cis,cis,cis-(Acetato-O,O')­bis­[1,2-bis­(di­phenyl­phosphino)­ethane-P,P']­ruthenium(II) hexa­fluoro­phosphate di­methanol solvate

In the cation of the title complex, cis,cis,cis-[Ru([eta]²-O₂CMe)(dppe)₂]PF₆·2MeOH [dppe is 1,2-bis­(di­phenyl­phosphino)­ethane, C₂₆H₂₄P₂], the Ru atom is in a pseudo-octahedral coordination environment with two chelating dppe ligands and one chelating acetate ligand. Intra-phosphine and intra-acetate bond lengths and angles are unexceptional. Deviations from idealized octahedral coordination angles at ruthenium [O-Ru-O 59.43 (8)° and P-Ru-P 103.19 (2)°] presumably derive from constraints imposed by the chelate rings. The Ru-P distances for the mutually trans P-donor atoms [2.3785 (6) Å] are significantly longer than those for the Ru-P linkages trans to the acetate ligand [2.3074 (6) Å]. The Ru1, C1 and C2 atoms lie on a twofold axis, and atom P3 of the anion lies on an inversion centre.

Computing details

Data collection: COLLECT (Nonius, 1999); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: TEXSAN (Molecular Structures Corporation, 1997); software used to prepare material for publication: TEXSAN.

(I)

Crystal data

[Ru(C2H3O2)(C26H24P2)2]PF6·2CH4O	F(000) = 2400
Mr = 1166.01	Dx = 1.457 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.7107 Å
a = 13.4832 (2) Å	Cell parameters from 41382 reflections
b = 19.6340 (2) Å	θ = 2.9–27.5°
c = 20.3112 (3) Å	µ = 0.51 mm^−1
β = 98.6340 (8)°	T = 273 K
V = 5316.0 (1) Å^3	Block, orange
Z = 4	0.30 × 0.20 × 0.15 mm

Data collection

KappaCCD diffractometer	6127 independent reflections
Radiation source: fine-focus sealed tube	4464 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.068
ω scans	θmax = 27.5°, θmin = 3.1°
Absorption correction: multi-scan [SORTAV (Blessing, 1995) implemented in maXus (Mackay et al., 1999)]	h = −17→17
Tmin = 0.847, Tmax = 0.926	k = −25→25
53848 measured reflections	l = −25→26

