Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270100006843/qa0298sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S0108270100006843/qa0298Isup2.hkl |
CCDC reference: 146090
Data collection: CAD-4 Operations Manual (Enraf-Nonius, 1977); cell refinement: CAD-4 Operations Manual; data reduction: DATARED (Pèpe, 1979); program(s) used to solve structure: SHELXS86 (Sheldrick, 1985); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: PLATON (Spek, 1990).
[Cr(C15H14O)(CO)3] | F(000) = 712 |
Mr = 346.29 | Dx = 1.456 Mg m−3 Dm = 1.45 (2) Mg m−3 Dm measured by Flotation in (Benzene/Chloroform) |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 12.190 (2) Å | Cell parameters from 25 reflections |
b = 9.147 (2) Å | θ = 9–15° |
c = 14.612 (3) Å | µ = 0.74 mm−1 |
β = 104.20 (2)° | T = 293 K |
V = 1579.5 (5) Å3 | Square platelet, red |
Z = 4 | 0.32 × 0.30 × 0.21 mm |
Nonius CAD-4 diffractometer | 4072 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | θmax = 30.2°, θmin = 2.0° |
Graphite monochromator | h = −16→16 |
ω/2θ scans | k = 0→12 |
Absorption correction: ψ scans (North et al., 1968) | l = 0→20 |
Tmin = 0.785, Tmax = 0.856 | 3 standard reflections every 60 min |
4663 measured reflections | intensity decay: none |
4663 independent reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.036 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.073 | Only H-atom coordinates refined |
S = 0.98 | Calculated w = 1/[σ2(Fo2) + (0.040P)2] where P = (Fo2 + 2Fc2)/3 |
4663 reflections | (Δ/σ)max = 0.002 |
250 parameters | Δρmax = 0.42 e Å−3 |
14 restraints | Δρmin = −0.26 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement on F2 for ALL reflections except for 0 with very negative F2 or flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The observed criterion of F2 > σ(F2) is used only for calculating _R_factor_obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Cr | 0.725047 (15) | 0.27169 (2) | 0.421771 (13) | 0.03160 (6) | |
C2 | 0.63706 (13) | 0.2134 (2) | 0.50202 (10) | 0.0525 (3) | |
O3 | 0.58353 (15) | 0.1779 (3) | 0.55139 (12) | 0.0980 (6) | |
C4 | 0.61716 (10) | 0.20193 (14) | 0.32023 (9) | 0.0377 (2) | |
