Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270110018238/eg3042sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S0108270110018238/eg3042Isup2.hkl |
CCDC reference: 786798
Data collection: COLLECT (Nonius, 1999); cell refinement: COLLECT (Nonius, 1999); data reduction: EVALCCD (Duisenberg et al., 2003); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).
[CrRh(C16H14N2O2)ClN(C8H12)] | F(000) = 1172 |
Mr = 578.84 | Dx = 1.667 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 34038 reflections |
a = 12.6140 (13) Å | θ = 1.7–34.0° |
b = 15.1085 (14) Å | µ = 1.33 mm−1 |
c = 12.6704 (17) Å | T = 122 K |
β = 107.259 (10)° | Prism, red |
V = 2306.0 (4) Å3 | 0.32 × 0.09 × 0.09 mm |
Z = 4 |
Nonius KappaCCD area-detector diffractometer | 9382 independent reflections |
Radiation source: fine-focus sealed tube | 7611 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.051 |
ω and φ scans | θmax = 34.0°, θmin = 1.7° |
Absorption correction: integration (Gaussian integration; Coppens, 1970) | h = −19→19 |
Tmin = 0.718, Tmax = 0.929 | k = −23→23 |
77914 measured reflections | l = −19→19 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.029 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.067 | H-atom parameters constrained |
S = 1.06 | w = 1/[σ2(Fo2) + (0.0224P)2 + 2.474P] where P = (Fo2 + 2Fc2)/3 |
9382 reflections | (Δ/σ)max = 0.001 |
289 parameters | Δρmax = 0.92 e Å−3 |
0 restraints | Δρmin = −0.98 e Å−3 |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. Least-squares planes (x,y,z in crystal coordinates) and deviations from them (* indicates atom used to define plane) - 6.1810 (0.0056) x + 13.0814 (0.0045) y + 0.6216 (0.0059) z = 1.8390 (0.0032) * -0.0620 (0.0006) O1 * 0.0621 (0.0006) O2 * 0.0628 (0.0006) N2 * -0.0628 (0.0006) N3 0.4827 (0.0007) Cr1 Rms deviation of fitted atoms = 0.0624 |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Rh1 | 0.210064 (10) | 0.544803 (8) | 0.061385 (10) | 0.01420 (3) | |
Cr1 | 0.35702 (2) | 0.341441 (16) | 0.099525 (19) | 0.01091 (5) | |
Cl1 | 0.14529 (4) | 0.51896 (4) | −0.13119 (4) | 0.03189 (11) | |
N1 | 0.29689 (11) | 0.43536 (9) | 0.07862 (11) | 0.0156 (2) | |
N2 | 0.32628 (11) | 0.30229 (9) | −0.05763 (10) | 0.0140 (2) | |
