Chloro­[2-(dimethyl­amino)benzyl-κ²C¹,N][4-(dimethyl­amino)pyridine-κN¹]palladium(II)

The title palladacycle, [Pd(C₉H₁₂N)Cl(C₇H₁₀N₂)] or [Pd(DMBA)Cl(DMP)] [DMBA is 2-(dimethyl­amino)benzyl, N(CH₃)₂–CH₂C₆H₄, and DMP is 4-(dimethyl­amino)pyridine, 4-N(CH₃)₂C₅H₄N], crystallizes with three crystallographically independent but conformationally almost identical mol­ecules (A, B and C) in the asymmetric unit. In all three mol­ecules, the Pd atoms are coordinated by slightly distorted square-planar arrays of two N (pyridine and amine), benzyl C and Cl atoms. The pyridine and amine N atoms are positioned trans to one another. The dihedral angles between benzene and pyridine rings are 7.47 (17), 7.34 (16) and 10.83 (15)° in mol­ecules A, B and C, respectively. In the crystal structure, weak intra- and inter­molecular C—H...N and C—H...Cl and C—H...π inter­actions stabilize the structure.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.036
• wR factor = 0.076
• Data-to-parameter ratio = 22.5

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT142_ALERT_4_C su on b - Axis Small or Missing (x 100000) .....         20 Ang.
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........         36

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   2 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2003).

Chloro[2-(dimethylamino)benzyl-κ²C¹,N][4-(dimethylamino)pyridine- κN¹]palladium(II)

Crystal data

[Pd(C9H12N)Cl(C7H10N2)]	F(000) = 2424
Mr = 398.24	Dx = 1.616 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 10570 reflections
a = 15.3217 (2) Å	θ = 1.5–29.0°
b = 20.5634 (2) Å	µ = 1.29 mm^−1
c = 17.1800 (2) Å	T = 100 K
β = 114.907 (1)°	Block, colourless
V = 4909.4 (1) Å^3	0.25 × 0.16 × 0.07 mm
Z = 12

Data collection

Bruker SMART APEXII CCD area-detector diffractometer	13045 independent reflections
Radiation source: fine-focus sealed tube	10570 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.072
Detector resolution: 8.33 pixels mm^-1	θmax = 29.0°, θmin = 1.5°
ω scans	h = −20→20
Absorption correction: multi-scan (SADABS; Bruker, 2005)	k = −28→28
Tmin = 0.737, Tmax = 0.918	l = −23→23
100404 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.036	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.076	H-atom parameters constrained
S = 1.05	w = 1/[σ^2(Fo^2) + (0.018P)^2 + 9.9822P] where P = (Fo^2 + 2Fc^2)/3
13045 reflections	(Δ/σ)max = 0.001
580 parameters	Δρmax = 1.28 e Å^−3
0 restraints	Δρmin = −0.90 e Å^−3

Special details

Experimental. The low-temperature data was collected with the Oxford Cyrosystem Cobra low-temperature attachment.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pd1A	0.190643 (17)	0.716937 (10)	0.682258 (14)	0.01365 (5)
Cl1A	0.27150 (6)	0.61631 (3)	0.75125 (5)	0.01913 (15)
N1A	0.28729 (18)	0.77418 (12)	0.78040 (16)	0.0156 (5)
N2A	0.09257 (18)	0.66646 (11)	0.58174 (15)	0.0145 (5)
N3A	−0.09539 (18)	0.54035 (11)	0.39496 (16)	0.0153 (5)
C1A	0.1373 (2)	0.80227 (14)	0.6299 (2)	0.0165 (6)
C2A	0.1770 (2)	0.85517 (15)	0.6858 (2)	0.0181 (6)
C3A	0.1528 (2)	0.91912 (15)	0.6577 (2)	0.0225 (7)
H3AA	0.1823	0.9536	0.6945	0.027*
C4A	0.0848 (3)	0.93120 (16)	0.5751 (2)	0.0263 (8)