O5 | 0.55113 (10) | 0.16002 (15) | 0.25553 (8) | 0.0598 (3) | |
C6 | 0.65063 (14) | 0.44741 (17) | 0.40515 (12) | 0.0523 (3) | |
O7 | 0.60292 (15) | 0.55714 (17) | 0.39262 (13) | 0.0905 (5) | |
C8 | 0.85745 (11) | 0.22875 (15) | 0.34544 (9) | 0.0397 (2) | |
C9 | 0.87721 (12) | 0.36545 (16) | 0.38713 (11) | 0.0453 (3) | |
C10 | 0.88708 (11) | 0.38202 (14) | 0.48535 (11) | 0.0434 (3) | |
C11 | 0.87876 (10) | 0.26017 (13) | 0.54063 (9) | 0.0363 (2) | |
C12 | 0.86641 (9) | 0.11498 (12) | 0.50096 (8) | 0.03060 (19) | |
C13 | 0.85386 (9) | 0.10027 (12) | 0.40071 (8) | 0.0316 (2) | |
C14 | 0.83557 (11) | −0.04192 (14) | 0.35979 (8) | 0.0376 (2) | |
C15 | 0.82969 (12) | −0.16109 (14) | 0.41282 (9) | 0.0392 (2) | |
C16 | 0.84096 (10) | −0.14649 (12) | 0.51141 (8) | 0.0338 (2) | |
C17 | 0.86168 (9) | −0.01307 (12) | 0.55651 (7) | 0.0310 (2) | |
C18 | 0.88723 (11) | −0.01345 (14) | 0.65950 (8) | 0.0372 (2) | |
C19 | 0.86368 (12) | −0.13166 (16) | 0.70411 (9) | 0.0426 (3) | |
C20 | 0.80350 (12) | −0.25997 (15) | 0.64990 (10) | 0.0432 (3) | |
O21 | 0.83591 (9) | −0.27235 (10) | 0.55959 (7) | 0.0422 (2) | |
C22 | 0.67646 (16) | −0.2406 (2) | 0.62840 (17) | 0.0607 (4) | |
C23 | 0.8397 (2) | −0.4047 (2) | 0.69920 (15) | 0.0618 (4) | |
H8 | 0.8465 (17) | 0.216 (2) | 0.2800 (14) | 0.053* | |
H9 | 0.8797 (15) | 0.449 (2) | 0.3494 (13) | 0.048* | |
H10 | 0.8964 (14) | 0.4869 (18) | 0.5119 (12) | 0.041* | |
H11 | 0.8836 (15) | 0.2632 (19) | 0.6048 (12) | 0.041* | |
H14 | 0.8304 (15) | −0.045 (2) | 0.2925 (13) | 0.048* | |
H15 | 0.8263 (15) | −0.2520 (18) | 0.3851 (12) | 0.040* | |
H18 | 0.9284 (15) | 0.069 (2) | 0.6932 (13) | 0.047* | |
H19 | 0.8833 (17) | −0.145 (2) | 0.7675 (14) | 0.058* | |
H221 | 0.656 (2) | −0.228 (3) | 0.6854 (17) | 0.073* | |
H222 | 0.662 (2) | −0.161 (3) | 0.5967 (17) | 0.073* | |
H223 | 0.641 (2) | −0.311 (3) | 0.5929 (17) | 0.073* | |
H231 | 0.9167 (17) | −0.414 (2) | 0.7127 (14) | 0.056* | |
H232 | 0.8216 (17) | −0.393 (2) | 0.7576 (14) | 0.056* | |
H233 | 0.7999 (17) | −0.481 (2) | 0.6597 (14) | 0.056* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Cr | 0.03068 (9) | 0.03117 (9) | 0.03098 (9) | 0.00232 (6) | 0.00379 (6) | 0.00045 (6) |
