P(C₆H₄CH₂NMe₂-2)₃-stabilized mononuclear penta­fluoro­propionatosilver(I)

The title complex, (penta­fluoro­propionato){tris­[2-(di­methyl­amino­methyl)­phenyl]­phosphine}silver(I), [P(C₆H₄CH₂NMe₂-2)₃]Ag[OC(O)CF₂CF₃] or [Ag(C₃F₅O₂)(C₂₇H₃₆N₃P)], possesses a tetracoordinated silver(I) ion, with silver in a distorted tetrahedral environment. In the solid state, two independent mol­ecules are found in the asymmetric unit. The P(C₆H₄CH₂NMe₂-2)₃ group acts as a tripodal ligand.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• R factor = 0.033
• wR factor = 0.080
• Data-to-parameter ratio = 20.3

checkCIF/PLATON results

No syntax errors found



Alert level A
GEOM005_ALERT_1_A  _geom_angle_atom_site_label_1 is missing
            Label identifying the atom site 1.
PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............       0.00 Deg.
PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low .......       0.00
PLAT037_ALERT_1_A _diffrn_reflns_theta_full .......... Not Given .          ?
PLAT038_ALERT_1_A _diffrn_measured_fraction_theta_max  Not Given .          ?
PLAT039_ALERT_1_A _diffrn_measured_fraction_theta_full Not Given .          ?
PLAT761_ALERT_1_A CIF Contains no X-H Bonds ......................          ?
PLAT762_ALERT_1_A CIF Contains no X-Y-H or H-Y-H Angles ..........          ?

Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.79 Ratio
PLAT222_ALERT_3_B Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       4.87 Ratio

Alert level C
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.69
PLAT164_ALERT_4_C Nr. of Refined C-H H-Atoms in Heavy-At Struct...         72
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.77 Ratio
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C29
PLAT301_ALERT_3_C Main Residue  Disorder .........................       2.00 Perc.

   8 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   6 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2001); software used to prepare material for publication: SHELXL97.

(Pentafluoropropionato){tris[2-(dimethylaminomethyl)phenyl]phosphine}silver(I)

Crystal data

[Ag(C3F5O2)(C27H36N3P)]	F(000) = 2880
Mr = 704.46	Dx = 1.498 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 8602 reflections
a = 16.8535 (7) Å	θ = 2.2–31.2°
b = 14.8719 (6) Å	µ = 0.76 mm^−1
c = 26.0014 (11) Å	T = 173 K
β = 106.567 (1)°	Irregular, colorless
V = 6246.5 (4) Å^3	0.50 × 0.28 × 0.25 mm
Z = 8

Data collection

Bruker SMART CCD area-detector diffractometer	21437 independent reflections
Radiation source: fine-focus sealed tube	17914 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.036
ω scans	θmax = 32.0°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 2001)	h = −25→24
Tmin = 0.775, Tmax = 0.827	k = 0→22
105617 measured reflections	l = 0→38