N3 | 0.50408 (11) | 0.37031 (9) | 0.07654 (11) | 0.0150 (2) | |
O1 | 0.25988 (10) | 0.25289 (8) | 0.12085 (9) | 0.0161 (2) | |
O2 | 0.42958 (9) | 0.33620 (8) | 0.25453 (9) | 0.0151 (2) | |
C1 | 0.07706 (15) | 0.63726 (12) | 0.06440 (18) | 0.0269 (4) | |
H1 | 0.0062 | 0.6286 | 0.0037 | 0.032* | |
C2 | 0.06342 (17) | 0.64628 (13) | 0.1791 (2) | 0.0305 (4) | |
H2A | −0.0165 | 0.6437 | 0.1734 | 0.037* | |
H2B | 0.0920 | 0.7047 | 0.2102 | 0.037* | |
C3 | 0.12487 (16) | 0.57354 (13) | 0.25749 (17) | 0.0254 (4) | |
H3A | 0.1460 | 0.5964 | 0.3342 | 0.031* | |
H3B | 0.0739 | 0.5229 | 0.2532 | 0.031* | |
C4 | 0.22799 (14) | 0.54118 (11) | 0.23201 (13) | 0.0173 (3) | |
H4 | 0.2570 | 0.4836 | 0.2681 | 0.021* | |
C5 | 0.31043 (14) | 0.59651 (11) | 0.21307 (14) | 0.0185 (3) | |
H5 | 0.3868 | 0.5707 | 0.2381 | 0.022* | |
C6 | 0.30788 (17) | 0.69704 (13) | 0.22029 (19) | 0.0303 (4) | |
H6A | 0.3851 | 0.7195 | 0.2438 | 0.036* | |
H6B | 0.2728 | 0.7140 | 0.2776 | 0.036* | |
C7 | 0.24431 (17) | 0.74162 (13) | 0.1105 (2) | 0.0335 (5) | |
H7A | 0.2064 | 0.7950 | 0.1268 | 0.040* | |
H7B | 0.2983 | 0.7612 | 0.0724 | 0.040* | |
C8 | 0.15901 (16) | 0.68242 (13) | 0.03333 (19) | 0.0287 (4) | |
H8 | 0.1370 | 0.7011 | −0.0459 | 0.034* | |
C11 | 0.18026 (13) | 0.20873 (10) | 0.04698 (12) | 0.0134 (3) | |
C12 | 0.10077 (14) | 0.16293 (12) | 0.08405 (14) | 0.0190 (3) | |
H12 | 0.1045 | 0.1649 | 0.1600 | 0.023* | |
C13 | 0.01718 (15) | 0.11494 (12) | 0.01064 (15) | 0.0216 (3) | |
H13 | −0.0365 | 0.0853 | 0.0368 | 0.026* | |
C14 | 0.01060 (14) | 0.10941 (12) | −0.10137 (15) | 0.0209 (3) | |
H14 | −0.0470 | 0.0762 | −0.1510 | 0.025* | |
C15 | 0.08845 (14) | 0.15257 (11) | −0.13867 (13) | 0.0173 (3) | |
H15 | 0.0848 | 0.1484 | −0.2145 | 0.021* | |
C16 | 0.17386 (13) | 0.20299 (10) | −0.06624 (12) | 0.0130 (3) | |
C17 | 0.25104 (13) | 0.24775 (10) | −0.11208 (12) | 0.0143 (3) | |
H17 | 0.2462 | 0.2364 | −0.1871 | 0.017* | |
C18 | 0.39613 (15) | 0.34919 (11) | −0.11428 (13) | 0.0198 (3) | |
H18A | 0.3689 | 0.4104 | −0.1328 | 0.024* | |
H18B | 0.3949 | 0.3182 | −0.1834 | 0.024* | |
C19 | 0.51269 (15) | 0.35004 (12) | −0.03480 (14) | 0.0212 (3) | |
H19A | 0.5484 | 0.2917 | −0.0346 | 0.025* | |
H19B | 0.5582 | 0.3955 | −0.0574 | 0.025* | |
C20 | 0.58805 (13) | 0.40544 (10) | 0.14935 (14) | 0.0164 (3) | |
