Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ₄-succinato)dicopper(II)], a ribbon-like coordination polymer

In the title com­pound, [Cu₂(C₄H₄O₄)₂(C₁₁H₁₀N₄O)]_n, mono-periodic coordination polymer ribbons are held into the crystal structure by means of N—H...O hydrogen bonding and crystal packing forces.

Key indicators

Structure: I

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.009 Å
• R factor = 0.056
• wR factor = 0.151
• Data-to-parameter ratio = 12.2

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT341_ALERT_3_C Low Bond Precision on  C-C Bonds ...............    0.00886 Ang.
PLAT482_ALERT_4_C Small D-H..A Angle Rep for C2       ..O3       .      99.60 Degree
PLAT482_ALERT_4_C Small D-H..A Angle Rep for C19      ..O4       .      98.40 Degree
PLAT601_ALERT_2_C Unit Cell Contains Solvent Accessible VOIDS of .         35 Ang   3
PLAT973_ALERT_2_C Check Calcd Positive Resid. Density on       Cu2       1.26 eA-3
PLAT973_ALERT_2_C Check Calcd Positive Resid. Density on       Cu1       1.11 eA-3

Alert level G
PLAT004_ALERT_5_G Polymeric Structure Found with Maximum Dimension          1 Info
PLAT007_ALERT_5_G Number of Unrefined Donor-H Atoms ..............          2 Report
PLAT480_ALERT_4_G Long H...A H-Bond Reported H9       ..O5       .       2.74 Ang.
PLAT480_ALERT_4_G Long H...A H-Bond Reported H19      ..O4       .       2.84 Ang.
PLAT794_ALERT_5_G Tentative Bond Valency for Cu1       (II)      .       2.09 Info
PLAT794_ALERT_5_G Tentative Bond Valency for Cu2       (II)      .       2.10 Info
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600          2 Note
PLAT941_ALERT_3_G Average HKL Measurement Multiplicity ...........        4.2 Low
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.          0 Info

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   6 ALERT level C = Check. Ensure it is not caused by an omission or oversight
   9 ALERT level G = General information/check it is not something unexpected

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   4 ALERT type 5 Informative message, check

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Computing details

Data collection: COSMO (Bruker, 2009); cell refinement: SAINT (Bruker, 2013); data reduction: SAINT (Bruker, 2013); program(s) used to solve structure: SHELXT2018 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2018 (Sheldrick, 2015b); molecular graphics: CrystalMakerX (Palmer, 2020); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

Poly[[µ-1,3-bis(pyridin-3-yl)urea]bis(µ₄-succinato)dicopper(II)]

Crystal data

[Cu2(C4H4O4)2(C11H10N4O)]	F(000) = 1160
Mr = 573.45	Dx = 1.857 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
a = 15.587 (2) Å	Cell parameters from 2446 reflections
b = 6.7579 (10) Å	θ = 2.8–25.1°
c = 20.942 (3) Å	µ = 2.14 mm^−1
β = 111.614 (2)°	T = 173 K
V = 2050.9 (5) Å^3	Plate, green
Z = 4	0.24 × 0.12 × 0.05 mm

Data collection

Bruker APEXII CCD diffractometer	3758 independent reflections
Radiation source: sealed tube	2378 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.110
Detector resolution: 8.36 pixels mm^-1	θmax = 25.4°, θmin = 1.4°
ω scans	h = −18→18
Absorption correction: multi-scan (SADABS; Bruker, 2013)	k = −8→8
Tmin = 0.568, Tmax = 0.745	l = −25→25
15941 measured reflections

Refinement

Refinement on F^2	Primary atom site location: dual
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.056	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.151	H-atom parameters constrained
S = 0.99	w = 1/[σ^2(Fo^2) + (0.0685P)^2] where P = (Fo^2 + 2Fc^2)/3
3758 reflections	(Δ/σ)max = 0.001
307 parameters	Δρmax = 1.12 e Å^−3
0 restraints	Δρmin = −0.60 e Å^−3

