[1,1'-Diferrocenyl-3,3'-(ethane-1,2-diyldinitrilo)dibutanolato]nickel(II) dichloro­methane solvate

The title compound, [Fe₂Ni(C₅H₅)₂(C₂₀H₂₀N₂O₂)]·CH₂Cl₂, is a four-coordinate square-planar nickel(II) complex with a tetra­dentate 1,1'-diferrocenyl-3,3'-(ethane-1,2-diyldinitrilo)dibutanolate ligand, which crystallizes with a mol­ecule of dichloro­methane. The ferrocene substituents are arranged in a syn conformation with respect to the Ni coordination plane. The complexes stack in an alternating assembly with channels occupied by the solvent mol­ecules.

Key indicators

• Single-crystal X-ray study
• T = 200 K
• Mean [sigma](C-C) = 0.004 Å
• R factor = 0.027
• wR factor = 0.070
• Data-to-parameter ratio = 15.7

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          2
              C H2 Cl2

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   1 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: SMART (Siemens, 1995); cell refinement: SAINT (Siemens, 1995); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

[1,1'-Diferrocenyl-3,3'-(ethane-1,2-diyldinitrilo)dibutanolato]nickel(II) dichloromethane solvate

Crystal data

[Fe2Ni(C5H5)2(C20H20N2O2)]·CH2Cl2	Z = 2
Mr = 705.90	F(000) = 724
Triclinic, P1	Dx = 1.667 Mg m^−3
a = 7.0218 (1) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.9673 (3) Å	Cell parameters from 8192 reflections
c = 16.3207 (3) Å	θ = 2–26°
α = 98.143 (1)°	µ = 1.90 mm^−1
β = 101.884 (1)°	T = 200 K
γ = 100.312 (1)°	Irregular fragment, brown
V = 1405.91 (5) Å^3	0.15 × 0.15 × 0.15 mm

Data collection

Siemens SMART area-detector diffractometer	5711 independent reflections
Radiation source: fine-focus sealed tube	4934 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.020
ω scans	θmax = 26.4°, θmin = 1.3°
Absorption correction: empirical (using intensity measurements) (XABS2; Parkin et al., 1995)	h = −8→8
Tmin = 0.729, Tmax = 0.752	k = −16→16
13215 measured reflections	l = 0→20

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.027	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.070	H-atom parameters constrained
S = 0.90	w = 1/[σ^2(Fo^2) + (0.0324P)^2 + 1.8447P] where P = (Fo^2 + 2Fc^2)/3
5711 reflections	(Δ/σ)max = 0.002
363 parameters	Δρmax = 0.42 e Å^−3
0 restraints	Δρmin = −0.34 e Å^−3

