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In the title compound, [AgI(C21H21P)3], important bond distances are: Ag-P = 2.5346 (9), 2.5562 (9) and 2.5617 (9) Å, and Ag-I = 2.8683 (5) Å. The AgI atom is in a distorted tetra­hedral environment and all bond angles are close to the ideal values.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806050884/hg2143sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806050884/hg2143Isup2.hkl
Contains datablock I

CCDC reference: 633877

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.006 Å
  • Disorder in main residue
  • R factor = 0.040
  • wR factor = 0.094
  • Data-to-parameter ratio = 19.6

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low ....... 0.98 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C13 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C15 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C93 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C93B PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C11 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C14 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C84 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C91 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C94 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C94B PLAT301_ALERT_3_C Main Residue Disorder ......................... 8.00 Perc.
Alert level G PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature . 293 K
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 12 ALERT level C = Check and explain 2 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 10 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART-NT (Bruker, 1999); cell refinement: SAINT-Plus (Bruker, 1999); data reduction: SAINT-Plus and XPREP (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

Iodotris(tri-p-tolylphosphine)silver(I) top
Crystal data top
[AgI(C21H21P)3]Z = 2
Mr = 1147.81F(000) = 1172
Triclinic, P1Dx = 1.36 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 11.0426 (13) ÅCell parameters from 891 reflections
b = 11.5665 (14) Åθ = 6.1–51.2°
c = 23.243 (3) ŵ = 1.03 mm1
α = 99.292 (3)°T = 293 K
β = 92.174 (2)°Cuboid, colourless
γ = 106.196 (2)°0.3 × 0.26 × 0.15 mm
V = 2802.7 (6) Å3
Data collection top
Bruker SMART 1K CCD area-detector
diffractometer
13246 independent reflections
Radiation source: fine-focus sealed tube8623 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.022
Detector resolution: 512 pixels mm-1θmax = 28°, θmin = 0.9°
ω scansh = 1414
Absorption correction: multi-scan
(SADABS; Bruker, 2004)
k = 1511
Tmin = 0.747, Tmax = 0.860l = 3028
19391 measured reflections
Refinement top
Refinement on F26 restraints
Least-squares matrix: fullH-atom parameters constrained
R[F2 > 2σ(F2)] = 0.040 w = 1/[σ2(Fo2) + (0.0327P)2 + 1.1965P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.094(Δ/σ)max < 0.001
S = 1.01Δρmax = 0.57 e Å3
13246 reflectionsΔρmin = 0.54 e Å3
677 parameters
Special details top

Experimental. The intensity data were collected on a Siemens SMART 1 K CCD diffractometer using an exposure time of 10 s/frame. A total of 1315 frames were collected with a frame width of 0.3° covering up to θ = 28.0° with 97.9% completeness accomplished. The first 50 frames were recollected at the end of each data collection to check for decay; none was found.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag0.14515 (2)0.21085 (2)0.248917 (11)0.04531 (8)
