Poly[diaqua­([mu]-4,4'-bipyridine)tetra­kis­([mu]-ferro­cenecarboxyl­ato)bis­(ferro­cenecarboxyl­ato)­tri­man­ganese(II)]

The title compound, [Mn₃Fe₆(C₅H₅)₆(C₆H₄O₂)₆(C₁₀H₈N₂)(H₂O)₂]_n, consists of two crystallographically unique Mn^II centers. One is situated on an inversion center and is octa­hedrally coordinated by two N atoms from two bridging 4,4'-bipyridine (4,4'-bipy) ligands and four O atoms, two from different bridging ferrocenecarboxyl­ate ([mu]₂-FcCOO^-; Fc is ferrocene) units and two from aqua ligands. The two halves of each 4,4'-bipy ligand are related by a center of symmetry. The second Mn^II center is in a strongly distorted tetra­gonal-pyramidal geometry, coordinated by five O atoms, three from three [mu]₂-FcCOO^- units and two from a fourth, chelating, [eta]²-FcCOO^- unit. The FcCOO^- units function as bridging ligands to adjacent Mn^II centers, leading to the formation of linear ...Mn1Mn2Mn2Mn1... chains. Adjacent chains are further bridged by 4,4'-bipy ligands, resulting in a two-dimensional layered polymer.

S1. Comment

The supramolecular assembly and crystal engineering of metal-organic coordination frameworks have recently attracted great interest, owing to their intriguing structural topologies and potential applications as functional materials (Batten & Robson, 1998; Eddaoudi et al., 2001). The construction of metal-organic coordination frameworks of mixed ligands with different metals continues to be an area of special interest in crystal engineering. The ferrocenecarboxylate (FcCOO⁻) ligand, like most carboxylate units, has been found to be versatile when generating complexes with various labile metal units. It can act not only as a bridging ligand, giving rise to one-dimensional polymers, but also as a simple ligand when combined with other bridging bipyridyl ligands (Hou et al., 2003; Li et al., 2003). As such, the coordination modes can be tailored by introducing different neutral ligands into the complexes. Recent examples have afforded a two-dimensional coordination polymer containing a mixture of carboxylate and bipyridyl (bipy) ligands, {[Mn(maleate)(µ-4,4'-bipy)]·0.5H₂O}_n (Zhan et al., 2000), and one with a mixture of phosphate and bipyridine ligands, {Mn[O₂PH(C₆H₅)]₂(µ-4,4'-bipy)}_n (Liao et al., 2001). We report here the crystal structure of the title two-dimensional polymeric compound, [Mn₃(C₁₀H₉FeCOO⁻)₆(H₂O)₂(C₁₀H₈N₂)]_n, (I), containing ferrocenecarboxylate and 4,4'-bipy ligands.

The structural unit of (I) is shown in Fig. 1. There are two types of Mn^II center. Atom Mn1 is situated on an inversion center with six-coordinated geometry, in which two O atoms from two µ₂-FcCOO⁻ units and two coordinated water molecules complete the equatorial plane, and two N atoms from two bridging 4,4'-bipy ligands occupy the axial positions (Table 1). Atoms Mn1, O6, O6A, O1W and O1WA [symmetry code: (A) −x + 2, −y + 1, −z + 2] are coplanar and the bond angles around each Mn1 center are 83.84 (12)–96.16 (12)° (Table 1), giving rise to a slightly distorted octahedral coordination environment. Each Mn2 center coordinates to five O atoms, two from one η²-FcCOO⁻ unit and three from three µ₂-FcCOO⁻ units (Table 1). Atoms Mn2, O1, O2, O3 and O5 are nearly coplanar (the mean deviation from the plane is 0.2215 Å). The five coordinating O atoms around the Mn2 center exhibit strongly distorted tetragonal–pyramidal geometry, mainly because of the presence of a chelating unit.

The FcCOO⁻ ligands function as bridging linkers to adjacent Mn^II centers, leading to the formation of linear ···Mn1Mn2Mn2Mn1··· chains (Fig. 2). The Mn1···Mn1A [symmetry code: (A) −x + 1, −y + 1, −z + 2] and Mn2···Mn2B [symmetry code: (B) −x + 1, −y + 1, −z + 2] distances are 10.9891 (11) and 3.7731 (12) Å, respectively. The Mn1 centers of adjacent chains are further connected by centrosymmetric 4,4'-bipy ligands, leading to a layered structure (Fig. 3); the nearest Mn1···Mn1(−x + 2, −y + 2, −z + 2) inter-chain separation is 11.4986 (11) Å. It is noteworthy that there are three types of FcCOO⁻ unit; one is a chelating bidentate ligand (η²-FcCOO⁻), and the other two are bridging bidentate µ₂-FcCOO⁻ ligands, of which one connects two Mn2 centers and the other bridges Mn1 and Mn2 centers (Fig. 1).

Analysis of the crystal packing of (I) reveals that there are two classical intramolecular hydrogen-bonding interactions, namely O—H···O involving the aqua ligands and carboxylate groups (Table 2).

S2. Experimental

A mixture of sodium ferrocenecarboxylate (0.1 mmol), 4,4'-bipyridine (0.1 mmol), MnSO₄·H₂O (0.1 mmol), ethane-1,2-diol (1.40 ml) and water (0.70 ml) were placed in a thick Pyrex tube. The tube was sealed and heated at 353 K for 18 h to give red block-like crystals. Analysis found: C 52.78, H 3.92, N 1.96%; calculated for C₇₆H₆₆Fe₆Mn₃N₂O₁₄: C 52.73, H 3.84, N 1.62%.

S3. Refinement

The H atoms of CH groups were positioned geometrically and allowed to ride on their parent atoms [C—H = 0.98 (Fc) and 0.93 Å (4,4'-bipy), with U_iso(H) = 1.2U_eq(C)]. The H atoms of water molecules were located in a difference Fourier map and refined with restraints on the O—H bond lengths.

Computing details

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.

Figures

	Fig. 1. The structure unit of (I), showing the atom-numbering scheme and displacement ellipsoids drawn at the 35% probability level. H atoms have been omitted for clarity. [Symmetry codes: (A) −x + 2, −y + 1, −z + 2; (B) −x + 1, −y + 1, −z + 2. Unlabelled atoms are related to labelled atoms by (−x + 1, −y + 1, −z + 2) and (−x + 2, −y + 1, −z + 2).]
	Fig. 2. The one-dimensional polymeric chain running parallel to the a axis. Fc units and H atoms have been omitted for clarity. [Symmetry codes: (A,B) −x + 1, −y + 1, −z + 2; (C) x + 1, y, z.]
	Fig. 3. The crystal structure of title compound, viewed along the c axis. Ferrocene groups and H atoms have been omitted for clarity.

Poly[diaqua(µ-4,4'-bipyridine)tetrakis(µ-ferrocenecarboxylato)bis(µ- ferrocenecarboxylato)trimanganese(II)]

Crystal data

[Mn3Fe6(C5H5)6(C6H4O2)6(C10H8N2)(H2O)2]	Z = 1
Mr = 1731.23	F(000) = 879
Triclinic, P1	Dx = 1.691 Mg m^−3
a = 10.9891 (11) Å	Mo Kα radiation, λ = 0.71073 Å
b = 11.4986 (11) Å	Cell parameters from 2728 reflections
c = 14.8928 (15) Å	θ = 2.7–28.2°
α = 82.308 (2)°	µ = 1.85 mm^−1
β = 83.418 (2)°	T = 293 K
γ = 66.000 (2)°	Block, red
V = 1699.9 (3) Å^3	0.40 × 0.30 × 0.21 mm

Data collection

Bruker SMART CCD 1K area-detector diffractometer	5972 independent reflections
Radiation source: fine-focus sealed tube	4258 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.027
ϕ and ω scans	θmax = 25.0°, θmin = 1.4°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −10→13
Tmin = 0.525, Tmax = 0.698	k = −13→13
9365 measured reflections	l = −17→17

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.102	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0427P)^2 + 0.8034P] where P = (Fo^2 + 2Fc^2)/3
5972 reflections	(Δ/σ)max = 0.001
465 parameters	Δρmax = 0.71 e Å^−3
6 restraints	Δρmin = −0.44 e Å^−3

Special details

Experimental. FT–IR data (KBr, cm⁻¹) 3446(m, b), 3100(w), 1577(m), 1532(s), 1473(s), 1392(s), 1357(s), 1190(w), 1105(w), 1026(w), 1002(w), 848(m), 584(s), 508(w), 485(m).