Special details

Experimental. Data was collected using a BRUKER CCD (charge coupled device) based diffractometer equipped with an Oxford low-temperature apparatus operating at 173 K. A suitable crystal was chosen and mounted on a nylon loop using Paratone oil. Data were measured using omega scans of 0.5° per frame for 30 s. The total number of images were based on results from the program COSMO where redundancy was expected to be 4 and completeness to 0.83Å to 100%. Cell parameters were retrieved using APEX II software and refined using SAINT on all observed reflections.Data reduction was performed using the SAINT software which corrects for Lp. Scaling and absorption corrections were applied using SADABS6 multi-scan technique, supplied by George Sheldrick. The structure was solved by the direct method using the SHELXT program and refined by least squares method on F2, SHELXL, incorporated in OLEX2.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.76095 (5)	0.56430 (10)	0.20555 (4)	0.0199 (2)
Cu2	0.77124 (5)	0.49295 (10)	0.33295 (4)	0.0198 (2)
O1	0.6695 (3)	0.6855 (6)	0.3154 (2)	0.0241 (10)
O2	0.6730 (3)	0.7626 (6)	0.2124 (2)	0.0257 (11)
O3	0.6784 (3)	1.2834 (6)	0.2892 (2)	0.0250 (10)
O4	0.6616 (3)	1.3542 (6)	0.1809 (2)	0.0228 (10)
O5	0.8617 (3)	0.7122 (6)	0.3540 (2)	0.0272 (11)
O6	0.8587 (3)	0.7601 (6)	0.2474 (2)	0.0269 (11)
O7	0.8683 (3)	1.3085 (6)	0.3309 (2)	0.0284 (11)
O8	0.8527 (3)	1.3529 (6)	0.2213 (2)	0.0232 (10)
O9	0.5334 (3)	0.3287 (7)	0.4400 (2)	0.0355 (12)
N1	0.7897 (3)	0.4419 (7)	0.4394 (3)	0.0190 (12)
N2	0.6521 (4)	0.3177 (7)	0.5442 (3)	0.0226 (12)
H2	0.665061	0.298117	0.588321	0.027*
N3	0.5065 (4)	0.2208 (7)	0.5341 (3)	0.0225 (12)
H3	0.533315	0.195629	0.578293	0.027*
N4	0.2765 (4)	0.1280 (7)	0.4043 (2)	0.0207 (12)
C1	0.6429 (4)	0.7848 (8)	0.2603 (3)	0.0196 (14)
C2	0.5697 (4)	0.9394 (8)	0.2500 (3)	0.0194 (14)
H2A	0.579259	1.002925	0.294759	0.023*
H2B	0.508546	0.874023	0.234080	0.023*
C3	0.5692 (4)	1.0992 (9)	0.1984 (3)	0.0190 (14)
H3A	0.576689	1.034695	0.158311	0.023*
H3B	0.508195	1.165147	0.181940	0.023*
C4	0.6433 (4)	1.2555 (8)	0.2259 (3)	0.0181 (14)
C5	0.8876 (4)	0.7960 (9)	0.3111 (3)	0.0197 (14)
C6	0.9644 (4)	0.9500 (8)	0.3372 (3)	0.0225 (15)
H6A	0.961873	1.010462	0.379568	0.027*
H6B	1.024551	0.881653	0.349782	0.027*
C7	0.9604 (4)	1.1147 (9)	0.2866 (3)	0.0240 (15)
H7A	1.021401	1.180573	0.301650	0.029*
H7B	0.948973	1.054800	0.241052	0.029*
C8	0.8870 (4)	1.2704 (9)	0.2789 (3)	0.0213 (15)
C9	0.8712 (5)	0.4774 (9)	0.4890 (3)	0.0280 (16)
H9	0.922054	0.513711	0.476843	0.034*
C10	0.8834 (5)	0.4625 (9)	0.5578 (3)	0.0279 (16)
H10	0.942091	0.487920	0.592295	0.034*
C11	0.8108 (4)	0.4111 (9)	0.5757 (3)	0.0250 (15)
H11	0.818417	0.401257	0.622687	0.030*
C12	0.7253 (4)	0.3733 (8)	0.5245 (3)	0.0213 (14)
