Methyl­tri­phenyl­stibonium tetra­fluoro­borate

In the title compound, [Sb(CH₃)(C₆H₅)₃]BF₄, there are four independent cations and anions in the asymmetric unit. The geometry around the Sb atom is distorted tetrahedral, with Sb-C distances in the range 2.077 (4)-2.099 (10) Å and angles at the Sb atom in the range 103.3 (3)-119.0 (4)°.

S1. Comment

Examination of the structure with PLATON (Spek, 2000) showed that there were no solvent-accessible voids in the crystal lattice.

S2. Experimental

The title compound was prepared from Ph₃Sb and [Me₃O][BF₄], following a published procedure (Henry & Wittig, 1960). The material was recrystallized from aqueous EtOH (m.p. 408–409 K).

S3. Refinement

Compound (I) crystallized in the triclinic system; space group P1 was assumed and confirmed by the analysis. The BF₄ anions and the phenyl rings showed large librational effects and were accordingly refined as rigid groups with anisotropic displacement parameters. The F-atom positions of the BF₄ anions were restrained using the DFIX option of SHELXL97 (Sheldrick, 1997), based on difference-map peaks. All H atoms were placed in calculated positions. In the case of the methyl H atoms, these were placed as six half-H atoms at the corners of a regular hexagon, and refined as riding atoms. The C—H distances were 0.93 and 0.96 Å. The largest peaks on the difference map were adjacent to B3, 1.25–1.46 Å, and its adjacent F atoms, and to the Sb atoms, 1.17–1.28 Å.

Computing details

Data collection: CAD-4-PC Software (Enraf-Nonius, 1992); cell refinement: SET4 and CELDIM in CAD-4-PC Software; data reduction: DATRD2 in NRCVAX (Gabe et al., 1989); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: NRCVAX, SHELXL97 and WORDPERFECT macro PREP8 (Ferguson, 1998).

methyltriphenylstibonium tetrafluoroborate

Crystal data

[Sb(CH3)(C6H5)3]BF4	Z = 8
Mr = 454.90	F(000) = 1792
Triclinic, P1	Dx = 1.583 Mg m^−3
a = 12.874 (4) Å	Mo Kα radiation, λ = 0.70930 Å
b = 13.760 (5) Å	Cell parameters from 25 reflections
c = 24.974 (7) Å	θ = 9.5–11.9°
α = 98.82 (3)°	µ = 1.48 mm^−1
β = 93.97 (2)°	T = 293 K
γ = 117.80 (3)°	Block, colourless
V = 3817 (2) Å^3	0.42 × 0.28 × 0.26 mm

