catena-Poly[[[tris­(pyridine-κN)copper(II)]-μ-3-carboxyl­atophenoxy­acetato-κ²O³:O′] trihydrate]

The 3-carboxy­phenoxy­acetate ligand in the title compound, [Cu(C₉H₆O₅)(C₅H₅N)₃]·3H₂O, links adjacent tripyridine­copper(II) groups into a helical chain, which runs along the c axis of the hexa­gonal unit cell. The covalently bonded O atoms occupy trans sites in the basal plane of the square-pyramidal coordination of the Cu atom. The uncoordinated water mol­ecules connect the chains into a three-dimensional network.

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean [sigma](C-C) = 0.009 Å
• R factor = 0.073
• wR factor = 0.146
• Data-to-parameter ratio = 17.0

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT420_ALERT_2_B D-H Without Acceptor       O3W    -   H3W2   ...          ?

Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR') is < 0.90
            Tmin and Tmax reported:      0.591     0.849
            Tmin(prime) and Tmax expected:      0.714     0.844
            RR(prime) =      0.823
            Please check that your absorption correction is appropriate.
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT061_ALERT_3_C Tmax/Tmin Range Test RR' too Large .............       0.82
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.61 Ratio
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O2
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O3
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C8
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          9
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          6

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           27.50
           From the CIF: _reflns_number_total               5518
           Count of symmetry unique reflns         3052
           Completeness (_total/calc)            180.80%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      2466
           Fraction of Friedel pairs measured     0.808
           Are heavy atom types Z>Si present        yes

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   9 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

catena-Poly[[[tris(pyridine-κN)copper(II)]-µ-3-carboxylatophenoxyacetato- κ²O³:O'] trihydrate]

Crystal data

[Cu(C9H6O5)(C5H5N)3]·3H2O	Dx = 1.407 Mg m^−3
Mr = 549.04	Mo Kα radiation, λ = 0.71073 Å
Hexagonal, P65	Cell parameters from 26385 reflections
Hall symbol: P 65	θ = 3.3–27.5°
a = 14.408 (2) Å	µ = 0.89 mm^−1
c = 21.630 (4) Å	T = 295 K
V = 3888.6 (8) Å^3	Block, blue
Z = 6	0.37 × 0.25 × 0.19 mm
F(000) = 1710

Data collection

Rigaku R-AXIS RAPID IP diffractometer	5518 independent reflections
Radiation source: fine-focus sealed tube	4814 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.036
ω scans	θmax = 27.5°, θmin = 3.3°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −18→18
Tmin = 0.591, Tmax = 0.849	k = −18→18
27636 measured reflections	l = −28→26

