Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229617014255/qs3062sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S2053229617014255/qs3062Isup2.hkl |
CCDC reference: 1577766
Data collection: CrystalClear (Rigaku, 2000); cell refinement: CrystalClear (Rigaku, 2000); data reduction: CrystalClear (Rigaku, 2000); program(s) used to solve structure: SIR2014 (Burla et al., 2015); program(s) used to refine structure: SHELXT (Sheldrick, 2015a); molecular graphics: SHELXL2016 (Sheldrick, 2015b); software used to prepare material for publication: ORTEP-3 (Farrugia, 2012).
[Pt(C17H18N2)(C5H5N)2](NO3)2 | Z = 2 |
Mr = 727.64 | F(000) = 716 |
Triclinic, P1 | Dx = 1.808 Mg m−3 |
a = 10.264 (2) Å | Mo Kα radiation, λ = 0.7107 Å |
b = 12.066 (3) Å | Cell parameters from 4674 reflections |
c = 13.382 (3) Å | θ = 3.2–27.5° |
α = 98.7061 (14)° | µ = 5.30 mm−1 |
β = 110.5915 (15)° | T = 173 K |
γ = 113.5911 (16)° | Prism, colorless |
V = 1336.8 (5) Å3 | 0.20 × 0.20 × 0.20 mm |
Rigaku Saturn diffractometer | 5457 reflections with I > 2σ(I) |
ω scans | Rint = 0.023 |
Absorption correction: multi-scan (CrystalClear; Rigaku, 2000) | θmax = 27.5°, θmin = 3.2° |
Tmin = 0.636, Tmax = 1.000 | h = −13→11 |
10468 measured reflections | k = −15→15 |
5837 independent reflections | l = −17→16 |
Refinement on F2 | 0 restraints |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.021 | H-atom parameters constrained |
wR(F2) = 0.050 | w = 1/[σ2(Fo2) + (0.0229P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.04 | (Δ/σ)max = 0.001 |
5837 reflections | Δρmax = 1.85 e Å−3 |
361 parameters | Δρmin = −1.11 e Å−3 |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
x | y | z | Uiso*/Ueq | ||
Pt1 | 0.05838 (2) | 0.20220 (2) | 0.20510 (2) | 0.01374 (4) | |
N1 | 0.2911 (3) | 0.3271 (2) | 0.25535 (19) | 0.0147 (5) | |
N2 | 0.1247 (3) | 0.1704 (2) | 0.3551 (2) | 0.0174 (5) | |
N3 | −0.0188 (3) | 0.2202 (2) | 0.04821 (19) | 0.0153 (5) | |
H3N | 0.061208 | 0.224607 | 0.020514 | 0.018* | |
N4 | −0.1767 (3) | 0.0759 (2) | 0.1488 (2) | 0.0206 (5) | |
H4BN | −0.188481 | −0.002700 | 0.150120 | 0.025* | |
H4AN | −0.211729 | 0.102905 | 0.196048 | 0.025* | |
