A Tetranuclear Iron Cluster Complex: [{Fe(CO)3}3{μ3-CC[Fe(CO)2(η5-C5H5)]C(CF3)}]

Muir, K.W.; Manojlovic-Muir, L.; Morrice, F.; Guennou, K.; Pétillon, F.; Rumin, R.

doi:10.1107/S0108270196012632

A Tetranuclear Iron Cluster Complex: [{Fe(CO)₃}₃{μ₃-CC[Fe(CO)₂(η⁵-C₅H₅)]C(CF₃)}]

K. W. Muir, L. Manojlovic-Muir, F. Morrice, K. Guennou, F. Pétillon and R. Rumin

Undecacarbonyl[4(η⁵)-cyclopentadienyl]-μ₃-(4,4,4-trifluorobutaneheptayl)-tetrairon(3 Fe—Fe), [{Fe(CO)₃}₃{μ₃-CC[Fe(CO)₂Cp]C(CF₃)}] (Cp is η⁵-C₅H₅) contains a triangular {Fe(CO)₃}₃ core [Fe—Fe distances 2.482 (1), 2.663 (1) and 2.693 (1) Å] linked via an unusual C₃CF₃ bridging unit to an Fe(CO)₂Cp group.

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A Tetranuclear Iron Cluster Complex: [{Fe(CO)₃}₃{μ₃-CC[Fe(CO)₂(η⁵-C₅H₅)]C(CF₃)}]

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	Crystallographic Information File (CIF) Contains datablock k4
	Structure factor file (CIF format) Contains datablock k4