Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229615018082/ku3165sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S2053229615018082/ku3165Isup2.hkl |
CCDC reference: 1427954
The interaction of the components in the Gd–Ni–Al system has been investigated at 1073 K in the concentration range 0–33.3 at.% Gd (Rykhal et al., 1978). The existence of two previously known compounds, GdNiAl2 (Rykhal et al., 1973) and GdNiAl (Oesterreicher, 1973), was confirmed, the formation of seven new ternary intermetallics was established, and the isothermal cross-section of the phase diagram was constructed. The crystal structures of six of the nine reported compounds are known, of which three exhibit orthorhombic symmetry [GdNiAl4 (structure type YNiAl4, Pearson symbol oS24, space group Cmcm), GdNiAl2 (MgCuAl2, oS16, Cmcm) and Gd2Ni2Al (W2CoB2, oI10, Immm)], two exhibit hexagonal symmetry [Gd3Ni8Al (Ce3Co8Si, hP24, P63/mmc) and GdNiAl (ZrNiAl, hP9, P62m)] and one exhibits cubic symmetry [Gd3Ni6Al2 (Ce3Ni6Si2, cI44, Im3m)]. For the other three compounds, of approximate compositions GdNi2Al3, ~Gd2Ni3Al7 and ~GdNi3Al16, only the cell parameters were determined. Later on, it was established that the crystal structure of GdNi2Al3 belongs to the hexagonal YNi2Al3 type (hP18, P6/mmm, composition GdNi2Al3 and GdNi2.75Al2.25; Zarechnyuk & Rykhal', 1981) or its substitution derivative YCo3Ga2 (hP18, P6/mmm, composition GdNi2.5Al2.5; Šorgić et al., 1995). The structure of the compound with nominal composition ~GdNi3Al16 was also solved and its composition was shown to be Gd3Ni5Al19, orthorhombic own structure type (oS108, Cmcm; Gladyshevskii et al., 1992).
It should be noted that four more compounds have been reported in the Gd–Ni–Al system, viz. GdNi3Al9 (Gd0.67Ni2Al6), Gd4Ni6Al23, GdNiAl3 and GdNi3Al2. The crystal structure of GdNi3Al9 was determined by X-ray single-crystal diffraction and belongs to the rhombohedral ErNi3Al9 type (hR78, R32; Gladyshevskii et al., 1993), whereas a recent investigation using X-ray powder diffraction showed the closely related partially disordered hexagonal structure type Yb0.67Ni2Al6 (hP11–2.33, P6m2, composition Gd0.67Ni2Al6; Matselko et al., 2013). The crystal structure of Gd4Ni6Al23 belongs to the monoclinic structure type Y4Ni6Al23 (mS66, C2/m; Gladyshevskii & Parthé, 1992) and that of GdNiAl3 to the orthorhombic structure type YNiAl3 (oP20, Pnma; Pukas et al., 2010a).
GdNi3Al2 exists in two modifications, i.e. the crystal structure of the room-temperature modification adopts the hexagonal structure type PrNi2Al3 (hP6, P6/mmm; Šorgić et al., 1995), whereas the crystal structure of the high-temperature modification is unknown (Pechev et al., 2000). A second modification of the equiatomic intermetallide (GdNiAl) is also known as a high-temperature high-pressure modification, the structure of which belongs to the hexagonal MgZn2 structure type (hP12, P63/mmc; Tsvyashchenko & Fomicheva, 1987).
The aim of the present work was to provide structural data for the compound with nominal composition ~Gd2Ni3Al7. A preliminary account was published as a conference abstract (Pukas et al., 2010b).
A sample of nominal composition Gd16.7Ni25.0Al58.3 was synthesized from high-purity elements (Gd ≥ 99.86 wt%, Ni ≥ 99.99 wt% and Al ≥ 99.998 wt%) by arc melting in a water-cooled copper crucible with a tungsten electrode, under a purified argon atmosphere (using Ti as a getter). The weight loss during the preparation of the alloy was less than 0.5% of the total mass, which was 1 g. The sample was annealed at 873 K in a quartz ampoule under vacuum for two months, and subsequently quenched in cold water.
A single-crystal extracted from the annealed sample was mounted on an Enraf–Nonius CAD-4 T diffractometer (Mo Kα radiation, λ = 0.71073 Å, graphite monochromator). The composition obtained from the structure refinement, i.e. Gd3Ni7Al14, differs slightly from the nominal composition of the alloy. Crystallographic data and details of the data collection and structure refinement are summarized in Table 1. The atomic coordinates were standardized by the program STRUCTURE TIDY (Gelato & Parthé, 1987).
Like the majority of the compounds in R–Ni–Al systems (where R is a rare-earth metal), the structure of Gd3Ni7Al14 is ordered. The Gd atoms occupy two Wyckoff positions, the Ni atoms occupy five Wyckoff positions and the Al atoms occupy ten Wyckoff positions. The structure belongs to a family of two-layer structures, which are characterized by at least one short translation parameter. Two kinds of monoatomic layer alternate along the short translation period. The atoms of each layer are situated at the centres of polyhedra built up of atoms of neighbouring layers. The structures can be described as an assembly of straight prisms with an equatorial mirror plane. The axes of the prisms are parallel to the short translation period. It should be mentioned that the complete coordination polyhedra also include atoms situated in the same layer as the central atoms, which cap the faces of the prisms.
A projection of the monoatomic layers in the structure of Gd3Ni7Al14 along the crystallographic [001] direction, drawn using the program ATOMS (Dowty, 1999), is presented in Fig. 1. The layers located at z = 0 and z = 1/2 can be considered as a net of triangles, squares (tetragons) and hexagons, and as a net of triangles, squares (tetragons) and pentagons, respectively.
As can be seen from Fig. 2, the Gd atoms are at the centres of hexagonal and pentagonal prisms consisting of four Ni and eight or six Al atoms, respectively. The rectangular faces of the hexagonal prisms are capped by one Ni and five Al atoms, whereas those of the pentagonal prisms are exclusively capped by Al atoms. The Ni atoms are situated in trigonal (Al4Gd2 and Al6) prisms, with an additional four to six atoms (Gd, Ni and Al) above the rectangular faces and/or edges of the prisms. In the case of the Ni atoms at site Ni5, the tricapped trigonal prisms are built up exclusively by Al atoms. The Al atoms are inside pentagonal (Ni4Al6 and Al10) and tetragonal (Ni2Al2Gd4, Ni2Al4Gd2, Al4Gd4, Ni4Al4 and Al8) prisms. The lateral faces of these prisms are capped by different atoms (Gd, Ni and Al). In the case of the Al atoms at the Al2 site, one more atom (an Ni atom), located beyond one of the edges of the tetragonal prism, is included in the coordination polyhedron.
The structure type Gd3Ni7Al14 shows structural features that have already been observed for two other ternary aluminides, namely PrNi2Al3 (hP6, P6/mmm) and ZrNiAl (hP9, P62m) (Fig. 3). Comparing these structures, one notes the similar environment of the Ni atoms, which are located inside straight trigonal prisms. In PrNi2Al3, the trigonal prisms have the composition Al6. In the ZrNiAl-type structure, the Ni atoms occupy two distinct sites at the centres of prisms consisting of six Zr atoms or six Al atoms. In Gd3Ni7Al14, the Ni atoms occupy five distinct sites.
In all the structures discussed here, the Ni-centred trigonal prisms form infinite columns (common triangular faces) along the short translation period (z axis). As can be seen from Fig. 3, in the PrNi2Al3-type structure, the Al6 trigonal prisms are connected via the prism edges in the (001) plane, forming infinite layers with six-membered rings. In such a way, hexagonal channels are formed, inside which isolated Pr atoms are situated. A similar situation is observed for the ZrNiAl-type structure, i.e. the Zr6 prisms share the prism edges and form infinite layers with six-membered rings. Inside the hexagonal channels, isolated columns of Al6 prisms are located.
In Gd3Ni7Al14, columns of Ni-centred Al4Gd2 trigonal prisms are arranged into `hexagonal tubes', with isolated columns of Al6 prisms inside the tubes. Two tubes of three per unit cell of Al4Gd2 prisms are connected via prism edges, the remaining tubes being isolated. Additional Al atoms occupy the space between the six-membered rings of trigonal prisms.
Data collection: CAD-4 EXPRESS (Enraf–Nonius, 1994); cell refinement: CAD-4 EXPRESS (Enraf–Nonius, 1994); data reduction: XCAD4 (Harms & Wocadlo, 1995); program(s) used to solve structure: SHELXL97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: ATOMS (Dowty, 1999); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2015).