Data collection

Enraf-Nonius CAD-4 diffractometer	8121 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	θmax = 25.4°, θmin = 2.0°
Graphite monochromator	h = −15→13
ω/2θ scans	k = 0→16
Absorption correction: gaussian (NRCVAX; Gabe et al., 1989)	l = −30→29
Tmin = 0.689, Tmax = 0.715	3 standard reflections every 120 min
14181 measured reflections	intensity decay: 3%
14181 independent reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.057	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.181	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0943P)^2 + 4.9573P] where P = (Fo^2 + 2Fc^2)/3
14181 reflections	(Δ/σ)max = 0.005
722 parameters	Δρmax = 1.15 e Å^−3
0 restraints	Δρmin = −0.78 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Sb1	0.60137 (6)	0.15922 (5)	0.11741 (2)	0.07008 (19)
Sb2	0.92577 (6)	0.81482 (6)	0.08202 (3)	0.07138 (19)
Sb3	0.20603 (5)	0.08417 (5)	0.43431 (2)	0.05697 (16)
Sb4	0.83974 (5)	0.39753 (5)	0.38364 (2)	0.06388 (18)
C17	0.5375 (9)	−0.0145 (8)	0.0938 (4)	0.095 (3)
C111	0.7691 (5)	0.2341 (6)	0.1656 (3)	0.073 (2)
C112	0.8369 (7)	0.1796 (5)	0.1642 (3)	0.098 (3)
C113	0.9519 (7)	0.2340 (8)	0.1932 (4)	0.120 (4)
C114	0.9993 (5)	0.3430 (9)	0.2237 (3)	0.118 (5)
C115	0.9315 (7)	0.3975 (6)	0.2251 (3)	0.113 (4)
C116	0.8165 (7)	0.3431 (6)	0.1960 (3)	0.102 (3)
C121	0.6228 (7)	0.2524 (6)	0.0570 (2)	0.078 (3)
C122	0.7360 (6)	0.3149 (7)	0.0448 (3)	0.108 (4)
C123	0.7529 (7)	0.3798 (7)	0.0054 (4)	0.133 (5)
C124	0.6564 (9)	0.3822 (7)	−0.0218 (3)	0.129 (5)
C125	0.5432 (8)	0.3197 (8)	−0.0096 (3)	0.118 (4)
C126	0.5263 (5)	0.2548 (6)	0.0298 (3)	0.093 (3)
C131	0.4800 (5)	0.1783 (6)	0.1637 (2)	0.075 (3)
C132	0.4888 (6)	0.2833 (5)	0.1806 (3)	0.093 (3)
C133	0.4074 (7)	0.2943 (6)	0.2113 (3)	0.099 (4)
C134	0.3173 (6)	0.2003 (8)	0.2252 (3)	0.118 (5)
C135	0.3085 (6)	0.0953 (7)	0.2083 (3)	0.113 (4)
C136	0.3899 (7)	0.0843 (5)	0.1776 (3)	0.097 (3)
C27	0.9939 (9)	0.9877 (8)	0.0945 (4)	0.090 (3)
C211	0.8840 (6)	0.7387 (6)	−0.0009 (2)	0.076 (3)
C212	0.7983 (7)	0.7477 (7)	−0.0336 (4)	0.123 (5)
C213	0.7633 (8)	0.6931 (9)	−0.0885 (3)	0.164 (8)
C214	0.8139 (10)	0.6295 (8)	−0.1107 (2)	0.173 (10)
C215	0.8996 (9)	0.6205 (7)	−0.0780 (4)	0.184 (9)
C216	0.9346 (7)	0.6751 (7)	−0.0231 (3)	0.112 (4)
C221	0.7637 (5)	0.7367 (6)	0.1101 (3)	0.080 (3)
C222	0.7271 (6)	0.7939 (5)	0.1483 (3)	0.103 (4)
C223	0.6193 (7)	0.7362 (8)	0.1665 (3)	0.116 (4)
C224	0.5482 (5)	0.6213 (8)	0.1465 (4)	0.115 (4)
C225	0.5848 (7)	0.5642 (5)	0.1082 (4)	0.123 (4)
C226	0.6926 (7)	0.6219 (6)	0.0900 (3)	0.110 (4)
C231	1.0413 (7)	0.7700 (8)	0.1206 (3)	0.088 (3)
C232	1.1501 (8)	0.7937 (8)	0.1042 (4)	0.140 (6)
C233	1.2225 (8)	0.7586 (10)	0.1295 (5)	0.163 (7)
C234	1.1860 (12)	0.6998 (11)	0.1712 (5)	0.191 (9)
C235	1.0772 (13)	0.6761 (12)	0.1876 (5)	0.274 (16)
C236	1.0048 (9)	0.7112 (11)	0.1623 (4)	0.196 (9)
C37	0.0205 (7)	−0.0083 (8)	0.4161 (4)	0.073 (2)
C311	0.2901 (4)	−0.0073 (4)	0.4061 (2)	0.0579 (19)
C312	0.2372 (4)	−0.0971 (5)	0.3612 (2)	0.079 (3)
C313	0.2961 (6)	−0.1560 (5)	0.3439 (2)	0.096 (3)
C314	0.4080 (6)	−0.1252 (5)	0.3715 (3)	0.082 (3)
C315	0.4609 (4)	−0.0355 (5)	0.4164 (2)	0.077 (3)
C316	0.4020 (5)	0.0235 (4)	0.4337 (2)	0.065 (2)
C321	0.2649 (5)	0.1370 (4)	0.51910 (17)	0.0540 (18)
C322	0.2593 (5)	0.0587 (4)	0.5496 (3)	0.069 (2)
C323	0.2909 (6)	0.0905 (6)	0.6063 (2)	0.092 (3)
C324	0.3281 (6)	0.2007 (7)	0.63267 (17)	0.085 (3)
C325	0.3338 (6)	0.2790 (5)	0.6022 (2)	0.104 (4)
C326	0.3021 (6)	0.2472 (4)	0.5454 (2)	0.082 (3)
C331	0.2774 (5)	0.2276 (4)	0.4013 (2)	0.0572 (19)
C332	0.2061 (4)	0.2564 (5)	0.3703 (2)	0.079 (3)
C333	0.2579 (7)	0.3493 (6)	0.3464 (2)	0.093 (3)
C334	0.3810 (7)	0.4134 (5)	0.3533 (3)	0.092 (3)
C335	0.4523 (5)	0.3845 (5)	0.3842 (3)	0.089 (3)
C336	0.4005 (5)	0.2917 (5)	0.4082 (2)	0.073 (2)
C47	1.0216 (8)	0.4480 (9)	0.4003 (4)	0.085 (3)