I0.40509 (2)0.21196 (2)0.247552 (11)0.06297 (9)
P10.12590 (8)0.27580 (7)0.35685 (4)0.04108 (19)
P20.15045 (8)0.38249 (8)0.19135 (4)0.0472 (2)
P30.00408 (8)0.00545 (7)0.19679 (4)0.04207 (19)
C110.1621 (3)0.1794 (3)0.40646 (14)0.0435 (7)
C120.2345 (5)0.1032 (4)0.38875 (19)0.0811 (13)
H120.26760.10420.35260.097*
C130.2593 (5)0.0244 (4)0.4242 (2)0.0924 (15)
H130.3080.02660.41090.111*
C140.2148 (4)0.0203 (3)0.47693 (18)0.0626 (10)
C150.1478 (4)0.0983 (4)0.49495 (19)0.0850 (14)
H150.11850.09960.5320.102*
C160.1203 (4)0.1773 (4)0.46037 (17)0.0752 (12)
H160.07280.2290.47450.09*
C170.2417 (5)0.0665 (4)0.5153 (2)0.0952 (16)
H17A0.21430.04730.55340.143*
H17B0.33090.05740.51860.143*
H17C0.19680.14930.49780.143*
C210.2325 (3)0.4264 (3)0.38682 (13)0.0417 (7)
C220.3472 (3)0.4409 (3)0.41686 (17)0.0601 (10)
H220.36720.37260.42590.072*
C230.4334 (3)0.5560 (4)0.43390 (18)0.0678 (11)
H230.51070.56320.45370.081*
C240.4069 (4)0.6590 (3)0.42223 (16)0.0602 (10)
C250.2919 (4)0.6451 (3)0.39367 (16)0.0612 (10)
H250.27090.71420.38640.073*
C260.2064 (3)0.5317 (3)0.37541 (16)0.0572 (9)
H260.12990.52530.35510.069*
C270.5046 (4)0.7819 (4)0.4402 (2)0.0934 (15)
H27A0.55280.80150.40780.14*
H27B0.56020.77880.47230.14*
H27C0.4630.84340.4520.14*
C310.0296 (3)0.2887 (3)0.37501 (13)0.0410 (7)
C320.0505 (3)0.3634 (3)0.42458 (14)0.0498 (8)
H320.01760.41140.45060.06*
C330.1719 (3)0.3667 (3)0.43537 (15)0.0550 (9)
H330.18410.4170.46880.066*
C340.2746 (3)0.2974 (3)0.39783 (16)0.0554 (9)
C350.2543 (3)0.2242 (3)0.34844 (15)0.0596 (10)
H350.32270.17740.32220.072*
C360.1336 (3)0.2196 (3)0.33751 (15)0.0527 (8)
H360.12220.16880.30410.063*
C370.4065 (4)0.3021 (5)0.4093 (2)0.0953 (16)
H37A0.40280.36330.44310.143*
H37B0.45590.22380.41620.143*
H37C0.44480.32210.37590.143*
C410.0020 (3)0.4039 (3)0.17181 (14)0.0475 (8)
C420.0224 (3)0.4734 (3)0.13047 (16)0.0596 (9)
H420.04450.51040.11030.072*
C430.1403 (4)0.4880 (4)0.11916 (16)0.0643 (10)
H430.15080.53590.09190.077*
C440.2425 (3)0.4333 (3)0.14718 (17)0.0590 (9)
C450.2239 (4)0.3639 (3)0.18798 (19)0.0656 (10)
H450.29170.32550.20730.079*
C460.1051 (3)0.3511 (3)0.20029 (16)0.0561 (9)
H460.09440.30550.22860.067*
C470.3720 (4)0.4486 (4)0.1339 (2)0.0909 (14)
H47A0.43130.40420.15740.136*0.5
H47B0.39930.41740.09320.136*0.5
H47C0.36750.53380.14260.136*0.5
H47D0.36750.49940.10470.136*0.5
H47E0.39940.48620.16890.136*0.5
H47F0.43130.36980.11960.136*0.5
C510.2184 (3)0.3535 (3)0.12181 (14)0.0445 (7)
C520.2115 (3)0.2342 (3)0.09761 (15)0.0489 (8)
H520.17340.17150.11730.059*
C530.2597 (3)0.2055 (3)0.04478 (15)0.0515 (8)
H530.25240.12420.02950.062*
C540.3190 (3)0.2967 (3)0.01431 (15)0.0484 (8)
C550.3264 (3)0.4164 (3)0.03887 (16)0.0570 (9)
H550.36540.47930.01940.068*
C560.2776 (3)0.4445 (3)0.09114 (15)0.0543 (9)
H560.28420.52580.10620.065*
C570.3754 (4)0.2666 (4)0.04213 (17)0.0675 (10)
H57A0.30890.23150.07310.101*
H57B0.42190.20910.03810.101*
H57C0.43140.340.05120.101*
C610.2469 (3)0.5374 (3)0.22309 (14)0.0494 (8)
C620.3751 (4)0.5575 (4)0.23764 (19)0.0726 (11)
H620.40960.49230.23170.087*