H20 | 0.6509 | 0.4211 | 0.1266 | 0.020* | |
C21 | 0.59273 (13) | 0.42237 (10) | 0.26236 (13) | 0.0153 (3) | |
C22 | 0.68418 (14) | 0.47114 (11) | 0.32913 (15) | 0.0200 (3) | |
H22 | 0.7370 | 0.4951 | 0.2969 | 0.024* | |
C23 | 0.69778 (15) | 0.48432 (12) | 0.43966 (15) | 0.0226 (3) | |
H23 | 0.7588 | 0.5177 | 0.4835 | 0.027* | |
C24 | 0.62023 (15) | 0.44770 (12) | 0.48682 (14) | 0.0224 (3) | |
H24 | 0.6294 | 0.4564 | 0.5633 | 0.027* | |
C25 | 0.53063 (14) | 0.39920 (11) | 0.42404 (13) | 0.0185 (3) | |
H25 | 0.4795 | 0.3748 | 0.4580 | 0.022* | |
C26 | 0.51429 (13) | 0.38559 (10) | 0.31042 (12) | 0.0142 (3) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Rh1 | 0.01302 (5) | 0.01412 (5) | 0.01470 (5) | 0.00064 (4) | 0.00295 (4) | 0.00308 (4) |
Cr1 | 0.01411 (10) | 0.01046 (10) | 0.00892 (9) | −0.00153 (8) | 0.00456 (8) | −0.00158 (8) |
Cl1 | 0.0227 (2) | 0.0547 (3) | 0.01440 (17) | −0.0086 (2) | −0.00046 (15) | 0.00491 (19) |
N1 | 0.0178 (6) | 0.0172 (6) | 0.0121 (5) | −0.0007 (5) | 0.0049 (5) | −0.0030 (5) |
N2 | 0.0203 (6) | 0.0117 (5) | 0.0114 (5) | −0.0018 (5) | 0.0072 (5) | −0.0008 (4) |
N3 | 0.0187 (6) | 0.0135 (6) | 0.0150 (6) | −0.0017 (5) | 0.0083 (5) | −0.0007 (5) |
O1 | 0.0199 (5) | 0.0184 (5) | 0.0101 (4) | −0.0079 (4) | 0.0045 (4) | −0.0017 (4) |
O2 | 0.0165 (5) | 0.0171 (5) | 0.0109 (5) | −0.0041 (4) | 0.0026 (4) | −0.0005 (4) |
C1 | 0.0186 (8) | 0.0199 (8) | 0.0427 (11) | 0.0068 (6) | 0.0099 (7) | 0.0117 (8) |
C2 | 0.0250 (9) | 0.0207 (9) | 0.0525 (13) | 0.0043 (7) | 0.0218 (9) | 0.0030 (8) |
C3 | 0.0242 (8) | 0.0258 (9) | 0.0321 (9) | −0.0011 (7) | 0.0172 (7) | −0.0019 (7) |
C4 | 0.0197 (7) | 0.0172 (7) | 0.0160 (6) | −0.0003 (6) | 0.0067 (5) | −0.0022 (6) |
C5 | 0.0177 (7) | 0.0174 (7) | 0.0205 (7) | −0.0015 (6) | 0.0058 (6) | −0.0052 (6) |
C6 | 0.0281 (9) | 0.0194 (8) | 0.0479 (12) | −0.0073 (7) | 0.0184 (9) | −0.0125 (8) |
C7 | 0.0270 (9) | 0.0140 (8) | 0.0661 (15) | 0.0005 (7) | 0.0236 (10) | 0.0038 (9) |
C8 | 0.0238 (9) | 0.0194 (8) | 0.0444 (11) | 0.0071 (7) | 0.0125 (8) | 0.0152 (8) |
C11 | 0.0154 (6) | 0.0122 (6) | 0.0122 (6) | −0.0014 (5) | 0.0036 (5) | −0.0019 (5) |
C12 | 0.0202 (7) | 0.0206 (8) | 0.0178 (7) | −0.0054 (6) | 0.0080 (6) | −0.0032 (6) |