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.033	Hydrogen site location: difference Fourier map
wR(F^2) = 0.080	All H-atom parameters refined
S = 1.09	w = 1/[σ^2(Fo^2) + (0.0303P)^2 + 6.2345P] where P = (Fo^2 + 2Fc^2)/3
21437 reflections	(Δ/σ)max = 0.006
1054 parameters	Δρmax = 1.21 e Å^−3
0 restraints	Δρmin = −0.45 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.414830 (8)	0.320664 (9)	0.636157 (5)	0.01734 (3)
Ag2	0.129597 (8)	0.729055 (9)	0.633881 (5)	0.01615 (3)
P1	0.38391 (3)	0.29310 (3)	0.540969 (16)	0.01345 (7)
P2	0.10642 (3)	0.79331 (3)	0.712572 (16)	0.01192 (7)
F1	0.44839 (12)	0.43849 (11)	0.83499 (6)	0.0515 (4)
F2	0.32098 (9)	0.41318 (11)	0.78878 (5)	0.0414 (4)
F3	0.36863 (10)	0.31724 (12)	0.87683 (6)	0.0442 (4)
F4	0.47132 (11)	0.26081 (15)	0.85454 (8)	0.0470 (6)	0.919 (5)
F5	0.34786 (15)	0.23319 (11)	0.80644 (8)	0.0469 (6)	0.919 (5)
F4A	0.4915 (11)	0.3168 (15)	0.8673 (7)	0.034 (5)*	0.081 (5)
F5A	0.3945 (14)	0.2297 (12)	0.8246 (8)	0.032 (5)*	0.081 (5)
F6	0.02333 (9)	0.66277 (10)	0.43834 (5)	0.0363 (3)
F7	0.14996 (10)	0.64176 (10)	0.43615 (5)	0.0381 (3)
F8	0.09324 (9)	0.79701 (9)	0.39336 (5)	0.0315 (3)
F9	0.18595 (11)	0.81644 (12)	0.46846 (6)	0.0503 (4)
F10	0.05760 (12)	0.83926 (10)	0.46229 (6)	0.0499 (4)
O1	0.37072 (9)	0.34240 (12)	0.71032 (5)	0.0296 (3)
O2	0.50182 (10)	0.37105 (15)	0.75743 (6)	0.0412 (4)
O3	0.08189 (10)	0.70947 (11)	0.54502 (5)	0.0278 (3)
O4	0.19142 (10)	0.62571 (12)	0.54170 (6)	0.0338 (3)
N1	0.50177 (11)	0.45034 (11)	0.63193 (6)	0.0216 (3)
N2	0.47774 (9)	0.17242 (11)	0.65556 (6)	0.0178 (3)
N3	0.21221 (11)	0.27262 (17)	0.55946 (7)	0.0362 (5)
N4	0.25909 (10)	0.80999 (13)	0.64796 (6)	0.0237 (3)
N5	0.13701 (10)	0.57626 (10)	0.67111 (6)	0.0190 (3)
N6	−0.01422 (9)	0.91003 (10)	0.62628 (6)	0.0178 (3)
C1	0.48136 (10)	0.31860 (11)	0.52484 (6)	0.0148 (3)
C2	0.52585 (11)	0.39708 (11)	0.54529 (6)	0.0164 (3)
C3	0.60245 (12)	0.41167 (13)	0.53577 (7)	0.0211 (3)
C4	0.63486 (12)	0.35195 (14)	0.50600 (8)	0.0233 (4)
C5	0.59003 (12)	0.27565 (13)	0.48483 (7)	0.0216 (3)
C6	0.51422 (11)	0.25873 (12)	0.49455 (7)	0.0180 (3)
C7	0.49228 (12)	0.46916 (12)	0.57458 (7)	0.0199 (3)
C8	0.58891 (14)	0.44013 (19)	0.66224 (8)	0.0342 (5)