C411	0.8191 (5)	0.5072 (4)	0.3395 (2)	0.062 (2)
C412	0.7118 (4)	0.4713 (4)	0.3059 (2)	0.073 (2)
C413	0.6985 (5)	0.5428 (6)	0.2757 (2)	0.086 (3)
C414	0.7923 (7)	0.6502 (5)	0.2792 (3)	0.089 (3)
C415	0.8995 (6)	0.6861 (4)	0.3128 (3)	0.109 (4)
C416	0.9129 (4)	0.6146 (5)	0.3430 (3)	0.097 (3)
C421	0.7425 (5)	0.2357 (4)	0.3354 (2)	0.066 (2)
C422	0.7977 (5)	0.1769 (6)	0.3126 (2)	0.076 (3)
C423	0.7294 (8)	0.0683 (6)	0.2816 (3)	0.096 (3)
C424	0.6060 (8)	0.0185 (4)	0.2733 (2)	0.109 (4)
C425	0.5509 (5)	0.0774 (6)	0.2960 (3)	0.096 (3)
C426	0.6191 (5)	0.1859 (6)	0.3271 (3)	0.084 (3)
C431	0.7541 (5)	0.3912 (5)	0.4512 (2)	0.059 (2)
C432	0.7202 (6)	0.2995 (4)	0.4761 (3)	0.084 (3)
C433	0.6639 (6)	0.2946 (5)	0.5219 (3)	0.095 (3)
C434	0.6416 (6)	0.3814 (7)	0.5429 (2)	0.101 (4)
C435	0.6755 (6)	0.4731 (5)	0.5180 (3)	0.095 (3)
C436	0.7318 (6)	0.4780 (4)	0.4722 (2)	0.073 (2)
B1	0.7574 (4)	0.0216 (4)	0.00319 (19)	0.086 (3)
F11	0.7430 (5)	−0.0564 (5)	0.0321 (3)	0.131 (2)
F12	0.8599 (5)	0.0566 (6)	−0.0156 (3)	0.165 (3)
F13	0.6683 (5)	−0.0215 (7)	−0.0385 (3)	0.210 (6)
F14	0.7573 (8)	0.1080 (5)	0.0354 (3)	0.201 (5)
B2	0.9775 (3)	0.2502 (3)	0.49727 (15)	0.077 (3)
F21	1.0063 (5)	0.3543 (3)	0.5221 (2)	0.114 (2)
F22	0.9116 (5)	0.2224 (4)	0.44831 (16)	0.118 (2)
F23	0.9154 (6)	0.1787 (4)	0.5280 (2)	0.145 (3)
F24	1.0763 (4)	0.2442 (5)	0.4910 (3)	0.154 (3)
B3	0.3642 (7)	0.6080 (5)	0.2625 (3)	0.110 (5)
F31	0.4144 (7)	0.7095 (5)	0.2509 (3)	0.146 (3)
F32	0.4387 (13)	0.5661 (10)	0.2587 (5)	0.306 (11)
F33	0.3385 (13)	0.6139 (8)	0.3130 (4)	0.299 (10)
F34	0.2653 (11)	0.5404 (8)	0.2269 (6)	0.441 (18)
B4	−0.0009 (4)	−0.0196 (4)	0.25962 (18)	0.087 (3)
F41	0.0892 (5)	−0.0085 (6)	0.2943 (2)	0.136 (3)
F42	−0.1033 (4)	−0.0784 (6)	0.2770 (3)	0.149 (3)
F43	−0.0031 (6)	−0.0727 (9)	0.21017 (19)	0.221 (6)
F44	0.0134 (7)	0.0814 (5)	0.2570 (4)	0.254 (7)
H17A	0.5022	−0.0503	0.1228	0.143*	0.50
H17B	0.6022	−0.0283	0.0865	0.143*	0.50
H17C	0.4789	−0.0444	0.0613	0.143*	0.50
H17D	0.5534	−0.0317	0.0575	0.143*	0.50
H17E	0.4533	−0.0537	0.0939	0.143*	0.50
H17F	0.5766	−0.0376	0.1191	0.143*	0.50
H112	0.8052	0.1067	0.1438	0.118*
H113	0.9973	0.1975	0.1923	0.144*
H114	1.0763	0.3794	0.2431	0.141*
H115	0.9632	0.4704	0.2454	0.135*
H116	0.7711	0.3796	0.1970	0.122*
H122	0.8006	0.3133	0.0630	0.129*
H123	0.8287	0.4216	−0.0028	0.160*
H124	0.6677	0.4256	−0.0482	0.154*
H125	0.4786	0.3213	−0.0278	0.141*
H126	0.4505	0.2129	0.0380	0.111*
H132	0.5491	0.3461	0.1713	0.112*
H133	0.4133	0.3646	0.2226	0.119*
H134	0.2629	0.2077	0.2457	0.142*
H135	0.2482	0.0325	0.2176	0.136*
H136	0.3840	0.0140	0.1663	0.116*
H27A	1.0498	1.0171	0.0699	0.134*	0.50
H27B	1.0333	1.0217	0.1317	0.134*	0.50
H27C	0.9302	1.0042	0.0875	0.134*	0.50
H27D	0.9591	1.0116	0.1228	0.134*	0.50
H27E	0.9755	1.0070	0.0611	0.134*	0.50
H27F	1.0787	1.0245	0.1053	0.134*	0.50
H212	0.7645	0.7903	−0.0187	0.148*
H213	0.7060	0.6992	−0.1104	0.197*
H214	0.7905	0.5930	−0.1475	0.208*
H215	0.9334	0.5779	−0.0929	0.220*
H216	0.9919	0.6691	−0.0012	0.134*
H222	0.7747	0.8708	0.1618	0.124*
H223	0.5948	0.7745	0.1921	0.139*
H224	0.4761	0.5827	0.1586	0.138*
H225	0.5372	0.4873	0.0948	0.148*
H226	0.7171	0.5836	0.0644	0.132*
H232	1.1745	0.8330	0.0763	0.168*
H233	1.2953	0.7744	0.1185	0.196*
H234	1.2344	0.6763	0.1881	0.229*
H235	1.0528	0.6368	0.2155	0.329*
H236	0.9320	0.6954	0.1733	0.235*
H37A	−0.0123	0.0415	0.4232	0.110*	0.50
H37B	−0.0083	−0.0631	0.4387	0.110*	0.50
H37C	−0.0030	−0.0456	0.3781	0.110*	0.50
H37D	−0.0034	−0.0863	0.4035	0.110*	0.50
H37E	−0.0074	0.0183	0.3880	0.110*	0.50
H37F	−0.0127	0.0008	0.4486	0.110*	0.50
H312	0.1624	−0.1177	0.3428	0.095*
H313	0.2607	−0.2161	0.3139	0.115*
H314	0.4474	−0.1647	0.3599	0.098*
H315	0.5357	−0.0149	0.4349	0.092*
H316	0.4374	0.0835	0.4638	0.078*
H322	0.2344	−0.0150	0.5320	0.083*
H323	0.2872	0.0381	0.6267	0.110*
H324	0.3493	0.2219	0.6707	0.102*