O1 | 0.1453 (3) | 0.1555 (2) | −0.06580 (17) | 0.0251 (5) | |
O2 | 0.1311 (3) | 0.1237 (2) | −0.23416 (19) | 0.0316 (5) | |
C14 | 0.0948 (3) | 0.4622 (3) | 0.1223 (2) | 0.0172 (6) | |
O3 | −0.0227 (3) | 0.1860 (2) | −0.1959 (2) | 0.0400 (6) | |
N6 | 0.5923 (3) | 0.1035 (3) | 0.2819 (2) | 0.0301 (6) | |
C15 | 0.2204 (3) | 0.5293 (3) | 0.0956 (2) | 0.0182 (6) | |
C26 | −0.0202 (4) | 0.4563 (3) | 0.2594 (3) | 0.0260 (7) | |
H26 | −0.105825 | 0.371888 | 0.213417 | 0.031* | |
C9 | 0.1065 (4) | 0.1686 (3) | 0.5273 (3) | 0.0266 (7) | |
H9 | 0.066114 | 0.187655 | 0.577487 | 0.032* | |
N5 | 0.0838 (3) | 0.1557 (2) | −0.1667 (2) | 0.0229 (5) | |
C2 | 0.5205 (3) | 0.5324 (3) | 0.3704 (3) | 0.0259 (7) | |
H2 | 0.568846 | 0.613826 | 0.426712 | 0.031* | |
C1 | 0.3650 (3) | 0.4429 (3) | 0.3362 (2) | 0.0188 (6) | |
H1 | 0.307155 | 0.463341 | 0.370833 | 0.023* | |
C6 | 0.2217 (3) | 0.1185 (3) | 0.3808 (2) | 0.0211 (6) | |
H6 | 0.262572 | 0.101740 | 0.330185 | 0.025* | |
C21 | 0.3374 (4) | 0.7163 (3) | 0.2636 (3) | 0.0267 (7) | |
H21 | 0.415990 | 0.802894 | 0.309382 | 0.032* | |
C12 | −0.1712 (3) | 0.0968 (3) | −0.0275 (2) | 0.0227 (6) | |
H12A | −0.147040 | 0.026706 | −0.044858 | 0.027* | |
H12B | −0.227792 | 0.106356 | −0.099843 | 0.027* | |
C10 | 0.0678 (3) | 0.1940 (3) | 0.4267 (2) | 0.0217 (6) | |
H10 | −0.001556 | 0.229460 | 0.407910 | 0.026* | |
C8 | 0.2047 (4) | 0.1151 (3) | 0.5534 (3) | 0.0287 (7) | |
H8 | 0.232453 | 0.096178 | 0.621808 | 0.034* | |
C17 | 0.3507 (4) | 0.5409 (3) | −0.0258 (3) | 0.0306 (7) | |
H17 | 0.354979 | 0.501322 | −0.090689 | 0.037* | |
C22 | 0.2200 (4) | 0.6500 (3) | 0.2933 (3) | 0.0240 (7) | |
C4 | 0.5325 (4) | 0.3822 (3) | 0.2417 (3) | 0.0280 (7) | |
H4 | 0.589754 | 0.358230 | 0.208696 | 0.034* | |
C5 | 0.3755 (3) | 0.2974 (3) | 0.2099 (2) | 0.0206 (6) | |
H5 | 0.325241 | 0.215161 | 0.154158 | 0.025* | |
C20 | 0.3428 (3) | 0.6585 (3) | 0.1676 (3) | 0.0226 (6) | |
C7 | 0.2624 (4) | 0.0892 (3) | 0.4791 (3) | 0.0264 (7) | |
H7 | 0.329471 | 0.051578 | 0.495459 | 0.032* | |
C11 | −0.2749 (3) | 0.0643 (3) | 0.0314 (3) | 0.0243 (7) | |
H11A | −0.318630 | 0.123827 | 0.033727 | 0.029* | |
H11B | −0.365337 | −0.024540 | −0.010430 | 0.029* | |
