Carbonylchloro(η5-cyclopentadienyl)(1-ethoxybutylidene)ruthenium

Abboud, K.A.; Yin, J.; Jones, W.

doi:10.1107/S0108270197099459

Carbonylchloro(⁵-cyclopentadienyl)(1-ethoxybutylidene)ruthenium

The title compound 1, [Ru(C₅H₅)(C₆H₁₂O)Cl(CO)], was synthesized from carbonyl-(⁵-cyclopentadienyl)(2-ethoxy)-1-Ruthenacyclopentene by treatment with HCl. Ru has a distorted tetrahedron geometry that is best described as a tri-legged piano stool. The cyclopentadienyl (cp) ring is asymmetrically bonded with Ru-C distances ranging from 2.188 (8) to 2.297 (7) Å.

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Carbonylchloro(⁵-cyclopentadienyl)(1-ethoxybutylidene)ruthenium

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	Crystallographic Information File (CIF) Contains datablocks 1, global
	Structure factor file (CIF format) Contains datablock rubc

Carbonylchloro(5-cyclopentadienyl)(1-ethoxybutylidene)ruthenium

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Carbonylchloro(⁵-cyclopentadienyl)(1-ethoxybutylidene)ruthenium