C2 | 0.0402 (6) | 0.0755 (10) | 0.0404 (6) | 0.0123 (7) | 0.0069 (5) | 0.0094 (7) |
O3 | 0.0706 (9) | 0.1621 (18) | 0.0729 (9) | 0.0160 (11) | 0.0399 (8) | 0.0373 (11) |
C4 | 0.0353 (5) | 0.0372 (5) | 0.0394 (5) | 0.0003 (4) | 0.0068 (4) | 0.0011 (4) |
O5 | 0.0518 (6) | 0.0696 (7) | 0.0493 (6) | −0.0103 (5) | −0.0045 (5) | −0.0094 (5) |
C6 | 0.0520 (7) | 0.0435 (7) | 0.0540 (8) | 0.0107 (6) | −0.0011 (6) | −0.0046 (6) |
O7 | 0.0947 (11) | 0.0586 (8) | 0.1009 (12) | 0.0404 (8) | −0.0091 (9) | −0.0062 (8) |
C8 | 0.0372 (5) | 0.0437 (6) | 0.0393 (6) | 0.0009 (5) | 0.0117 (4) | 0.0060 (5) |
C9 | 0.0425 (6) | 0.0400 (6) | 0.0531 (7) | −0.0045 (5) | 0.0109 (5) | 0.0089 (5) |
C10 | 0.0394 (6) | 0.0336 (5) | 0.0535 (7) | −0.0064 (5) | 0.0040 (5) | −0.0022 (5) |
C11 | 0.0345 (5) | 0.0345 (5) | 0.0348 (5) | −0.0014 (4) | −0.0015 (4) | −0.0053 (4) |
C12 | 0.0275 (4) | 0.0311 (5) | 0.0307 (4) | 0.0006 (4) | 0.0024 (3) | −0.0041 (4) |
C13 | 0.0307 (5) | 0.0325 (5) | 0.0309 (5) | 0.0020 (4) | 0.0060 (4) | −0.0013 (4) |
C14 | 0.0426 (6) | 0.0391 (6) | 0.0303 (5) | 0.0033 (5) | 0.0077 (4) | −0.0059 (4) |
C15 | 0.0470 (6) | 0.0331 (5) | 0.0362 (5) | 0.0011 (5) | 0.0075 (5) | −0.0092 (4) |
C16 | 0.0354 (5) | 0.0295 (5) | 0.0360 (5) | 0.0037 (4) | 0.0077 (4) | −0.0014 (4) |
C17 | 0.0303 (4) | 0.0323 (5) | 0.0285 (4) | 0.0037 (4) | 0.0036 (4) | −0.0021 (4) |
C18 | 0.0397 (5) | 0.0391 (6) | 0.0304 (5) | 0.0034 (4) | 0.0036 (4) | −0.0037 (4) |
C19 | 0.0470 (6) | 0.0473 (7) | 0.0338 (5) | 0.0054 (5) | 0.0108 (5) | 0.0025 (5) |
C20 | 0.0482 (7) | 0.0399 (6) | 0.0455 (6) | 0.0040 (5) | 0.0192 (5) | 0.0046 (5) |
O21 | 0.0555 (5) | 0.0306 (4) | 0.0432 (4) | 0.0048 (4) | 0.0174 (4) | 0.0005 (3) |
C22 | 0.0490 (8) | 0.0613 (10) | 0.0749 (12) | −0.0023 (7) | 0.0212 (8) | −0.0048 (9) |
C23 | 0.0846 (13) | 0.0469 (8) | 0.0621 (10) | 0.0109 (8) | 0.0337 (9) | 0.0153 (7) |
Cr—C6 | 1.8323 (15) | C12—C13 | 1.4412 (15) |
Cr—C4 | 1.8387 (13) | C13—C14 | 1.4259 (16) |
Cr—C2 | 1.8510 (16) | C14—C15 | 1.3494 (19) |
Cr—C10 | 2.2097 (13) | C14—H14 | 0.970 (18) |
Cr—C8 | 2.2105 (13) | C15—C16 | 1.4195 (17) |
Cr—C9 | 2.2120 (14) | C15—H15 | 0.921 (16) |
Cr—C11 | 2.2230 (13) | C16—O21 | 1.3587 (15) |