C630.4523 (4)0.6742 (4)0.2610 (2)0.0811 (13)
H630.53830.68590.26940.097*
C640.4052 (5)0.7723 (4)0.27180 (18)0.0734 (12)
C650.2785 (5)0.7523 (4)0.25944 (18)0.0755 (12)
H650.24410.81730.26740.091*
C660.1997 (4)0.6368 (3)0.23513 (17)0.0656 (10)
H660.11390.62610.22680.079*
C670.4925 (5)0.8998 (4)0.2983 (2)0.0988 (17)
H67A0.49180.9550.27160.148*
H67B0.57720.89530.30520.148*
H67C0.46320.92910.33460.148*
C710.1473 (3)0.0207 (3)0.16081 (14)0.0439 (7)
C720.2609 (3)0.0009 (3)0.18623 (15)0.0566 (9)
H720.26740.03160.22090.068*
C730.3650 (4)0.0224 (4)0.16094 (16)0.0653 (10)
H730.43970.00830.17930.078*
C740.3604 (3)0.0660 (3)0.10907 (16)0.0555 (9)
C750.2479 (3)0.0867 (3)0.08341 (17)0.0598 (9)
H750.24270.11490.0480.072*
C760.1422 (3)0.0664 (3)0.10909 (16)0.0540 (9)
H760.06670.08370.09140.065*
C770.4755 (4)0.0909 (4)0.08200 (19)0.0804 (13)
H77A0.5390.01480.06760.121*
H77B0.45170.13390.05020.121*
H77C0.50870.13990.1110.121*
C810.0597 (3)0.0827 (3)0.13968 (14)0.0434 (7)
C820.0075 (4)0.1510 (3)0.08838 (16)0.0614 (10)
H820.08950.14870.07960.074*
C830.0458 (4)0.2235 (4)0.04947 (16)0.0681 (11)
H830.00070.26740.01470.082*
C840.1648 (4)0.2314 (3)0.06145 (16)0.0611 (10)
C850.2318 (4)0.1630 (4)0.11189 (19)0.0704 (11)
H850.31350.16640.12060.085*
C860.1812 (3)0.0881 (3)0.15071 (16)0.0604 (9)
H860.22980.04130.18440.072*
C870.2194 (5)0.3142 (4)0.01950 (19)0.0956 (16)
H87A0.17790.39810.02150.143*
H87B0.30840.29640.03010.143*
H87C0.20660.30050.01960.143*
C910.0626 (3)0.1085 (3)0.24329 (14)0.0445 (7)
C920.0089 (11)0.0844 (7)0.3002 (3)0.069 (3)0.648 (17)
H920.050.00930.31490.083*0.648 (17)
C930.0426 (12)0.1719 (8)0.3354 (3)0.085 (4)0.648 (17)
H930.00650.15140.37390.102*0.648 (17)
C940.1230 (18)0.283 (2)0.3184 (10)0.069 (4)0.648 (17)
C950.1826 (17)0.3059 (19)0.2601 (11)0.074 (4)0.648 (17)
H950.24610.37860.24670.088*0.648 (17)
C960.1469 (10)0.2212 (12)0.2232 (6)0.064 (3)0.648 (17)
H960.18070.24120.18440.076*0.648 (17)
C970.1539 (14)0.3725 (12)0.3593 (6)0.095 (4)0.648 (17)
H97A0.23910.38220.36960.143*0.648 (17)
H97B0.09650.34240.39410.143*0.648 (17)
H97C0.1460.450.34070.143*0.648 (17)
C92B0.087 (2)0.0716 (12)0.2991 (6)0.071 (5)0.352 (17)
H92B0.06880.01180.31340.086*0.352 (17)
C93B0.138 (3)0.1556 (13)0.3365 (6)0.088 (7)0.352 (17)
H93B0.15450.12910.37460.106*0.352 (17)
C94B0.162 (3)0.274 (4)0.3143 (18)0.061 (6)0.352 (17)
C95B0.134 (3)0.314 (3)0.261 (2)0.083 (10)0.352 (17)
H95B0.14460.39660.24830.1*0.352 (17)
C96B0.089 (3)0.229 (2)0.2255 (11)0.076 (7)0.352 (17)
H96B0.07690.25820.18710.091*0.352 (17)
C97B0.222 (2)0.380 (3)0.3510 (12)0.099 (8)0.352 (17)
H97D0.19360.35160.39170.149*0.352 (17)
H97E0.19620.45120.33680.149*0.352 (17)
H97F0.31310.40070.34630.149*0.352 (17)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag0.04831 (14)0.04667 (15)0.04342 (14)0.01687 (11)0.00701 (11)0.00893 (11)
I0.04693 (13)0.08375 (19)0.06328 (16)0.02666 (12)0.00769 (11)0.01324 (13)
P10.0410 (4)0.0427 (5)0.0399 (4)0.0145 (4)0.0049 (3)0.0041 (4)
P20.0533 (5)0.0455 (5)0.0485 (5)0.0189 (4)0.0103 (4)0.0147 (4)
P30.0458 (4)0.0396 (5)0.0411 (5)0.0143 (4)0.0027 (4)0.0046 (4)
C110.0402 (17)0.0421 (18)0.0478 (19)0.0102 (14)0.0038 (14)0.0100 (15)
C120.124 (4)0.072 (3)0.074 (3)0.059 (3)0.044 (3)0.029 (2)