H4AA	0.0670	0.9737	0.5567	0.032*
C5A	0.0435 (3)	0.87982 (16)	0.5199 (2)	0.0251 (7)
H5AA	−0.0022	0.8879	0.4643	0.030*
C6A	0.0697 (2)	0.81612 (15)	0.5467 (2)	0.0198 (6)
H6AA	0.0417	0.7821	0.5086	0.024*
C7A	0.2399 (2)	0.83852 (14)	0.7767 (2)	0.0185 (6)
H7AA	0.2017	0.8365	0.8095	0.022*
H7AB	0.2885	0.8719	0.8016	0.022*
C8A	0.3203 (3)	0.74785 (16)	0.8687 (2)	0.0255 (7)
H8AA	0.3615	0.7790	0.9091	0.038*
H8AB	0.3553	0.7082	0.8734	0.038*
H8AC	0.2656	0.7393	0.8807	0.038*
C9A	0.3717 (2)	0.78229 (15)	0.7601 (2)	0.0205 (6)
H9AA	0.4198	0.8079	0.8041	0.031*
H9AB	0.3521	0.8039	0.7058	0.031*
H9AC	0.3978	0.7404	0.7574	0.031*
C10A	0.0170 (2)	0.63866 (14)	0.58954 (19)	0.0159 (6)
H10A	0.0085	0.6471	0.6391	0.019*
C11A	−0.0482 (2)	0.59853 (13)	0.52875 (19)	0.0150 (6)
H11A	−0.1003	0.5819	0.5368	0.018*
C12A	−0.0359 (2)	0.58255 (13)	0.45379 (19)	0.0139 (6)
C13A	0.0414 (2)	0.61389 (13)	0.44456 (19)	0.0148 (6)
H13A	0.0516	0.6070	0.3955	0.018*
C14A	0.1015 (2)	0.65462 (14)	0.50812 (19)	0.0159 (6)
H14A	0.1511	0.6751	0.4999	0.019*
C15A	−0.1774 (2)	0.51245 (14)	0.4057 (2)	0.0186 (6)
H15A	−0.1551	0.4911	0.4603	0.028*
H15B	−0.2093	0.4815	0.3608	0.028*
H15C	−0.2215	0.5464	0.4029	0.028*
C16A	−0.0801 (2)	0.52285 (15)	0.3193 (2)	0.0201 (7)
H16A	−0.0146	0.5093	0.3367	0.030*
H16B	−0.0931	0.5598	0.2820	0.030*
H16C	−0.1225	0.4879	0.2895	0.030*
Pd1B	0.066604 (17)	0.279882 (11)	0.243404 (14)	0.01449 (5)
Cl1B	−0.03499 (6)	0.19058 (4)	0.16373 (5)	0.02557 (17)
N1B	0.16109 (19)	0.22226 (12)	0.34263 (16)	0.0170 (5)
N2B	−0.02102 (19)	0.34143 (12)	0.15216 (16)	0.0180 (5)
N3B	−0.2042 (2)	0.46501 (13)	−0.04101 (18)	0.0238 (6)
C1B	0.1476 (2)	0.35190 (14)	0.31482 (19)	0.0155 (6)
C2B	0.2297 (2)	0.33139 (15)	0.3864 (2)	0.0181 (6)
C3B	0.2905 (2)	0.37473 (16)	0.4476 (2)	0.0214 (7)
H3BA	0.3426	0.3597	0.4959	0.026*
C4B	0.2714 (3)	0.44112 (16)	0.4349 (2)	0.0252 (7)
H4BA	0.3113	0.4707	0.4750	0.030*
C5B	0.1939 (3)	0.46318 (15)	0.3633 (2)	0.0231 (7)
H5BA	0.1829	0.5076	0.3543	0.028*
C6B	0.1316 (2)	0.41879 (14)	0.3039 (2)	0.0183 (6)
H6BA	0.0786	0.4342	0.2565	0.022*
C7B	0.2523 (2)	0.25946 (15)	0.3902 (2)	0.0226 (7)
H7BA	0.2969	0.2514	0.3646	0.027*
H7BB	0.2823	0.2452	0.4495	0.027*
C8B	0.1851 (3)	0.15952 (15)	0.3133 (2)	0.0260 (7)
H8BA	0.2318	0.1366	0.3616	0.039*
H8BB	0.2111	0.1678	0.2723	0.039*
H8BC	0.1279	0.1336	0.2871	0.039*
C9B	0.1142 (3)	0.20872 (15)	0.4005 (2)	0.0225 (7)
H9BA	0.1552	0.1814	0.4468	0.034*
H9BB	0.0540	0.1871	0.3691	0.034*
H9BC	0.1030	0.2489	0.4233	0.034*
C10B	0.0005 (2)	0.36192 (15)	0.0876 (2)	0.0209 (7)
H10B	0.0580	0.3480	0.0871	0.025*
C11B	−0.0577 (2)	0.40217 (15)	0.0228 (2)	0.0224 (7)
H11B	−0.0395	0.4145	−0.0203	0.027*
C12B	−0.1454 (2)	0.42482 (14)	0.0217 (2)	0.0180 (6)
C13B	−0.1678 (2)	0.40287 (15)	0.0891 (2)	0.0201 (7)
H13B	−0.2247	0.4158	0.0916	0.024*
C14B	−0.1048 (2)	0.36228 (15)	0.1510 (2)	0.0188 (6)
H14B	−0.1212	0.3484	0.1946	0.023*
C15B	−0.1751 (3)	0.48966 (17)	−0.1061 (2)	0.0307 (8)
H15D	−0.1127	0.5094	−0.0787	0.046*
H15E	−0.2209	0.5214	−0.1408	0.046*
H15F	−0.1726	0.4544	−0.1417	0.046*
C16B	−0.2975 (3)	0.48400 (16)	−0.0444 (2)	0.0304 (8)
H16D	−0.3338	0.4458	−0.0452	0.046*
H16E	−0.3320	0.5090	−0.0954	0.046*