Refinement

Refinement on F	1 restraint
Least-squares matrix: full	0 constraints
R[F^2 > 2σ(F^2)] = 0.035	H atoms treated by a mixture of independent and constrained refinement
wR(F^2) = 0.039	Weighting scheme based on measured s.u.'s w = 1/[σ^2(Fo) + 0.00040|Fo|^2]
S = 0.94	(Δ/σ)max = 0.022
4464 reflections	Δρmax = 0.49 e Å^−3
328 parameters	Δρmin = −0.66 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	1.0000	0.01398 (1)	0.7500	0.02060 (7)
P1	0.88724 (5)	0.00522 (3)	0.64840 (3)	0.0234 (2)
P2	1.07225 (5)	0.09704 (3)	0.69230 (3)	0.0243 (2)
P3	0.7500	0.2500	0.5000	0.0391 (3)
F1	0.7197 (2)	0.3242 (1)	0.5187 (1)	0.0877 (8)
F2	0.8302 (2)	0.2805 (1)	0.4579 (1)	0.0668 (7)
F3	0.8338 (2)	0.2478 (1)	0.5633 (1)	0.0833 (8)
O1	0.9338 (1)	−0.08288 (9)	0.77453 (8)	0.0258 (5)
O2	1.0276 (2)	0.3288 (2)	0.5381 (2)	0.097 (1)
C1	1.0000	−0.1163 (2)	0.7500	0.0266 (9)
C2	1.0000	−0.1924 (2)	0.7500	0.040 (1)
C3	1.0052 (4)	0.3866 (2)	0.5708 (2)	0.092 (2)
C101	0.9285 (2)	0.0628 (1)	0.5872 (1)	0.0300 (7)
C111	0.8819 (2)	−0.0790 (1)	0.6089 (1)	0.0280 (7)
C112	0.9611 (2)	−0.1018 (1)	0.5779 (1)	0.0351 (8)
C113	0.9610 (2)	−0.1664 (2)	0.5511 (1)	0.0426 (9)
C114	0.8818 (3)	−0.2095 (2)	0.5544 (2)	0.049 (1)
C115	0.8028 (3)	−0.1882 (2)	0.5843 (2)	0.052 (1)
C116	0.8027 (2)	−0.1234 (2)	0.6121 (1)	0.0380 (8)
C121	0.7557 (2)	0.0233 (1)	0.6515 (1)	0.0255 (7)
C122	0.7142 (2)	−0.0049 (1)	0.7045 (1)	0.0300 (7)
C123	0.6163 (2)	0.0082 (2)	0.7122 (1)	0.0376 (8)
C124	0.5578 (2)	0.0502 (2)	0.6672 (2)	0.0428 (9)
C125	0.5970 (2)	0.0778 (2)	0.6145 (2)	0.0407 (8)
C126	0.6958 (2)	0.0644 (1)	0.6058 (1)	0.0325 (7)
C201	0.9756 (2)	0.1254 (1)	0.6236 (1)	0.0283 (7)
C211	1.1267 (2)	0.1780 (1)	0.7251 (1)	0.0302 (7)
C212	1.0854 (2)	0.2405 (2)	0.7061 (2)	0.0418 (9)
C213	1.1319 (3)	0.3003 (2)	0.7311 (2)	0.055 (1)
C214	1.2195 (3)	0.2979 (2)	0.7754 (2)	0.056 (1)
C215	1.2616 (3)	0.2364 (2)	0.7944 (2)	0.050 (1)
C216	1.2166 (2)	0.1766 (2)	0.7689 (1)	0.0404 (8)
C221	1.1696 (2)	0.0687 (1)	0.6434 (1)	0.0269 (7)
C222	1.2232 (2)	0.1163 (1)	0.6122 (2)	0.0396 (9)
C223	1.2896 (2)	0.0957 (2)	0.5704 (2)	0.0460 (9)
C224	1.3044 (2)	0.0278 (2)	0.5597 (2)	0.0423 (9)
C225	1.2525 (2)	−0.0201 (2)	0.5906 (1)	0.0383 (9)
C226	1.1855 (2)	0.0003 (1)	0.6321 (1)	0.0304 (7)
H1c	1.0588	−0.2085	0.7345	0.048*	0.500
H1a	0.9988	−0.2085	0.7940	0.048*	0.500
H1b	0.9424	−0.2085	0.7215	0.048*	0.500
H3c	1.0573	0.3954	0.6068	0.111*
H3a	0.9437	0.3804	0.5875	0.111*
H3b	0.9992	0.4240	0.5408	0.111*
H4	0.9615	0.3135	0.5177	0.043*
H101a	0.8727	0.0761	0.5556	0.036*
H101b	0.9766	0.0406	0.5650	0.036*
H112	1.0163	−0.0723	0.5752	0.042*
H113	1.0159	−0.1811	0.5303	0.051*
H114	0.8817	−0.2540	0.5359	0.059*
H115	0.7476	−0.2178	0.5862	0.062*
H116	0.7480	−0.1095	0.6334	0.046*
H122	0.7542	−0.0336	0.7355	0.036*
H123	0.5889	−0.0114	0.7483	0.045*
H124	0.4906	0.0600	0.6728	0.051*
H125	0.5563	0.1063	0.5837	0.049*
H126	0.7221	0.0832	0.5689	0.039*
H201b	1.0056	0.1530	0.5936	0.034*