Gd3Ni7Al14 | Dx = 5.554 Mg m−3 |
Mr = 1260.44 | Mo Kα radiation, λ = 0.71073 Å |
Hexagonal, P62m | Cell parameters from 25 reflections |
a = 17.966 (5) Å | θ = 5.5–12.9° |
c = 4.0448 (6) Å | µ = 22.31 mm−1 |
V = 1130.6 (7) Å3 | T = 293 K |
Z = 3 | Needle, metallic-grey |
F(000) = 1710 | 0.10 × 0.02 × 0.02 mm |
Enraf–Nonius CAD-4T diffractometer | Rint = 0.066 |
Radiation source: fine-focus sealed tube | θmax = 35.0°, θmin = 2.3° |
ω/2θ scans | h = −28→24 |
Absorption correction: multi-scan (SORTAV; Blessing, 1995) | k = −3→28 |
Tmin = 0.407, Tmax = 0.799 | l = −6→6 |
8229 measured reflections | 2 standard reflections every 120 min |
1834 independent reflections | intensity decay: 12% |
1575 reflections with I > 2σ(I) |
Refinement on F2 | 0 restraints |
Least-squares matrix: full | w = 1/[σ2(Fo2) + (0.005P)2] where P = (Fo2 + 2Fc2)/3 |
R[F2 > 2σ(F2)] = 0.023 | (Δ/σ)max < 0.001 |
wR(F2) = 0.031 | Δρmax = 1.30 e Å−3 |
S = 0.81 | Δρmin = −1.59 e Å−3 |
1834 reflections | Absolute structure: Flack x parameter determined using 647 quotients [(I+) - (I-)]/[(I+) + (I-)] (Parsons et al., 2013) |
81 parameters | Absolute structure parameter: −0.040 (17) |
Gd3Ni7Al14 | Z = 3 |
Mr = 1260.44 | Mo Kα radiation |
Hexagonal, P62m | µ = 22.31 mm−1 |
a = 17.966 (5) Å | T = 293 K |
c = 4.0448 (6) Å | 0.10 × 0.02 × 0.02 mm |
V = 1130.6 (7) Å3 |
Enraf–Nonius CAD-4T diffractometer | 1575 reflections with I > 2σ(I) |
Absorption correction: multi-scan (SORTAV; Blessing, 1995) | Rint = 0.066 |
Tmin = 0.407, Tmax = 0.799 | 2 standard reflections every 120 min |
8229 measured reflections | intensity decay: 12% |
1834 independent reflections |
R[F2 > 2σ(F2)] = 0.023 | 0 restraints |
wR(F2) = 0.031 | Δρmax = 1.30 e Å−3 |
S = 0.81 | Δρmin = −1.59 e Å−3 |
1834 reflections | Absolute structure: Flack x parameter determined using 647 quotients [(I+) - (I-)]/[(I+) + (I-)] (Parsons et al., 2013) |
81 parameters | Absolute structure parameter: −0.040 (17) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
x | y | z | Uiso*/Ueq | ||
Gd1 | 0.30680 (3) | 0.48122 (3) | 0.5000 | 0.00642 (7) | |
Gd2 | 0.20317 (3) | 0.0000 | 0.0000 | 0.00673 (10) | |
Ni1 | 0.14012 (7) | 0.22783 (7) | 0.5000 | 0.0068 (2) | |
Ni2 | 0.08542 (7) | 0.53536 (7) | 0.0000 | 0.0068 (2) | |
Ni3 | 0.15216 (7) | 0.42823 (7) | 0.0000 | 0.0068 (2) | |
Ni4 | 0.3333 | 0.6667 | 0.5000 | 0.0056 (3) | |
Ni5 | 0.0000 | 0.0000 | 0.0000 | 0.0090 (5) | |
Al1 | 0.09982 (17) | 0.34005 (19) | 0.5000 | 0.0088 (5) | |
Al2 | 0.14542 (17) | 0.50499 (16) | 0.5000 | 0.0085 (5) | |
Al3 | 0.20022 (18) | 0.32339 (18) | 0.0000 | 0.0094 (5) | |
Al4 | 0.24196 (19) | 0.58817 (19) | 0.0000 | 0.0093 (5) | |
Al5 | 0.0851 (2) | 0.0000 | 0.5000 | 0.0080 (7) | |
Al6 | 0.5127 (2) | 0.0000 | 0.5000 | 0.0096 (8) | |
Al7 | 0.7055 (2) | 0.0000 | 0.5000 | 0.0094 (7) | |
Al8 | 0.3766 (2) | 0.0000 | 0.0000 | 0.0146 (9) | |
Al9 | 0.6093 (3) | 0.0000 | 0.0000 | 0.0169 (9) | |
Al10 | 0.8590 (2) | 0.0000 | 0.0000 | 0.0098 (7) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Gd1 | 0.00689 (17) | 0.00654 (18) | 0.00604 (15) | 0.00352 (15) | 0.000 | 0.000 |
Gd2 | 0.00689 (18) | 0.0066 (3) | 0.0066 (3) | 0.00331 (14) | 0.000 | 0.000 |
Ni1 | 0.0068 (5) | 0.0063 (5) | 0.0066 (5) | 0.0028 (4) | 0.000 | 0.000 |
Ni2 | 0.0069 (5) | 0.0061 (5) | 0.0072 (5) | 0.0031 (4) | 0.000 | 0.000 |
Ni3 | 0.0066 (5) | 0.0066 (5) | 0.0075 (5) | 0.0036 (4) | 0.000 | 0.000 |
Ni4 | 0.0057 (5) | 0.0057 (5) | 0.0054 (9) | 0.0028 (2) | 0.000 | 0.000 |
Ni5 | 0.0083 (8) | 0.0083 (8) | 0.0106 (14) | 0.0041 (4) | 0.000 | 0.000 |
Al1 | 0.0092 (13) | 0.0107 (14) | 0.0081 (14) | 0.0063 (11) | 0.000 | 0.000 |
Al2 | 0.0069 (13) | 0.0069 (12) | 0.0111 (13) | 0.0029 (11) | 0.000 | 0.000 |
Al3 | 0.0088 (12) | 0.0102 (12) | 0.0080 (13) | 0.0038 (10) | 0.000 | 0.000 |
Al4 | 0.0105 (11) | 0.0098 (12) | 0.0090 (13) | 0.0061 (10) | 0.000 | 0.000 |
Al5 | 0.0079 (12) | 0.0038 (15) | 0.0111 (19) | 0.0019 (8) | 0.000 | 0.000 |
Al6 | 0.0100 (14) | 0.0116 (19) | 0.0077 (19) | 0.0058 (10) | 0.000 | 0.000 |
Al7 | 0.0089 (12) | 0.0076 (17) | 0.011 (2) | 0.0038 (9) | 0.000 | 0.000 |
Al8 | 0.0173 (16) | 0.016 (2) | 0.0100 (18) | 0.0081 (10) | 0.000 | 0.000 |
Al9 | 0.0241 (17) | 0.0095 (19) | 0.012 (2) | 0.0048 (9) | 0.000 | 0.000 |
Al10 | 0.0088 (12) | 0.0114 (19) | 0.0101 (18) | 0.0057 (9) | 0.000 | 0.000 |
Gd1—Ni4 | 3.1208 (10) | Al2—Ni2ii | 2.4774 (17) |
Gd1—Al2 | 3.135 (3) | Al2—Ni3ii | 2.4847 (17) |
Gd1—Al2i | 3.153 (3) | Al2—Al4ii | 2.596 (3) |
Gd1—Ni3ii | 3.1733 (11) | Al2—Al4 | 2.596 (3) |
Gd1—Ni3 | 3.1733 (11) | Al2—Al6vi | 2.685 (3) |
Gd1—Ni2iii | 3.1866 (10) | Al2—Gd1xiii | 3.153 (3) |
Gd1—Ni2i | 3.1866 (10) | Al3—Ni1v | 2.5199 (19) |
Gd1—Al6iv | 3.190 (2) | Al3—Al1v | 2.824 (3) |
Gd1—Al3ii | 3.220 (2) | Al3—Al7iv | 2.848 (2) |
Gd1—Al3 | 3.220 (2) | Al3—Al7xviii | 2.848 (2) |
Gd1—Al7iv | 3.250 (3) | Al3—Al10iv | 2.895 (4) |
Gd1—Al1 | 3.291 (3) | Al3—Gd2vi | 3.136 (3) |
Gd2—Al5v | 2.931 (3) | Al3—Gd1v | 3.220 (2) |
Gd2—Al5 | 2.931 (3) | Al4—Ni4v | 2.5414 (18) |
Gd2—Al1vi | 2.991 (2) | Al4—Al2v | 2.596 (3) |
Gd2—Al1vii | 2.991 (2) | Al4—Al4xiv | 2.666 (5) |
Gd2—Al1viii | 2.991 (2) | Al4—Al4i | 2.666 (5) |
Gd2—Al1ix | 2.991 (2) | Al4—Gd1v | 3.373 (2) |