C13	0.7181 (5)	0.3899 (9)	0.4566 (3)	0.0234 (15)
H13	0.660291	0.363379	0.421060	0.028*
C14	0.5621 (5)	0.2911 (9)	0.5012 (3)	0.0235 (15)
C15	0.2276 (5)	0.0979 (9)	0.4441 (4)	0.0260 (16)
H15	0.163956	0.066116	0.423285	0.031*
C16	0.2677 (5)	0.1121 (8)	0.5150 (3)	0.0253 (15)
H16	0.231447	0.093317	0.542417	0.030*
C17	0.3608 (4)	0.1539 (9)	0.5456 (3)	0.0249 (15)
H17	0.389672	0.160856	0.594176	0.030*
C18	0.4114 (4)	0.1852 (8)	0.5044 (3)	0.0188 (14)
C19	0.3656 (5)	0.1700 (9)	0.4340 (3)	0.0251 (15)
H19	0.399984	0.190872	0.405368	0.030*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0226 (5)	0.0173 (4)	0.0204 (4)	0.0010 (3)	0.0088 (4)	0.0007 (3)
Cu2	0.0227 (5)	0.0170 (4)	0.0207 (4)	0.0002 (3)	0.0092 (4)	0.0002 (3)
O1	0.030 (3)	0.021 (2)	0.025 (3)	0.0066 (19)	0.015 (2)	0.0068 (19)
O2	0.034 (3)	0.021 (2)	0.025 (3)	0.009 (2)	0.015 (2)	0.0029 (19)
O3	0.031 (3)	0.023 (2)	0.022 (3)	−0.007 (2)	0.010 (2)	−0.0049 (19)
O4	0.026 (3)	0.024 (2)	0.018 (2)	−0.0066 (19)	0.008 (2)	0.0026 (19)
O5	0.032 (3)	0.022 (2)	0.025 (3)	−0.012 (2)	0.007 (2)	0.001 (2)
O6	0.032 (3)	0.024 (3)	0.028 (3)	−0.006 (2)	0.015 (2)	−0.006 (2)
O7	0.029 (3)	0.026 (3)	0.032 (3)	0.012 (2)	0.012 (2)	0.003 (2)
O8	0.025 (3)	0.022 (2)	0.021 (2)	0.0053 (19)	0.007 (2)	0.0023 (19)
O9	0.028 (3)	0.049 (3)	0.027 (3)	−0.003 (2)	0.006 (2)	0.013 (2)
N1	0.019 (3)	0.015 (3)	0.019 (3)	0.002 (2)	0.004 (2)	0.002 (2)
N2	0.029 (3)	0.019 (3)	0.024 (3)	0.001 (2)	0.015 (3)	0.004 (2)
N3	0.029 (3)	0.017 (3)	0.021 (3)	0.001 (2)	0.009 (3)	0.005 (2)
N4	0.028 (3)	0.015 (3)	0.019 (3)	−0.002 (2)	0.008 (3)	0.001 (2)
C1	0.024 (4)	0.012 (3)	0.025 (4)	−0.009 (3)	0.012 (3)	−0.006 (3)
C2	0.018 (3)	0.018 (3)	0.024 (3)	−0.002 (3)	0.010 (3)	0.004 (3)
C3	0.018 (3)	0.020 (3)	0.021 (3)	−0.001 (3)	0.009 (3)	−0.002 (3)
C4	0.016 (3)	0.010 (3)	0.026 (4)	0.005 (2)	0.005 (3)	−0.002 (3)
C5	0.013 (3)	0.020 (3)	0.024 (4)	0.005 (3)	0.003 (3)	0.005 (3)
C6	0.017 (4)	0.020 (4)	0.028 (4)	−0.004 (3)	0.005 (3)	−0.003 (3)
C7	0.021 (4)	0.023 (4)	0.028 (4)	0.001 (3)	0.009 (3)	−0.002 (3)
C8	0.021 (4)	0.016 (3)	0.032 (4)	−0.007 (3)	0.014 (3)	−0.004 (3)
C9	0.023 (4)	0.036 (4)	0.028 (4)	−0.001 (3)	0.013 (3)	0.001 (3)
C10	0.024 (4)	0.029 (4)	0.021 (4)	−0.001 (3)	−0.002 (3)	0.008 (3)
C11	0.032 (4)	0.026 (4)	0.017 (3)	0.006 (3)	0.009 (3)	0.000 (3)
C12	0.028 (4)	0.012 (3)	0.027 (4)	−0.001 (3)	0.014 (3)	0.001 (3)
C13	0.031 (4)	0.021 (4)	0.019 (3)	0.002 (3)	0.011 (3)	−0.001 (3)
C14	0.027 (4)	0.017 (3)	0.029 (4)	0.003 (3)	0.012 (3)	0.002 (3)
C15	0.019 (4)	0.019 (4)	0.040 (4)	0.002 (3)	0.011 (3)	−0.003 (3)
C16	0.038 (4)	0.014 (3)	0.033 (4)	−0.001 (3)	0.024 (4)	0.005 (3)
C17	0.026 (4)	0.026 (4)	0.024 (4)	0.001 (3)	0.011 (3)	−0.002 (3)
C18	0.024 (4)	0.015 (3)	0.018 (3)	0.000 (3)	0.008 (3)	0.001 (3)
C19	0.029 (4)	0.021 (4)	0.027 (4)	0.001 (3)	0.013 (3)	−0.001 (3)