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Mn1	1.0000	0.5000	1.0000	0.0282 (2)
Mn2	0.53658 (6)	0.59642 (6)	0.89577 (4)	0.03230 (16)
O5	0.7154 (3)	0.6198 (3)	0.88344 (18)	0.0409 (7)
O6	0.9328 (3)	0.5692 (3)	0.86428 (18)	0.0397 (7)
Fe3	0.79051 (6)	0.58642 (6)	0.63538 (4)	0.03417 (16)
C23	0.8042 (4)	0.6750 (4)	0.7411 (3)	0.0315 (9)
C24	0.9105 (4)	0.6643 (4)	0.6726 (3)	0.0398 (10)
H24	1.0063	0.6199	0.6811	0.048*
C25	0.8517 (5)	0.7315 (4)	0.5908 (3)	0.0461 (11)
H25	0.9004	0.7395	0.5325	0.055*
C26	0.7115 (5)	0.7813 (4)	0.6067 (3)	0.0451 (11)
H26	0.6466	0.8297	0.5614	0.054*
C27	0.6805 (4)	0.7481 (4)	0.6994 (3)	0.0347 (9)
H27	0.5908	0.7699	0.7292	0.042*
C28	0.8187 (5)	0.4031 (4)	0.6832 (3)	0.0506 (12)
H28	0.8401	0.3636	0.7450	0.061*
C29	0.9115 (5)	0.4035 (4)	0.6098 (4)	0.0561 (13)
H29	1.0089	0.3643	0.6118	0.067*
C30	0.8402 (5)	0.4704 (5)	0.5332 (3)	0.0585 (14)
H30	0.8787	0.4855	0.4723	0.070*
C31	0.7027 (5)	0.5103 (5)	0.5603 (3)	0.0555 (13)
H31	0.6290	0.5590	0.5212	0.067*
C32	0.6897 (5)	0.4688 (4)	0.6519 (3)	0.0508 (12)
H32	0.6055	0.4833	0.6883	0.061*
C33	0.8183 (4)	0.6172 (4)	0.8355 (3)	0.0316 (9)
O3	0.6180 (3)	0.4056 (3)	0.85991 (19)	0.0426 (7)
O4	0.4744 (3)	0.3806 (3)	0.96866 (18)	0.0479 (8)
Fe2	0.46868 (7)	0.21055 (6)	0.76441 (4)	0.04619 (19)
C12	0.5694 (4)	0.2224 (4)	0.8675 (3)	0.0368 (9)
C13	0.4924 (5)	0.1491 (4)	0.8992 (3)	0.0525 (12)
H13	0.4210	0.1696	0.9478	0.063*
C14	0.5337 (6)	0.0442 (5)	0.8478 (4)	0.0721 (16)
H14	0.4971	−0.0215	0.8547	0.086*
C15	0.6363 (6)	0.0496 (5)	0.7856 (4)	0.0754 (17)
H15	0.6837	−0.0119	0.7410	0.090*
C16	0.6598 (4)	0.1593 (4)	0.7956 (3)	0.0537 (13)
H16	0.7268	0.1860	0.7606	0.064*
C17	0.3534 (6)	0.3910 (5)	0.7138 (4)	0.0724 (16)
H17	0.3450	0.4700	0.7370	0.087*
C18	0.2719 (6)	0.3237 (7)	0.7424 (4)	0.0794 (18)
H18	0.1967	0.3468	0.7882	0.095*
C19	0.3188 (6)	0.2166 (6)	0.6908 (4)	0.0844 (19)
H19	0.2820	0.1512	0.6957	0.101*
C20	0.4268 (7)	0.2189 (7)	0.6335 (4)	0.084 (2)
H20	0.4782	0.1565	0.5903	0.101*
C21	0.4477 (7)	0.3278 (6)	0.6467 (4)	0.0821 (19)
H21	0.5160	0.3549	0.6143	0.098*
C22	0.5537 (4)	0.3428 (4)	0.9005 (2)	0.0316 (9)
O1W	0.8029 (3)	0.5279 (4)	1.0666 (2)	0.0444 (8)
H1WA	0.778 (5)	0.480 (4)	1.095 (3)	0.071 (19)*
H1WB	0.744 (4)	0.574 (5)	1.040 (4)	0.09 (2)*
N1	0.9756 (3)	0.6996 (3)	1.0187 (2)	0.0415 (9)
C34	0.8826 (4)	0.8052 (4)	0.9817 (4)	0.0538 (13)
H34	0.8101	0.7982	0.9600	0.065*
C35	0.8862 (4)	0.9245 (4)	0.9734 (4)	0.0545 (13)
H35	0.8180	0.9952	0.9469	0.065*
C36	0.9939 (4)	0.9370 (3)	1.0055 (3)	0.0341 (9)
C37	1.0884 (5)	0.8293 (4)	1.0441 (3)	0.0540 (13)
H37	1.1620	0.8333	1.0666	0.065*
C38	1.0757 (5)	0.7139 (4)	1.0501 (3)	0.0540 (13)
H38	1.1414	0.6422	1.0778	0.065*
O1	0.4028 (3)	0.7858 (3)	0.8429 (2)	0.0504 (8)
O2	0.3321 (3)	0.6327 (3)	0.8512 (2)	0.0523 (8)
Fe1	0.17992 (6)	0.87763 (6)	0.65468 (5)	0.04489 (18)
C1	0.1887 (4)	0.8393 (4)	0.7915 (3)	0.0401 (10)
C2	0.1532 (5)	0.9726 (4)	0.7662 (3)	0.0550 (13)
H2	0.2029	1.0225	0.7779	0.066*
C3	0.0336 (5)	1.0195 (5)	0.7215 (4)	0.0689 (15)
H3	−0.0135	1.1079	0.6958	0.083*
C4	−0.0059 (5)	0.9184 (6)	0.7186 (4)	0.0673 (15)
H4	−0.0850	0.9242	0.6908	0.081*
C5	0.0878 (4)	0.8072 (5)	0.7624 (3)	0.0528 (12)
H5	0.0853	0.7222	0.7703	0.063*
C6	0.3653 (5)	0.7802 (6)	0.6002 (4)	0.0690 (16)
H6	0.4446	0.7299	0.6340	0.083*
C7	0.3216 (7)	0.9108 (7)	0.5693 (5)	0.090 (2)
H7	0.3648	0.9683	0.5767	0.108*
C8	0.2066 (7)	0.9415 (7)	0.5227 (4)	0.091 (2)
H8	0.1533	1.0257	0.4930	0.109*
C9	0.1817 (6)	0.8319 (7)	0.5257 (4)	0.0807 (18)
H9	0.1073	0.8256	0.4991	0.097*
C10	0.2785 (6)	0.7345 (6)	0.5725 (4)	0.0743 (16)
H10	0.2849	0.6464	0.5850	0.089*
C11	0.3133 (4)	0.7486 (4)	0.8307 (3)	0.0397 (10)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mn1	0.0285 (5)	0.0225 (4)	0.0364 (5)	−0.0129 (4)	−0.0035 (3)	−0.0021 (4)
Mn2	0.0346 (4)	0.0395 (4)	0.0265 (3)	−0.0187 (3)	−0.0031 (2)	−0.0013 (3)
O5	0.0375 (17)	0.0568 (19)	0.0332 (16)	−0.0260 (15)	−0.0040 (13)	0.0053 (14)
O6	0.0335 (16)	0.0505 (18)	0.0372 (17)	−0.0192 (14)	−0.0104 (13)	0.0042 (14)
Fe3	0.0422 (4)	0.0384 (3)	0.0278 (3)	−0.0225 (3)	−0.0003 (2)	−0.0033 (3)
C23	0.036 (2)	0.033 (2)	0.031 (2)	−0.0190 (19)	−0.0008 (17)	−0.0023 (17)
C24	0.043 (3)	0.044 (3)	0.042 (3)	−0.027 (2)	0.0012 (19)	−0.005 (2)
C25	0.068 (3)	0.045 (3)	0.033 (3)	−0.034 (2)	0.006 (2)	0.002 (2)
C26	0.056 (3)	0.038 (3)	0.039 (3)	−0.019 (2)	−0.009 (2)	0.008 (2)
C27	0.040 (2)	0.032 (2)	0.031 (2)	−0.0140 (19)	−0.0050 (17)	0.0009 (18)
C28	0.077 (4)	0.039 (3)	0.044 (3)	−0.032 (3)	−0.002 (2)	−0.002 (2)
C29	0.058 (3)	0.043 (3)	0.066 (4)	−0.019 (2)	0.007 (3)	−0.017 (3)
C30	0.088 (4)	0.062 (3)	0.037 (3)	−0.043 (3)	0.017 (3)	−0.019 (3)
C31	0.074 (4)	0.066 (3)	0.044 (3)	−0.043 (3)	−0.013 (2)	−0.010 (3)
C32	0.060 (3)	0.055 (3)	0.052 (3)	−0.038 (3)	0.001 (2)	−0.012 (2)
C33	0.035 (2)	0.034 (2)	0.034 (2)	−0.0204 (19)	−0.0025 (18)	−0.0052 (18)
O3	0.0439 (17)	0.0393 (17)	0.0507 (19)	−0.0234 (15)	0.0019 (14)	−0.0069 (14)
O4	0.0473 (18)	0.064 (2)	0.0276 (16)	−0.0162 (16)	0.0017 (13)	−0.0125 (15)
Fe2	0.0565 (4)	0.0530 (4)	0.0424 (4)	−0.0343 (4)	0.0027 (3)	−0.0131 (3)
C12	0.040 (2)	0.035 (2)	0.036 (2)	−0.016 (2)	−0.0030 (18)	−0.0019 (19)
C13	0.060 (3)	0.049 (3)	0.051 (3)	−0.029 (3)	−0.006 (2)	0.011 (2)
C14	0.090 (4)	0.045 (3)	0.092 (5)	−0.038 (3)	−0.013 (3)	0.001 (3)
C15	0.078 (4)	0.050 (3)	0.101 (5)	−0.021 (3)	0.001 (3)	−0.035 (3)
C16	0.045 (3)	0.052 (3)	0.068 (3)	−0.021 (2)	0.007 (2)	−0.022 (3)
C17	0.095 (5)	0.065 (4)	0.065 (4)	−0.033 (3)	−0.045 (3)	0.005 (3)
C18	0.065 (4)	0.122 (6)	0.058 (4)	−0.043 (4)	−0.013 (3)	−0.005 (4)
C19	0.106 (5)	0.110 (5)	0.076 (4)	−0.081 (4)	−0.018 (4)	−0.005 (4)
C20	0.118 (5)	0.128 (6)	0.043 (3)	−0.081 (5)	−0.003 (3)	−0.025 (4)
C21	0.120 (5)	0.120 (5)	0.043 (3)	−0.087 (5)	−0.016 (3)	0.003 (3)
C22	0.027 (2)	0.037 (2)	0.025 (2)	−0.0064 (18)	−0.0069 (16)	−0.0013 (18)
O1W	0.0314 (18)	0.051 (2)	0.050 (2)	−0.0178 (17)	−0.0063 (15)	0.0055 (17)
N1	0.050 (2)	0.0292 (19)	0.051 (2)	−0.0196 (18)	−0.0082 (17)	−0.0038 (17)
C34	0.041 (3)	0.033 (3)	0.092 (4)	−0.016 (2)	−0.018 (2)	−0.006 (3)
C35	0.041 (3)	0.026 (2)	0.097 (4)	−0.012 (2)	−0.025 (2)	0.003 (2)
C36	0.043 (2)	0.022 (2)	0.037 (2)	−0.0123 (18)	−0.0051 (18)	−0.0031 (18)
C37	0.059 (3)	0.029 (2)	0.081 (4)	−0.019 (2)	−0.040 (3)	0.003 (2)
C38	0.070 (3)	0.027 (2)	0.069 (3)	−0.018 (2)	−0.038 (3)	0.007 (2)
O1	0.0451 (18)	0.0532 (19)	0.062 (2)	−0.0286 (16)	−0.0167 (15)	0.0054 (16)
O2	0.0504 (19)	0.0391 (18)	0.068 (2)	−0.0188 (15)	−0.0233 (16)	0.0115 (16)
Fe1	0.0391 (4)	0.0383 (4)	0.0500 (4)	−0.0087 (3)	−0.0088 (3)	0.0029 (3)
C1	0.036 (2)	0.039 (2)	0.044 (3)	−0.013 (2)	−0.0026 (19)	−0.004 (2)
C2	0.062 (3)	0.034 (3)	0.064 (3)	−0.015 (2)	0.001 (3)	−0.009 (2)
C3	0.052 (3)	0.050 (3)	0.076 (4)	0.007 (3)	−0.006 (3)	0.002 (3)
C4	0.038 (3)	0.078 (4)	0.073 (4)	−0.011 (3)	−0.009 (2)	−0.002 (3)
C5	0.041 (3)	0.063 (3)	0.057 (3)	−0.025 (3)	−0.007 (2)	0.000 (3)
C6	0.044 (3)	0.096 (5)	0.053 (3)	−0.008 (3)	−0.004 (2)	−0.028 (3)
C7	0.099 (5)	0.100 (5)	0.093 (5)	−0.066 (5)	0.042 (4)	−0.039 (4)
C8	0.092 (5)	0.079 (5)	0.060 (4)	−0.003 (4)	0.007 (3)	0.023 (3)
C9	0.080 (4)	0.107 (5)	0.057 (4)	−0.036 (4)	−0.022 (3)	−0.004 (4)
C10	0.104 (5)	0.060 (4)	0.055 (4)	−0.026 (4)	−0.004 (3)	−0.014 (3)
C11	0.043 (3)	0.041 (3)	0.035 (2)	−0.018 (2)	−0.0005 (19)	−0.001 (2)