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.073	H-atom parameters constrained
wR(F^2) = 0.146	w = 1/[σ^2(Fo^2) + (0.0697P)^2 + 0.7075P] where P = (Fo^2 + 2Fc^2)/3
S = 1.24	(Δ/σ)max = 0.03
5518 reflections	Δρmax = 0.48 e Å^−3
325 parameters	Δρmin = −0.39 e Å^−3
19 restraints	Absolute structure: Flack (1983), 2571 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.05 (2)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.49488 (4)	0.00056 (4)	0.50004 (5)	0.0515 (2)
O1	0.3917 (3)	−0.0023 (3)	0.5596 (2)	0.061 (1)
O2	0.5016 (2)	0.0021 (3)	0.6330 (2)	0.066 (1)
O3	0.3345 (2)	0.0087 (3)	0.8301 (2)	0.074 (1)
O4	0.2685 (3)	−0.0082 (3)	0.9884 (2)	0.068 (1)
O5	0.4064 (2)	−0.0022 (3)	0.9377 (1)	0.057 (1)
O1W	0.6947 (5)	0.0025 (6)	0.6174 (3)	0.140 (2)
O2W	0.8857 (6)	0.0568 (5)	0.6762 (3)	0.153 (2)
O3w	0.9723 (9)	−0.0003 (8)	0.7682 (7)	0.224 (5)
N1	0.4281 (3)	−0.1623 (3)	0.5108 (2)	0.056 (1)
N2	0.3847 (3)	−0.0051 (3)	0.4194 (2)	0.061 (1)
N3	0.5853 (3)	0.1641 (3)	0.5095 (2)	0.053 (1)
C1	0.4879 (4)	−0.2089 (4)	0.5137 (2)	0.068 (1)
C2	0.4450 (5)	−0.3187 (5)	0.5173 (3)	0.080 (2)
C3	0.3375 (6)	−0.3827 (5)	0.5187 (3)	0.088 (2)
C4	0.2742 (5)	−0.3359 (5)	0.5161 (3)	0.086 (2)
C5	0.3231 (4)	−0.2256 (5)	0.5123 (2)	0.072 (1)
C6	0.2907 (5)	−0.0092 (6)	0.4291 (3)	0.088 (2)
C7	0.2264 (6)	−0.0115 (7)	0.3827 (5)	0.114 (3)
C8	0.2566 (8)	−0.0110 (7)	0.3230 (4)	0.119 (3)
C9	0.3535 (6)	−0.0069 (5)	0.3111 (3)	0.092 (2)
C10	0.4121 (5)	−0.0044 (4)	0.3609 (2)	0.070 (1)
C11	0.5377 (4)	0.2232 (4)	0.5104 (2)	0.064 (1)
C12	0.5962 (4)	0.3341 (4)	0.5150 (3)	0.071 (1)
C13	0.7045 (5)	0.3843 (4)	0.5193 (2)	0.069 (1)
C14	0.7541 (4)	0.3228 (5)	0.5190 (2)	0.070 (1)
C15	0.6908 (4)	0.2136 (4)	0.5139 (2)	0.059 (1)
C16	0.4187 (4)	−0.0019 (3)	0.6157 (2)	0.049 (1)
C17	0.3398 (3)	−0.0076 (3)	0.6637 (2)	0.045 (1)
C18	0.2378 (3)	−0.0280 (3)	0.6474 (2)	0.052 (1)
C19	0.1669 (4)	−0.0353 (4)	0.6931 (2)	0.054 (1)
C20	0.1953 (3)	−0.0227 (3)	0.7550 (2)	0.052 (1)
C21	0.2973 (3)	−0.0039 (3)	0.7704 (2)	0.050 (1)
C22	0.3678 (3)	0.0041 (4)	0.7254 (2)	0.050 (1)
C23	0.2649 (4)	−0.0051 (4)	0.8796 (2)	0.059 (1)
C24	0.3179 (4)	−0.0046 (4)	0.9400 (2)	0.053 (1)
H1W1	0.6281	−0.0374	0.6248	0.168*
H1W2	0.7083	−0.0099	0.5809	0.168*
H2W1	0.9357	0.0979	0.6514	0.183*
H2w2	0.8383	0.0030	0.6555	0.183*
H3w1	0.9504	0.0179	0.7357	0.269*
H3w2	0.9992	−0.0406	0.7548	0.269*
H1	0.5621	−0.1654	0.5134	0.081*
H2	0.4897	−0.3481	0.5187	0.096*
H3	0.3067	−0.4567	0.5213	0.106*
H4	0.1999	−0.3779	0.5170	0.104*
H5	0.2800	−0.1945	0.5106	0.087*
H6	0.2686	−0.0106	0.4697	0.106*
H7	0.1623	−0.0133	0.3915	0.136*
H8	0.2131	−0.0133	0.2906	0.142*
H9	0.3770	−0.0059	0.2709	0.110*
H10	0.4768	−0.0020	0.3533	0.083*
H11	0.4634	0.1892	0.5079	0.077*
