41.7 (2)	C31—C32—C33—S4	0.4 (2)
C11—C13—C14—C15	−178.61 (18)	C3—C2—S1—C5	−0.41 (15)
S2—C13—C14—C15	−0.5 (2)	C1—C2—S1—C5	179.73 (15)
C11—C13—C14—C12	−0.5 (3)	C4—C5—S1—C2	0.56 (15)
S2—C13—C14—C12	177.61 (15)	C7—C5—S1—C2	179.36 (15)
C13—C14—C15—C16	0.0 (2)	C15—C16—S2—C13	−0.58 (15)
C12—C14—C15—C16	−178.11 (17)	C17—C16—S2—C13	179.67 (16)
C14—C15—C16—C17	−179.86 (18)	C14—C13—S2—C16	0.61 (15)
C14—C15—C16—S2	0.4 (2)	C11—C13—S2—C16	178.92 (15)
C24—C19—C20—C21	−175.79 (16)	C21—C22—S3—C19	0.83 (15)
S3—C19—C20—C21	0.88 (19)	C23—C22—S3—C19	−179.85 (16)
C24—C19—C20—C18	6.3 (3)	C20—C19—S3—C22	−0.99 (14)
S3—C19—C20—C18	−177.07 (14)	C24—C19—S3—C22	175.95 (15)
C19—C20—C21—C22	−0.3 (2)	C32—C33—S4—C30	0.07 (15)
C18—C20—C21—C22	177.75 (16)	C34—C33—S4—C30	179.65 (17)
C20—C21—C22—C23	−179.74 (18)	C31—C30—S4—C33	−0.52 (14)
C20—C21—C22—S3	−0.5 (2)	C28—C30—S4—C33	179.28 (15)