Gd2—Ni1vi | 3.0834 (10) | Al4—Gd1xiii | 3.378 (2) |
Gd2—Ni1ix | 3.0834 (10) | Al4—Gd1xiv | 3.378 (2) |
Gd2—Ni1vii | 3.0835 (10) | Al5—Ni5ii | 2.535 (2) |
Gd2—Ni1viii | 3.0835 (10) | Al5—Ni1viii | 2.541 (2) |
Gd2—Al8 | 3.115 (5) | Al5—Ni1vi | 2.541 (2) |
Gd2—Al3vi | 3.136 (3) | Al5—Al5xii | 2.648 (7) |
Ni1—Al7iv | 2.410 (4) | Al5—Al5vi | 2.648 (7) |
Ni1—Al1 | 2.459 (3) | Al5—Gd2ii | 2.931 (3) |
Ni1—Al3 | 2.5199 (19) | Al5—Al10xv | 2.996 (2) |
Ni1—Al3ii | 2.5199 (19) | Al5—Al10x | 2.996 (2) |
Ni1—Al5vi | 2.541 (2) | Al5—Al10xix | 2.996 (2) |
Ni1—Al10iv | 2.5588 (14) | Al5—Al10iv | 2.996 (2) |
Ni1—Al10x | 2.5588 (14) | Al6—Ni2vii | 2.4467 (9) |
Ni1—Ni1vi | 2.729 (2) | Al6—Ni2xi | 2.4467 (9) |
Ni1—Gd2vi | 3.0835 (10) | Al6—Ni2vi | 2.4467 (9) |
Ni1—Gd2xi | 3.0835 (10) | Al6—Ni2viii | 2.4467 (9) |
Ni2—Al6ix | 2.4467 (9) | Al6—Al9 | 2.665 (4) |
Ni2—Al6vi | 2.4467 (9) | Al6—Al9ii | 2.665 (4) |
Ni2—Al8vi | 2.473 (4) | Al6—Al2viii | 2.685 (3) |
Ni2—Al2 | 2.4774 (17) | Al6—Al2vi | 2.685 (3) |
Ni2—Al2v | 2.4774 (17) | Al6—Gd1xx | 3.190 (2) |
Ni2—Al4 | 2.478 (3) | Al6—Gd1xxi | 3.190 (2) |
Ni2—Al9vi | 2.482 (5) | Al7—Ni1xxi | 2.409 (4) |
Ni2—Ni2xii | 2.658 (2) | Al7—Ni1xx | 2.410 (4) |
Ni2—Ni3 | 2.7293 (17) | Al7—Al9ii | 2.660 (4) |
Ni2—Gd1xiii | 3.1865 (10) | Al7—Al9 | 2.660 (4) |
Ni2—Gd1xiv | 3.1865 (10) | Al7—Al3xxii | 2.847 (2) |
Ni3—Al8vi | 2.4078 (15) | Al7—Al3xxi | 2.847 (2) |
Ni3—Al3 | 2.433 (3) | Al7—Al3xxiii | 2.847 (2) |
Ni3—Al1v | 2.4484 (18) | Al7—Al3xx | 2.847 (2) |
Ni3—Al1 | 2.4484 (18) | Al7—Gd1xxi | 3.250 (3) |
Ni3—Al2v | 2.4847 (17) | Al7—Gd1xx | 3.250 (3) |
Ni3—Al2 | 2.4847 (17) | Al8—Ni3vii | 2.4078 (15) |
Ni3—Al4 | 2.495 (3) | Al8—Ni3vi | 2.4078 (15) |
Ni3—Gd1v | 3.1734 (11) | Al8—Ni2vi | 2.473 (4) |
Ni4—Al4xiii | 2.5413 (18) | Al8—Ni2vii | 2.473 (4) |
Ni4—Al4xiv | 2.5413 (18) | Al8—Al1vii | 2.986 (3) |
Ni4—Al4 | 2.5414 (18) | Al8—Al1vi | 2.986 (3) |
Ni4—Al4ii | 2.5414 (18) | Al8—Al1ix | 2.986 (3) |
Ni4—Al4iii | 2.5414 (18) | Al8—Al1viii | 2.986 (3) |
Ni4—Al4i | 2.5414 (18) | Al9—Ni2vii | 2.482 (5) |
Ni4—Gd1xiii | 3.1207 (10) | Al9—Ni2vi | 2.482 (5) |
Ni4—Gd1i | 3.1208 (10) | Al9—Al7v | 2.660 (4) |
Ni5—Al10iv | 2.534 (4) | Al9—Al6v | 2.665 (4) |
Ni5—Al10xv | 2.534 (4) | Al9—Gd1xxiv | 3.3850 (7) |
Ni5—Al10xvi | 2.534 (4) | Al9—Gd1xx | 3.3850 (7) |
Ni5—Al5 | 2.535 (2) | Al9—Gd1xxi | 3.3850 (7) |
Ni5—Al5xvii | 2.535 (2) | Al9—Gd1xxv | 3.3850 (7) |
Ni5—Al5vi | 2.535 (2) | Al10—Ni5xxvi | 2.534 (4) |
Ni5—Al5v | 2.535 (2) | Al10—Ni1xx | 2.5588 (14) |
Ni5—Al5ix | 2.535 (2) | Al10—Ni1xxv | 2.5588 (14) |
Ni5—Al5xii | 2.535 (2) | Al10—Ni1xxiv | 2.5588 (14) |
Al1—Ni3ii | 2.4484 (18) | Al10—Ni1xxi | 2.5588 (14) |
Al1—Al2 | 2.650 (4) | Al10—Al3xxi | 2.895 (4) |
Al1—Al3 | 2.824 (3) | Al10—Al3xx | 2.895 (4) |
Al1—Al3ii | 2.824 (3) | Al10—Al5xxvii | 2.996 (2) |
Al1—Al8vi | 2.986 (3) | Al10—Al5xxv | 2.996 (2) |
Al1—Al8xi | 2.986 (3) | Al10—Al5xx | 2.996 (2) |
Al1—Gd2vi | 2.991 (2) | Al10—Al5xxviii | 2.996 (2) |
Al1—Gd2xi | 2.991 (2) | Al10—Gd2xxvii | 3.2396 (13) |
Ni4—Gd1—Al2 | 60.83 (5) | Al4—Al2—Gd1 | 71.41 (9) |
Ni4—Gd1—Al2i | 60.63 (5) | Al1—Al2—Gd1 | 68.75 (8) |
Al2—Gd1—Al2i | 121.45 (8) | Al6vi—Al2—Gd1 | 175.79 (12) |
Ni4—Gd1—Ni3ii | 87.92 (2) | Ni2—Al2—Gd1xiii | 67.71 (6) |
Al2—Gd1—Ni3ii | 46.39 (3) | Ni2ii—Al2—Gd1xiii | 67.71 (6) |
Al2i—Gd1—Ni3ii | 130.77 (3) | Ni3—Al2—Gd1xiii | 124.57 (5) |
Ni4—Gd1—Ni3 | 87.92 (2) | Ni3ii—Al2—Gd1xiii | 124.57 (5) |
Al2—Gd1—Ni3 | 46.39 (3) | Al4ii—Al2—Gd1xiii | 71.23 (8) |
Al2i—Gd1—Ni3 | 130.77 (3) | Al4—Al2—Gd1xiii | 71.22 (8) |
Ni3ii—Gd1—Ni3 | 79.18 (3) | Al1—Al2—Gd1xiii | 172.70 (12) |
Ni4—Gd1—Ni2iii | 87.38 (2) | Al6vi—Al2—Gd1xiii | 65.66 (8) |
Al2—Gd1—Ni2iii | 130.64 (3) | Gd1—Al2—Gd1xiii | 118.55 (8) |
Al2i—Gd1—Ni2iii | 46.00 (3) | Ni3—Al3—Ni1v | 109.30 (8) |
Ni3ii—Gd1—Ni2iii | 100.82 (3) | Ni3—Al3—Ni1 | 109.30 (8) |
Ni3—Gd1—Ni2iii | 175.30 (3) | Ni1v—Al3—Ni1 | 106.75 (12) |
Ni4—Gd1—Ni2i | 87.38 (2) | Ni3—Al3—Al1 | 54.92 (7) |
Al2—Gd1—Ni2i | 130.64 (3) | Ni1v—Al3—Al1 | 124.63 (12) |
Al2i—Gd1—Ni2i | 46.00 (3) | Ni1—Al3—Al1 | 54.45 (6) |
Ni3ii—Gd1—Ni2i | 175.30 (3) | Ni3—Al3—Al1v | 54.91 (7) |
Ni3—Gd1—Ni2i | 100.82 (3) | Ni1v—Al3—Al1v | 54.45 (7) |
Ni2iii—Gd1—Ni2i | 78.79 (3) | Ni1—Al3—Al1v | 124.63 (12) |
Ni4—Gd1—Al6iv | 110.70 (6) | Al1—Al3—Al1v | 91.49 (11) |
Al2—Gd1—Al6iv | 171.53 (7) | Ni3—Al3—Al7iv | 127.94 (7) |
Al2i—Gd1—Al6iv | 50.08 (7) | Ni1v—Al3—Al7iv | 122.49 (12) |
Ni3ii—Gd1—Al6iv | 137.13 (3) | Ni1—Al3—Al7iv | 52.92 (8) |
Ni3—Gd1—Al6iv | 137.13 (3) | Al1—Al3—Al7iv | 88.87 (5) |
Ni2iii—Gd1—Al6iv | 45.13 (3) | Al1v—Al3—Al7iv | 176.18 (15) |
Ni2i—Gd1—Al6iv | 45.13 (3) | Ni3—Al3—Al7xviii | 127.94 (7) |
Ni4—Gd1—Al3ii | 130.26 (4) | Ni1v—Al3—Al7xviii | 52.92 (8) |
Al2—Gd1—Al3ii | 86.37 (6) | Ni1—Al3—Al7xviii | 122.49 (12) |
Al2i—Gd1—Al3ii | 134.00 (5) | Al1—Al3—Al7xviii | 176.18 (15) |
Ni3ii—Gd1—Al3ii | 44.73 (5) | Al1v—Al3—Al7xviii | 88.87 (5) |
Ni3—Gd1—Al3ii | 95.17 (5) | Al7iv—Al3—Al7xviii | 90.51 (9) |
Ni2iii—Gd1—Al3ii | 88.00 (5) | Ni3—Al3—Al10iv | 143.55 (13) |
Ni2i—Gd1—Al3ii | 139.68 (6) | Ni1v—Al3—Al10iv | 55.88 (6) |
Al6iv—Gd1—Al3ii | 100.19 (7) | Ni1—Al3—Al10iv | 55.88 (6) |
Ni4—Gd1—Al3 | 130.26 (4) | Al1—Al3—Al10iv | 103.14 (9) |
Al2—Gd1—Al3 | 86.37 (6) | Al1v—Al3—Al10iv | 103.14 (9) |