Special details

Experimental. ¹H NMR (CDCl₃, δ, p.p.m.): 1.93 (s, 6H, CH₃), 3.04 (m, 3H, CH₂), 4.21 (m, 10H, Cp), 4.24 (t, 4H, Cp), 4.63 (t, 4H, Cp), 5.26 (s, 2H, CH); HR—MS (FAB), calculated for C₃₀H₃₀N₂O₂Fe₂⁵⁸Ni (M⁺) m/z 620.03595; found: 620.03567.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ni	0.17718 (4)	0.99380 (2)	0.391416 (17)	0.01840 (7)
Fe1	0.10423 (5)	0.72007 (2)	0.07639 (2)	0.02042 (8)
Fe2	0.40449 (5)	1.37870 (2)	0.27434 (2)	0.02070 (8)
O1	0.1724 (2)	1.11294 (12)	0.34046 (10)	0.0238 (3)
O2	0.0839 (2)	0.92090 (12)	0.28018 (10)	0.0243 (3)
N1	0.2734 (3)	1.07140 (15)	0.50123 (11)	0.0212 (4)
N2	0.1697 (3)	0.87205 (15)	0.43901 (11)	0.0209 (4)
C1	0.2282 (3)	1.21170 (17)	0.37829 (14)	0.0215 (4)
C2	0.3053 (3)	1.24503 (18)	0.46454 (15)	0.0253 (5)
H2A	0.3480	1.3196	0.4856	0.030*
C3	0.3255 (3)	1.17611 (18)	0.52382 (14)	0.0234 (5)
C4	0.3008 (4)	1.00805 (19)	0.56857 (14)	0.0262 (5)
H4A	0.2267	1.0294	0.6113	0.031*
H4B	0.4439	1.0225	0.5976	0.031*
C5	0.2282 (4)	0.89072 (19)	0.53288 (14)	0.0271 (5)
H5A	0.3351	0.8526	0.5513	0.033*
H5B	0.1125	0.8622	0.5551	0.033*
C6	0.1119 (3)	0.77224 (18)	0.39741 (15)	0.0226 (5)
C7	0.0482 (3)	0.74516 (18)	0.30801 (15)	0.0236 (5)
H7A	0.0111	0.6716	0.2828	0.028*
C8	0.0362 (3)	0.81842 (17)	0.25465 (14)	0.0209 (4)
C9	0.4068 (4)	1.2265 (2)	0.61664 (15)	0.0300 (5)
H9A	0.3016	1.2132	0.6475	0.045*
H9B	0.4535	1.3036	0.6218	0.045*
H9C	0.5182	1.1955	0.6409	0.045*
C10	0.1152 (4)	0.68118 (19)	0.44608 (16)	0.0308 (5)
H10A	0.2525	0.6839	0.4763	0.046*
H10B	0.0629	0.6132	0.4061	0.046*
H10C	0.0324	0.6876	0.4873	0.046*
C11	0.1967 (3)	1.29008 (18)	0.32211 (15)	0.0239 (5)
C12	0.1453 (3)	1.26597 (19)	0.23109 (15)	0.0266 (5)
H12A	0.1291	1.1943	0.1952	0.032*
C13	0.1226 (4)	1.3611 (2)	0.20043 (17)	0.0313 (5)
H13A	0.0878	1.3683	0.1392	0.038*
C14	0.1597 (4)	1.4443 (2)	0.27167 (18)	0.0334 (6)
H14A	0.1560	1.5205	0.2693	0.040*
C15	0.2068 (4)	1.40173 (19)	0.34715 (17)	0.0293 (5)
H15A	0.2400	1.4423	0.4069	0.035*
C16	0.6852 (4)	1.4426 (3)	0.34581 (19)	0.0457 (7)
H16A	0.7219	1.4763	0.4075	0.055*
C17	0.6680 (4)	1.3341 (3)	0.31293 (19)	0.0417 (7)
H17A	0.6898	1.2772	0.3471	0.050*
C18	0.6150 (4)	1.3197 (2)	0.22368 (18)	0.0341 (6)
H18A	0.5915	1.2506	0.1833	0.041*
C19	0.5992 (4)	1.4194 (2)	0.20073 (17)	0.0302 (5)
H19A	0.5627	1.4332	0.1413	0.036*
C20	0.6428 (4)	1.4960 (2)	0.27613 (19)	0.0378 (6)
H20A	0.6441	1.5738	0.2799	0.045*
C21	−0.0399 (3)	0.78317 (18)	0.16180 (15)	0.0230 (5)
C22	−0.1495 (3)	0.67924 (19)	0.11753 (15)	0.0267 (5)
H22A	−0.1859	0.6159	0.1442	0.032*
C23	−0.1991 (4)	0.6825 (2)	0.02943 (16)	0.0306 (5)
H23A	−0.2751	0.6214	−0.0171	0.037*
C24	−0.1192 (4)	0.7866 (2)	0.01827 (16)	0.0316 (6)
H24A	−0.1294	0.8115	−0.0374	0.038*
C25	−0.0207 (4)	0.84902 (19)	0.09943 (15)	0.0279 (5)
H25A	0.0498	0.9256	0.1111	0.033*
C26	0.3885 (4)	0.7253 (3)	0.14014 (18)	0.0409 (7)
H26A	0.4493	0.7570	0.2015	0.049*
C27	0.2864 (4)	0.6178 (2)	0.10714 (19)	0.0394 (7)
H27A	0.2623	0.5604	0.1410	0.047*
C28	0.2254 (4)	0.60666 (19)	0.01726 (17)	0.0314 (5)
H28A	0.1498	0.5400	−0.0235	0.038*
C29	0.2908 (4)	0.70639 (19)	−0.00417 (16)	0.0285 (5)
H29A	0.2684	0.7227	−0.0630	0.034*
C30	0.3905 (4)	0.7793 (2)	0.07102 (17)	0.0345 (6)
H30A	0.4523	0.8560	0.0749	0.041*
Cl1	−0.49908 (11)	1.03339 (6)	0.22953 (5)	0.04306 (17)
Cl2	−0.28203 (12)	1.06183 (5)	0.09701 (4)	0.04228 (16)
C31	−0.2715 (4)	1.0366 (3)	0.2012 (2)	0.0480 (8)
H31A	−0.2328	0.9674	0.2051	0.058*
H31B	−0.1676	1.0929	0.2421	0.058*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ni	0.02079 (14)	0.01931 (14)	0.01543 (14)	0.00407 (11)	0.00559 (11)	0.00272 (10)
Fe1	0.02327 (17)	0.01951 (16)	0.01895 (16)	0.00541 (13)	0.00659 (13)	0.00179 (12)
Fe2	0.02275 (17)	0.01720 (15)	0.02241 (17)	0.00239 (12)	0.00837 (13)	0.00255 (12)
O1	0.0323 (9)	0.0204 (8)	0.0176 (8)	0.0030 (7)	0.0064 (7)	0.0029 (6)
O2	0.0328 (9)	0.0199 (8)	0.0188 (8)	0.0046 (7)	0.0055 (7)	0.0015 (6)
N1	0.0193 (9)	0.0271 (10)	0.0176 (9)	0.0052 (8)	0.0056 (7)	0.0036 (7)
N2	0.0203 (9)	0.0260 (9)	0.0182 (9)	0.0068 (8)	0.0063 (7)	0.0053 (7)
C1	0.0193 (11)	0.0208 (11)	0.0259 (12)	0.0027 (9)	0.0105 (9)	0.0042 (9)
C2	0.0264 (12)	0.0218 (11)	0.0248 (12)	0.0015 (9)	0.0059 (9)	−0.0002 (9)
C3	0.0187 (11)	0.0296 (12)	0.0207 (11)	0.0046 (9)	0.0059 (9)	−0.0008 (9)
C4	0.0262 (12)	0.0338 (13)	0.0186 (11)	0.0067 (10)	0.0048 (9)	0.0054 (9)
C5	0.0311 (13)	0.0336 (13)	0.0196 (11)	0.0076 (10)	0.0084 (10)	0.0099 (10)
C6	0.0189 (11)	0.0246 (11)	0.0280 (12)	0.0062 (9)	0.0100 (9)	0.0089 (9)
C7	0.0241 (11)	0.0215 (11)	0.0249 (12)	0.0048 (9)	0.0071 (9)	0.0020 (9)
C8	0.0180 (10)	0.0230 (11)	0.0223 (11)	0.0051 (9)	0.0081 (9)	0.0007 (9)
C9	0.0294 (13)	0.0358 (13)	0.0213 (12)	0.0061 (11)	0.0053 (10)	−0.0038 (10)
C10	0.0350 (14)	0.0266 (12)	0.0341 (14)	0.0082 (11)	0.0094 (11)	0.0123 (10)
C11	0.0222 (11)	0.0228 (11)	0.0280 (12)	0.0032 (9)	0.0094 (9)	0.0063 (9)
C12	0.0239 (12)	0.0261 (12)	0.0262 (12)	−0.0015 (9)	0.0038 (10)	0.0049 (9)
C13	0.0258 (12)	0.0345 (13)	0.0332 (14)	0.0033 (10)	0.0046 (10)	0.0124 (11)
C14	0.0358 (14)	0.0305 (13)	0.0442 (15)	0.0165 (11)	0.0190 (12)	0.0151 (11)
C15	0.0367 (14)	0.0251 (12)	0.0332 (13)	0.0110 (10)	0.0192 (11)	0.0073 (10)
C16	0.0286 (14)	0.064 (2)	0.0328 (15)	−0.0107 (13)	0.0043 (12)	0.0015 (14)
C17	0.0288 (14)	0.0580 (18)	0.0473 (17)	0.0143 (13)	0.0141 (12)	0.0258 (14)
C18	0.0351 (14)	0.0321 (13)	0.0442 (16)	0.0132 (11)	0.0228 (12)	0.0096 (11)
C19	0.0292 (13)	0.0319 (13)	0.0339 (14)	0.0050 (10)	0.0153 (11)	0.0109 (11)
C20	0.0351 (14)	0.0284 (13)	0.0472 (17)	−0.0061 (11)	0.0190 (13)	0.0005 (11)
C21	0.0229 (11)	0.0225 (11)	0.0240 (11)	0.0076 (9)	0.0066 (9)	0.0005 (9)
C22	0.0228 (12)	0.0271 (12)	0.0282 (12)	0.0033 (9)	0.0083 (10)	−0.0019 (10)
C23	0.0263 (12)	0.0347 (13)	0.0260 (12)	0.0078 (10)	0.0023 (10)	−0.0061 (10)
C24	0.0352 (14)	0.0367 (14)	0.0241 (12)	0.0178 (11)	0.0031 (10)	0.0024 (10)
C25	0.0358 (13)	0.0265 (12)	0.0231 (12)	0.0149 (10)	0.0060 (10)	0.0017 (9)
C26	0.0265 (13)	0.0651 (19)	0.0287 (14)	0.0163 (13)	0.0019 (11)	−0.0005 (13)
C27	0.0432 (16)	0.0490 (16)	0.0456 (16)	0.0291 (14)	0.0244 (13)	0.0283 (13)
C28	0.0347 (14)	0.0232 (12)	0.0392 (14)	0.0081 (10)	0.0170 (11)	0.0009 (10)
C29	0.0317 (13)	0.0302 (12)	0.0282 (13)	0.0083 (10)	0.0155 (10)	0.0061 (10)
C30	0.0267 (13)	0.0335 (13)	0.0408 (15)	0.0008 (11)	0.0126 (11)	−0.0004 (11)
Cl1	0.0424 (4)	0.0487 (4)	0.0397 (4)	0.0090 (3)	0.0107 (3)	0.0130 (3)
Cl2	0.0542 (4)	0.0370 (3)	0.0376 (4)	0.0091 (3)	0.0128 (3)	0.0116 (3)
C31	0.0332 (15)	0.070 (2)	0.0434 (17)	0.0133 (15)	0.0045 (13)	0.0244 (16)

