Two Heteroleptic Cobalt(III) Cyclopentadienyl/Dithiolene Complexes

Fourmigué, M.; Perrocheau, V.

doi:10.1107/S0108270197005544

Two Heteroleptic Cobalt(III) Cyclopentadienyl/Dithiolene Complexes

Crystal structure determinations of (η⁵-cyclopentadienyl)(4,5-dimercapto-1,3-dithiole-2-thionato)cobalt(III), [Co(C₈H₅S₅)], and (η⁵-pentamethylcyclopentadienyl)(4,5-dimercapto-1,3-dithiole-2-thionato) cobalt(II), [Co(C₁₃H₁₅S₅)], show that Cp^* substitution does not significantly modify the geometric features of these complexes, which are characterized by a perpendicular arrangement of the planar Cp or Cp^* and (CoS₂C₂) moieties.

Read article Similar articles

Subscribe to Acta Crystallographica Section C: Structural Chemistry

The full text of this article is available to subscribers to the journal.

Information on subscribing
Sample issue
Purchase subscription
Reduced-price subscriptions
If you have already subscribed, you may need to register

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.

E-mail address*
Repeat e-mail address* (for error checking)

Format*	PDF (US $40)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number (non-UK EC countries only)
Country*

Terms and conditions of use
Contact us

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Text
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

Two Heteroleptic Cobalt(III) Cyclopentadienyl/Dithiolene Complexes

Supporting information

Subscribe to Acta Crystallographica Section C: Structural Chemistry

Buy online

	Crystallographic Information File (CIF) Contains datablocks paper, I, II
	Structure factor file (CIF format) Contains datablock I
	Structure factor file (CIF format) Contains datablock (II)