H12	0.5613	0.3737	0.5152	0.085*
H13	0.7449	0.4585	0.5224	0.083*
H14	0.8282	0.3547	0.5221	0.084*
H15	0.7239	0.1723	0.5136	0.071*
H18	0.2173	−0.0366	0.6061	0.062*
H19	0.0989	−0.0490	0.6819	0.065*
H20	0.1478	−0.0266	0.7853	0.063*
H22	0.4358	0.0177	0.7367	0.059*
H23a	0.1984	−0.0725	0.8749	0.071*
H23b	0.2483	0.0523	0.8794	0.071*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0544 (3)	0.0654 (3)	0.0384 (2)	0.0328 (3)	0.0004 (2)	−0.0032 (2)
O1	0.066 (2)	0.077 (2)	0.044 (2)	0.039 (2)	0.006 (1)	−0.002 (1)
O2	0.055 (2)	0.083 (2)	0.062 (2)	0.036 (2)	0.002 (1)	−0.001 (2)
O3	0.047 (2)	0.129 (3)	0.037 (2)	0.037 (2)	−0.002 (1)	−0.002 (2)
O4	0.074 (2)	0.100 (3)	0.041 (2)	0.050 (2)	0.011 (2)	0.010 (2)
O5	0.055 (2)	0.080 (2)	0.040 (2)	0.036 (2)	0.001 (1)	0.003 (1)
O1w	0.130 (4)	0.255 (7)	0.086 (3)	0.135 (5)	−0.023 (3)	−0.036 (4)
O2w	0.164 (5)	0.116 (4)	0.162 (5)	0.058 (4)	−0.028 (4)	0.020 (4)
O3w	0.232 (7)	0.226 (7)	0.25 (1)	0.144 (6)	−0.026 (6)	0.009 (5)
N1	0.058 (2)	0.067 (2)	0.047 (2)	0.033 (2)	0.001 (2)	−0.005 (2)
N2	0.060 (2)	0.070 (2)	0.053 (2)	0.033 (2)	−0.014 (2)	−0.008 (2)
N3	0.057 (2)	0.067 (2)	0.041 (2)	0.035 (2)	−0.003 (2)	0.002 (2)
C1	0.066 (3)	0.071 (3)	0.065 (3)	0.034 (3)	0.007 (2)	0.005 (2)
C2	0.097 (4)	0.087 (4)	0.072 (4)	0.058 (4)	0.012 (3)	0.008 (3)
C3	0.115 (5)	0.067 (4)	0.078 (4)	0.042 (4)	0.004 (3)	0.001 (3)
C4	0.076 (4)	0.070 (4)	0.094 (5)	0.022 (3)	0.003 (3)	−0.002 (3)
C5	0.067 (3)	0.081 (4)	0.068 (3)	0.037 (3)	−0.001 (2)	−0.008 (3)
C6	0.074 (4)	0.121 (5)	0.084 (4)	0.059 (4)	−0.013 (3)	−0.011 (4)
C7	0.082 (4)	0.141 (7)	0.137 (7)	0.071 (5)	−0.039 (5)	−0.018 (5)
C8	0.147 (7)	0.137 (6)	0.091 (5)	0.085 (6)	−0.064 (5)	−0.032 (5)
C9	0.124 (5)	0.110 (5)	0.066 (4)	0.078 (4)	−0.030 (4)	−0.015 (3)
C10	0.088 (4)	0.064 (3)	0.062 (3)	0.042 (3)	−0.017 (3)	−0.006 (2)
C11	0.059 (3)	0.080 (3)	0.060 (3)	0.039 (3)	−0.005 (2)	0.001 (2)
C12	0.078 (3)	0.075 (3)	0.078 (4)	0.052 (3)	−0.007 (3)	−0.002 (3)
C13	0.073 (3)	0.061 (3)	0.069 (3)	0.032 (3)	−0.002 (2)	−0.003 (2)
C14	0.058 (3)	0.079 (4)	0.072 (3)	0.034 (3)	−0.007 (2)	−0.002 (3)
C15	0.062 (3)	0.062 (3)	0.064 (3)	0.039 (2)	−0.011 (2)	−0.003 (2)
C16	0.052 (3)	0.048 (2)	0.045 (2)	0.024 (2)	0.006 (2)	0.002 (2)
C17	0.046 (2)	0.041 (2)	0.046 (2)	0.019 (2)	0.001 (2)	−0.001 (2)
C18	0.052 (2)	0.056 (2)	0.040 (2)	0.022 (2)	−0.009 (2)	0.000 (2)
C19	0.043 (2)	0.071 (3)	0.049 (2)	0.029 (2)	−0.006 (2)	0.001 (2)
C20	0.044 (2)	0.058 (2)	0.048 (2)	0.021 (2)	0.006 (2)	0.009 (2)
C21	0.048 (2)	0.058 (2)	0.039 (2)	0.023 (2)	−0.002 (2)	0.005 (2)
C22	0.037 (2)	0.063 (3)	0.048 (2)	0.025 (2)	−0.003 (2)	0.003 (2)
C23	0.046 (2)	0.084 (3)	0.045 (2)	0.031 (2)	0.003 (2)	0.003 (2)
C24	0.057 (3)	0.059 (3)	0.041 (2)	0.028 (2)	0.004 (2)	0.003 (2)