H210a	0.9255	0.1508	0.6410	0.034*
H212	1.0246	0.2427	0.6757	0.050*
H213	1.1029	0.3431	0.7175	0.066*
H214	1.2506	0.3389	0.7927	0.067*
H215	1.3220	0.2346	0.8252	0.060*
H216	1.2475	0.1341	0.7816	0.049*
H222	1.2141	0.1635	0.6197	0.048*
H223	1.3251	0.1288	0.5491	0.055*
H224	1.3502	0.0139	0.5310	0.051*
H225	1.2628	−0.0672	0.5834	0.046*
H226	1.1499	−0.0331	0.6531	0.037*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ru1	0.0205 (1)	0.0189 (1)	0.0230 (2)	0.0000	0.0052 (1)	0.0000
P1	0.0220 (3)	0.0253 (4)	0.0233 (4)	−0.0005 (3)	0.0042 (3)	−0.0004 (3)
P2	0.0251 (4)	0.0213 (4)	0.0272 (4)	−0.0016 (3)	0.0064 (3)	0.0017 (3)
P3	0.0446 (7)	0.0299 (6)	0.0424 (7)	0.0075 (5)	0.0047 (5)	0.0069 (5)
F1	0.108 (2)	0.036 (1)	0.125 (2)	0.014 (1)	0.041 (2)	−0.011 (1)
F2	0.068 (1)	0.073 (1)	0.064 (1)	−0.006 (1)	0.024 (1)	0.016 (1)
F3	0.070 (1)	0.118 (2)	0.055 (1)	0.001 (1)	−0.014 (1)	0.019 (1)
O1	0.026 (1)	0.0215 (9)	0.031 (1)	−0.0001 (7)	0.0080 (8)	0.0012 (8)
O2	0.070 (2)	0.091 (2)	0.130 (3)	0.005 (2)	0.018 (2)	−0.041 (2)
C1	0.026 (2)	0.025 (2)	0.028 (2)	0.0000	0.003 (2)	0.0000
C2	0.042 (2)	0.024 (2)	0.059 (3)	0.0000	0.020 (2)	0.0000
C3	0.099 (4)	0.088 (3)	0.083 (3)	0.020 (3)	−0.008 (3)	−0.026 (2)
C101	0.027 (1)	0.036 (2)	0.027 (1)	0.001 (1)	0.004 (1)	0.005 (1)
C111	0.031 (1)	0.028 (1)	0.024 (1)	0.000 (1)	0.000 (1)	−0.003 (1)
C112	0.033 (2)	0.038 (2)	0.035 (2)	−0.001 (1)	0.006 (1)	−0.008 (1)
C113	0.049 (2)	0.043 (2)	0.037 (2)	0.010 (1)	0.009 (1)	−0.010 (1)
C114	0.066 (2)	0.032 (2)	0.048 (2)	0.001 (1)	0.009 (2)	−0.013 (1)
C115	0.059 (2)	0.033 (2)	0.064 (2)	−0.014 (2)	0.014 (2)	−0.011 (2)
C116	0.040 (2)	0.032 (2)	0.044 (2)	−0.005 (1)	0.013 (1)	−0.007 (1)
C121	0.023 (1)	0.026 (1)	0.027 (1)	−0.002 (1)	0.003 (1)	−0.005 (1)
C122	0.028 (1)	0.033 (2)	0.029 (1)	0.001 (1)	0.005 (1)	0.000 (1)
C123	0.031 (1)	0.045 (2)	0.039 (2)	−0.001 (1)	0.012 (1)	0.002 (1)
C124	0.025 (2)	0.055 (2)	0.050 (2)	0.005 (1)	0.009 (1)	−0.001 (1)
C125	0.031 (1)	0.047 (2)	0.043 (2)	0.009 (1)	0.000 (1)	0.006 (1)
C126	0.030 (1)	0.035 (2)	0.033 (2)	0.002 (1)	0.003 (1)	0.002 (1)
C201	0.029 (1)	0.028 (1)	0.029 (1)	0.001 (1)	0.008 (1)	0.008 (1)
C211	0.037 (1)	0.025 (1)	0.031 (1)	−0.007 (1)	0.013 (1)	0.000 (1)
C212	0.040 (2)	0.028 (1)	0.058 (2)	−0.001 (1)	0.009 (2)	0.000 (1)
C213	0.064 (2)	0.022 (2)	0.081 (3)	−0.006 (1)	0.019 (2)	−0.004 (2)
C214	0.076 (2)	0.039 (2)	0.055 (2)	−0.028 (2)	0.017 (2)	−0.011 (2)
C215	0.062 (2)	0.048 (2)	0.039 (2)	−0.028 (2)	0.000 (2)	0.003 (1)
C216	0.048 (2)	0.035 (2)	0.037 (2)	−0.012 (1)	0.003 (1)	0.009 (1)
C221	0.025 (1)	0.030 (1)	0.025 (1)	0.000 (1)	0.003 (1)	0.003 (1)
C222	0.043 (2)	0.030 (2)	0.050 (2)	−0.001 (1)	0.021 (1)	0.007 (1)
C223	0.048 (2)	0.046 (2)	0.051 (2)	−0.006 (2)	0.027 (2)	0.007 (2)
C224	0.039 (2)	0.052 (2)	0.041 (2)	0.000 (1)	0.022 (1)	−0.004 (1)
C225	0.038 (2)	0.038 (2)	0.041 (2)	0.001 (1)	0.014 (1)	−0.008 (1)
C226	0.030 (2)	0.031 (1)	0.031 (1)	−0.005 (1)	0.007 (1)	−0.001 (1)