H325	0.3587	0.3527	0.6198	0.125*
H326	0.3059	0.2996	0.5250	0.098*
H332	0.1237	0.2136	0.3657	0.094*
H333	0.2102	0.3686	0.3257	0.112*
H334	0.4157	0.4755	0.3372	0.110*
H335	0.5347	0.4274	0.3889	0.107*
H336	0.4482	0.2724	0.4289	0.088*
H47A	1.0339	0.3850	0.3883	0.127*	0.50
H47B	1.0491	0.4758	0.4390	0.127*	0.50
H47C	1.0650	0.5063	0.3811	0.127*	0.50
H47D	1.0648	0.5264	0.4173	0.127*	0.50
H47E	1.0495	0.4356	0.3666	0.127*	0.50
H47F	1.0337	0.4051	0.4245	0.127*	0.50
H412	0.6491	0.3994	0.3035	0.087*
H413	0.6267	0.5188	0.2532	0.103*
H414	0.7833	0.6980	0.2590	0.107*
H415	0.9623	0.7579	0.3152	0.131*
H416	0.9847	0.6386	0.3655	0.117*
H422	0.8802	0.2102	0.3182	0.091*
H423	0.7663	0.0289	0.2664	0.115*
H424	0.5603	−0.0541	0.2525	0.131*
H425	0.4683	0.0441	0.2905	0.115*
H426	0.5823	0.2253	0.3423	0.101*
H432	0.7351	0.2414	0.4621	0.100*
H433	0.6412	0.2333	0.5386	0.114*
H434	0.6039	0.3781	0.5736	0.121*
H435	0.6606	0.5311	0.5320	0.114*
H436	0.7545	0.5393	0.4556	0.087*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Sb1	0.0705 (4)	0.0741 (4)	0.0631 (4)	0.0342 (3)	0.0150 (3)	0.0078 (3)
Sb2	0.0713 (4)	0.0766 (4)	0.0653 (4)	0.0356 (3)	0.0099 (3)	0.0133 (3)
Sb3	0.0502 (3)	0.0615 (3)	0.0595 (3)	0.0284 (3)	0.0094 (2)	0.0087 (3)
Sb4	0.0623 (4)	0.0666 (4)	0.0596 (3)	0.0288 (3)	0.0095 (3)	0.0127 (3)
C17	0.088 (7)	0.076 (7)	0.098 (8)	0.026 (6)	0.032 (6)	−0.005 (6)
C111	0.071 (6)	0.084 (7)	0.060 (5)	0.035 (5)	0.016 (4)	0.013 (5)
C112	0.085 (8)	0.109 (9)	0.109 (8)	0.051 (7)	0.015 (6)	0.034 (7)
C113	0.090 (9)	0.154 (13)	0.138 (12)	0.071 (9)	0.019 (8)	0.051 (10)
C114	0.089 (9)	0.165 (14)	0.073 (7)	0.038 (10)	0.011 (6)	0.034 (8)
C115	0.092 (9)	0.112 (10)	0.089 (8)	0.022 (8)	0.001 (7)	−0.002 (7)
C116	0.080 (7)	0.107 (9)	0.106 (8)	0.044 (7)	0.010 (6)	−0.004 (7)
C121	0.094 (7)	0.082 (7)	0.062 (5)	0.046 (6)	0.020 (5)	0.013 (5)
C122	0.111 (9)	0.135 (11)	0.110 (9)	0.074 (9)	0.041 (7)	0.055 (8)
C123	0.126 (11)	0.146 (12)	0.169 (14)	0.076 (10)	0.073 (10)	0.090 (11)
C124	0.169 (14)	0.142 (12)	0.107 (10)	0.089 (12)	0.038 (10)	0.062 (9)
C125	0.112 (10)	0.121 (10)	0.100 (9)	0.042 (9)	−0.013 (8)	0.028 (8)
C126	0.092 (8)	0.107 (8)	0.075 (7)	0.046 (7)	0.004 (6)	0.022 (6)
C131	0.076 (6)	0.107 (8)	0.046 (5)	0.051 (6)	0.010 (4)	0.007 (5)
C132	0.085 (7)	0.083 (7)	0.097 (8)	0.034 (6)	0.023 (6)	−0.004 (6)
C133	0.093 (8)	0.107 (9)	0.079 (7)	0.047 (7)	0.006 (6)	−0.023 (6)
C134	0.086 (8)	0.182 (14)	0.083 (8)	0.076 (10)	0.008 (6)	−0.018 (9)
C135	0.096 (9)	0.127 (11)	0.116 (9)	0.049 (8)	0.044 (7)	0.028 (8)
C136	0.093 (8)	0.103 (8)	0.097 (8)	0.048 (7)	0.036 (6)	0.016 (6)
C27	0.090 (7)	0.077 (7)	0.099 (8)	0.042 (6)	0.012 (6)	0.008 (6)
C211	0.072 (6)	0.080 (6)	0.064 (6)	0.023 (5)	0.021 (5)	0.024 (5)
C212	0.157 (13)	0.130 (11)	0.079 (8)	0.071 (10)	−0.008 (8)	0.023 (7)
C213	0.161 (15)	0.199 (18)	0.070 (9)	0.039 (13)	−0.007 (9)	0.028 (10)
C214	0.148 (15)	0.174 (17)	0.063 (8)	−0.028 (13)	0.023 (9)	0.013 (9)
C215	0.164 (16)	0.175 (16)	0.116 (12)	0.016 (13)	0.077 (12)	−0.035 (12)
C216	0.087 (8)	0.141 (11)	0.085 (8)	0.048 (8)	0.013 (6)	−0.012 (7)
C221	0.089 (7)	0.082 (7)	0.067 (6)	0.036 (6)	0.019 (5)	0.027 (5)
C222	0.082 (8)	0.115 (9)	0.085 (7)	0.030 (7)	0.016 (6)	0.000 (7)
C223	0.082 (8)	0.158 (13)	0.094 (8)	0.050 (9)	0.024 (7)	0.010 (8)
C224	0.094 (9)	0.137 (12)	0.099 (9)	0.035 (9)	0.030 (7)	0.047 (8)
C225	0.115 (11)	0.108 (10)	0.133 (11)	0.033 (9)	0.038 (9)	0.050 (9)
C226	0.108 (9)	0.106 (10)	0.112 (9)	0.044 (8)	0.041 (8)	0.027 (8)
C231	0.102 (8)	0.113 (8)	0.068 (6)	0.066 (7)	0.005 (5)	0.028 (6)
C232	0.086 (9)	0.159 (13)	0.193 (15)	0.063 (9)	−0.003 (9)	0.078 (12)
C233	0.126 (12)	0.162 (15)	0.199 (18)	0.081 (12)	−0.036 (12)	0.022 (13)
C234	0.20 (2)	0.24 (2)	0.172 (18)	0.14 (2)	−0.040 (15)	0.061 (16)
C235	0.24 (3)	0.31 (3)	0.33 (3)	0.15 (3)	−0.03 (3)	0.18 (3)
C236	0.192 (18)	0.25 (2)	0.203 (19)	0.125 (18)	0.052 (15)	0.151 (18)
