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Y
3Au
4 (triyttrium tetragold) and Y
14Au
51 (tetradecayttrium henpentacontagold), two binary representatives of Au-rich rare earth (
R) systems crystallize with the space groups
R and
P6/
m, adopting the Pu
3Pd
4 and Gd
14Ag
51 structure types, respectively (Pearson symbols
hR42 and
hP65). A variety of binary
R–Au compounds have been reported, although only a few have been investigated thoroughly. Many reports lack information or misinterpret known compounds reported elsewhere. The Pu
3Pd
4 type is fairly common for group 10 elements Ni, Pd, and Pt, while Au representatives are restricted to just five examples,
i.e. Ca
3Au
4, Pr
3Au
4, Nd
3Au
4, Gd
3Au
4, and Th
3Au
4. Sm
6Au
7 is suspected to be Sm
3Au
4 due to identical symmetry and close unit-cell parameters. The Pu
3Pd
4 structure type allows for full substitution of the position of the rare earth atom by more electronegative and smaller elements,
i.e. Ti and Zr. The Gd
14Ag
51 type instead is more common for the group 11 metals, while rare representatives of group 12 are known. Y
3Au
4 can be represented as a tunnel structure with encapsulated cations and anionic chains. Though tunnels are present in Y
14Au
51, this structure is more complex and is best described in terms of polyhedral `pinwheels' around the tunnel forming polyhedra along the
c axis.
Supporting information
CCDC references: 1565065; 1565064
For both structures, data collection: APEX3 (Bruker, 2015); cell refinement: SAINT (Bruker, 2015); data reduction: SAINT (Bruker, 2015); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015b); molecular graphics: 'DIAMOND (Brandenburg, 2006); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2015b).
Triyttrium tetragold (vsY3_0m)
top
Crystal data top
Y3Au4 | Dx = 11.386 Mg m−3 |
Mr = 1054.60 | Mo Kα radiation, λ = 0.71073 Å |
Trigonal, R3:H | Cell parameters from 3552 reflections |
a = 13.3664 (15) Å | θ = 4.9–32.9° |
c = 5.9640 (9) Å | µ = 122.83 mm−1 |
V = 922.8 (2) Å3 | T = 296 K |
Z = 6 | Irregular fragment, grey |
F(000) = 2598 | 0.09 × 0.07 × 0.07 mm |
Data collection top
Bruker Venture diffractometer | 567 reflections with I > 2σ(I) |
w scan | Rint = 0.102 |
Absorption correction: empirical (using intensity measurements) [Blessing (1995) OR SADABS (Krause et al., 2015)] | θmax = 32.9°, θmin = 4.9° |
Tmin = 0.02, Tmax = 0.06 | h = −20→18 |
3552 measured reflections | k = −16→20 |
722 independent reflections | l = −8→8 |
Refinement top