Cr—C13 | 2.2926 (11) | C16—C17 | 1.3804 (15) |
Cr—C12 | 2.3205 (11) | C17—C18 | 1.4601 (16) |
C2—O3 | 1.133 (2) | C18—C19 | 1.3298 (19) |
C4—O5 | 1.1468 (17) | C18—H18 | 0.973 (18) |
C6—O7 | 1.152 (2) | C19—C20 | 1.503 (2) |
C8—C9 | 1.386 (2) | C19—H19 | 0.905 (19) |
C8—C13 | 1.4327 (17) | C20—O21 | 1.4718 (16) |
C8—H8 | 0.940 (19) | C20—C22 | 1.513 (2) |
C9—C10 | 1.419 (2) | C20—C23 | 1.520 (2) |
C9—H9 | 0.946 (18) | C22—H221 | 0.93 (2) |
C10—C11 | 1.3947 (19) | C22—H222 | 0.85 (2) |
C10—H10 | 1.030 (17) | C22—H223 | 0.87 (2) |
C11—C12 | 1.4420 (15) | C23—H231 | 0.91 (2) |
C11—H11 | 0.926 (17) | C23—H232 | 0.939 (19) |
C12—C17 | 1.4343 (16) | C23—H233 | 0.96 (2) |
C6—Cr—C4 | 87.97 (6) | Cr—C10—H10 | 126.0 (10) |
C6—Cr—C2 | 89.52 (8) | C10—C11—C12 | 121.23 (11) |
C4—Cr—C2 | 90.02 (7) | C10—C11—Cr | 71.14 (7) |
C6—Cr—C10 | 91.00 (6) | C12—C11—Cr | 75.21 (6) |
C4—Cr—C10 | 152.42 (6) | C10—C11—H11 | 124.6 (11) |
C2—Cr—C10 | 117.53 (7) | C12—C11—H11 | 114.2 (11) |
C6—Cr—C8 | 119.21 (7) | Cr—C11—H11 | 128.5 (11) |
C4—Cr—C8 | 89.85 (6) | C17—C12—C13 | 119.33 (10) |
C2—Cr—C8 | 151.25 (7) | C17—C12—C11 | 122.64 (10) |
C10—Cr—C8 | 66.75 (6) | C13—C12—C11 | 117.98 (10) |
C6—Cr—C9 | 92.59 (7) | C17—C12—Cr | 131.19 (8) |
C4—Cr—C9 | 115.08 (6) | C13—C12—Cr | 70.74 (6) |
C2—Cr—C9 | 154.86 (7) | C11—C12—Cr | 67.86 (6) |
C10—Cr—C9 | 37.43 (6) | C14—C13—C8 | 122.35 (11) |
C8—Cr—C9 | 36.52 (5) | C14—C13—C12 | 118.56 (10) |
C6—Cr—C11 | 116.11 (6) | C8—C13—C12 | 119.08 (11) |
C4—Cr—C11 | 155.92 (5) | C14—C13—Cr | 129.66 (8) |
C2—Cr—C11 | 89.99 (6) | C8—C13—Cr | 68.36 (7) |
C10—Cr—C11 | 36.68 (5) | C12—C13—Cr | 72.85 (6) |
C8—Cr—C11 | 78.81 (5) | C15—C14—C13 | 121.39 (11) |
C9—Cr—C11 | 66.65 (5) | C15—C14—H14 | 124.1 (11) |
C6—Cr—C13 | 156.25 (7) | C13—C14—H14 | 114.5 (11) |
C4—Cr—C13 | 91.85 (5) | C14—C15—C16 | 120.08 (11) |
C2—Cr—C13 | 114.24 (6) | C14—C15—H15 | 118.7 (11) |
C10—Cr—C13 | 78.33 (5) | C16—C15—H15 | 120.9 (11) |
C8—Cr—C13 | 37.05 (4) | O21—C16—C17 | 121.87 (11) |
C9—Cr—C13 | 66.05 (5) | O21—C16—C15 | 116.15 (10) |
C11—Cr—C13 | 66.34 (4) | C17—C16—C15 | 121.90 (11) |
C6—Cr—C12 | 152.99 (6) | C16—C17—C12 | 118.68 (10) |
C4—Cr—C12 | 118.99 (5) | C16—C17—C18 | 117.24 (10) |