C37	0.054 (5)	0.090 (7)	0.071 (6)	0.033 (5)	0.007 (4)	0.009 (5)
C311	0.055 (5)	0.059 (5)	0.065 (5)	0.033 (4)	0.008 (4)	0.008 (4)
C312	0.064 (6)	0.071 (6)	0.089 (7)	0.030 (5)	0.004 (5)	−0.006 (5)
C313	0.095 (8)	0.079 (7)	0.096 (8)	0.041 (6)	0.000 (6)	−0.019 (6)
C314	0.091 (7)	0.071 (6)	0.097 (7)	0.048 (6)	0.026 (6)	0.020 (6)
C315	0.079 (6)	0.094 (7)	0.079 (6)	0.059 (6)	0.012 (5)	0.022 (5)
C316	0.071 (6)	0.061 (5)	0.067 (5)	0.035 (5)	0.016 (4)	0.010 (4)
C321	0.039 (4)	0.052 (4)	0.060 (5)	0.016 (4)	0.007 (3)	0.003 (4)
C322	0.061 (5)	0.064 (5)	0.088 (7)	0.030 (4)	0.011 (5)	0.027 (5)
C323	0.087 (7)	0.136 (10)	0.084 (7)	0.071 (7)	0.025 (6)	0.051 (7)
C324	0.082 (7)	0.107 (8)	0.062 (6)	0.045 (7)	0.010 (5)	0.010 (6)
C325	0.119 (9)	0.089 (8)	0.085 (8)	0.043 (7)	0.021 (7)	−0.012 (6)
C326	0.108 (8)	0.060 (6)	0.075 (6)	0.040 (6)	0.023 (6)	0.011 (5)
C331	0.067 (5)	0.063 (5)	0.049 (4)	0.038 (4)	0.011 (4)	0.011 (4)
C332	0.088 (7)	0.087 (7)	0.068 (6)	0.051 (6)	0.004 (5)	0.010 (5)
C333	0.130 (10)	0.101 (8)	0.066 (6)	0.072 (8)	0.001 (6)	0.017 (6)
C334	0.123 (10)	0.092 (8)	0.061 (6)	0.050 (8)	0.021 (6)	0.019 (5)
C335	0.096 (8)	0.093 (7)	0.082 (7)	0.042 (6)	0.032 (6)	0.032 (6)
C336	0.070 (6)	0.075 (6)	0.083 (6)	0.037 (5)	0.018 (5)	0.029 (5)
C47	0.065 (6)	0.105 (8)	0.080 (6)	0.041 (6)	−0.002 (5)	0.012 (6)
C411	0.068 (5)	0.061 (5)	0.049 (4)	0.027 (4)	0.006 (4)	0.005 (4)
C412	0.076 (6)	0.066 (6)	0.064 (5)	0.026 (5)	0.010 (5)	0.013 (4)
C413	0.092 (7)	0.095 (8)	0.067 (6)	0.050 (7)	−0.010 (5)	0.003 (5)
C414	0.116 (9)	0.073 (7)	0.087 (7)	0.051 (7)	0.016 (6)	0.022 (6)
C415	0.104 (9)	0.056 (6)	0.136 (10)	0.014 (6)	−0.014 (8)	0.032 (6)
C416	0.077 (7)	0.070 (7)	0.115 (9)	0.016 (6)	−0.017 (6)	0.019 (6)
C421	0.078 (6)	0.067 (5)	0.057 (5)	0.037 (5)	0.016 (4)	0.013 (4)
C422	0.091 (7)	0.074 (6)	0.058 (5)	0.036 (6)	0.009 (5)	0.016 (5)
C423	0.153 (11)	0.085 (8)	0.071 (7)	0.073 (8)	0.034 (7)	0.015 (6)
C424	0.176 (14)	0.067 (7)	0.066 (7)	0.044 (9)	0.020 (8)	0.014 (5)
C425	0.093 (8)	0.070 (7)	0.083 (7)	0.007 (6)	−0.005 (6)	0.016 (6)
C426	0.086 (7)	0.078 (7)	0.083 (7)	0.035 (6)	0.018 (5)	0.015 (5)
C431	0.059 (5)	0.055 (5)	0.053 (5)	0.018 (4)	0.011 (4)	0.015 (4)
C432	0.097 (7)	0.077 (7)	0.078 (6)	0.041 (6)	0.018 (6)	0.022 (5)
C433	0.103 (8)	0.071 (7)	0.092 (8)	0.021 (6)	0.020 (6)	0.034 (6)
C434	0.093 (8)	0.117 (10)	0.061 (6)	0.026 (7)	0.022 (5)	0.016 (6)
C435	0.099 (8)	0.095 (8)	0.077 (7)	0.042 (7)	0.021 (6)	−0.009 (6)
C436	0.075 (6)	0.060 (5)	0.066 (5)	0.019 (5)	0.013 (5)	0.014 (4)
B1	0.072 (8)	0.101 (10)	0.094 (9)	0.046 (7)	0.025 (7)	0.024 (8)
F11	0.109 (5)	0.131 (6)	0.170 (7)	0.061 (5)	0.024 (5)	0.068 (5)
F12	0.109 (6)	0.194 (9)	0.205 (9)	0.069 (6)	0.075 (6)	0.069 (7)
F13	0.155 (8)	0.187 (9)	0.152 (7)	−0.032 (7)	−0.065 (6)	0.089 (7)
F14	0.261 (12)	0.130 (7)	0.244 (11)	0.109 (8)	0.139 (10)	0.034 (7)
B2	0.076 (7)	0.052 (6)	0.090 (8)	0.019 (6)	−0.001 (6)	0.020 (6)
F21	0.112 (5)	0.080 (4)	0.136 (5)	0.038 (4)	0.014 (4)	0.012 (4)
F22	0.139 (6)	0.114 (5)	0.085 (4)	0.054 (4)	−0.010 (4)	0.016 (4)
F23	0.170 (7)	0.092 (5)	0.101 (5)	0.005 (5)	−0.003 (5)	0.032 (4)
F24	0.109 (6)	0.122 (6)	0.219 (9)	0.065 (5)	−0.003 (6)	−0.014 (6)
B3	0.149 (14)	0.087 (10)	0.138 (13)	0.082 (11)	0.058 (11)	0.047 (9)
F31	0.161 (7)	0.132 (6)	0.186 (8)	0.083 (6)	0.068 (6)	0.083 (6)
F32	0.59 (3)	0.40 (2)	0.260 (13)	0.44 (2)	0.258 (18)	0.232 (15)
F33	0.58 (3)	0.163 (9)	0.285 (14)	0.234 (15)	0.300 (18)	0.111 (10)
F34	0.31 (2)	0.27 (2)	0.42 (3)	−0.076 (17)	−0.19 (2)	0.062 (19)
B4	0.080 (8)	0.096 (9)	0.071 (8)	0.033 (7)	0.006 (6)	0.017 (7)
F41	0.117 (5)	0.194 (8)	0.114 (5)	0.089 (6)	0.002 (4)	0.038 (5)
F42	0.114 (6)	0.174 (8)	0.137 (6)	0.047 (6)	0.027 (5)	0.050 (6)
F43	0.148 (8)	0.339 (16)	0.084 (5)	0.075 (9)	0.004 (5)	−0.060 (7)
F44	0.239 (13)	0.128 (8)	0.365 (18)	0.073 (8)	−0.085 (12)	0.081 (10)

