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Two new isostructural compounds, namely heptapotassium silver tetrakis(tetraoxomolybdate), K
7–xAg
1+x(MoO
4)
4 (0 ≤
x ≤ 0.4), and heptapotassium silver tetrakis(tetraoxotungstate), K
7–xAg
1+x(WO
4)
4 (0 ≤
x ≤ 0.4), have been synthesized and found to crystallize in the polar space group
P6
3mc (
Z = 2) with the unit-cell dimensions
a = 12.4188 (2) and
c = 7.4338 (2) Å for K
6.68Ag
1.32(MoO
4)
4 (single-crystal data), and
a = 12.4912 (5) and
c = 7.4526 (3) Å for K
7Ag(WO
4)
4 (Rietveld analysis data). Both structures represent a new structure type, with characteristic [K1(
XO
4)
6] `pinwheels' of K1O
6 octahedra and six
XO
4 tetrahedra (
X = Mo, W) connected by common opposite faces into columns along the
c axes. The octahedral columns are linked to each other through Ag1O
4 tetrahedra along with the K2 and K3/Ag2 polyhedra, forming the polar rods (
Ag1O
4–
X1O
4–empty octahedron–Ag1O
4). Ag1 is located almost at the centre of the largest face of its coordination tetrahedron and seems to have some mobility. The new structure type is related to the Ba
6Nd
2Al
4O
15 and CaBaSiO
4 types, and to other structures of the α-K
2SO
4–glaserite family. The differential scanning calorimetry (DSC) and second harmonic generation (SHG) results show that both compounds undergo first-order phase transformations to high-temperature centrosymmetric phases.
Supporting information
CCDC reference: 1582528
Data collection: APEX2 (Bruker, 2004) for (I). Cell refinement: SAINT (Bruker, 2004) for (I); GSAS (Larson & von Dreele, 2004) for K7Ag(WO4)4. Data reduction: SAINT (Bruker, 2004) for (I); GSAS (Larson & von Dreele, 2004) for K7Ag(WO4)4. Program(s) used to solve structure: SHELXS97 (Sheldrick, 2008) for (I); GSAS (Larson & von Dreele, 2004) for K7Ag(WO4)4. Program(s) used to refine structure: SHELXL2017 (Sheldrick, 2015) for (I); GSAS (Larson & von Dreele, 2004) for K7Ag(WO4)4. For both structures, molecular graphics: DIAMOND (Brandenburg, 2008). Software used to prepare material for publication: SHELXL2017 (Sheldrick, 2015) for (I); GSAS (Larson & von Dreele, 2004) for K7Ag(WO4)4.
Heptapotassium silver tetrakis(tetraoxomolybdate) (I)
top
Crystal data top
K6.68Ag1.32Mo4O16 | Dx = 3.490 Mg m−3 |
Mr = 1043.34 | Mo Kα radiation, λ = 0.71073 Å |
Hexagonal, P63mc | Cell parameters from 9592 reflections |
Hall symbol: P 6c -2c | θ = 3.8–31.5° |
a = 12.4188 (2) Å | µ = 5.20 mm−1 |
c = 7.4338 (2) Å | T = 296 K |
V = 992.89 (4) Å3 | Fragment, colourless |
Z = 2 | 0.25 × 0.20 × 0.18 mm |
F(000) = 969.8 | |
Data collection top
Bruker–Nonius X8 APEX CCD area-detector diffractometer | 1189 independent reflections |
Radiation source: fine-focus sealed tube | 1178 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.033 |
Detector resolution: 25 pixels mm-1 | θmax = 31.5°, θmin = 3.8° |
φ and ω scans | h = −16→18 |
Absorption correction: multi-scan (SADABS; Bruker, 2004) | k = −18→11 |
Tmin = 0.356, Tmax = 0.455 | l = −10→8 |
9592 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.018 | w = 1/[σ2(Fo2) + 2.0336P] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.040 | (Δ/σ)max < 0.001 |
S = 1.12 | Δρmax = 1.40 e Å−3 |
1189 reflections | Δρmin = −1.31 e Å−3 |
65 parameters | Absolute structure: Refined as an inversion twin |
0 restraints | Absolute structure parameter: 0.15 (8) |
Special details top
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Mo1 | 0.333333 | 0.666667 | 0.2815 (3) | 0.01895 (17) | |
Mo2 | 0.33981 (4) | 0.16990 (2) | 0.1711 (3) | 0.01329 (9) | |
K1 | 0.000000 | 0.000000 | 0.000000 | 0.0188 (4) | |
K2 | 0.17108 (6) | 0.34216 (13) | 0.1756 (4) | 0.0251 (2) | |
K3 | 0.5161 (4) | 0.4839 (4) | 0.3916 (8) | 0.0254 (6) | 0.894 (5) |
Ag1 | 0.666667 | 0.333333 | 0.3296 (3) | 0.0274 (2) | |
Ag2 | 0.5074 (12) | 0.4926 (12) | 0.428 (4) | 0.055 (8) | 0.106 (5) |
O1 | 0.333333 | 0.666667 | 0.522 (2) | 0.079 (5) | |
O2 | 0.4100 (2) | 0.5900 (2) | 0.2003 (8) | 0.0345 (11) | |
O3 | 0.3559 (4) | 0.2931 (4) | 0.0376 (7) | 0.0450 (9) | |
O4 | 0.1885 (4) | 0.0943 (2) | 0.2621 (7) | 0.0339 (10) | |
O5 | 0.4512 (4) | 0.22559 (18) | 0.3471 (7) | 0.0308 (9) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Mo1 | 0.0198 (2) | 0.0198 (2) | 0.0172 (4) | 0.00991 (11) | 0.000 | 0.000 |
Mo2 | 0.01140 (16) | 0.01374 (13) | 0.01394 (18) | 0.00570 (8) | 0.00047 (18) | 0.00024 (9) |
K1 | 0.0205 (5) | 0.0205 (5) | 0.0153 (10) | 0.0102 (3) | 0.000 | 0.000 |
K2 | 0.0238 (4) | 0.0301 (6) | 0.0237 (6) | 0.0150 (3) | 0.0017 (3) | 0.0034 (7) |
K3 | 0.0185 (7) | 0.0185 (7) | 0.0383 (15) | 0.0087 (9) | −0.0027 (5) | 0.0027 (5) |
Ag1 | 0.0259 (2) | 0.0259 (2) | 0.0305 (6) | 0.01293 (12) | 0.000 | 0.000 |
Ag2 | 0.037 (6) | 0.037 (6) | 0.089 (18) | 0.018 (4) | −0.012 (5) | 0.012 (5) |
O1 | 0.080 (7) | 0.080 (7) | 0.079 (14) | 0.040 (3) | 0.000 | 0.000 |
O2 | 0.0373 (19) | 0.0373 (19) | 0.039 (3) | 0.026 (2) | 0.0027 (10) | −0.0027 (10) |
O3 | 0.0446 (19) | 0.045 (2) | 0.057 (2) | 0.0306 (17) | 0.014 (2) | 0.030 (2) |
O4 | 0.0142 (17) | 0.047 (2) | 0.030 (2) | 0.0071 (9) | 0.0049 (17) | 0.0024 (9) |
O5 | 0.0158 (17) | 0.046 (2) | 0.0199 (19) | 0.0079 (9) | −0.0025 (15) | −0.0012 (8) |
Geometric parameters (Å, º) top
Mo1—O2 | 1.757 (5) | K2—O2i | 3.0296 (13) |
Mo1—O2i | 1.757 (5) | K2—O3xiv | 3.051 (6) |
Mo1—O2ii | 1.757 (5) | K2—O3xv | 3.051 (6) |
Mo1—O1 | 1.786 (18) | K2—O4 | 3.2567 (17) |
Mo1—Ag1iii | 3.3592 (12) | K2—O4xi | 3.2567 (17) |
Mo1—K2i | 3.5777 (15) | K2—O4x | 3.489 (6) |
Mo1—K2ii | 3.5777 (15) | K2—Ag2iii | 3.916 (18) |
Mo1—K2 | 3.5777 (15) | K2—Ag2x | 3.917 (18) |
Mo1—Ag2ii | 3.90 (3) | K2—K3iii | 3.978 (5) |
Mo1—Ag2i | 3.90 (3) | K2—K3x | 3.978 (5) |
