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The title compound, [Ni(C20H14N2S2)], was formed from a Schiff base reaction of 2-tert-butylthiobenzaldehyde with 1,2-phenylenediamine, followed by reaction with Ni(BF4)2.6H2O. The square-planar NiN2S2 complex has Ni-N distances of 1.8992 (17) and 1.9014 (15) Å, and Ni-S distances of 2.1519 (6) and 2.1587 (6) Å. Molecules pack in layers with a tilt angle of 46.09 (1)°; the (0 0 1) packing plane is arranged so that the molecules in superimposed layers stack approximately perpendicular to each other.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, s1488a

hkl

Structure factor file (CIF format)
Contains datablock shelxl

CCDC reference: 129270

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