Geometric parameters (Å, º)

Mn1—O6	2.167 (3)	C13—H13	0.9800
Mn1—O6^i	2.167 (3)	C14—C15	1.392 (7)
Mn1—O1W	2.192 (3)	C14—H14	0.9800
Mn1—O1W^i	2.192 (3)	C15—C16	1.416 (6)
Mn1—N1	2.252 (3)	C15—H15	0.9800
Mn1—N1^i	2.252 (3)	C16—H16	0.9800
Mn2—O4^ii	2.055 (3)	C17—C21	1.395 (8)
Mn2—O5	2.073 (3)	C17—C18	1.404 (7)
Mn2—O3	2.123 (3)	C17—H17	0.9800
Mn2—O1	2.174 (3)	C18—C19	1.421 (8)
Mn2—O2	2.273 (3)	C18—H18	0.9800
Mn2—C11	2.573 (4)	C19—C20	1.387 (7)
O5—C33	1.259 (4)	C19—H19	0.9800
O6—C33	1.252 (4)	C20—C21	1.403 (8)
Fe3—C24	2.027 (4)	C20—H20	0.9800
Fe3—C31	2.036 (4)	C21—H21	0.9800
Fe3—C23	2.036 (4)	O1W—H1WA	0.76 (3)
Fe3—C30	2.038 (4)	O1W—H1WB	0.76 (3)
Fe3—C29	2.040 (5)	N1—C38	1.320 (5)
Fe3—C28	2.041 (4)	N1—C34	1.328 (6)
Fe3—C32	2.046 (4)	C34—C35	1.376 (6)
Fe3—C25	2.046 (4)	C34—H34	0.9300
Fe3—C26	2.051 (4)	C35—C36	1.392 (5)
Fe3—C27	2.052 (4)	C35—H35	0.9300
C23—C24	1.436 (5)	C36—C37	1.358 (6)
C23—C27	1.437 (5)	C36—C36^iii	1.495 (7)
C23—C33	1.469 (5)	C37—C38	1.380 (6)
C24—C25	1.422 (6)	C37—H37	0.9300
C24—H24	0.9800	C38—H38	0.9300
C25—C26	1.411 (6)	O1—C11	1.260 (5)
C25—H25	0.9800	O2—C11	1.263 (5)
C26—C27	1.423 (5)	Fe1—C6	2.018 (5)
C26—H26	0.9800	Fe1—C7	2.022 (5)
C27—H27	0.9800	Fe1—C1	2.031 (4)
C28—C29	1.407 (6)	Fe1—C8	2.036 (6)
C28—C32	1.408 (6)	Fe1—C2	2.037 (5)
C28—H28	0.9800	Fe1—C10	2.042 (5)
C29—C30	1.410 (7)	Fe1—C3	2.042 (5)
C29—H29	0.9800	Fe1—C4	2.047 (5)
C30—C31	1.415 (6)	Fe1—C5	2.049 (5)
C30—H30	0.9800	Fe1—C9	2.055 (6)
C31—C32	1.395 (6)	C1—C2	1.427 (6)
C31—H31	0.9800	C1—C5	1.427 (6)
C32—H32	0.9800	C1—C11	1.470 (6)
O3—C22	1.259 (4)	C2—C3	1.411 (7)
O4—C22	1.259 (4)	C2—H2	0.9800
O4—Mn2^ii	2.055 (3)	C3—C4	1.403 (7)
Fe2—C16	2.030 (5)	C3—H3	0.9800
Fe2—C15	2.030 (6)	C4—C5	1.407 (7)
Fe2—C17	2.034 (6)	C4—H4	0.9800
Fe2—C20	2.035 (5)	C5—H5	0.9800
Fe2—C21	2.038 (6)	C6—C10	1.383 (7)
Fe2—C12	2.041 (4)	C6—C7	1.406 (9)
Fe2—C14	2.042 (6)	C6—H6	0.9800
Fe2—C13	2.046 (5)	C7—C8	1.406 (9)
Fe2—C19	2.054 (6)	C7—H7	0.9800
Fe2—C18	2.058 (6)	C8—C9	1.388 (9)
C12—C13	1.425 (6)	C8—H8	0.9800
C12—C16	1.427 (6)	C9—C10	1.365 (8)
C12—C22	1.470 (5)	C9—H9	0.9800
C13—C14	1.403 (7)	C10—H10	0.9800
O6—Mn1—O6^i	180.000 (1)	C22—C12—Fe2	124.4 (3)
O6—Mn1—O1W	96.16 (12)	C14—C13—C12	108.6 (4)
O6^i—Mn1—O1W	83.84 (12)	C14—C13—Fe2	69.8 (3)
O6—Mn1—O1W^i	83.84 (12)	C12—C13—Fe2	69.4 (2)
O6^i—Mn1—O1W^i	96.16 (12)	C14—C13—H13	125.7
O1W—Mn1—O1W^i	180.0	C12—C13—H13	125.7
O6—Mn1—N1	88.43 (12)	Fe2—C13—H13	125.7
O6^i—Mn1—N1	91.57 (12)	C15—C14—C13	107.9 (4)
O1W—Mn1—N1	92.86 (13)	C15—C14—Fe2	69.6 (3)
O1W^i—Mn1—N1	87.14 (13)	C13—C14—Fe2	70.1 (3)
O6—Mn1—N1^i	91.57 (12)	C15—C14—H14	126.0
O6^i—Mn1—N1^i	88.43 (12)	C13—C14—H14	126.0
O1W—Mn1—N1^i	87.14 (13)	Fe2—C14—H14	126.0
O1W^i—Mn1—N1^i	92.86 (13)	C14—C15—C16	109.3 (4)
N1—Mn1—N1^i	180.000 (1)	C14—C15—Fe2	70.5 (3)
O4^ii—Mn2—O5	87.53 (11)	C16—C15—Fe2	69.6 (3)
O4^ii—Mn2—O3	116.69 (12)	C14—C15—H15	125.3
O5—Mn2—O3	96.43 (11)	C16—C15—H15	125.3
O4^ii—Mn2—O1	101.24 (12)	Fe2—C15—H15	125.3
O5—Mn2—O1	100.32 (11)	C15—C16—C12	107.1 (4)
O3—Mn2—O1	139.01 (12)	C15—C16—Fe2	69.6 (3)
O4^ii—Mn2—O2	110.57 (12)	C12—C16—Fe2	69.9 (2)
O5—Mn2—O2	153.78 (11)	C15—C16—H16	126.4
O3—Mn2—O2	92.14 (11)	C12—C16—H16	126.4
O1—Mn2—O2	58.64 (10)	Fe2—C16—H16	126.4
O4^ii—Mn2—C11	108.33 (12)	C21—C17—C18	109.0 (5)
O5—Mn2—C11	128.02 (12)	C21—C17—Fe2	70.1 (3)
O3—Mn2—C11	117.02 (12)	C18—C17—Fe2	70.9 (4)
O1—Mn2—C11	29.26 (11)	C21—C17—H17	125.5
O2—Mn2—C11	29.38 (11)	C18—C17—H17	125.5
C33—O5—Mn2	149.0 (3)	Fe2—C17—H17	125.5
C33—O6—Mn1	131.4 (3)	C17—C18—C19	106.4 (5)
C24—Fe3—C31	162.08 (18)	C17—C18—Fe2	69.0 (3)
C24—Fe3—C23	41.39 (15)	C19—C18—Fe2	69.6 (4)
C31—Fe3—C23	155.80 (17)	C17—C18—H18	126.8
C24—Fe3—C30	124.03 (18)	C19—C18—H18	126.8
C31—Fe3—C30	40.64 (18)	Fe2—C18—H18	126.8
C23—Fe3—C30	161.9 (2)	C20—C19—C18	108.5 (5)
C24—Fe3—C29	106.29 (19)	C20—C19—Fe2	69.4 (3)
C31—Fe3—C29	67.8 (2)	C18—C19—Fe2	69.9 (3)
C23—Fe3—C29	124.98 (19)	C20—C19—H19	125.7
C30—Fe3—C29	40.5 (2)	C18—C19—H19	125.7
C24—Fe3—C28	119.65 (19)	Fe2—C19—H19	125.7
C31—Fe3—C28	67.6 (2)	C19—C20—C21	108.2 (5)
C23—Fe3—C28	107.66 (17)	C19—C20—Fe2	70.9 (3)
C30—Fe3—C28	68.05 (19)	C21—C20—Fe2	70.0 (3)
C29—Fe3—C28	40.34 (18)	C19—C20—H20	125.9
C24—Fe3—C32	155.33 (19)	C21—C20—H20	125.9
C31—Fe3—C32	39.98 (18)	Fe2—C20—H20	125.9
C23—Fe3—C32	121.01 (17)	C17—C21—C20	107.8 (5)
C30—Fe3—C32	67.94 (18)	C17—C21—Fe2	69.9 (3)
C29—Fe3—C32	67.74 (19)	C20—C21—Fe2	69.7 (3)
C28—Fe3—C32	40.31 (18)	C17—C21—H21	126.1
C24—Fe3—C25	40.87 (17)	C20—C21—H21	126.1
C31—Fe3—C25	125.91 (19)	Fe2—C21—H21	126.1
C23—Fe3—C25	68.82 (16)	O4—C22—O3	122.0 (4)
C30—Fe3—C25	107.02 (18)	O4—C22—C12	118.3 (4)
C29—Fe3—C25	119.63 (19)	O3—C22—C12	119.6 (3)
C28—Fe3—C25	154.5 (2)	Mn1—O1W—H1WA	130 (4)