Mo1—Ag2 | 3.90 (3) | K3—O3xvi | 2.640 (5) |
Mo1—K3ii | 4.016 (8) | K3—O3xiv | 2.640 (5) |
Mo2—O3iv | 1.750 (3) | K3—O2 | 2.689 (9) |
Mo2—O3 | 1.750 (3) | K3—O2xvi | 2.791 (9) |
Mo2—O4 | 1.762 (4) | K3—O5 | 2.909 (6) |
Mo2—O5 | 1.774 (4) | K3—O5xvii | 2.909 (6) |
Mo2—K2v | 3.6675 (7) | K3—Ag1 | 3.271 (7) |
Mo2—K2 | 3.6675 (7) | K3—O3xviii | 3.433 (7) |
Mo2—K2vi | 3.683 (3) | K3—O3 | 3.433 (7) |
Mo2—Ag1 | 3.7077 (6) | K3—Ag2iii | 3.48 (3) |
Mo2—K2vii | 3.751 (3) | K3—K3xvi | 3.781 (3) |
Mo2—K3viii | 3.761 (4) | K3—K3iii | 3.781 (3) |
Mo2—K3 | 3.761 (4) | K3—Ag2xvi | 4.02 (3) |
Mo2—K1 | 3.8695 (8) | Ag1—O1iii | 2.289 (17) |
K1—O4ix | 2.690 (5) | Ag1—O5 | 2.321 (4) |
K1—O4x | 2.690 (5) | Ag1—O5viii | 2.321 (4) |
K1—O4vi | 2.690 (5) | Ag1—O5xvii | 2.321 (4) |
K1—O4v | 2.812 (5) | Ag1—O2xvi | 3.212 (6) |
K1—O4 | 2.812 (5) | Ag1—O2xix | 3.212 (6) |
K1—O4xi | 2.812 (5) | Ag1—O2vii | 3.212 (6) |
K1—K1ix | 3.7169 (1) | Ag1—Ag2 | 3.50 (3) |
K1—K1xii | 3.7169 (1) | Ag1—Ag2xvii | 3.50 (3) |
K1—K2 | 3.9046 (17) | Ag1—Ag2viii | 3.50 (3) |
K1—K2xi | 3.9046 (17) | Ag2—O3xvi | 2.470 (12) |
K1—K2v | 3.9046 (17) | Ag2—O3xiv | 2.470 (12) |
K1—K2ix | 4.400 (2) | Ag2—O2xvi | 2.69 (3) |
K1—K2x | 4.400 (2) | Ag2—O2 | 2.69 (3) |
K1—K2vi | 4.400 (2) | Ag2—O5 | 3.088 (19) |
K2—O5x | 2.709 (5) | Ag2—O5xvii | 3.088 (19) |
K2—O3xiii | 2.844 (4) | Ag2—Ag2iii | 3.730 (4) |
K2—O3 | 2.844 (4) | Ag2—Ag2xvi | 3.730 (4) |
K2—O2 | 3.0295 (13) | | |
| | | |
O2—Mo1—O2i | 108.84 (19) | O5xvii—K3—K2xvi | 42.92 (12) |
O2—Mo1—O2ii | 108.84 (19) | Ag1—K3—K2xvi | 72.73 (12) |
O2i—Mo1—O2ii | 108.83 (19) | O3xviii—K3—K2xvi | 83.60 (9) |
O2—Mo1—O1 | 110.10 (19) | O3—K3—K2xvi | 148.6 (2) |
O2i—Mo1—O1 | 110.10 (19) | Ag2iii—K3—K2xvi | 125.42 (16) |
O2ii—Mo1—O1 | 110.10 (19) | Mo2xvii—K3—K2xvi | 57.89 (6) |
O2—Mo1—Ag1iii | 69.90 (19) | Mo2—K3—K2xvi | 134.3 (2) |
O2i—Mo1—Ag1iii | 69.90 (19) | K3xvi—K3—K2xvi | 63.07 (11) |
O2ii—Mo1—Ag1iii | 69.90 (19) | K3iii—K3—K2xvi | 126.20 (11) |
O1—Mo1—Ag1iii | 180.0 | O3xvi—K3—K2vii | 123.7 (2) |
O2—Mo1—K2i | 147.2 (2) | O3xiv—K3—K2vii | 45.56 (11) |
O2i—Mo1—K2i | 57.746 (17) | O2—K3—K2vii | 126.82 (12) |
O2ii—Mo1—K2i | 57.746 (18) | O2xvi—K3—K2vii | 49.45 (8) |
O1—Mo1—K2i | 102.71 (5) | O5—K3—K2vii | 42.92 (12) |
Ag1iii—Mo1—K2i | 77.29 (5) | O5xvii—K3—K2vii | 108.4 (2) |
O2—Mo1—K2ii | 57.747 (18) | Ag1—K3—K2vii | 72.73 (12) |
O2i—Mo1—K2ii | 147.2 (2) | O3xviii—K3—K2vii | 148.6 (2) |
O2ii—Mo1—K2ii | 57.749 (18) | O3—K3—K2vii | 83.60 (9) |
O1—Mo1—K2ii | 102.71 (5) | Ag2iii—K3—K2vii | 125.42 (16) |
Ag1iii—Mo1—K2ii | 77.29 (5) | Mo2xvii—K3—K2vii | 134.3 (2) |
K2i—Mo1—K2ii | 115.30 (4) | Mo2—K3—K2vii | 57.89 (6) |
O2—Mo1—K2 | 57.747 (18) | K3xvi—K3—K2vii | 63.07 (11) |
O2i—Mo1—K2 | 57.749 (18) | K3iii—K3—K2vii | 126.20 (11) |
O2ii—Mo1—K2 | 147.2 (2) | K2xvi—K3—K2vii | 98.90 (16) |
O1—Mo1—K2 | 102.71 (5) | O3xvi—K3—Mo1 | 72.85 (18) |
Ag1iii—Mo1—K2 | 77.29 (5) | O3xiv—K3—Mo1 | 72.85 (18) |
K2i—Mo1—K2 | 115.30 (4) | O2—K3—Mo1 | 20.18 (13) |
K2ii—Mo1—K2 | 115.30 (4) | O2xvi—K3—Mo1 | 136.4 (2) |
O2—Mo1—Ag2ii | 123.16 (10) | O5—K3—Mo1 | 132.59 (14) |
O2i—Mo1—Ag2ii | 123.16 (9) | O5xvii—K3—Mo1 | 132.59 (14) |
O2ii—Mo1—Ag2ii | 36.4 (4) | Ag1—K3—Mo1 | 160.15 (19) |
O1—Mo1—Ag2ii | 73.7 (4) | O3xviii—K3—Mo1 | 86.41 (15) |
Ag1iii—Mo1—Ag2ii | 106.3 (4) | O3—K3—Mo1 | 86.41 (15) |
K2i—Mo1—Ag2ii | 66.01 (14) | Ag2iii—K3—Mo1 | 69.9 (3) |
K2ii—Mo1—Ag2ii | 66.01 (15) | Mo2xvii—K3—Mo1 | 107.25 (13) |
K2—Mo1—Ag2ii | 176.4 (4) | Mo2—K3—Mo1 | 107.25 (13) |
O2—Mo1—Ag2i | 123.16 (10) | K3xvi—K3—Mo1 | 91.2 (3) |
O2i—Mo1—Ag2i | 36.4 (4) | K3iii—K3—Mo1 | 67.7 (2) |
O2ii—Mo1—Ag2i | 123.16 (10) | K2xvi—K3—Mo1 | 118.41 (12) |
O1—Mo1—Ag2i | 73.7 (4) | K2vii—K3—Mo1 | 118.41 (12) |
Ag1iii—Mo1—Ag2i | 106.3 (4) | O3xvi—K3—Ag2xvi | 62.8 (2) |
K2i—Mo1—Ag2i | 66.01 (15) | O3xiv—K3—Ag2xvi | 62.8 (2) |
K2ii—Mo1—Ag2i | 176.4 (4) | O2—K3—Ag2xvi | 114.7 (3) |
K2—Mo1—Ag2i | 66.01 (15) | O2xvi—K3—Ag2xvi | 41.9 (4) |
Ag2ii—Mo1—Ag2i | 112.5 (3) | O5—K3—Ag2xvi | 101.7 (2) |
O2—Mo1—Ag2 | 36.4 (4) | O5xvii—K3—Ag2xvi | 101.7 (2) |
O2i—Mo1—Ag2 | 123.16 (10) | Ag1—K3—Ag2xvi | 105.3 (3) |
O2ii—Mo1—Ag2 | 123.16 (10) | O3xviii—K3—Ag2xvi | 140.59 (9) |
O1—Mo1—Ag2 | 73.7 (4) | O3—K3—Ag2xvi | 140.59 (9) |
Ag1iii—Mo1—Ag2 | 106.3 (4) | Ag2iii—K3—Ag2xvi | 164.4 (6) |
K2i—Mo1—Ag2 | 176.4 (4) | Mo2xvii—K3—Ag2xvi | 118.80 (13) |
K2ii—Mo1—Ag2 | 66.01 (15) | Mo2—K3—Ag2xvi | 118.80 (13) |
K2—Mo1—Ag2 | 66.01 (14) | K3xvi—K3—Ag2xvi | 3.4 (5) |
Ag2ii—Mo1—Ag2 | 112.5 (3) | K3iii—K3—Ag2xvi | 162.22 (15) |
Ag2i—Mo1—Ag2 | 112.5 (3) | K2xvi—K3—Ag2xvi | 61.35 (19) |
O2—Mo1—K3ii | 121.99 (3) | K2vii—K3—Ag2xvi | 61.35 (19) |
O2i—Mo1—K3ii | 121.99 (3) | Mo1—K3—Ag2xvi | 94.5 (3) |
O2ii—Mo1—K3ii | 31.9 (2) | O3xvi—K3—K2ii | 48.70 (15) |
O1—Mo1—K3ii | 78.24 (9) | O3xiv—K3—K2ii | 124.7 (3) |
Ag1iii—Mo1—K3ii | 101.76 (9) | O2—K3—K2ii | 48.24 (8) |
K2i—Mo1—K3ii | 64.36 (3) | O2xvi—K3—K2ii | 129.16 (10) |
K2ii—Mo1—K3ii | 64.36 (3) | O5—K3—K2ii | 148.6 (2) |
K2—Mo1—K3ii | 179.05 (11) | O5xvii—K3—K2ii | 80.01 (10) |
Ag2ii—Mo1—K3ii | 4.5 (4) | Ag1—K3—K2ii | 118.51 (12) |
Ag2i—Mo1—K3ii | 114.38 (12) | O3xviii—K3—K2ii | 43.60 (9) |
Ag2—Mo1—K3ii | 114.38 (12) | O3—K3—K2ii | 102.76 (17) |
O3iv—Mo2—O3 | 109.7 (3) | Ag2iii—K3—K2ii | 62.01 (19) |
O3iv—Mo2—O4 | 108.00 (14) | Mo2xvii—K3—K2ii | 55.76 (5) |
O3—Mo2—O4 | 108.00 (14) | Mo2—K3—K2ii | 129.94 (17) |
O3iv—Mo2—O5 | 110.59 (17) | K3xvi—K3—K2ii | 106.9 (2) |
O3—Mo2—O5 | 110.59 (17) | K3iii—K3—K2ii | 60.83 (14) |
O4—Mo2—O5 | 109.9 (2) | K2xvi—K3—K2ii | 81.17 (4) |
O3iv—Mo2—K2v | 48.97 (14) | K2vii—K3—K2ii | 167.8 (2) |
O3—Mo2—K2v | 139.87 (17) | Mo1—K3—K2ii | 52.58 (9) |
O4—Mo2—K2v | 62.59 (5) | Ag2xvi—K3—K2ii | 108.94 (16) |