Geometric parameters (Å, º)

Sb1—C121	2.077 (5)	C37—H37A	0.96
Sb1—C111	2.087 (5)	C37—H37B	0.96
Sb1—C131	2.095 (5)	C37—H37C	0.96
Sb1—C17	2.099 (10)	C37—H37D	0.96
Sb2—C27	2.077 (10)	C37—H37E	0.96
Sb2—C211	2.081 (5)	C37—H37F	0.96
Sb2—C221	2.083 (5)	C311—C312	1.39
Sb2—C231	2.089 (6)	C311—C316	1.39
Sb3—C331	2.082 (4)	C312—C313	1.39
Sb3—C311	2.088 (4)	C312—H312	0.93
Sb3—C37	2.090 (8)	C313—C314	1.39
Sb3—C321	2.093 (4)	C313—H313	0.93
Sb4—C431	2.070 (4)	C314—C315	1.39
Sb4—C421	2.085 (5)	C314—H314	0.93
Sb4—C47	2.096 (9)	C315—C316	1.39
Sb4—C411	2.099 (4)	C315—H315	0.93
C17—H17A	0.96	C316—H316	0.93
C17—H17B	0.96	C321—C322	1.39
C17—H17C	0.96	C321—C326	1.39
C17—H17D	0.96	C322—C323	1.39
C17—H17E	0.96	C322—H322	0.93
C17—H17F	0.96	C323—C324	1.39
C111—C112	1.39	C323—H323	0.93
C111—C116	1.39	C324—C325	1.39
C112—C113	1.39	C324—H324	0.93
C112—H112	0.93	C325—C326	1.39
C113—C114	1.39	C325—H325	0.93
C113—H113	0.93	C326—H326	0.93
C114—C115	1.39	C331—C332	1.39
C114—H114	0.93	C331—C336	1.39
C115—C116	1.39	C332—C333	1.39
C115—H115	0.93	C332—H332	0.93
C116—H116	0.93	C333—C334	1.39
C121—C122	1.39	C333—H333	0.93
C121—C126	1.39	C334—C335	1.39
C122—C123	1.39	C334—H334	0.93
C122—H122	0.93	C335—C336	1.39
C123—C124	1.39	C335—H335	0.93
C123—H123	0.93	C336—H336	0.93
C124—C125	1.39	C47—H47A	0.96
C124—H124	0.93	C47—H47B	0.96
C125—C126	1.39	C47—H47C	0.96
C125—H125	0.93	C47—H47D	0.96
C126—H126	0.93	C47—H47E	0.96
C131—C132	1.39	C47—H47F	0.96
C131—C136	1.39	C411—C412	1.39
C132—C133	1.39	C411—C416	1.39
C132—H132	0.93	C412—C413	1.39
C133—C134	1.39	C412—H412	0.93
C133—H133	0.93	C413—C414	1.39
C134—C135	1.39	C413—H413	0.93
C134—H134	0.93	C414—C415	1.39
C135—C136	1.39	C414—H414	0.93
C135—H135	0.93	C415—C416	1.39
C136—H136	0.93	C415—H415	0.93
C27—H27A	0.96	C416—H416	0.93
C27—H27B	0.96	C421—C422	1.39
C27—H27C	0.96	C421—C426	1.39
C27—H27D	0.96	C422—C423	1.39
C27—H27E	0.96	C422—H422	0.93
C27—H27F	0.96	C423—C424	1.39
C211—C212	1.39	C423—H423	0.93
C211—C216	1.39	C424—C425	1.39
C212—C213	1.39	C424—H424	0.93
C212—H212	0.93	C425—C426	1.39
C213—C214	1.39	C425—H425	0.93
C213—H213	0.93	C426—H426	0.93
C214—C215	1.39	C431—C432	1.39
C214—H214	0.93	C431—C436	1.39
C215—C216	1.39	C432—C433	1.39
C215—H215	0.93	C432—H432	0.93
C216—H216	0.93	C433—C434	1.39
C221—C222	1.39	C433—H433	0.93
C221—C226	1.39	C434—C435	1.39
C222—C223	1.39	C434—H434	0.93
C222—H222	0.93	C435—C436	1.39
C223—C224	1.39	C435—H435	0.93
C223—H223	0.93	C436—H436	0.93
C224—C225	1.39	B1—F12	1.3257
C224—H224	0.93	B1—F13	1.3274
C225—C226	1.39	B1—F14	1.3298
C225—H225	0.93	B1—F11	1.3326
C226—H226	0.93	B2—F22	1.3306
C231—C232	1.39	B2—F24	1.3316
C231—C236	1.39	B2—F21	1.3318
C232—C233	1.39	B2—F23	1.3354
C232—H232	0.93	B3—F33	1.3249
C233—C234	1.39	B3—F34	1.3269
C233—H233	0.93	B3—F31	1.3275
C234—C235	1.39	B3—F32	1.3311
C234—H234	0.93	B4—F43	1.3261
C235—C236	1.39	B4—F44	1.3266
C235—H235	0.93	B4—F42	1.3316
C236—H236	0.93	B4—F41	1.3317
C121—Sb1—C111	104.9 (3)	Sb3—C37—H37A	109.5
C121—Sb1—C131	107.3 (3)	Sb3—C37—H37B	109.5
C111—Sb1—C131	110.1 (3)	H37A—C37—H37B	109.5
C121—Sb1—C17	119.0 (4)	Sb3—C37—H37C	109.5
C111—Sb1—C17	109.4 (4)	H37A—C37—H37C	109.5
C131—Sb1—C17	106.1 (3)	H37B—C37—H37C	109.5
C27—Sb2—C211	112.3 (4)	Sb3—C37—H37D	109.5
C27—Sb2—C221	111.9 (4)	H37A—C37—H37D	141.1
C211—Sb2—C221	103.3 (3)	H37B—C37—H37D	56.3
C27—Sb2—C231	112.7 (4)	H37C—C37—H37D	56.3
C211—Sb2—C231	108.4 (3)	Sb3—C37—H37E	109.5
C221—Sb2—C231	107.8 (3)	H37A—C37—H37E	56.3
C331—Sb3—C311	106.1 (2)	H37B—C37—H37E	141.1
C331—Sb3—C37	113.3 (3)	H37C—C37—H37E	56.3
C311—Sb3—C37	113.4 (3)	H37D—C37—H37E	109.5
C331—Sb3—C321	106.9 (2)	Sb3—C37—H37F	109.5
C311—Sb3—C321	105.2 (2)	H37A—C37—H37F	56.3
C37—Sb3—C321	111.5 (3)	H37B—C37—H37F	56.3
C431—Sb4—C421	104.0 (2)	H37C—C37—H37F	141.1
C431—Sb4—C47	116.0 (3)	H37D—C37—H37F	109.5
C421—Sb4—C47	112.0 (3)	H37E—C37—H37F	109.5
C431—Sb4—C411	108.7 (2)	C312—C311—C316	120
C421—Sb4—C411	107.4 (2)	C312—C311—Sb3	121.9 (3)
C47—Sb4—C411	108.4 (3)	C316—C311—Sb3	118.1 (3)
Sb1—C17—H17A	109.5	C311—C312—C313	120
Sb1—C17—H17B	109.5	C311—C312—H312	120
H17A—C17—H17B	109.5	C313—C312—H312	120
Sb1—C17—H17C	109.5	C314—C313—C312	120
H17A—C17—H17C	109.5	C314—C313—H313	120
H17B—C17—H17C	109.5	C312—C313—H313	120
Sb1—C17—H17D	109.5	C313—C314—C315	120
H17A—C17—H17D	141.1	C313—C314—H314	120
H17B—C17—H17D	56.3	C315—C314—H314	120
H17C—C17—H17D	56.3	C316—C315—C314	120
Sb1—C17—H17E	109.5	C316—C315—H315	120
H17A—C17—H17E	56.3	C314—C315—H315	120
H17B—C17—H17E	141.1	C315—C316—C311	120
H17C—C17—H17E	56.3	C315—C316—H316	120
H17D—C17—H17E	109.5	C311—C316—H316	120
Sb1—C17—H17F	109.5	C322—C321—C326	120
H17A—C17—H17F	56.3	C322—C321—Sb3	119.1 (3)
H17B—C17—H17F	56.3	C326—C321—Sb3	120.8 (3)
H17C—C17—H17F	141.1	C323—C322—C321	120
H17D—C17—H17F	109.5	C323—C322—H322	120
H17E—C17—H17F	109.5	C321—C322—H322	120