C13 | −0.0433 (3) | 0.3333 (3) | 0.0391 (2) | 0.0183 (6) | |
H13A | −0.138552 | 0.320098 | 0.049504 | 0.022* | |
H13B | −0.066466 | 0.335362 | −0.038764 | 0.022* | |
C16 | 0.2290 (4) | 0.4740 (3) | −0.0021 (3) | 0.0224 (6) | |
H16 | 0.148608 | 0.389184 | −0.051682 | 0.027* | |
C27 | 0.0950 (3) | 0.5203 (3) | 0.2220 (2) | 0.0199 (6) | |
C25 | −0.0092 (4) | 0.5143 (4) | 0.3596 (3) | 0.0356 (8) | |
H25 | −0.085807 | 0.468527 | 0.383191 | 0.043* | |
C19 | 0.4666 (4) | 0.7256 (3) | 0.1380 (3) | 0.0315 (8) | |
H19 | 0.546968 | 0.811583 | 0.184356 | 0.038* | |
C24 | 0.1134 (5) | 0.6406 (4) | 0.4294 (3) | 0.0414 (9) | |
H24 | 0.118572 | 0.679229 | 0.499114 | 0.050* | |
O4 | 0.6838 (4) | 0.0678 (3) | 0.3318 (3) | 0.0643 (9) | |
O5 | 0.6216 (5) | 0.1590 (3) | 0.2158 (3) | 0.0789 (12) | |
C23 | 0.2232 (4) | 0.7067 (3) | 0.3972 (3) | 0.0365 (8) | |
H23 | 0.304134 | 0.792388 | 0.444066 | 0.044* | |
C18 | 0.4709 (4) | 0.6684 (4) | 0.0452 (3) | 0.0358 (8) | |
H18 | 0.554694 | 0.713845 | 0.027524 | 0.043* | |
O6 | 0.4757 (3) | 0.0869 (3) | 0.2963 (3) | 0.0719 (10) | |
C3 | 0.6060 (4) | 0.5021 (3) | 0.3216 (3) | 0.0309 (7) | |
H3 | 0.713373 | 0.562879 | 0.342839 | 0.037* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Pt1 | 0.01219 (6) | 0.01539 (6) | 0.01482 (6) | 0.00744 (5) | 0.00585 (4) | 0.00684 (4) |
N1 | 0.0122 (11) | 0.0164 (11) | 0.0146 (11) | 0.0066 (9) | 0.0046 (9) | 0.0084 (9) |
N2 | 0.0145 (12) | 0.0182 (11) | 0.0176 (12) | 0.0067 (10) | 0.0061 (10) | 0.0081 (10) |
N3 | 0.0135 (12) | 0.0186 (11) | 0.0147 (11) | 0.0093 (10) | 0.0053 (9) | 0.0061 (9) |
N4 | 0.0151 (12) | 0.0220 (12) | 0.0256 (13) | 0.0091 (10) | 0.0094 (11) | 0.0104 (11) |
O1 | 0.0300 (12) | 0.0319 (12) | 0.0208 (11) | 0.0194 (10) | 0.0129 (10) | 0.0117 (9) |
O2 | 0.0414 (14) | 0.0331 (12) | 0.0259 (12) | 0.0159 (11) | 0.0231 (11) | 0.0113 (10) |
C14 | 0.0174 (14) | 0.0208 (13) | 0.0174 (14) | 0.0142 (12) | 0.0049 (11) | 0.0100 (11) |
O3 | 0.0436 (15) | 0.0486 (15) | 0.0308 (13) | 0.0343 (13) | 0.0078 (11) | 0.0097 (12) |
N6 | 0.0241 (15) | 0.0318 (15) | 0.0301 (15) | 0.0143 (13) | 0.0105 (12) | 0.0026 (12) |
C15 | 0.0174 (14) | 0.0209 (14) | 0.0209 (14) | 0.0129 (12) | 0.0070 (12) | 0.0127 (12) |