H16F	−0.2881	0.5097	0.0051	0.046*
Pd1C	0.218745 (17)	0.231212 (10)	0.073454 (14)	0.01361 (5)
Cl1C	0.30821 (6)	0.14343 (4)	0.16581 (5)	0.02005 (15)
N1C	0.11053 (19)	0.17102 (12)	−0.01014 (16)	0.0165 (5)
N2C	0.31162 (18)	0.29897 (12)	0.15135 (16)	0.0152 (5)
N3C	0.4618 (2)	0.46578 (12)	0.27831 (17)	0.0187 (6)
C1C	0.1459 (2)	0.29885 (15)	−0.01337 (19)	0.0178 (6)
C2C	0.0544 (2)	0.27815 (14)	−0.07051 (19)	0.0166 (6)
C3C	−0.0044 (2)	0.31733 (15)	−0.1383 (2)	0.0187 (6)
H3CA	−0.0647	0.3026	−0.1764	0.022*
C4C	0.0273 (2)	0.37860 (15)	−0.1488 (2)	0.0215 (7)
H4CA	−0.0123	0.4055	−0.1932	0.026*
C5C	0.1186 (3)	0.39952 (15)	−0.0926 (2)	0.0218 (7)
H5CA	0.1403	0.4404	−0.0997	0.026*
C6C	0.1777 (2)	0.35932 (15)	−0.0256 (2)	0.0199 (6)
H6CA	0.2390	0.3734	0.0113	0.024*
C7C	0.0232 (2)	0.21290 (15)	−0.0524 (2)	0.0188 (6)
H7CA	−0.0094	0.2178	−0.0151	0.023*
H7CB	−0.0212	0.1929	−0.1056	0.023*
C8C	0.1406 (2)	0.14436 (15)	−0.0752 (2)	0.0215 (7)
H8CA	0.0900	0.1177	−0.1150	0.032*
H8CB	0.1976	0.1186	−0.0473	0.032*
H8CC	0.1536	0.1795	−0.1056	0.032*
C9C	0.0850 (2)	0.11620 (14)	0.0327 (2)	0.0217 (7)
H9CA	0.0310	0.0931	−0.0087	0.032*
H9CB	0.0687	0.1329	0.0771	0.032*
H9CC	0.1389	0.0872	0.0575	0.032*
C10C	0.2843 (2)	0.33425 (14)	0.20375 (18)	0.0147 (6)
H10C	0.2288	0.3217	0.2091	0.018*
C11C	0.3334 (2)	0.38727 (14)	0.24940 (19)	0.0151 (6)
H11C	0.3120	0.4087	0.2859	0.018*
C12C	0.4163 (2)	0.40954 (14)	0.24120 (19)	0.0147 (6)
C13C	0.4488 (2)	0.36968 (14)	0.1916 (2)	0.0176 (6)
H13C	0.5063	0.3793	0.1880	0.021*
C14C	0.3952 (2)	0.31674 (14)	0.1487 (2)	0.0178 (6)
H14C	0.4179	0.2917	0.1161	0.021*
C15C	0.4245 (2)	0.50608 (14)	0.3274 (2)	0.0214 (7)
H15G	0.4281	0.4825	0.3768	0.032*
H15J	0.3587	0.5172	0.2921	0.032*
H15H	0.4621	0.5451	0.3455	0.032*
C16C	0.5372 (2)	0.49260 (15)	0.2570 (2)	0.0234 (7)
H16J	0.5916	0.4639	0.2774	0.035*
H16G	0.5563	0.5344	0.2837	0.035*
H16H	0.5132	0.4972	0.1959	0.035*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pd1A	0.01285 (11)	0.01455 (10)	0.01270 (11)	−0.00272 (8)	0.00456 (9)	−0.00152 (8)
Cl1A	0.0196 (4)	0.0155 (3)	0.0207 (4)	−0.0006 (3)	0.0070 (3)	−0.0018 (3)
N1A	0.0140 (13)	0.0143 (11)	0.0148 (12)	−0.0027 (9)	0.0025 (10)	−0.0031 (9)
N2A	0.0126 (13)	0.0164 (12)	0.0134 (12)	−0.0015 (9)	0.0045 (10)	−0.0009 (9)
N3A	0.0156 (13)	0.0152 (12)	0.0145 (13)	−0.0003 (9)	0.0056 (11)	−0.0025 (9)
C1A	0.0142 (15)	0.0199 (14)	0.0170 (15)	0.0014 (11)	0.0082 (13)	0.0019 (11)
C2A	0.0162 (16)	0.0201 (14)	0.0208 (16)	0.0004 (12)	0.0104 (13)	0.0003 (12)
C3A	0.0221 (18)	0.0191 (15)	0.0291 (18)	0.0019 (13)	0.0135 (15)	−0.0016 (13)
C4A	0.030 (2)	0.0222 (16)	0.032 (2)	0.0068 (14)	0.0173 (16)	0.0061 (13)
C5A	0.0250 (19)	0.0306 (17)	0.0192 (17)	0.0088 (14)	0.0087 (15)	0.0075 (13)
C6A	0.0199 (17)	0.0257 (16)	0.0163 (16)	0.0002 (13)	0.0100 (14)	0.0002 (12)
C7A	0.0212 (17)	0.0167 (14)	0.0178 (15)	−0.0026 (12)	0.0083 (13)	−0.0049 (11)
C8A	0.033 (2)	0.0212 (15)	0.0160 (16)	−0.0069 (14)	0.0040 (15)	−0.0016 (12)
C9A	0.0149 (16)	0.0207 (15)	0.0236 (17)	−0.0025 (12)	0.0058 (13)	−0.0028 (12)
C10A	0.0160 (16)	0.0186 (14)	0.0141 (14)	0.0001 (11)	0.0073 (12)	0.0000 (11)
C11A	0.0133 (15)	0.0149 (13)	0.0178 (15)	0.0007 (11)	0.0075 (12)	0.0015 (11)