C9	0.4647 (2)	0.52536 (16)	0.65375 (10)	0.0382 (6)
C10	0.37270 (10)	0.17215 (11)	0.52731 (6)	0.0150 (3)
C11	0.42666 (11)	0.10998 (12)	0.56110 (7)	0.0163 (3)
C12	0.41497 (13)	0.01859 (13)	0.54903 (8)	0.0246 (4)
C13	0.35134 (15)	−0.01211 (14)	0.50571 (9)	0.0286 (4)
C14	0.29830 (13)	0.04904 (13)	0.47329 (8)	0.0251 (4)
C15	0.30948 (11)	0.14043 (13)	0.48409 (7)	0.0190 (3)
C16	0.49951 (11)	0.13595 (12)	0.60832 (7)	0.0169 (3)
C17	0.55446 (12)	0.18308 (15)	0.69981 (8)	0.0250 (4)
C18	0.42031 (13)	0.11377 (14)	0.67300 (8)	0.0232 (4)
C19	0.30530 (11)	0.34628 (12)	0.48555 (7)	0.0172 (3)
C20	0.23147 (13)	0.37930 (16)	0.49306 (8)	0.0287 (4)
C21	0.17411 (16)	0.42161 (19)	0.45007 (10)	0.0417 (6)
C22	0.18776 (16)	0.42910 (17)	0.40063 (9)	0.0377 (5)
C23	0.25934 (14)	0.39541 (14)	0.39241 (8)	0.0272 (4)
C24	0.31853 (12)	0.35546 (12)	0.43512 (7)	0.0195 (3)
C25	0.21204 (14)	0.3673 (2)	0.54576 (9)	0.0369 (6)
C26	0.20575 (18)	0.2608 (3)	0.61388 (10)	0.0560 (10)
C27	0.14459 (16)	0.2241 (3)	0.52182 (10)	0.0509 (9)
C28	0.42756 (12)	0.36264 (13)	0.75102 (7)	0.0206 (3)
C29	0.39833 (12)	0.37969 (12)	0.80148 (7)	0.0188 (3)
C30	0.39742 (13)	0.29661 (15)	0.83551 (8)	0.0266 (4)
C31	0.15414 (10)	0.90446 (11)	0.72538 (6)	0.0147 (3)
C32	0.23085 (10)	0.92117 (12)	0.71515 (6)	0.0170 (3)
C33	0.26034 (12)	1.00923 (14)	0.72008 (7)	0.0242 (4)
C34	0.21729 (14)	1.07944 (14)	0.73481 (8)	0.0280 (4)
C35	0.14366 (13)	1.06243 (13)	0.74668 (8)	0.0248 (4)
C36	0.11292 (11)	0.97500 (12)	0.74215 (7)	0.0185 (3)
C37	0.28546 (11)	0.84851 (14)	0.70264 (7)	0.0203 (3)
C38	0.32142 (14)	0.7425 (2)	0.64388 (10)	0.0382 (6)
C39	0.25364 (17)	0.8807 (2)	0.60784 (8)	0.0382 (6)
C40	0.16858 (10)	0.72608 (11)	0.76952 (6)	0.0141 (3)
C41	0.16574 (10)	0.63135 (12)	0.76667 (6)	0.0158 (3)
C42	0.21480 (11)	0.58228 (13)	0.80990 (7)	0.0199 (3)
C43	0.26587 (12)	0.62460 (14)	0.85509 (7)	0.0219 (3)
C44	0.26789 (11)	0.71766 (14)	0.85790 (7)	0.0208 (3)
C45	0.21952 (11)	0.76761 (13)	0.81525 (7)	0.0173 (3)
C46	0.10912 (12)	0.58009 (12)	0.72023 (7)	0.0189 (3)
C47	0.07435 (15)	0.52787 (15)	0.62914 (8)	0.0293 (4)
C48	0.21715 (14)	0.53025 (15)	0.68098 (9)	0.0282 (4)
C49	0.00722 (10)	0.80243 (11)	0.72771 (6)	0.0138 (3)