C130.137 (4)0.079 (3)0.097 (4)0.072 (3)0.045 (3)0.039 (3)
C140.059 (2)0.057 (2)0.077 (3)0.0144 (19)0.004 (2)0.030 (2)
C150.102 (3)0.115 (4)0.066 (3)0.054 (3)0.034 (3)0.046 (3)
C160.099 (3)0.096 (3)0.058 (2)0.063 (3)0.024 (2)0.029 (2)
C170.104 (4)0.087 (3)0.111 (4)0.030 (3)0.011 (3)0.059 (3)
C210.0407 (16)0.0447 (18)0.0408 (17)0.0134 (14)0.0061 (14)0.0082 (14)
C220.0446 (19)0.053 (2)0.084 (3)0.0142 (17)0.0025 (18)0.017 (2)
C230.046 (2)0.064 (3)0.084 (3)0.0023 (19)0.0123 (19)0.013 (2)
C240.066 (2)0.052 (2)0.055 (2)0.0043 (19)0.0059 (19)0.0118 (18)
C250.077 (3)0.045 (2)0.062 (2)0.0178 (19)0.001 (2)0.0123 (18)
C260.058 (2)0.054 (2)0.060 (2)0.0161 (18)0.0067 (18)0.0124 (18)
C270.097 (3)0.058 (3)0.104 (4)0.010 (2)0.010 (3)0.015 (2)
C310.0381 (16)0.0445 (18)0.0401 (17)0.0121 (14)0.0029 (13)0.0069 (14)
C320.0446 (18)0.059 (2)0.0450 (19)0.0187 (16)0.0003 (15)0.0011 (16)
C330.059 (2)0.065 (2)0.047 (2)0.0312 (19)0.0094 (17)0.0057 (17)
C340.0467 (19)0.077 (3)0.052 (2)0.0274 (18)0.0097 (17)0.0204 (19)
C350.0395 (18)0.080 (3)0.050 (2)0.0060 (18)0.0022 (16)0.0054 (19)
C360.0448 (18)0.061 (2)0.0461 (19)0.0080 (16)0.0047 (15)0.0029 (16)
C370.054 (2)0.158 (5)0.077 (3)0.041 (3)0.011 (2)0.009 (3)
C410.0525 (19)0.0466 (19)0.0471 (19)0.0177 (16)0.0092 (15)0.0116 (15)
C420.058 (2)0.073 (3)0.056 (2)0.0216 (19)0.0120 (18)0.0264 (19)
C430.073 (3)0.071 (3)0.059 (2)0.034 (2)0.002 (2)0.019 (2)
C440.052 (2)0.055 (2)0.072 (3)0.0235 (18)0.0031 (19)0.0025 (19)
C450.057 (2)0.056 (2)0.092 (3)0.0204 (19)0.027 (2)0.023 (2)
C460.058 (2)0.053 (2)0.067 (2)0.0239 (17)0.0174 (18)0.0226 (18)
C470.067 (3)0.094 (3)0.120 (4)0.037 (3)0.003 (3)0.020 (3)
C510.0443 (17)0.0455 (19)0.0476 (19)0.0163 (15)0.0056 (15)0.0131 (15)
C520.0495 (19)0.0430 (19)0.055 (2)0.0113 (15)0.0078 (16)0.0146 (16)
C530.0518 (19)0.047 (2)0.055 (2)0.0173 (16)0.0019 (16)0.0023 (16)
C540.0412 (17)0.055 (2)0.051 (2)0.0174 (16)0.0049 (15)0.0091 (16)
C550.064 (2)0.052 (2)0.061 (2)0.0188 (18)0.0196 (18)0.0202 (18)
C560.069 (2)0.0404 (19)0.059 (2)0.0210 (17)0.0183 (18)0.0124 (16)
C570.065 (2)0.072 (3)0.065 (3)0.022 (2)0.023 (2)0.008 (2)
C610.059 (2)0.0463 (19)0.0461 (19)0.0168 (16)0.0114 (16)0.0133 (15)
C620.063 (2)0.060 (3)0.091 (3)0.018 (2)0.012 (2)0.001 (2)
C630.056 (2)0.083 (3)0.092 (3)0.007 (2)0.015 (2)0.001 (3)
C640.096 (3)0.057 (3)0.065 (3)0.012 (2)0.024 (2)0.016 (2)
C650.108 (4)0.050 (2)0.073 (3)0.031 (2)0.001 (3)0.011 (2)
C660.083 (3)0.054 (2)0.065 (2)0.030 (2)0.005 (2)0.0113 (19)
C670.124 (4)0.062 (3)0.085 (3)0.011 (3)0.014 (3)0.008 (2)
C710.0483 (18)0.0390 (17)0.0444 (18)0.0163 (14)0.0021 (15)0.0017 (14)
C720.056 (2)0.074 (3)0.047 (2)0.0266 (19)0.0068 (17)0.0142 (18)
C730.056 (2)0.090 (3)0.058 (2)0.033 (2)0.0144 (18)0.013 (2)
C740.058 (2)0.058 (2)0.053 (2)0.0279 (18)0.0007 (18)0.0013 (17)
C750.065 (2)0.059 (2)0.061 (2)0.0201 (19)0.0017 (19)0.0225 (19)
C760.053 (2)0.052 (2)0.061 (2)0.0167 (17)0.0100 (17)0.0191 (17)
C770.076 (3)0.103 (3)0.077 (3)0.052 (3)0.002 (2)0.014 (3)
C810.0484 (18)0.0401 (18)0.0444 (18)0.0171 (14)0.0043 (15)0.0074 (14)
C820.059 (2)0.071 (3)0.055 (2)0.0265 (19)0.0015 (18)0.0000 (19)
C830.087 (3)0.072 (3)0.045 (2)0.032 (2)0.001 (2)0.0043 (19)
C840.090 (3)0.057 (2)0.052 (2)0.039 (2)0.026 (2)0.0209 (19)
C850.062 (2)0.079 (3)0.085 (3)0.042 (2)0.013 (2)0.017 (2)