Geometric parameters (Å, º)

Ru1—P1	2.3787 (6)	C114—C115	1.369 (4)
Ru1—P1^i	2.3787 (6)	C114—H114	0.95
Ru1—P2	2.3075 (7)	C115—C116	1.391 (4)
Ru1—P2^i	2.3075 (7)	C115—H115	0.95
Ru1—O1	2.190 (2)	C116—H116	0.95
Ru1—O1^i	2.190 (2)	C121—C122	1.398 (4)
P1—C101	1.828 (3)	C121—C126	1.394 (4)
P1—C111	1.835 (3)	C122—C123	1.378 (4)
P1—C121	1.819 (2)	C122—H122	0.95
P2—C201	1.847 (2)	C123—C124	1.387 (4)
P2—C211	1.833 (3)	C123—H123	0.95
P2—C221	1.847 (3)	C124—C125	1.373 (4)
P3—F1	1.574 (2)	C124—H124	0.95
P3—F1^ii	1.574 (2)	C125—C126	1.396 (4)
P3—F2	1.592 (2)	C125—H125	0.95
P3—F2^ii	1.592 (2)	C126—H126	0.95
P3—F3	1.579 (2)	C201—H201b	0.95
P3—F3^ii	1.579 (2)	C201—H210a	0.95
O1—C1	1.268 (2)	C211—C212	1.378 (4)
O2—C3	1.371 (5)	C211—C216	1.393 (4)
O2—H4	0.97	C212—C213	1.391 (4)
C1—C2	1.495 (5)	C212—H212	0.95
C2—H1c	0.95	C213—C214	1.373 (5)
C2—H1c^i	0.95	C213—H213	0.95
C2—H1a	0.95	C214—C215	1.366 (5)
C2—H1a^i	0.95	C214—H214	0.95
C2—H1b	0.95	C215—C216	1.385 (4)
C2—H1b^i	0.95	C215—H215	0.95
C3—H3c	0.95	C216—H216	0.95
C3—H3a	0.95	C221—C222	1.390 (4)
C3—H3b	0.95	C221—C226	1.385 (4)
C101—C201	1.522 (4)	C222—C223	1.384 (4)
C101—H101a	0.95	C222—H222	0.95
C101—H101b	0.95	C223—C224	1.370 (4)
C111—C112	1.393 (4)	C223—H223	0.95
C111—C116	1.387 (4)	C224—C225	1.379 (4)
C112—C113	1.380 (4)	C224—H224	0.95
C112—H112	0.95	C225—C226	1.385 (4)
C113—C114	1.373 (4)	C225—H225	0.95
C113—H113	0.95	C226—H226	0.95
F1···C225^iii	3.388 (4)	F3···O2	3.166 (4)
F1···C101^ii	3.500 (4)	F3···C201	3.199 (3)
F2···O2	3.055 (4)	F3···C215^i	3.344 (4)
F2···C126^ii	3.307 (3)	F3···C3	3.562 (5)
F2···C215^iv	3.328 (4)	F3···C214^i	3.596 (4)
F2···C125^ii	3.363 (4)	O2···C114^v	3.346 (4)
P1—Ru1—P1^i	171.71 (3)	H101a—C101—H101b	109.5
P1—Ru1—P2	82.77 (2)	P1—C111—C112	120.3 (2)
P1—Ru1—P2^i	103.19 (2)	P1—C111—C116	121.7 (2)
P1—Ru1—O1	84.56 (5)	C112—C111—C116	117.9 (2)
P1—Ru1—O1^i	88.24 (5)	C111—C112—C113	121.2 (3)
P1^i—Ru1—P2	103.19 (2)	C111—C112—H112	119.4
P1^i—Ru1—P2^i	82.77 (2)	C113—C112—H112	119.4
P1^i—Ru1—O1	88.24 (5)	C112—C113—C114	120.2 (3)
P1^i—Ru1—O1^i	84.56 (5)	C112—C113—H113	119.9
P2—Ru1—P2^i	90.07 (3)	C114—C113—H113	119.9