C50	−0.06694 (10)	0.81669 (11)	0.68665 (7)	0.0159 (3)
C51	−0.14170 (11)	0.81815 (13)	0.69999 (8)	0.0207 (3)
C52	−0.14386 (12)	0.80649 (13)	0.75265 (8)	0.0225 (4)
C53	−0.07112 (12)	0.79274 (13)	0.79285 (8)	0.0226 (3)
C54	0.00399 (11)	0.79058 (12)	0.78041 (7)	0.0183 (3)
C55	−0.06644 (11)	0.83300 (12)	0.62946 (7)	0.0184 (3)
C56	0.00169 (14)	0.91593 (16)	0.57416 (8)	0.0266 (4)
C57	−0.05039 (13)	0.99378 (13)	0.63779 (8)	0.0238 (4)
C58	0.12919 (12)	0.67111 (13)	0.52268 (7)	0.0210 (3)
C59	0.10288 (12)	0.68855 (13)	0.46112 (7)	0.0213 (3)
C60	0.10923 (14)	0.78696 (14)	0.44634 (7)	0.0249 (4)
H3	0.6308 (15)	0.4650 (17)	0.5482 (10)	0.025 (6)*
H4	0.6851 (16)	0.3636 (17)	0.4992 (10)	0.026 (6)*
H5	0.6093 (16)	0.2381 (17)	0.4640 (10)	0.025 (6)*
H6	0.4862 (15)	0.2052 (17)	0.4807 (10)	0.023 (6)*
H7A	0.4345 (14)	0.4785 (15)	0.5578 (9)	0.016 (5)*
H7B	0.5186 (14)	0.5271 (16)	0.5721 (9)	0.020 (6)*
H8A	0.5906 (17)	0.4290 (19)	0.6983 (11)	0.036 (7)*
H8B	0.6141 (16)	0.3903 (19)	0.6475 (11)	0.030 (7)*
H8C	0.621 (2)	0.493 (2)	0.6596 (13)	0.051 (9)*
H9A	0.4704 (17)	0.5118 (19)	0.6916 (11)	0.036 (7)*
H9B	0.404 (2)	0.533 (2)	0.6335 (12)	0.046 (9)*
H9C	0.487 (2)	0.578 (2)	0.6486 (13)	0.052 (9)*
H12	0.4500 (16)	−0.0212 (18)	0.5690 (10)	0.029 (7)*
H13	0.3449 (17)	−0.073 (2)	0.4991 (11)	0.040 (8)*
H14	0.2523 (17)	0.0279 (19)	0.4431 (11)	0.036 (7)*
H15	0.2732 (15)	0.1814 (17)	0.4614 (10)	0.024 (6)*
H16A	0.5338 (14)	0.1797 (15)	0.5987 (9)	0.015 (5)*
H16B	0.5355 (15)	0.0807 (17)	0.6185 (10)	0.024 (6)*
H17A	0.5419 (15)	0.2108 (17)	0.7287 (10)	0.025 (6)*
H17B	0.5907 (17)	0.2215 (18)	0.6885 (11)	0.030 (7)*
H17C	0.5837 (15)	0.1268 (18)	0.7105 (10)	0.025 (6)*
H18A	0.3679 (15)	0.1068 (16)	0.6440 (10)	0.022 (6)*
H18B	0.4417 (16)	0.0562 (19)	0.6815 (10)	0.029 (6)*
H18C	0.4059 (16)	0.1406 (18)	0.7014 (11)	0.029 (6)*
H21	0.125 (2)	0.439 (2)	0.4540 (13)	0.057 (10)*
H22	0.148 (2)	0.455 (2)	0.3719 (13)	0.056 (9)*
H23	0.2691 (17)	0.4018 (19)	0.3580 (11)	0.037 (7)*
H24	0.3689 (15)	0.3351 (16)	0.4294 (9)	0.018 (5)*
H25B	0.160 (2)	0.395 (2)	0.5458 (13)	0.057 (10)*
H25C	0.2572 (17)	0.3976 (19)	0.5757 (11)	0.034 (7)*
H26A	0.2057 (17)	0.1978 (19)	0.6214 (11)	0.028 (7)*
H26B	0.248 (2)	0.291 (2)	0.6387 (13)	0.046 (8)*