Al2i—Gd1—Al3 | 134.00 (5) | Al7iv—Al3—Al10iv | 73.09 (10) |
Ni3ii—Gd1—Al3 | 95.17 (5) | Al7xviii—Al3—Al10iv | 73.09 (10) |
Ni3—Gd1—Al3 | 44.73 (5) | Ni3—Al3—Gd2vi | 78.72 (8) |
Ni2iii—Gd1—Al3 | 139.68 (6) | Ni1v—Al3—Gd2vi | 65.01 (7) |
Ni2i—Gd1—Al3 | 88.00 (5) | Ni1—Al3—Gd2vi | 65.01 (7) |
Al6iv—Gd1—Al3 | 100.19 (7) | Al1—Al3—Gd2vi | 59.97 (7) |
Al3ii—Gd1—Al3 | 77.82 (7) | Al1v—Al3—Gd2vi | 59.97 (7) |
Ni4—Gd1—Al7iv | 175.77 (6) | Al7iv—Al3—Gd2vi | 117.16 (10) |
Al2—Gd1—Al7iv | 123.40 (7) | Al7xviii—Al3—Gd2vi | 117.16 (10) |
Al2i—Gd1—Al7iv | 115.15 (9) | Al10iv—Al3—Gd2vi | 64.83 (8) |
Ni3ii—Gd1—Al7iv | 95.33 (5) | Ni3—Al3—Gd1v | 66.63 (6) |
Ni3—Gd1—Al7iv | 95.33 (5) | Ni1v—Al3—Gd1v | 87.68 (4) |
Ni2iii—Gd1—Al7iv | 89.35 (5) | Ni1—Al3—Gd1v | 165.39 (9) |
Ni2i—Gd1—Al7iv | 89.35 (5) | Al1—Al3—Gd1v | 119.13 (10) |
Al6iv—Gd1—Al7iv | 65.07 (8) | Al1v—Al3—Gd1v | 65.60 (6) |
Al3ii—Gd1—Al7iv | 52.22 (6) | Al7iv—Al3—Gd1v | 117.42 (12) |
Al3—Gd1—Al7iv | 52.22 (6) | Al7xviii—Al3—Gd1v | 64.43 (7) |
Ni4—Gd1—Al1 | 109.47 (5) | Al10iv—Al3—Gd1v | 135.79 (6) |
Al2—Gd1—Al1 | 48.65 (7) | Gd2vi—Al3—Gd1v | 125.37 (6) |
Al2i—Gd1—Al1 | 170.10 (7) | Ni3—Al3—Gd1 | 66.62 (6) |
Ni3ii—Gd1—Al1 | 44.47 (3) | Ni1v—Al3—Gd1 | 165.39 (9) |
Ni3—Gd1—Al1 | 44.47 (3) | Ni1—Al3—Gd1 | 87.68 (4) |
Ni2iii—Gd1—Al1 | 137.95 (2) | Al1—Al3—Gd1 | 65.60 (6) |
Ni2i—Gd1—Al1 | 137.95 (2) | Al1v—Al3—Gd1 | 119.12 (10) |
Al6iv—Gd1—Al1 | 139.82 (8) | Al7iv—Al3—Gd1 | 64.43 (7) |
Al3ii—Gd1—Al1 | 51.39 (5) | Al7xviii—Al3—Gd1 | 117.42 (12) |
Al3—Gd1—Al1 | 51.39 (5) | Al10iv—Al3—Gd1 | 135.79 (6) |
Al7iv—Gd1—Al1 | 74.75 (8) | Gd2vi—Al3—Gd1 | 125.37 (6) |
Al5v—Gd2—Al5 | 87.27 (10) | Gd1v—Al3—Gd1 | 77.82 (7) |
Al5v—Gd2—Al1vi | 147.65 (5) | Ni2—Al4—Ni3 | 66.57 (8) |
Al5—Gd2—Al1vi | 84.92 (6) | Ni2—Al4—Ni4 | 120.46 (7) |
Al5v—Gd2—Al1vii | 84.92 (6) | Ni3—Al4—Ni4 | 120.36 (7) |
Al5—Gd2—Al1vii | 147.65 (5) | Ni2—Al4—Ni4v | 120.46 (7) |
Al1vi—Gd2—Al1vii | 117.00 (10) | Ni3—Al4—Ni4v | 120.36 (7) |
Al5v—Gd2—Al1viii | 147.65 (5) | Ni4—Al4—Ni4v | 105.46 (11) |
Al5—Gd2—Al1viii | 84.92 (6) | Ni2—Al4—Al2 | 58.39 (8) |
Al1vi—Gd2—Al1viii | 62.58 (9) | Ni3—Al4—Al2 | 58.39 (7) |
Al1vii—Gd2—Al1viii | 85.10 (8) | Ni4—Al4—Al2 | 76.10 (5) |
Al5v—Gd2—Al1ix | 84.92 (6) | Ni4v—Al4—Al2 | 178.44 (12) |
Al5—Gd2—Al1ix | 147.65 (5) | Ni2—Al4—Al2v | 58.39 (8) |
Al1vi—Gd2—Al1ix | 85.10 (8) | Ni3—Al4—Al2v | 58.39 (7) |
Al1vii—Gd2—Al1ix | 62.58 (9) | Ni4—Al4—Al2v | 178.44 (12) |
Al1viii—Gd2—Al1ix | 117.00 (10) | Ni4v—Al4—Al2v | 76.10 (5) |
Al5v—Gd2—Ni1vi | 105.14 (4) | Al2—Al4—Al2v | 102.34 (14) |
Al5—Gd2—Ni1vi | 49.91 (3) | Ni2—Al4—Al4xiv | 116.84 (17) |
Al1vi—Gd2—Ni1vi | 47.74 (5) | Ni3—Al4—Al4xiv | 176.58 (18) |
Al1vii—Gd2—Ni1vi | 161.61 (5) | Ni4—Al4—Al4xiv | 58.37 (4) |
Al1viii—Gd2—Ni1vi | 93.54 (4) | Ni4v—Al4—Al4xiv | 58.37 (4) |
Al1ix—Gd2—Ni1vi | 102.39 (5) | Al2—Al4—Al4xiv | 122.94 (10) |
Al5v—Gd2—Ni1ix | 49.91 (3) | Al2v—Al4—Al4xiv | 122.94 (10) |
Al5—Gd2—Ni1ix | 105.14 (4) | Ni2—Al4—Al4i | 176.84 (17) |
Al1vi—Gd2—Ni1ix | 102.39 (5) | Ni3—Al4—Al4i | 116.58 (18) |
Al1vii—Gd2—Ni1ix | 93.54 (4) | Ni4—Al4—Al4i | 58.37 (4) |
Al1viii—Gd2—Ni1ix | 161.61 (5) | Ni4v—Al4—Al4i | 58.37 (4) |
Al1ix—Gd2—Ni1ix | 47.74 (5) | Al2—Al4—Al4i | 122.84 (11) |
Ni1vi—Gd2—Ni1ix | 81.97 (3) | Al2v—Al4—Al4i | 122.84 (11) |
Al5v—Gd2—Ni1vii | 49.91 (3) | Al4xiv—Al4—Al4i | 60.0 |
Al5—Gd2—Ni1vii | 105.14 (4) | Ni2—Al4—Gd1 | 115.53 (8) |
Al1vi—Gd2—Ni1vii | 161.61 (5) | Ni3—Al4—Gd1 | 63.42 (6) |
Al1vii—Gd2—Ni1vii | 47.74 (5) | Ni4—Al4—Gd1 | 61.82 (4) |
Al1viii—Gd2—Ni1vii | 102.39 (5) | Ni4v—Al4—Gd1 | 118.82 (10) |
Al1ix—Gd2—Ni1vii | 93.55 (4) | Al2—Al4—Gd1 | 61.75 (7) |
Ni1vi—Gd2—Ni1vii | 149.32 (5) | Al2v—Al4—Gd1 | 117.44 (11) |
Ni1ix—Gd2—Ni1vii | 89.98 (3) | Al4xiv—Al4—Gd1 | 114.02 (9) |
Al5v—Gd2—Ni1viii | 105.14 (4) | Al4i—Al4—Gd1 | 66.85 (10) |
Al5—Gd2—Ni1viii | 49.91 (3) | Ni2—Al4—Gd1v | 115.53 (8) |
Al1vi—Gd2—Ni1viii | 93.55 (4) | Ni3—Al4—Gd1v | 63.42 (6) |
Al1vii—Gd2—Ni1viii | 102.39 (5) | Ni4—Al4—Gd1v | 118.82 (10) |
Al1viii—Gd2—Ni1viii | 47.74 (5) | Ni4v—Al4—Gd1v | 61.82 (4) |
Al1ix—Gd2—Ni1viii | 161.61 (5) | Al2—Al4—Gd1v | 117.44 (11) |
Ni1vi—Gd2—Ni1viii | 89.98 (3) | Al2v—Al4—Gd1v | 61.75 (7) |
Ni1ix—Gd2—Ni1viii | 149.32 (5) | Al4xiv—Al4—Gd1v | 114.02 (9) |
Ni1vii—Gd2—Ni1viii | 81.97 (3) | Al4i—Al4—Gd1v | 66.85 (10) |
Al5v—Gd2—Al8 | 136.37 (5) | Gd1—Al4—Gd1v | 73.68 (6) |
Al5—Gd2—Al8 | 136.37 (5) | Ni2—Al4—Gd1xiii | 63.77 (6) |
Al1vi—Gd2—Al8 | 58.50 (5) | Ni3—Al4—Gd1xiii | 115.93 (8) |
Al1vii—Gd2—Al8 | 58.50 (5) | Ni4—Al4—Gd1xiii | 61.73 (4) |
Al1viii—Gd2—Al8 | 58.50 (5) | Ni4v—Al4—Gd1xiii | 118.63 (10) |
Al1ix—Gd2—Al8 | 58.50 (5) | Al2—Al4—Gd1xiii | 62.09 (7) |
Ni1vi—Gd2—Al8 | 105.34 (2) | Al2v—Al4—Gd1xiii | 117.69 (12) |
Ni1ix—Gd2—Al8 | 105.34 (2) | Al4xiv—Al4—Gd1xiii | 66.64 (10) |
Ni1vii—Gd2—Al8 | 105.34 (2) | Al4i—Al4—Gd1xiii | 113.86 (9) |
Ni1viii—Gd2—Al8 | 105.34 (2) | Gd1—Al4—Gd1xiii | 106.381 (19) |
Al5v—Gd2—Al3vi | 94.78 (4) | Gd1v—Al4—Gd1xiii | 179.27 (10) |
Al5—Gd2—Al3vi | 94.78 (4) | Ni2—Al4—Gd1xiv | 63.77 (6) |
Al1vi—Gd2—Al3vi | 54.82 (5) | Ni3—Al4—Gd1xiv | 115.93 (8) |
Al1vii—Gd2—Al3vi | 117.11 (6) | Ni4—Al4—Gd1xiv | 118.63 (10) |
Al1viii—Gd2—Al3vi | 117.11 (6) | Ni4v—Al4—Gd1xiv | 61.73 (4) |