P2—Ru1—O1	161.24 (5)	C113—C114—C115	119.7 (3)
P2—Ru1—O1^i	106.29 (5)	C113—C114—H114	120.1
P2^i—Ru1—O1	106.29 (5)	C115—C114—H114	120.2
P2^i—Ru1—O1^i	161.24 (5)	C114—C115—C116	120.5 (3)
O1—Ru1—O1^i	59.45 (9)	C114—C115—H115	119.7
Ru1—P1—C101	108.96 (8)	C116—C115—H115	119.7
Ru1—P1—C111	115.02 (8)	C111—C116—C115	120.6 (3)
Ru1—P1—C121	117.07 (8)	C111—C116—H116	119.7
C101—P1—C111	104.8 (1)	C115—C116—H116	119.7
C101—P1—C121	107.6 (1)	P1—C121—C122	117.0 (2)
C111—P1—C121	102.5 (1)	P1—C121—C126	124.0 (2)
Ru1—P2—C201	107.03 (8)	C122—C121—C126	118.9 (2)
Ru1—P2—C211	127.21 (9)	C121—C122—C123	121.0 (2)
Ru1—P2—C221	116.68 (9)	C121—C122—H122	119.5
C201—P2—C211	102.3 (1)	C123—C122—H122	119.5
C201—P2—C221	99.3 (1)	C122—C123—C124	119.7 (3)
C211—P2—C221	100.2 (1)	C122—C123—H123	120.1
F1—P3—F1^ii	180.00	C124—C123—H123	120.1
F1—P3—F2	90.2 (1)	C123—C124—C125	120.1 (3)
F1—P3—F2^ii	89.8 (1)	C123—C124—H124	119.9
F1—P3—F3	90.5 (1)	C125—C124—H124	119.9
F1—P3—F3^ii	89.5 (1)	C124—C125—C126	120.7 (3)
F1^ii—P3—F2	89.8 (1)	C124—C125—H125	119.6
F1^ii—P3—F2^ii	90.2 (1)	C126—C125—H125	119.6
F1^ii—P3—F3	89.5 (1)	C121—C126—C125	119.5 (3)
F1^ii—P3—F3^ii	90.5 (1)	C121—C126—H126	120.2
F2—P3—F2^ii	180.00	C125—C126—H126	120.2
F2—P3—F3	89.2 (1)	P2—C201—C101	108.6 (2)
F2—P3—F3^ii	90.8 (1)	P2—C201—H201b	109.7
F2^ii—P3—F3	90.8 (1)	P2—C201—H210a	109.7
F2^ii—P3—F3^ii	89.2 (1)	C101—C201—H201b	109.7
F3—P3—F3^ii	180.00	C101—C201—H210a	109.7
Ru1—O1—C1	91.4 (2)	H201b—C201—H210a	109.5
C3—O2—H4	102.0	P2—C211—C212	123.2 (2)
O1—C1—O1^i	117.8 (3)	P2—C211—C216	118.6 (2)
O1—C1—C2	121.1 (2)	C212—C211—C216	118.2 (3)
O1^i—C1—C2	121.1 (2)	C211—C212—C213	120.6 (3)
C1—C2—H1c	109.5	C211—C212—H212	119.7
C1—C2—H1c^i	109.5	C213—C212—H212	119.7
C1—C2—H1a	109.5	C212—C213—C214	120.4 (3)
C1—C2—H1a^i	109.5	C212—C213—H213	119.8
C1—C2—H1b	109.5	C214—C213—H213	119.8
C1—C2—H1b^i	109.5	C213—C214—C215	119.7 (3)
H1c—C2—H1c^i	141.1	C213—C214—H214	120.1
H1c—C2—H1a	109.5	C215—C214—H214	120.1
H1c—C2—H1a^i	56.3	C214—C215—C216	120.2 (3)
H1c—C2—H1b	109.5	C214—C215—H215	119.9
H1c—C2—H1b^i	56.3	C216—C215—H215	119.9