Refinement on F2 | 0 restraints |
Least-squares matrix: full | w = 1/[σ2(Fo2) + (0.0185P)2] where P = (Fo2 + 2Fc2)/3 |
R[F2 > 2σ(F2)] = 0.047 | (Δ/σ)max < 0.001 |
wR(F2) = 0.094 | Δρmax = 4.07 e Å−3 |
S = 1.04 | Δρmin = −3.91 e Å−3 |
722 reflections | Extinction correction: SHELXL2014 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
25 parameters | Extinction coefficient: 0.00007 (2) |
Special details top
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Au1 | 0.39424 (5) | 0.11583 (5) | 0.04425 (10) | 0.00796 (19) | |
Au2 | 0.0000 | 0.0000 | 0.0000 | 0.0248 (5) | |
Au3 | 0.0000 | 0.0000 | 0.5000 | 0.0246 (4) | |
Y4 | 0.04328 (13) | 0.21357 (14) | 0.2266 (3) | 0.0089 (3) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Au1 | 0.0086 (3) | 0.0077 (3) | 0.0082 (3) | 0.0046 (3) | 0.0007 (2) | 0.0002 (2) |
Au2 | 0.0096 (5) | 0.0096 (5) | 0.0554 (13) | 0.0048 (3) | 0.000 | 0.000 |
Au3 | 0.0230 (6) | 0.0230 (6) | 0.0278 (10) | 0.0115 (3) | 0.000 | 0.000 |
Y4 | 0.0069 (7) | 0.0120 (8) | 0.0079 (7) | 0.0047 (6) | −0.0012 (5) | −0.0021 (6) |
Geometric parameters (Å, º) top
Au1—Y4i | 2.8810 (17) | Au3—Au2xiv | 2.9820 (4) |
Au1—Au1ii | 2.9738 (12) | Au3—Y4 | 3.0808 (17) |
Au1—Y4iii | 2.9773 (17) | Au3—Y4xv | 3.0808 (17) |
Au1—Au1iv | 3.0577 (9) | Au3—Y4xii | 3.0808 (17) |
Au1—Au1v | 3.0578 (9) | Au3—Y4xvi | 3.0808 (17) |
Au1—Y4ii | 3.0596 (17) | Au3—Y4i | 3.0808 (17) |
Au1—Y4vi | 3.0651 (17) | Au3—Y4xvii | 3.0808 (17) |
Au1—Y4vii | 3.1590 (17) | Y4—Au1xii | 2.8810 (17) |
Au1—Y4viii | 3.1688 (18) | Y4—Au1xviii | 2.9773 (17) |
Au1—Y4ix | 3.2754 (17) | Y4—Au1ii | 3.0596 (17) |
Au2—Y4x | 2.9425 (16) | Y4—Au1xix | 3.0651 (17) |
Au2—Y4xi | 2.9425 (16) | Y4—Au1xx | 3.1590 (17) |
Au2—Y4i | 2.9425 (16) | Y4—Au1xxi | 3.1688 (18) |
Au2—Y4ix | 2.9425 (16) | Y4—Au1xi | 3.2755 (17) |
Au2—Y4xii | 2.9425 (16) | Y4—Y4xxii | 3.492 (3) |
Au2—Y4 | 2.9425 (16) | Y4—Y4xi | 3.760 (3) |
Au2—Au3 | 2.9820 (4) | Y4—Y4ix | 3.760 (3) |
Au2—Au3xiii | 2.9820 (4) | | |
| | | |
Y4i—Au1—Au1ii | 63.11 (4) | Au2—Au3—Y4xvi | 121.96 (3) |
Y4i—Au1—Y4iii | 126.13 (5) | Y4—Au3—Y4xvi | 85.43 (4) |
Au1ii—Au1—Y4iii | 121.77 (4) | Y4xv—Au3—Y4xvi | 94.57 (4) |
Y4i—Au1—Au1iv | 64.41 (3) | Y4xii—Au3—Y4xvi | 85.43 (4) |
Au1ii—Au1—Au1iv | 103.00 (2) | Au2xiv—Au3—Y4i | 121.96 (3) |
Y4iii—Au1—Au1iv | 134.16 (4) | Au2—Au3—Y4i | 58.04 (3) |
Y4i—Au1—Au1v | 64.19 (4) | Y4—Au3—Y4i | 94.57 (4) |
Au1ii—Au1—Au1v | 105.38 (4) | Y4xv—Au3—Y4i | 85.43 (4) |
Y4iii—Au1—Au1v | 63.33 (3) | Y4xii—Au3—Y4i | 94.57 (4) |