H26C	0.154 (2)	0.290 (2)	0.6159 (13)	0.054 (9)*
H27A	0.1476 (18)	0.164 (2)	0.5296 (11)	0.032 (8)*
H27B	0.1501 (18)	0.2300 (19)	0.4853 (12)	0.037 (7)*
H27C	0.089 (2)	0.240 (3)	0.5230 (15)	0.073 (12)*
H33	0.3079 (17)	1.0174 (18)	0.7133 (10)	0.031 (7)*
H34	0.2375 (17)	1.135 (2)	0.7364 (11)	0.036 (7)*
H35	0.1129 (17)	1.1097 (19)	0.7561 (11)	0.034 (7)*
H36	0.0641 (15)	0.9635 (16)	0.7500 (9)	0.021 (6)*
H37A	0.2900 (14)	0.7988 (16)	0.7281 (9)	0.019 (6)*
H37B	0.3392 (16)	0.8733 (17)	0.7081 (10)	0.026 (6)*
H38A	0.3047 (17)	0.7167 (19)	0.6093 (11)	0.035 (7)*
H38B	0.3247 (18)	0.695 (2)	0.6725 (12)	0.040 (8)*
H38C	0.375 (2)	0.770 (2)	0.6489 (13)	0.050 (9)*
H39A	0.2119 (16)	0.9236 (18)	0.6084 (10)	0.026 (6)*
H39C	0.2387 (17)	0.8585 (19)	0.5751 (12)	0.036 (7)*
H39B	0.3090 (18)	0.912 (2)	0.6127 (11)	0.039 (7)*
H42	0.2122 (15)	0.5197 (18)	0.8064 (10)	0.026 (6)*
H43	0.2984 (16)	0.5903 (18)	0.8823 (11)	0.030 (7)*
H44	0.2992 (15)	0.7449 (17)	0.8867 (10)	0.023 (6)*
H45	0.2211 (15)	0.8270 (17)	0.8172 (10)	0.022 (6)*
H46A	0.0546 (15)	0.6080 (17)	0.7093 (10)	0.023 (6)*
H46B	0.1027 (14)	0.5195 (16)	0.7317 (9)	0.021 (6)*
H47A	0.0922 (17)	0.5241 (19)	0.5972 (11)	0.035 (7)*
H47B	0.0194 (17)	0.5619 (19)	0.6200 (11)	0.035 (7)*
H47C	0.0675 (16)	0.4678 (19)	0.6417 (11)	0.032 (7)*
H48A	0.2607 (16)	0.5627 (18)	0.7084 (11)	0.029 (6)*
H48B	0.2150 (17)	0.468 (2)	0.6916 (12)	0.040 (8)*
H48C	0.2324 (16)	0.5325 (18)	0.6493 (11)	0.031 (7)*
H51	−0.1924 (16)	0.8291 (17)	0.6721 (10)	0.029 (7)*
H52	−0.1940 (16)	0.8106 (17)	0.7600 (10)	0.028 (6)*
H53	−0.0715 (15)	0.7823 (16)	0.8277 (10)	0.023 (6)*
H54	0.0525 (15)	0.7799 (16)	0.8083 (9)	0.018 (6)*
H55A	−0.0446 (14)	0.7807 (16)	0.6161 (9)	0.019 (6)*
H55B	−0.1232 (17)	0.8409 (18)	0.6068 (11)	0.032 (7)*
H56A	0.0252 (16)	0.8622 (19)	0.5666 (10)	0.031 (7)*
H56B	−0.0495 (16)	0.9284 (17)	0.5442 (10)	0.026 (6)*
H56C	0.0394 (16)	0.9651 (18)	0.5747 (10)	0.030 (7)*
H57A	−0.0603 (14)	0.9899 (16)	0.6720 (10)	0.021 (6)*
H57B	−0.0123 (16)	1.0452 (18)	0.6384 (10)	0.031 (7)*
H57C	−0.1026 (18)	1.0069 (19)	0.6128 (12)	0.038 (7)*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag1	0.01859 (6)	0.02178 (6)	0.01143 (5)	−0.00109 (5)	0.00392 (4)	−0.00228 (4)