C112—C111—C116	120	C322—C323—C324	120
C112—C111—Sb1	120.7 (4)	C322—C323—H323	120
C116—C111—Sb1	119.1 (4)	C324—C323—H323	120
C111—C112—C113	120	C323—C324—C325	120
C111—C112—H112	120	C323—C324—H324	120
C113—C112—H112	120	C325—C324—H324	120
C112—C113—C114	120	C326—C325—C324	120
C112—C113—H113	120	C326—C325—H325	120
C114—C113—H113	120	C324—C325—H325	120
C115—C114—C113	120	C325—C326—C321	120
C115—C114—H114	120	C325—C326—H326	120
C113—C114—H114	120	C321—C326—H326	120
C114—C115—C116	120	C332—C331—C336	120
C114—C115—H115	120	C332—C331—Sb3	122.0 (3)
C116—C115—H115	120	C336—C331—Sb3	117.9 (3)
C115—C116—C111	120	C333—C332—C331	120
C115—C116—H116	120	C333—C332—H332	120
C111—C116—H116	120	C331—C332—H332	120
C122—C121—C126	120	C334—C333—C332	120
C122—C121—Sb1	119.0 (4)	C334—C333—H333	120
C126—C121—Sb1	121.0 (4)	C332—C333—H333	120
C123—C122—C121	120	C333—C334—C335	120
C123—C122—H122	120	C333—C334—H334	120
C121—C122—H122	120	C335—C334—H334	120
C124—C123—C122	120	C334—C335—C336	120
C124—C123—H123	120	C334—C335—H335	120
C122—C123—H123	120	C336—C335—H335	120
C123—C124—C125	120	C335—C336—C331	120
C123—C124—H124	120	C335—C336—H336	120
C125—C124—H124	120	C331—C336—H336	120
C126—C125—C124	120	Sb4—C47—H47A	109.5
C126—C125—H125	120	Sb4—C47—H47B	109.5
C124—C125—H125	120	H47A—C47—H47B	109.5
C125—C126—C121	120	Sb4—C47—H47C	109.5
C125—C126—H126	120	H47A—C47—H47C	109.5
C121—C126—H126	120	H47B—C47—H47C	109.5
C132—C131—C136	120	Sb4—C47—H47D	109.5
C132—C131—Sb1	120.8 (4)	H47A—C47—H47D	141.1
C136—C131—Sb1	119.2 (4)	H47B—C47—H47D	56.3
C133—C132—C131	120	H47C—C47—H47D	56.3
C133—C132—H132	120	Sb4—C47—H47E	109.5
C131—C132—H132	120	H47A—C47—H47E	56.3
C134—C133—C132	120	H47B—C47—H47E	141.1
C134—C133—H133	120	H47C—C47—H47E	56.3
C132—C133—H133	120	H47D—C47—H47E	109.5
C133—C134—C135	120	Sb4—C47—H47F	109.5
C133—C134—H134	120	H47A—C47—H47F	56.3
C135—C134—H134	120	H47B—C47—H47F	56.3
C136—C135—C134	120	H47C—C47—H47F	141.1
C136—C135—H135	120	H47D—C47—H47F	109.5
C134—C135—H135	120	H47E—C47—H47F	109.5
C135—C136—C131	120	C412—C411—C416	120
C135—C136—H136	120	C412—C411—Sb4	119.8 (3)
C131—C136—H136	120	C416—C411—Sb4	120.2 (3)
Sb2—C27—H27A	109.5	C413—C412—C411	120
Sb2—C27—H27B	109.5	C413—C412—H412	120
H27A—C27—H27B	109.5	C411—C412—H412	120
Sb2—C27—H27C	109.5	C412—C413—C414	120
H27A—C27—H27C	109.5	C412—C413—H413	120
H27B—C27—H27C	109.5	C414—C413—H413	120
Sb2—C27—H27D	109.5	C413—C414—C415	120
H27A—C27—H27D	141.1	C413—C414—H414	120
H27B—C27—H27D	56.3	C415—C414—H414	120
H27C—C27—H27D	56.3	C416—C415—C414	120
Sb2—C27—H27E	109.5	C416—C415—H415	120
H27A—C27—H27E	56.3	C414—C415—H415	120
H27B—C27—H27E	141.1	C415—C416—C411	120
H27C—C27—H27E	56.3	C415—C416—H416	120
H27D—C27—H27E	109.5	C411—C416—H416	120
Sb2—C27—H27F	109.5	C422—C421—C426	120
H27A—C27—H27F	56.3	C422—C421—Sb4	121.9 (4)
H27B—C27—H27F	56.3	C426—C421—Sb4	118.1 (4)
H27C—C27—H27F	141.1	C423—C422—C421	120
H27D—C27—H27F	109.5	C423—C422—H422	120
H27E—C27—H27F	109.5	C421—C422—H422	120
C212—C211—C216	120	C422—C423—C424	120
C212—C211—Sb2	118.2 (5)	C422—C423—H423	120
C216—C211—Sb2	121.7 (5)	C424—C423—H423	120
C211—C212—C213	120	C425—C424—C423	120
C211—C212—H212	120	C425—C424—H424	120
C213—C212—H212	120	C423—C424—H424	120
C212—C213—C214	120	C426—C425—C424	120
C212—C213—H213	120	C426—C425—H425	120
C214—C213—H213	120	C424—C425—H425	120
C215—C214—C213	120	C425—C426—C421	120
C215—C214—H214	120	C425—C426—H426	120
C213—C214—H214	120	C421—C426—H426	120
C214—C215—C216	120	C432—C431—C436	120
C214—C215—H215	120	C432—C431—Sb4	119.3 (3)
C216—C215—H215	120	C436—C431—Sb4	120.7 (3)
C215—C216—C211	120	C433—C432—C431	120
C215—C216—H216	120	C433—C432—H432	120
C211—C216—H216	120	C431—C432—H432	120
C222—C221—C226	120	C432—C433—C434	120
C222—C221—Sb2	122.9 (4)	C432—C433—H433	120
C226—C221—Sb2	117.1 (4)	C434—C433—H433	120
C221—C222—C223	120	C435—C434—C433	120
C221—C222—H222	120	C435—C434—H434	120
C223—C222—H222	120	C433—C434—H434	120
C224—C223—C222	120	C436—C435—C434	120
C224—C223—H223	120	C436—C435—H435	120
C222—C223—H223	120	C434—C435—H435	120
C223—C224—C225	120	C435—C436—C431	120
C223—C224—H224	120	C435—C436—H436	120
C225—C224—H224	120	C431—C436—H436	120
C226—C225—C224	120	F12—B1—F13	109.8
C226—C225—H225	120	F12—B1—F14	109.4
C224—C225—H225	120	F13—B1—F14	109.2
C225—C226—C221	120	F12—B1—F11	109.8
C225—C226—H226	120	F13—B1—F11	109.4
C221—C226—H226	120	F14—B1—F11	109.2
C232—C231—C236	120	F22—B2—F24	109.3
C232—C231—Sb2	121.7 (5)	F22—B2—F21	110.4
C236—C231—Sb2	118.2 (5)	F24—B2—F21	109.4
C233—C232—C231	120	F22—B2—F23	109.0
C233—C232—H232	120	F24—B2—F23	109.5
C231—C232—H232	120	F21—B2—F23	109.3
C234—C233—C232	120	F33—B3—F34	109.6
C234—C233—H233	120	F33—B3—F31	110.1
C232—C233—H233	120	F34—B3—F31	109.6
C233—C234—C235	120	F33—B3—F32	109.3
C233—C234—H234	120	F34—B3—F32	108.8