Au1iv—Au1—Au1v | 97.70 (2) | Y4xvi—Au3—Y4i | 180.0 |
Y4i—Au1—Y4ii | 128.93 (6) | Au2xiv—Au3—Y4xvii | 58.04 (3) |
Au1ii—Au1—Y4ii | 134.78 (4) | Au2—Au3—Y4xvii | 121.96 (3) |
Y4iii—Au1—Y4ii | 87.62 (5) | Y4—Au3—Y4xvii | 180.0 |
Au1iv—Au1—Y4ii | 64.75 (4) | Y4xv—Au3—Y4xvii | 94.57 (4) |
Au1v—Au1—Y4ii | 119.02 (4) | Y4xii—Au3—Y4xvii | 85.43 (4) |
Y4i—Au1—Y4vi | 120.08 (4) | Y4xvi—Au3—Y4xvii | 94.57 (4) |
Au1ii—Au1—Y4vi | 56.96 (4) | Y4i—Au3—Y4xvii | 85.43 (4) |
Y4iii—Au1—Y4vi | 87.52 (5) | Au1xii—Y4—Au2 | 107.57 (5) |
Au1iv—Au1—Y4vi | 128.63 (4) | Au1xii—Y4—Au1xviii | 103.63 (5) |
Au1v—Au1—Y4vi | 131.80 (4) | Au2—Y4—Au1xviii | 131.36 (6) |
Y4ii—Au1—Y4vi | 95.32 (6) | Au1xii—Y4—Au1ii | 157.52 (6) |
Y4i—Au1—Y4vii | 80.97 (5) | Au2—Y4—Au1ii | 77.42 (4) |
Au1ii—Au1—Y4vii | 64.48 (4) | Au1xviii—Y4—Au1ii | 87.57 (4) |
Y4iii—Au1—Y4vii | 152.77 (7) | Au1xii—Y4—Au1xix | 59.92 (4) |
Au1iv—Au1—Y4vii | 55.19 (3) | Au2—Y4—Au1xix | 77.34 (4) |
Au1v—Au1—Y4vii | 143.55 (4) | Au1xviii—Y4—Au1xix | 87.47 (4) |
Y4ii—Au1—Y4vii | 74.38 (5) | Au1ii—Y4—Au1xix | 141.21 (6) |
Y4vi—Au1—Y4vii | 74.31 (5) | Au1xii—Y4—Au3 | 130.82 (6) |
Y4i—Au1—Y4viii | 80.80 (2) | Au2—Y4—Au3 | 59.30 (3) |
Au1ii—Au1—Y4viii | 143.91 (4) | Au1xviii—Y4—Au3 | 72.07 (4) |
Y4iii—Au1—Y4viii | 79.36 (5) | Au1ii—Y4—Au3 | 70.98 (4) |
Au1iv—Au1—Y4viii | 57.10 (3) | Au1xix—Y4—Au3 | 70.91 (4) |
Au1v—Au1—Y4viii | 55.09 (3) | Au1xii—Y4—Au1xx | 60.62 (4) |
Y4ii—Au1—Y4viii | 68.17 (5) | Au2—Y4—Au1xx | 75.87 (4) |
Y4vi—Au1—Y4viii | 159.11 (5) | Au1xviii—Y4—Au1xx | 152.77 (7) |
Y4vii—Au1—Y4viii | 111.26 (4) | Au1ii—Y4—Au1xx | 100.96 (5) |
Y4i—Au1—Y4ix | 74.98 (6) | Au1xix—Y4—Au1xx | 100.84 (5) |
Au1ii—Au1—Y4ix | 60.50 (4) | Au3—Y4—Au1xx | 135.16 (6) |
Y4iii—Au1—Y4ix | 67.70 (5) | Au1xii—Y4—Au1xxi | 60.50 (3) |
Au1iv—Au1—Y4ix | 139.02 (4) | Au2—Y4—Au1xxi | 167.29 (6) |
Au1v—Au1—Y4ix | 57.66 (3) | Au1xviii—Y4—Au1xxi | 59.58 (3) |
Y4ii—Au1—Y4ix | 154.05 (5) | Au1ii—Y4—Au1xxi | 111.83 (5) |
Y4vi—Au1—Y4ix | 76.46 (6) | Au1xix—Y4—Au1xxi | 98.44 (5) |
Y4vii—Au1—Y4ix | 124.98 (3) | Au3—Y4—Au1xxi | 131.04 (5) |
Y4viii—Au1—Y4ix | 112.58 (2) | Au1xx—Y4—Au1xxi | 93.40 (5) |
Y4x—Au2—Y4xi | 100.58 (4) | Au1xii—Y4—Au1xi | 99.94 (5) |
Y4x—Au2—Y4i | 79.42 (4) | Au2—Y4—Au1xi | 98.02 (5) |
Y4xi—Au2—Y4i | 180.00 (7) | Au1xviii—Y4—Au1xi | 112.30 (5) |
Y4x—Au2—Y4ix | 100.58 (4) | Au1ii—Y4—Au1xi | 57.60 (3) |
Y4xi—Au2—Y4ix | 100.58 (4) | Au1xix—Y4—Au1xi | 155.52 (6) |
Y4i—Au2—Y4ix | 79.42 (4) | Au3—Y4—Au1xi | 127.63 (5) |
Y4x—Au2—Y4xii | 79.42 (4) | Au1xx—Y4—Au1xi | 55.02 (3) |