O5—Mo2—K2v | 109.11 (7) | O3xvi—K3—K2 | 124.7 (3) |
O3iv—Mo2—K2 | 139.87 (17) | O3xiv—K3—K2 | 48.70 (15) |
O3—Mo2—K2 | 48.97 (14) | O2—K3—K2 | 48.24 (8) |
O4—Mo2—K2 | 62.59 (5) | O2xvi—K3—K2 | 129.16 (10) |
O5—Mo2—K2 | 109.11 (7) | O5—K3—K2 | 80.01 (10) |
K2v—Mo2—K2 | 120.68 (4) | O5xvii—K3—K2 | 148.6 (2) |
O3iv—Mo2—K2vi | 55.40 (17) | Ag1—K3—K2 | 118.51 (12) |
O3—Mo2—K2vi | 55.40 (17) | O3xviii—K3—K2 | 102.76 (17) |
O4—Mo2—K2vi | 112.99 (17) | O3—K3—K2 | 43.60 (9) |
O5—Mo2—K2vi | 137.14 (15) | Ag2iii—K3—K2 | 62.01 (19) |
K2v—Mo2—K2vi | 90.72 (5) | Mo2xvii—K3—K2 | 129.94 (17) |
K2—Mo2—K2vi | 90.72 (5) | Mo2—K3—K2 | 55.76 (5) |
O3iv—Mo2—Ag1 | 94.97 (14) | K3xvi—K3—K2 | 106.9 (2) |
O3—Mo2—Ag1 | 94.97 (14) | K3iii—K3—K2 | 60.83 (14) |
O4—Mo2—Ag1 | 138.87 (17) | K2xvi—K3—K2 | 167.8 (2) |
O5—Mo2—Ag1 | 29.00 (15) | K2vii—K3—K2 | 81.17 (4) |
K2v—Mo2—Ag1 | 117.79 (2) | Mo1—K3—K2 | 52.58 (9) |
K2—Mo2—Ag1 | 117.79 (2) | Ag2xvi—K3—K2 | 108.94 (16) |
K2vi—Mo2—Ag1 | 108.14 (3) | K2ii—K3—K2 | 96.18 (16) |
O3iv—Mo2—K2vii | 124.50 (17) | O1iii—Ag1—O5 | 93.21 (12) |
O3—Mo2—K2vii | 124.50 (17) | O1iii—Ag1—O5viii | 93.21 (12) |
O4—Mo2—K2vii | 67.79 (17) | O5—Ag1—O5viii | 119.69 (2) |
O5—Mo2—K2vii | 42.08 (15) | O1iii—Ag1—O5xvii | 93.21 (12) |
K2v—Mo2—K2vii | 89.67 (5) | O5—Ag1—O5xvii | 119.69 (2) |
K2—Mo2—K2vii | 89.67 (5) | O5viii—Ag1—O5xvii | 119.69 (2) |
K2vi—Mo2—K2vii | 179.22 (5) | O1iii—Ag1—O2xvi | 149.08 (8) |
Ag1—Mo2—K2vii | 71.08 (3) | O5—Ag1—O2xvi | 72.27 (11) |
O3iv—Mo2—K3viii | 65.7 (2) | O5viii—Ag1—O2xvi | 117.70 (15) |
O3—Mo2—K3viii | 143.81 (15) | O5xvii—Ag1—O2xvi | 72.27 (11) |
O4—Mo2—K3viii | 107.34 (14) | O1iii—Ag1—O2xix | 149.09 (9) |
O5—Mo2—K3viii | 48.56 (11) | O5—Ag1—O2xix | 117.71 (15) |
K2v—Mo2—K3viii | 66.27 (11) | O5viii—Ag1—O2xix | 72.27 (11) |
K2—Mo2—K3viii | 153.30 (11) | O5xvii—Ag1—O2xix | 72.27 (11) |
K2vi—Mo2—K3viii | 115.61 (9) | O2xvi—Ag1—O2xix | 52.84 (14) |
Ag1—Mo2—K3viii | 51.94 (10) | O1iii—Ag1—O2vii | 149.09 (9) |
K2vii—Mo2—K3viii | 63.95 (9) | O5—Ag1—O2vii | 72.27 (11) |
O3iv—Mo2—K3 | 143.81 (15) | O5viii—Ag1—O2vii | 72.27 (11) |
O3—Mo2—K3 | 65.7 (2) | O5xvii—Ag1—O2vii | 117.70 (15) |
O4—Mo2—K3 | 107.34 (14) | O2xvi—Ag1—O2vii | 52.84 (14) |
O5—Mo2—K3 | 48.56 (11) | O2xix—Ag1—O2vii | 52.84 (14) |
K2v—Mo2—K3 | 153.30 (11) | O1iii—Ag1—K3 | 98.09 (11) |
K2—Mo2—K3 | 66.27 (11) | O5—Ag1—K3 | 59.859 (16) |
K2vi—Mo2—K3 | 115.61 (9) | O5viii—Ag1—K3 | 168.69 (17) |
Ag1—Mo2—K3 | 51.94 (11) | O5xvii—Ag1—K3 | 59.859 (16) |
K2vii—Mo2—K3 | 63.95 (9) | O2xvi—Ag1—K3 | 50.99 (14) |
K3viii—Mo2—K3 | 96.4 (2) | O2xix—Ag1—K3 | 97.67 (11) |
O3iv—Mo2—K1 | 84.65 (14) | O2vii—Ag1—K3 | 97.67 (11) |
O3—Mo2—K1 | 84.65 (14) | O1iii—Ag1—K3xvii | 98.10 (11) |
O4—Mo2—K1 | 41.78 (17) | O5—Ag1—K3xvii | 168.69 (17) |
O5—Mo2—K1 | 151.66 (15) | O5viii—Ag1—K3xvii | 59.859 (16) |
K2v—Mo2—K1 | 62.34 (2) | O5xvii—Ag1—K3xvii | 59.859 (16) |
K2—Mo2—K1 | 62.34 (2) | O2xvi—Ag1—K3xvii | 97.67 (11) |
K2vi—Mo2—K1 | 71.21 (4) | O2xix—Ag1—K3xvii | 50.99 (14) |
Ag1—Mo2—K1 | 179.35 (3) | O2vii—Ag1—K3xvii | 97.67 (11) |
K2vii—Mo2—K1 | 109.57 (4) | K3—Ag1—K3xvii | 118.05 (5) |
K3viii—Mo2—K1 | 128.27 (11) | O1iii—Ag1—K3viii | 98.10 (11) |
K3—Mo2—K1 | 128.27 (11) | O5—Ag1—K3viii | 59.859 (16) |
O4ix—K1—O4x | 81.50 (16) | O5viii—Ag1—K3viii | 59.859 (16) |
O4ix—K1—O4vi | 81.50 (16) | O5xvii—Ag1—K3viii | 168.69 (17) |
O4x—K1—O4vi | 81.50 (16) | O2xvi—Ag1—K3viii | 97.67 (11) |
O4ix—K1—O4v | 100.58 (9) | O2xix—Ag1—K3viii | 97.67 (11) |
O4x—K1—O4v | 177.23 (17) | O2vii—Ag1—K3viii | 50.99 (14) |
O4vi—K1—O4v | 100.58 (9) | K3—Ag1—K3viii | 118.05 (5) |
O4ix—K1—O4 | 177.23 (17) | K3xvii—Ag1—K3viii | 118.05 (5) |
O4x—K1—O4 | 100.58 (9) | O1iii—Ag1—Mo1xvi | 180.0 |
O4vi—K1—O4 | 100.58 (9) | O5—Ag1—Mo1xvi | 86.79 (12) |
O4v—K1—O4 | 77.28 (15) | O5viii—Ag1—Mo1xvi | 86.79 (12) |
O4ix—K1—O4xi | 100.58 (9) | O5xvii—Ag1—Mo1xvi | 86.79 (12) |
O4x—K1—O4xi | 100.58 (9) | O2xvi—Ag1—Mo1xvi | 30.91 (8) |
O4vi—K1—O4xi | 177.23 (17) | O2xix—Ag1—Mo1xvi | 30.92 (8) |
O4v—K1—O4xi | 77.28 (15) | O2vii—Ag1—Mo1xvi | 30.92 (8) |
O4—K1—O4xi | 77.28 (15) | K3—Ag1—Mo1xvi | 81.90 (11) |
O4ix—K1—K1ix | 48.91 (11) | K3xvii—Ag1—Mo1xvi | 81.90 (11) |
O4x—K1—K1ix | 48.91 (11) | K3viii—Ag1—Mo1xvi | 81.90 (11) |
O4vi—K1—K1ix | 48.91 (11) | O1iii—Ag1—Ag2 | 102.1 (5) |
O4v—K1—K1ix | 133.86 (10) | O5—Ag1—Ag2 | 60.01 (4) |
O4—K1—K1ix | 133.86 (10) | O5viii—Ag1—Ag2 | 164.7 (5) |
O4xi—K1—K1ix | 133.86 (10) | O5xvii—Ag1—Ag2 | 60.01 (4) |
O4ix—K1—K1xii | 131.09 (11) | O2xvi—Ag1—Ag2 | 47.0 (5) |
O4x—K1—K1xii | 131.09 (11) | O2xix—Ag1—Ag2 | 94.1 (4) |
O4vi—K1—K1xii | 131.09 (11) | O2vii—Ag1—Ag2 | 94.1 (4) |
O4v—K1—K1xii | 46.14 (10) | K3—Ag1—Ag2 | 4.0 (5) |
O4—K1—K1xii | 46.14 (10) | K3xvii—Ag1—Ag2 | 117.03 (10) |
O4xi—K1—K1xii | 46.14 (10) | K3viii—Ag1—Ag2 | 117.03 (10) |
K1ix—K1—K1xii | 180.0 | Mo1xvi—Ag1—Ag2 | 77.9 (5) |
O4ix—K1—Mo2v | 81.95 (6) | O1iii—Ag1—Ag2xvii | 102.1 (5) |
O4x—K1—Mo2v | 158.10 (12) | O5—Ag1—Ag2xvii | 164.7 (5) |
O4vi—K1—Mo2v | 81.96 (6) | O5viii—Ag1—Ag2xvii | 60.01 (4) |
O4v—K1—Mo2v | 24.67 (9) | O5xvii—Ag1—Ag2xvii | 60.01 (4) |
O4—K1—Mo2v | 96.48 (6) | O2xvi—Ag1—Ag2xvii | 94.1 (4) |
O4xi—K1—Mo2v | 96.48 (6) | O2xix—Ag1—Ag2xvii | 47.0 (5) |
K1ix—K1—Mo2v | 109.19 (3) | O2vii—Ag1—Ag2xvii | 94.1 (4) |
K1xii—K1—Mo2v | 70.81 (3) | K3—Ag1—Ag2xvii | 117.03 (10) |
O4ix—K1—Mo2 | 158.10 (12) | K3xvii—Ag1—Ag2xvii | 4.0 (5) |
O4x—K1—Mo2 | 81.95 (6) | K3viii—Ag1—Ag2xvii | 117.03 (10) |
O4vi—K1—Mo2 | 81.95 (6) | Mo1xvi—Ag1—Ag2xvii | 77.9 (5) |
O4v—K1—Mo2 | 96.48 (6) | Ag2—Ag1—Ag2xvii | 115.7 (3) |
O4—K1—Mo2 | 24.67 (9) | O1iii—Ag1—Ag2viii | 102.1 (5) |
O4xi—K1—Mo2 | 96.48 (6) | O5—Ag1—Ag2viii | 60.01 (4) |
K1ix—K1—Mo2 | 109.19 (3) | O5viii—Ag1—Ag2viii | 60.01 (4) |