Geometric parameters (Å, º)

Ni—O2	1.8496 (15)	C9—H9C	0.9800
Ni—N1	1.8515 (18)	C10—H10A	0.9800
Ni—N2	1.8529 (18)	C10—H10B	0.9800
Ni—O1	1.8575 (15)	C10—H10C	0.9800
Fe1—C26	2.037 (3)	C11—C12	1.429 (3)
Fe1—C22	2.040 (2)	C11—C15	1.432 (3)
Fe1—C27	2.044 (2)	C12—C13	1.417 (3)
Fe1—C30	2.044 (3)	C12—H12A	1.0000
Fe1—C25	2.047 (2)	C13—C14	1.415 (4)
Fe1—C21	2.048 (2)	C13—H13A	1.0000
Fe1—C28	2.050 (2)	C14—C15	1.422 (4)
Fe1—C24	2.052 (2)	C14—H14A	1.0000
Fe1—C29	2.050 (2)	C15—H15A	1.0000
Fe1—C23	2.052 (2)	C16—C17	1.407 (4)
Fe2—C16	2.032 (3)	C16—C20	1.421 (4)
Fe2—C15	2.038 (2)	C16—H16A	1.0000
Fe2—C17	2.040 (3)	C17—C18	1.403 (4)
Fe2—C11	2.044 (2)	C17—H17A	1.0000
Fe2—C12	2.043 (2)	C18—C19	1.413 (3)
Fe2—C20	2.042 (3)	C18—H18A	1.0000
Fe2—C14	2.045 (2)	C19—C20	1.409 (4)
Fe2—C18	2.046 (2)	C19—H19A	1.0000
Fe2—C19	2.047 (2)	C20—H20A	1.0000
Fe2—C13	2.050 (3)	C21—C25	1.430 (3)
O1—C1	1.293 (3)	C21—C22	1.433 (3)
O2—C8	1.295 (3)	C22—C23	1.416 (3)
N1—C3	1.318 (3)	C22—H22A	1.0000
N1—C4	1.465 (3)	C23—C24	1.419 (4)
N2—C6	1.323 (3)	C23—H23A	1.0000
N2—C5	1.475 (3)	C24—C25	1.416 (3)
C1—C2	1.375 (3)	C24—H24A	1.0000
C1—C11	1.478 (3)	C25—H25A	1.0000
C2—C3	1.410 (3)	C26—C30	1.410 (4)
C2—H2A	0.9500	C26—C27	1.421 (4)
C3—C9	1.509 (3)	C26—H26A	1.0000
C4—C5	1.504 (3)	C27—C28	1.419 (4)
C4—H4A	0.9900	C27—H27A	1.0000
C4—H4B	0.9900	C28—C29	1.410 (3)
C5—H5A	0.9900	C28—H28A	1.0000
C5—H5B	0.9900	C29—C30	1.403 (4)
C6—C7	1.408 (3)	C29—H29A	1.0000
C6—C10	1.515 (3)	C30—H30A	1.0000
C7—C8	1.379 (3)	Cl1—C31	1.748 (3)
C7—H7A	0.9500	Cl2—C31	1.766 (3)
C8—C21	1.474 (3)	C31—H31A	0.9900
C9—H9A	0.9800	C31—H31B	0.9900
C9—H9B	0.9800
O2—Ni—N1	177.85 (8)	H9A—C9—H9B	109.5
O2—Ni—N2	94.93 (7)	C3—C9—H9C	109.5
N1—Ni—N2	87.16 (8)	H9A—C9—H9C	109.5
O2—Ni—O1	83.18 (7)	H9B—C9—H9C	109.5
N1—Ni—O1	94.75 (8)	C6—C10—H10A	109.5
N2—Ni—O1	177.23 (8)	C6—C10—H10B	109.5
C26—Fe1—C22	127.10 (11)	H10A—C10—H10B	109.5
C26—Fe1—C27	40.74 (12)	C6—C10—H10C	109.5
C22—Fe1—C27	109.20 (10)	H10A—C10—H10C	109.5
C26—Fe1—C30	40.43 (11)	H10B—C10—H10C	109.5
C22—Fe1—C30	163.68 (10)	C12—C11—C15	107.4 (2)
C27—Fe1—C30	68.13 (11)	C12—C11—C1	125.1 (2)
C26—Fe1—C25	119.45 (11)	C15—C11—C1	127.4 (2)
C22—Fe1—C25	68.81 (10)	C12—C11—Fe2	69.49 (13)
C27—Fe1—C25	155.22 (11)	C15—C11—Fe2	69.24 (13)
C30—Fe1—C25	106.47 (11)	C1—C11—Fe2	127.58 (16)
C26—Fe1—C21	107.95 (10)	C13—C12—C11	108.3 (2)
C22—Fe1—C21	41.05 (9)	C13—C12—Fe2	70.00 (14)
C27—Fe1—C21	121.18 (10)	C11—C12—Fe2	69.58 (13)
C30—Fe1—C21	125.35 (10)	C13—C12—H12A	125.8
C25—Fe1—C21	40.89 (9)	C11—C12—H12A	125.8
C26—Fe1—C28	68.21 (11)	Fe2—C12—H12A	125.8
C22—Fe1—C28	121.39 (10)	C12—C13—C14	108.0 (2)
C27—Fe1—C28	40.57 (11)	C12—C13—Fe2	69.47 (14)
C30—Fe1—C28	67.84 (10)	C14—C13—Fe2	69.59 (15)
C25—Fe1—C28	161.86 (10)	C12—C13—H13A	126.0
C21—Fe1—C28	156.33 (10)	C14—C13—H13A	126.0
C26—Fe1—C24	153.55 (12)	Fe2—C13—H13A	126.0
C22—Fe1—C24	68.36 (10)	C15—C14—C13	108.6 (2)
C27—Fe1—C24	163.68 (12)	C15—C14—Fe2	69.38 (14)
C30—Fe1—C24	118.88 (11)	C13—C14—Fe2	69.98 (14)
C25—Fe1—C24	40.43 (10)	C15—C14—H14A	125.7
C21—Fe1—C24	68.34 (9)	C13—C14—H14A	125.7
C28—Fe1—C24	125.77 (10)	Fe2—C14—H14A	125.7
C26—Fe1—C29	67.75 (11)	C14—C15—C11	107.6 (2)
C22—Fe1—C29	155.34 (10)	C14—C15—Fe2	69.87 (14)
C27—Fe1—C29	67.85 (10)	C11—C15—Fe2	69.68 (13)
C30—Fe1—C29	40.10 (10)	C14—C15—H15A	126.2