Y4xi—Au2—Y4xii | 79.42 (4) | Au1xxi—Y4—Au1xi | 80.81 (4) |
Y4i—Au2—Y4xii | 100.58 (4) | Au1xii—Y4—Y4xxii | 111.27 (7) |
Y4ix—Au2—Y4xii | 180.00 (9) | Au2—Y4—Y4xxii | 133.98 (8) |
Y4x—Au2—Y4 | 180.00 (4) | Au1xviii—Y4—Y4xxii | 60.22 (5) |
Y4xi—Au2—Y4 | 79.42 (4) | Au1ii—Y4—Y4xxii | 57.40 (4) |
Y4i—Au2—Y4 | 100.58 (4) | Au1xix—Y4—Y4xxii | 144.71 (8) |
Y4ix—Au2—Y4 | 79.42 (4) | Au3—Y4—Y4xxii | 108.07 (7) |
Y4xii—Au2—Y4 | 100.58 (4) | Au1xx—Y4—Y4xxii | 102.73 (7) |
Y4x—Au2—Au3 | 117.34 (3) | Au1xxi—Y4—Y4xxii | 54.44 (5) |
Y4xi—Au2—Au3 | 117.34 (3) | Au1xi—Y4—Y4xxii | 52.08 (4) |
Y4i—Au2—Au3 | 62.66 (3) | Au1xii—Y4—Y4xi | 57.29 (5) |
Y4ix—Au2—Au3 | 117.34 (3) | Au2—Y4—Y4xi | 50.291 (19) |
Y4xii—Au2—Au3 | 62.66 (3) | Au1xviii—Y4—Y4xi | 141.34 (6) |
Y4—Au2—Au3 | 62.66 (3) | Au1ii—Y4—Y4xi | 123.26 (4) |
Y4x—Au2—Au3xiii | 62.66 (3) | Au1xix—Y4—Y4xi | 53.99 (3) |
Y4xi—Au2—Au3xiii | 62.66 (3) | Au3—Y4—Y4xi | 94.91 (3) |
Y4i—Au2—Au3xiii | 117.34 (3) | Au1xx—Y4—Y4xi | 51.60 (5) |
Y4ix—Au2—Au3xiii | 62.66 (3) | Au1xxi—Y4—Y4xi | 117.55 (5) |
Y4xii—Au2—Au3xiii | 117.34 (3) | Au1xi—Y4—Y4xi | 104.48 (6) |
Y4—Au2—Au3xiii | 117.34 (3) | Y4xxii—Y4—Y4xi | 154.22 (9) |
Au3—Au2—Au3xiii | 180.0 | Au1xii—Y4—Y4ix | 111.70 (7) |
Au2xiv—Au3—Au2 | 180.0 | Au2—Y4—Y4ix | 50.291 (19) |
Au2xiv—Au3—Y4 | 121.96 (3) | Au1xviii—Y4—Y4ix | 141.48 (6) |
Au2—Au3—Y4 | 58.04 (3) | Au1ii—Y4—Y4ix | 54.01 (3) |
Au2xiv—Au3—Y4xv | 58.04 (3) | Au1xix—Y4—Y4ix | 123.20 (4) |
Au2—Au3—Y4xv | 121.96 (3) | Au3—Y4—Y4ix | 94.91 (3) |
Y4—Au3—Y4xv | 85.43 (4) | Au1xx—Y4—Y4ix | 51.70 (5) |
Au2xiv—Au3—Y4xii | 121.96 (3) | Au1xxi—Y4—Y4ix | 127.39 (5) |
Au2—Au3—Y4xii | 58.04 (3) | Au1xi—Y4—Y4ix | 47.74 (4) |
Y4—Au3—Y4xii | 94.57 (4) | Y4xxii—Y4—Y4ix | 92.07 (6) |
Y4xv—Au3—Y4xii | 180.0 | Y4xi—Y4—Y4ix | 74.04 (6) |
Au2xiv—Au3—Y4xvi | 58.04 (3) | | |
Symmetry codes: (i) −x+y, −x, z; (ii) −x+2/3, −y+1/3, −z+1/3; (iii) −y+2/3, x−y+1/3, z−2/3; (iv) −x+y+2/3, −x+1/3, z+1/3; (v) −y+1/3, x−y−1/3, z−1/3; (vi) x−y+2/3, x+1/3, −z+1/3; (vii) −y+2/3, x−y+1/3, z+1/3; (viii) x+1/3, y−1/3, z−1/3; (ix) y, −x+y, −z; (x) −x, −y, −z; (xi) x−y, x, −z; (xii) −y, x−y, z; (xiii) x, y, z−1; (xiv) x, y, z+1; (xv) y, −x+y, −z+1; (xvi) x−y, x, −z+1; (xvii) −x, −y, −z+1; (xviii) −x+y+1/3, −x+2/3, z+2/3; (xix) y−1/3, −x+y+1/3, −z+1/3; (xx) −x+y+1/3, −x+2/3, z−1/3; (xxi) x−1/3, y+1/3, z+1/3; (xxii) −x+1/3, −y+2/3, −z+2/3. |
Tetradecayttrium henpentacontagold (vsYAu_0m)
top
Crystal data top
Y14Au51 | Dx = 15.056 Mg m−3 |