K1xii—K1—Mo2 | 70.81 (3) | O5xvii—Ag1—Ag2viii | 164.7 (5) |
Mo2v—K1—Mo2 | 109.76 (3) | O2xvi—Ag1—Ag2viii | 94.1 (4) |
O4ix—K1—Mo2xi | 81.96 (6) | O2xix—Ag1—Ag2viii | 94.1 (4) |
O4x—K1—Mo2xi | 81.96 (6) | O2vii—Ag1—Ag2viii | 47.0 (5) |
O4vi—K1—Mo2xi | 158.10 (12) | K3—Ag1—Ag2viii | 117.03 (10) |
O4v—K1—Mo2xi | 96.47 (6) | K3xvii—Ag1—Ag2viii | 117.03 (10) |
O4—K1—Mo2xi | 96.48 (6) | K3viii—Ag1—Ag2viii | 4.0 (5) |
O4xi—K1—Mo2xi | 24.67 (9) | Mo1xvi—Ag1—Ag2viii | 77.9 (5) |
K1ix—K1—Mo2xi | 109.19 (3) | Ag2—Ag1—Ag2viii | 115.7 (3) |
K1xii—K1—Mo2xi | 70.81 (3) | Ag2xvii—Ag1—Ag2viii | 115.7 (3) |
Mo2v—K1—Mo2xi | 109.75 (3) | O1iii—Ag1—Mo2viii | 71.468 (16) |
Mo2—K1—Mo2xi | 109.76 (3) | O5—Ag1—Mo2viii | 119.41 (4) |
O4ix—K1—K2 | 125.09 (3) | O5viii—Ag1—Mo2viii | 21.74 (12) |
O4x—K1—K2 | 60.62 (11) | O5xvii—Ag1—Mo2viii | 119.42 (4) |
O4vi—K1—K2 | 125.09 (3) | O2xvi—Ag1—Mo2viii | 139.45 (9) |
O4v—K1—K2 | 116.61 (11) | O2xix—Ag1—Mo2viii | 91.67 (5) |
O4—K1—K2 | 55.15 (3) | O2vii—Ag1—Mo2viii | 91.67 (5) |
O4xi—K1—K2 | 55.15 (3) | K3—Ag1—Mo2viii | 169.56 (11) |
K1ix—K1—K2 | 109.53 (4) | K3xvii—Ag1—Mo2viii | 64.88 (5) |
K1xii—K1—K2 | 70.47 (4) | K3viii—Ag1—Mo2viii | 64.88 (5) |
Mo2v—K1—K2 | 141.28 (6) | Mo1xvi—Ag1—Mo2viii | 108.535 (16) |
Mo2—K1—K2 | 56.295 (12) | Ag2—Ag1—Mo2viii | 173.6 (5) |
Mo2xi—K1—K2 | 56.295 (12) | Ag2xvii—Ag1—Mo2viii | 66.6 (2) |
O4ix—K1—K2xi | 60.62 (11) | Ag2viii—Ag1—Mo2viii | 66.6 (2) |
O4x—K1—K2xi | 125.09 (3) | O1iii—Ag1—Mo2 | 71.466 (16) |
O4vi—K1—K2xi | 125.09 (3) | O5—Ag1—Mo2 | 21.74 (12) |
O4v—K1—K2xi | 55.15 (3) | O5viii—Ag1—Mo2 | 119.41 (4) |
O4—K1—K2xi | 116.61 (11) | O5xvii—Ag1—Mo2 | 119.41 (4) |
O4xi—K1—K2xi | 55.15 (3) | O2xvi—Ag1—Mo2 | 91.67 (5) |
K1ix—K1—K2xi | 109.53 (4) | O2xix—Ag1—Mo2 | 139.45 (9) |
K1xii—K1—K2xi | 70.47 (4) | O2vii—Ag1—Mo2 | 91.67 (5) |
Mo2v—K1—K2xi | 56.294 (12) | K3—Ag1—Mo2 | 64.88 (5) |
Mo2—K1—K2xi | 141.28 (6) | K3xvii—Ag1—Mo2 | 169.56 (11) |
Mo2xi—K1—K2xi | 56.295 (12) | K3viii—Ag1—Mo2 | 64.88 (5) |
K2—K1—K2xi | 109.41 (4) | Mo1xvi—Ag1—Mo2 | 108.533 (16) |
O4ix—K1—K2v | 125.09 (3) | Ag2—Ag1—Mo2 | 66.6 (2) |
O4x—K1—K2v | 125.09 (3) | Ag2xvii—Ag1—Mo2 | 173.6 (5) |
O4vi—K1—K2v | 60.62 (11) | Ag2viii—Ag1—Mo2 | 66.6 (2) |
O4v—K1—K2v | 55.15 (3) | Mo2viii—Ag1—Mo2 | 110.392 (16) |
O4—K1—K2v | 55.15 (3) | O1iii—Ag1—Mo2xvii | 71.466 (17) |
O4xi—K1—K2v | 116.61 (11) | O5—Ag1—Mo2xvii | 119.41 (4) |
K1ix—K1—K2v | 109.53 (4) | O5viii—Ag1—Mo2xvii | 119.42 (4) |
K1xii—K1—K2v | 70.47 (4) | O5xvii—Ag1—Mo2xvii | 21.74 (12) |
Mo2v—K1—K2v | 56.295 (12) | O2xvi—Ag1—Mo2xvii | 91.67 (5) |
Mo2—K1—K2v | 56.295 (12) | O2xix—Ag1—Mo2xvii | 91.67 (5) |
Mo2xi—K1—K2v | 141.29 (6) | O2vii—Ag1—Mo2xvii | 139.45 (9) |
K2—K1—K2v | 109.41 (4) | K3—Ag1—Mo2xvii | 64.88 (5) |
K2xi—K1—K2v | 109.41 (4) | K3xvii—Ag1—Mo2xvii | 64.88 (5) |
O4ix—K1—K2ix | 47.51 (3) | K3viii—Ag1—Mo2xvii | 169.56 (11) |
O4x—K1—K2ix | 105.67 (12) | Mo1xvi—Ag1—Mo2xvii | 108.533 (16) |
O4vi—K1—K2ix | 47.51 (3) | Ag2—Ag1—Mo2xvii | 66.6 (2) |
O4v—K1—K2ix | 77.10 (10) | Ag2xvii—Ag1—Mo2xvii | 66.6 (2) |
O4—K1—K2ix | 132.95 (2) | Ag2viii—Ag1—Mo2xvii | 173.6 (5) |
O4xi—K1—K2ix | 132.95 (2) | Mo2viii—Ag1—Mo2xvii | 110.393 (16) |
K1ix—K1—K2ix | 56.76 (4) | Mo2—Ag1—Mo2xvii | 110.392 (16) |
K1xii—K1—K2ix | 123.24 (4) | O1iii—Ag1—Mo1iii | 0.001 (1) |
Mo2v—K1—K2ix | 52.42 (3) | O5—Ag1—Mo1iii | 93.21 (12) |
Mo2—K1—K2ix | 125.107 (14) | O5viii—Ag1—Mo1iii | 93.21 (12) |
Mo2xi—K1—K2ix | 125.107 (14) | O5xvii—Ag1—Mo1iii | 93.21 (12) |
K2—K1—K2ix | 166.29 (8) | O2xvi—Ag1—Mo1iii | 149.08 (8) |
K2xi—K1—K2ix | 77.824 (15) | O2xix—Ag1—Mo1iii | 149.09 (8) |
K2v—K1—K2ix | 77.825 (15) | O2vii—Ag1—Mo1iii | 149.09 (8) |
O4ix—K1—K2x | 47.51 (3) | K3—Ag1—Mo1iii | 98.10 (11) |
O4x—K1—K2x | 47.51 (3) | K3xvii—Ag1—Mo1iii | 98.10 (11) |
O4vi—K1—K2x | 105.68 (12) | K3viii—Ag1—Mo1iii | 98.10 (11) |
O4v—K1—K2x | 132.95 (2) | Mo1xvi—Ag1—Mo1iii | 180.0 |
O4—K1—K2x | 132.95 (2) | Ag2—Ag1—Mo1iii | 102.1 (5) |
O4xi—K1—K2x | 77.10 (10) | Ag2xvii—Ag1—Mo1iii | 102.1 (5) |
K1ix—K1—K2x | 56.76 (4) | Ag2viii—Ag1—Mo1iii | 102.1 (5) |
K1xii—K1—K2x | 123.24 (4) | Mo2viii—Ag1—Mo1iii | 71.467 (16) |
Mo2v—K1—K2x | 125.106 (14) | Mo2—Ag1—Mo1iii | 71.466 (16) |
Mo2—K1—K2x | 125.107 (14) | Mo2xvii—Ag1—Mo1iii | 71.466 (16) |
Mo2xi—K1—K2x | 52.42 (3) | O1iii—Ag1—K2xix | 126.39 (4) |
K2—K1—K2x | 77.824 (15) | O5—Ag1—K2xix | 111.63 (8) |
K2xi—K1—K2x | 77.824 (15) | O5viii—Ag1—K2xix | 33.18 (12) |
K2v—K1—K2x | 166.29 (8) | O5xvii—Ag1—K2xix | 111.63 (8) |
K2ix—K1—K2x | 92.83 (5) | O2xvi—Ag1—K2xix | 84.53 (9) |
O4ix—K1—K2vi | 105.67 (12) | O2xix—Ag1—K2xix | 44.29 (3) |
O4x—K1—K2vi | 47.51 (3) | O2vii—Ag1—K2xix | 44.29 (3) |
O4vi—K1—K2vi | 47.51 (3) | K3—Ag1—K2xix | 135.52 (12) |
O4v—K1—K2vi | 132.95 (2) | K3xvii—Ag1—K2xix | 61.18 (7) |
O4—K1—K2vi | 77.10 (10) | K3viii—Ag1—K2xix | 61.18 (7) |
O4xi—K1—K2vi | 132.95 (2) | Mo1xvi—Ag1—K2xix | 53.61 (4) |
K1ix—K1—K2vi | 56.76 (4) | Ag2—Ag1—K2xix | 131.5 (5) |
K1xii—K1—K2vi | 123.24 (4) | Ag2xvii—Ag1—K2xix | 58.8 (3) |
Mo2v—K1—K2vi | 125.107 (14) | Ag2viii—Ag1—K2xix | 58.8 (3) |
Mo2—K1—K2vi | 52.42 (3) | Mo2viii—Ag1—K2xix | 54.92 (3) |
Mo2xi—K1—K2vi | 125.107 (14) | Mo2—Ag1—K2xix | 124.764 (10) |
K2—K1—K2vi | 77.824 (15) | Mo2xvii—Ag1—K2xix | 124.765 (10) |
K2xi—K1—K2vi | 166.29 (8) | Mo1iii—Ag1—K2xix | 126.39 (4) |
K2v—K1—K2vi | 77.824 (15) | O1iii—Ag1—K2xvi | 126.39 (4) |
K2ix—K1—K2vi | 92.83 (5) | O5—Ag1—K2xvi | 111.63 (8) |
K2x—K1—K2vi | 92.83 (5) | O5viii—Ag1—K2xvi | 111.63 (8) |
O5x—K2—O3xiii | 75.82 (11) | O5xvii—Ag1—K2xvi | 33.18 (12) |
O5x—K2—O3 | 75.82 (11) | O2xvi—Ag1—K2xvi | 44.29 (3) |
O3xiii—K2—O3 | 132.1 (2) | O2xix—Ag1—K2xvi | 44.29 (3) |
O5x—K2—O2 | 70.96 (14) | O2vii—Ag1—K2xvi | 84.53 (9) |