C25—Fe1—C29	124.53 (10)	C11—C15—H15A	126.2
C21—Fe1—C29	161.95 (10)	Fe2—C15—H15A	126.2
C28—Fe1—C29	40.22 (10)	C17—C16—C20	108.2 (3)
C24—Fe1—C29	107.22 (10)	C17—C16—Fe2	70.11 (16)
C26—Fe1—C23	164.70 (12)	C20—C16—Fe2	70.00 (16)
C22—Fe1—C23	40.50 (10)	C17—C16—H16A	125.9
C27—Fe1—C23	127.33 (12)	C20—C16—H16A	125.9
C30—Fe1—C23	153.84 (11)	Fe2—C16—H16A	125.9
C25—Fe1—C23	68.20 (10)	C16—C17—C18	108.0 (2)
C21—Fe1—C23	68.37 (9)	C16—C17—Fe2	69.44 (16)
C28—Fe1—C23	108.82 (10)	C18—C17—Fe2	70.12 (15)
C24—Fe1—C23	40.45 (10)	C16—C17—H17A	126.0
C29—Fe1—C23	120.40 (10)	C18—C17—H17A	126.0
C16—Fe2—C15	108.87 (12)	Fe2—C17—H17A	126.0
C16—Fe2—C17	40.44 (13)	C17—C18—C19	108.3 (2)
C15—Fe2—C17	125.88 (11)	C17—C18—Fe2	69.71 (15)
C16—Fe2—C11	121.40 (11)	C19—C18—Fe2	69.83 (14)
C15—Fe2—C11	41.08 (9)	C17—C18—H18A	125.9
C17—Fe2—C11	107.52 (10)	C19—C18—H18A	125.9
C16—Fe2—C12	155.88 (12)	Fe2—C18—H18A	125.9
C15—Fe2—C12	68.82 (10)	C20—C19—C18	108.1 (2)
C17—Fe2—C12	120.15 (11)	C20—C19—Fe2	69.69 (14)
C11—Fe2—C12	40.93 (9)	C18—C19—Fe2	69.76 (14)
C16—Fe2—C20	40.83 (12)	C20—C19—H19A	126.0
C15—Fe2—C20	121.96 (11)	C18—C19—H19A	126.0
C17—Fe2—C20	68.27 (12)	Fe2—C19—H19A	126.0
C11—Fe2—C20	157.18 (11)	C19—C20—C16	107.5 (2)
C12—Fe2—C20	160.96 (11)	C19—C20—Fe2	70.01 (14)
C16—Fe2—C14	126.73 (13)	C16—C20—Fe2	69.17 (15)
C15—Fe2—C14	40.75 (10)	C19—C20—H20A	126.3
C17—Fe2—C14	163.46 (12)	C16—C20—H20A	126.3
C11—Fe2—C14	68.58 (10)	Fe2—C20—H20A	126.3
C12—Fe2—C14	68.18 (10)	C25—C21—C22	107.5 (2)
C20—Fe2—C14	108.70 (11)	C25—C21—C8	125.4 (2)
C16—Fe2—C18	67.79 (12)	C22—C21—C8	127.1 (2)
C15—Fe2—C18	162.03 (10)	C25—C21—Fe1	69.54 (13)
C17—Fe2—C18	40.18 (11)	C22—C21—Fe1	69.19 (13)
C11—Fe2—C18	124.24 (10)	C8—C21—Fe1	127.71 (16)
C12—Fe2—C18	106.59 (11)	C23—C22—C21	107.9 (2)
C20—Fe2—C18	67.94 (11)	C23—C22—Fe1	70.20 (14)
C14—Fe2—C18	155.32 (11)	C21—C22—Fe1	69.75 (13)
C16—Fe2—C19	68.04 (11)	C23—C22—H22A	126.1
C15—Fe2—C19	156.48 (10)	C21—C22—H22A	126.1
C17—Fe2—C19	67.93 (11)	Fe1—C22—H22A	126.1
C11—Fe2—C19	160.88 (10)	C22—C23—C24	108.3 (2)
C12—Fe2—C19	123.87 (10)	C22—C23—Fe1	69.29 (14)
C20—Fe2—C19	40.30 (10)	C24—C23—Fe1	69.76 (14)
C14—Fe2—C19	121.06 (10)	C22—C23—H23A	125.8
C18—Fe2—C19	40.41 (10)	C24—C23—H23A	125.8
C16—Fe2—C13	162.87 (12)	Fe1—C23—H23A	125.8
C15—Fe2—C13	68.61 (11)	C25—C24—C23	108.3 (2)
C17—Fe2—C13	154.73 (12)	C25—C24—Fe1	69.61 (13)
C11—Fe2—C13	68.62 (10)	C23—C24—Fe1	69.79 (14)
C12—Fe2—C13	40.52 (9)	C25—C24—H24A	125.8
C20—Fe2—C13	124.97 (11)	C23—C24—H24A	125.8
C14—Fe2—C13	40.44 (11)	Fe1—C24—H24A	125.8
C18—Fe2—C13	119.94 (11)	C24—C25—C21	108.0 (2)
C19—Fe2—C13	107.10 (10)	C24—C25—Fe1	69.96 (13)
C1—O1—Ni	126.80 (14)	C21—C25—Fe1	69.58 (13)
C8—O2—Ni	126.96 (14)	C24—C25—H25A	126.0
C3—N1—C4	117.74 (19)	C21—C25—H25A	126.0
C3—N1—Ni	126.75 (16)	Fe1—C25—H25A	126.0
C4—N1—Ni	115.46 (14)	C30—C26—C27	108.0 (2)
C6—N2—C5	118.06 (18)	C30—C26—Fe1	70.06 (15)
C6—N2—Ni	126.51 (15)	C27—C26—Fe1	69.91 (15)
C5—N2—Ni	115.39 (15)	C30—C26—H26A	126.0
O1—C1—C2	124.4 (2)	C27—C26—H26A	126.0
O1—C1—C11	115.0 (2)	Fe1—C26—H26A	126.0
C2—C1—C11	120.5 (2)	C28—C27—C26	107.6 (2)
C1—C2—C3	124.5 (2)	C28—C27—Fe1	69.92 (14)
C1—C2—H2A	117.8	C26—C27—Fe1	69.34 (15)
C3—C2—H2A	117.8	C28—C27—H27A	126.2
N1—C3—C2	122.7 (2)	C26—C27—H27A	126.2
N1—C3—C9	119.8 (2)	Fe1—C27—H27A	126.2
C2—C3—C9	117.5 (2)	C29—C28—C27	107.7 (2)