Al1ix—Gd2—Al3vi | 54.82 (5) | Al2—Al4—Gd1xiv | 117.69 (12) |
Ni1vi—Gd2—Al3vi | 47.79 (3) | Al2v—Al4—Gd1xiv | 62.09 (7) |
Ni1ix—Gd2—Al3vi | 47.79 (3) | Al4xiv—Al4—Gd1xiv | 66.64 (10) |
Ni1vii—Gd2—Al3vi | 137.12 (2) | Al4i—Al4—Gd1xiv | 113.86 (9) |
Ni1viii—Gd2—Al3vi | 137.12 (2) | Gd1—Al4—Gd1xiv | 179.27 (10) |
Al8—Gd2—Al3vi | 83.38 (5) | Gd1v—Al4—Gd1xiv | 106.382 (19) |
Al7iv—Ni1—Al1 | 109.26 (10) | Gd1xiii—Al4—Gd1xiv | 73.55 (6) |
Al7iv—Ni1—Al3 | 70.53 (8) | Ni5—Al5—Ni5ii | 105.83 (14) |
Al1—Ni1—Al3 | 69.08 (7) | Ni5—Al5—Ni1viii | 108.049 (19) |
Al7iv—Ni1—Al3ii | 70.53 (8) | Ni5ii—Al5—Ni1viii | 108.049 (19) |
Al1—Ni1—Al3ii | 69.08 (7) | Ni5—Al5—Ni1vi | 108.050 (19) |
Al3—Ni1—Al3ii | 106.75 (12) | Ni5ii—Al5—Ni1vi | 108.050 (19) |
Al7iv—Ni1—Al5vi | 144.59 (10) | Ni1viii—Al5—Ni1vi | 118.16 (16) |
Al1—Ni1—Al5vi | 106.15 (11) | Ni5—Al5—Al5xii | 58.52 (6) |
Al3—Ni1—Al5vi | 123.94 (6) | Ni5ii—Al5—Al5xii | 58.52 (6) |
Al3ii—Ni1—Al5vi | 123.94 (6) | Ni1viii—Al5—Al5xii | 90.92 (8) |
Al7iv—Ni1—Al10iv | 86.93 (8) | Ni1vi—Al5—Al5xii | 150.92 (8) |
Al1—Ni1—Al10iv | 126.43 (3) | Ni5—Al5—Al5vi | 58.52 (6) |
Al3—Ni1—Al10iv | 69.50 (8) | Ni5ii—Al5—Al5vi | 58.52 (6) |
Al3ii—Ni1—Al10iv | 156.70 (10) | Ni1viii—Al5—Al5vi | 150.92 (8) |
Al5vi—Ni1—Al10iv | 71.94 (9) | Ni1vi—Al5—Al5vi | 90.92 (8) |
Al7iv—Ni1—Al10x | 86.93 (8) | Al5xii—Al5—Al5vi | 60.0 |
Al1—Ni1—Al10x | 126.43 (3) | Ni5—Al5—Gd2 | 83.45 (3) |
Al3—Ni1—Al10x | 156.70 (10) | Ni5ii—Al5—Gd2 | 170.72 (12) |
Al3ii—Ni1—Al10x | 69.50 (8) | Ni1viii—Al5—Gd2 | 68.17 (7) |
Al5vi—Ni1—Al10x | 71.94 (9) | Ni1vi—Al5—Gd2 | 68.17 (7) |
Al10iv—Ni1—Al10x | 104.44 (8) | Al5xii—Al5—Gd2 | 128.81 (4) |
Al7iv—Ni1—Ni1vi | 55.50 (6) | Al5vi—Al5—Gd2 | 128.81 (4) |
Al1—Ni1—Ni1vi | 164.77 (7) | Ni5—Al5—Gd2ii | 170.72 (12) |
Al3—Ni1—Ni1vi | 102.65 (7) | Ni5ii—Al5—Gd2ii | 83.45 (3) |
Al3ii—Ni1—Ni1vi | 102.65 (7) | Ni1viii—Al5—Gd2ii | 68.17 (7) |
Al5vi—Ni1—Ni1vi | 89.08 (8) | Ni1vi—Al5—Gd2ii | 68.17 (7) |
Al10iv—Ni1—Ni1vi | 57.77 (3) | Al5xii—Al5—Gd2ii | 128.81 (4) |
Al10x—Ni1—Ni1vi | 57.77 (3) | Al5vi—Al5—Gd2ii | 128.81 (4) |
Al7iv—Ni1—Gd2vi | 136.52 (3) | Gd2—Al5—Gd2ii | 87.27 (10) |
Al1—Ni1—Gd2vi | 64.15 (5) | Ni5—Al5—Al10xv | 53.75 (6) |
Al3—Ni1—Gd2vi | 67.19 (6) | Ni5ii—Al5—Al10xv | 119.07 (9) |
Al3ii—Ni1—Gd2vi | 131.70 (8) | Ni1viii—Al5—Al10xv | 54.30 (6) |
Al5vi—Ni1—Gd2vi | 61.92 (6) | Ni1vi—Al5—Al10xv | 132.32 (8) |
Al10iv—Ni1—Gd2vi | 69.37 (4) | Al5xii—Al5—Al10xv | 63.77 (7) |
Al10x—Ni1—Gd2vi | 133.19 (9) | Al5vi—Al5—Al10xv | 106.89 (9) |
Ni1vi—Ni1—Gd2vi | 125.63 (2) | Gd2—Al5—Al10xv | 66.26 (3) |
Al7iv—Ni1—Gd2xi | 136.52 (3) | Gd2ii—Al5—Al10xv | 121.95 (10) |
Al1—Ni1—Gd2xi | 64.15 (5) | Ni5—Al5—Al10x | 119.07 (9) |
Al3—Ni1—Gd2xi | 131.69 (8) | Ni5ii—Al5—Al10x | 53.75 (6) |
Al3ii—Ni1—Gd2xi | 67.20 (6) | Ni1viii—Al5—Al10x | 132.33 (8) |
Al5vi—Ni1—Gd2xi | 61.92 (6) | Ni1vi—Al5—Al10x | 54.31 (6) |
Al10iv—Ni1—Gd2xi | 133.19 (9) | Al5xii—Al5—Al10x | 106.89 (9) |
Al10x—Ni1—Gd2xi | 69.37 (4) | Al5vi—Al5—Al10x | 63.77 (7) |
Ni1vi—Ni1—Gd2xi | 125.63 (2) | Gd2—Al5—Al10x | 121.95 (10) |
Gd2vi—Ni1—Gd2xi | 81.97 (3) | Gd2ii—Al5—Al10x | 66.26 (3) |
Al6ix—Ni2—Al6vi | 111.50 (6) | Al10xv—Al5—Al10x | 169.97 (16) |
Al6ix—Ni2—Al8vi | 80.34 (9) | Ni5—Al5—Al10xix | 119.07 (9) |
Al6vi—Ni2—Al8vi | 80.34 (9) | Ni5ii—Al5—Al10xix | 53.75 (6) |
Al6ix—Ni2—Al2 | 160.72 (11) | Ni1viii—Al5—Al10xix | 54.30 (6) |
Al6vi—Ni2—Al2 | 66.07 (7) | Ni1vi—Al5—Al10xix | 132.32 (8) |
Al8vi—Ni2—Al2 | 80.41 (7) | Al5xii—Al5—Al10xix | 63.77 (7) |
Al6ix—Ni2—Al2v | 66.07 (7) | Al5vi—Al5—Al10xix | 106.89 (9) |
Al6vi—Ni2—Al2v | 160.72 (11) | Gd2—Al5—Al10xix | 121.95 (10) |
Al8vi—Ni2—Al2v | 80.41 (7) | Gd2ii—Al5—Al10xix | 66.26 (3) |
Al2—Ni2—Al2v | 109.44 (11) | Al10xv—Al5—Al10xix | 84.93 (8) |
Al6ix—Ni2—Al4 | 124.13 (3) | Al10x—Al5—Al10xix | 94.19 (9) |
Al6vi—Ni2—Al4 | 124.13 (3) | Ni5—Al5—Al10iv | 53.75 (6) |
Al8vi—Ni2—Al4 | 111.88 (10) | Ni5ii—Al5—Al10iv | 119.07 (9) |
Al2—Ni2—Al4 | 63.18 (7) | Ni1viii—Al5—Al10iv | 132.33 (8) |
Al2v—Ni2—Al4 | 63.19 (7) | Ni1vi—Al5—Al10iv | 54.31 (6) |
Al6ix—Ni2—Al9vi | 65.46 (9) | Al5xii—Al5—Al10iv | 106.89 (9) |
Al6vi—Ni2—Al9vi | 65.46 (9) | Al5vi—Al5—Al10iv | 63.77 (7) |
Al8vi—Ni2—Al9vi | 115.11 (9) | Gd2—Al5—Al10iv | 66.26 (3) |
Al2—Ni2—Al9vi | 124.85 (6) | Gd2ii—Al5—Al10iv | 121.95 (10) |
Al2v—Ni2—Al9vi | 124.85 (6) | Al10xv—Al5—Al10iv | 94.19 (9) |
Al4—Ni2—Al9vi | 133.02 (10) | Al10x—Al5—Al10iv | 84.93 (8) |
Al6ix—Ni2—Ni2xii | 57.10 (2) | Al10xix—Al5—Al10iv | 169.97 (16) |
Al6vi—Ni2—Ni2xii | 57.10 (2) | Ni2vii—Al6—Ni2xi | 163.05 (19) |
Al8vi—Ni2—Ni2xii | 57.49 (6) | Ni2vii—Al6—Ni2vi | 65.80 (5) |
Al2—Ni2—Ni2xii | 112.14 (6) | Ni2xi—Al6—Ni2vi | 111.50 (6) |
Al2v—Ni2—Ni2xii | 112.13 (6) | Ni2vii—Al6—Ni2viii | 111.50 (6) |
Al4—Ni2—Ni2xii | 169.36 (7) | Ni2xi—Al6—Ni2viii | 65.80 (5) |
Al9vi—Ni2—Ni2xii | 57.62 (7) | Ni2vi—Al6—Ni2viii | 163.05 (19) |
Al6ix—Ni2—Ni3 | 110.05 (9) | Ni2vii—Al6—Al9 | 57.90 (8) |
Al6vi—Ni2—Ni3 | 110.05 (9) | Ni2xi—Al6—Al9 | 136.32 (13) |
Al8vi—Ni2—Ni3 | 54.87 (6) | Ni2vi—Al6—Al9 | 57.90 (8) |
Al2—Ni2—Ni3 | 56.76 (6) | Ni2viii—Al6—Al9 | 136.32 (13) |
Al2v—Ni2—Ni3 | 56.76 (6) | Ni2vii—Al6—Al9ii | 136.32 (13) |
Al4—Ni2—Ni3 | 57.00 (8) | Ni2xi—Al6—Al9ii | 57.90 (8) |
Al9vi—Ni2—Ni3 | 169.98 (8) | Ni2vi—Al6—Al9ii | 136.32 (13) |