Mr = 11290.03 | Mo Kα radiation, λ = 0.71073 Å |
Hexagonal, P6/m | Cell parameters from 12877 reflections |
a = 12.5433 (17) Å | θ = 2.2–28.0° |
c = 9.1389 (14) Å | µ = 165.57 mm−1 |
V = 1245.2 (4) Å3 | T = 293 K |
Z = 1 | Irregular fragment, grey |
F(000) = 4575 | 0.06 × 0.05 × 0.05 mm |
Data collection top
Bruker Venture diffractometer | 994 reflections with I > 2σ(I) |
w scan | Rint = 0.054 |
Absorption correction: empirical (using intensity measurements) [Blessing (1995) OR SADABS (Krause et al., 2015)] | θmax = 28.0°, θmin = 2.2° |
Tmin = 0.01, Tmax = 0.06 | h = −13→16 |
12877 measured reflections | k = −16→13 |
1075 independent reflections | l = −12→12 |
Refinement top
Refinement on F2 | 0 restraints |
Least-squares matrix: full | w = 1/[σ2(Fo2) + (0.0098P)2 + 45.996P] where P = (Fo2 + 2Fc2)/3 |
R[F2 > 2σ(F2)] = 0.022 | (Δ/σ)max < 0.001 |
wR(F2) = 0.044 | Δρmax = 2.26 e Å−3 |
S = 1.13 | Δρmin = −2.50 e Å−3 |
1075 reflections | Extinction correction: SHELXL2014 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
62 parameters | Extinction coefficient: 0.000329 (14) |
Special details top
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Au1 | 0.10236 (4) | 0.44248 (4) | 0.33624 (4) | 0.00635 (12) | |
Au2 | 0.26705 (4) | 0.07670 (4) | 0.23249 (5) | 0.00579 (12) | |
Au3 | 0.49390 (4) | 0.11652 (4) | 0.15151 (4) | 0.00630 (12) | |
Au4 | 0.05851 (5) | 0.23798 (5) | 0.5000 | 0.00462 (14) | |
Au5 | 0.02801 (12) | 0.13909 (11) | 0.0000 | 0.0075 (3) | 0.5 |
Au6 | 0.3333 | 0.6667 | 0.31031 (8) | 0.00596 (16) | |
Au7 | 0.3333 | 0.6667 | 0.0000 | 0.0094 (2) | |
Y1 | 0.46512 (14) | 0.14113 (14) | 0.5000 | 0.0039 (3) | |
Y2 | 0.11316 (15) | 0.39227 (16) | 0.0000 | 0.0104 (3) | |
Y3 | 0.0000 | 0.0000 | 0.3018 (3) | 0.0034 (5) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Au1 | 0.0060 (2) | 0.0039 (2) | 0.0069 (2) | 0.00078 (17) | −0.00081 (15) | 0.00170 (15) |
Au2 | 0.0045 (2) | 0.0066 (2) | 0.0072 (2) | 0.00352 (17) | 0.00225 (16) | 0.00177 (16) |
Au3 | 0.0028 (2) | 0.0078 (2) | 0.00664 (19) | 0.00136 (17) | 0.00011 (15) | 0.00101 (16) |
Au4 | 0.0015 (3) | 0.0063 (3) | 0.0061 (3) | 0.0019 (2) | 0.000 | 0.000 |
Au5 | 0.0138 (7) | 0.0032 (5) | 0.0058 (5) | 0.0046 (5) | 0.000 | 0.000 |
Au6 | 0.0035 (2) | 0.0035 (2) | 0.0110 (3) | 0.00173 (11) | 0.000 | 0.000 |
Au7 | 0.0093 (3) | 0.0093 (3) | 0.0097 (5) | 0.00463 (17) | 0.000 | 0.000 |
Y1 | 0.0030 (7) | 0.0037 (7) | 0.0053 (7) | 0.0020 (6) | 0.000 | 0.000 |
Y2 | 0.0084 (8) | 0.0214 (9) | 0.0054 (7) | 0.0103 (7) | 0.000 | 0.000 |