N1—C4—C5	111.20 (18)	C29—C28—Fe1	69.90 (13)
N1—C4—H4A	109.4	C27—C28—Fe1	69.50 (14)
C5—C4—H4A	109.4	C29—C28—H28A	126.1
N1—C4—H4B	109.4	C27—C28—H28A	126.1
C5—C4—H4B	109.4	Fe1—C28—H28A	126.1
H4A—C4—H4B	108.0	C30—C29—C28	108.6 (2)
N2—C5—C4	110.47 (18)	C30—C29—Fe1	69.71 (14)
N2—C5—H5A	109.6	C28—C29—Fe1	69.88 (14)
C4—C5—H5A	109.6	C30—C29—H29A	125.7
N2—C5—H5B	109.6	C28—C29—H29A	125.7
C4—C5—H5B	109.6	Fe1—C29—H29A	125.7
H5A—C5—H5B	108.1	C29—C30—C26	108.1 (2)
N2—C6—C7	122.9 (2)	C29—C30—Fe1	70.19 (14)
N2—C6—C10	120.0 (2)	C26—C30—Fe1	69.51 (15)
C7—C6—C10	117.1 (2)	C29—C30—H30A	125.9
C8—C7—C6	124.3 (2)	C26—C30—H30A	125.9
C8—C7—H7A	117.9	Fe1—C30—H30A	125.9
C6—C7—H7A	117.9	Cl1—C31—Cl2	112.34 (16)
O2—C8—C7	124.4 (2)	Cl1—C31—H31A	109.1
O2—C8—C21	114.78 (19)	Cl2—C31—H31A	109.1
C7—C8—C21	120.8 (2)	Cl1—C31—H31B	109.1
C3—C9—H9A	109.5	Cl2—C31—H31B	109.1
C3—C9—H9B	109.5	H31A—C31—H31B	107.9
O2—Ni—O1—C1	−177.83 (19)	Fe2—C16—C20—C19	−59.79 (18)
N1—Ni—O1—C1	1.58 (19)	C17—C16—C20—Fe2	59.96 (19)
N2—Ni—O2—C8	−0.13 (19)	C16—Fe2—C20—C19	118.7 (2)
O1—Ni—O2—C8	−178.10 (19)	C15—Fe2—C20—C19	−159.28 (15)
N2—Ni—N1—C3	178.41 (19)	C17—Fe2—C20—C19	81.05 (17)
O1—Ni—N1—C3	−3.60 (19)	C11—Fe2—C20—C19	164.6 (2)
N2—Ni—N1—C4	1.07 (16)	C12—Fe2—C20—C19	−39.1 (4)
O1—Ni—N1—C4	179.07 (15)	C14—Fe2—C20—C19	−116.29 (16)
O2—Ni—N2—C6	−0.13 (19)	C18—Fe2—C20—C19	37.60 (16)
N1—Ni—N2—C6	−179.61 (19)	C13—Fe2—C20—C19	−74.34 (19)
O2—Ni—N2—C5	−177.92 (15)	C15—Fe2—C20—C16	82.0 (2)
N1—Ni—N2—C5	2.60 (16)	C17—Fe2—C20—C16	−37.65 (18)
Ni—O1—C1—C2	1.2 (3)	C11—Fe2—C20—C16	45.9 (3)
Ni—O1—C1—C11	−176.59 (14)	C12—Fe2—C20—C16	−157.8 (3)
O1—C1—C2—C3	−3.1 (4)	C14—Fe2—C20—C16	125.02 (18)
C11—C1—C2—C3	174.7 (2)	C18—Fe2—C20—C16	−81.10 (19)
C4—N1—C3—C2	−179.8 (2)	C19—Fe2—C20—C16	−118.7 (2)
Ni—N1—C3—C2	2.9 (3)	C13—Fe2—C20—C16	166.96 (17)
C4—N1—C3—C9	−1.0 (3)	O2—C8—C21—C25	15.5 (3)
Ni—N1—C3—C9	−178.32 (16)	C7—C8—C21—C25	−166.1 (2)
C1—C2—C3—N1	0.9 (4)	O2—C8—C21—C22	−162.9 (2)
C1—C2—C3—C9	−177.9 (2)	C7—C8—C21—C22	15.5 (3)
C3—N1—C4—C5	178.1 (2)	O2—C8—C21—Fe1	105.9 (2)
Ni—N1—C4—C5	−4.3 (2)	C7—C8—C21—Fe1	−75.7 (3)
C6—N2—C5—C4	176.6 (2)	C26—Fe1—C21—C25	114.55 (16)
Ni—N2—C5—C4	−5.5 (2)	C22—Fe1—C21—C25	−119.0 (2)
N1—C4—C5—N2	6.0 (3)	C27—Fe1—C21—C25	157.26 (16)
C5—N2—C6—C7	178.4 (2)	C30—Fe1—C21—C25	73.25 (18)
Ni—N2—C6—C7	0.7 (3)	C28—Fe1—C21—C25	−168.9 (2)
C5—N2—C6—C10	−2.4 (3)	C24—Fe1—C21—C25	−37.57 (15)
Ni—N2—C6—C10	179.83 (16)	C29—Fe1—C21—C25	41.5 (4)
N2—C6—C7—C8	−1.0 (4)	C23—Fe1—C21—C25	−81.24 (15)
C10—C6—C7—C8	179.8 (2)	C26—Fe1—C21—C22	−126.40 (16)
Ni—O2—C8—C7	−0.2 (3)	C27—Fe1—C21—C22	−83.70 (17)
Ni—O2—C8—C21	178.16 (14)	C30—Fe1—C21—C22	−167.71 (15)
C6—C7—C8—O2	0.7 (4)	C25—Fe1—C21—C22	119.0 (2)
C6—C7—C8—C21	−177.5 (2)	C28—Fe1—C21—C22	−49.9 (3)
O1—C1—C11—C12	−11.6 (3)	C24—Fe1—C21—C22	81.47 (15)
C2—C1—C11—C12	170.5 (2)	C29—Fe1—C21—C22	160.5 (3)
O1—C1—C11—C15	166.9 (2)	C23—Fe1—C21—C22	37.80 (14)
C2—C1—C11—C15	−11.1 (4)	C26—Fe1—C21—C8	−4.9 (2)
O1—C1—C11—Fe2	−101.6 (2)	C22—Fe1—C21—C8	121.5 (3)
C2—C1—C11—Fe2	80.4 (3)	C27—Fe1—C21—C8	37.8 (2)
C16—Fe2—C11—C12	−158.17 (16)	C30—Fe1—C21—C8	−46.2 (2)
C15—Fe2—C11—C12	118.9 (2)	C25—Fe1—C21—C8	−119.5 (3)
C17—Fe2—C11—C12	−116.10 (16)	C28—Fe1—C21—C8	71.6 (3)
C20—Fe2—C11—C12	168.4 (3)	C24—Fe1—C21—C8	−157.1 (2)