Ni2xii—Ni2—Ni3 | 112.36 (3) | Ni2viii—Al6—Al9ii | 57.90 (8) |
Al6ix—Ni2—Gd1xiii | 131.80 (10) | Al9—Al6—Al9ii | 98.7 (2) |
Al6vi—Ni2—Gd1xiii | 67.50 (6) | Ni2vii—Al6—Al2viii | 57.51 (5) |
Al8vi—Ni2—Gd1xiii | 140.573 (16) | Ni2xi—Al6—Al2viii | 112.24 (9) |
Al2—Ni2—Gd1xiii | 66.29 (6) | Ni2vi—Al6—Al2viii | 112.24 (9) |
Al2v—Ni2—Gd1xiii | 129.35 (7) | Ni2viii—Al6—Al2viii | 57.51 (5) |
Al4—Ni2—Gd1xiii | 71.99 (5) | Al9—Al6—Al2viii | 110.52 (5) |
Al9vi—Ni2—Gd1xiii | 72.13 (6) | Al9ii—Al6—Al2viii | 110.52 (5) |
Ni2xii—Ni2—Gd1xiii | 115.76 (2) | Ni2vii—Al6—Al2vi | 112.24 (9) |
Ni3—Ni2—Gd1xiii | 115.19 (3) | Ni2xi—Al6—Al2vi | 57.51 (5) |
Al6ix—Ni2—Gd1xiv | 67.50 (6) | Ni2vi—Al6—Al2vi | 57.51 (5) |
Al6vi—Ni2—Gd1xiv | 131.80 (10) | Ni2viii—Al6—Al2vi | 112.24 (9) |
Al8vi—Ni2—Gd1xiv | 140.573 (16) | Al9—Al6—Al2vi | 110.52 (5) |
Al2—Ni2—Gd1xiv | 129.35 (7) | Al9ii—Al6—Al2vi | 110.52 (5) |
Al2v—Ni2—Gd1xiv | 66.29 (6) | Al2viii—Al6—Al2vi | 114.87 (17) |
Al4—Ni2—Gd1xiv | 71.99 (5) | Ni2vii—Al6—Gd1xx | 122.66 (6) |
Al9vi—Ni2—Gd1xiv | 72.13 (6) | Ni2xi—Al6—Gd1xx | 67.37 (4) |
Ni2xii—Ni2—Gd1xiv | 115.76 (2) | Ni2vi—Al6—Gd1xx | 67.37 (4) |
Ni3—Ni2—Gd1xiv | 115.19 (3) | Ni2viii—Al6—Gd1xx | 122.66 (6) |
Gd1xiii—Ni2—Gd1xiv | 78.79 (3) | Al9—Al6—Gd1xx | 69.99 (7) |
Al8vi—Ni3—Al3 | 118.40 (14) | Al9ii—Al6—Gd1xx | 69.99 (7) |
Al8vi—Ni3—Al1v | 75.87 (9) | Al2viii—Al6—Gd1xx | 179.13 (14) |
Al3—Ni3—Al1v | 70.68 (7) | Al2vi—Al6—Gd1xx | 64.26 (5) |
Al8vi—Ni3—Al1 | 75.87 (9) | Ni2vii—Al6—Gd1xxi | 67.37 (4) |
Al3—Ni3—Al1 | 70.68 (7) | Ni2xi—Al6—Gd1xxi | 122.66 (6) |
Al1v—Ni3—Al1 | 111.38 (12) | Ni2vi—Al6—Gd1xxi | 122.66 (6) |
Al8vi—Ni3—Al2v | 81.54 (9) | Ni2viii—Al6—Gd1xxi | 67.37 (4) |
Al3—Ni3—Al2v | 124.36 (6) | Al9—Al6—Gd1xxi | 69.99 (7) |
Al1v—Ni3—Al2v | 64.99 (8) | Al9ii—Al6—Gd1xxi | 69.99 (7) |
Al1—Ni3—Al2v | 157.21 (10) | Al2viii—Al6—Gd1xxi | 64.26 (5) |
Al8vi—Ni3—Al2 | 81.54 (9) | Al2vi—Al6—Gd1xxi | 179.13 (14) |
Al3—Ni3—Al2 | 124.36 (6) | Gd1xx—Al6—Gd1xxi | 116.61 (12) |
Al1v—Ni3—Al2 | 157.21 (10) | Ni1xxi—Al7—Ni1xx | 68.99 (13) |
Al1—Ni3—Al2 | 64.99 (8) | Ni1xxi—Al7—Al9ii | 122.37 (7) |
Al2v—Ni3—Al2 | 108.97 (11) | Ni1xx—Al7—Al9ii | 122.37 (7) |
Al8vi—Ni3—Al4 | 113.56 (15) | Ni1xxi—Al7—Al9 | 122.37 (7) |
Al3—Ni3—Al4 | 128.04 (11) | Ni1xx—Al7—Al9 | 122.37 (7) |
Al1v—Ni3—Al4 | 124.28 (6) | Al9ii—Al7—Al9 | 99.0 (2) |
Al1—Ni3—Al4 | 124.28 (6) | Ni1xxi—Al7—Al3xxii | 102.19 (13) |
Al2v—Ni3—Al4 | 62.85 (7) | Ni1xx—Al7—Al3xxii | 56.55 (7) |
Al2—Ni3—Al4 | 62.85 (7) | Al9ii—Al7—Al3xxii | 66.05 (8) |
Al8vi—Ni3—Ni2 | 57.14 (11) | Al9—Al7—Al3xxii | 132.38 (11) |
Al3—Ni3—Ni2 | 175.54 (9) | Ni1xxi—Al7—Al3xxi | 56.55 (7) |
Al1v—Ni3—Ni2 | 107.11 (7) | Ni1xx—Al7—Al3xxi | 102.19 (13) |
Al1—Ni3—Ni2 | 107.12 (7) | Al9ii—Al7—Al3xxi | 132.38 (11) |
Al2v—Ni3—Ni2 | 56.50 (6) | Al9—Al7—Al3xxi | 66.05 (8) |
Al2—Ni3—Ni2 | 56.50 (6) | Al3xxii—Al7—Al3xxi | 156.2 (2) |
Al4—Ni3—Ni2 | 56.42 (8) | Ni1xxi—Al7—Al3xxiii | 56.55 (7) |
Al8vi—Ni3—Gd1 | 140.408 (16) | Ni1xx—Al7—Al3xxiii | 102.19 (13) |
Al3—Ni3—Gd1 | 68.65 (5) | Al9ii—Al7—Al3xxiii | 66.05 (8) |
Al1v—Ni3—Gd1 | 135.72 (7) | Al9—Al7—Al3xxiii | 132.38 (10) |
Al1—Ni3—Gd1 | 70.31 (6) | Al3xxii—Al7—Al3xxiii | 84.60 (9) |
Al2v—Ni3—Gd1 | 129.09 (7) | Al3xxi—Al7—Al3xxiii | 90.51 (9) |
Al2—Ni3—Gd1 | 65.99 (6) | Ni1xxi—Al7—Al3xx | 102.19 (13) |
Al4—Ni3—Gd1 | 71.91 (6) | Ni1xx—Al7—Al3xx | 56.55 (7) |
Ni2—Ni3—Gd1 | 114.57 (3) | Al9ii—Al7—Al3xx | 132.38 (11) |
Al8vi—Ni3—Gd1v | 140.408 (16) | Al9—Al7—Al3xx | 66.05 (8) |
Al3—Ni3—Gd1v | 68.65 (5) | Al3xxii—Al7—Al3xx | 90.51 (9) |
Al1v—Ni3—Gd1v | 70.31 (6) | Al3xxi—Al7—Al3xx | 84.60 (9) |
Al1—Ni3—Gd1v | 135.72 (7) | Al3xxiii—Al7—Al3xx | 156.2 (2) |
Al2v—Ni3—Gd1v | 65.99 (6) | Ni1xxi—Al7—Gd1xxi | 88.88 (3) |
Al2—Ni3—Gd1v | 129.09 (8) | Ni1xx—Al7—Gd1xxi | 157.87 (12) |
Al4—Ni3—Gd1v | 71.91 (6) | Al9ii—Al7—Gd1xxi | 69.06 (8) |
Ni2—Ni3—Gd1v | 114.57 (3) | Al9—Al7—Gd1xxi | 69.06 (8) |
Gd1—Ni3—Gd1v | 79.18 (3) | Al3xxii—Al7—Gd1xxi | 132.50 (7) |
Al4xiii—Ni4—Al4xiv | 105.46 (11) | Al3xxi—Al7—Gd1xxi | 63.35 (6) |
Al4xiii—Ni4—Al4 | 144.75 (4) | Al3xxiii—Al7—Gd1xxi | 63.35 (6) |
Al4xiv—Ni4—Al4 | 63.26 (9) | Al3xx—Al7—Gd1xxi | 132.50 (7) |
Al4xiii—Ni4—Al4ii | 63.26 (9) | Ni1xxi—Al7—Gd1xx | 157.87 (12) |
Al4xiv—Ni4—Al4ii | 144.75 (4) | Ni1xx—Al7—Gd1xx | 88.88 (3) |
Al4—Ni4—Al4ii | 105.46 (11) | Al9ii—Al7—Gd1xx | 69.06 (8) |
Al4xiii—Ni4—Al4iii | 63.26 (9) | Al9—Al7—Gd1xx | 69.06 (8) |
Al4xiv—Ni4—Al4iii | 144.75 (4) | Al3xxii—Al7—Gd1xx | 63.35 (6) |
Al4—Ni4—Al4iii | 144.75 (4) | Al3xxi—Al7—Gd1xx | 132.50 (7) |
Al4ii—Ni4—Al4iii | 63.26 (9) | Al3xxiii—Al7—Gd1xx | 132.50 (7) |
Al4xiii—Ni4—Al4i | 144.75 (4) | Al3xx—Al7—Gd1xx | 63.35 (6) |
Al4xiv—Ni4—Al4i | 63.26 (9) | Gd1xxi—Al7—Gd1xx | 113.25 (12) |
Al4—Ni4—Al4i | 63.26 (9) | Ni3vii—Al8—Ni3vi | 159.0 (2) |
Al4ii—Ni4—Al4i | 144.75 (4) | Ni3vii—Al8—Ni2vi | 133.02 (16) |
Al4iii—Ni4—Al4i | 105.46 (11) | Ni3vi—Al8—Ni2vi | 67.99 (6) |
Al4xiii—Ni4—Gd1xiii | 72.31 (6) | Ni3vii—Al8—Ni2vii | 67.99 (6) |
Al4xiv—Ni4—Gd1xiii | 72.31 (6) | Ni3vi—Al8—Ni2vii | 133.02 (16) |
Al4—Ni4—Gd1xiii | 72.44 (6) | Ni2vi—Al8—Ni2vii | 65.02 (12) |
Al4ii—Ni4—Gd1xiii | 72.45 (6) | Ni3vii—Al8—Al1vii | 52.68 (6) |
Al4iii—Ni4—Gd1xiii | 127.27 (5) | Ni3vi—Al8—Al1vii | 114.62 (12) |