Geometric parameters (Å, º)

Cu1—O2	1.960 (4)	C2—H2A	0.9900
Cu1—O4^i	2.023 (4)	C2—H2B	0.9900
Cu1—O6	1.963 (4)	C2—C3	1.526 (8)
Cu1—O8^i	1.961 (4)	C3—H3A	0.9900
Cu1—N4^ii	2.197 (5)	C3—H3B	0.9900
Cu2—O1	1.979 (4)	C3—C4	1.515 (8)
Cu2—O3^i	1.990 (4)	C5—C6	1.528 (8)
Cu2—O5	1.980 (4)	C6—H6A	0.9900
Cu2—O7^i	1.973 (4)	C6—H6B	0.9900
Cu2—N1	2.167 (5)	C6—C7	1.522 (8)
O1—C1	1.265 (7)	C7—H7A	0.9900
O2—C1	1.264 (7)	C7—H7B	0.9900
O3—C4	1.248 (7)	C7—C8	1.519 (8)
O4—C4	1.271 (7)	C9—H9	0.9500
O5—C5	1.249 (7)	C9—C10	1.386 (9)
O6—C5	1.263 (7)	C10—H10	0.9500
O7—C8	1.254 (7)	C10—C11	1.361 (9)
O8—C8	1.256 (7)	C11—H11	0.9500
O9—C14	1.218 (7)	C11—C12	1.392 (8)
N1—C9	1.333 (8)	C12—C13	1.389 (8)
N1—C13	1.340 (7)	C13—H13	0.9500
N2—H2	0.8800	C15—H15	0.9500
N2—C12	1.401 (8)	C15—C16	1.387 (9)
N2—C14	1.371 (8)	C16—H16	0.9500
N3—H3	0.8800	C16—C17	1.383 (9)
N3—C14	1.376 (8)	C17—H17	0.9500
N3—C18	1.400 (8)	C17—C18	1.383 (8)
N4—C15	1.335 (8)	C18—C19	1.385 (8)
N4—C19	1.327 (8)	C19—H19	0.9500
C1—C2	1.504 (8)
O2—Cu1—O4^i	90.48 (18)	O3—C4—O4	125.4 (5)
O2—Cu1—O6	87.41 (18)	O3—C4—C3	119.0 (5)
O2—Cu1—O8^i	166.45 (17)	O4—C4—C3	115.5 (5)
O2—Cu1—N4^ii	91.11 (18)	O5—C5—O6	126.1 (6)
O4^i—Cu1—N4^ii	89.25 (17)	O5—C5—C6	117.9 (6)
O6—Cu1—O4^i	169.11 (17)	O6—C5—C6	115.9 (5)
O6—Cu1—N4^ii	101.47 (18)	C5—C6—H6A	108.5
O8^i—Cu1—O4^i	88.52 (17)	C5—C6—H6B	108.5
O8^i—Cu1—O6	91.03 (18)	H6A—C6—H6B	107.5
O8^i—Cu1—N4^ii	102.38 (18)	C7—C6—C5	115.0 (5)
O1—Cu2—O3^i	89.16 (18)	C7—C6—H6A	108.5
O1—Cu2—O5	90.34 (18)	C7—C6—H6B	108.5
O1—Cu2—N1	95.10 (17)	C6—C7—H7A	108.6
O3^i—Cu2—N1	99.11 (18)	C6—C7—H7B	108.6
O5—Cu2—O3^i	166.52 (17)	H7A—C7—H7B	107.6
O5—Cu2—N1	94.36 (18)	C8—C7—C6	114.6 (5)
O7^i—Cu2—O1	168.62 (18)	C8—C7—H7A	108.6