C32—Fe3—C25	163.2 (2)	Mn1—O1W—H1WB	115 (5)
C24—Fe3—C26	68.74 (18)	H1WA—O1W—H1WB	106 (6)
C31—Fe3—C26	108.8 (2)	C38—N1—C34	116.0 (4)
C23—Fe3—C26	68.83 (17)	C38—N1—Mn1	117.9 (3)
C30—Fe3—C26	120.2 (2)	C34—N1—Mn1	124.2 (3)
C29—Fe3—C26	154.41 (19)	N1—C34—C35	124.4 (4)
C28—Fe3—C26	164.02 (18)	N1—C34—H34	117.8
C32—Fe3—C26	127.04 (19)	C35—C34—H34	117.8
C25—Fe3—C26	40.29 (17)	C34—C35—C36	118.6 (4)
C24—Fe3—C27	69.21 (16)	C34—C35—H35	120.7
C31—Fe3—C27	121.26 (19)	C36—C35—H35	120.7
C23—Fe3—C27	41.15 (15)	C37—C36—C35	117.0 (4)
C30—Fe3—C27	155.4 (2)	C37—C36—C36^iii	122.1 (5)
C29—Fe3—C27	163.22 (19)	C35—C36—C36^iii	120.9 (5)
C28—Fe3—C27	126.70 (17)	C36—C37—C38	120.3 (4)
C32—Fe3—C27	109.21 (17)	C36—C37—H37	119.9
C25—Fe3—C27	68.23 (16)	C38—C37—H37	119.9
C26—Fe3—C27	40.58 (15)	N1—C38—C37	123.7 (4)
C24—C23—C27	107.5 (4)	N1—C38—H38	118.2
C24—C23—C33	126.5 (4)	C37—C38—H38	118.2
C27—C23—C33	125.9 (3)	C11—O1—Mn2	93.2 (3)
C24—C23—Fe3	69.0 (2)	C11—O2—Mn2	88.6 (2)
C27—C23—Fe3	70.0 (2)	C6—Fe1—C7	40.7 (2)
C33—C23—Fe3	124.3 (3)	C6—Fe1—C1	106.5 (2)
C25—C24—C23	107.6 (4)	C7—Fe1—C1	124.8 (3)
C25—C24—Fe3	70.3 (2)	C6—Fe1—C8	67.5 (2)
C23—C24—Fe3	69.6 (2)	C7—Fe1—C8	40.5 (3)
C25—C24—H24	126.2	C1—Fe1—C8	163.3 (3)
C23—C24—H24	126.2	C6—Fe1—C2	120.4 (2)
Fe3—C24—H24	126.2	C7—Fe1—C2	108.0 (2)
C26—C25—C24	108.7 (4)	C1—Fe1—C2	41.07 (17)
C26—C25—Fe3	70.0 (2)	C8—Fe1—C2	127.2 (3)
C24—C25—Fe3	68.8 (2)	C6—Fe1—C10	39.8 (2)
C26—C25—H25	125.6	C7—Fe1—C10	67.4 (2)
C24—C25—H25	125.6	C1—Fe1—C10	119.8 (2)
Fe3—C25—H25	125.6	C8—Fe1—C10	66.3 (3)
C25—C26—C27	108.4 (4)	C2—Fe1—C10	155.0 (2)
C25—C26—Fe3	69.7 (2)	C6—Fe1—C3	156.2 (2)
C27—C26—Fe3	69.7 (2)	C7—Fe1—C3	121.9 (3)
C25—C26—H26	125.8	C1—Fe1—C3	68.4 (2)
C27—C26—H26	125.8	C8—Fe1—C3	110.4 (2)
Fe3—C26—H26	125.8	C2—Fe1—C3	40.5 (2)
C26—C27—C23	107.8 (4)	C10—Fe1—C3	163.0 (3)
C26—C27—Fe3	69.7 (2)	C6—Fe1—C4	161.6 (3)
C23—C27—Fe3	68.9 (2)	C7—Fe1—C4	156.5 (3)
C26—C27—H27	126.1	C1—Fe1—C4	68.47 (19)
C23—C27—H27	126.1	C8—Fe1—C4	122.1 (3)
Fe3—C27—H27	126.1	C2—Fe1—C4	68.1 (2)
C29—C28—C32	108.0 (5)	C10—Fe1—C4	126.0 (2)
C29—C28—Fe3	69.8 (3)	C3—Fe1—C4	40.1 (2)
C32—C28—Fe3	70.0 (3)	C6—Fe1—C5	124.6 (2)
C29—C28—H28	126.0	C7—Fe1—C5	162.0 (3)
C32—C28—H28	126.0	C1—Fe1—C5	40.95 (16)
Fe3—C28—H28	126.0	C8—Fe1—C5	155.3 (3)
C28—C29—C30	108.2 (5)	C2—Fe1—C5	68.46 (19)
C28—C29—Fe3	69.9 (3)	C10—Fe1—C5	107.9 (2)
C30—C29—Fe3	69.7 (3)	C3—Fe1—C5	67.6 (2)
C28—C29—H29	125.9	C4—Fe1—C5	40.2 (2)
C30—C29—H29	125.9	C6—Fe1—C9	66.7 (2)
Fe3—C29—H29	125.9	C7—Fe1—C9	67.5 (3)
C29—C30—C31	107.2 (4)	C1—Fe1—C9	154.0 (2)
C29—C30—Fe3	69.8 (3)	C8—Fe1—C9	39.7 (3)
C31—C30—Fe3	69.6 (2)	C2—Fe1—C9	164.3 (2)
C29—C30—H30	126.4	C10—Fe1—C9	38.9 (2)
C31—C30—H30	126.4	C3—Fe1—C9	127.9 (2)
Fe3—C30—H30	126.4	C4—Fe1—C9	109.6 (2)
C32—C31—C30	108.6 (5)	C5—Fe1—C9	120.6 (2)
C32—C31—Fe3	70.4 (2)	C2—C1—C5	107.3 (4)
C30—C31—Fe3	69.8 (2)	C2—C1—C11	126.4 (4)
C32—C31—H31	125.7	C5—C1—C11	126.0 (4)
C30—C31—H31	125.7	C2—C1—Fe1	69.7 (3)
Fe3—C31—H31	125.7	C5—C1—Fe1	70.2 (3)
C31—C32—C28	108.0 (4)	C11—C1—Fe1	120.2 (3)
C31—C32—Fe3	69.6 (3)	C3—C2—C1	107.6 (4)
C28—C32—Fe3	69.6 (2)	C3—C2—Fe1	70.0 (3)
C31—C32—H32	126.0	C1—C2—Fe1	69.2 (2)
C28—C32—H32	126.0	C3—C2—H2	126.2
Fe3—C32—H32	126.0	C1—C2—H2	126.2
O6—C33—O5	123.5 (4)	Fe1—C2—H2	126.2
O6—C33—C23	117.8 (3)	C4—C3—C2	108.8 (5)
O5—C33—C23	118.7 (3)	C4—C3—Fe1	70.1 (3)
C22—O3—Mn2	111.4 (2)	C2—C3—Fe1	69.6 (3)
C22—O4—Mn2^ii	143.9 (3)	C4—C3—H3	125.6
C16—Fe2—C15	40.81 (19)	C2—C3—H3	125.6
C16—Fe2—C17	122.5 (2)	Fe1—C3—H3	125.6
C15—Fe2—C17	158.1 (3)	C3—C4—C5	108.3 (5)
C16—Fe2—C20	120.1 (2)	C3—C4—Fe1	69.8 (3)
C15—Fe2—C20	106.4 (3)	C5—C4—Fe1	70.0 (3)
C17—Fe2—C20	67.5 (3)	C3—C4—H4	125.9
C16—Fe2—C21	105.4 (2)	C5—C4—H4	125.9
C15—Fe2—C21	121.7 (3)	Fe1—C4—H4	125.9
C17—Fe2—C21	40.1 (2)	C4—C5—C1	108.1 (4)
C20—Fe2—C21	40.3 (2)	C4—C5—Fe1	69.8 (3)
C16—Fe2—C12	41.03 (16)	C1—C5—Fe1	68.8 (3)
C15—Fe2—C12	68.33 (19)	C4—C5—H5	126.0
C17—Fe2—C12	108.51 (19)	C1—C5—H5	126.0
C20—Fe2—C12	156.7 (2)	Fe1—C5—H5	126.0
C21—Fe2—C12	121.72 (19)	C10—C6—C7	107.9 (5)
C16—Fe2—C14	68.5 (2)	C10—C6—Fe1	71.0 (3)
C15—Fe2—C14	40.0 (2)	C7—C6—Fe1	69.8 (3)
C17—Fe2—C14	160.9 (3)	C10—C6—H6	126.0
C20—Fe2—C14	123.0 (2)	C7—C6—H6	126.0
C21—Fe2—C14	157.9 (3)	Fe1—C6—H6	126.0
C12—Fe2—C14	68.46 (19)	C8—C7—C6	106.4 (5)
C16—Fe2—C13	68.45 (19)	C8—C7—Fe1	70.3 (3)
C15—Fe2—C13	67.3 (2)	C6—C7—Fe1	69.5 (3)
C17—Fe2—C13	125.4 (2)	C8—C7—H7	126.8
C20—Fe2—C13	160.0 (2)	C6—C7—H7	126.8
C21—Fe2—C13	159.3 (2)	Fe1—C7—H7	126.8
C12—Fe2—C13	40.82 (16)	C9—C8—C7	108.3 (6)
C14—Fe2—C13	40.13 (19)	C9—C8—Fe1	70.9 (4)
C16—Fe2—C19	156.3 (2)	C7—C8—Fe1	69.2 (4)
C15—Fe2—C19	122.4 (2)	C9—C8—H8	125.8
C17—Fe2—C19	67.2 (2)	C7—C8—H8	125.8