Al4i—Ni4—Gd1xiii | 127.27 (5) | Ni2vi—Al8—Al1vii | 135.91 (8) |
Al4xiii—Ni4—Gd1i | 72.44 (6) | Ni2vii—Al8—Al1vii | 99.15 (6) |
Al4xiv—Ni4—Gd1i | 72.44 (6) | Ni3vii—Al8—Al1vi | 114.62 (12) |
Al4—Ni4—Gd1i | 127.27 (5) | Ni3vi—Al8—Al1vi | 52.68 (6) |
Al4ii—Ni4—Gd1i | 127.27 (5) | Ni2vi—Al8—Al1vi | 99.15 (6) |
Al4iii—Ni4—Gd1i | 72.31 (6) | Ni2vii—Al8—Al1vi | 135.91 (8) |
Al4i—Ni4—Gd1i | 72.31 (6) | Al1vii—Al8—Al1vi | 117.31 (18) |
Gd1xiii—Ni4—Gd1i | 120.002 (1) | Ni3vii—Al8—Al1ix | 114.62 (12) |
Al4xiii—Ni4—Gd1 | 127.27 (5) | Ni3vi—Al8—Al1ix | 52.68 (6) |
Al4xiv—Ni4—Gd1 | 127.27 (5) | Ni2vi—Al8—Al1ix | 99.15 (6) |
Al4—Ni4—Gd1 | 72.31 (6) | Ni2vii—Al8—Al1ix | 135.91 (8) |
Al4ii—Ni4—Gd1 | 72.30 (6) | Al1vii—Al8—Al1ix | 62.69 (11) |
Al4iii—Ni4—Gd1 | 72.44 (6) | Al1vi—Al8—Al1ix | 85.28 (11) |
Al4i—Ni4—Gd1 | 72.44 (6) | Ni3vii—Al8—Al1viii | 52.68 (6) |
Gd1xiii—Ni4—Gd1 | 120.0 | Ni3vi—Al8—Al1viii | 114.62 (12) |
Gd1i—Ni4—Gd1 | 120.0 | Ni2vi—Al8—Al1viii | 135.91 (8) |
Al10iv—Ni5—Al10xv | 120.0 | Ni2vii—Al8—Al1viii | 99.15 (6) |
Al10iv—Ni5—Al10xvi | 120.0 | Al1vii—Al8—Al1viii | 85.28 (11) |
Al10xv—Ni5—Al10xvi | 120.0 | Al1vi—Al8—Al1viii | 62.69 (11) |
Al10iv—Ni5—Al5 | 72.45 (3) | Al1ix—Al8—Al1viii | 117.31 (18) |
Al10xv—Ni5—Al5 | 72.45 (3) | Ni3vii—Al8—Gd2 | 79.50 (11) |
Al10xvi—Ni5—Al5 | 127.09 (7) | Ni3vi—Al8—Gd2 | 79.50 (11) |
Al10iv—Ni5—Al5xvii | 127.09 (7) | Ni2vi—Al8—Gd2 | 147.49 (6) |
Al10xv—Ni5—Al5xvii | 72.45 (3) | Ni2vii—Al8—Gd2 | 147.49 (6) |
Al10xvi—Ni5—Al5xvii | 72.45 (3) | Al1vii—Al8—Gd2 | 58.66 (9) |
Al5—Ni5—Al5xvii | 144.90 (6) | Al1vi—Al8—Gd2 | 58.66 (9) |
Al10iv—Ni5—Al5vi | 72.45 (3) | Al1ix—Al8—Gd2 | 58.66 (9) |
Al10xv—Ni5—Al5vi | 127.09 (7) | Al1viii—Al8—Gd2 | 58.66 (9) |
Al10xvi—Ni5—Al5vi | 72.45 (3) | Ni2vii—Al9—Ni2vi | 64.76 (14) |
Al5—Ni5—Al5vi | 62.97 (11) | Ni2vii—Al9—Al7v | 123.27 (7) |
Al5xvii—Ni5—Al5vi | 144.90 (6) | Ni2vi—Al9—Al7v | 123.27 (7) |
Al10iv—Ni5—Al5v | 72.45 (3) | Ni2vii—Al9—Al7 | 123.27 (7) |
Al10xv—Ni5—Al5v | 72.45 (3) | Ni2vi—Al9—Al7 | 123.27 (7) |
Al10xvi—Ni5—Al5v | 127.09 (7) | Al7v—Al9—Al7 | 99.0 (2) |
Al5—Ni5—Al5v | 105.83 (14) | Ni2vii—Al9—Al6 | 56.64 (11) |
Al5xvii—Ni5—Al5v | 62.97 (11) | Ni2vi—Al9—Al6 | 56.64 (11) |
Al5vi—Ni5—Al5v | 144.90 (6) | Al7v—Al9—Al6 | 179.9 (2) |
Al10iv—Ni5—Al5ix | 72.45 (3) | Al7—Al9—Al6 | 81.15 (9) |
Al10xv—Ni5—Al5ix | 127.09 (7) | Ni2vii—Al9—Al6v | 56.64 (11) |
Al10xvi—Ni5—Al5ix | 72.45 (3) | Ni2vi—Al9—Al6v | 56.64 (11) |
Al5—Ni5—Al5ix | 144.90 (6) | Al7v—Al9—Al6v | 81.14 (9) |
Al5xvii—Ni5—Al5ix | 62.97 (11) | Al7—Al9—Al6v | 179.9 (2) |
Al5vi—Ni5—Al5ix | 105.82 (14) | Al6—Al9—Al6v | 98.7 (2) |
Al5v—Ni5—Al5ix | 62.97 (11) | Ni2vii—Al9—Gd1xxiv | 63.63 (4) |
Al10iv—Ni5—Al5xii | 127.09 (7) | Ni2vi—Al9—Gd1xxiv | 114.49 (13) |
Al10xv—Ni5—Al5xii | 72.45 (3) | Al7v—Al9—Gd1xxiv | 63.72 (4) |
Al10xvi—Ni5—Al5xii | 72.45 (3) | Al7—Al9—Gd1xxiv | 117.75 (11) |
Al5—Ni5—Al5xii | 62.97 (11) | Al6—Al9—Gd1xxiv | 116.23 (11) |
Al5xvii—Ni5—Al5xii | 105.82 (14) | Al6v—Al9—Gd1xxiv | 62.30 (4) |
Al5vi—Ni5—Al5xii | 62.97 (11) | Ni2vii—Al9—Gd1xx | 114.49 (13) |
Al5v—Ni5—Al5xii | 144.90 (6) | Ni2vi—Al9—Gd1xx | 63.63 (4) |
Al5ix—Ni5—Al5xii | 144.90 (6) | Al7v—Al9—Gd1xx | 117.75 (11) |
Ni3ii—Al1—Ni3 | 111.38 (12) | Al7—Al9—Gd1xx | 63.72 (4) |
Ni3ii—Al1—Ni1 | 110.81 (7) | Al6—Al9—Gd1xx | 62.30 (4) |
Ni3—Al1—Ni1 | 110.81 (7) | Al6v—Al9—Gd1xx | 116.23 (11) |
Ni3ii—Al1—Al2 | 58.17 (6) | Gd1xxiv—Al9—Gd1xx | 177.98 (18) |
Ni3—Al1—Al2 | 58.17 (7) | Ni2vii—Al9—Gd1xxi | 63.63 (4) |
Ni1—Al1—Al2 | 149.71 (13) | Ni2vi—Al9—Gd1xxi | 114.49 (13) |
Ni3ii—Al1—Al3 | 126.96 (11) | Al7v—Al9—Gd1xxi | 117.75 (11) |
Ni3—Al1—Al3 | 54.40 (6) | Al7—Al9—Gd1xxi | 63.72 (4) |
Ni1—Al1—Al3 | 56.47 (7) | Al6—Al9—Gd1xxi | 62.30 (4) |
Al2—Al1—Al3 | 105.17 (10) | Al6v—Al9—Gd1xxi | 116.23 (11) |
Ni3ii—Al1—Al3ii | 54.40 (6) | Gd1xxiv—Al9—Gd1xxi | 73.376 (19) |
Ni3—Al1—Al3ii | 126.96 (11) | Gd1xx—Al9—Gd1xxi | 106.59 (2) |
Ni1—Al1—Al3ii | 56.47 (7) | Ni2vii—Al9—Gd1xxv | 114.49 (13) |
Al2—Al1—Al3ii | 105.17 (10) | Ni2vi—Al9—Gd1xxv | 63.63 (4) |
Al3—Al1—Al3ii | 91.49 (11) | Al7v—Al9—Gd1xxv | 63.72 (4) |
Ni3ii—Al1—Al8vi | 119.73 (13) | Al7—Al9—Gd1xxv | 117.75 (11) |
Ni3—Al1—Al8vi | 51.45 (5) | Al6—Al9—Gd1xxv | 116.23 (11) |
Ni1—Al1—Al8vi | 129.46 (10) | Al6v—Al9—Gd1xxv | 62.30 (4) |
Al2—Al1—Al8vi | 68.78 (10) | Gd1xxiv—Al9—Gd1xxv | 106.59 (2) |
Al3—Al1—Al8vi | 91.37 (6) | Gd1xx—Al9—Gd1xxv | 73.376 (19) |
Al3ii—Al1—Al8vi | 173.83 (13) | Gd1xxi—Al9—Gd1xxv | 177.98 (18) |
Ni3ii—Al1—Al8xi | 51.45 (5) | Ni5xxvi—Al10—Ni1xx | 107.55 (8) |
Ni3—Al1—Al8xi | 119.73 (13) | Ni5xxvi—Al10—Ni1xxv | 107.55 (8) |
Ni1—Al1—Al8xi | 129.46 (10) | Ni1xx—Al10—Ni1xxv | 104.44 (8) |
Al2—Al1—Al8xi | 68.78 (10) | Ni5xxvi—Al10—Ni1xxiv | 107.55 (8) |
Al3—Al1—Al8xi | 173.83 (13) | Ni1xx—Al10—Ni1xxiv | 144.91 (17) |
Al3ii—Al1—Al8xi | 91.37 (6) | Ni1xxv—Al10—Ni1xxiv | 64.46 (6) |
Al8vi—Al1—Al8xi | 85.28 (11) | Ni5xxvi—Al10—Ni1xxi | 107.55 (8) |
Ni3ii—Al1—Gd2vi | 165.71 (10) | Ni1xx—Al10—Ni1xxi | 64.46 (6) |
Ni3—Al1—Gd2vi | 81.48 (3) | Ni1xxv—Al10—Ni1xxi | 144.91 (17) |
Ni1—Al1—Gd2vi | 68.11 (7) | Ni1xxiv—Al10—Ni1xxi | 104.44 (8) |
Al2—Al1—Gd2vi | 129.97 (6) | Ni5xxvi—Al10—Al3xxi | 138.55 (7) |
Al3—Al1—Gd2vi | 65.21 (6) | Ni1xx—Al10—Al3xxi | 97.30 (10) |