C860.064 (2)0.061 (2)0.058 (2)0.0293 (19)0.0036 (18)0.0021 (18)
C870.153 (5)0.098 (3)0.071 (3)0.083 (3)0.045 (3)0.026 (3)
C910.0513 (19)0.0409 (19)0.0424 (18)0.0156 (15)0.0062 (15)0.0060 (14)
C920.093 (7)0.049 (4)0.055 (4)0.005 (4)0.010 (4)0.011 (3)
C930.122 (9)0.071 (5)0.051 (4)0.003 (5)0.007 (5)0.023 (4)
C940.098 (11)0.055 (6)0.067 (7)0.039 (7)0.001 (7)0.020 (5)
C950.084 (9)0.046 (7)0.085 (9)0.004 (5)0.013 (8)0.018 (6)
C960.071 (6)0.051 (5)0.057 (5)0.001 (5)0.002 (5)0.009 (4)
C970.122 (11)0.065 (6)0.095 (7)0.007 (7)0.005 (8)0.042 (5)
C92B0.130 (17)0.038 (6)0.047 (7)0.029 (8)0.005 (9)0.005 (5)
C93B0.16 (2)0.061 (9)0.045 (7)0.033 (10)0.017 (9)0.021 (6)
C94B0.084 (16)0.055 (11)0.062 (12)0.031 (11)0.013 (13)0.038 (9)
C95B0.12 (3)0.033 (8)0.089 (19)0.017 (16)0.05 (2)0.004 (9)
C96B0.118 (19)0.059 (9)0.055 (10)0.030 (13)0.038 (13)0.005 (7)
C97B0.092 (14)0.112 (14)0.086 (13)0.003 (14)0.008 (13)0.058 (11)
Geometric parameters (Å, º) top
Ag—P12.5346 (9)C54—C551.388 (5)
Ag—P22.5562 (9)C54—C571.505 (5)
Ag—P32.5617 (9)C55—C561.375 (5)
Ag—I2.8683 (5)C55—H550.93
P1—C211.819 (3)C56—H560.93
P1—C311.824 (3)C57—H57A0.96
P1—C111.833 (3)C57—H57B0.96
P2—C411.820 (3)C57—H57C0.96
P2—C611.827 (3)C61—C661.383 (5)
P2—C511.829 (3)C61—C621.388 (5)
P3—C811.825 (3)C62—C631.389 (5)
P3—C711.826 (3)C62—H620.93
P3—C911.833 (3)C63—C641.367 (6)
C11—C161.353 (5)C63—H630.93
C11—C121.373 (5)C64—C651.364 (6)
C12—C131.396 (5)C64—C671.534 (6)
C12—H120.93C65—C661.390 (5)
C13—C141.340 (6)C65—H650.93
C13—H130.93C66—H660.93
C14—C151.346 (5)C67—H67A0.96
C14—C171.524 (5)C67—H67B0.96
C15—C161.395 (5)C67—H67C0.96
C15—H150.93C71—C721.384 (4)
C16—H160.93C71—C761.386 (4)
C17—H17A0.96C72—C731.382 (5)
C17—H17B0.96C72—H720.93
C17—H17C0.96C73—C741.378 (5)
C21—C221.377 (4)C73—H730.93
C21—C261.389 (4)C74—C751.376 (5)
C22—C231.389 (5)C74—C771.515 (5)
C22—H220.93C75—C761.385 (5)
C23—C241.368 (5)C75—H750.93
C23—H230.93C76—H760.93
C24—C251.366 (5)C77—H77A0.96
C24—C271.509 (5)C77—H77B0.96
C25—C261.376 (5)C77—H77C0.96
C25—H250.93C81—C861.377 (4)
C26—H260.93C81—C821.378 (5)
C27—H27A0.96C82—C831.392 (5)
C27—H27B0.96C82—H820.93
C27—H27C0.96C83—C841.364 (5)
C31—C361.381 (4)C83—H830.93
C31—C321.392 (4)C84—C851.363 (5)
C32—C331.382 (4)C84—C871.515 (5)
C32—H320.93C85—C861.390 (5)
C33—C341.373 (5)C85—H850.93
C33—H330.93C86—H860.93
C34—C351.377 (5)C87—H87A0.96
C34—C371.504 (5)C87—H87B0.96
C35—C361.380 (5)C87—H87C0.96
C35—H350.93C91—C96B1.34 (2)
C36—H360.93C91—C92B1.359 (15)
C37—H37A0.96C91—C961.370 (13)
C37—H37B0.96C91—C921.382 (9)
C37—H37C0.96C92—C931.383 (10)
C41—C461.381 (4)C92—H920.93
C41—C421.398 (4)C93—C941.33 (2)
C42—C431.379 (5)C93—H930.93
C42—H420.93C94—C951.44 (3)
C43—C441.374 (5)C94—C971.49 (2)
C43—H430.93C95—C961.39 (3)
C44—C451.382 (5)C95—H950.93
C44—C471.516 (5)C96—H960.93
C45—C461.385 (5)C97—H97A0.96
C45—H450.93C97—H97B0.96
C46—H460.93C97—H97C0.96
C47—H47A0.96C92B—C93B1.423 (19)
C47—H47B0.96C92B—H92B0.93
C47—H47C0.96C93B—C94B1.33 (4)
C47—H47D0.96C93B—H93B0.93
C47—H47E0.96C94B—C95B1.33 (6)
C47—H47F0.96C94B—C97B1.62 (4)
C51—C521.384 (4)C95B—C96B1.38 (5)
C51—C561.392 (4)C95B—H95B0.93
C52—C531.385 (4)C96B—H96B0.93
C52—H520.93C97B—H97D0.96
C53—C541.390 (4)C97B—H97E0.96
C53—H530.93C97B—H97F0.96