Geometric parameters (Å, º)

Cu1—O1	1.952 (3)	C18—C19	1.386 (6)
Cu1—O5^i	1.951 (3)	C19—C20	1.384 (6)
Cu1—N1	2.057 (4)	C20—C21	1.395 (6)
Cu1—N2	2.332 (4)	C21—C22	1.369 (6)
Cu1—N3	2.055 (4)	C23—C24	1.512 (7)
O1—C16	1.274 (5)	O1w—H1w1	0.85
O2—C16	1.224 (5)	O1w—H1w2	0.85
O3—C21	1.375 (5)	O2w—H2w1	0.86
O3—C23	1.411 (6)	O2w—H2w2	0.86
O4—C24	1.252 (5)	O3w—H3w1	0.86
O5—C24	1.259 (5)	O3w—H3w2	0.89
N1—C5	1.320 (7)	C1—H1	0.93
N1—C1	1.331 (6)	C2—H2	0.93
N2—C10	1.324 (7)	C3—H3	0.93
N2—C6	1.343 (7)	C4—H4	0.93
N3—C15	1.321 (6)	C5—H5	0.93
N3—C11	1.334 (6)	C6—H6	0.93
C1—C2	1.384 (8)	C7—H7	0.93
C2—C3	1.350 (10)	C8—H8	0.93
C3—C4	1.379 (9)	C9—H9	0.93
C4—C5	1.382 (8)	C10—H10	0.93
C6—C7	1.356 (10)	C11—H11	0.93
C7—C8	1.362 (13)	C12—H12	0.93
C8—C9	1.392 (12)	C13—H13	0.93
C9—C10	1.359 (8)	C14—H14	0.93
C11—C12	1.388 (8)	C15—H15	0.93
C12—C13	1.356 (8)	C18—H18	0.93
C13—C14	1.389 (8)	C19—H19	0.93
C14—C15	1.372 (7)	C20—H20	0.93
C16—C17	1.511 (6)	C22—H22	0.93
C17—C22	1.380 (6)	C23—H23a	0.97
C17—C18	1.393 (6)	C23—H23b	0.97
O1—Cu1—O5^i	177.5 (2)	C22—C21—C20	120.8 (4)
O1—Cu1—N1	89.1 (2)	O3—C21—C20	123.6 (4)
O1—Cu1—N2	89.7 (1)	C21—C22—C17	121.1 (4)
O1—Cu1—N3	89.9 (1)	C21—C22—H22	119.4
O5^i—Cu1—N1	90.8 (1)	C17—C22—H22	119.4
O5^i—Cu1—N2	87.9 (2)	O3—C23—C24	109.5 (4)
O5^i—Cu1—N3	90.8 (1)	O4—C24—O5	125.5 (4)
N1—Cu1—N2	97.1 (2)	O4—C24—C23	116.5 (4)
N1—Cu1—N3	164.6 (2)	O5—C24—C23	117.9 (4)
N2—Cu1—N3	98.3 (1)	N1—C1—H1	118.4
C16—O1—Cu1	113.7 (3)	C2—C1—H1	118.4
C21—O3—C23	119.4 (3)	C3—C2—H2	120.5
C24—O5—Cu1^ii	134.0 (3)	C1—C2—H2	120.5
H1w1—O1w—H1w2	109.3	C2—C3—H3	120.7
H2w1—O2w—H2w2	108.2	C4—C3—H3	120.7
H3w1—O3w—H3w2	106.2	C5—C4—H4	120.6
C5—N1—C1	117.2 (5)	C3—C4—H4	120.6
C5—N1—Cu1	120.7 (4)	N1—C5—H5	118.5