C12A	0.0131 (15)	0.0124 (13)	0.0142 (14)	0.0034 (10)	0.0038 (12)	0.0017 (10)
C13A	0.0155 (15)	0.0158 (13)	0.0128 (14)	0.0032 (11)	0.0055 (12)	0.0002 (10)
C14A	0.0124 (15)	0.0191 (14)	0.0163 (15)	0.0004 (11)	0.0061 (12)	0.0037 (11)
C15A	0.0193 (17)	0.0163 (14)	0.0178 (16)	−0.0037 (12)	0.0053 (13)	−0.0006 (11)
C16A	0.0230 (18)	0.0179 (14)	0.0181 (16)	0.0002 (12)	0.0074 (14)	−0.0048 (12)
Pd1B	0.01489 (12)	0.01478 (10)	0.01449 (11)	0.00106 (8)	0.00685 (9)	0.00080 (8)
Cl1B	0.0248 (4)	0.0242 (4)	0.0267 (4)	−0.0053 (3)	0.0099 (4)	−0.0065 (3)
N1B	0.0199 (14)	0.0158 (12)	0.0162 (13)	0.0028 (10)	0.0084 (11)	0.0023 (10)
N2B	0.0170 (14)	0.0203 (13)	0.0153 (13)	0.0017 (10)	0.0055 (11)	0.0015 (10)
N3B	0.0252 (16)	0.0187 (13)	0.0210 (15)	0.0026 (11)	0.0034 (12)	0.0012 (10)
C1B	0.0159 (16)	0.0167 (14)	0.0177 (15)	0.0004 (11)	0.0110 (13)	0.0019 (11)
C2B	0.0181 (16)	0.0192 (14)	0.0194 (16)	−0.0001 (12)	0.0103 (13)	0.0024 (12)
C3B	0.0178 (17)	0.0282 (16)	0.0187 (16)	−0.0037 (13)	0.0082 (14)	−0.0018 (12)
C4B	0.0268 (19)	0.0258 (16)	0.0264 (18)	−0.0083 (14)	0.0146 (16)	−0.0070 (13)
C5B	0.0295 (19)	0.0178 (15)	0.0311 (19)	−0.0014 (13)	0.0216 (16)	−0.0012 (13)
C6B	0.0175 (16)	0.0177 (14)	0.0219 (16)	0.0021 (12)	0.0104 (13)	0.0026 (12)
C7B	0.0134 (16)	0.0263 (16)	0.0261 (17)	0.0044 (12)	0.0063 (14)	0.0045 (13)
C8B	0.033 (2)	0.0202 (15)	0.0264 (18)	0.0086 (14)	0.0134 (16)	0.0016 (13)
C9B	0.0273 (19)	0.0205 (15)	0.0224 (17)	0.0033 (13)	0.0132 (15)	0.0035 (12)
C10B	0.0169 (17)	0.0262 (16)	0.0188 (16)	0.0044 (13)	0.0068 (13)	0.0039 (12)
C11B	0.0258 (19)	0.0244 (16)	0.0180 (16)	−0.0003 (13)	0.0102 (14)	0.0037 (12)
C12B	0.0200 (17)	0.0126 (13)	0.0169 (15)	−0.0017 (11)	0.0035 (13)	−0.0033 (11)
C13B	0.0174 (17)	0.0218 (15)	0.0185 (16)	0.0046 (12)	0.0051 (13)	−0.0019 (12)
C14B	0.0167 (16)	0.0237 (15)	0.0164 (15)	−0.0003 (12)	0.0074 (13)	−0.0005 (12)
C15B	0.033 (2)	0.0241 (17)	0.0237 (18)	−0.0025 (15)	0.0011 (16)	0.0100 (14)
C16B	0.0233 (19)	0.0216 (16)	0.033 (2)	0.0055 (14)	−0.0014 (16)	0.0026 (14)
Pd1C	0.01330 (11)	0.01438 (10)	0.01201 (11)	−0.00092 (8)	0.00422 (9)	−0.00101 (8)
Cl1C	0.0203 (4)	0.0188 (3)	0.0178 (4)	0.0029 (3)	0.0048 (3)	0.0006 (3)
N1C	0.0148 (13)	0.0165 (12)	0.0169 (13)	−0.0028 (10)	0.0055 (11)	−0.0003 (10)
N2C	0.0146 (13)	0.0166 (12)	0.0136 (12)	0.0012 (9)	0.0052 (11)	−0.0006 (9)
N3C	0.0210 (15)	0.0148 (12)	0.0230 (14)	−0.0033 (10)	0.0119 (12)	−0.0025 (10)
C1C	0.0164 (16)	0.0202 (14)	0.0143 (15)	0.0032 (12)	0.0039 (13)	0.0015 (11)
C2C	0.0155 (15)	0.0177 (14)	0.0160 (15)	−0.0007 (12)	0.0062 (12)	−0.0010 (11)
C3C	0.0149 (16)	0.0252 (16)	0.0152 (15)	0.0014 (12)	0.0056 (13)	0.0001 (12)
C4C	0.0244 (18)	0.0225 (15)	0.0180 (16)	0.0066 (13)	0.0093 (14)	0.0041 (12)
C5C	0.0290 (19)	0.0158 (14)	0.0205 (16)	−0.0011 (13)	0.0103 (15)	0.0005 (12)
C6C	0.0202 (17)	0.0205 (15)	0.0169 (16)	−0.0016 (12)	0.0059 (13)	−0.0015 (12)
C7C	0.0130 (15)	0.0225 (15)	0.0193 (16)	0.0007 (12)	0.0053 (13)	0.0015 (12)
C8C	0.0194 (17)	0.0237 (15)	0.0205 (17)	−0.0054 (13)	0.0074 (14)	−0.0077 (12)
C9C	0.0200 (17)	0.0175 (14)	0.0242 (17)	−0.0060 (12)	0.0061 (14)	0.0009 (12)
C10C	0.0121 (15)	0.0191 (14)	0.0130 (14)	0.0013 (11)	0.0054 (12)	0.0022 (11)
