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The structure of the title compound, (C36H30NP2)2[OsCl5F].H2O, has been determined by single-crystal X-ray diffraction at 208 K. The octahedral [OsCl5F]2− complex anions are completely ordered in an A2B-type lattice. The monoclinic unit cell contains four formula units, each with a solvent water molecule linked to the F ligand by a hydrogen bond [O...F 2.737 (8) Å]. The Os—F bond [1.960 (4) Å] is weakened by a trans influence and, correspondingly, the Os—Cl1 bond [2.307 (2) Å] trans to Os—F is strengthened compared with the average Os—Cl bond length along the Cl—Os—Cl axes of 2.339 Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks osfcl5, global

fcf

Structure factor file (CIF format)
Contains datablock a2

CCDC reference: 128386

-1

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