P1—Ag—P2112.04 (3)C56—C51—P2124.1 (3)
P1—Ag—P3117.65 (3)C51—C52—C53121.8 (3)
P2—Ag—P3111.94 (3)C51—C52—H52119.1
P1—Ag—I102.35 (2)C53—C52—H52119.1
P2—Ag—I99.38 (2)C52—C53—C54120.9 (3)
P3—Ag—I111.51 (2)C52—C53—H53119.5
C21—P1—C31103.78 (14)C54—C53—H53119.5
C21—P1—C11103.15 (14)C55—C54—C53117.2 (3)
C31—P1—C11103.84 (14)C55—C54—C57121.6 (3)
C21—P1—Ag112.53 (10)C53—C54—C57121.2 (3)
C31—P1—Ag115.08 (10)C56—C55—C54121.8 (3)
C11—P1—Ag116.91 (11)C56—C55—H55119.1
C41—P2—C61103.04 (15)C54—C55—H55119.1
C41—P2—C51105.19 (14)C55—C56—C51121.2 (3)
C61—P2—C51102.39 (15)C55—C56—H56119.4
C41—P2—Ag116.04 (11)C51—C56—H56119.4
C61—P2—Ag118.32 (11)C54—C57—H57A109.5
C51—P2—Ag110.25 (10)C54—C57—H57B109.5
C81—P3—C71104.34 (14)H57A—C57—H57B109.5
C81—P3—C91100.96 (14)C54—C57—H57C109.5
C71—P3—C91104.35 (15)H57A—C57—H57C109.5
C81—P3—Ag116.80 (11)H57B—C57—H57C109.5
C71—P3—Ag112.91 (10)C66—C61—C62117.2 (3)
C91—P3—Ag115.84 (11)C66—C61—P2124.1 (3)
C16—C11—C12116.9 (3)C62—C61—P2118.7 (3)
C16—C11—P1123.8 (3)C61—C62—C63120.6 (4)
C12—C11—P1119.4 (3)C61—C62—H62119.7
C11—C12—C13121.0 (4)C63—C62—H62119.7
C11—C12—H12119.5C64—C63—C62121.8 (4)
C13—C12—H12119.5C64—C63—H63119.1
C14—C13—C12121.9 (4)C62—C63—H63119.1
C14—C13—H13119.1C65—C64—C63117.8 (4)
C12—C13—H13119.1C65—C64—C67121.5 (4)
C13—C14—C15116.8 (4)C63—C64—C67120.6 (5)
C13—C14—C17121.5 (4)C64—C65—C66121.4 (4)
C15—C14—C17121.6 (4)C64—C65—H65119.3
C14—C15—C16122.7 (4)C66—C65—H65119.3
C14—C15—H15118.6C61—C66—C65121.1 (4)
C16—C15—H15118.6C61—C66—H66119.4
C11—C16—C15120.6 (4)C65—C66—H66119.4
C11—C16—H16119.7C64—C67—H67A109.5
C15—C16—H16119.7C64—C67—H67B109.5
C14—C17—H17A109.5H67A—C67—H67B109.5
C14—C17—H17B109.5C64—C67—H67C109.5
H17A—C17—H17B109.5H67A—C67—H67C109.5
C14—C17—H17C109.5H67B—C67—H67C109.5
H17A—C17—H17C109.5C72—C71—C76117.4 (3)
H17B—C17—H17C109.5C72—C71—P3122.1 (3)
C22—C21—C26117.1 (3)C76—C71—P3120.3 (3)
C22—C21—P1121.8 (2)C73—C72—C71121.1 (3)
C26—C21—P1120.8 (2)C73—C72—H72119.4
C21—C22—C23121.0 (3)C71—C72—H72119.4
C21—C22—H22119.5C74—C73—C72121.5 (3)
C23—C22—H22119.5C74—C73—H73119.3
C24—C23—C22121.4 (3)C72—C73—H73119.3
C24—C23—H23119.3C75—C74—C73117.6 (3)
C22—C23—H23119.3C75—C74—C77121.7 (4)
C25—C24—C23117.7 (3)C73—C74—C77120.7 (3)
C25—C24—C27122.7 (4)C74—C75—C76121.4 (3)
C23—C24—C27119.6 (4)C74—C75—H75119.3
C24—C25—C26121.7 (3)C76—C75—H75119.3
C24—C25—H25119.1C75—C76—C71121.0 (3)
C26—C25—H25119.1C75—C76—H76119.5
C25—C26—C21121.0 (3)C71—C76—H76119.5
C25—C26—H26119.5C74—C77—H77A109.5
C21—C26—H26119.5C74—C77—H77B109.5
C24—C27—H27A109.5H77A—C77—H77B109.5
C24—C27—H27B109.5C74—C77—H77C109.5
H27A—C27—H27B109.5H77A—C77—H77C109.5
C24—C27—H27C109.5H77B—C77—H77C109.5
H27A—C27—H27C109.5C86—C81—C82117.6 (3)
H27B—C27—H27C109.5C86—C81—P3117.3 (3)
C36—C31—C32117.6 (3)C82—C81—P3124.9 (3)
C36—C31—P1118.1 (2)C81—C82—C83120.9 (3)
C32—C31—P1124.2 (2)C81—C82—H82119.5
C33—C32—C31120.5 (3)C83—C82—H82119.5
C33—C32—H32119.7C84—C83—C82121.2 (4)
C31—C32—H32119.7C84—C83—H83119.4
C34—C33—C32121.4 (3)C82—C83—H83119.4
C34—C33—H33119.3C85—C84—C83117.9 (3)
C32—C33—H33119.3C85—C84—C87121.7 (4)
C33—C34—C35118.4 (3)C83—C84—C87120.4 (4)
C33—C34—C37121.3 (3)C84—C85—C86121.7 (4)
C35—C34—C37120.3 (3)C84—C85—H85119.2
C34—C35—C36120.7 (3)C86—C85—H85119.2
C34—C35—H35119.7C81—C86—C85120.6 (4)