Y3 | 0.0016 (7) | 0.0016 (7) | 0.0068 (11) | 0.0008 (3) | 0.000 | 0.000 |
Geometric parameters (Å, º) top
Au1—Au3i | 2.7542 (7) | Au5—Y3xviii | 3.188 (2) |
Au1—Au4 | 2.7769 (7) | Au5—Y3 | 3.188 (2) |
Au1—Au6 | 2.8654 (6) | Au5—Au5xviii | 3.196 (2) |
Au1—Au3ii | 2.9686 (7) | Au6—Au7 | 2.8358 (9) |
Au1—Au2ii | 2.9735 (7) | Au6—Au1xix | 2.8653 (6) |
Au1—Au1iii | 2.9933 (9) | Au6—Au1xx | 2.8654 (6) |
Au1—Y1iv | 3.0393 (14) | Au6—Au3i | 2.8818 (6) |
Au1—Y1v | 3.0429 (14) | Au6—Au3xxi | 2.8818 (6) |
Au1—Au2v | 3.0640 (7) | Au6—Au3v | 2.8818 (6) |
Au1—Y1i | 3.1036 (14) | Au6—Y1i | 3.0189 (13) |
Au1—Y2 | 3.1532 (7) | Au6—Y1xxii | 3.0189 (13) |
Au2—Au3 | 2.7337 (7) | Au6—Y1v | 3.0189 (13) |
Au2—Au5vi | 2.7381 (9) | Au7—Au6xxiii | 2.8358 (9) |
Au2—Au5vii | 2.8229 (10) | Au7—Au3xxiv | 2.8488 (5) |
Au2—Au4viii | 2.8630 (6) | Au7—Au3xxi | 2.8488 (5) |
Au2—Au4vii | 2.8708 (6) | Au7—Au3i | 2.8488 (5) |
Au2—Au1ix | 2.9735 (7) | Au7—Au3xii | 2.8488 (5) |
Au2—Au2v | 2.9872 (6) | Au7—Au3xvii | 2.8488 (5) |
Au2—Au2vii | 2.9872 (6) | Au7—Au3v | 2.8488 (5) |
Au2—Y3 | 3.0537 (8) | Au7—Y2 | 3.1572 (18) |
Au2—Au1vii | 3.0639 (7) | Au7—Y2xxiii | 3.1572 (18) |
Au2—Y2vii | 3.0723 (13) | Au7—Y2xxv | 3.1572 (18) |
Au2—Y2vi | 3.2509 (14) | Y1—Au6xxii | 3.0190 (13) |
Au3—Au1x | 2.7542 (7) | Y1—Au6x | 3.0190 (13) |
Au3—Au3xi | 2.7692 (9) | Y1—Au1ix | 3.0393 (14) |
Au3—Au7xii | 2.8489 (5) | Y1—Au1viii | 3.0393 (14) |
Au3—Au6x | 2.8818 (6) | Y1—Au1xxvi | 3.0429 (14) |
Au3—Au1ix | 2.9686 (7) | Y1—Au1vii | 3.0429 (14) |
Au3—Au3xiii | 3.0024 (10) | Y1—Au1xxvii | 3.1037 (14) |
Au3—Y2vi | 3.1167 (15) | Y1—Au1x | 3.1037 (14) |
Au3—Y2x | 3.1852 (17) | Y1—Au4vii | 3.1174 (16) |
Au3—Y2vii | 3.2096 (16) | Y1—Au4viii | 3.1837 (16) |
Au3—Y1 | 3.2373 (7) | Y1—Au3iii | 3.2374 (7) |
Au4—Au4v | 2.6942 (7) | Y2—Au2xvii | 3.0723 (13) |
Au4—Au4vii | 2.6942 (7) | Y2—Au2v | 3.0723 (13) |
Au4—Au1iii | 2.7769 (7) | Y2—Au3xvi | 3.1167 (15) |
Au4—Au2ii | 2.8630 (6) | Y2—Au3ii | 3.1167 (15) |
Au4—Au2iv | 2.8630 (6) | Y2—Au1xi | 3.1532 (7) |
Au4—Au2xiv | 2.8709 (6) | Y2—Au3i | 3.1852 (16) |
Au4—Au2v | 2.8709 (6) | Y2—Au3xxiv | 3.1852 (17) |
Au4—Y1v | 3.1175 (17) | Y2—Au3v | 3.2096 (15) |
Au4—Y1iv | 3.1837 (16) | Y2—Au3xvii | 3.2096 (15) |
Au4—Y3 | 3.2463 (15) | Y3—Au2ix | 3.0537 (8) |
Au4—Y3xv | 3.2463 (15) | Y3—Au2xxviii | 3.0537 (8) |
Au5—Au5vii | 1.5982 (12) | Y3—Au2v | 3.0537 (8) |
Au5—Au5v | 1.5983 (12) | Y3—Au2vii | 3.0537 (8) |
Au5—Au2xvi | 2.7381 (9) | Y3—Au2ii | 3.0537 (8) |
Au5—Au2ii | 2.7381 (9) | Y3—Au5xvi | 3.188 (2) |