C2—Cr—C12 | 88.92 (6) | C12—C17—C18 | 123.86 (10) |
C10—Cr—C12 | 66.08 (5) | C19—C18—C17 | 119.35 (12) |
C8—Cr—C12 | 66.23 (5) | C19—C18—H18 | 122.1 (11) |
C9—Cr—C12 | 77.98 (5) | C17—C18—H18 | 118.2 (11) |
C11—Cr—C12 | 36.93 (4) | C18—C19—C20 | 120.85 (12) |
C13—Cr—C12 | 36.40 (4) | C18—C19—H19 | 125.0 (14) |
O3—C2—Cr | 179.8 (2) | C20—C19—H19 | 114.2 (14) |
O5—C4—Cr | 178.42 (13) | O21—C20—C19 | 109.21 (11) |
O7—C6—Cr | 178.48 (16) | O21—C20—C22 | 107.99 (13) |
C9—C8—C13 | 121.23 (12) | C19—C20—C22 | 111.12 (13) |
C9—C8—Cr | 71.80 (8) | O21—C20—C23 | 104.31 (12) |
C13—C8—Cr | 74.59 (7) | C19—C20—C23 | 112.52 (14) |
C9—C8—H8 | 121.8 (12) | C22—C20—C23 | 111.35 (15) |
C13—C8—H8 | 116.9 (12) | C16—O21—C20 | 117.10 (9) |
Cr—C8—H8 | 126.6 (12) | C20—C22—H221 | 108.1 (16) |
C8—C9—C10 | 120.23 (12) | C20—C22—H222 | 105.8 (17) |
C8—C9—Cr | 71.68 (8) | H221—C22—H222 | 109 (2) |
C10—C9—Cr | 71.20 (8) | C20—C22—H223 | 111.8 (17) |
C8—C9—H9 | 119.8 (11) | H221—C22—H223 | 115 (2) |
C10—C9—H9 | 119.8 (11) | H222—C22—H223 | 107 (2) |
Cr—C9—H9 | 126.5 (11) | C20—C23—H231 | 110.3 (14) |
C11—C10—C9 | 120.02 (12) | C20—C23—H232 | 102.9 (13) |
C11—C10—Cr | 72.18 (7) | H231—C23—H232 | 105.8 (18) |
C9—C10—Cr | 71.38 (8) | C20—C23—H233 | 107.6 (13) |
C11—C10—H10 | 122.9 (10) | H231—C23—H233 | 114.0 (18) |
C9—C10—H10 | 117.1 (10) | H232—C23—H233 | 115.8 (18) |
C6—Cr—C2—O3 | −98 (50) | C10—C11—C12—C17 | 177.72 (11) |
C4—Cr—C2—O3 | 174 (100) | Cr—C11—C12—C17 | −125.71 (10) |
C10—Cr—C2—O3 | −7 (50) | C10—C11—C12—C13 | −4.83 (17) |
C8—Cr—C2—O3 | 84 (50) | Cr—C11—C12—C13 | 51.73 (9) |
C9—Cr—C2—O3 | −3 (50) | C10—C11—C12—Cr | −56.57 (11) |
C11—Cr—C2—O3 | 18 (50) | C6—Cr—C12—C17 | 110.08 (16) |
C13—Cr—C2—O3 | 82 (50) | C4—Cr—C12—C17 | −66.16 (11) |
C12—Cr—C2—O3 | 55 (50) | C2—Cr—C12—C17 | 23.27 (11) |
C6—Cr—C4—O5 | 79 (5) | C10—Cr—C12—C17 | 144.21 (11) |
C2—Cr—C4—O5 | 169 (5) | C8—Cr—C12—C17 | −141.85 (11) |
C10—Cr—C4—O5 | −9 (5) | C9—Cr—C12—C17 | −178.33 (11) |
C8—Cr—C4—O5 | −40 (5) | C11—Cr—C12—C17 | 114.69 (13) |
C9—Cr—C4—O5 | −13 (5) | C13—Cr—C12—C17 | −112.57 (12) |
C11—Cr—C4—O5 | −101 (5) | C6—Cr—C12—C13 | −137.34 (15) |
C13—Cr—C4—O5 | −77 (5) | C4—Cr—C12—C13 | 46.41 (8) |