C1—N1—Cu1	121.9 (3)	C4—C5—H5	118.5
C10—N2—C6	116.2 (5)	N2—C6—H6	118.4
C10—N2—Cu1	121.2 (3)	C7—C6—H6	118.4
C6—N2—Cu1	122.6 (4)	C6—C7—H7	120.3
C15—N3—C11	118.3 (4)	C8—C7—H7	120.3
C15—N3—Cu1	121.7 (3)	C7—C8—H8	120.4
C11—N3—Cu1	120.0 (3)	C9—C8—H8	120.4
N1—C1—C2	123.2 (5)	C10—C9—H9	121.6
C3—C2—C1	119.0 (6)	C8—C9—H9	121.6
C2—C3—C4	118.6 (6)	N2—C10—H10	117.3
C5—C4—C3	118.9 (6)	C9—C10—H10	117.3
N1—C5—C4	123.0 (6)	N3—C11—H11	119.2
N2—C6—C7	123.1 (7)	C12—C11—H11	119.2
C6—C7—C8	119.4 (7)	C13—C12—H12	120.2
C7—C8—C9	119.1 (6)	C11—C12—H12	120.2
C10—C9—C8	116.8 (7)	C12—C13—H13	120.6
N2—C10—C9	125.3 (6)	C14—C13—H13	120.6
N3—C11—C12	121.7 (5)	C15—C14—H14	120.9
C13—C12—C11	119.6 (5)	C13—C14—H14	120.9
C12—C13—C14	118.8 (5)	N3—C15—H15	118.3
C15—C14—C13	118.2 (5)	C14—C15—H15	118.3
N3—C15—C14	123.4 (4)	C19—C18—H18	120.2
O2—C16—O1	125.4 (4)	C17—C18—H18	120.2
O2—C16—C17	118.9 (4)	C20—C19—H19	119.3
O1—C16—C17	115.8 (4)	C18—C19—H19	119.3
C22—C17—C18	118.9 (4)	C19—C20—H20	121.0
C22—C17—C16	119.4 (4)	C21—C20—H20	121.0
C18—C17—C16	121.6 (4)	O3—C23—H23a	109.8
C19—C18—C17	119.7 (4)	C24—C23—H23a	109.8
C20—C19—C18	121.4 (4)	O3—C23—H23b	109.8
C19—C20—C21	118.0 (4)	C24—C23—H23b	109.8
C22—C21—O3	115.6 (4)	H23a—C23—H23b	108.2
N3—Cu1—O1—C16	−82.7 (3)	N2—C6—C7—C8	0.9 (12)
N1—Cu1—O1—C16	82.0 (3)	C6—C7—C8—C9	−0.7 (13)
N2—Cu1—O1—C16	179.0 (3)	C7—C8—C9—C10	0.4 (11)
O5^i—Cu1—N1—C5	−133.8 (4)	C6—N2—C10—C9	0.3 (8)
O1—Cu1—N1—C5	43.8 (4)	Cu1—N2—C10—C9	−179.6 (5)
N3—Cu1—N1—C5	130.1 (5)	C8—C9—C10—N2	−0.3 (10)
N2—Cu1—N1—C5	−45.8 (4)	C15—N3—C11—C12	0.9 (7)
O5^i—Cu1—N1—C1	43.2 (4)	Cu1—N3—C11—C12	−178.2 (4)
O1—Cu1—N1—C1	−139.3 (4)	N3—C11—C12—C13	−0.6 (8)
N3—Cu1—N1—C1	−52.9 (7)	C11—C12—C13—C14	0.0 (8)
