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organic compounds
In the centrosymmetric formula unit of the title complex, C12H24O6.2C2H6OS.2C12H9F2NO4S2, each dimethyl sulfoxide molecule is bonded to 18-crown-6 via a set of C—H
O interactions involving two H atoms of one methyl group. The sulfoxide O atoms accept a nearly linear N—HO hydrogen bond from the disulfonylamine NH functions [NO 2.651 (2) Å]. The macrocycle has approximately D3d symmetry, and the disulfonylamine molecules feature a folded pseudo-Cs symmetric conformation.
O interactions involving two H atoms of one methyl group. The sulfoxide O atoms accept a nearly linear N—HO hydrogen bond from the disulfonylamine NH functions [NO 2.651 (2) Å]. The macrocycle has approximately D3d symmetry, and the disulfonylamine molecules feature a folded pseudo-Cs symmetric conformation.Supporting information
 | Crystallographic Information File (CIF) |
 | Structure factor file (CIF format) |
CCDC reference: 130546