O3xiii—K2—O2 | 128.03 (13) | K3—Ag1—K2xvi | 61.18 (7) |
O3—K2—O2 | 75.75 (12) | K3xvii—Ag1—K2xvi | 61.18 (7) |
O5x—K2—O2i | 70.96 (14) | K3viii—Ag1—K2xvi | 135.52 (12) |
O3xiii—K2—O2i | 75.75 (12) | Mo1xvi—Ag1—K2xvi | 53.61 (4) |
O3—K2—O2i | 128.03 (13) | Ag2—Ag1—K2xvi | 58.8 (3) |
O2—K2—O2i | 56.29 (18) | Ag2xvii—Ag1—K2xvi | 58.8 (3) |
O5x—K2—O3xiv | 140.73 (10) | Ag2viii—Ag1—K2xvi | 131.5 (5) |
O3xiii—K2—O3xiv | 139.09 (16) | Mo2viii—Ag1—K2xvi | 124.765 (10) |
O3—K2—O3xiv | 84.18 (9) | Mo2—Ag1—K2xvi | 124.765 (9) |
O2—K2—O3xiv | 71.51 (13) | Mo2xvii—Ag1—K2xvi | 54.92 (3) |
O2i—K2—O3xiv | 97.20 (14) | Mo1iii—Ag1—K2xvi | 126.39 (4) |
O5x—K2—O3xv | 140.73 (10) | K2xix—Ag1—K2xvi | 88.40 (6) |
O3xiii—K2—O3xv | 84.18 (9) | O3xvi—Ag2—O3xiv | 123.8 (10) |
O3—K2—O3xv | 139.09 (16) | O3xvi—Ag2—O2xvi | 88.6 (7) |
O2—K2—O3xv | 97.20 (14) | O3xiv—Ag2—O2xvi | 88.6 (7) |
O2i—K2—O3xv | 71.51 (13) | O3xvi—Ag2—O2 | 86.8 (7) |
O3xiv—K2—O3xv | 55.93 (14) | O3xiv—Ag2—O2 | 86.8 (7) |
O5x—K2—O4 | 122.17 (14) | O2xvi—Ag2—O2 | 170.3 (11) |
O3xiii—K2—O4 | 114.36 (12) | O3xvi—Ag2—O5 | 152.3 (10) |
O3—K2—O4 | 55.02 (10) | O3xiv—Ag2—O5 | 74.8 (3) |
O2—K2—O4 | 116.99 (12) | O2xvi—Ag2—O5 | 70.3 (6) |
O2i—K2—O4 | 164.27 (17) | O2—Ag2—O5 | 116.6 (7) |
O3xiv—K2—O4 | 67.20 (12) | O3xvi—Ag2—O5xvii | 74.8 (3) |
O3xv—K2—O4 | 96.78 (13) | O3xiv—Ag2—O5xvii | 152.3 (10) |
O5x—K2—O4xi | 122.17 (14) | O2xvi—Ag2—O5xvii | 70.3 (6) |
O3xiii—K2—O4xi | 55.01 (10) | O2—Ag2—O5xvii | 116.6 (7) |
O3—K2—O4xi | 114.36 (12) | O5—Ag2—O5xvii | 81.1 (6) |
O2—K2—O4xi | 164.27 (17) | O3xvi—Ag2—K3xvi | 68.0 (6) |
O2i—K2—O4xi | 116.99 (12) | O3xiv—Ag2—K3xvi | 68.0 (6) |
O3xiv—K2—O4xi | 96.79 (13) | O2xvi—Ag2—K3xvi | 49.7 (5) |
O3xv—K2—O4xi | 67.20 (12) | O2—Ag2—K3xvi | 120.7 (7) |
O4—K2—O4xi | 65.27 (15) | O5—Ag2—K3xvi | 107.5 (6) |
O5x—K2—O4x | 53.91 (12) | O5xvii—Ag2—K3xvi | 107.5 (6) |
O3xiii—K2—O4x | 66.07 (12) | O3xvi—Ag2—Ag1 | 113.5 (6) |
O3—K2—O4x | 66.07 (12) | O3xiv—Ag2—Ag1 | 113.5 (6) |
O2—K2—O4x | 118.02 (15) | O2xvi—Ag2—Ag1 | 60.8 (5) |
O2i—K2—O4x | 118.02 (15) | O2—Ag2—Ag1 | 128.9 (9) |
O3xiv—K2—O4x | 143.10 (8) | O5—Ag2—Ag1 | 40.6 (3) |
O3xv—K2—O4x | 143.10 (8) | O5xvii—Ag2—Ag1 | 40.6 (3) |
O4—K2—O4x | 77.67 (10) | K3xvi—Ag2—Ag1 | 110.4 (7) |
O4xi—K2—O4x | 77.67 (10) | O3xvi—Ag2—Ag2iii | 107.4 (8) |
O5x—K2—Mo1 | 77.06 (10) | O3xiv—Ag2—Ag2iii | 107.4 (8) |
O3xiii—K2—Mo1 | 105.08 (9) | O2xvi—Ag2—Ag2iii | 143.5 (12) |
O3—K2—Mo1 | 105.08 (9) | O2—Ag2—Ag2iii | 46.1 (7) |
O2—K2—Mo1 | 29.37 (9) | O5—Ag2—Ag2iii | 82.4 (7) |
O2i—K2—Mo1 | 29.37 (9) | O5xvii—Ag2—Ag2iii | 82.4 (7) |
O3xiv—K2—Mo1 | 76.04 (9) | K3xvi—Ag2—Ag2iii | 166.8 (11) |
O3xv—K2—Mo1 | 76.04 (9) | Ag1—Ag2—Ag2iii | 82.8 (8) |
O4—K2—Mo1 | 139.03 (10) | O3xvi—Ag2—Ag2xvi | 69.2 (6) |
O4xi—K2—Mo1 | 139.03 (10) | O3xiv—Ag2—Ag2xvi | 69.2 (6) |
O4x—K2—Mo1 | 130.97 (11) | O2xvi—Ag2—Ag2xvi | 46.2 (6) |
O5x—K2—Mo2 | 102.14 (7) | O2—Ag2—Ag2xvi | 124.1 (12) |
O3xiii—K2—Mo2 | 133.78 (11) | O5—Ag2—Ag2xvi | 104.9 (9) |
O3—K2—Mo2 | 27.66 (7) | O5xvii—Ag2—Ag2xvi | 104.9 (9) |
O2—K2—Mo2 | 92.17 (9) | K3xvi—Ag2—Ag2xvi | 3.5 (5) |
O2i—K2—Mo2 | 148.43 (9) | Ag1—Ag2—Ag2xvi | 107.0 (10) |
O3xiv—K2—Mo2 | 68.15 (7) | Ag2iii—Ag2—Ag2xvi | 170.3 (16) |
O3xv—K2—Mo2 | 115.92 (10) | O3xvi—Ag2—Mo1 | 76.6 (6) |
O4—K2—Mo2 | 28.71 (7) | O3xiv—Ag2—Mo1 | 76.6 (6) |
O4xi—K2—Mo2 | 93.08 (8) | O2xvi—Ag2—Mo1 | 147.6 (9) |
O4x—K2—Mo2 | 75.68 (5) | O2—Ag2—Mo1 | 22.7 (3) |
Mo1—K2—Mo2 | 119.66 (3) | O5—Ag2—Mo1 | 130.5 (6) |
O5x—K2—Mo2xi | 102.14 (7) | O5xvii—Ag2—Mo1 | 130.5 (6) |
O3xiii—K2—Mo2xi | 27.66 (7) | K3xvi—Ag2—Mo1 | 97.9 (5) |
O3—K2—Mo2xi | 133.78 (11) | Ag1—Ag2—Mo1 | 151.6 (8) |
O2—K2—Mo2xi | 148.43 (9) | Ag2iii—Ag2—Mo1 | 68.9 (8) |
O2i—K2—Mo2xi | 92.17 (9) | Ag2xvi—Ag2—Mo1 | 101.4 (9) |
O3xiv—K2—Mo2xi | 115.92 (10) | O3xvi—Ag2—K2xvi | 46.4 (3) |
O3xv—K2—Mo2xi | 68.15 (7) | O3xiv—Ag2—K2xvi | 132.2 (10) |
O4—K2—Mo2xi | 93.08 (8) | O2xvi—Ag2—K2xvi | 50.5 (3) |
O4xi—K2—Mo2xi | 28.71 (7) | O2—Ag2—K2xvi | 129.0 (3) |
O4x—K2—Mo2xi | 75.69 (5) | O5—Ag2—K2xvi | 106.1 (7) |
Mo1—K2—Mo2xi | 119.65 (3) | O5xvii—Ag2—K2xvi | 43.5 (2) |
Mo2—K2—Mo2xi | 119.31 (4) | K3xvi—Ag2—K2xvi | 66.3 (4) |
O5x—K2—Mo2xv | 154.75 (10) | Ag1—Ag2—K2xvi | 71.2 (4) |
O3xiii—K2—Mo2xv | 111.07 (11) | Ag2iii—Ag2—K2xvi | 120.3 (5) |
O3—K2—Mo2xv | 111.07 (11) | Ag2xvi—Ag2—K2xvi | 64.5 (5) |
O2—K2—Mo2xv | 86.88 (13) | Mo1—Ag2—K2xvi | 122.9 (4) |
O2i—K2—Mo2xv | 86.88 (12) | O3xvi—Ag2—K2vii | 132.2 (10) |
O3xiv—K2—Mo2xv | 28.17 (7) | O3xiv—Ag2—K2vii | 46.4 (3) |
O3xv—K2—Mo2xv | 28.17 (7) | O2xvi—Ag2—K2vii | 50.5 (3) |
O4—K2—Mo2xv | 78.27 (11) | O2—Ag2—K2vii | 129.0 (3) |
O4xi—K2—Mo2xv | 78.27 (11) | O5—Ag2—K2vii | 43.5 (2) |
O4x—K2—Mo2xv | 151.34 (9) | O5xvii—Ag2—K2vii | 106.1 (7) |
Mo1—K2—Mo2xv | 77.68 (6) | K3xvi—Ag2—K2vii | 66.3 (4) |
Mo2—K2—Mo2xv | 90.32 (5) | Ag1—Ag2—K2vii | 71.2 (4) |
Mo2xi—K2—Mo2xv | 90.33 (5) | Ag2iii—Ag2—K2vii | 120.3 (5) |
O5x—K2—Mo2x | 26.03 (9) | Ag2xvi—Ag2—K2vii | 64.5 (5) |
O3xiii—K2—Mo2x | 68.78 (11) | Mo1—Ag2—K2vii | 122.9 (4) |
O3—K2—Mo2x | 68.77 (11) | K2xvi—Ag2—K2vii | 101.0 (6) |
O2—K2—Mo2x | 93.81 (13) | O3xvi—Ag2—Mo2xvii | 67.8 (3) |
O2i—K2—Mo2x | 93.81 (13) | O3xiv—Ag2—Mo2xvii | 168.0 (8) |
O3xiv—K2—Mo2x | 151.91 (7) | O2xvi—Ag2—Mo2xvii | 94.8 (5) |
O3xv—K2—Mo2x | 151.91 (7) | O2—Ag2—Mo2xvii | 91.3 (6) |
O4—K2—Mo2x | 101.07 (10) | O5—Ag2—Mo2xvii | 95.5 (6) |
O4xi—K2—Mo2x | 101.07 (10) | O5xvii—Ag2—Mo2xvii | 25.47 (16) |
O4x—K2—Mo2x | 27.87 (7) | K3xvi—Ag2—Mo2xvii | 122.6 (4) |
Mo1—K2—Mo2x | 103.10 (6) | Ag1—Ag2—Mo2xvii | 59.1 (3) |
Mo2—K2—Mo2x | 89.28 (5) | Ag2iii—Ag2—Mo2xvii | 63.6 (4) |
Mo2xi—K2—Mo2x | 89.28 (5) | Ag2xvi—Ag2—Mo2xvii | 121.1 (6) |