C11C	0.0154 (15)	0.0159 (13)	0.0148 (14)	0.0011 (11)	0.0072 (12)	−0.0010 (11)
C12C	0.0148 (15)	0.0153 (13)	0.0121 (14)	−0.0005 (11)	0.0037 (12)	−0.0005 (10)
C13C	0.0146 (16)	0.0202 (14)	0.0194 (16)	−0.0008 (12)	0.0084 (13)	−0.0025 (12)
C14C	0.0179 (16)	0.0186 (14)	0.0168 (15)	0.0007 (12)	0.0073 (13)	−0.0025 (11)
C15C	0.0248 (18)	0.0158 (14)	0.0242 (17)	−0.0011 (12)	0.0109 (15)	−0.0045 (12)
C16C	0.0245 (19)	0.0193 (15)	0.0283 (18)	−0.0071 (13)	0.0130 (15)	−0.0019 (13)

Geometric parameters (Å, º)

Pd1A—C1A	1.984 (3)	C7B—H7BA	0.9700
Pd1A—N2A	2.033 (2)	C7B—H7BB	0.9700
Pd1A—N1A	2.078 (2)	C8B—H8BA	0.9600
Pd1A—Cl1A	2.4463 (8)	C8B—H8BB	0.9600
N1A—C9A	1.484 (4)	C8B—H8BC	0.9600
N1A—C8A	1.485 (4)	C9B—H9BA	0.9600
N1A—C7A	1.497 (4)	C9B—H9BB	0.9600
N2A—C10A	1.347 (4)	C9B—H9BC	0.9600
N2A—C14A	1.351 (4)	C10B—C11B	1.373 (4)
N3A—C12A	1.353 (4)	C10B—H10B	0.9300
N3A—C16A	1.460 (4)	C11B—C12B	1.415 (5)
N3A—C15A	1.461 (4)	C11B—H11B	0.9300
C1A—C6A	1.397 (4)	C12B—C13B	1.413 (4)
C1A—C2A	1.408 (4)	C13B—C14B	1.376 (4)
C2A—C3A	1.396 (4)	C13B—H13B	0.9300
C2A—C7A	1.489 (4)	C14B—H14B	0.9300
C3A—C4A	1.385 (5)	C15B—H15D	0.9600
C3A—H3AA	0.9300	C15B—H15E	0.9600
C4A—C5A	1.382 (5)	C15B—H15F	0.9600
C4A—H4AA	0.9300	C16B—H16D	0.9600
C5A—C6A	1.391 (4)	C16B—H16E	0.9600
C5A—H5AA	0.9300	C16B—H16F	0.9600
C6A—H6AA	0.9300	Pd1C—C1C	2.001 (3)
C7A—H7AA	0.9700	Pd1C—N2C	2.038 (2)
C7A—H7AB	0.9700	Pd1C—N1C	2.083 (2)
C8A—H8AA	0.9600	Pd1C—Cl1C	2.4130 (8)
C8A—H8AB	0.9600	N1C—C8C	1.482 (4)
C8A—H8AC	0.9600	N1C—C9C	1.486 (4)
C9A—H9AA	0.9600	N1C—C7C	1.497 (4)
C9A—H9AB	0.9600	N2C—C14C	1.351 (4)
C9A—H9AC	0.9600	N2C—C10C	1.352 (4)
C10A—C11A	1.376 (4)	N3C—C12C	1.362 (4)
C10A—H10A	0.9300	N3C—C16C	1.459 (4)
C11A—C12A	1.417 (4)	N3C—C15C	1.460 (4)
C11A—H11A	0.9300	C1C—C6C	1.383 (4)
C12A—C13A	1.415 (4)	C1C—C2C	1.397 (4)
C13A—C14A	1.377 (4)	C2C—C3C	1.390 (4)
C13A—H13A	0.9300	C2C—C7C	1.500 (4)
C14A—H14A	0.9300	C3C—C4C	1.389 (4)
C15A—H15A	0.9600	C3C—H3CA	0.9300
C15A—H15B	0.9600	C4C—C5C	1.391 (5)
C15A—H15C	0.9600	C4C—H4CA	0.9300
C16A—H16A	0.9600	C5C—C6C	1.397 (4)
C16A—H16B	0.9600	C5C—H5CA	0.9300
C16A—H16C	0.9600	C6C—H6CA	0.9300
Pd1B—C1B	1.989 (3)	C7C—H7CA	0.9700
Pd1B—N2B	2.022 (3)	C7C—H7CB	0.9700
Pd1B—N1B	2.080 (2)	C8C—H8CA	0.9600
Pd1B—Cl1B	2.4237 (8)	C8C—H8CB	0.9600
N1B—C9B	1.478 (4)	C8C—H8CC	0.9600
N1B—C8B	1.486 (4)	C9C—H9CA	0.9600
N1B—C7B	1.498 (4)	C9C—H9CB	0.9600
N2B—C14B	1.346 (4)	C9C—H9CC	0.9600
N2B—C10B	1.351 (4)	C10C—C11C	1.368 (4)
N3B—C12B	1.355 (4)	C10C—H10C	0.9300
N3B—C15B	1.458 (4)	C11C—C12C	1.413 (4)
N3B—C16B	1.458 (5)	C11C—H11C	0.9300
C1B—C6B	1.396 (4)	C12C—C13C	1.415 (4)
C1B—C2B	1.403 (4)	C13C—C14C	1.376 (4)
C2B—C3B	1.394 (4)	C13C—H13C	0.9300
C2B—C7B	1.514 (4)	C14C—H14C	0.9300
C3B—C4B	1.394 (5)	C15C—H15G	0.9600
C3B—H3BA	0.9300	C15C—H15J	0.9600
C4B—C5B	1.379 (5)	C15C—H15H	0.9600
C4B—H4BA	0.9300	C16C—H16J	0.9600
C5B—C6B	1.401 (4)	C16C—H16G	0.9600
C5B—H5BA	0.9300	C16C—H16H	0.9600
C6B—H6BA	0.9300
C1A—Pd1A—N2A	92.91 (11)	H7BA—C7B—H7BB	108.3
C1A—Pd1A—N1A	83.30 (11)	N1B—C8B—H8BA	109.5
N2A—Pd1A—N1A	176.19 (10)	N1B—C8B—H8BB	109.5
C1A—Pd1A—Cl1A	174.58 (9)	H8BA—C8B—H8BB	109.5
N2A—Pd1A—Cl1A	91.26 (7)	N1B—C8B—H8BC	109.5
N1A—Pd1A—Cl1A	92.50 (7)	H8BA—C8B—H8BC	109.5