C14—Fe2—C11—C12	80.96 (15)	C29—Fe1—C21—C8	−78.0 (4)
C18—Fe2—C11—C12	−75.07 (17)	C23—Fe1—C21—C8	159.3 (2)
C19—Fe2—C11—C12	−43.1 (3)	C25—C21—C22—C23	−0.9 (3)
C13—Fe2—C11—C12	37.38 (14)	C8—C21—C22—C23	177.7 (2)
C16—Fe2—C11—C15	82.90 (18)	Fe1—C21—C22—C23	−60.13 (16)
C17—Fe2—C11—C15	124.97 (16)	C25—C21—C22—Fe1	59.20 (16)
C12—Fe2—C11—C15	−118.9 (2)	C8—C21—C22—Fe1	−122.2 (2)
C20—Fe2—C11—C15	49.5 (3)	C26—Fe1—C22—C23	−167.58 (16)
C14—Fe2—C11—C15	−37.97 (15)	C27—Fe1—C22—C23	−125.52 (16)
C18—Fe2—C11—C15	166.00 (16)	C30—Fe1—C22—C23	156.9 (3)
C19—Fe2—C11—C15	−162.1 (3)	C25—Fe1—C22—C23	80.83 (15)
C13—Fe2—C11—C15	−81.55 (16)	C21—Fe1—C22—C23	118.7 (2)
C16—Fe2—C11—C1	−39.0 (2)	C28—Fe1—C22—C23	−82.39 (17)
C15—Fe2—C11—C1	−121.9 (3)	C24—Fe1—C22—C23	37.25 (14)
C17—Fe2—C11—C1	3.1 (2)	C29—Fe1—C22—C23	−47.0 (3)
C12—Fe2—C11—C1	119.2 (3)	C26—Fe1—C22—C21	73.74 (18)
C20—Fe2—C11—C1	−72.4 (3)	C27—Fe1—C22—C21	115.79 (15)
C14—Fe2—C11—C1	−159.9 (2)	C30—Fe1—C22—C21	38.2 (4)
C18—Fe2—C11—C1	44.1 (2)	C25—Fe1—C22—C21	−37.86 (13)
C19—Fe2—C11—C1	76.0 (4)	C28—Fe1—C22—C21	158.92 (14)
C13—Fe2—C11—C1	156.5 (2)	C24—Fe1—C22—C21	−81.44 (15)
C15—C11—C12—C13	−0.4 (3)	C29—Fe1—C22—C21	−165.7 (2)
C1—C11—C12—C13	178.3 (2)	C23—Fe1—C22—C21	−118.7 (2)
Fe2—C11—C12—C13	−59.48 (17)	C21—C22—C23—C24	0.8 (3)
C15—C11—C12—Fe2	59.07 (16)	Fe1—C22—C23—C24	−59.01 (17)
C1—C11—C12—Fe2	−122.2 (2)	C21—C22—C23—Fe1	59.85 (16)
C16—Fe2—C12—C13	170.5 (3)	C26—Fe1—C23—C22	40.6 (4)
C15—Fe2—C12—C13	81.45 (16)	C27—Fe1—C23—C22	75.16 (18)
C17—Fe2—C12—C13	−158.43 (16)	C30—Fe1—C23—C22	−165.5 (2)
C11—Fe2—C12—C13	119.5 (2)	C25—Fe1—C23—C22	−82.47 (15)
C20—Fe2—C12—C13	−46.7 (4)	C21—Fe1—C23—C22	−38.30 (14)
C14—Fe2—C12—C13	37.50 (15)	C28—Fe1—C23—C22	116.63 (15)
C18—Fe2—C12—C13	−116.92 (16)	C24—Fe1—C23—C22	−119.9 (2)
C19—Fe2—C12—C13	−76.11 (18)	C29—Fe1—C23—C22	159.29 (14)
C16—Fe2—C12—C11	51.0 (3)	C26—Fe1—C23—C24	160.4 (4)
C15—Fe2—C12—C11	−38.08 (14)	C22—Fe1—C23—C24	119.9 (2)
C17—Fe2—C12—C11	82.04 (17)	C27—Fe1—C23—C24	−164.98 (15)
C20—Fe2—C12—C11	−166.2 (3)	C30—Fe1—C23—C24	−45.6 (3)
C14—Fe2—C12—C11	−82.03 (15)	C25—Fe1—C23—C24	37.40 (14)
C18—Fe2—C12—C11	123.54 (14)	C21—Fe1—C23—C24	81.56 (15)
C19—Fe2—C12—C11	164.36 (13)	C28—Fe1—C23—C24	−123.51 (15)
C13—Fe2—C12—C11	−119.5 (2)	C29—Fe1—C23—C24	−80.84 (16)
C11—C12—C13—C14	0.1 (3)	C22—C23—C24—C25	−0.4 (3)
Fe2—C12—C13—C14	−59.14 (17)	Fe1—C23—C24—C25	−59.14 (17)
C11—C12—C13—Fe2	59.21 (16)	C22—C23—C24—Fe1	58.72 (17)
C16—Fe2—C13—C12	−166.8 (3)	C26—Fe1—C24—C25	−48.9 (3)
C15—Fe2—C13—C12	−82.01 (16)	C22—Fe1—C24—C25	82.31 (16)
C17—Fe2—C13—C12	48.1 (3)	C27—Fe1—C24—C25	166.8 (3)
C11—Fe2—C13—C12	−37.74 (14)	C30—Fe1—C24—C25	−81.49 (18)
C20—Fe2—C13—C12	163.17 (15)	C21—Fe1—C24—C25	37.98 (15)
C14—Fe2—C13—C12	−119.4 (2)	C28—Fe1—C24—C25	−163.82 (15)
C18—Fe2—C13—C12	80.41 (17)	C29—Fe1—C24—C25	−123.45 (16)
C19—Fe2—C13—C12	122.50 (15)	C23—Fe1—C24—C25	119.6 (2)
C16—Fe2—C13—C14	−47.4 (4)	C26—Fe1—C24—C23	−168.5 (2)
C15—Fe2—C13—C14	37.38 (15)	C22—Fe1—C24—C23	−37.30 (14)
C17—Fe2—C13—C14	167.5 (2)	C27—Fe1—C24—C23	47.2 (4)
C11—Fe2—C13—C14	81.65 (16)	C30—Fe1—C24—C23	158.90 (14)
C12—Fe2—C13—C14	119.4 (2)	C25—Fe1—C24—C23	−119.6 (2)
C20—Fe2—C13—C14	−77.44 (18)	C21—Fe1—C24—C23	−81.63 (15)
C18—Fe2—C13—C14	−160.20 (15)	C28—Fe1—C24—C23	76.57 (18)
C19—Fe2—C13—C14	−118.11 (15)	C29—Fe1—C24—C23	116.94 (15)