Mo2xv—K2—Mo2x | 179.22 (5) | Mo1—Ag2—Mo2xvii | 105.6 (5) |
O5x—K2—K1 | 96.12 (11) | K2xvi—Ag2—Mo2xvii | 56.84 (17) |
O3xiii—K2—K1 | 72.82 (10) | K2vii—Ag2—Mo2xvii | 129.7 (7) |
O3—K2—K1 | 72.82 (10) | O3xvi—Ag2—Mo2 | 168.0 (8) |
O2—K2—K1 | 148.14 (10) | O3xiv—Ag2—Mo2 | 67.8 (3) |
O2i—K2—K1 | 148.14 (10) | O2xvi—Ag2—Mo2 | 94.8 (5) |
O3xiv—K2—K1 | 109.90 (8) | O2—Ag2—Mo2 | 91.3 (6) |
O3xv—K2—K1 | 109.90 (8) | O5—Ag2—Mo2 | 25.47 (16) |
O4—K2—K1 | 45.13 (9) | O5xvii—Ag2—Mo2 | 95.5 (6) |
O4xi—K2—K1 | 45.13 (9) | K3xvi—Ag2—Mo2 | 122.6 (4) |
O4x—K2—K1 | 42.21 (8) | Ag1—Ag2—Mo2 | 59.1 (3) |
Mo1—K2—K1 | 173.18 (9) | Ag2iii—Ag2—Mo2 | 63.6 (4) |
Mo2—K2—K1 | 61.37 (2) | Ag2xvi—Ag2—Mo2 | 121.1 (6) |
Mo2xi—K2—K1 | 61.37 (2) | Mo1—Ag2—Mo2 | 105.6 (5) |
Mo2xv—K2—K1 | 109.13 (5) | K2xvi—Ag2—Mo2 | 129.7 (7) |
Mo2x—K2—K1 | 70.08 (5) | K2vii—Ag2—Mo2 | 56.84 (17) |
O5x—K2—Ag2iii | 51.7 (4) | Mo2xvii—Ag2—Mo2 | 100.3 (5) |
O3xiii—K2—Ag2iii | 127.4 (4) | O3xvi—Ag2—K3iii | 106.5 (7) |
O3—K2—Ag2iii | 38.9 (3) | O3xiv—Ag2—K3iii | 106.5 (7) |
O2—K2—Ag2iii | 43.3 (3) | O2xvi—Ag2—K3iii | 145.9 (8) |
O2i—K2—Ag2iii | 89.2 (3) | O2—Ag2—K3iii | 43.8 (4) |
O3xiv—K2—Ag2iii | 92.1 (4) | O5—Ag2—K3iii | 84.1 (5) |
O3xv—K2—Ag2iii | 138.3 (3) | O5xvii—Ag2—K3iii | 84.1 (5) |
O4—K2—Ag2iii | 93.2 (4) | K3xvi—Ag2—K3iii | 164.4 (6) |
O4xi—K2—Ag2iii | 150.8 (3) | Ag1—Ag2—K3iii | 85.1 (5) |
O4x—K2—Ag2iii | 78.6 (3) | Ag2iii—Ag2—K3iii | 2.3 (5) |
Mo1—K2—Ag2iii | 70.2 (3) | Ag2xvi—Ag2—K3iii | 167.9 (11) |
Mo2—K2—Ag2iii | 64.6 (3) | Mo1—Ag2—K3iii | 66.5 (4) |
Mo2xi—K2—Ag2iii | 151.5 (4) | K2xvi—Ag2—K3iii | 121.3 (4) |
Mo2xv—K2—Ag2iii | 118.2 (3) | K2vii—Ag2—K3iii | 121.3 (4) |
Mo2x—K2—Ag2iii | 62.2 (3) | Mo2xvii—Ag2—K3iii | 64.8 (4) |
K1—K2—Ag2iii | 105.7 (3) | Mo2—Ag2—K3iii | 64.8 (4) |
O5x—K2—Ag2x | 51.7 (4) | O3xvi—Ag2—Mo2xvi | 13.4 (3) |
O3xiii—K2—Ag2x | 38.9 (3) | O3xiv—Ag2—Mo2xvi | 110.5 (8) |
O3—K2—Ag2x | 127.4 (4) | O2xvi—Ag2—Mo2xvi | 89.4 (5) |
O2—K2—Ag2x | 89.2 (3) | O2—Ag2—Mo2xvi | 84.2 (5) |
O2i—K2—Ag2x | 43.3 (3) | O5—Ag2—Mo2xvi | 159.1 (9) |
O3xiv—K2—Ag2x | 138.3 (3) | O5xvii—Ag2—Mo2xvi | 87.64 (17) |
O3xv—K2—Ag2x | 92.1 (4) | K3xvi—Ag2—Mo2xvi | 59.3 (3) |
O4—K2—Ag2x | 150.8 (3) | Ag1—Ag2—Mo2xvi | 124.9 (4) |
O4xi—K2—Ag2x | 93.2 (4) | Ag2iii—Ag2—Mo2xvi | 113.7 (7) |
O4x—K2—Ag2x | 78.6 (3) | Ag2xvi—Ag2—Mo2xvi | 61.0 (4) |
Mo1—K2—Ag2x | 70.2 (3) | Mo1—Ag2—Mo2xvi | 69.8 (4) |
Mo2—K2—Ag2x | 151.5 (3) | K2xvi—Ag2—Mo2xvi | 54.73 (18) |
Mo2xi—K2—Ag2x | 64.6 (3) | K2vii—Ag2—Mo2xvi | 125.5 (7) |
Mo2xv—K2—Ag2x | 118.2 (3) | Mo2xvii—Ag2—Mo2xvi | 81.05 (3) |
Mo2x—K2—Ag2x | 62.2 (3) | Mo2—Ag2—Mo2xvi | 175.4 (8) |
K1—K2—Ag2x | 105.7 (3) | K3iii—Ag2—Mo2xvi | 112.3 (4) |
Ag2iii—K2—Ag2x | 98.5 (7) | O3xvi—Ag2—Mo2xv | 110.5 (8) |
O5x—K2—K3iii | 47.00 (10) | O3xiv—Ag2—Mo2xv | 13.4 (3) |
O3xiii—K2—K3iii | 122.69 (16) | O2xvi—Ag2—Mo2xv | 89.4 (5) |
O3—K2—K3iii | 41.52 (12) | O2—Ag2—Mo2xv | 84.2 (5) |
O2—K2—K3iii | 44.43 (13) | O5—Ag2—Mo2xv | 87.64 (17) |
O2i—K2—K3iii | 87.19 (15) | O5xvii—Ag2—Mo2xv | 159.1 (9) |
O3xiv—K2—K3iii | 96.59 (11) | K3xvi—Ag2—Mo2xv | 59.3 (3) |
O3xv—K2—K3iii | 140.89 (11) | Ag1—Ag2—Mo2xv | 124.9 (4) |
O4—K2—K3iii | 96.30 (13) | Ag2iii—Ag2—Mo2xv | 113.7 (7) |
O4xi—K2—K3iii | 150.47 (13) | Ag2xvi—Ag2—Mo2xv | 61.0 (4) |
O4x—K2—K3iii | 75.83 (10) | Mo1—Ag2—Mo2xv | 69.8 (4) |
Mo1—K2—K3iii | 70.00 (9) | K2xvi—Ag2—Mo2xv | 125.5 (7) |
Mo2—K2—K3iii | 67.93 (10) | K2vii—Ag2—Mo2xv | 54.73 (18) |
Mo2xi—K2—K3iii | 147.26 (12) | Mo2xvii—Ag2—Mo2xv | 175.4 (8) |
Mo2xv—K2—K3iii | 122.27 (9) | Mo2—Ag2—Mo2xv | 81.05 (3) |
Mo2x—K2—K3iii | 58.16 (9) | K3iii—Ag2—Mo2xv | 112.3 (4) |
K1—K2—K3iii | 105.42 (9) | Mo2xvi—Ag2—Mo2xv | 97.2 (5) |
Ag2iii—K2—K3iii | 4.7 (4) | O3xvi—Ag2—K2ii | 48.2 (4) |
Ag2x—K2—K3iii | 94.1 (3) | O3xiv—Ag2—K2ii | 129.8 (9) |
O5x—K2—K3x | 47.00 (10) | O2xvi—Ag2—K2ii | 132.0 (3) |
O3xiii—K2—K3x | 41.52 (12) | O2—Ag2—K2ii | 47.9 (3) |
O3—K2—K3x | 122.69 (16) | O5—Ag2—K2ii | 138.6 (8) |
O2—K2—K3x | 87.19 (15) | O5xvii—Ag2—K2ii | 77.8 (3) |
O2i—K2—K3x | 44.43 (13) | K3xvi—Ag2—K2ii | 112.6 (4) |
O3xiv—K2—K3x | 140.89 (11) | Ag1—Ag2—K2ii | 112.5 (5) |
O3xv—K2—K3x | 96.59 (11) | Ag2iii—Ag2—K2ii | 60.0 (5) |
O4—K2—K3x | 150.47 (13) | Ag2xvi—Ag2—K2ii | 114.7 (6) |
O4xi—K2—K3x | 96.30 (13) | Mo1—Ag2—K2ii | 53.2 (3) |
O4x—K2—K3x | 75.83 (10) | K2xvi—Ag2—K2ii | 81.65 (4) |
Mo1—K2—K3x | 70.00 (9) | K2vii—Ag2—K2ii | 176.1 (7) |
Mo2—K2—K3x | 147.26 (12) | Mo2xvii—Ag2—K2ii | 54.21 (19) |
Mo2xi—K2—K3x | 67.93 (10) | Mo2—Ag2—K2ii | 123.5 (7) |
Mo2xv—K2—K3x | 122.28 (9) | K3iii—Ag2—K2ii | 58.8 (3) |
Mo2x—K2—K3x | 58.16 (9) | Mo2xvi—Ag2—K2ii | 53.81 (18) |
K1—K2—K3x | 105.42 (9) | Mo2xv—Ag2—K2ii | 121.4 (6) |
Ag2iii—K2—K3x | 94.1 (3) | O3xvi—Ag2—K2 | 129.8 (9) |
Ag2x—K2—K3x | 4.7 (4) | O3xiv—Ag2—K2 | 48.2 (4) |
K3iii—K2—K3x | 89.7 (2) | O2xvi—Ag2—K2 | 132.0 (3) |
O3xvi—K3—O3xiv | 111.3 (3) | O2—Ag2—K2 | 47.9 (3) |
O3xvi—K3—O2 | 83.6 (2) | O5—Ag2—K2 | 77.8 (3) |
O3xiv—K3—O2 | 83.6 (2) | O5xvii—Ag2—K2 | 138.6 (8) |
O3xvi—K3—O2xvi | 83.23 (19) | K3xvi—Ag2—K2 | 112.6 (4) |
O3xiv—K3—O2xvi | 83.23 (19) | Ag1—Ag2—K2 | 112.5 (5) |
O2—K3—O2xvi | 156.6 (3) | Ag2iii—Ag2—K2 | 60.0 (5) |
O3xvi—K3—O5 | 153.2 (3) | Ag2xvi—Ag2—K2 | 114.7 (6) |
O3xiv—K3—O5 | 75.74 (13) | Mo1—Ag2—K2 | 53.2 (3) |
O2—K3—O5 | 123.13 (19) | K2xvi—Ag2—K2 | 176.1 (7) |
O2xvi—K3—O5 | 71.74 (19) | K2vii—Ag2—K2 | 81.65 (4) |
O3xvi—K3—O5xvii | 75.74 (13) | Mo2xvii—Ag2—K2 | 123.5 (7) |
O3xiv—K3—O5xvii | 153.2 (3) | Mo2—Ag2—K2 | 54.21 (19) |
O2—K3—O5xvii | 123.13 (19) | K3iii—Ag2—K2 | 58.8 (3) |
O2xvi—K3—O5xvii | 71.74 (19) | Mo2xvi—Ag2—K2 | 121.4 (6) |
O5—K3—O5xvii | 87.3 (2) | Mo2xv—Ag2—K2 | 53.81 (18) |
O3xvi—K3—Ag1 | 116.16 (18) | K2ii—Ag2—K2 | 95.5 (6) |