H1c^i—C2—H1a	56.3	C211—C216—C215	120.8 (3)
H1c^i—C2—H1a^i	109.5	C211—C216—H216	119.6
H1c^i—C2—H1b	56.3	C215—C216—H216	119.6
H1c^i—C2—H1b^i	109.5	P2—C221—C222	120.1 (2)
H1a—C2—H1a^i	141.1	P2—C221—C226	121.3 (2)
H1a—C2—H1b	109.5	C222—C221—C226	118.3 (2)
H1a—C2—H1b^i	56.3	C221—C222—C223	120.7 (3)
H1a^i—C2—H1b	56.3	C221—C222—H222	119.6
H1a^i—C2—H1b^i	109.5	C223—C222—H222	119.6
H1b—C2—H1b^i	141.1	C222—C223—C224	120.4 (3)
O2—C3—H3c	109.5	C222—C223—H223	119.8
O2—C3—H3a	109.5	C224—C223—H223	119.8
O2—C3—H3b	109.5	C223—C224—C225	119.7 (3)
H3c—C3—H3a	109.5	C223—C224—H224	120.2
H3c—C3—H3b	109.5	C225—C224—H224	120.2
H3a—C3—H3b	109.5	C224—C225—C226	120.2 (3)
P1—C101—C201	108.4 (2)	C224—C225—H225	119.9
P1—C101—H101a	109.7	C226—C225—H225	119.9
P1—C101—H101b	109.7	C221—C226—C225	120.8 (2)
C201—C101—H101a	109.7	C221—C226—H226	119.6
C201—C101—H101b	109.7	C225—C226—H226	119.6
Ru1—P1—C101—C201	−33.5 (2)	O1—Ru1—P1—C111	−45.4 (1)
Ru1—P1—C111—C112	−72.7 (2)	O1—Ru1—P1—C121	75.0 (1)
Ru1—P1—C111—C116	103.4 (2)	O1—Ru1—P1^i—C101^i	−103.2 (1)
Ru1—P1—C121—C122	−44.3 (2)	O1—Ru1—P1^i—C111^i	14.1 (1)
Ru1—P1—C121—C126	134.0 (2)	O1—Ru1—P1^i—C121^i	134.5 (1)
Ru1—P1^i—C101^i—C201^i	−33.5 (2)	O1—Ru1—P2—C201	69.1 (2)
Ru1—P1^i—C111^i—C112^i	−72.7 (2)	O1—Ru1—P2—C211	−170.1 (2)
Ru1—P1^i—C111^i—C116^i	103.4 (2)	O1—Ru1—P2—C221	−41.0 (2)
Ru1—P1^i—C121^i—C122^i	−44.3 (2)	O1—Ru1—P2^i—C201^i	107.3 (1)
Ru1—P1^i—C121^i—C126^i	134.0 (2)	O1—Ru1—P2^i—C211^i	−131.9 (1)
Ru1—P2—C201—C101	−49.0 (2)	O1—Ru1—P2^i—C221^i	−2.8 (1)
Ru1—P2—C211—C212	−112.6 (2)	O1—Ru1—O1^i—C1	0.0000 (1)
Ru1—P2—C211—C216	70.4 (2)	C101—P1—C111—C112	46.9 (2)
Ru1—P2—C221—C222	−174.1 (2)	C101—P1—C111—C116	−137.0 (2)
Ru1—P2—C221—C226	11.3 (2)	C101—P1—C121—C122	−167.3 (2)
Ru1—P2^i—C201^i—C101^i	−49.0 (2)	C101—P1—C121—C126	11.0 (3)
Ru1—P2^i—C211^i—C212^i	−112.6 (2)	C101—C201—P2—C211	175.5 (2)
Ru1—P2^i—C211^i—C216^i	70.4 (2)	C101—C201—P2—C221	72.7 (2)
Ru1—P2^i—C221^i—C222^i	−174.1 (2)	C111—P1—C101—C201	−157.1 (2)
Ru1—P2^i—C221^i—C226^i	11.3 (2)	C111—P1—C121—C122	82.6 (2)
Ru1—O1—C1—O1^i	0.0000	C111—P1—C121—C126	−99.1 (2)