Ag2	0.01753 (6)	0.01899 (6)	0.01283 (5)	−0.00021 (4)	0.00576 (4)	−0.00121 (4)
P1	0.01391 (18)	0.01522 (18)	0.01052 (16)	0.00014 (14)	0.00232 (13)	−0.00153 (13)
P2	0.01216 (17)	0.01246 (17)	0.01140 (16)	0.00009 (14)	0.00380 (13)	0.00045 (13)
F1	0.0778 (12)	0.0442 (9)	0.0360 (7)	−0.0358 (8)	0.0219 (8)	−0.0248 (7)
F2	0.0445 (8)	0.0547 (9)	0.0295 (6)	0.0329 (7)	0.0178 (6)	0.0109 (6)
F3	0.0455 (8)	0.0671 (11)	0.0267 (6)	0.0059 (7)	0.0210 (6)	0.0137 (7)
F4	0.0350 (9)	0.0579 (14)	0.0488 (10)	0.0210 (9)	0.0133 (8)	0.0315 (9)
F5	0.0587 (14)	0.0317 (9)	0.0492 (10)	−0.0255 (8)	0.0136 (10)	−0.0016 (7)
F6	0.0345 (7)	0.0465 (8)	0.0228 (6)	−0.0168 (6)	0.0001 (5)	−0.0046 (5)
F7	0.0563 (9)	0.0369 (7)	0.0245 (6)	0.0199 (7)	0.0170 (6)	−0.0032 (5)
F8	0.0480 (8)	0.0320 (6)	0.0155 (5)	0.0040 (6)	0.0104 (5)	0.0017 (5)
F9	0.0582 (10)	0.0587 (10)	0.0287 (7)	−0.0350 (8)	0.0041 (7)	0.0014 (7)
F10	0.0929 (13)	0.0289 (7)	0.0430 (8)	0.0257 (8)	0.0437 (9)	0.0089 (6)
O1	0.0264 (7)	0.0486 (9)	0.0140 (6)	−0.0013 (7)	0.0062 (5)	−0.0072 (6)
O2	0.0206 (7)	0.0761 (14)	0.0277 (8)	0.0016 (8)	0.0081 (6)	0.0048 (8)
O3	0.0319 (8)	0.0356 (8)	0.0149 (6)	0.0070 (6)	0.0051 (5)	−0.0013 (5)
O4	0.0321 (8)	0.0445 (9)	0.0247 (7)	0.0128 (7)	0.0079 (6)	0.0071 (6)
N1	0.0294 (8)	0.0202 (7)	0.0131 (6)	−0.0050 (6)	0.0030 (6)	−0.0016 (5)
N2	0.0172 (7)	0.0215 (7)	0.0141 (6)	−0.0030 (5)	0.0036 (5)	0.0019 (5)
N3	0.0172 (8)	0.0752 (15)	0.0178 (7)	−0.0084 (9)	0.0075 (6)	−0.0122 (8)
N4	0.0179 (7)	0.0372 (9)	0.0176 (7)	−0.0072 (6)	0.0079 (6)	−0.0051 (6)
N5	0.0242 (7)	0.0166 (7)	0.0161 (6)	0.0018 (6)	0.0056 (5)	−0.0013 (5)
N6	0.0184 (7)	0.0189 (7)	0.0155 (6)	0.0023 (5)	0.0038 (5)	0.0016 (5)
C1	0.0159 (7)	0.0157 (7)	0.0121 (6)	−0.0008 (6)	0.0028 (5)	0.0018 (5)
C2	0.0199 (8)	0.0151 (7)	0.0122 (6)	−0.0005 (6)	0.0012 (6)	0.0030 (5)
C3	0.0206 (8)	0.0212 (8)	0.0186 (7)	−0.0051 (7)	0.0006 (6)	0.0058 (6)
C4	0.0174 (8)	0.0290 (9)	0.0237 (8)	−0.0001 (7)	0.0061 (7)	0.0100 (7)
C5	0.0208 (8)	0.0243 (9)	0.0221 (8)	0.0041 (7)	0.0101 (7)	0.0056 (7)
C6	0.0201 (8)	0.0177 (8)	0.0169 (7)	−0.0002 (6)	0.0062 (6)	0.0008 (6)
C7	0.0282 (9)	0.0149 (7)	0.0145 (7)	−0.0027 (7)	0.0027 (6)	−0.0005 (6)
