Bis[(anhydro-meso-rhodochlorinato-XV methyl ester)zinc(II)]

Senge, M.O.; Smith, K.M.

doi:10.1107/S0108270197002977

Bis[(anhydro-meso-rhodochlorinato-XV methyl ester)zinc(II)]

The title compound bis[(methyl 8,13-diethyl-2,2¹,2²,2³-tetrahydro- 3,7,12,17-tetramethyl-2³-oxo-3H-benzo[at]porphyrin-18-carboxylato-κ⁴N)- zinc(II)], [Zn(C₃₃H₃₄N₄O₃)]₂, has similar structural characteristics to the naturally occurring factor F430 and forms dimers that are held together by axial interactions between the zinc(II) center and the cyclohexanone carbonyl O atom of a neighboring macrocycle [Zn—O3 = 2.204 (3) Å]. These dimers form infinite stacks in the crystal stabilized by π–π interactions between the aromatic ring systems.

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Bis[(anhydro-meso-rhodochlorinato-XV methyl ester)zinc(II)]

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	Crystallographic Information File (CIF) Contains datablocks MS68, global
	Structure factor file (CIF format) Contains datablock ms68