C36—C35—H35119.7C81—C86—H86119.7
C35—C36—C31121.5 (3)C85—C86—H86119.7
C35—C36—H36119.3C84—C87—H87A109.5
C31—C36—H36119.3C84—C87—H87B109.5
C34—C37—H37A109.5H87A—C87—H87B109.5
C34—C37—H37B109.5C84—C87—H87C109.5
H37A—C37—H37B109.5H87A—C87—H87C109.5
C34—C37—H37C109.5H87B—C87—H87C109.5
H37A—C37—H37C109.5C96B—C91—C92B115.8 (12)
H37B—C37—H37C109.5C96—C91—C92117.9 (7)
C46—C41—C42116.8 (3)C96B—C91—P3124.4 (11)
C46—C41—P2118.7 (3)C92B—C91—P3119.7 (6)
C42—C41—P2124.5 (3)C96—C91—P3123.7 (6)
C43—C42—C41121.1 (3)C92—C91—P3118.0 (4)
C43—C42—H42119.5C91—C92—C93120.0 (7)
C41—C42—H42119.5C91—C92—H92120
C44—C43—C42121.5 (3)C93—C92—H92120
C44—C43—H43119.2C94—C93—C92124.9 (11)
C42—C43—H43119.2C94—C93—H93117.6
C43—C44—C45118.1 (3)C92—C93—H93117.6
C43—C44—C47121.1 (4)C93—C94—C95114.8 (16)
C45—C44—C47120.8 (4)C93—C94—C97121.3 (17)
C44—C45—C46120.5 (3)C95—C94—C97123.7 (19)
C44—C45—H45119.7C96—C95—C94121.1 (18)
C46—C45—H45119.7C96—C95—H95119.4
C41—C46—C45122.0 (3)C94—C95—H95119.4
C41—C46—H46119C91—C96—C95120.9 (14)
C45—C46—H46119C91—C96—H96119.5
C44—C47—H47A109.5C95—C96—H96119.5
C44—C47—H47B109.5C91—C92B—C93B122.5 (11)
H47A—C47—H47B109.5C91—C92B—H92B118.7
C44—C47—H47C109.5C93B—C92B—H92B118.7
H47A—C47—H47C109.5C94B—C93B—C92B116.7 (19)
H47B—C47—H47C109.5C94B—C93B—H93B121.6
C44—C47—H47D109.5C92B—C93B—H93B121.6
H47A—C47—H47D141.1C93B—C94B—C95B123 (3)
H47B—C47—H47D56.3C93B—C94B—C97B123 (3)
H47C—C47—H47D56.3C95B—C94B—C97B114 (3)
C44—C47—H47E109.5C94B—C95B—C96B118 (3)
H47A—C47—H47E56.3C94B—C95B—H95B120.9
H47B—C47—H47E141.1C96B—C95B—H95B120.9
H47C—C47—H47E56.3C91—C96B—C95B123 (2)
H47D—C47—H47E109.5C91—C96B—H96B118.3
C44—C47—H47F109.5C95B—C96B—H96B118.3
H47A—C47—H47F56.3C94B—C97B—H97D109.5
H47B—C47—H47F56.3C94B—C97B—H97E109.5
H47C—C47—H47F141.1H97D—C97B—H97E109.5
H47D—C47—H47F109.5C94B—C97B—H97F109.5
H47E—C47—H47F109.5H97D—C97B—H97F109.5
C52—C51—C56117.2 (3)H97E—C97B—H97F109.5
C52—C51—P2118.7 (2)
P2—Ag—P1—C2145.40 (11)P2—C51—C52—C53179.3 (3)
P3—Ag—P1—C21177.24 (11)C51—C52—C53—C540.9 (5)
I—Ag—P1—C2160.19 (11)C52—C53—C54—C550.6 (5)
P2—Ag—P1—C3173.21 (11)C52—C53—C54—C57178.0 (3)
P3—Ag—P1—C3158.63 (11)C53—C54—C55—C560.1 (5)
I—Ag—P1—C31178.80 (11)C57—C54—C55—C56178.4 (3)
P2—Ag—P1—C11164.53 (11)C54—C55—C56—C510.0 (6)
P3—Ag—P1—C1163.63 (12)C52—C51—C56—C550.3 (5)
I—Ag—P1—C1158.94 (11)P2—C51—C56—C55179.8 (3)
P1—Ag—P2—C4180.36 (12)C41—P2—C61—C668.3 (3)
P3—Ag—P2—C4154.29 (13)C51—P2—C61—C66117.3 (3)
I—Ag—P2—C41172.13 (12)Ag—P2—C61—C66121.3 (3)
P1—Ag—P2—C6142.91 (13)C41—P2—C61—C62173.4 (3)
P3—Ag—P2—C61177.56 (13)C51—P2—C61—C6264.4 (3)
I—Ag—P2—C6164.59 (13)Ag—P2—C61—C6257.0 (3)
P1—Ag—P2—C51160.22 (11)C66—C61—C62—C632.7 (6)
P3—Ag—P2—C5165.14 (12)P2—C61—C62—C63178.9 (3)
I—Ag—P2—C5152.71 (11)C61—C62—C63—C641.7 (7)
P1—Ag—P3—C81144.81 (11)C62—C63—C64—C650.5 (7)
P2—Ag—P3—C8183.31 (12)C62—C63—C64—C67179.2 (4)
I—Ag—P3—C8127.03 (12)C63—C64—C65—C661.7 (6)
P1—Ag—P3—C7194.22 (12)C67—C64—C65—C66179.6 (4)
P2—Ag—P3—C7137.67 (12)C62—C61—C66—C651.6 (6)
I—Ag—P3—C71148.01 (11)P2—C61—C66—C65179.9 (3)
P1—Ag—P3—C9126.03 (12)C64—C65—C66—C610.6 (6)
P2—Ag—P3—C91157.91 (11)C81—P3—C71—C72133.4 (3)
I—Ag—P3—C9191.75 (12)C91—P3—C71—C7227.8 (3)
C21—P1—C11—C1677.3 (3)Ag—P3—C71—C7298.8 (3)
C31—P1—C11—C1630.7 (4)C81—P3—C71—C7653.0 (3)
Ag—P1—C11—C16158.6 (3)C91—P3—C71—C76158.5 (3)