C8	0.0298 (11)	0.0498 (14)	0.0179 (8)	−0.0189 (10)	−0.0016 (7)	0.0043 (9)
C9	0.0684 (18)	0.0205 (10)	0.0300 (11)	−0.0022 (11)	0.0208 (11)	−0.0079 (8)
C10	0.0157 (7)	0.0171 (7)	0.0130 (6)	−0.0017 (6)	0.0055 (5)	−0.0007 (5)
C11	0.0176 (7)	0.0160 (7)	0.0154 (7)	−0.0012 (6)	0.0047 (6)	0.0011 (6)
C12	0.0314 (10)	0.0164 (8)	0.0230 (8)	−0.0001 (7)	0.0028 (7)	0.0030 (7)
C13	0.0381 (11)	0.0162 (8)	0.0281 (9)	−0.0039 (8)	0.0038 (8)	−0.0024 (7)
C14	0.0274 (10)	0.0208 (9)	0.0236 (8)	−0.0060 (7)	0.0016 (7)	−0.0049 (7)
C15	0.0185 (8)	0.0200 (8)	0.0174 (7)	−0.0015 (6)	0.0035 (6)	−0.0020 (6)
C16	0.0165 (7)	0.0182 (8)	0.0154 (7)	−0.0004 (6)	0.0035 (6)	0.0025 (6)
C17	0.0215 (9)	0.0333 (11)	0.0169 (7)	0.0006 (8)	0.0003 (6)	0.0020 (7)
C18	0.0246 (9)	0.0250 (9)	0.0227 (8)	−0.0040 (7)	0.0113 (7)	0.0041 (7)
C19	0.0179 (8)	0.0159 (7)	0.0145 (7)	0.0024 (6)	−0.0006 (6)	−0.0032 (6)
C20	0.0250 (9)	0.0372 (11)	0.0198 (8)	0.0124 (8)	−0.0003 (7)	−0.0097 (8)
C21	0.0335 (12)	0.0517 (15)	0.0320 (11)	0.0255 (11)	−0.0032 (9)	−0.0075 (10)
C22	0.0392 (13)	0.0344 (12)	0.0279 (10)	0.0144 (10)	−0.0089 (9)	0.0001 (9)
C23	0.0318 (10)	0.0236 (9)	0.0196 (8)	−0.0022 (8)	−0.0033 (7)	0.0038 (7)
C24	0.0227 (8)	0.0168 (8)	0.0161 (7)	−0.0021 (6)	0.0010 (6)	0.0005 (6)
C25	0.0240 (10)	0.0626 (16)	0.0228 (9)	0.0146 (10)	0.0046 (8)	−0.0146 (10)
C26	0.0311 (13)	0.120 (3)	0.0206 (10)	−0.0212 (17)	0.0130 (9)	−0.0121 (14)
C27	0.0255 (11)	0.102 (3)	0.0276 (11)	−0.0198 (14)	0.0107 (9)	−0.0192 (14)
C28	0.0228 (8)	0.0251 (9)	0.0145 (7)	0.0020 (7)	0.0064 (6)	0.0008 (6)
C29	0.0245 (8)	0.0169 (8)	0.0152 (7)	−0.0015 (6)	0.0059 (6)	−0.0031 (6)
C30	0.0257 (9)	0.0308 (10)	0.0245 (9)	0.0029 (8)	0.0089 (7)	0.0073 (8)
C31	0.0158 (7)	0.0148 (7)	0.0128 (6)	−0.0019 (6)	0.0028 (5)	0.0016 (5)
C32	0.0159 (7)	0.0214 (8)	0.0121 (6)	−0.0039 (6)	0.0014 (5)	0.0016 (6)
C33	0.0226 (9)	0.0278 (10)	0.0196 (8)	−0.0109 (7)	0.0016 (7)	0.0046 (7)
C34	0.0345 (11)	0.0181 (9)	0.0255 (9)	−0.0100 (8)	−0.0007 (8)	0.0031 (7)
C35	0.0303 (10)	0.0161 (8)	0.0234 (8)	−0.0011 (7)	0.0002 (7)	−0.0019 (7)
C36	0.0202 (8)	0.0152 (7)	0.0184 (7)	−0.0004 (6)	0.0027 (6)	−0.0004 (6)
C37	0.0142 (7)	0.0313 (9)	0.0158 (7)	−0.0050 (7)	0.0052 (6)	−0.0024 (7)