C20—Fe2—C19	39.7 (2)	Fe1—C8—H8	125.8
C21—Fe2—C19	67.1 (2)	C10—C9—C8	108.1 (6)
C12—Fe2—C19	162.1 (2)	C10—C9—Fe1	70.0 (3)
C14—Fe2—C19	109.5 (2)	C8—C9—Fe1	69.4 (3)
C13—Fe2—C19	126.3 (2)	C10—C9—H9	125.9
C16—Fe2—C18	159.7 (2)	C8—C9—H9	125.9
C15—Fe2—C18	159.1 (2)	Fe1—C9—H9	125.9
C17—Fe2—C18	40.1 (2)	C9—C10—C6	109.2 (6)
C20—Fe2—C18	67.7 (2)	C9—C10—Fe1	71.1 (3)
C21—Fe2—C18	67.6 (2)	C6—C10—Fe1	69.1 (3)
C12—Fe2—C18	125.1 (2)	C9—C10—H10	125.4
C14—Fe2—C18	125.1 (2)	C6—C10—H10	125.4
C13—Fe2—C18	111.0 (2)	Fe1—C10—H10	125.4
C19—Fe2—C18	40.4 (2)	O1—C11—O2	119.6 (4)
C13—C12—C16	107.0 (4)	O1—C11—C1	120.2 (4)
C13—C12—C22	126.0 (4)	O2—C11—C1	120.3 (4)
C16—C12—C22	126.9 (4)	O1—C11—Mn2	57.5 (2)
C13—C12—Fe2	69.8 (2)	O2—C11—Mn2	62.0 (2)
C16—C12—Fe2	69.1 (2)	C1—C11—Mn2	177.4 (3)
O4^ii—Mn2—O5—C33	172.6 (5)	C14—Fe2—C17—C18	−45.4 (8)
O3—Mn2—O5—C33	56.0 (5)	C13—Fe2—C17—C18	−80.7 (4)
O1—Mn2—O5—C33	−86.4 (5)	C19—Fe2—C17—C18	38.5 (3)
O2—Mn2—O5—C33	−52.3 (6)	C21—C17—C18—C19	0.0 (7)
C11—Mn2—O5—C33	−75.9 (6)	Fe2—C17—C18—C19	−59.9 (4)
O6^i—Mn1—O6—C33	49 (100)	C21—C17—C18—Fe2	59.9 (4)
O1W—Mn1—O6—C33	4.3 (3)	C16—Fe2—C18—C17	36.1 (8)
O1W^i—Mn1—O6—C33	−175.7 (3)	C15—Fe2—C18—C17	−158.3 (6)
N1—Mn1—O6—C33	−88.4 (3)	C20—Fe2—C18—C17	−81.0 (4)
N1^i—Mn1—O6—C33	91.6 (3)	C21—Fe2—C18—C17	−37.3 (3)
C31—Fe3—C23—C24	−170.4 (4)	C12—Fe2—C18—C17	76.6 (4)
C30—Fe3—C23—C24	41.8 (7)	C14—Fe2—C18—C17	163.5 (3)
C29—Fe3—C23—C24	74.0 (3)	C13—Fe2—C18—C17	120.5 (3)
C28—Fe3—C23—C24	115.1 (3)	C19—Fe2—C18—C17	−117.7 (5)
C32—Fe3—C23—C24	157.1 (3)	C16—Fe2—C18—C19	153.8 (6)
C25—Fe3—C23—C24	−38.1 (3)	C15—Fe2—C18—C19	−40.6 (8)
C26—Fe3—C23—C24	−81.5 (3)	C17—Fe2—C18—C19	117.7 (5)
C27—Fe3—C23—C24	−118.8 (3)	C20—Fe2—C18—C19	36.7 (3)
C24—Fe3—C23—C27	118.8 (3)	C21—Fe2—C18—C19	80.4 (4)
C31—Fe3—C23—C27	−51.5 (5)	C12—Fe2—C18—C19	−165.6 (3)
C30—Fe3—C23—C27	160.7 (5)	C14—Fe2—C18—C19	−78.8 (4)
C29—Fe3—C23—C27	−167.2 (2)	C13—Fe2—C18—C19	−121.8 (3)
C28—Fe3—C23—C27	−126.1 (2)	C17—C18—C19—C20	0.7 (7)
C32—Fe3—C23—C27	−84.0 (3)	Fe2—C18—C19—C20	−58.8 (5)
C25—Fe3—C23—C27	80.7 (3)	C17—C18—C19—Fe2	59.5 (4)
C26—Fe3—C23—C27	37.4 (2)	C16—Fe2—C19—C20	−37.7 (8)
C24—Fe3—C23—C33	−120.6 (4)	C15—Fe2—C19—C20	−76.0 (5)
C31—Fe3—C23—C33	69.0 (6)	C17—Fe2—C19—C20	81.7 (4)
C30—Fe3—C23—C33	−78.8 (6)	C21—Fe2—C19—C20	38.1 (4)
C29—Fe3—C23—C33	−46.7 (4)	C12—Fe2—C19—C20	161.3 (6)
C28—Fe3—C23—C33	−5.6 (4)	C14—Fe2—C19—C20	−118.4 (4)
C32—Fe3—C23—C33	36.5 (4)	C13—Fe2—C19—C20	−160.2 (4)
C25—Fe3—C23—C33	−158.8 (4)	C18—Fe2—C19—C20	119.9 (6)
C26—Fe3—C23—C33	157.9 (4)	C16—Fe2—C19—C18	−157.6 (5)
C27—Fe3—C23—C33	120.5 (4)	C15—Fe2—C19—C18	164.1 (4)
C27—C23—C24—C25	0.6 (4)	C17—Fe2—C19—C18	−38.2 (4)
C33—C23—C24—C25	178.1 (3)	C20—Fe2—C19—C18	−119.9 (6)
Fe3—C23—C24—C25	60.3 (3)	C21—Fe2—C19—C18	−81.9 (4)
C27—C23—C24—Fe3	−59.6 (3)	C12—Fe2—C19—C18	41.3 (9)
C33—C23—C24—Fe3	117.8 (4)	C14—Fe2—C19—C18	121.6 (4)
C31—Fe3—C24—C25	48.7 (7)	C13—Fe2—C19—C18	79.8 (4)
C23—Fe3—C24—C25	−118.4 (4)	C18—C19—C20—C21	−1.2 (8)
C30—Fe3—C24—C25	76.1 (3)	Fe2—C19—C20—C21	−60.3 (4)
C29—Fe3—C24—C25	116.7 (3)	C18—C19—C20—Fe2	59.1 (5)
C28—Fe3—C24—C25	158.3 (3)	C16—Fe2—C20—C19	163.5 (4)
C32—Fe3—C24—C25	−171.3 (4)	C15—Fe2—C20—C19	121.3 (4)
C26—Fe3—C24—C25	−36.8 (2)	C17—Fe2—C20—C19	−80.9 (4)
C27—Fe3—C24—C25	−80.4 (3)	C21—Fe2—C20—C19	−118.6 (6)
C31—Fe3—C24—C23	167.1 (6)	C12—Fe2—C20—C19	−165.6 (5)
C30—Fe3—C24—C23	−165.5 (3)	C14—Fe2—C20—C19	80.9 (5)
C29—Fe3—C24—C23	−124.9 (3)	C13—Fe2—C20—C19	52.9 (9)
C28—Fe3—C24—C23	−83.2 (3)	C18—Fe2—C20—C19	−37.4 (4)
C32—Fe3—C24—C23	−52.9 (5)	C16—Fe2—C20—C21	−77.9 (4)
C25—Fe3—C24—C23	118.4 (4)	C15—Fe2—C20—C21	−120.1 (4)
C26—Fe3—C24—C23	81.7 (3)	C17—Fe2—C20—C21	37.6 (4)
C27—Fe3—C24—C23	38.1 (2)	C12—Fe2—C20—C21	−47.0 (8)
C23—C24—C25—C26	−1.1 (5)	C14—Fe2—C20—C21	−160.5 (4)
Fe3—C24—C25—C26	58.8 (3)	C13—Fe2—C20—C21	171.4 (6)
C23—C24—C25—Fe3	−59.9 (3)	C19—Fe2—C20—C21	118.6 (6)
C24—Fe3—C25—C26	−120.4 (4)	C18—Fe2—C20—C21	81.2 (4)
C31—Fe3—C25—C26	76.2 (3)	C18—C17—C21—C20	−0.8 (7)
C23—Fe3—C25—C26	−81.8 (3)	Fe2—C17—C21—C20	59.7 (4)
C30—Fe3—C25—C26	116.8 (3)	C18—C17—C21—Fe2	−60.4 (4)
C29—Fe3—C25—C26	159.0 (3)	C19—C20—C21—C17	1.2 (7)
C28—Fe3—C25—C26	−168.6 (4)	Fe2—C20—C21—C17	−59.7 (4)
C32—Fe3—C25—C26	47.0 (7)	C19—C20—C21—Fe2	60.9 (5)
C27—Fe3—C25—C26	−37.5 (2)	C16—Fe2—C21—C17	−122.5 (3)
C31—Fe3—C25—C24	−163.4 (3)	C15—Fe2—C21—C17	−163.7 (3)
C23—Fe3—C25—C24	38.6 (2)	C20—Fe2—C21—C17	118.8 (5)
C30—Fe3—C25—C24	−122.7 (3)	C12—Fe2—C21—C17	−81.1 (4)
C29—Fe3—C25—C24	−80.6 (3)	C14—Fe2—C21—C17	166.9 (5)
C28—Fe3—C25—C24	−48.2 (5)	C13—Fe2—C21—C17	−52.9 (8)
C32—Fe3—C25—C24	167.4 (5)	C19—Fe2—C21—C17	81.3 (4)
C26—Fe3—C25—C24	120.4 (4)	C18—Fe2—C21—C17	37.3 (3)
C27—Fe3—C25—C24	82.9 (3)	C16—Fe2—C21—C20	118.7 (4)