N2—Cu1—N1—C1	131.1 (4)	C12—C13—C14—C15	0.4 (8)
O5^i—Cu1—N2—C10	−0.8 (4)	C11—N3—C15—C14	−0.5 (7)
O1—Cu1—N2—C10	179.5 (4)	Cu1—N3—C15—C14	178.6 (4)
N3—Cu1—N2—C10	89.7 (4)	C13—C14—C15—N3	−0.2 (8)
N1—Cu1—N2—C10	−91.4 (4)	Cu1—O1—C16—O2	1.4 (5)
O5^i—Cu1—N2—C6	179.2 (5)	Cu1—O1—C16—C17	−178.1 (2)
O1—Cu1—N2—C6	−0.4 (4)	O2—C16—C17—C22	7.4 (6)
N3—Cu1—N2—C6	−90.3 (4)	O1—C16—C17—C22	−173.0 (4)
N1—Cu1—N2—C6	88.6 (4)	O2—C16—C17—C18	−170.5 (4)
O5^i—Cu1—N3—C15	−45.3 (3)	O1—C16—C17—C18	9.1 (6)
O1—Cu1—N3—C15	137.1 (3)	C22—C17—C18—C19	0.4 (6)
N1—Cu1—N3—C15	50.8 (7)	C16—C17—C18—C19	178.4 (4)
N2—Cu1—N3—C15	−133.2 (3)	C17—C18—C19—C20	0.1 (7)
O5^i—Cu1—N3—C11	133.8 (3)	C18—C19—C20—C21	−1.0 (7)
O1—Cu1—N3—C11	−43.8 (4)	C23—O3—C21—C22	−176.0 (5)
N1—Cu1—N3—C11	−130.1 (5)	C23—O3—C21—C20	4.6 (7)
N2—Cu1—N3—C11	45.8 (4)	C19—C20—C21—C22	1.4 (6)
C5—N1—C1—C2	1.0 (8)	C19—C20—C21—O3	−179.2 (4)
Cu1—N1—C1—C2	−176.0 (4)	O3—C21—C22—C17	179.6 (4)
N1—C1—C2—C3	−0.9 (9)	C20—C21—C22—C17	−0.9 (7)
C1—C2—C3—C4	0.4 (9)	C18—C17—C22—C21	0.0 (6)
C2—C3—C4—C5	0.0 (10)	C16—C17—C22—C21	−178.0 (4)
C1—N1—C5—C4	−0.6 (8)	C21—O3—C23—C24	171.1 (4)
Cu1—N1—C5—C4	176.5 (5)	Cu1^ii—O5—C24—O4	−1.1 (7)
C3—C4—C5—N1	0.1 (9)	Cu1^ii—O5—C24—C23	180.0 (3)
C10—N2—C6—C7	−0.6 (9)	O3—C23—C24—O4	174.9 (4)
Cu1—N2—C6—C7	179.3 (6)	O3—C23—C24—O5	−6.1 (6)

Symmetry codes: (i) −x+1, −y, z−1/2; (ii) −x+1, −y, z+1/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O1w—H1w1···O2	0.85	2.17	2.800 (6)	131
O1w—H1w2···O4^i	0.85	2.03	2.835 (6)	158
O2w—H2w1···O4^iii	0.86	2.25	2.789 (7)	121
O2w—H2w2···O1w	0.86	2.22	2.766 (8)	121
O3w—H3w1···O2w	0.86	1.83	2.69 (1)	170

Symmetry codes: (i) −x+1, −y, z−1/2; (iii) −y+1, x−y, z−1/3.