Octakis(dimethyl sulfoxide-O)gadolinium(III) Hexacyanoferrate(III)

Klinga, M.; Cuesta, R.; Moreno, J.M.; Dominguez-Vera, J.M.; Colacio, E.; Kivekäs, R.

doi:10.1107/S0108270198004545

Octakis(dimethyl sulfoxide-O)gadolinium(III) Hexacyanoferrate(III)

M. Klinga, R. Cuesta, J. M. Moreno, J. M. Dominguez-Vera, E. Colacio and R. Kivekäs

In [Gd(C₂H₆OS)₈][Fe(CN)₆], the central atom of the [Gd(C₂H₆OS)₈]³⁺ complex cation occupies a twofold axis, while in the [Fe(CN)₆]^3- anion it is positioned on a centre of inversion. Gd-O bond lengths vary between 2.374 (5) and 2.417 (5) Å, but the Fe-C distances of 1.943 (8)-1.952 (8) Å are equal, within experimental error.

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Octakis(dimethyl sulfoxide-O)gadolinium(III) Hexacyanoferrate(III)

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	Crystallographic Information File (CIF) Contains datablocks rgd, global
	Structure factor file (CIF format) Contains datablock rgd