C38	0.0193 (9)	0.0615 (17)	0.0372 (12)	−0.0030 (10)	0.0135 (9)	−0.0214 (12)
C39	0.0447 (14)	0.0544 (16)	0.0167 (8)	−0.0223 (12)	0.0106 (9)	−0.0009 (9)
C40	0.0139 (7)	0.0160 (7)	0.0133 (6)	0.0016 (6)	0.0052 (5)	0.0015 (5)
C41	0.0167 (7)	0.0170 (7)	0.0158 (7)	0.0021 (6)	0.0077 (6)	0.0021 (6)
C42	0.0213 (8)	0.0194 (8)	0.0213 (8)	0.0048 (6)	0.0098 (6)	0.0060 (6)
C43	0.0193 (8)	0.0281 (9)	0.0184 (7)	0.0049 (7)	0.0056 (6)	0.0098 (7)
C44	0.0182 (8)	0.0290 (9)	0.0137 (7)	−0.0001 (7)	0.0020 (6)	0.0022 (6)
C45	0.0172 (7)	0.0199 (8)	0.0146 (7)	0.0005 (6)	0.0043 (6)	0.0010 (6)
C46	0.0227 (8)	0.0143 (7)	0.0205 (7)	−0.0003 (6)	0.0077 (6)	−0.0004 (6)
C47	0.0407 (12)	0.0211 (9)	0.0229 (9)	−0.0068 (8)	0.0040 (8)	−0.0049 (7)
C48	0.0345 (11)	0.0273 (10)	0.0249 (9)	0.0123 (8)	0.0116 (8)	0.0009 (8)
C49	0.0147 (7)	0.0122 (7)	0.0155 (6)	−0.0004 (5)	0.0059 (5)	−0.0009 (5)
C50	0.0149 (7)	0.0142 (7)	0.0185 (7)	−0.0005 (6)	0.0045 (6)	−0.0020 (6)
C51	0.0145 (7)	0.0195 (8)	0.0282 (8)	0.0004 (6)	0.0060 (6)	−0.0024 (7)
C52	0.0185 (8)	0.0197 (8)	0.0338 (9)	−0.0014 (6)	0.0147 (7)	−0.0024 (7)
C53	0.0259 (9)	0.0218 (8)	0.0248 (8)	−0.0003 (7)	0.0149 (7)	0.0010 (7)
C54	0.0205 (8)	0.0192 (8)	0.0170 (7)	0.0003 (6)	0.0083 (6)	0.0008 (6)
C55	0.0158 (7)	0.0202 (8)	0.0170 (7)	0.0003 (6)	0.0013 (6)	−0.0015 (6)
C56	0.0306 (10)	0.0308 (10)	0.0198 (8)	0.0022 (8)	0.0093 (7)	0.0042 (7)
C57	0.0240 (9)	0.0200 (9)	0.0254 (9)	0.0050 (7)	0.0039 (7)	0.0022 (7)
C58	0.0250 (9)	0.0223 (8)	0.0154 (7)	−0.0016 (7)	0.0050 (6)	−0.0009 (6)
C59	0.0256 (9)	0.0219 (9)	0.0155 (7)	0.0008 (7)	0.0043 (6)	−0.0045 (6)
C60	0.0358 (10)	0.0249 (9)	0.0152 (7)	−0.0005 (8)	0.0093 (7)	−0.0025 (6)

Bond lengths (Å)

Ag1—O1	2.2789 (13)	F2—C29	1.346 (2)
Ag1—P1	2.4145 (4)	F3—C30	1.334 (2)
Ag1—N2	2.4360 (16)	F4—C30	1.315 (3)
Ag1—N1	2.4433 (16)	F5—C30	1.341 (3)
Ag2—O3	2.2383 (13)	F4A—C30	1.594 (19)
Ag2—P2	2.3892 (4)	F5A—C30	1.032 (19)
Ag2—N4	2.4270 (16)	F6—C59	1.357 (2)
Ag2—N5	2.4592 (15)	F7—C59	1.353 (2)
P1—C10	1.8327 (18)	F8—C60	1.335 (2)
P1—C19	1.8353 (17)	F9—C60	1.331 (3)
P1—C1	1.8466 (17)	F10—C60	1.319 (2)
P2—C31	1.8268 (17)	O1—C28	1.245 (2)
P2—C49	1.8285 (16)	O2—C28	1.221 (2)
P2—C40	1.8452 (16)	O3—C58	1.250 (2)
F1—C29	1.348 (2)