C13 | 0.0191 (7) | 0.0218 (8) | 0.0251 (8) | −0.0060 (6) | 0.0084 (6) | −0.0050 (7) |
C14 | 0.0175 (7) | 0.0202 (8) | 0.0221 (8) | −0.0039 (6) | 0.0014 (6) | −0.0070 (6) |
C15 | 0.0183 (7) | 0.0169 (7) | 0.0140 (6) | 0.0006 (6) | 0.0005 (5) | −0.0028 (5) |
C16 | 0.0157 (6) | 0.0114 (6) | 0.0108 (6) | 0.0009 (5) | 0.0022 (5) | −0.0013 (5) |
C17 | 0.0203 (7) | 0.0118 (6) | 0.0104 (6) | 0.0019 (5) | 0.0039 (5) | −0.0001 (5) |
C18 | 0.0315 (9) | 0.0177 (7) | 0.0139 (6) | −0.0071 (6) | 0.0127 (6) | −0.0023 (6) |
C19 | 0.0263 (8) | 0.0232 (8) | 0.0194 (7) | −0.0077 (7) | 0.0149 (6) | −0.0064 (6) |
C20 | 0.0168 (7) | 0.0131 (6) | 0.0204 (7) | −0.0013 (5) | 0.0071 (6) | 0.0009 (5) |
C21 | 0.0157 (6) | 0.0117 (6) | 0.0170 (7) | −0.0009 (5) | 0.0025 (5) | 0.0006 (5) |
C22 | 0.0184 (7) | 0.0151 (7) | 0.0236 (8) | −0.0025 (6) | 0.0017 (6) | 0.0005 (6) |
C23 | 0.0218 (8) | 0.0173 (7) | 0.0229 (8) | −0.0027 (6) | −0.0022 (6) | −0.0046 (6) |
C24 | 0.0243 (8) | 0.0223 (8) | 0.0161 (7) | 0.0013 (7) | −0.0010 (6) | −0.0046 (6) |
C25 | 0.0203 (7) | 0.0193 (7) | 0.0143 (7) | 0.0012 (6) | 0.0028 (6) | −0.0023 (6) |
C26 | 0.0156 (6) | 0.0118 (6) | 0.0134 (6) | 0.0014 (5) | 0.0015 (5) | −0.0007 (5) |
Rh1—N1 | 1.9594 (14) | C7—C8 | 1.513 (3) |
Rh1—Cl1 | 2.3644 (6) | C7—H7A | 0.9900 |
Rh1—C1 | 2.1921 (18) | C7—H7B | 0.9900 |
Rh1—C8 | 2.1744 (18) | C8—H8 | 1.0000 |
Rh1—C4 | 2.1065 (16) | C11—C12 | 1.409 (2) |
Rh1—C5 | 2.1126 (17) | C11—C16 | 1.415 (2) |
Cr1—N1 | 1.5936 (14) | C12—C13 | 1.386 (2) |
Cr1—O1 | 1.8870 (11) | C12—H12 | 0.9500 |
Cr1—O2 | 1.9063 (11) | C13—C14 | 1.399 (3) |
Cr1—N2 | 2.0017 (13) | C13—H13 | 0.9500 |
Cr1—N3 | 2.0091 (14) | C14—C15 | 1.374 (2) |
N2—C17 | 1.291 (2) | C14—H14 | 0.9500 |
N2—C18 | 1.473 (2) | C15—C16 | 1.413 (2) |
N3—C20 | 1.294 (2) | C15—H15 | 0.9500 |
N3—C19 | 1.479 (2) | C16—C17 | 1.441 (2) |
O1—C11 | 1.3312 (18) | C17—H17 | 0.9500 |
O2—C26 | 1.3232 (18) | C18—C19 | 1.516 (3) |
C1—C8 | 1.389 (3) | C18—H18A | 0.9900 |
C1—C2 | 1.520 (3) | C18—H18B | 0.9900 |
C1—H1 | 1.0000 | C19—H19A | 0.9900 |
C2—C3 | 1.529 (3) | C19—H19B | 0.9900 |
C2—H2A | 0.9900 | C20—C21 | 1.438 (2) |
C2—H2B | 0.9900 | C20—H20 | 0.9500 |
C3—C4 | 1.511 (2) | C21—C22 | 1.418 (2) |
C3—H3A | 0.9900 | C21—C26 | 1.420 (2) |
C3—H3B | 0.9900 | C22—C23 | 1.374 (3) |