C9A—N1A—C8A	109.0 (3)	H8BB—C8B—H8BC	109.5
C9A—N1A—C7A	110.2 (2)	N1B—C9B—H9BA	109.5
C8A—N1A—C7A	108.4 (2)	N1B—C9B—H9BB	109.5
C9A—N1A—Pd1A	105.49 (18)	H9BA—C9B—H9BB	109.5
C8A—N1A—Pd1A	116.26 (19)	N1B—C9B—H9BC	109.5
C7A—N1A—Pd1A	107.38 (18)	H9BA—C9B—H9BC	109.5
C10A—N2A—C14A	116.6 (3)	H9BB—C9B—H9BC	109.5
C10A—N2A—Pd1A	119.4 (2)	N2B—C10B—C11B	123.6 (3)
C14A—N2A—Pd1A	123.9 (2)	N2B—C10B—H10B	118.2
C12A—N3A—C16A	120.9 (3)	C11B—C10B—H10B	118.2
C12A—N3A—C15A	120.2 (2)	C10B—C11B—C12B	119.9 (3)
C16A—N3A—C15A	119.0 (2)	C10B—C11B—H11B	120.0
C6A—C1A—C2A	117.5 (3)	C12B—C11B—H11B	120.0
C6A—C1A—Pd1A	129.1 (2)	N3B—C12B—C13B	122.4 (3)
C2A—C1A—Pd1A	113.4 (2)	N3B—C12B—C11B	121.5 (3)
C3A—C2A—C1A	121.1 (3)	C13B—C12B—C11B	116.1 (3)
C3A—C2A—C7A	122.7 (3)	C14B—C13B—C12B	119.6 (3)
C1A—C2A—C7A	116.1 (3)	C14B—C13B—H13B	120.2
C4A—C3A—C2A	119.9 (3)	C12B—C13B—H13B	120.2
C4A—C3A—H3AA	120.0	N2B—C14B—C13B	123.9 (3)
C2A—C3A—H3AA	120.0	N2B—C14B—H14B	118.0
C5A—C4A—C3A	119.7 (3)	C13B—C14B—H14B	118.0
C5A—C4A—H4AA	120.1	N3B—C15B—H15D	109.5
C3A—C4A—H4AA	120.1	N3B—C15B—H15E	109.5
C4A—C5A—C6A	120.5 (3)	H15D—C15B—H15E	109.5
C4A—C5A—H5AA	119.7	N3B—C15B—H15F	109.5
C6A—C5A—H5AA	119.7	H15D—C15B—H15F	109.5
C5A—C6A—C1A	121.2 (3)	H15E—C15B—H15F	109.5
C5A—C6A—H6AA	119.4	N3B—C16B—H16D	109.5
C1A—C6A—H6AA	119.4	N3B—C16B—H16E	109.5
C2A—C7A—N1A	109.6 (2)	H16D—C16B—H16E	109.5
C2A—C7A—H7AA	109.7	N3B—C16B—H16F	109.5
N1A—C7A—H7AA	109.7	H16D—C16B—H16F	109.5
C2A—C7A—H7AB	109.7	H16E—C16B—H16F	109.5
N1A—C7A—H7AB	109.7	C1C—Pd1C—N2C	91.73 (11)
H7AA—C7A—H7AB	108.2	C1C—Pd1C—N1C	82.36 (11)
N1A—C8A—H8AA	109.5	N2C—Pd1C—N1C	172.76 (10)
N1A—C8A—H8AB	109.5	C1C—Pd1C—Cl1C	173.87 (9)
H8AA—C8A—H8AB	109.5	N2C—Pd1C—Cl1C	91.92 (7)
N1A—C8A—H8AC	109.5	N1C—Pd1C—Cl1C	94.34 (7)
H8AA—C8A—H8AC	109.5	C8C—N1C—C9C	108.9 (2)
H8AB—C8A—H8AC	109.5	C8C—N1C—C7C	110.2 (2)
N1A—C9A—H9AA	109.5	C9C—N1C—C7C	108.0 (2)
N1A—C9A—H9AB	109.5	C8C—N1C—Pd1C	109.26 (19)
H9AA—C9A—H9AB	109.5	C9C—N1C—Pd1C	114.09 (19)
N1A—C9A—H9AC	109.5	C7C—N1C—Pd1C	106.39 (17)
H9AA—C9A—H9AC	109.5	C14C—N2C—C10C	116.1 (3)
H9AB—C9A—H9AC	109.5	C14C—N2C—Pd1C	124.9 (2)
N2A—C10A—C11A	124.0 (3)	C10C—N2C—Pd1C	118.5 (2)
N2A—C10A—H10A	118.0	C12C—N3C—C16C	120.4 (3)
C11A—C10A—H10A	118.0	C12C—N3C—C15C	120.3 (3)
C10A—C11A—C12A	119.7 (3)	C16C—N3C—C15C	118.3 (2)
C10A—C11A—H11A	120.1	C6C—C1C—C2C	118.7 (3)
C12A—C11A—H11A	120.1	C6C—C1C—Pd1C	128.1 (2)
N3A—C12A—C13A	122.8 (3)	C2C—C1C—Pd1C	113.1 (2)
N3A—C12A—C11A	121.4 (3)	C3C—C2C—C1C	121.1 (3)
C13A—C12A—C11A	115.8 (3)	C3C—C2C—C7C	122.7 (3)
C14A—C13A—C12A	120.0 (3)	C1C—C2C—C7C	116.1 (3)
C14A—C13A—H13A	120.0	C4C—C3C—C2C	119.8 (3)
C12A—C13A—H13A	120.0	C4C—C3C—H3CA	120.1
N2A—C14A—C13A	123.7 (3)	C2C—C3C—H3CA	120.1
N2A—C14A—H14A	118.2	C3C—C4C—C5C	119.6 (3)
C13A—C14A—H14A	118.2	C3C—C4C—H4CA	120.2
N3A—C15A—H15A	109.5	C5C—C4C—H4CA	120.2
N3A—C15A—H15B	109.5	C4C—C5C—C6C	120.2 (3)
H15A—C15A—H15B	109.5	C4C—C5C—H5CA	119.9
N3A—C15A—H15C	109.5	C6C—C5C—H5CA	119.9
H15A—C15A—H15C	109.5	C1C—C6C—C5C	120.6 (3)
H15B—C15A—H15C	109.5	C1C—C6C—H6CA	119.7
N3A—C16A—H16A	109.5	C5C—C6C—H6CA	119.7
N3A—C16A—H16B	109.5	N1C—C7C—C2C	108.5 (2)
H16A—C16A—H16B	109.5	N1C—C7C—H7CA	110.0
N3A—C16A—H16C	109.5	C2C—C7C—H7CA	110.0