Au5—Au5vi | 2.768 (2) | Y3—Au5xviii | 3.188 (2) |
Au5—Au5xvi | 2.768 (2) | Y3—Au5v | 3.188 (2) |
Au5—Y2 | 2.799 (2) | Y3—Au5vi | 3.188 (2) |
Au5—Au2v | 2.8228 (10) | Y3—Au5vii | 3.188 (2) |
Au5—Au2xvii | 2.8228 (10) | | |
| | | |
Au3i—Au1—Au4 | 171.85 (2) | Y2—Au5—Au5xviii | 171.68 (8) |
Au3i—Au1—Au6 | 61.666 (16) | Au2v—Au5—Au5xviii | 108.85 (4) |
Au4—Au1—Au6 | 125.96 (2) | Au2xvii—Au5—Au5xviii | 108.85 (4) |
Au3i—Au1—Au3ii | 63.156 (19) | Y3xviii—Au5—Au5xviii | 59.91 (3) |
Au4—Au1—Au3ii | 108.88 (2) | Y3—Au5—Au5xviii | 59.91 (3) |
Au6—Au1—Au3ii | 124.41 (2) | Au7—Au6—Au1xix | 94.744 (17) |
Au3i—Au1—Au2ii | 112.435 (19) | Au7—Au6—Au1 | 94.744 (17) |
Au4—Au1—Au2ii | 59.603 (16) | Au1xix—Au6—Au1 | 119.324 (5) |
Au6—Au1—Au2ii | 150.78 (2) | Au7—Au6—Au1xx | 94.744 (17) |
Au3ii—Au1—Au2ii | 54.779 (14) | Au1xix—Au6—Au1xx | 119.324 (5) |
Au3i—Au1—Au1iii | 127.804 (14) | Au1—Au6—Au1xx | 119.323 (5) |
Au4—Au1—Au1iii | 57.388 (12) | Au7—Au6—Au3i | 59.762 (16) |
Au6—Au1—Au1iii | 94.744 (17) | Au1xix—Au6—Au3i | 151.89 (3) |
Au3ii—Au1—Au1iii | 124.659 (13) | Au1—Au6—Au3i | 57.269 (13) |
Au2ii—Au1—Au1iii | 108.595 (12) | Au1xx—Au6—Au3i | 77.503 (13) |
Au3i—Au1—Y1iv | 109.87 (3) | Au7—Au6—Au3xxi | 59.762 (16) |
Au4—Au1—Y1iv | 66.20 (3) | Au1xix—Au6—Au3xxi | 77.503 (13) |
Au6—Au1—Y1iv | 142.78 (3) | Au1—Au6—Au3xxi | 151.89 (3) |
Au3ii—Au1—Y1iv | 65.20 (2) | Au1xx—Au6—Au3xxi | 57.269 (13) |
Au2ii—Au1—Y1iv | 66.23 (3) | Au3i—Au6—Au3xxi | 96.87 (2) |
Au1iii—Au1—Y1iv | 60.499 (16) | Au7—Au6—Au3v | 59.762 (16) |
Au3i—Au1—Y1v | 122.94 (3) | Au1xix—Au6—Au3v | 57.269 (13) |
Au4—Au1—Y1v | 64.59 (3) | Au1—Au6—Au3v | 77.504 (13) |
Au6—Au1—Y1v | 61.37 (3) | Au1xx—Au6—Au3v | 151.89 (3) |
Au3ii—Au1—Y1v | 168.96 (3) | Au3i—Au6—Au3v | 96.87 (2) |
Au2ii—Au1—Y1v | 115.16 (3) | Au3xxi—Au6—Au3v | 96.87 (2) |
Au1iii—Au1—Y1v | 60.540 (17) | Au7—Au6—Y1i | 125.05 (2) |
Y1iv—Au1—Y1v | 116.82 (3) | Au1xix—Au6—Y1i | 140.20 (3) |
Au3i—Au1—Au2v | 120.06 (2) | Au1—Au6—Y1i | 63.60 (3) |
Au4—Au1—Au2v | 58.635 (16) | Au1xx—Au6—Y1i | 62.21 (3) |
Au6—Au1—Au2v | 97.393 (15) | Au3i—Au6—Y1i | 66.50 (2) |
Au3ii—Au1—Au2v | 104.016 (18) | Au3xxi—Au6—Y1i | 119.40 (3) |
Au2ii—Au1—Au2v | 59.287 (16) | Au3v—Au6—Y1i | 140.85 (3) |
Au1iii—Au1—Au2v | 108.028 (11) | Au7—Au6—Y1xxii | 125.05 (2) |
Y1iv—Au1—Au2v | 115.85 (3) | Au1xix—Au6—Y1xxii | 62.21 (3) |
Y1v—Au1—Au2v | 65.09 (3) | Au1—Au6—Y1xxii | 140.20 (3) |
Au3i—Au1—Y1i | 66.79 (2) | Au1xx—Au6—Y1xxii | 63.60 (3) |
Au4—Au1—Y1i | 118.50 (2) | Au3i—Au6—Y1xxii | 140.85 (3) |