C24—C25—C26—C27	1.1 (5)	C15—Fe2—C21—C20	77.5 (4)
Fe3—C25—C26—C27	59.2 (3)	C17—Fe2—C21—C20	−118.8 (5)
C24—C25—C26—Fe3	−58.1 (3)	C12—Fe2—C21—C20	160.1 (3)
C24—Fe3—C26—C25	37.3 (2)	C14—Fe2—C21—C20	48.1 (8)
C31—Fe3—C26—C25	−123.8 (3)	C13—Fe2—C21—C20	−171.7 (6)
C23—Fe3—C26—C25	81.8 (3)	C19—Fe2—C21—C20	−37.5 (4)
C30—Fe3—C26—C25	−80.7 (3)	C18—Fe2—C21—C20	−81.5 (4)
C29—Fe3—C26—C25	−46.1 (5)	Mn2^ii—O4—C22—O3	−72.9 (6)
C28—Fe3—C26—C25	162.0 (6)	Mn2^ii—O4—C22—C12	107.9 (5)
C32—Fe3—C26—C25	−164.6 (3)	Mn2—O3—C22—O4	−15.9 (5)
C27—Fe3—C26—C25	119.7 (4)	Mn2—O3—C22—C12	163.3 (3)
C24—Fe3—C26—C27	−82.5 (3)	C13—C12—C22—O4	7.1 (6)
C31—Fe3—C26—C27	116.5 (3)	C16—C12—C22—O4	−175.6 (4)
C23—Fe3—C26—C27	−37.9 (2)	Fe2—C12—C22—O4	96.0 (4)
C30—Fe3—C26—C27	159.6 (3)	C13—C12—C22—O3	−172.1 (4)
C29—Fe3—C26—C27	−165.8 (4)	C16—C12—C22—O3	5.2 (7)
C28—Fe3—C26—C27	42.3 (8)	Fe2—C12—C22—O3	−83.2 (4)
C32—Fe3—C26—C27	75.7 (3)	O6—Mn1—N1—C38	−130.6 (3)
C25—Fe3—C26—C27	−119.7 (4)	O6^i—Mn1—N1—C38	49.4 (3)
C25—C26—C27—C23	−0.7 (4)	O1W—Mn1—N1—C38	133.3 (4)
Fe3—C26—C27—C23	58.5 (3)	O1W^i—Mn1—N1—C38	−46.7 (4)
C25—C26—C27—Fe3	−59.1 (3)	N1^i—Mn1—N1—C38	137 (100)
C24—C23—C27—C26	0.0 (4)	O6—Mn1—N1—C34	33.2 (4)
C33—C23—C27—C26	−177.5 (3)	O6^i—Mn1—N1—C34	−146.8 (4)
Fe3—C23—C27—C26	−59.0 (3)	O1W—Mn1—N1—C34	−62.9 (4)
C24—C23—C27—Fe3	59.0 (3)	O1W^i—Mn1—N1—C34	117.1 (4)
C33—C23—C27—Fe3	−118.5 (4)	N1^i—Mn1—N1—C34	−60 (100)
C24—Fe3—C27—C26	81.2 (3)	C38—N1—C34—C35	1.1 (7)
C31—Fe3—C27—C26	−82.6 (3)	Mn1—N1—C34—C35	−163.0 (4)
C23—Fe3—C27—C26	119.5 (3)	N1—C34—C35—C36	0.0 (8)
C30—Fe3—C27—C26	−46.2 (5)	C34—C35—C36—C37	−0.7 (7)
C29—Fe3—C27—C26	158.5 (6)	C34—C35—C36—C36^iii	177.2 (5)
C28—Fe3—C27—C26	−166.6 (3)	C35—C36—C37—C38	0.2 (7)
C32—Fe3—C27—C26	−125.0 (3)	C36^iii—C36—C37—C38	−177.7 (5)
C25—Fe3—C27—C26	37.2 (2)	C34—N1—C38—C37	−1.6 (7)
C24—Fe3—C27—C23	−38.3 (2)	Mn1—N1—C38—C37	163.5 (4)
C31—Fe3—C27—C23	158.0 (2)	C36—C37—C38—N1	1.0 (8)
C30—Fe3—C27—C23	−165.7 (4)	O4^ii—Mn2—O1—C11	−107.5 (2)
C29—Fe3—C27—C23	39.0 (7)	O5—Mn2—O1—C11	163.0 (2)
C28—Fe3—C27—C23	73.9 (3)	O3—Mn2—O1—C11	50.4 (3)
C32—Fe3—C27—C23	115.5 (2)	O2—Mn2—O1—C11	−0.2 (2)
C25—Fe3—C27—C23	−82.3 (2)	O4^ii—Mn2—O2—C11	91.0 (3)
C26—Fe3—C27—C23	−119.5 (3)	O5—Mn2—O2—C11	−40.1 (4)
C24—Fe3—C28—C29	−80.1 (3)	O3—Mn2—O2—C11	−149.3 (3)
C31—Fe3—C28—C29	81.6 (3)	O1—Mn2—O2—C11	0.2 (2)
C23—Fe3—C28—C29	−123.7 (3)	C6—Fe1—C1—C2	117.7 (3)
C30—Fe3—C28—C29	37.6 (3)	C7—Fe1—C1—C2	76.9 (4)
C32—Fe3—C28—C29	118.9 (4)	C8—Fe1—C1—C2	51.6 (8)
C25—Fe3—C28—C29	−46.0 (5)	C10—Fe1—C1—C2	158.8 (3)
C26—Fe3—C28—C29	161.7 (6)	C3—Fe1—C1—C2	−37.7 (3)
C27—Fe3—C28—C29	−165.2 (3)	C4—Fe1—C1—C2	−81.0 (3)
C24—Fe3—C28—C32	161.0 (3)	C5—Fe1—C1—C2	−118.0 (4)
C31—Fe3—C28—C32	−37.3 (3)	C9—Fe1—C1—C2	−171.8 (5)
C23—Fe3—C28—C32	117.4 (3)	C6—Fe1—C1—C5	−124.3 (3)
C30—Fe3—C28—C32	−81.3 (3)	C7—Fe1—C1—C5	−165.1 (3)
C29—Fe3—C28—C32	−118.9 (4)	C8—Fe1—C1—C5	169.6 (7)
C25—Fe3—C28—C32	−164.9 (4)	C2—Fe1—C1—C5	118.0 (4)
C26—Fe3—C28—C32	42.8 (8)	C10—Fe1—C1—C5	−83.2 (3)
C27—Fe3—C28—C32	75.9 (3)	C3—Fe1—C1—C5	80.3 (3)
C32—C28—C29—C30	0.5 (5)	C4—Fe1—C1—C5	37.0 (3)
Fe3—C28—C29—C30	−59.4 (3)	C9—Fe1—C1—C5	−53.8 (6)
C32—C28—C29—Fe3	59.9 (3)	C6—Fe1—C1—C11	−3.4 (4)
C24—Fe3—C29—C28	116.9 (3)	C7—Fe1—C1—C11	−44.2 (4)
C31—Fe3—C29—C28	−81.1 (3)	C8—Fe1—C1—C11	−69.6 (8)
C23—Fe3—C29—C28	75.4 (3)	C2—Fe1—C1—C11	−121.1 (4)
C30—Fe3—C29—C28	−119.4 (4)	C10—Fe1—C1—C11	37.7 (4)
C32—Fe3—C29—C28	−37.7 (3)	C3—Fe1—C1—C11	−158.8 (4)
C25—Fe3—C29—C28	159.1 (3)	C4—Fe1—C1—C11	157.9 (4)
C26—Fe3—C29—C28	−168.4 (4)	C5—Fe1—C1—C11	120.9 (4)
C27—Fe3—C29—C28	45.0 (7)	C9—Fe1—C1—C11	67.1 (6)
C24—Fe3—C29—C30	−123.8 (3)	C5—C1—C2—C3	−0.8 (5)
C31—Fe3—C29—C30	38.3 (3)	C11—C1—C2—C3	172.9 (4)
C23—Fe3—C29—C30	−165.2 (3)	Fe1—C1—C2—C3	59.7 (4)
C28—Fe3—C29—C30	119.4 (4)	C5—C1—C2—Fe1	−60.5 (3)
C32—Fe3—C29—C30	81.6 (3)	C11—C1—C2—Fe1	113.2 (4)
C25—Fe3—C29—C30	−81.5 (3)	C6—Fe1—C2—C3	161.2 (4)
C26—Fe3—C29—C30	−49.1 (6)	C7—Fe1—C2—C3	118.4 (4)
C27—Fe3—C29—C30	164.4 (5)	C1—Fe1—C2—C3	−118.8 (4)
C28—C29—C30—C31	−0.4 (5)	C8—Fe1—C2—C3	77.6 (4)
Fe3—C29—C30—C31	−59.8 (3)	C10—Fe1—C2—C3	−166.7 (5)
C28—C29—C30—Fe3	59.5 (3)	C4—Fe1—C2—C3	−37.0 (3)
C24—Fe3—C30—C29	74.3 (3)	C5—Fe1—C2—C3	−80.4 (3)
C31—Fe3—C30—C29	−118.2 (4)	C9—Fe1—C2—C3	47.8 (9)
C23—Fe3—C30—C29	42.2 (7)	C6—Fe1—C2—C1	−80.0 (3)
C28—Fe3—C30—C29	−37.5 (3)	C7—Fe1—C2—C1	−122.8 (4)
C32—Fe3—C30—C29	−81.1 (3)	C8—Fe1—C2—C1	−163.6 (3)
C25—Fe3—C30—C29	116.0 (3)	C10—Fe1—C2—C1	−47.9 (6)
C26—Fe3—C30—C29	157.8 (3)	C3—Fe1—C2—C1	118.8 (4)
C27—Fe3—C30—C29	−169.3 (4)	C4—Fe1—C2—C1	81.9 (3)
C24—Fe3—C30—C31	−167.4 (3)	C5—Fe1—C2—C1	38.5 (3)
C23—Fe3—C30—C31	160.4 (5)	C9—Fe1—C2—C1	166.6 (8)
C29—Fe3—C30—C31	118.2 (4)	C1—C2—C3—C4	0.1 (6)