C12—Cr—C4—O5 | −102 (5) | C2—Cr—C12—C13 | 135.84 (8) |
C4—Cr—C6—O7 | −26 (7) | C10—Cr—C12—C13 | −103.22 (8) |
C2—Cr—C6—O7 | −116 (7) | C8—Cr—C12—C13 | −29.27 (7) |
C10—Cr—C6—O7 | 127 (7) | C9—Cr—C12—C13 | −65.76 (7) |
C8—Cr—C6—O7 | 63 (7) | C11—Cr—C12—C13 | −132.74 (10) |
C9—Cr—C6—O7 | 89 (7) | C6—Cr—C12—C11 | −4.60 (17) |
C11—Cr—C6—O7 | 154 (7) | C4—Cr—C12—C11 | 179.15 (8) |
C13—Cr—C6—O7 | 64 (7) | C2—Cr—C12—C11 | −91.42 (9) |
C12—Cr—C6—O7 | 158 (7) | C10—Cr—C12—C11 | 29.52 (8) |
C6—Cr—C8—C9 | 48.10 (10) | C8—Cr—C12—C11 | 103.47 (8) |
C4—Cr—C8—C9 | 135.69 (9) | C9—Cr—C12—C11 | 66.98 (8) |
C2—Cr—C8—C9 | −134.53 (13) | C13—Cr—C12—C11 | 132.74 (10) |
C10—Cr—C8—C9 | −29.29 (8) | C9—C8—C13—C14 | −178.93 (12) |
C11—Cr—C8—C9 | −65.70 (8) | Cr—C8—C13—C14 | 124.16 (11) |
C13—Cr—C8—C9 | −131.05 (11) | C9—C8—C13—C12 | 2.60 (18) |
C12—Cr—C8—C9 | −102.26 (9) | Cr—C8—C13—C12 | −54.30 (9) |
C6—Cr—C8—C13 | 179.14 (8) | C9—C8—C13—Cr | 56.91 (11) |
C4—Cr—C8—C13 | −93.26 (8) | C17—C12—C13—C14 | 0.81 (16) |
C2—Cr—C8—C13 | −3.48 (16) | C11—C12—C13—C14 | −176.72 (10) |
C10—Cr—C8—C13 | 101.76 (8) | Cr—C12—C13—C14 | −126.34 (10) |
C9—Cr—C8—C13 | 131.05 (11) | C17—C12—C13—C8 | 179.34 (10) |
C11—Cr—C8—C13 | 65.35 (7) | C11—C12—C13—C8 | 1.80 (16) |
C12—Cr—C8—C13 | 28.79 (6) | Cr—C12—C13—C8 | 52.19 (9) |
C13—C8—C9—C10 | −4.1 (2) | C17—C12—C13—Cr | 127.15 (10) |
Cr—C8—C9—C10 | 54.13 (12) | C11—C12—C13—Cr | −50.38 (9) |
C13—C8—C9—Cr | −58.23 (11) | C6—Cr—C13—C14 | −116.61 (16) |
C6—Cr—C9—C8 | −139.44 (9) | C4—Cr—C13—C14 | −27.45 (11) |
C4—Cr—C9—C8 | −50.47 (9) | C2—Cr—C13—C14 | 63.40 (12) |
C2—Cr—C9—C8 | 126.18 (16) | C10—Cr—C13—C14 | 178.53 (11) |
C10—Cr—C9—C8 | 132.30 (12) | C8—Cr—C13—C14 | −114.76 (13) |
C11—Cr—C9—C8 | 103.15 (9) | C9—Cr—C13—C14 | −144.17 (12) |
C13—Cr—C9—C8 | 29.81 (7) | C11—Cr—C13—C14 | 142.01 (12) |
C12—Cr—C9—C8 | 66.12 (8) | C12—Cr—C13—C14 | 113.21 (13) |
C6—Cr—C9—C10 | 88.26 (9) | C6—Cr—C13—C8 | −1.85 (17) |
C4—Cr—C9—C10 | 177.23 (8) | C4—Cr—C13—C8 | 87.31 (8) |
C2—Cr—C9—C10 | −6.12 (19) | C2—Cr—C13—C8 | 178.16 (9) |
C8—Cr—C9—C10 | −132.30 (12) | C10—Cr—C13—C8 | −66.71 (8) |
C11—Cr—C9—C10 | −29.15 (8) | C9—Cr—C13—C8 | −29.41 (8) |
C13—Cr—C9—C10 | −102.49 (9) | C11—Cr—C13—C8 | −103.23 (8) |