C26 | 0.0244 (17) | 0.0322 (16) | 0.0278 (17) | 0.0200 (14) | 0.0108 (13) | 0.0115 (14) |
C9 | 0.0271 (17) | 0.0242 (15) | 0.0215 (16) | 0.0045 (13) | 0.0137 (14) | 0.0067 (13) |
N5 | 0.0250 (14) | 0.0180 (12) | 0.0215 (13) | 0.0090 (11) | 0.0088 (11) | 0.0052 (10) |
C2 | 0.0191 (16) | 0.0193 (14) | 0.0248 (16) | 0.0067 (13) | 0.0006 (13) | 0.0019 (12) |
C1 | 0.0193 (15) | 0.0217 (14) | 0.0150 (14) | 0.0109 (12) | 0.0060 (12) | 0.0070 (11) |
C6 | 0.0192 (15) | 0.0243 (14) | 0.0206 (15) | 0.0127 (13) | 0.0068 (12) | 0.0095 (12) |
C21 | 0.0230 (16) | 0.0204 (14) | 0.0240 (16) | 0.0107 (13) | −0.0009 (13) | 0.0040 (12) |
C12 | 0.0177 (15) | 0.0201 (14) | 0.0201 (15) | 0.0056 (12) | 0.0041 (12) | 0.0032 (12) |
C10 | 0.0194 (15) | 0.0238 (14) | 0.0224 (15) | 0.0090 (13) | 0.0117 (13) | 0.0084 (12) |
C8 | 0.0264 (17) | 0.0291 (16) | 0.0175 (15) | 0.0042 (14) | 0.0055 (13) | 0.0125 (13) |
C17 | 0.0320 (19) | 0.0411 (19) | 0.0328 (18) | 0.0232 (17) | 0.0200 (16) | 0.0200 (16) |
C22 | 0.0266 (17) | 0.0258 (15) | 0.0200 (15) | 0.0181 (14) | 0.0053 (13) | 0.0065 (13) |
C4 | 0.0223 (17) | 0.0318 (17) | 0.0350 (18) | 0.0139 (14) | 0.0167 (15) | 0.0134 (15) |
C5 | 0.0202 (15) | 0.0221 (14) | 0.0199 (15) | 0.0098 (13) | 0.0101 (12) | 0.0069 (12) |
C20 | 0.0171 (15) | 0.0256 (15) | 0.0234 (15) | 0.0118 (13) | 0.0039 (12) | 0.0129 (13) |
C7 | 0.0208 (16) | 0.0257 (15) | 0.0268 (16) | 0.0110 (13) | 0.0042 (13) | 0.0119 (13) |
C11 | 0.0109 (14) | 0.0238 (15) | 0.0265 (16) | 0.0038 (12) | 0.0021 (12) | 0.0087 (13) |
C13 | 0.0171 (15) | 0.0211 (14) | 0.0189 (14) | 0.0122 (12) | 0.0058 (12) | 0.0100 (12) |
C16 | 0.0256 (16) | 0.0265 (15) | 0.0240 (16) | 0.0169 (14) | 0.0130 (13) | 0.0150 (13) |
C27 | 0.0221 (16) | 0.0247 (15) | 0.0192 (14) | 0.0180 (13) | 0.0071 (12) | 0.0104 (12) |
C25 | 0.040 (2) | 0.051 (2) | 0.036 (2) | 0.0317 (19) | 0.0231 (17) | 0.0211 (18) |
C19 | 0.0181 (16) | 0.0307 (17) | 0.0340 (19) | 0.0057 (14) | 0.0049 (14) | 0.0165 (15) |
C24 | 0.054 (3) | 0.054 (2) | 0.0252 (18) | 0.036 (2) | 0.0185 (18) | 0.0067 (17) |
O4 | 0.0558 (19) | 0.082 (2) | 0.066 (2) | 0.0550 (19) | 0.0147 (16) | 0.0256 (18) |
O5 | 0.150 (4) | 0.092 (3) | 0.090 (3) | 0.097 (3) | 0.095 (3) | 0.064 (2) |