O3xiv—K3—Ag1 | 116.16 (18) | Mo1—O1—Ag1xvi | 180.0 |
O2—K3—Ag1 | 140.0 (3) | Mo1—O2—K3 | 128.0 (3) |
O2xvi—K3—Ag1 | 63.41 (19) | Mo1—O2—Ag2iii | 151.4 (6) |
O5—K3—Ag1 | 43.64 (12) | K3—O2—Ag2iii | 80.6 (6) |
O5xvii—K3—Ag1 | 43.64 (12) | Mo1—O2—Ag2 | 120.9 (6) |
O3xvi—K3—O3xviii | 80.09 (13) | K3—O2—Ag2 | 7.1 (6) |
O3xiv—K3—O3xviii | 151.2 (3) | Ag2iii—O2—Ag2 | 87.70 (17) |
O2—K3—O3xviii | 71.07 (16) | Mo1—O2—K3iii | 144.8 (3) |
O2xvi—K3—O3xviii | 125.2 (2) | K3—O2—K3iii | 87.25 (14) |
O5—K3—O3xviii | 106.4 (2) | Ag2iii—O2—K3iii | 6.6 (6) |
O5xvii—K3—O3xviii | 53.59 (13) | Ag2—O2—K3iii | 94.3 (6) |
Ag1—K3—O3xviii | 78.31 (14) | Mo1—O2—K2ii | 92.88 (9) |
O3xvi—K3—O3 | 151.2 (3) | K3—O2—K2ii | 90.31 (10) |
O3xiv—K3—O3 | 80.10 (13) | Ag2iii—O2—K2ii | 86.21 (11) |
O2—K3—O3 | 71.07 (16) | Ag2—O2—K2ii | 90.79 (11) |
O2xvi—K3—O3 | 125.2 (2) | K3iii—O2—K2ii | 86.12 (11) |
O5—K3—O3 | 53.59 (13) | Mo1—O2—K2 | 92.88 (9) |
O5xvii—K3—O3 | 106.4 (2) | K3—O2—K2 | 90.31 (10) |
Ag1—K3—O3 | 78.31 (14) | Ag2iii—O2—K2 | 86.21 (11) |
O3xviii—K3—O3 | 78.83 (18) | Ag2—O2—K2 | 90.79 (11) |
O3xvi—K3—Ag2iii | 110.52 (17) | K3iii—O2—K2 | 86.12 (11) |
O3xiv—K3—Ag2iii | 110.52 (17) | K2ii—O2—K2 | 172.2 (2) |
O2—K3—Ag2iii | 49.7 (4) | Mo1—O2—Ag1iii | 79.19 (18) |
O2xvi—K3—Ag2iii | 153.7 (3) | K3—O2—Ag1iii | 152.9 (2) |
O5—K3—Ag2iii | 89.5 (3) | Ag2iii—O2—Ag1iii | 72.2 (5) |
O5xvii—K3—Ag2iii | 89.5 (3) | Ag2—O2—Ag1iii | 159.9 (6) |
Ag1—K3—Ag2iii | 90.2 (4) | K3iii—O2—Ag1iii | 65.61 (19) |
O3xviii—K3—Ag2iii | 41.87 (18) | K2ii—O2—Ag1iii | 87.95 (12) |
O3—K3—Ag2iii | 41.87 (18) | K2—O2—Ag1iii | 87.95 (12) |
O3xvi—K3—Mo2xvii | 70.32 (10) | Mo2—O3—Ag2iii | 147.6 (6) |
O3xiv—K3—Mo2xvii | 178.3 (2) | Mo2—O3—K3iii | 153.6 (2) |
O2—K3—Mo2xvii | 95.94 (15) | Ag2iii—O3—K3iii | 6.4 (6) |
O2xvi—K3—Mo2xvii | 97.72 (16) | Mo2—O3—K2 | 103.38 (18) |
O5—K3—Mo2xvii | 103.2 (2) | Ag2iii—O3—K2 | 94.7 (6) |
O5xvii—K3—Mo2xvii | 27.20 (9) | K3iii—O3—K2 | 92.92 (19) |
Ag1—K3—Mo2xvii | 63.19 (10) | Mo2—O3—K2vi | 96.43 (18) |
O3xviii—K3—Mo2xvii | 27.67 (6) | Ag2iii—O3—K2vi | 94.8 (7) |
O3—K3—Mo2xvii | 98.17 (16) | K3iii—O3—K2vi | 90.8 (2) |
Ag2iii—K3—Mo2xvii | 68.0 (2) | K2—O3—K2vi | 125.03 (16) |
O3xvi—K3—Mo2 | 178.3 (2) | Mo2—O3—K3 | 86.7 (2) |
O3xiv—K3—Mo2 | 70.32 (10) | Ag2iii—O3—K3 | 70.1 (7) |
O2—K3—Mo2 | 95.94 (15) | K3iii—O3—K3 | 75.76 (13) |
O2xvi—K3—Mo2 | 97.72 (16) | K2—O3—K3 | 80.05 (17) |
O5—K3—Mo2 | 27.20 (9) | K2vi—O3—K3 | 152.63 (16) |
O5xvii—K3—Mo2 | 103.1 (2) | Mo2—O4—K1xii | 161.5 (3) |
Ag1—K3—Mo2 | 63.18 (10) | Mo2—O4—K1 | 113.5 (2) |
O3xviii—K3—Mo2 | 98.17 (16) | K1xii—O4—K1 | 84.95 (12) |
O3—K3—Mo2 | 27.67 (6) | Mo2—O4—K2 | 88.70 (9) |
Ag2iii—K3—Mo2 | 68.0 (2) | K1xii—O4—K2 | 94.96 (8) |
Mo2xvii—K3—Mo2 | 108.07 (16) | K1—O4—K2 | 79.72 (9) |
O3xvi—K3—K3xvi | 61.64 (18) | Mo2—O4—K2v | 88.70 (9) |
O3xiv—K3—K3xvi | 61.64 (18) | K1xii—O4—K2v | 94.96 (8) |
O2—K3—K3xvi | 111.4 (3) | K1—O4—K2v | 79.72 (9) |
O2xvi—K3—K3xvi | 45.26 (17) | K2—O4—K2v | 156.2 (2) |
O5—K3—K3xvi | 104.1 (2) | Mo2—O4—K2vii | 84.34 (17) |
O5xvii—K3—K3xvi | 104.1 (2) | K1xii—O4—K2vii | 77.17 (13) |
Ag1—K3—K3xvi | 108.7 (3) | K1—O4—K2vii | 162.12 (17) |
O3xviii—K3—K3xvi | 140.46 (10) | K2—O4—K2vii | 101.62 (10) |
O3—K3—K3xvi | 140.46 (10) | K2v—O4—K2vii | 101.62 (10) |
Ag2iii—K3—K3xvi | 161.09 (17) | Mo2—O5—Ag1 | 129.3 (2) |
Mo2xvii—K3—K3xvi | 120.04 (12) | Mo2—O5—K2vii | 111.88 (19) |
Mo2—K3—K3xvi | 120.04 (12) | Ag1—O5—K2vii | 118.86 (18) |
O3xvi—K3—K3iii | 109.5 (2) | Mo2—O5—K3 | 104.24 (15) |
O3xiv—K3—K3iii | 109.5 (2) | Ag1—O5—K3 | 76.51 (12) |
O2—K3—K3iii | 47.5 (2) | K2vii—O5—K3 | 90.08 (15) |
O2xvi—K3—K3iii | 155.9 (4) | Mo2—O5—K3viii | 104.24 (15) |
O5—K3—K3iii | 91.1 (2) | Ag1—O5—K3viii | 76.51 (12) |
O5xvii—K3—K3iii | 91.1 (2) | K2vii—O5—K3viii | 90.08 (15) |
Ag1—K3—K3iii | 92.5 (2) | K3—O5—K3viii | 149.2 (3) |
O3xviii—K3—K3iii | 42.60 (9) | Mo2—O5—Ag2 | 106.1 (5) |
O3—K3—K3iii | 42.60 (9) | Ag1—O5—Ag2 | 79.4 (3) |
Ag2iii—K3—K3iii | 2.2 (5) | K2vii—O5—Ag2 | 84.7 (5) |
Mo2xvii—K3—K3iii | 69.13 (11) | K3—O5—Ag2 | 5.4 (5) |
Mo2—K3—K3iii | 69.13 (11) | K3viii—O5—Ag2 | 149.0 (4) |
K3xvi—K3—K3iii | 158.9 (5) | Mo2—O5—Ag2viii | 106.1 (5) |
O3xvi—K3—K2xvi | 45.56 (11) | Ag1—O5—Ag2viii | 79.4 (3) |
O3xiv—K3—K2xvi | 123.7 (2) | K2vii—O5—Ag2viii | 84.7 (5) |
O2—K3—K2xvi | 126.82 (12) | K3—O5—Ag2viii | 149.0 (4) |
O2xvi—K3—K2xvi | 49.45 (8) | K3viii—O5—Ag2viii | 5.4 (5) |
O5—K3—K2xvi | 108.4 (2) | Ag2—O5—Ag2viii | 147.9 (10) |
Symmetry codes: (i) −x+y, −x+1, z; (ii) −y+1, x−y+1, z; (iii) −x+1, −y+1, z−1/2; (iv) x, x−y, z; (v) −x+y, −x, z; (vi) y, −x+y, z−1/2; (vii) y, −x+y, z+1/2; (viii) −y+1, x−y, z; (ix) −x, −y, z−1/2; (x) x−y, x, z−1/2; (xi) −y, x−y, z; (xii) −x, −y, z+1/2; (xiii) −x+y, y, z; (xiv) y, x, z+1/2; (xv) x−y, x, z+1/2; (xvi) −x+1, −y+1, z+1/2; (xvii) −x+y+1, −x+1, z; (xviii) −y+1, −x+1, z; (xix) x−y+1, x, z+1/2. |
Heptapotassium silver tetrakis(tetraoxotungstate) (K7Ag(WO4)4)
top
Crystal data top
K7Ag(WO4)4 | Z = 2 |
Mr = 1372.94 | F(000) = 1208.0 |
Hexagonal, P63mc | Dx = 4.528 Mg m−3 |
a = 12.4912 (5) Å | CuKα radiation, λ = 1.540562, 1.544390 Å |
c = 7.4526 (3) Å | T = 296 K |
V = 1007.04 (11) Å3 | white |
Data collection top
D8 ADVANCE Bruker AX diffractometer | Data collection mode: reflection |
Radiation source: X-ray tube | Scan method: step |
None monochromator | 2θmin = 7°, 2θmax = 100°, 2θstep = 0.021° |
Specimen mounting: packed powder pellet | |
Refinement top
Least-squares matrix: full with fixed elements per cycle | 53 parameters |
Rp = 0.040 | 0 restraints |
Rwp = 0.053 | Weighting scheme based on measured s.u.'s |
Rexp = 0.015 | (Δ/σ)max = 0.006 |
R(F2) = 0.06450 | Background function: GSAS Background function number 1 with 14 terms.