O7^i—Cu2—O3^i	88.50 (18)	C8—C7—H7B	108.6
O7^i—Cu2—O5	89.35 (19)	O7—C8—O8	126.2 (6)
O7^i—Cu2—N1	96.27 (18)	O7—C8—C7	117.2 (6)
C1—O1—Cu2	119.2 (4)	O8—C8—C7	116.6 (5)
C1—O2—Cu1	127.8 (4)	N1—C9—H9	119.2
C4—O3—Cu2^iii	123.8 (4)	N1—C9—C10	121.6 (6)
C4—O4—Cu1^iii	122.6 (4)	C10—C9—H9	119.2
C5—O5—Cu2	124.8 (4)	C9—C10—H10	120.2
C5—O6—Cu1	121.1 (4)	C11—C10—C9	119.7 (6)
C8—O7—Cu2^iii	125.0 (4)	C11—C10—H10	120.2
C8—O8—Cu1^iii	120.7 (4)	C10—C11—H11	120.3
C9—N1—Cu2	120.0 (4)	C10—C11—C12	119.5 (6)
C9—N1—C13	119.1 (5)	C12—C11—H11	120.3
C13—N1—Cu2	120.7 (4)	C11—C12—N2	118.4 (6)
C12—N2—H2	116.9	C13—C12—N2	123.7 (6)
C14—N2—H2	116.9	C13—C12—C11	117.9 (6)
C14—N2—C12	126.1 (5)	N1—C13—C12	122.3 (6)
C14—N3—H3	116.7	N1—C13—H13	118.8
C14—N3—C18	126.5 (5)	C12—C13—H13	118.8
C18—N3—H3	116.7	O9—C14—N2	123.6 (6)
C15—N4—Cu1^iv	129.1 (4)	O9—C14—N3	122.9 (6)
C19—N4—Cu1^iv	111.2 (4)	N2—C14—N3	113.4 (6)
C19—N4—C15	118.6 (6)	N4—C15—H15	119.2
O1—C1—C2	118.4 (5)	N4—C15—C16	121.5 (6)
O2—C1—O1	124.7 (6)	C16—C15—H15	119.2
O2—C1—C2	116.9 (5)	C15—C16—H16	120.3
C1—C2—H2A	108.9	C17—C16—C15	119.4 (6)
C1—C2—H2B	108.9	C17—C16—H16	120.3
C1—C2—C3	113.5 (5)	C16—C17—H17	120.5
H2A—C2—H2B	107.7	C18—C17—C16	119.0 (6)
C3—C2—H2A	108.9	C18—C17—H17	120.5
C3—C2—H2B	108.9	C17—C18—N3	120.1 (6)
C2—C3—H3A	108.6	C17—C18—C19	117.7 (6)
C2—C3—H3B	108.6	C19—C18—N3	122.1 (6)
H3A—C3—H3B	107.5	N4—C19—C18	123.7 (6)
C4—C3—C2	114.8 (5)	N4—C19—H19	118.2
C4—C3—H3A	108.6	C18—C19—H19	118.2
C4—C3—H3B	108.6
Cu1—O2—C1—O1	4.2 (9)	N4—C15—C16—C17	−1.5 (9)
Cu1—O2—C1—C2	−175.2 (4)	C1—C2—C3—C4	−78.3 (7)
Cu1^iii—O4—C4—O3	5.2 (8)	C2—C3—C4—O3	−22.2 (8)
Cu1^iii—O4—C4—C3	−177.9 (4)	C2—C3—C4—O4	160.7 (5)
Cu1—O6—C5—O5	2.4 (9)	C5—C6—C7—C8	75.8 (7)
