Pentacarbonyl(triphenylsilyl)manganese(I)

Lebuis, A.-M.; Christendat, D.; Gilson, D.F.R.; Butler, I.S.

doi:10.1107/S0108270197005192

Pentacarbonyl(triphenylsilyl)manganese(I)

A.-M. Lebuis, D. Christendat, D. F. R. Gilson and I. S. Butler

The title compound, [Mn(C₁₈H₁₅Si)(CO)₅], crystallizes in the space group P $\overline{1}$ with two molecules in the asymmetric unit. It is a strong covalent `bimetallic' complex with partial multiple-bond character in the `metal-metal' bond as evidenced by the short (average) Mn-Si distance of 2.504 (6) Å.

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Pentacarbonyl(triphenylsilyl)manganese(I)

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	Crystallographic Information File (CIF) Contains datablocks butl29, global
	Structure factor file (CIF format) Contains datablock butl29