C12—C13—C14—C15	0.3 (3)	C23—C24—C25—C21	−0.2 (3)
Fe2—C13—C14—C15	−58.77 (18)	Fe1—C24—C25—C21	−59.42 (16)
C12—C13—C14—Fe2	59.07 (17)	C23—C24—C25—Fe1	59.25 (17)
C16—Fe2—C14—C15	−75.66 (19)	C22—C21—C25—C24	0.7 (3)
C17—Fe2—C14—C15	−41.1 (4)	C8—C21—C25—C24	−178.0 (2)
C11—Fe2—C14—C15	38.26 (15)	Fe1—C21—C25—C24	59.65 (17)
C12—Fe2—C14—C15	82.45 (16)	C22—C21—C25—Fe1	−58.98 (15)
C20—Fe2—C14—C15	−117.59 (16)	C8—C21—C25—Fe1	122.4 (2)
C18—Fe2—C14—C15	164.7 (2)	C26—Fe1—C25—C24	157.32 (17)
C19—Fe2—C14—C15	−160.19 (15)	C22—Fe1—C25—C24	−81.08 (17)
C13—Fe2—C14—C15	120.0 (2)	C27—Fe1—C25—C24	−171.2 (2)
C16—Fe2—C14—C13	164.31 (16)	C30—Fe1—C25—C24	115.44 (17)
C15—Fe2—C14—C13	−120.0 (2)	C21—Fe1—C25—C24	−119.1 (2)
C17—Fe2—C14—C13	−161.1 (4)	C28—Fe1—C25—C24	46.6 (4)
C11—Fe2—C14—C13	−81.76 (15)	C29—Fe1—C25—C24	75.33 (19)
C12—Fe2—C14—C13	−37.58 (14)	C23—Fe1—C25—C24	−37.41 (16)
C20—Fe2—C14—C13	122.39 (16)	C26—Fe1—C25—C21	−83.59 (17)
C18—Fe2—C14—C13	44.7 (3)	C22—Fe1—C25—C21	38.01 (14)
C19—Fe2—C14—C13	79.78 (17)	C27—Fe1—C25—C21	−52.1 (3)
C13—C14—C15—C11	−0.6 (3)	C30—Fe1—C25—C21	−125.47 (15)
Fe2—C14—C15—C11	−59.69 (16)	C28—Fe1—C25—C21	165.7 (3)
C13—C14—C15—Fe2	59.14 (18)	C24—Fe1—C25—C21	119.1 (2)
C12—C11—C15—C14	0.6 (3)	C29—Fe1—C25—C21	−165.58 (14)
C1—C11—C15—C14	−178.1 (2)	C23—Fe1—C25—C21	81.68 (15)
Fe2—C11—C15—C14	59.81 (17)	C22—Fe1—C26—C30	−165.41 (15)
C12—C11—C15—Fe2	−59.22 (16)	C27—Fe1—C26—C30	118.8 (2)
C1—C11—C15—Fe2	122.1 (2)	C25—Fe1—C26—C30	−80.76 (18)
C16—Fe2—C15—C14	124.85 (18)	C21—Fe1—C26—C30	−123.90 (16)
C17—Fe2—C15—C14	166.66 (17)	C28—Fe1—C26—C30	80.96 (17)
C11—Fe2—C15—C14	−118.7 (2)	C24—Fe1—C26—C30	−46.6 (3)
C12—Fe2—C15—C14	−80.73 (17)	C29—Fe1—C26—C30	37.42 (15)
C20—Fe2—C15—C14	81.67 (19)	C23—Fe1—C26—C30	162.6 (3)
C18—Fe2—C15—C14	−159.1 (3)	C22—Fe1—C26—C27	75.75 (19)
C19—Fe2—C15—C14	46.7 (3)	C30—Fe1—C26—C27	−118.8 (2)
C13—Fe2—C15—C14	−37.09 (15)	C25—Fe1—C26—C27	160.39 (15)
C16—Fe2—C15—C11	−116.47 (16)	C21—Fe1—C26—C27	117.26 (16)
C17—Fe2—C15—C11	−74.66 (19)	C28—Fe1—C26—C27	−37.89 (15)
C12—Fe2—C15—C11	37.95 (14)	C24—Fe1—C26—C27	−165.4 (2)
C20—Fe2—C15—C11	−159.66 (15)	C29—Fe1—C26—C27	−81.42 (16)
C14—Fe2—C15—C11	118.7 (2)	C23—Fe1—C26—C27	43.8 (5)
C18—Fe2—C15—C11	−40.4 (4)	C30—C26—C27—C28	−0.2 (3)
C19—Fe2—C15—C11	165.3 (2)	Fe1—C26—C27—C28	59.73 (18)
C13—Fe2—C15—C11	81.58 (15)	C30—C26—C27—Fe1	−59.96 (18)
C15—Fe2—C16—C17	123.62 (17)	C26—Fe1—C27—C28	−118.8 (2)
C11—Fe2—C16—C17	80.06 (19)	C22—Fe1—C27—C28	116.19 (16)
C12—Fe2—C16—C17	43.5 (3)	C30—Fe1—C27—C28	−81.01 (17)
C20—Fe2—C16—C17	−119.0 (2)	C25—Fe1—C27—C28	−163.0 (2)
C14—Fe2—C16—C17	165.57 (16)	C21—Fe1—C27—C28	159.91 (14)
C18—Fe2—C16—C17	−37.51 (16)	C24—Fe1—C27—C28	37.8 (5)
C19—Fe2—C16—C17	−81.28 (17)	C29—Fe1—C27—C28	−37.62 (15)
C13—Fe2—C16—C17	−157.9 (3)	C23—Fe1—C27—C28	74.52 (19)
C15—Fe2—C16—C20	−117.38 (17)	C22—Fe1—C27—C26	−125.06 (16)
C17—Fe2—C16—C20	119.0 (2)	C30—Fe1—C27—C26	37.74 (16)
C11—Fe2—C16—C20	−160.94 (15)	C25—Fe1—C27—C26	−44.2 (3)
C12—Fe2—C16—C20	162.5 (2)	C21—Fe1—C27—C26	−81.33 (18)
C14—Fe2—C16—C20	−75.4 (2)	C28—Fe1—C27—C26	118.8 (2)
C18—Fe2—C16—C20	81.49 (17)	C24—Fe1—C27—C26	156.5 (4)
C19—Fe2—C16—C20	37.72 (16)	C29—Fe1—C27—C26	81.14 (17)
C13—Fe2—C16—C20	−38.9 (5)	C23—Fe1—C27—C26	−166.72 (16)
C20—C16—C17—C18	−0.1 (3)	C26—C27—C28—C29	0.3 (3)