C23 | 0.045 (2) | 0.0348 (18) | 0.0271 (18) | 0.0251 (17) | 0.0100 (16) | 0.0028 (15) |
C18 | 0.0232 (18) | 0.049 (2) | 0.042 (2) | 0.0162 (17) | 0.0179 (16) | 0.0277 (18) |
O6 | 0.0392 (18) | 0.086 (2) | 0.093 (3) | 0.0303 (18) | 0.0407 (18) | 0.009 (2) |
C3 | 0.0155 (16) | 0.0252 (16) | 0.0385 (19) | 0.0024 (13) | 0.0090 (14) | 0.0066 (15) |
Pt1—N1 | 2.028 (2) | C2—H2 | 0.9500 |
Pt1—N2 | 2.030 (2) | C1—H1 | 0.9500 |
Pt1—N3 | 2.047 (2) | C6—C7 | 1.379 (4) |
Pt1—N4 | 2.035 (2) | C6—H6 | 0.9500 |
N1—C1 | 1.348 (3) | C21—C22 | 1.383 (4) |
C1—C2 | 1.371 (4) | C21—H21 | 0.9500 |
C2—C3 | 1.385 (4) | C12—H12A | 0.9900 |
N4—C11 | 1.487 (4) | C12—H12B | 0.9900 |
C11—C12 | 1.502 (4) | C10—H10 | 0.9500 |
N3—C12 | 1.501 (3) | C8—C7 | 1.380 (5) |
N3—C13 | 1.497 (3) | C8—H8 | 0.9500 |
C13—C14 | 1.506 (4) | C17—C16 | 1.364 (4) |
C14—C15 | 1.421 (4) | C17—C18 | 1.416 (5) |
C15—C16 | 1.424 (4) | C17—H17 | 0.9500 |
C19—C20 | 1.434 (4) | C22—C23 | 1.437 (4) |
C20—C21 | 1.395 (4) | C22—C27 | 1.444 (4) |
N1—C5 | 1.342 (3) | C4—C5 | 1.375 (4) |
N2—C10 | 1.337 (4) | C4—C3 | 1.377 (4) |
N2—C6 | 1.351 (3) | C4—H4 | 0.9500 |
N3—H3N | 1.0000 | C5—H5 | 0.9500 |
N4—H4BN | 0.9100 | C7—H7 | 0.9500 |
N4—H4AN | 0.9100 | C11—H11A | 0.9900 |
O1—N5 | 1.274 (3) | C11—H11B | 0.9900 |
O2—N5 | 1.246 (3) | C13—H13A | 0.9900 |
C14—C27 | 1.409 (4) | C13—H13B | 0.9900 |
O3—N5 | 1.243 (3) | C16—H16 | 0.9500 |
N6—O6 | 1.221 (3) | C25—C24 | 1.410 (5) |
N6—O4 | 1.218 (4) | C25—H25 | 0.9500 |
N6—O5 | 1.236 (4) | C19—C18 | 1.349 (5) |
C15—C20 | 1.436 (4) | C19—H19 | 0.9500 |
C26—C25 | 1.359 (4) | C24—C23 | 1.349 (5) |
C26—C27 | 1.431 (4) | C24—H24 | 0.9500 |
C26—H26 | 0.9500 | C23—H23 | 0.9500 |
C9—C8 | 1.377 (5) | C18—H18 | 0.9500 |
C9—C10 | 1.382 (4) | C3—H3 | 0.9500 |
C9—H9 | 0.9500 | ||
N1—Pt1—N2 | 88.76 (9) | N2—C10—C9 | 122.1 (3) |
N1—Pt1—N4 | 177.95 (8) | N2—C10—H10 | 119.0 |
N2—Pt1—N4 | 93.10 (9) | C9—C10—H10 | 119.0 |
N1—Pt1—N3 | 94.14 (9) | C9—C8—C7 | 119.2 (3) |
N2—Pt1—N3 | 175.87 (8) | C9—C8—H8 | 120.4 |
N4—Pt1—N3 | 83.96 (10) | C7—C8—H8 | 120.4 |
C5—N1—C1 | 118.3 (2) | C16—C17—C18 | 120.9 (3) |
C5—N1—Pt1 | 121.50 (19) | C16—C17—H17 | 119.6 |
C1—N1—Pt1 | 120.16 (19) | C18—C17—H17 | 119.6 |