Cu1—O6—C5—C6	179.4 (4)	C6—C7—C8—O7	32.4 (8)
Cu1^iii—O8—C8—O7	0.4 (9)	C6—C7—C8—O8	−149.6 (5)
Cu1^iii—O8—C8—C7	−177.5 (4)	C9—N1—C13—C12	0.7 (9)
Cu1^iv—N4—C15—C16	167.8 (4)	C9—C10—C11—C12	0.3 (9)
Cu1^iv—N4—C19—C18	−169.4 (5)	C10—C11—C12—N2	179.0 (6)
Cu2—O1—C1—O2	4.5 (8)	C10—C11—C12—C13	0.0 (9)
Cu2—O1—C1—C2	−176.2 (4)	C11—C12—C13—N1	−0.5 (9)
Cu2^iii—O3—C4—O4	0.4 (8)	C12—N2—C14—O9	−6.2 (9)
Cu2^iii—O3—C4—C3	−176.4 (4)	C12—N2—C14—N3	175.0 (5)
Cu2—O5—C5—O6	2.4 (9)	C13—N1—C9—C10	−0.3 (9)
Cu2—O5—C5—C6	−174.6 (4)	C14—N2—C12—C11	174.2 (5)
Cu2^iii—O7—C8—O8	5.8 (9)	C14—N2—C12—C13	−6.8 (9)
Cu2^iii—O7—C8—C7	−176.4 (4)	C14—N3—C18—C17	−166.6 (6)
Cu2—N1—C9—C10	174.5 (5)	C14—N3—C18—C19	16.7 (9)
Cu2—N1—C13—C12	−174.1 (4)	C15—N4—C19—C18	−0.2 (9)
O1—C1—C2—C3	157.7 (5)	C15—C16—C17—C18	1.6 (9)
O2—C1—C2—C3	−22.9 (8)	C16—C17—C18—N3	−177.7 (5)
O5—C5—C6—C7	−150.1 (6)	C16—C17—C18—C19	−0.9 (9)
O6—C5—C6—C7	32.6 (8)	C17—C18—C19—N4	0.3 (9)
N1—C9—C10—C11	−0.2 (10)	C18—N3—C14—O9	−1.0 (10)
N2—C12—C13—N1	−179.5 (5)	C18—N3—C14—N2	177.8 (5)
N3—C18—C19—N4	177.0 (5)	C19—N4—C15—C16	0.8 (9)

Symmetry codes: (i) x, y−1, z; (ii) −x+1, y+1/2, −z+1/2; (iii) x, y+1, z; (iv) −x+1, y−1/2, −z+1/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2···O4^v	0.88	2.21	3.042 (6)	157
N3—H3···O4^v	0.88	2.36	3.174 (6)	154
C2—H2A···O3	0.99	2.48	2.815 (7)	100
C3—H3A···O2	0.99	2.38	2.744 (7)	101
C6—H6A···O7	0.99	2.47	2.825 (7)	100
C7—H7B···O6	0.99	2.47	2.824 (8)	101
C9—H9···O5	0.95	2.74	3.196 (8)	110
C13—H13···O9	0.95	2.17	2.800 (8)	123
C19—H19···O2^iv	0.95	2.35	2.965 (8)	122
C19—H19···O4^vi	0.95	2.84	3.126 (7)	98
C19—H19···O9	0.95	2.15	2.786 (8)	124

Symmetry codes: (iv) −x+1, y−1/2, −z+1/2; (v) x, −y+3/2, z+1/2; (vi) −x+1, y−3/2, −z+1/2.