Al3ii—Al1—Gd2vi | 123.33 (11) | Ni1xxv—Al10—Al3xxi | 97.30 (10) |
Al8vi—Al1—Gd2vi | 62.84 (8) | Ni1xxiv—Al10—Al3xxi | 54.62 (6) |
Al8xi—Al1—Gd2vi | 117.37 (9) | Ni1xxi—Al10—Al3xxi | 54.62 (6) |
Ni3ii—Al1—Gd2xi | 81.48 (3) | Ni5xxvi—Al10—Al3xx | 138.55 (7) |
Ni3—Al1—Gd2xi | 165.71 (10) | Ni1xx—Al10—Al3xx | 54.62 (6) |
Ni1—Al1—Gd2xi | 68.11 (7) | Ni1xxv—Al10—Al3xx | 54.62 (6) |
Al2—Al1—Gd2xi | 129.97 (6) | Ni1xxiv—Al10—Al3xx | 97.30 (10) |
Al3—Al1—Gd2xi | 123.33 (11) | Ni1xxi—Al10—Al3xx | 97.30 (10) |
Al3ii—Al1—Gd2xi | 65.21 (6) | Al3xxi—Al10—Al3xx | 82.90 (14) |
Al8vi—Al1—Gd2xi | 117.37 (9) | Ni5xxvi—Al10—Al5xxvii | 53.80 (8) |
Al8xi—Al1—Gd2xi | 62.84 (8) | Ni1xx—Al10—Al5xxvii | 53.75 (6) |
Gd2vi—Al1—Gd2xi | 85.10 (8) | Ni1xxv—Al10—Al5xxvii | 118.42 (7) |
Ni3ii—Al1—Gd1 | 65.22 (6) | Ni1xxiv—Al10—Al5xxvii | 161.33 (15) |
Ni3—Al1—Gd1 | 65.22 (6) | Ni1xxi—Al10—Al5xxvii | 83.12 (5) |
Ni1—Al1—Gd1 | 87.10 (8) | Al3xxi—Al10—Al5xxvii | 137.33 (3) |
Al2—Al1—Gd1 | 62.60 (9) | Al3xx—Al10—Al5xxvii | 98.63 (8) |
Al3—Al1—Gd1 | 63.01 (7) | Ni5xxvi—Al10—Al5xxv | 53.80 (8) |
Al3ii—Al1—Gd1 | 63.01 (7) | Ni1xx—Al10—Al5xxv | 161.33 (15) |
Al8vi—Al1—Gd1 | 113.71 (8) | Ni1xxv—Al10—Al5xxv | 83.12 (5) |
Al8xi—Al1—Gd1 | 113.71 (8) | Ni1xxiv—Al10—Al5xxv | 53.76 (6) |
Gd2vi—Al1—Gd1 | 128.00 (5) | Ni1xxi—Al10—Al5xxv | 118.42 (7) |
Gd2xi—Al1—Gd1 | 128.00 (5) | Al3xxi—Al10—Al5xxv | 98.63 (8) |
Ni2—Al2—Ni2ii | 109.44 (11) | Al3xx—Al10—Al5xxv | 137.33 (3) |
Ni2—Al2—Ni3 | 66.74 (4) | Al5xxvii—Al10—Al5xxv | 107.60 (15) |
Ni2ii—Al2—Ni3 | 159.06 (12) | Ni5xxvi—Al10—Al5xx | 53.80 (8) |
Ni2—Al2—Ni3ii | 159.07 (12) | Ni1xx—Al10—Al5xx | 83.12 (5) |
Ni2ii—Al2—Ni3ii | 66.74 (4) | Ni1xxv—Al10—Al5xx | 161.33 (15) |
Ni3—Al2—Ni3ii | 108.97 (11) | Ni1xxiv—Al10—Al5xx | 118.42 (7) |
Ni2—Al2—Al4ii | 138.44 (13) | Ni1xxi—Al10—Al5xx | 53.76 (6) |
Ni2ii—Al2—Al4ii | 58.42 (7) | Al3xxi—Al10—Al5xx | 98.63 (8) |
Ni3—Al2—Al4ii | 138.55 (14) | Al3xx—Al10—Al5xx | 137.33 (3) |
Ni3ii—Al2—Al4ii | 58.76 (7) | Al5xxvii—Al10—Al5xx | 52.46 (14) |
Ni2—Al2—Al4 | 58.42 (7) | Al5xxv—Al10—Al5xx | 84.93 (8) |
Ni2ii—Al2—Al4 | 138.44 (13) | Ni5xxvi—Al10—Al5xxviii | 53.80 (8) |
Ni3—Al2—Al4 | 58.76 (7) | Ni1xx—Al10—Al5xxviii | 118.42 (7) |
Ni3ii—Al2—Al4 | 138.56 (14) | Ni1xxv—Al10—Al5xxviii | 53.75 (6) |
Al4ii—Al2—Al4 | 102.34 (14) | Ni1xxiv—Al10—Al5xxviii | 83.12 (5) |
Ni2—Al2—Al1 | 108.72 (8) | Ni1xxi—Al10—Al5xxviii | 161.33 (15) |
Ni2ii—Al2—Al1 | 108.72 (8) | Al3xxi—Al10—Al5xxviii | 137.33 (3) |
Ni3—Al2—Al1 | 56.84 (6) | Al3xx—Al10—Al5xxviii | 98.63 (8) |
Ni3ii—Al2—Al1 | 56.84 (6) | Al5xxvii—Al10—Al5xxviii | 84.93 (8) |
Al4ii—Al2—Al1 | 112.80 (10) | Al5xxv—Al10—Al5xxviii | 52.46 (14) |
Al4—Al2—Al1 | 112.81 (10) | Al5xx—Al10—Al5xxviii | 107.60 (15) |
Ni2—Al2—Al6vi | 56.42 (6) | Ni5xxvi—Al10—Gd2xxvii | 77.36 (6) |
Ni2ii—Al2—Al6vi | 56.41 (6) | Ni1xx—Al10—Gd2xxvii | 62.97 (2) |
Ni3—Al2—Al6vi | 110.33 (8) | Ni1xxv—Al10—Gd2xxvii | 62.97 (2) |
Ni3ii—Al2—Al6vi | 110.33 (8) | Ni1xxiv—Al10—Gd2xxvii | 125.90 (3) |
Al4ii—Al2—Al6vi | 110.96 (10) | Ni1xxi—Al10—Gd2xxvii | 125.90 (2) |
Al4—Al2—Al6vi | 110.96 (10) | Al3xxi—Al10—Gd2xxvii | 144.09 (12) |
Al1—Al2—Al6vi | 107.04 (13) | Al3xx—Al10—Gd2xxvii | 61.18 (6) |
Ni2—Al2—Gd1 | 124.32 (6) | Al5xxvii—Al10—Gd2xxvii | 55.91 (7) |
Ni2ii—Al2—Gd1 | 124.32 (6) | Al5xxv—Al10—Gd2xxvii | 107.58 (10) |
Ni3—Al2—Gd1 | 67.62 (6) | Al5xx—Al10—Gd2xxvii | 107.58 (10) |
Ni3ii—Al2—Gd1 | 67.62 (6) | Al5xxviii—Al10—Gd2xxvii | 55.91 (7) |
Al4ii—Al2—Gd1 | 71.41 (9) |
Symmetry codes: (i) −y+1, x−y+1, z; (ii) x, y, z+1; (iii) −y+1, x−y+1, z+1; (iv) −x+1, −x+y+1, z; (v) x, y, z−1; (vi) y, x, z; (vii) −x+y, −x, −z; (viii) −x+y, −x, −z+1; (ix) y, x, z−1; (x) −x+1, −x+y+1, z+1; (xi) y, x, z+1; (xii) −x, −x+y, z; (xiii) −x+y, −x+1, −z+1; (xiv) −x+y, −x+1, −z; (xv) y, x−1, z; (xvi) x−1, y, z; (xvii) −x, −x+y, z−1; (xviii) −x+1, −x+y+1, z−1; (xix) y, x−1, z+1; (xx) −x+1, −x+y, z; (xxi) −y+1, x−y, z; (xxii) −x+1, −x+y, z+1; (xxiii) −y+1, x−y, z+1; (xxiv) −y+1, x−y, z−1; (xxv) −x+1, −x+y, z−1; (xxvi) x+1, y, z; (xxvii) y+1, x, z; (xxviii) y+1, x, z−1. |
Experimental details
Crystal data | |
Chemical formula | Gd3Ni7Al14 |
Mr | 1260.44 |
Crystal system, space group | Hexagonal, P62m |
Temperature (K) | 293 |
a, c (Å) | 17.966 (5), 4.0448 (6) |
V (Å3) | 1130.6 (7) |
Z | 3 |
Radiation type | Mo Kα |
µ (mm−1) | 22.31 |
Crystal size (mm) | 0.10 × 0.02 × 0.02 |
Data collection | |
Diffractometer | Enraf–Nonius CAD-4T diffractometer |
Absorption correction | Multi-scan (SORTAV; Blessing, 1995) |
Tmin, Tmax | 0.407, 0.799 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 8229, 1834, 1575 |
Rint | 0.066 |
(sin θ/λ)max (Å−1) | 0.807 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.023, 0.031, 0.81 |
No. of reflections | 1834 |
No. of parameters | 81 |
Δρmax, Δρmin (e Å−3) | 1.30, −1.59 |
Absolute structure | Flack x parameter determined using 647 quotients [(I+) - (I-)]/[(I+) + (I-)] (Parsons et al., 2013) |
Absolute structure parameter | −0.040 (17) |
Computer programs: CAD-4 EXPRESS (Enraf–Nonius, 1994), XCAD4 (Harms & Wocadlo, 1995), SHELXL97 (Sheldrick, 2008), SHELXL2014 (Sheldrick, 2015), ATOMS (Dowty, 1999).
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