C10—N2—C6 | 119.1 (3) | C21—C22—C23 | 120.9 (3) |
C10—N2—Pt1 | 121.09 (19) | C21—C22—C27 | 120.3 (3) |
C6—N2—Pt1 | 119.7 (2) | C23—C22—C27 | 118.8 (3) |
C13—N3—C12 | 110.5 (2) | C5—C4—C3 | 119.4 (3) |
C13—N3—Pt1 | 117.71 (17) | C5—C4—H4 | 120.3 |
C12—N3—Pt1 | 105.66 (17) | C3—C4—H4 | 120.3 |
C13—N3—H3N | 107.5 | N1—C5—C4 | 122.1 (3) |
C12—N3—H3N | 107.5 | N1—C5—H5 | 119.0 |
Pt1—N3—H3N | 107.5 | C4—C5—H5 | 119.0 |
C11—N4—Pt1 | 111.34 (18) | C21—C20—C19 | 121.6 (3) |
C11—N4—H4BN | 109.4 | C21—C20—C15 | 119.4 (3) |
Pt1—N4—H4BN | 109.4 | C19—C20—C15 | 118.9 (3) |
C11—N4—H4AN | 109.4 | C6—C7—C8 | 119.4 (3) |
Pt1—N4—H4AN | 109.4 | C6—C7—H7 | 120.3 |
H4BN—N4—H4AN | 108.0 | C8—C7—H7 | 120.3 |
C27—C14—C15 | 119.9 (3) | N4—C11—C12 | 108.6 (2) |
C27—C14—C13 | 120.7 (3) | N4—C11—H11A | 110.0 |
C15—C14—C13 | 119.3 (2) | C12—C11—H11A | 110.0 |
O6—N6—O4 | 122.1 (4) | N4—C11—H11B | 110.0 |
O6—N6—O5 | 120.2 (3) | C12—C11—H11B | 110.0 |
O4—N6—O5 | 117.7 (3) | H11A—C11—H11B | 108.3 |
C14—C15—C16 | 122.4 (3) | N3—C13—C14 | 115.5 (2) |
C14—C15—C20 | 119.8 (3) | N3—C13—H13A | 108.4 |
C16—C15—C20 | 117.8 (3) | C14—C13—H13A | 108.4 |
C25—C26—C27 | 121.1 (3) | N3—C13—H13B | 108.4 |
C25—C26—H26 | 119.4 | C14—C13—H13B | 108.4 |
C27—C26—H26 | 119.4 | H13A—C13—H13B | 107.5 |
C8—C9—C10 | 118.9 (3) | C17—C16—C15 | 121.1 (3) |
C8—C9—H9 | 120.6 | C17—C16—H16 | 119.4 |
C10—C9—H9 | 120.6 | C15—C16—H16 | 119.4 |
O3—N5—O2 | 121.6 (3) | C14—C27—C26 | 123.5 (3) |
O3—N5—O1 | 119.5 (3) | C14—C27—C22 | 119.2 (3) |
O2—N5—O1 | 118.9 (2) | C26—C27—C22 | 117.3 (3) |
C1—C2—C3 | 119.0 (3) | C26—C25—C24 | 121.5 (3) |
C1—C2—H2 | 120.5 | C26—C25—H25 | 119.2 |
C3—C2—H2 | 120.5 | C24—C25—H25 | 119.2 |
N1—C1—C2 | 122.4 (3) | C18—C19—C20 | 121.0 (3) |
N1—C1—H1 | 118.8 | C18—C19—H19 | 119.5 |
C2—C1—H1 | 118.8 | C20—C19—H19 | 119.5 |
N2—C6—C7 | 121.3 (3) | C23—C24—C25 | 119.9 (3) |
N2—C6—H6 | 119.3 | C23—C24—H24 | 120.0 |
C7—C6—H6 | 119.3 | C25—C24—H24 | 120.0 |
C22—C21—C20 | 121.4 (3) | C24—C23—C22 | 121.3 (3) |
C22—C21—H21 | 119.3 | C24—C23—H23 | 119.4 |
C20—C21—H21 | 119.3 | C22—C23—H23 | 119.4 |
N3—C12—C11 | 109.2 (2) | C19—C18—C17 | 120.2 (3) |
N3—C12—H12A | 109.8 | C19—C18—H18 | 119.9 |