Fe2—C16—C17—C18	59.76 (19)	Fe1—C27—C28—C29	59.68 (17)
C20—C16—C17—Fe2	−59.89 (19)	C26—C27—C28—Fe1	−59.36 (18)
C15—Fe2—C17—C16	−76.5 (2)	C26—Fe1—C28—C29	−80.86 (17)
C11—Fe2—C17—C16	−118.16 (17)	C22—Fe1—C28—C29	158.01 (15)
C12—Fe2—C17—C16	−161.03 (16)	C27—Fe1—C28—C29	−118.9 (2)
C20—Fe2—C17—C16	38.00 (17)	C30—Fe1—C28—C29	−37.10 (16)
C14—Fe2—C17—C16	−44.6 (4)	C25—Fe1—C28—C29	37.9 (4)
C18—Fe2—C17—C16	119.1 (2)	C21—Fe1—C28—C29	−166.0 (2)
C19—Fe2—C17—C16	81.59 (18)	C24—Fe1—C28—C29	73.34 (19)
C13—Fe2—C17—C16	164.9 (2)	C23—Fe1—C28—C29	115.15 (16)
C16—Fe2—C17—C18	−119.1 (2)	C26—Fe1—C28—C27	38.04 (17)
C15—Fe2—C17—C18	164.39 (15)	C22—Fe1—C28—C27	−83.09 (19)
C11—Fe2—C17—C18	122.74 (16)	C30—Fe1—C28—C27	81.80 (18)
C12—Fe2—C17—C18	79.87 (18)	C25—Fe1—C28—C27	156.8 (3)
C20—Fe2—C17—C18	−81.10 (17)	C21—Fe1—C28—C27	−47.1 (3)
C14—Fe2—C17—C18	−163.7 (3)	C24—Fe1—C28—C27	−167.76 (17)
C19—Fe2—C17—C18	−37.51 (16)	C29—Fe1—C28—C27	118.9 (2)
C13—Fe2—C17—C18	45.8 (3)	C23—Fe1—C28—C27	−125.94 (17)
C16—C17—C18—C19	0.0 (3)	C27—C28—C29—C30	−0.3 (3)
Fe2—C17—C18—C19	59.37 (18)	Fe1—C28—C29—C30	59.15 (17)
C16—C17—C18—Fe2	−59.34 (19)	C27—C28—C29—Fe1	−59.43 (17)
C16—Fe2—C18—C17	37.75 (18)	C26—Fe1—C29—C30	−37.73 (17)
C15—Fe2—C18—C17	−45.0 (4)	C22—Fe1—C29—C30	−169.9 (2)
C11—Fe2—C18—C17	−76.0 (2)	C27—Fe1—C29—C30	−81.90 (18)
C12—Fe2—C18—C17	−117.35 (17)	C25—Fe1—C29—C30	73.58 (19)
C20—Fe2—C18—C17	82.00 (19)	C21—Fe1—C29—C30	41.8 (4)
C14—Fe2—C18—C17	168.9 (2)	C28—Fe1—C29—C30	−119.8 (2)
C19—Fe2—C18—C17	119.5 (2)	C24—Fe1—C29—C30	114.64 (17)
C13—Fe2—C18—C17	−159.30 (17)	C23—Fe1—C29—C30	156.75 (16)
C16—Fe2—C18—C19	−81.74 (18)	C26—Fe1—C29—C28	82.11 (18)
C15—Fe2—C18—C19	−164.5 (3)	C22—Fe1—C29—C28	−50.0 (3)
C17—Fe2—C18—C19	−119.5 (2)	C27—Fe1—C29—C28	37.94 (17)
C11—Fe2—C18—C19	164.50 (15)	C30—Fe1—C29—C28	119.8 (2)
C12—Fe2—C18—C19	123.16 (16)	C25—Fe1—C29—C28	−166.59 (15)
C20—Fe2—C18—C19	−37.50 (16)	C21—Fe1—C29—C28	161.7 (3)
C14—Fe2—C18—C19	49.5 (3)	C24—Fe1—C29—C28	−125.53 (16)
C13—Fe2—C18—C19	81.21 (18)	C23—Fe1—C29—C28	−83.41 (18)
C17—C18—C19—C20	0.1 (3)	C28—C29—C30—C26	0.1 (3)
Fe2—C18—C19—C20	59.37 (18)	Fe1—C29—C30—C26	59.39 (18)
C17—C18—C19—Fe2	−59.29 (18)	C28—C29—C30—Fe1	−59.25 (17)
C16—Fe2—C19—C20	−38.20 (18)	C27—C26—C30—C29	0.1 (3)
C15—Fe2—C19—C20	48.8 (3)	Fe1—C26—C30—C29	−59.81 (18)
C17—Fe2—C19—C20	−81.98 (19)	C27—C26—C30—Fe1	59.87 (18)
C11—Fe2—C19—C20	−161.7 (3)	C26—Fe1—C30—C29	119.2 (2)
C12—Fe2—C19—C20	165.65 (16)	C22—Fe1—C30—C29	164.8 (3)
C14—Fe2—C19—C20	82.46 (19)	C27—Fe1—C30—C29	81.14 (17)
C18—Fe2—C19—C20	−119.3 (2)	C25—Fe1—C30—C29	−124.51 (15)
C13—Fe2—C19—C20	124.36 (17)	C21—Fe1—C30—C29	−165.32 (14)
C16—Fe2—C19—C18	81.08 (19)	C28—Fe1—C30—C29	37.22 (15)
C15—Fe2—C19—C18	168.1 (3)	C24—Fe1—C30—C29	−82.53 (17)
C17—Fe2—C19—C18	37.30 (17)	C23—Fe1—C30—C29	−50.5 (3)
C11—Fe2—C19—C18	−42.4 (4)	C22—Fe1—C30—C26	45.7 (4)
C12—Fe2—C19—C18	−75.07 (19)	C27—Fe1—C30—C26	−38.02 (17)
C20—Fe2—C19—C18	119.3 (2)	C25—Fe1—C30—C26	116.33 (17)
C14—Fe2—C19—C18	−158.26 (17)	C21—Fe1—C30—C26	75.51 (19)
C13—Fe2—C19—C18	−116.36 (17)	C28—Fe1—C30—C26	−81.95 (18)
C18—C19—C20—C16	−0.2 (3)	C24—Fe1—C30—C26	158.31 (16)
Fe2—C19—C20—C16	59.26 (18)	C29—Fe1—C30—C26	−119.2 (2)
C18—C19—C20—Fe2	−59.41 (18)	C23—Fe1—C30—C26	−169.7 (2)
C17—C16—C20—C19	0.2 (3)