C4—C5 | 1.409 (2) | C22—H22 | 0.9500 |
C4—H4 | 1.0000 | C23—C24 | 1.402 (3) |
C5—C6 | 1.522 (3) | C23—H23 | 0.9500 |
C5—H5 | 1.0000 | C24—C25 | 1.383 (2) |
C6—C7 | 1.540 (3) | C24—H24 | 0.9500 |
C6—H6A | 0.9900 | C25—C26 | 1.407 (2) |
C6—H6B | 0.9900 | C25—H25 | 0.9500 |
N1—Rh1—C4 | 88.71 (6) | C7—C6—H6B | 108.9 |
N1—Rh1—C5 | 92.66 (6) | H6A—C6—H6B | 107.7 |
C4—Rh1—C5 | 39.02 (6) | C8—C7—C6 | 113.90 (16) |
N1—Rh1—C8 | 162.51 (7) | C8—C7—H7A | 108.8 |
C4—Rh1—C8 | 97.41 (8) | C6—C7—H7A | 108.8 |
C5—Rh1—C8 | 82.16 (8) | C8—C7—H7B | 108.8 |
N1—Rh1—C1 | 160.25 (6) | C6—C7—H7B | 108.8 |
C4—Rh1—C1 | 81.28 (7) | H7A—C7—H7B | 107.7 |
C5—Rh1—C1 | 90.21 (7) | C1—C8—C7 | 123.6 (2) |
C8—Rh1—C1 | 37.10 (7) | C1—C8—Rh1 | 72.14 (11) |
N1—Rh1—Cl1 | 89.21 (4) | C7—C8—Rh1 | 109.89 (13) |
C4—Rh1—Cl1 | 162.51 (5) | C1—C8—H8 | 114.5 |
C5—Rh1—Cl1 | 158.47 (5) | C7—C8—H8 | 114.5 |
C8—Rh1—Cl1 | 89.67 (6) | Rh1—C8—H8 | 114.5 |
C1—Rh1—Cl1 | 95.24 (6) | O1—C11—C12 | 118.36 (14) |
N1—Cr1—O1 | 110.97 (6) | O1—C11—C16 | 123.20 (14) |
N1—Cr1—O2 | 105.52 (6) | C12—C11—C16 | 118.41 (14) |
O1—Cr1—O2 | 87.52 (5) | C13—C12—C11 | 120.55 (15) |
N1—Cr1—N2 | 98.95 (6) | C13—C12—H12 | 119.7 |
O1—Cr1—N2 | 89.46 (5) | C11—C12—H12 | 119.7 |
O2—Cr1—N2 | 154.77 (6) | C12—C13—C14 | 121.08 (16) |
N1—Cr1—N3 | 101.36 (6) | C12—C13—H13 | 119.5 |
O1—Cr1—N3 | 147.29 (6) | C14—C13—H13 | 119.5 |
O2—Cr1—N3 | 88.66 (5) | C15—C14—C13 | 119.15 (15) |
N2—Cr1—N3 | 80.48 (6) | C15—C14—H14 | 120.4 |
Cr1—N1—Rh1 | 173.03 (9) | C13—C14—H14 | 120.4 |
C17—N2—C18 | 119.86 (13) | C14—C15—C16 | 121.16 (15) |
C17—N2—Cr1 | 127.94 (11) | C14—C15—H15 | 119.4 |
C18—N2—Cr1 | 112.04 (10) | C16—C15—H15 | 119.4 |
C20—N3—C19 | 119.25 (14) | C15—C16—C11 | 119.64 (14) |
C20—N3—Cr1 | 125.54 (11) | C15—C16—C17 | 117.85 (14) |
C19—N3—Cr1 | 115.19 (10) | C11—C16—C17 | 122.51 (14) |
C11—O1—Cr1 | 129.88 (10) | N2—C17—C16 | 124.15 (14) |
C26—O2—Cr1 | 126.34 (10) | N2—C17—H17 | 117.9 |
C8—C1—C2 | 122.1 (2) | C16—C17—H17 | 117.9 |
C8—C1—Rh1 | 70.75 (11) | N2—C18—C19 | 106.43 (13) |
C2—C1—Rh1 | 112.22 (12) | N2—C18—H18A | 110.4 |
C8—C1—H1 | 114.7 | C19—C18—H18A | 110.4 |
C2—C1—H1 | 114.7 | N2—C18—H18B | 110.4 |
Rh1—C1—H1 | 114.7 | C19—C18—H18B | 110.4 |
C1—C2—C3 | 112.16 (15) | H18A—C18—H18B | 108.6 |
C1—C2—H2A | 109.2 | N3—C19—C18 | 107.71 (13) |