C11—C12—H12A | 109.8 | C17—C18—H18 | 119.9 |
N3—C12—H12B | 109.8 | C4—C3—C2 | 118.8 (3) |
C11—C12—H12B | 109.8 | C4—C3—H3 | 120.6 |
H12A—C12—H12B | 108.3 | C2—C3—H3 | 120.6 |
N3—Pt1—N1—C1 | 110.2 (2) | Pt1—N4—C11—C12 | 26.1 (3) |
Pt1—N3—C13—C14 | 50.8 (3) | N3—C12—C11—N4 | −48.5 (3) |
N4—Pt1—N2—C10 | −60.1 (3) | C12—N3—C13—C14 | 172.3 (2) |
C27—C14—C15—C16 | 178.1 (3) | Pt1—N3—C13—C14 | 50.8 (3) |
C13—C14—C15—C16 | −6.2 (4) | C27—C14—C13—N3 | −98.9 (3) |
C27—C14—C15—C20 | −3.0 (4) | C15—C14—C13—N3 | 85.4 (3) |
C13—C14—C15—C20 | 172.7 (2) | C18—C17—C16—C15 | −1.2 (5) |
C5—N1—C1—C2 | 2.4 (4) | C14—C15—C16—C17 | 179.8 (3) |
Pt1—N1—C1—C2 | −177.8 (2) | C20—C15—C16—C17 | 0.9 (4) |
C3—C2—C1—N1 | −1.1 (5) | C15—C14—C27—C26 | −175.4 (2) |
C10—N2—C6—C7 | 0.2 (4) | C13—C14—C27—C26 | 9.0 (4) |
Pt1—N2—C6—C7 | −176.5 (2) | C15—C14—C27—C22 | 2.6 (4) |
C13—N3—C12—C11 | −81.7 (3) | C13—C14—C27—C22 | −173.0 (2) |
Pt1—N3—C12—C11 | 46.7 (2) | C25—C26—C27—C14 | 176.2 (3) |
C6—N2—C10—C9 | 0.9 (4) | C25—C26—C27—C22 | −1.8 (4) |
Pt1—N2—C10—C9 | 177.5 (2) | C21—C22—C27—C14 | 0.4 (4) |
C8—C9—C10—N2 | −1.2 (4) | C23—C22—C27—C14 | −177.5 (3) |
C10—C9—C8—C7 | 0.4 (5) | C21—C22—C27—C26 | 178.5 (3) |
C20—C21—C22—C23 | 174.9 (3) | C23—C22—C27—C26 | 0.6 (4) |
C20—C21—C22—C27 | −3.0 (4) | C27—C26—C25—C24 | 1.6 (5) |
C1—N1—C5—C4 | −1.5 (4) | C21—C20—C19—C18 | 179.7 (3) |
Pt1—N1—C5—C4 | 178.7 (2) | C15—C20—C19—C18 | −1.1 (4) |
C3—C4—C5—N1 | −0.7 (5) | C26—C25—C24—C23 | −0.1 (5) |
C22—C21—C20—C19 | −178.3 (3) | C25—C24—C23—C22 | −1.2 (5) |
C22—C21—C20—C15 | 2.5 (4) | C21—C22—C23—C24 | −177.0 (3) |
C14—C15—C20—C21 | 0.5 (4) | C27—C22—C23—C24 | 0.9 (5) |
C16—C15—C20—C21 | 179.4 (3) | C20—C19—C18—C17 | 0.9 (5) |
C14—C15—C20—C19 | −178.7 (3) | C16—C17—C18—C19 | 0.2 (5) |
C16—C15—C20—C19 | 0.2 (4) | C5—C4—C3—C2 | 1.9 (5) |
N2—C6—C7—C8 | −0.9 (5) | C1—C2—C3—C4 | −1.1 (5) |
C9—C8—C7—C6 | 0.6 (5) |
Subscribe to Acta Crystallographica Section C: Structural Chemistry
The full text of this article is available to subscribers to the journal.
- Information on subscribing
- Sample issue
- Purchase subscription
- Reduced-price subscriptions
- If you have already subscribed, you may need to register