A New Pentachlorotellurate(IV): catena-Poly[hexakis(acetonitrile)aluminium tris[tetrachlorotellurate(IV)-μ-chloro] acetonitrile]

Favier, F.; Pascal, J.L.; Belin, C.; Tillard-Charbonnel, M.

doi:10.1107/S0108270197004824

A New Pentachlorotellurate(IV): catena-Poly[hexakis(acetonitrile)aluminium tris[tetrachlorotellurate(IV)-μ-chloro] acetonitrile]

F. Favier, J. L. Pascal, C. Belin and M. Tillard-Charbonnel

In the title compound, [Al(CH₃CN)₆][TeCl₅]₃. CH₃CN, the polymeric anions form infinite helical chains from apex-sharing distorted octahedral TeCl₆ units. These anionic chains are stabilized by [Al(CH₃CN)₆]³⁺ counterions.

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A New Pentachlorotellurate(IV): catena-Poly[hexakis(acetonitrile)aluminium tris[tetrachlorotellurate(IV)-μ-chloro] acetonitrile]

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	Crystallographic Information File (CIF) Contains datablocks global, TeClAlAce
	Structure factor file (CIF format) Contains datablock ww