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The CuII atom in the title complex, (2,2'-bipyridine-N,N')(nitrato-O)(1-phenyl-1,3-butanedionato-O,O')copper(II), [Cu(C10H9O2)(NO3)(C10H8N2)], has a square-pyramidal coordination. Both the benzoylacetone anion and the 2,2'-bipyridine ligand chelate to the CuII atom in the equatorial plane, while a nitrate anion occupies the apical site, with a longer Cu-O distance of 2.335 (4) Å. Within the delocalized enol ring of benzoylacetone, the C-C bond closest to the phenyl ring is longer than the C-C bond farthest from the phenyl ring.

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CCDC reference: 128519

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