Ru1—O1—C1—C2	180.0000 (1)	C111—C112—C113—C114	0.2 (5)
Ru1—O1^i—C1—O1	0.0000	C111—C116—C115—C114	1.1 (5)
Ru1—O1^i—C1—C2	180.0000 (1)	C112—C111—P1—C121	159.1 (2)
P1—Ru1—P1^i—C101^i	−132.90 (9)	C112—C111—C116—C115	−0.8 (4)
P1—Ru1—P1^i—C111^i	−15.6 (1)	C112—C113—C114—C115	0.0 (5)
P1—Ru1—P1^i—C121^i	104.84 (9)	C113—C112—C111—C116	0.2 (4)
P1—Ru1—P2—C201	21.29 (9)	C113—C114—C115—C116	−0.6 (5)
P1—Ru1—P2—C211	142.0 (1)	C116—C111—P1—C121	−24.8 (3)
P1—Ru1—P2—C221	−88.81 (9)	C121—P1—C101—C201	94.3 (2)
P1—Ru1—P2^i—C201^i	−164.58 (9)	C121—C122—C123—C124	−0.3 (4)
P1—Ru1—P2^i—C211^i	−43.8 (1)	C121—C126—C125—C124	−0.8 (4)
P1—Ru1—P2^i—C221^i	85.32 (9)	C122—C121—C126—C125	1.4 (4)
P1—Ru1—O1—C1	91.16 (8)	C122—C123—C124—C125	1.0 (5)
P1—Ru1—O1^i—C1	−84.72 (8)	C123—C122—C121—C126	−0.9 (4)
P1—C101—C201—P2	52.3 (2)	C123—C124—C125—C126	−0.4 (5)
P1—C111—C112—C113	176.4 (2)	C201—P2—C211—C212	10.1 (3)
P1—C111—C116—C115	−177.0 (2)	C201—P2—C211—C216	−166.8 (2)
P1—C121—C122—C123	177.5 (2)	C201—P2—C221—C222	71.4 (2)
P1—C121—C126—C125	−176.8 (2)	C201—P2—C221—C226	−103.2 (2)
P2—Ru1—P1—C101	3.44 (9)	C211—P2—C221—C222	−33.0 (2)
P2—Ru1—P1—C111	120.8 (1)	C211—P2—C221—C226	152.5 (2)
P2—Ru1—P1—C121	−118.8 (1)	C211—C212—C213—C214	−0.4 (5)
P2—Ru1—P1^i—C101^i	91.80 (9)	C211—C216—C215—C214	−1.6 (5)
P2—Ru1—P1^i—C111^i	−150.9 (1)	C212—C211—P2—C221	112.1 (2)
P2—Ru1—P1^i—C121^i	−30.5 (1)	C212—C211—C216—C215	2.0 (4)
P2—Ru1—P2^i—C201^i	−82.00 (9)	C212—C213—C214—C215	0.7 (5)
P2—Ru1—P2^i—C211^i	38.8 (1)	C213—C212—C211—C216	−1.0 (4)
P2—Ru1—P2^i—C221^i	167.9 (1)	C213—C214—C215—C216	0.3 (5)
P2—Ru1—O1—C1	43.5 (2)	C216—C211—P2—C221	−64.8 (2)
P2—Ru1—O1^i—C1	−166.66 (7)	C221—C222—C223—C224	−0.7 (5)
P2—C211—C212—C213	−177.9 (2)	C221—C226—C225—C224	−0.2 (4)
P2—C211—C216—C215	179.1 (2)	C222—C221—C226—C225	−0.3 (4)
P2—C221—C222—C223	−173.9 (2)	C222—C223—C224—C225	0.2 (5)
P2—C221—C226—C225	174.3 (2)	C223—C222—C221—C226	0.8 (4)
O1—Ru1—P1—C101	−162.7 (1)	C223—C224—C225—C226	0.3 (5)

Symmetry codes: (i) −x+2, y, −z+3/2; (ii) −x+3/2, −y+1/2, −z+1; (iii) x−1/2, y+1/2, z; (iv) x−1/2, −y+1/2, z−1/2; (v) −x+2, −y, −z+1.