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The title compound, [Ni(C5H10NS2)(C28H28P2)]ClO4, is planar. The pairs of Ni-S [2.2089 (8) and 2.2075 (8) Å] and Ni-P [2.1945 (7) and 2.1932 (8) Å] bond lengths are respectively equal, and the P-Ni-P angle [95.12 (3)°] is large as a consequence of the flexible butyl chain between the two P atoms. The butyl chain lies on one side of the planar NiS2P2 chromophore and two of the phenyl rings are arranged laterally above the plane.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks omar37a, global

sft

Structure factor file (SHELXL table format)
Supplementary material

CCDC reference: 130358

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