C3—C2—H2A | 109.2 | N3—C19—H19A | 110.2 |
C1—C2—H2B | 109.2 | C18—C19—H19A | 110.2 |
C3—C2—H2B | 109.2 | N3—C19—H19B | 110.2 |
H2A—C2—H2B | 107.9 | C18—C19—H19B | 110.2 |
C4—C3—C2 | 113.36 (15) | H19A—C19—H19B | 108.5 |
C4—C3—H3A | 108.9 | N3—C20—C21 | 124.45 (15) |
C2—C3—H3A | 108.9 | N3—C20—H20 | 117.8 |
C4—C3—H3B | 108.9 | C21—C20—H20 | 117.8 |
C2—C3—H3B | 108.9 | C22—C21—C26 | 119.65 (15) |
H3A—C3—H3B | 107.7 | C22—C21—C20 | 118.17 (15) |
C5—C4—C3 | 124.74 (16) | C26—C21—C20 | 121.96 (14) |
C5—C4—Rh1 | 70.72 (9) | C23—C22—C21 | 121.12 (17) |
C3—C4—Rh1 | 111.94 (12) | C23—C22—H22 | 119.4 |
C5—C4—H4 | 113.9 | C21—C22—H22 | 119.4 |
C3—C4—H4 | 113.9 | C22—C23—C24 | 119.03 (16) |
Rh1—C4—H4 | 113.9 | C22—C23—H23 | 120.5 |
C4—C5—C6 | 123.49 (16) | C24—C23—H23 | 120.5 |
C4—C5—Rh1 | 70.26 (9) | C25—C24—C23 | 121.20 (16) |
C6—C5—Rh1 | 113.95 (13) | C25—C24—H24 | 119.4 |
C4—C5—H5 | 113.9 | C23—C24—H24 | 119.4 |
C6—C5—H5 | 113.9 | C24—C25—C26 | 120.82 (16) |
Rh1—C5—H5 | 113.9 | C24—C25—H25 | 119.6 |
C5—C6—C7 | 113.38 (17) | C26—C25—H25 | 119.6 |
C5—C6—H6A | 108.9 | O2—C26—C25 | 118.67 (15) |
C7—C6—H6A | 108.9 | O2—C26—C21 | 123.10 (14) |
C5—C6—H6B | 108.9 | C25—C26—C21 | 118.17 (14) |
(salen)Cr(µ-N)RhCl(COD)a | Cr(N)(salen)b | |
Cr≡N | 1.5936 (14) | 1.559 (2) |
Cr—O | 1.8869 (11)–1.9063 (11) | 1.910 (2)–1.913 (2) |
Cr—N | 2.0016 (13)–2.0091 (14) | 2.017 (2)–2.019 (2) |
Cr-oop c | 0.4827 (7) | 0.501 (1) |
Notes: (a) present work; (b) Bendix et al. (1998); (c) oop = out-of-plane. |
Rh/Ir—N | Rh/Ir—Cl | Rh/Ir—C | M≡N—Rh/Ir | |
(salen)Cr(µ-N)RhCl(COD)a | 1.9594 (14) | 2.3644 (6) | 2.1065 (16)–2.1921 (18) | 173.03 (9) |
(Me2PhP)3Cl2Re(µ-N)RhCl(COD)b | 1.956 (6) | 2.373 (3) | 2.10 (1)–2.17 (1) | 174.8 (4) |
(Ph3Sb)2Cl3Os(µ-N)RhCl(COD)c | 1.846 (6) | 2.337 (3) | 2.138 (10)–2.274 (11) | 175.3 (5) |
(Me2PhP)3Cl2Re(µ-N)IrCl(COD)d | 1.962 (8) | 2.342 (3) | 2.10 (1)–2.18 (1) | 173.8 (4) |
[O3Os(µ-N)IrCl(COD)]-d | 1.978 (7) | 2.353 (3) | 2.09 (1)–2.142 (9) | 161.8 (4) |
[Rh(COD)Cl]2e | - | 2.402 (1)–2.421 (1) | 2.097 (6)–2.126 (6) | - |
Notes: (a) present work; (b) Schwarz & Strähle (2003); (c) Schwarz et al. (2004); (d) Schwarz et al. (2003); (e) De Ridder & Imhoff (1994). |
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