C235—C234—H234	120	F31—B3—F32	109.5
C236—C235—C234	120	F43—B4—F44	109.5
C236—C235—H235	120	F43—B4—F42	109.3
C234—C235—H235	120	F44—B4—F42	109.3
C235—C236—C231	120	F43—B4—F41	109.5
C235—C236—H236	120	F44—B4—F41	109.3
C231—C236—H236	120	F42—B4—F41	109.9
C121—Sb1—C111—C112	−109.2 (4)	C331—Sb3—C311—C312	−98.3 (4)
C131—Sb1—C111—C112	135.7 (4)	C37—Sb3—C311—C312	26.6 (5)
C17—Sb1—C111—C112	19.5 (5)	C321—Sb3—C311—C312	148.6 (3)
C121—Sb1—C111—C116	65.9 (4)	C331—Sb3—C311—C316	81.9 (4)
C131—Sb1—C111—C116	−49.2 (4)	C37—Sb3—C311—C316	−153.2 (4)
C17—Sb1—C111—C116	−165.3 (4)	C321—Sb3—C311—C316	−31.2 (4)
C116—C111—C112—C113	0.0	C316—C311—C312—C313	0.0
Sb1—C111—C112—C113	175.1 (5)	Sb3—C311—C312—C313	−179.8 (4)
C111—C112—C113—C114	0.0	C311—C312—C313—C314	0.0
C112—C113—C114—C115	0.0	C312—C313—C314—C315	0.0
C113—C114—C115—C116	0.0	C313—C314—C315—C316	0.0
C114—C115—C116—C111	0.0	C314—C315—C316—C311	0.0
C112—C111—C116—C115	0.0	C312—C311—C316—C315	0.0
Sb1—C111—C116—C115	−175.1 (4)	Sb3—C311—C316—C315	179.8 (4)
C111—Sb1—C121—C122	21.8 (5)	C331—Sb3—C321—C322	−162.2 (3)
C131—Sb1—C121—C122	138.8 (4)	C311—Sb3—C321—C322	−49.7 (4)
C17—Sb1—C121—C122	−101.0 (5)	C37—Sb3—C321—C322	73.6 (4)
C111—Sb1—C121—C126	−156.8 (4)	C331—Sb3—C321—C326	21.9 (4)
C131—Sb1—C121—C126	−39.8 (5)	C311—Sb3—C321—C326	134.4 (3)
C17—Sb1—C121—C126	80.4 (5)	C37—Sb3—C321—C326	−102.4 (4)
C126—C121—C122—C123	0.0	C326—C321—C322—C323	0.0
Sb1—C121—C122—C123	−178.6 (5)	Sb3—C321—C322—C323	−176.0 (4)
C121—C122—C123—C124	0.0	C321—C322—C323—C324	0.0
C122—C123—C124—C125	0.0	C322—C323—C324—C325	0.0
C123—C124—C125—C126	0.0	C323—C324—C325—C326	0.0
C124—C125—C126—C121	0.0	C324—C325—C326—C321	0.0
C122—C121—C126—C125	0.0	C322—C321—C326—C325	0.0
Sb1—C121—C126—C125	178.6 (5)	Sb3—C321—C326—C325	175.9 (4)
C121—Sb1—C131—C132	−44.5 (4)	C311—Sb3—C331—C332	125.0 (3)
C111—Sb1—C131—C132	69.1 (4)	C37—Sb3—C331—C332	−0.1 (4)
C17—Sb1—C131—C132	−172.6 (5)	C321—Sb3—C331—C332	−123.2 (3)
C121—Sb1—C131—C136	135.5 (4)	C311—Sb3—C331—C336	−51.3 (3)
C111—Sb1—C131—C136	−110.9 (4)	C37—Sb3—C331—C336	−176.3 (4)
C17—Sb1—C131—C136	7.4 (5)	C321—Sb3—C331—C336	60.6 (3)
C136—C131—C132—C133	0.0	C336—C331—C332—C333	0.0
Sb1—C131—C132—C133	−180.0 (5)	Sb3—C331—C332—C333	−176.2 (4)
C131—C132—C133—C134	0.0	C331—C332—C333—C334	0.0
C132—C133—C134—C135	0.0	C332—C333—C334—C335	0.0
C133—C134—C135—C136	0.0	C333—C334—C335—C336	0.0
C134—C135—C136—C131	0.0	C334—C335—C336—C331	0.0
C132—C131—C136—C135	0.0	C332—C331—C336—C335	0.0
Sb1—C131—C136—C135	180.0 (4)	Sb3—C331—C336—C335	176.3 (4)
C27—Sb2—C211—C212	−61.4 (5)	C431—Sb4—C411—C412	−77.6 (4)
C221—Sb2—C211—C212	59.4 (5)	C421—Sb4—C411—C412	34.3 (4)
C231—Sb2—C211—C212	173.5 (5)	C47—Sb4—C411—C412	155.5 (4)
C27—Sb2—C211—C216	122.1 (5)	C431—Sb4—C411—C416	103.7 (4)
C221—Sb2—C211—C216	−117.1 (5)	C421—Sb4—C411—C416	−144.4 (4)
C231—Sb2—C211—C216	−3.0 (5)	C47—Sb4—C411—C416	−23.2 (5)
C216—C211—C212—C213	0.0	C416—C411—C412—C413	0.0
Sb2—C211—C212—C213	−176.6 (5)	Sb4—C411—C412—C413	−178.7 (4)
C211—C212—C213—C214	0.0	C411—C412—C413—C414	0.0
C212—C213—C214—C215	0.0	C412—C413—C414—C415	0.0
C213—C214—C215—C216	0.0	C413—C414—C415—C416	0.0
C214—C215—C216—C211	0.0	C414—C415—C416—C411	0.0
C212—C211—C216—C215	0.0	C412—C411—C416—C415	0.0
Sb2—C211—C216—C215	176.5 (5)	Sb4—C411—C416—C415	178.7 (4)
C27—Sb2—C221—C222	−20.5 (5)	C431—Sb4—C421—C422	−133.0 (3)
C211—Sb2—C221—C222	−141.5 (4)	C47—Sb4—C421—C422	−6.9 (5)
C231—Sb2—C221—C222	103.9 (5)	C411—Sb4—C421—C422	112.0 (4)
C27—Sb2—C221—C226	161.3 (5)	C431—Sb4—C421—C426	45.8 (4)
C211—Sb2—C221—C226	40.3 (4)	C47—Sb4—C421—C426	171.9 (4)
C231—Sb2—C221—C226	−74.3 (5)	C411—Sb4—C421—C426	−69.3 (3)
C226—C221—C222—C223	0.0	C426—C421—C422—C423	0.0
Sb2—C221—C222—C223	−178.2 (5)	Sb4—C421—C422—C423	178.8 (4)
C221—C222—C223—C224	0.0	C421—C422—C423—C424	0.0
C222—C223—C224—C225	0.0	C422—C423—C424—C425	0.0
C223—C224—C225—C226	0.0	C423—C424—C425—C426	0.0
C224—C225—C226—C221	0.0	C424—C425—C426—C421	0.0
C222—C221—C226—C225	0.0	C422—C421—C426—C425	0.0
Sb2—C221—C226—C225	178.3 (5)	Sb4—C421—C426—C425	−178.8 (4)
C27—Sb2—C231—C232	−66.5 (7)	C421—Sb4—C431—C432	44.3 (4)
C211—Sb2—C231—C232	58.4 (7)	C47—Sb4—C431—C432	−79.2 (5)
C221—Sb2—C231—C232	169.5 (6)	C411—Sb4—C431—C432	158.5 (3)
C27—Sb2—C231—C236	116.0 (6)	C421—Sb4—C431—C436	−136.5 (4)
C211—Sb2—C231—C236	−119.1 (6)	C47—Sb4—C431—C436	100.0 (5)
C221—Sb2—C231—C236	−8.0 (6)	C411—Sb4—C431—C436	−22.3 (4)
C236—C231—C232—C233	0.0	C436—C431—C432—C433	0.0
Sb2—C231—C232—C233	−177.4 (7)	Sb4—C431—C432—C433	179.2 (4)
C231—C232—C233—C234	0.0	C431—C432—C433—C434	0.0
C232—C233—C234—C235	0.0	C432—C433—C434—C435	0.0
C233—C234—C235—C236	0.0	C433—C434—C435—C436	0.0
C234—C235—C236—C231	0.0	C434—C435—C436—C431	0.0
C232—C231—C236—C235	0.0	C432—C431—C436—C435	0.0
Sb2—C231—C236—C235	177.5 (6)	Sb4—C431—C436—C435	−179.2 (4)