H16A—C16A—H16C	109.5	N1C—C7C—H7CB	110.0
H16B—C16A—H16C	109.5	C2C—C7C—H7CB	110.0
C1B—Pd1B—N2B	92.89 (11)	H7CA—C7C—H7CB	108.4
C1B—Pd1B—N1B	83.13 (11)	N1C—C8C—H8CA	109.5
N2B—Pd1B—N1B	175.97 (10)	N1C—C8C—H8CB	109.5
C1B—Pd1B—Cl1B	176.38 (9)	H8CA—C8C—H8CB	109.5
N2B—Pd1B—Cl1B	88.72 (8)	N1C—C8C—H8CC	109.5
N1B—Pd1B—Cl1B	95.22 (7)	H8CA—C8C—H8CC	109.5
C9B—N1B—C8B	108.9 (2)	H8CB—C8C—H8CC	109.5
C9B—N1B—C7B	109.6 (2)	N1C—C9C—H9CA	109.5
C8B—N1B—C7B	108.7 (3)	N1C—C9C—H9CB	109.5
C9B—N1B—Pd1B	106.91 (19)	H9CA—C9C—H9CB	109.5
C8B—N1B—Pd1B	113.8 (2)	N1C—C9C—H9CC	109.5
C7B—N1B—Pd1B	108.88 (18)	H9CA—C9C—H9CC	109.5
C14B—N2B—C10B	116.7 (3)	H9CB—C9C—H9CC	109.5
C14B—N2B—Pd1B	121.9 (2)	N2C—C10C—C11C	124.1 (3)
C10B—N2B—Pd1B	121.3 (2)	N2C—C10C—H10C	118.0
C12B—N3B—C15B	120.4 (3)	C11C—C10C—H10C	118.0
C12B—N3B—C16B	120.5 (3)	C10C—C11C—C12C	120.0 (3)
C15B—N3B—C16B	119.1 (3)	C10C—C11C—H11C	120.0
C6B—C1B—C2B	117.1 (3)	C12C—C11C—H11C	120.0
C6B—C1B—Pd1B	128.5 (2)	N3C—C12C—C11C	122.2 (3)
C2B—C1B—Pd1B	114.4 (2)	N3C—C12C—C13C	122.2 (3)
C3B—C2B—C1B	122.4 (3)	C11C—C12C—C13C	115.6 (3)
C3B—C2B—C7B	121.6 (3)	C14C—C13C—C12C	119.9 (3)
C1B—C2B—C7B	115.8 (3)	C14C—C13C—H13C	120.0
C2B—C3B—C4B	118.6 (3)	C12C—C13C—H13C	120.0
C2B—C3B—H3BA	120.7	N2C—C14C—C13C	123.8 (3)
C4B—C3B—H3BA	120.7	N2C—C14C—H14C	118.1
C5B—C4B—C3B	120.5 (3)	C13C—C14C—H14C	118.1
C5B—C4B—H4BA	119.8	N3C—C15C—H15G	109.5
C3B—C4B—H4BA	119.8	N3C—C15C—H15J	109.5
C4B—C5B—C6B	120.1 (3)	H15G—C15C—H15J	109.5
C4B—C5B—H5BA	119.9	N3C—C15C—H15H	109.5
C6B—C5B—H5BA	119.9	H15G—C15C—H15H	109.5
C1B—C6B—C5B	121.1 (3)	H15J—C15C—H15H	109.5
C1B—C6B—H6BA	119.4	N3C—C16C—H16J	109.5
C5B—C6B—H6BA	119.4	N3C—C16C—H16G	109.5
N1B—C7B—C2B	109.3 (3)	H16J—C16C—H16G	109.5
N1B—C7B—H7BA	109.8	N3C—C16C—H16H	109.5
C2B—C7B—H7BA	109.8	H16J—C16C—H16H	109.5
N1B—C7B—H7BB	109.8	H16G—C16C—H16H	109.5
C2B—C7B—H7BB	109.8
C1A—Pd1A—N1A—C9A	−93.5 (2)	C2B—C1B—C6B—C5B	−1.3 (4)
Cl1A—Pd1A—N1A—C9A	83.05 (18)	Pd1B—C1B—C6B—C5B	176.6 (2)
C1A—Pd1A—N1A—C8A	145.6 (2)	C4B—C5B—C6B—C1B	−1.5 (5)
Cl1A—Pd1A—N1A—C8A	−37.8 (2)	C9B—N1B—C7B—C2B	−85.8 (3)
C1A—Pd1A—N1A—C7A	24.0 (2)	C8B—N1B—C7B—C2B	155.3 (3)
Cl1A—Pd1A—N1A—C7A	−159.40 (18)	Pd1B—N1B—C7B—C2B	30.9 (3)
C1A—Pd1A—N2A—C10A	−102.5 (2)	C3B—C2B—C7B—N1B	156.7 (3)
Cl1A—Pd1A—N2A—C10A	81.0 (2)	C1B—C2B—C7B—N1B	−27.3 (4)
C1A—Pd1A—N2A—C14A	82.5 (2)	C14B—N2B—C10B—C11B	0.2 (5)
Cl1A—Pd1A—N2A—C14A	−94.1 (2)	Pd1B—N2B—C10B—C11B	178.1 (2)
N2A—Pd1A—C1A—C6A	−10.7 (3)	N2B—C10B—C11B—C12B	0.5 (5)
N1A—Pd1A—C1A—C6A	168.9 (3)	C15B—N3B—C12B—C13B	176.1 (3)
N2A—Pd1A—C1A—C2A	171.3 (2)	C16B—N3B—C12B—C13B	−4.1 (4)
N1A—Pd1A—C1A—C2A	−9.1 (2)	C15B—N3B—C12B—C11B	−4.3 (4)
C6A—C1A—C2A—C3A	−2.8 (5)	C16B—N3B—C12B—C11B	175.5 (3)
Pd1A—C1A—C2A—C3A	175.5 (2)	C10B—C11B—C12B—N3B	179.5 (3)
C6A—C1A—C2A—C7A	173.0 (3)	C10B—C11B—C12B—C13B	−0.8 (4)
Pd1A—C1A—C2A—C7A	−8.7 (4)	N3B—C12B—C13B—C14B	−179.8 (3)
C1A—C2A—C3A—C4A	3.5 (5)	C11B—C12B—C13B—C14B	0.6 (4)
C7A—C2A—C3A—C4A	−172.1 (3)	C10B—N2B—C14B—C13B	−0.5 (5)
C2A—C3A—C4A—C5A	−2.0 (5)	Pd1B—N2B—C14B—C13B	−178.4 (2)
C3A—C4A—C5A—C6A	0.0 (5)	C12B—C13B—C14B—N2B	0.1 (5)
C4A—C5A—C6A—C1A	0.6 (5)	C1C—Pd1C—N1C—C8C	89.5 (2)
C2A—C1A—C6A—C5A	0.7 (5)	Cl1C—Pd1C—N1C—C8C	−85.34 (19)
Pd1A—C1A—C6A—C5A	−177.2 (3)	C1C—Pd1C—N1C—C9C	−148.4 (2)