C28—Fe3—C30—C31	80.8 (3)	Fe1—C2—C3—C4	59.3 (4)
C32—Fe3—C30—C31	37.1 (3)	C1—C2—C3—Fe1	−59.2 (3)
C25—Fe3—C30—C31	−125.8 (3)	C6—Fe1—C3—C4	−163.6 (5)
C26—Fe3—C30—C31	−84.0 (3)	C7—Fe1—C3—C4	159.7 (4)
C27—Fe3—C30—C31	−51.1 (5)	C1—Fe1—C3—C4	−81.8 (3)
C29—C30—C31—C32	0.1 (5)	C8—Fe1—C3—C4	116.0 (4)
Fe3—C30—C31—C32	−59.9 (3)	C2—Fe1—C3—C4	−120.0 (5)
C29—C30—C31—Fe3	60.0 (3)	C10—Fe1—C3—C4	40.5 (9)
C24—Fe3—C31—C32	155.3 (6)	C5—Fe1—C3—C4	−37.5 (3)
C23—Fe3—C31—C32	−45.8 (6)	C9—Fe1—C3—C4	74.7 (4)
C30—Fe3—C31—C32	119.5 (4)	C6—Fe1—C3—C2	−43.6 (7)
C29—Fe3—C31—C32	81.3 (3)	C7—Fe1—C3—C2	−80.3 (4)
C28—Fe3—C31—C32	37.6 (3)	C1—Fe1—C3—C2	38.2 (3)
C25—Fe3—C31—C32	−167.3 (3)	C8—Fe1—C3—C2	−123.9 (4)
C26—Fe3—C31—C32	−125.8 (3)	C10—Fe1—C3—C2	160.5 (7)
C27—Fe3—C31—C32	−82.8 (3)	C4—Fe1—C3—C2	120.0 (5)
C24—Fe3—C31—C30	35.9 (8)	C5—Fe1—C3—C2	82.6 (3)
C23—Fe3—C31—C30	−165.2 (4)	C9—Fe1—C3—C2	−165.3 (3)
C29—Fe3—C31—C30	−38.1 (3)	C2—C3—C4—C5	0.6 (6)
C28—Fe3—C31—C30	−81.9 (3)	Fe1—C3—C4—C5	59.6 (4)
C32—Fe3—C31—C30	−119.5 (4)	C2—C3—C4—Fe1	−59.0 (4)
C25—Fe3—C31—C30	73.2 (4)	C6—Fe1—C4—C3	158.8 (6)
C26—Fe3—C31—C30	114.7 (3)	C7—Fe1—C4—C3	−47.6 (8)
C27—Fe3—C31—C30	157.7 (3)	C1—Fe1—C4—C3	81.6 (3)
C30—C31—C32—C28	0.3 (5)	C8—Fe1—C4—C3	−83.9 (4)
Fe3—C31—C32—C28	−59.3 (3)	C2—Fe1—C4—C3	37.3 (3)
C30—C31—C32—Fe3	59.5 (3)	C10—Fe1—C4—C3	−166.4 (3)
C29—C28—C32—C31	−0.5 (5)	C5—Fe1—C4—C3	119.3 (5)
Fe3—C28—C32—C31	59.2 (3)	C9—Fe1—C4—C3	−126.1 (4)
C29—C28—C32—Fe3	−59.7 (3)	C6—Fe1—C4—C5	39.5 (8)
C24—Fe3—C32—C31	−162.1 (4)	C7—Fe1—C4—C5	−166.9 (6)
C23—Fe3—C32—C31	160.0 (3)	C1—Fe1—C4—C5	−37.7 (3)
C30—Fe3—C32—C31	−37.7 (3)	C8—Fe1—C4—C5	156.7 (4)
C29—Fe3—C32—C31	−81.6 (3)	C2—Fe1—C4—C5	−82.1 (3)
C28—Fe3—C32—C31	−119.3 (4)	C10—Fe1—C4—C5	74.2 (4)
C25—Fe3—C32—C31	37.9 (7)	C3—Fe1—C4—C5	−119.3 (5)
C26—Fe3—C32—C31	74.2 (3)	C9—Fe1—C4—C5	114.6 (4)
C27—Fe3—C32—C31	116.1 (3)	C3—C4—C5—C1	−1.1 (6)
C24—Fe3—C32—C28	−42.7 (5)	Fe1—C4—C5—C1	58.4 (3)
C31—Fe3—C32—C28	119.3 (4)	C3—C4—C5—Fe1	−59.5 (4)
C23—Fe3—C32—C28	−80.7 (3)	C2—C1—C5—C4	1.2 (5)
C30—Fe3—C32—C28	81.6 (3)	C11—C1—C5—C4	−172.6 (4)
C29—Fe3—C32—C28	37.8 (3)	Fe1—C1—C5—C4	−59.0 (4)
C25—Fe3—C32—C28	157.2 (5)	C2—C1—C5—Fe1	60.1 (3)
C26—Fe3—C32—C28	−166.5 (3)	C11—C1—C5—Fe1	−113.6 (4)
C27—Fe3—C32—C28	−124.6 (3)	C6—Fe1—C5—C4	−165.9 (3)
Mn1—O6—C33—O5	−9.3 (6)	C7—Fe1—C5—C4	163.0 (7)
Mn1—O6—C33—C23	169.7 (2)	C1—Fe1—C5—C4	119.8 (4)
Mn2—O5—C33—O6	−136.9 (4)	C8—Fe1—C5—C4	−53.1 (7)
Mn2—O5—C33—C23	44.1 (7)	C2—Fe1—C5—C4	81.2 (3)
C24—C23—C33—O6	11.1 (6)	C10—Fe1—C5—C4	−125.1 (4)
C27—C23—C33—O6	−171.8 (3)	C3—Fe1—C5—C4	37.4 (3)
Fe3—C23—C33—O6	99.2 (4)	C9—Fe1—C5—C4	−84.5 (4)
C24—C23—C33—O5	−169.8 (3)	C6—Fe1—C5—C1	74.3 (3)
C27—C23—C33—O5	7.3 (6)	C7—Fe1—C5—C1	43.2 (8)
Fe3—C23—C33—O5	−81.8 (4)	C8—Fe1—C5—C1	−172.9 (5)
O4^ii—Mn2—O3—C22	57.6 (3)	C2—Fe1—C5—C1	−38.6 (3)
O5—Mn2—O3—C22	148.0 (3)	C10—Fe1—C5—C1	115.1 (3)
O1—Mn2—O3—C22	−98.1 (3)	C3—Fe1—C5—C1	−82.4 (3)
O2—Mn2—O3—C22	−56.8 (3)	C4—Fe1—C5—C1	−119.8 (4)
C11—Mn2—O3—C22	−73.1 (3)	C9—Fe1—C5—C1	155.7 (3)
C16—Fe2—C12—C13	−118.3 (4)	C7—Fe1—C6—C10	−118.2 (5)
C15—Fe2—C12—C13	−80.0 (3)	C1—Fe1—C6—C10	117.0 (4)
C17—Fe2—C12—C13	123.1 (3)	C8—Fe1—C6—C10	−79.5 (4)
C20—Fe2—C12—C13	−161.0 (6)	C2—Fe1—C6—C10	159.5 (3)
C21—Fe2—C12—C13	165.2 (3)	C3—Fe1—C6—C10	−169.3 (5)
C14—Fe2—C12—C13	−36.8 (3)	C4—Fe1—C6—C10	46.0 (8)
C19—Fe2—C12—C13	50.2 (8)	C5—Fe1—C6—C10	75.9 (4)
C18—Fe2—C12—C13	81.7 (4)	C9—Fe1—C6—C10	−36.2 (4)
C15—Fe2—C12—C16	38.4 (3)	C1—Fe1—C6—C7	−124.7 (4)
C17—Fe2—C12—C16	−118.6 (3)	C8—Fe1—C6—C7	38.8 (4)
C20—Fe2—C12—C16	−42.7 (7)	C2—Fe1—C6—C7	−82.3 (4)
C21—Fe2—C12—C16	−76.5 (4)	C10—Fe1—C6—C7	118.2 (5)
C14—Fe2—C12—C16	81.5 (3)	C3—Fe1—C6—C7	−51.0 (7)
C13—Fe2—C12—C16	118.3 (4)	C4—Fe1—C6—C7	164.2 (7)
C19—Fe2—C12—C16	168.5 (7)	C5—Fe1—C6—C7	−165.9 (4)
C18—Fe2—C12—C16	−159.9 (3)	C9—Fe1—C6—C7	82.0 (4)
C16—Fe2—C12—C22	121.2 (4)	C10—C6—C7—C8	0.2 (6)
C15—Fe2—C12—C22	159.6 (4)	Fe1—C6—C7—C8	−60.9 (4)
C17—Fe2—C12—C22	2.6 (4)	C10—C6—C7—Fe1	61.1 (4)
C20—Fe2—C12—C22	78.5 (7)	C6—Fe1—C7—C8	117.1 (5)
C21—Fe2—C12—C22	44.7 (4)	C1—Fe1—C7—C8	−169.1 (4)
C14—Fe2—C12—C22	−157.3 (4)	C2—Fe1—C7—C8	−126.8 (4)
C13—Fe2—C12—C22	−120.5 (4)	C10—Fe1—C7—C8	79.4 (4)
C19—Fe2—C12—C22	−70.3 (8)	C3—Fe1—C7—C8	−84.6 (4)
C18—Fe2—C12—C22	−38.7 (4)	C4—Fe1—C7—C8	−50.5 (8)
C16—C12—C13—C14	−0.4 (6)	C5—Fe1—C7—C8	157.7 (6)
C22—C12—C13—C14	177.3 (4)	C9—Fe1—C7—C8	37.1 (4)
Fe2—C12—C13—C14	58.9 (4)	C1—Fe1—C7—C6	73.8 (4)
C16—C12—C13—Fe2	−59.3 (3)	C8—Fe1—C7—C6	−117.1 (5)
C22—C12—C13—Fe2	118.4 (4)	C2—Fe1—C7—C6	116.1 (3)
C16—Fe2—C13—C14	−81.7 (3)	C10—Fe1—C7—C6	−37.7 (3)
C15—Fe2—C13—C14	−37.5 (3)	C3—Fe1—C7—C6	158.3 (3)
C17—Fe2—C13—C14	162.9 (3)	C4—Fe1—C7—C6	−167.6 (5)