C21—P1—C11—C12103.3 (3)Ag—P3—C71—C7674.8 (3)
C31—P1—C11—C12148.7 (3)C76—C71—C72—C730.1 (5)
Ag—P1—C11—C1220.7 (3)P3—C71—C72—C73173.8 (3)
C16—C11—C12—C132.3 (7)C71—C72—C73—C741.1 (6)
P1—C11—C12—C13177.1 (4)C72—C73—C74—C750.5 (6)
C11—C12—C13—C140.6 (8)C72—C73—C74—C77180.0 (4)
C12—C13—C14—C151.8 (7)C73—C74—C75—C761.0 (6)
C12—C13—C14—C17179.7 (4)C77—C74—C75—C76178.5 (3)
C13—C14—C15—C162.5 (7)C74—C75—C76—C712.1 (6)
C17—C14—C15—C16179.0 (4)C72—C71—C76—C751.5 (5)
C12—C11—C16—C151.7 (6)P3—C71—C76—C75175.4 (3)
P1—C11—C16—C15177.7 (3)C71—P3—C81—C86167.5 (3)
C14—C15—C16—C110.7 (7)C91—P3—C81—C8684.5 (3)
C31—P1—C21—C22137.0 (3)Ag—P3—C81—C8642.1 (3)
C11—P1—C21—C2228.9 (3)C71—P3—C81—C8217.4 (3)
Ag—P1—C21—C2298.0 (3)C91—P3—C81—C8290.6 (3)
C31—P1—C21—C2649.2 (3)Ag—P3—C81—C82142.8 (3)
C11—P1—C21—C26157.3 (3)C86—C81—C82—C830.5 (5)
Ag—P1—C21—C2675.8 (3)P3—C81—C82—C83174.6 (3)
C26—C21—C22—C231.1 (5)C81—C82—C83—C841.5 (6)
P1—C21—C22—C23172.9 (3)C82—C83—C84—C852.1 (6)
C21—C22—C23—C240.9 (6)C82—C83—C84—C87177.9 (4)
C22—C23—C24—C250.7 (6)C83—C84—C85—C860.8 (6)
C22—C23—C24—C27178.5 (4)C87—C84—C85—C86179.2 (4)
C23—C24—C25—C262.0 (6)C82—C81—C86—C851.8 (5)
C27—C24—C25—C26177.1 (4)P3—C81—C86—C85173.7 (3)
C24—C25—C26—C211.8 (6)C84—C85—C86—C811.2 (6)
C22—C21—C26—C250.2 (5)C81—P3—C91—C96B20.8 (14)
P1—C21—C26—C25174.3 (3)C71—P3—C91—C96B87.3 (14)
C21—P1—C31—C36149.1 (3)Ag—P3—C91—C96B147.9 (14)
C11—P1—C31—C36103.3 (3)C81—P3—C91—C92B162.2 (12)
Ag—P1—C31—C3625.7 (3)C71—P3—C91—C92B89.8 (12)
C21—P1—C31—C3231.3 (3)Ag—P3—C91—C92B35.0 (12)
C11—P1—C31—C3276.2 (3)C81—P3—C91—C9655.5 (7)
Ag—P1—C31—C32154.7 (2)C71—P3—C91—C9652.5 (7)
C36—C31—C32—C330.3 (5)Ag—P3—C91—C96177.3 (6)
P1—C31—C32—C33179.3 (3)C81—P3—C91—C92117.6 (6)
C31—C32—C33—C340.1 (5)C71—P3—C91—C92134.4 (6)
C32—C33—C34—C350.4 (5)Ag—P3—C91—C929.6 (6)
C32—C33—C34—C37179.4 (4)C96B—C91—C92—C9329.6 (12)
C33—C34—C35—C360.9 (5)C92B—C91—C92—C9381.7 (13)
C37—C34—C35—C36179.8 (4)C96—C91—C92—C931.3 (9)
C34—C35—C36—C310.8 (5)P3—C91—C92—C93174.8 (5)
C32—C31—C36—C350.2 (5)C91—C92—C93—C942.0 (14)
P1—C31—C36—C35179.8 (3)C92—C93—C94—C954.5 (19)
C61—P2—C41—C46114.9 (3)C92—C93—C94—C97179.8 (11)
C51—P2—C41—C46138.1 (3)C93—C94—C95—C967 (2)
Ag—P2—C41—C4616.0 (3)C97—C94—C95—C96177.8 (13)
C61—P2—C41—C4263.4 (3)C96B—C91—C96—C9575 (3)
C51—P2—C41—C4243.5 (3)C92B—C91—C96—C9537.1 (12)
Ag—P2—C41—C42165.7 (3)C92—C91—C96—C953.6 (12)
C46—C41—C42—C430.1 (5)P3—C91—C96—C95176.6 (8)
P2—C41—C42—C43178.3 (3)C94—C95—C96—C916.4 (18)
C41—C42—C43—C441.1 (6)C96B—C91—C92B—C93B0.6 (13)
C42—C43—C44—C450.8 (6)C96—C91—C92B—C93B28.9 (12)
C42—C43—C44—C47179.2 (4)C92—C91—C92B—C93B84.5 (13)
C43—C44—C45—C460.5 (6)P3—C91—C92B—C93B176.7 (8)
C47—C44—C45—C46179.5 (4)C91—C92B—C93B—C94B0.0 (18)
C42—C41—C46—C451.2 (5)C92B—C93B—C94B—C95B4 (3)
P2—C41—C46—C45179.6 (3)C92B—C93B—C94B—C97B179.4 (16)
C44—C45—C46—C411.5 (6)C93B—C94B—C95B—C96B6 (4)
C41—P2—C51—C52100.8 (3)C97B—C94B—C95B—C96B176 (2)
C61—P2—C51—C52151.8 (3)C92B—C91—C96B—C95B2 (2)
Ag—P2—C51—C5225.0 (3)C96—C91—C96B—C95B81 (3)
C41—P2—C51—C5679.3 (3)C92—C91—C96B—C95B38 (2)
C61—P2—C51—C5628.1 (3)P3—C91—C96B—C95B179.4 (17)
Ag—P2—C51—C56154.9 (3)C94B—C95B—C96B—C916 (4)
C56—C51—C52—C530.8 (5)
 

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