C3A—C2A—C7A—N1A	−155.1 (3)	Cl1C—Pd1C—N1C—C9C	36.8 (2)
C1A—C2A—C7A—N1A	29.1 (4)	C1C—Pd1C—N1C—C7C	−29.4 (2)
C9A—N1A—C7A—C2A	80.6 (3)	Cl1C—Pd1C—N1C—C7C	155.75 (18)
C8A—N1A—C7A—C2A	−160.2 (3)	C1C—Pd1C—N2C—C14C	−90.6 (3)
Pd1A—N1A—C7A—C2A	−33.9 (3)	Cl1C—Pd1C—N2C—C14C	84.5 (2)
C14A—N2A—C10A—C11A	1.7 (4)	C1C—Pd1C—N2C—C10C	82.0 (2)
Pd1A—N2A—C10A—C11A	−173.7 (2)	Cl1C—Pd1C—N2C—C10C	−103.0 (2)
N2A—C10A—C11A—C12A	2.2 (4)	N2C—Pd1C—C1C—C6C	22.5 (3)
C16A—N3A—C12A—C13A	2.5 (4)	N1C—Pd1C—C1C—C6C	−161.7 (3)
C15A—N3A—C12A—C13A	−176.4 (3)	N2C—Pd1C—C1C—C2C	−162.0 (2)
C16A—N3A—C12A—C11A	−178.2 (3)	N1C—Pd1C—C1C—C2C	13.8 (2)
C15A—N3A—C12A—C11A	3.0 (4)	C6C—C1C—C2C—C3C	−0.3 (5)
C10A—C11A—C12A—N3A	176.2 (3)	Pd1C—C1C—C2C—C3C	−176.3 (2)
C10A—C11A—C12A—C13A	−4.4 (4)	C6C—C1C—C2C—C7C	−178.4 (3)
N3A—C12A—C13A—C14A	−177.7 (3)	Pd1C—C1C—C2C—C7C	5.6 (4)
C11A—C12A—C13A—C14A	2.9 (4)	C1C—C2C—C3C—C4C	−1.1 (5)
C10A—N2A—C14A—C13A	−3.4 (4)	C7C—C2C—C3C—C4C	176.9 (3)
Pd1A—N2A—C14A—C13A	171.7 (2)	C2C—C3C—C4C—C5C	1.5 (5)
C12A—C13A—C14A—N2A	1.1 (4)	C3C—C4C—C5C—C6C	−0.5 (5)
C1B—Pd1B—N1B—C9B	96.9 (2)	C2C—C1C—C6C—C5C	1.4 (5)
Cl1B—Pd1B—N1B—C9B	−79.86 (19)	Pd1C—C1C—C6C—C5C	176.6 (2)
C1B—Pd1B—N1B—C8B	−142.8 (2)	C4C—C5C—C6C—C1C	−0.9 (5)
Cl1B—Pd1B—N1B—C8B	40.4 (2)	C8C—N1C—C7C—C2C	−79.5 (3)
C1B—Pd1B—N1B—C7B	−21.4 (2)	C9C—N1C—C7C—C2C	161.7 (2)
Cl1B—Pd1B—N1B—C7B	161.82 (19)	Pd1C—N1C—C7C—C2C	38.8 (3)
C1B—Pd1B—N2B—C14B	−96.0 (2)	C3C—C2C—C7C—N1C	151.3 (3)
Cl1B—Pd1B—N2B—C14B	80.7 (2)	C1C—C2C—C7C—N1C	−30.6 (4)
C1B—Pd1B—N2B—C10B	86.2 (3)	C14C—N2C—C10C—C11C	3.3 (4)
Cl1B—Pd1B—N2B—C10B	−97.1 (2)	Pd1C—N2C—C10C—C11C	−170.0 (2)
N2B—Pd1B—C1B—C6B	8.3 (3)	N2C—C10C—C11C—C12C	2.1 (5)
N1B—Pd1B—C1B—C6B	−171.0 (3)	C16C—N3C—C12C—C11C	−169.9 (3)
N2B—Pd1B—C1B—C2B	−173.8 (2)	C15C—N3C—C12C—C11C	−1.1 (4)
N1B—Pd1B—C1B—C2B	6.9 (2)	C16C—N3C—C12C—C13C	9.9 (4)
C6B—C1B—C2B—C3B	3.7 (5)	C15C—N3C—C12C—C13C	178.7 (3)
Pd1B—C1B—C2B—C3B	−174.5 (2)	C10C—C11C—C12C—N3C	173.1 (3)
C6B—C1B—C2B—C7B	−172.2 (3)	C10C—C11C—C12C—C13C	−6.6 (4)
Pd1B—C1B—C2B—C7B	9.6 (4)	N3C—C12C—C13C—C14C	−173.8 (3)
C1B—C2B—C3B—C4B	−3.1 (5)	C11C—C12C—C13C—C14C	6.0 (4)
C7B—C2B—C3B—C4B	172.6 (3)	C10C—N2C—C14C—C13C	−3.9 (4)
C2B—C3B—C4B—C5B	0.1 (5)	Pd1C—N2C—C14C—C13C	168.8 (2)
C3B—C4B—C5B—C6B	2.1 (5)	C12C—C13C—C14C—N2C	−0.8 (5)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C7A—H7AB···N3A^i	0.97	2.57	3.519 (4)	167
C8A—H8AB···Cl1A	0.96	2.71	3.267 (3)	117
C5B—H5BA···Cl1C^ii	0.93	2.83	3.738 (3)	168
C15A—H15B···Cl1A^iii	0.96	2.67	3.617 (3)	171
C6B—H6BA···N2B	0.93	2.62	3.108 (4)	113
C8B—H8BA···N3B^iv	0.96	2.60	3.482 (4)	153
C8B—H8BC···Cl1B	0.96	2.76	3.329 (4)	118
C3C—H3CA···Cl1C^v	0.93	2.82	3.476 (3)	129
C9C—H9CC···Cl1C	0.96	2.73	3.264 (3)	116
C9A—H9AB···Cg5^ii	0.96	2.76	3.580 (3)	143
C11A—H11A···Cg4^iii	0.93	2.74	3.522 (4)	142
C15A—H15A···Cg1^iii	0.96	3.02	3.537 (3)	116
C9B—H9BB···Cg3^iii	0.96	2.98	3.766 (5)	140
C10B—H10B···Cg5	0.93	3.11	3.693 (4)	122
C11B—H11B···Cg5	0.93	3.00	3.625 (4)	126
C6C—H6CA···Cg2	0.93	2.99	3.700 (3)	134
C11C—H11C···Cg4	0.93	2.61	3.414 (4)	145

Symmetry codes: (i) x+1/2, −y+3/2, z+1/2; (ii) −x+1/2, y+1/2, −z+1/2; (iii) −x, −y+1, −z+1; (iv) x+1/2, −y+1/2, z+1/2; (v) x−1/2, −y+1/2, z−1/2.