Shifted Chebyshev function of 1st kind
1: 3805.50 2: -4412.29 3: 3122.14 4: -1928.69
5: 1209.58 6: -754.027 7: 531.881 8: -377.433
9: 249.957 10: -172.455 11: 78.0314 12: -188.338
13: 153.634 14: -119.875 |
4480 data points | Preferred orientation correction: March-Dollase
AXIS 1 Ratio= 0.780 Frac 0.250 h= 0.000 k= 2.000 l= 1.000
AXIS 2 Ratio= 0.439 Frac 0.250 h= 0.000 k= 0.000 l= 2.000
AXIS 3 Ratio= 0.447 Frac 0.250 h= 0.000 k= 1.000 l= 2.000
AXIS 4 Ratio= 1.557 Frac 0.250 h=-2.000 k= 4.000 l= 1.000
Prefered orientation correction range: Min= 0.58799, Max= 4.44535 |
Profile function: pseudo-Voigt | |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
W1 | 0.3333 | 0.6667 | 0.2956 (4) | 0.0345 (8)* | |
W2 | 0.33919 (19) | 0.16959 (9) | 0.1815 (4) | 0.0288 (4)* | |
K1 | 0.0 | 0.0 | 0.0035 (8) | 0.0470 (14)* | |
K2 | 0.1706 (4) | 0.3412 (9) | 0.1975 (17) | 0.0470 (14)* | |
K3 | 0.5133 (4) | 0.4867 (4) | 0.4175 (10) | 0.0470 (14)* | |
Ag1 | 0.6667 | 0.3333 | 0.3398 (5) | 0.0385 (15)* | |
O1 | 0.3333 | 0.6667 | 0.5164 (4) | 0.071 (4)* | |
O2 | 0.4025 (9) | 0.5975 (9) | 0.207 (2) | 0.071 (4)* | |
O3 | 0.3601 (11) | 0.3039 (12) | 0.0661 (16) | 0.071 (4)* | |
O4 | 0.1862 (18) | 0.0931 (9) | 0.2775 (19) | 0.031 (4)* | |
O5 | 0.4408 (16) | 0.2204 (8) | 0.3553 (17) | 0.031 (4)* | |
Geometric parameters (Å, º) top
W1—O1 | 1.646 (3) | K2—O3x | 2.808 (13) |
W1—O2 | 1.636 (19) | K2—O3xi | 3.159 (15) |
W1—O2i | 1.635 (19) | K2—O4 | 3.256 (8) |
W1—O2ii | 1.635 (19) | K2—O4iv | 3.551 (2) |
W2—O3 | 1.784 (13) | K2—O4v | 3.256 (8) |
W2—O3iii | 1.784 (13) | K2—O5iv | 2.769 (17) |
W2—O4 | 1.803 (18) | K3—O2 | 2.865 (19) |
W2—O5 | 1.699 (15) | K3—O2xii | 2.824 (19) |
K1—O4 | 2.868 (2) | K3—O3 | 3.371 (14) |
K1—O4iv | 2.626 (16) | K3—O3xii | 2.536 (13) |
K1—O4v | 2.868 (2) | K3—O3xiii | 3.371 (14) |
K1—O4vi | 2.626 (16) | K3—O3xi | 2.536 (13) |
K1—O4vii | 2.868 (2) | K3—O5 | 3.015 (8) |
K1—O4viii | 2.626 (16) | K3—O5xiv | 3.015 (8) |
K2—O2 | 3.061 (9) | Ag1—O1xv | 2.410 (3) |
K2—O2ii | 3.061 (9) | Ag1—O5 | 2.446 (18) |
K2—O3 | 2.808 (13) | Ag1—O5xvi | 2.445 (18) |
K2—O3ix | 3.159 (15) | Ag1—O5xiv | 2.446 (18) |
| | | |
O1—W1—O2 | 113.8 (6) | O2ii—K2—O4v | 121.0 (6) |
O1—W1—O2i | 113.8 (6) | O2ii—K2—O5iv | 70.7 (5) |
O1—W1—O2ii | 113.8 (6) | O3—K2—O3ix | 140.0 (5) |
O2—W1—O2i | 104.8 (6) | O3—K2—O3x | 135.7 (6) |
O2—W1—O2ii | 104.8 (6) | O3—K2—O3xi | 81.9 (2) |
O2i—W1—O2ii | 104.8 (6) | O3—K2—O4 | 56.6 (4) |
O3—W2—O4 | 107.9 (5) | O3—K2—O4v | 116.2 (6) |
O3—W2—O5 | 106.6 (4) | O3—K2—O5iv | 74.6 (3) |
O3iii—W2—O4 | 107.9 (5) | O3ix—K2—O3x | 81.9 (2) |
O3iii—W2—O5 | 106.6 (4) | O3ix—K2—O3xi | 58.6 (5) |
O4—W2—O5 | 106.9 (7) | O3ix—K2—O4 | 99.0 (5) |
O4—K1—O4iv | 100.8 (4) | O3ix—K2—O4v | 68.4 (4) |
O4—K1—O4v | 74.9 (5) | O3ix—K2—O5iv | 140.9 (4) |
O4—K1—O4vi | 174.5 (5) | O3x—K2—O3xi | 140.0 (5) |
O4—K1—O4vii | 74.9 (5) | O3x—K2—O4 | 116.2 (6) |
O4—K1—O4viii | 100.8 (4) | O3x—K2—O4v | 56.6 (4) |
O4iv—K1—O4v | 100.8 (4) | O3x—K2—O5iv | 74.6 (3) |
O4iv—K1—O4vi | 83.3 (6) | O3xi—K2—O4 | 68.4 (4) |
O4iv—K1—O4vii | 174.5 (5) | O3xi—K2—O4v | 99.0 (5) |
O4iv—K1—O4viii | 83.3 (6) | O3xi—K2—O5iv | 140.9 (4) |
O4v—K1—O4vi | 100.8 (4) | O4—K2—O4v | 64.8 (7) |
O4v—K1—O4vii | 74.9 (5) | O4—K2—O5iv | 119.3 (5) |
O4v—K1—O4viii | 174.5 (5) | O4v—K2—O5iv | 119.3 (5) |
O4vi—K1—O4vii | 100.8 (4) | O2—K3—O2xii | 163.4 (5) |
O4vi—K1—O4viii | 83.3 (6) | O2—K3—O3xii | 86.8 (4) |
O4vii—K1—O4viii | 100.8 (4) | O2—K3—O3xi | 86.8 (4) |
O2—K2—O2ii | 50.1 (7) | O2—K3—O5 | 119.8 (3) |
O2—K2—O3 | 75.3 (5) | O2—K3—O5xiv | 119.8 (3) |
O2—K2—O3ix | 97.4 (5) | O2xii—K3—O3xii | 83.9 (4) |
O2—K2—O3x | 122.0 (5) | O2xii—K3—O3xi | 83.9 (4) |
O2—K2—O3xi | 73.4 (4) | O2xii—K3—O5 | 70.7 (4) |
O2—K2—O4 | 121.0 (6) | O2xii—K3—O5xiv | 70.7 (4) |
O2—K2—O4v | 165.7 (6) | O3xii—K3—O3xi | 111.7 (7) |
O2—K2—O5iv | 70.7 (5) | O3xii—K3—O5 | 153.3 (5) |
O2ii—K2—O3 | 122.0 (5) | O3xii—K3—O5xiv | 74.5 (4) |
O2ii—K2—O3ix | 73.4 (4) | O3xi—K3—O5 | 74.5 (4) |
O2ii—K2—O3x | 75.3 (5) | O3xi—K3—O5xiv | 153.3 (5) |
O2ii—K2—O3xi | 97.4 (5) | O5—K3—O5xiv | 89.2 (7) |
O2ii—K2—O4 | 165.7 (6) | | |
Symmetry codes: (i) −y+1, x−y+1, z; (ii) y−x, −x+1, z; (iii) x, x−y, z; (iv) x−y, x, z−1/2; (v) −y, x−y, z; (vi) −x, −y, z−1/2; (vii) y−x, −x, z; (viii) y, y−x, z−1/2; (ix) x−y, x, z+1/2; (x) y−x, y, z; (xi) y, x, z+1/2; (xii) −x+1, −y+1, z+1/2; (xiii) −y+1, −x+1, z; (xiv) y−x+1, −x+1, z; (xv) x−y+1, x, z−1/2; (xvi) −y+1, x−y, z. |
Selected interatomic distances (Å) for K6.68Ag1.32(MoO4)4 and
K7Ag(WO4)4 topK6.68Ag1.32(MoO4)4 | | K7Ag(WO4)4 | |
X1 tetrahedron | | | |
Mo1—O1 | 1.786 (18) | W1—O1 | 1.714 (3) |
Mo1—O2 | 1.757 (5) (× 3) | W1—O2 | 1.771 (3) (× 3) |
<Mo1—O> | 1.764 | <W1—O> | 1.757 |
| | | |
X2 tetrahedron | | | |
Mo2—O3 | 1.750 (3) (× 2) | W2—O3 | 1.807 (13) (× 2) |
Mo2—O4 | 1.762 (4) | W2—O4 | 1.758 (16) |
Mo2—O5 | 1.774 (4) | W2—O5 | 1.778 (6) |
<Mo2—O> | 1.759 | <W2—O> | 1.788 |
| | | |
K1 octahedron | | | |
K1—O4 | 2.690 (5) (× 3) | K1—O4 | 2.925 (18) (× 2) |
K1—O4' | 2.812 (5) (× 3) | K1—O4' | 2.655 (15) (× 2) |
<K1—O> | 2.751 | <K1—O> | 2.790 |
| | | |
K2 polyhedron | | | |
K2—O5 | 2.709 (5) | K2—O5 | 2.790 (14) |
K2—O3 | 2.844 (4) (× 2) | K2—O3 | 2.766 (14) (× 2) |
K2—O2 | 3.0295 (13) (× 2) | K2—O2 | 3.060 (9) (× 2) |
K2—O3' | 3.051 (6) (× 2) | K2—O3' | 3.165 (15) (× 2) |
K2—O4 | 3.2567 (17) (× 2) | K2—O4 | 3.260 (8) (× 2) |
<K2—O> | 3.008 | <K2—O> | 3.032 |
| | | |
K3 octahedron | | | |
K3—O3 | 2.640 (5) (× 2) | K3—O3 | 2.550 (14) (× 2) |
K3—O2 | 2.689 (9) | K3—O2 | 2.733 (10) |
K3—O2' | 2.791 (9) | K3—O2' | 2.737 (10) |
K3—O5 | 2.909 (6) (× 2) | K3—O5 | 2.968 (6) (× 2) |
<K3—O> | 2.763 | <K3—O> | 2.751 |
| | | |
Ag1 tetrahedron | | | |
Ag1—O5 | 2.321 (4) (× 3) | Ag1—O5 | 2.3379 (5) (× 3) |
Ag1—O1 | 2.289 (17) | Ag1—O1 | 2.356 (3) |
<Ag1—O> | 2.313 | <Ag1—O> | 2.342 |
| | | |
Ag2 polyhedron | | | |
Ag2—O3 | 2.470 (12) (× 2) | | |
Ag2—O2 | 2.69 (3) (× 2) | | |
Ag2—O5 | 3.088 (19) (× 2) | | |
<Ag2—O> | 2.749 | | |
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