C20—Fe2—C13—C14	37.8 (8)	C5—Fe1—C7—C6	40.7 (9)
C21—Fe2—C13—C14	−158.0 (6)	C9—Fe1—C7—C6	−80.0 (4)
C12—Fe2—C13—C14	−120.1 (4)	C6—C7—C8—C9	0.0 (7)
C19—Fe2—C13—C14	76.9 (4)	Fe1—C7—C8—C9	−60.4 (4)
C18—Fe2—C13—C14	120.0 (4)	C6—C7—C8—Fe1	60.4 (4)
C16—Fe2—C13—C12	38.4 (2)	C6—Fe1—C8—C9	80.2 (4)
C15—Fe2—C13—C12	82.6 (3)	C7—Fe1—C8—C9	119.2 (6)
C17—Fe2—C13—C12	−76.9 (3)	C1—Fe1—C8—C9	151.9 (7)
C20—Fe2—C13—C12	157.9 (6)	C2—Fe1—C8—C9	−167.9 (3)
C21—Fe2—C13—C12	−37.9 (8)	C10—Fe1—C8—C9	36.7 (4)
C14—Fe2—C13—C12	120.1 (4)	C3—Fe1—C8—C9	−125.3 (4)
C19—Fe2—C13—C12	−163.0 (3)	C4—Fe1—C8—C9	−82.1 (4)
C18—Fe2—C13—C12	−119.8 (3)	C5—Fe1—C8—C9	−44.6 (7)
C12—C13—C14—C15	0.8 (6)	C6—Fe1—C8—C7	−39.0 (4)
Fe2—C13—C14—C15	59.5 (4)	C1—Fe1—C8—C7	32.7 (10)
C12—C13—C14—Fe2	−58.7 (3)	C2—Fe1—C8—C7	73.0 (4)
C16—Fe2—C14—C15	−37.3 (3)	C10—Fe1—C8—C7	−82.4 (4)
C17—Fe2—C14—C15	−166.0 (6)	C3—Fe1—C8—C7	115.5 (4)
C20—Fe2—C14—C15	75.5 (4)	C4—Fe1—C8—C7	158.7 (4)
C21—Fe2—C14—C15	40.5 (7)	C5—Fe1—C8—C7	−163.8 (5)
C12—Fe2—C14—C15	−81.5 (3)	C9—Fe1—C8—C7	−119.2 (6)
C13—Fe2—C14—C15	−119.0 (4)	C7—C8—C9—C10	−0.2 (7)
C19—Fe2—C14—C15	117.5 (4)	Fe1—C8—C9—C10	−59.5 (4)
C18—Fe2—C14—C15	159.9 (3)	C7—C8—C9—Fe1	59.3 (4)
C16—Fe2—C14—C13	81.7 (3)	C6—Fe1—C9—C10	37.1 (4)
C15—Fe2—C14—C13	119.0 (4)	C7—Fe1—C9—C10	81.5 (4)
C17—Fe2—C14—C13	−47.0 (8)	C1—Fe1—C9—C10	−42.7 (7)
C20—Fe2—C14—C13	−165.5 (3)	C8—Fe1—C9—C10	119.4 (6)
C21—Fe2—C14—C13	159.5 (5)	C2—Fe1—C9—C10	157.6 (7)
C12—Fe2—C14—C13	37.4 (3)	C3—Fe1—C9—C10	−164.9 (4)
C19—Fe2—C14—C13	−123.6 (3)	C4—Fe1—C9—C10	−123.6 (4)
C18—Fe2—C14—C13	−81.1 (4)	C5—Fe1—C9—C10	−80.6 (4)
C13—C14—C15—C16	−1.0 (7)	C6—Fe1—C9—C8	−82.3 (4)
Fe2—C14—C15—C16	58.9 (4)	C7—Fe1—C9—C8	−37.9 (4)
C13—C14—C15—Fe2	−59.8 (4)	C1—Fe1—C9—C8	−162.0 (4)
C16—Fe2—C15—C14	120.5 (5)	C2—Fe1—C9—C8	38.2 (10)
C17—Fe2—C15—C14	167.7 (5)	C10—Fe1—C9—C8	−119.4 (6)
C20—Fe2—C15—C14	−122.1 (3)	C3—Fe1—C9—C8	75.8 (5)
C21—Fe2—C15—C14	−163.3 (3)	C4—Fe1—C9—C8	117.1 (4)
C12—Fe2—C15—C14	81.9 (3)	C5—Fe1—C9—C8	160.1 (4)
C13—Fe2—C15—C14	37.7 (3)	C8—C9—C10—C6	0.3 (7)
C19—Fe2—C15—C14	−81.9 (4)	Fe1—C9—C10—C6	−58.8 (4)
C18—Fe2—C15—C14	−52.0 (8)	C8—C9—C10—Fe1	59.1 (4)
C17—Fe2—C15—C16	47.2 (7)	C7—C6—C10—C9	−0.3 (7)
C20—Fe2—C15—C16	117.4 (3)	Fe1—C6—C10—C9	60.0 (4)
C21—Fe2—C15—C16	76.2 (4)	C7—C6—C10—Fe1	−60.3 (4)
C12—Fe2—C15—C16	−38.6 (3)	C6—Fe1—C10—C9	−120.2 (6)
C14—Fe2—C15—C16	−120.5 (5)	C7—Fe1—C10—C9	−81.7 (4)
C13—Fe2—C15—C16	−82.8 (3)	C1—Fe1—C10—C9	160.0 (4)
C19—Fe2—C15—C16	157.6 (3)	C8—Fe1—C10—C9	−37.4 (4)
C18—Fe2—C15—C16	−172.4 (6)	C2—Fe1—C10—C9	−165.9 (5)
C14—C15—C16—C12	0.7 (7)	C3—Fe1—C10—C9	44.9 (10)
Fe2—C15—C16—C12	60.1 (3)	C4—Fe1—C10—C9	76.1 (5)
C14—C15—C16—Fe2	−59.4 (4)	C5—Fe1—C10—C9	116.8 (4)
C13—C12—C16—C15	−0.2 (6)	C7—Fe1—C10—C6	38.5 (4)
C22—C12—C16—C15	−177.9 (4)	C1—Fe1—C10—C6	−79.8 (4)
Fe2—C12—C16—C15	−59.9 (4)	C8—Fe1—C10—C6	82.8 (4)
C13—C12—C16—Fe2	59.7 (3)	C2—Fe1—C10—C6	−45.7 (7)
C22—C12—C16—Fe2	−117.9 (4)	C3—Fe1—C10—C6	165.1 (7)
C17—Fe2—C16—C15	−161.1 (4)	C4—Fe1—C10—C6	−163.7 (4)
C20—Fe2—C16—C15	−80.0 (4)	C5—Fe1—C10—C6	−123.0 (4)
C21—Fe2—C16—C15	−121.0 (4)	C9—Fe1—C10—C6	120.2 (6)
C12—Fe2—C16—C15	118.0 (4)	Mn2—O1—C11—O2	0.3 (4)
C14—Fe2—C16—C15	36.5 (3)	Mn2—O1—C11—C1	−178.7 (3)
C13—Fe2—C16—C15	79.8 (3)	Mn2—O2—C11—O1	−0.3 (4)
C19—Fe2—C16—C15	−53.2 (7)	Mn2—O2—C11—C1	178.7 (4)
C18—Fe2—C16—C15	172.2 (6)	C2—C1—C11—O1	−1.9 (7)
C15—Fe2—C16—C12	−118.0 (4)	C5—C1—C11—O1	170.7 (4)
C17—Fe2—C16—C12	80.9 (3)	Fe1—C1—C11—O1	84.2 (4)
C20—Fe2—C16—C12	161.9 (3)	C2—C1—C11—O2	179.1 (4)
C21—Fe2—C16—C12	120.9 (3)	C5—C1—C11—O2	−8.3 (7)
C14—Fe2—C16—C12	−81.5 (3)	Fe1—C1—C11—O2	−94.8 (4)
C13—Fe2—C16—C12	−38.2 (3)	C2—C1—C11—Mn2	−27 (7)
C19—Fe2—C16—C12	−171.2 (5)	C5—C1—C11—Mn2	145 (7)
C18—Fe2—C16—C12	54.2 (7)	Fe1—C1—C11—Mn2	59 (7)
C16—Fe2—C17—C21	74.5 (4)	O4^ii—Mn2—C11—O1	80.1 (3)
C15—Fe2—C17—C21	39.8 (7)	O5—Mn2—C11—O1	−21.5 (3)
C20—Fe2—C17—C21	−37.8 (3)	O3—Mn2—C11—O1	−145.4 (2)
C12—Fe2—C17—C21	117.6 (3)	O2—Mn2—C11—O1	179.7 (4)
C14—Fe2—C17—C21	−164.9 (6)	O4^ii—Mn2—C11—O2	−99.5 (3)
C13—Fe2—C17—C21	159.8 (3)	O5—Mn2—C11—O2	158.8 (2)
C19—Fe2—C17—C21	−81.0 (3)	O3—Mn2—C11—O2	34.9 (3)
C18—Fe2—C17—C21	−119.5 (5)	O1—Mn2—C11—O2	−179.7 (4)
C16—Fe2—C17—C18	−166.0 (3)	O4^ii—Mn2—C11—C1	106 (7)
C15—Fe2—C17—C18	159.3 (5)	O5—Mn2—C11—C1	5 (7)
C20—Fe2—C17—C18	81.7 (4)	O3—Mn2—C11—C1	−119 (7)
C21—Fe2—C17—C18	119.5 (5)	O1—Mn2—C11—C1	26 (7)
C12—Fe2—C17—C18	−122.9 (3)	O2—Mn2—C11—C1	−154 (7)

Symmetry codes: (i) −x+2, −y+1, −z+2; (ii) −x+1, −y+1, −z+2; (iii) −x+2, −y+2, −z+2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1WA···O2^ii	0.76 (3)	2.14 (3)	2.884 (5)	164 (6)
O1W—H1WB···O4^ii	0.76 (3)	2.26 (4)	2.878 (4)	139 (6)

Symmetry code: (ii) −x+1, −y+1, −z+2.