C12—Cr—C9—C10 | −66.18 (8) | C12—Cr—C13—C8 | −132.03 (10) |
C8—C9—C10—C11 | 1.1 (2) | C6—Cr—C13—C12 | 130.18 (14) |
Cr—C9—C10—C11 | 55.41 (11) | C4—Cr—C13—C12 | −140.66 (7) |
C8—C9—C10—Cr | −54.36 (12) | C2—Cr—C13—C12 | −49.80 (9) |
C6—Cr—C10—C11 | 135.52 (9) | C10—Cr—C13—C12 | 65.32 (7) |
C4—Cr—C10—C11 | −136.94 (11) | C8—Cr—C13—C12 | 132.03 (10) |
C2—Cr—C10—C11 | 45.55 (11) | C9—Cr—C13—C12 | 102.62 (8) |
C8—Cr—C10—C11 | −102.90 (9) | C11—Cr—C13—C12 | 28.80 (6) |
C9—Cr—C10—C11 | −131.52 (12) | C8—C13—C14—C15 | −178.33 (12) |
C13—Cr—C10—C11 | −65.87 (8) | C12—C13—C14—C15 | 0.14 (18) |
C12—Cr—C10—C11 | −29.71 (7) | Cr—C13—C14—C15 | −90.73 (14) |
C6—Cr—C10—C9 | −92.95 (10) | C13—C14—C15—C16 | 0.5 (2) |
C4—Cr—C10—C9 | −5.42 (16) | C14—C15—C16—O21 | −178.91 (12) |
C2—Cr—C10—C9 | 177.07 (9) | C14—C15—C16—C17 | −2.13 (19) |
C8—Cr—C10—C9 | 28.63 (8) | O21—C16—C17—C12 | 179.65 (10) |
C11—Cr—C10—C9 | 131.52 (12) | C15—C16—C17—C12 | 3.05 (17) |
C13—Cr—C10—C9 | 65.66 (8) | O21—C16—C17—C18 | 4.84 (17) |
C12—Cr—C10—C9 | 101.81 (9) | C15—C16—C17—C18 | −171.75 (11) |
C9—C10—C11—C12 | 3.47 (19) | C13—C12—C17—C16 | −2.37 (16) |
Cr—C10—C11—C12 | 58.50 (10) | C11—C12—C17—C16 | 175.04 (11) |
C9—C10—C11—Cr | −55.03 (12) | Cr—C12—C17—C16 | 87.00 (13) |
C6—Cr—C11—C10 | −51.27 (11) | C13—C12—C17—C18 | 172.07 (10) |
C4—Cr—C11—C10 | 129.24 (13) | C11—C12—C17—C18 | −10.52 (17) |
C2—Cr—C11—C10 | −140.73 (10) | Cr—C12—C17—C18 | −98.56 (12) |
C8—Cr—C11—C10 | 65.92 (9) | C16—C17—C18—C19 | −15.90 (17) |
C9—Cr—C11—C10 | 29.71 (8) | C12—C17—C18—C19 | 169.58 (12) |
C13—Cr—C11—C10 | 102.64 (9) | C17—C18—C19—C20 | −4.56 (19) |
C12—Cr—C11—C10 | 131.05 (12) | C18—C19—C20—O21 | 32.53 (17) |
C6—Cr—C11—C12 | 177.67 (9) | C18—C19—C20—C22 | −86.50 (17) |
C4—Cr—C11—C12 | −1.81 (16) | C18—C19—C20—C23 | 147.86 (14) |
C2—Cr—C11—C12 | 88.22 (9) | C17—C16—O21—C20 | 26.14 (17) |
C10—Cr—C11—C12 | −131.05 (12) | C15—C16—O21—C20 | −157.08 (12) |
C8—Cr—C11—C12 | −65.13 (7) | C19—C20—O21—C16 | −42.78 (15) |
C9—Cr—C11—C12 | −101.35 (8) | C22—C20—O21—C16 | 78.18 (15) |
C13—Cr—C11—C12 | −28.42 (6) | C23—C20—O21—C16 | −163.28 (14) |
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