4-Methylpyridinium Pentachloro(4-methylpyridine-N)titanate(IV) Acetonitrile Solvate at 143K

The structure of the title compound, (C₆H₈N)[TiCl₅(C₆H₇N)].C₂H₃N, consists of discrete complexes in which the Ti atom has a distorted pseudo-octahedral coordination with an N-hydro-4-methylpyridinium cation as counterion. The 4-methylpyridine ligand and one chloro ligand occupy axial positions with the other four chloro ligands in the equatorial plane. The acetonitrile solvent molecule occupies a cavity in the structure.

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