Au6—Au1—Y1i | 60.61 (3) | Au3xxi—Au6—Y1xxii | 66.50 (2) |
Au3ii—Au1—Y1i | 102.75 (3) | Au3v—Au6—Y1xxii | 119.40 (3) |
Au2ii—Au1—Y1i | 146.74 (3) | Y1i—Au6—Y1xxii | 90.31 (3) |
Au1iii—Au1—Y1i | 61.169 (16) | Au7—Au6—Y1v | 125.05 (2) |
Y1iv—Au1—Y1i | 82.47 (4) | Au1xix—Au6—Y1v | 63.60 (3) |
Y1v—Au1—Y1i | 88.28 (5) | Au1—Au6—Y1v | 62.21 (3) |
Au2v—Au1—Y1i | 152.17 (3) | Au1xx—Au6—Y1v | 140.20 (3) |
Au3i—Au1—Y2 | 64.84 (3) | Au3i—Au6—Y1v | 119.40 (3) |
Au4—Au1—Y2 | 110.44 (4) | Au3xxi—Au6—Y1v | 140.85 (3) |
Au6—Au1—Y2 | 89.55 (4) | Au3v—Au6—Y1v | 66.50 (2) |
Au3ii—Au1—Y2 | 61.12 (3) | Y1i—Au6—Y1v | 90.31 (3) |
Au2ii—Au1—Y2 | 64.01 (3) | Y1xxii—Au6—Y1v | 90.31 (3) |
Au1iii—Au1—Y2 | 167.04 (3) | Au6xxiii—Au7—Au6 | 180.0 |
Y1iv—Au1—Y2 | 121.01 (4) | Au6xxiii—Au7—Au3xxiv | 60.922 (10) |
Y1v—Au1—Y2 | 111.68 (4) | Au6—Au7—Au3xxiv | 119.079 (10) |
Au2v—Au1—Y2 | 59.21 (3) | Au6xxiii—Au7—Au3xxi | 119.080 (10) |
Y1i—Au1—Y2 | 131.02 (4) | Au6—Au7—Au3xxi | 60.921 (10) |
Au3—Au2—Au5vi | 107.84 (3) | Au3xxiv—Au7—Au3xxi | 128.178 (5) |
Au3—Au2—Au5vii | 112.81 (3) | Au6xxiii—Au7—Au3i | 119.080 (10) |
Au5vi—Au2—Au5vii | 33.36 (3) | Au6—Au7—Au3i | 60.921 (10) |
Au3—Au2—Au4viii | 113.29 (2) | Au3xxiv—Au7—Au3i | 58.16 (2) |
Au5vi—Au2—Au4viii | 114.08 (3) | Au3xxi—Au7—Au3i | 98.377 (12) |
Au5vii—Au2—Au4viii | 130.86 (3) | Au6xxiii—Au7—Au3xii | 60.921 (10) |
Au3—Au2—Au4vii | 120.19 (2) | Au6—Au7—Au3xii | 119.079 (10) |
Au5vi—Au2—Au4vii | 130.96 (3) | Au3xxiv—Au7—Au3xii | 98.377 (12) |
Au5vii—Au2—Au4vii | 111.27 (3) | Au3xxi—Au7—Au3xii | 58.158 (19) |
Au4viii—Au2—Au4vii | 56.052 (18) | Au3i—Au7—Au3xii | 128.178 (5) |
Au3—Au2—Au1ix | 62.518 (15) | Au6xxiii—Au7—Au3xvii | 60.920 (10) |
Au5vi—Au2—Au1ix | 107.53 (3) | Au6—Au7—Au3xvii | 119.079 (10) |
Au5vii—Au2—Au1ix | 140.26 (3) | Au3xxiv—Au7—Au3xvii | 98.377 (12) |
Au4viii—Au2—Au1ix | 56.781 (16) | Au3xxi—Au7—Au3xvii | 128.178 (5) |
Au4vii—Au2—Au1ix | 102.94 (2) | Au3i—Au7—Au3xvii | 128.178 (5) |
Au3—Au2—Au2v | 125.154 (19) | Au3xii—Au7—Au3xvii | 98.377 (13) |
Au5vi—Au2—Au2v | 86.85 (3) | Au6xxiii—Au7—Au3v | 119.078 (10) |
Au5vii—Au2—Au2v | 56.15 (2) | Au6—Au7—Au3v | 60.921 (10) |
Au4viii—Au2—Au2v | 106.976 (13) | Au3xxiv—Au7—Au3v | 128.178 (5) |
Au4vii—Au2—Au2v | 58.475 (14) | Au3xxi—Au7—Au3v | 98.377 (12) |
Au1ix—Au2—Au2v | 161.406 (12) | Au3i—Au7—Au3v | 98.377 (12) |
Au3—Au2—Au2vii | 112.347 (19) | Au3xii—Au7—Au3v | 128.178 (5) |
Au5vi—Au2—Au2vii | 58.89 (3) | Au3xvii—Au7—Au3v | 58.16 (2) |
Au5vii—Au2—Au2vii | 88.54 (3) | Au6xxiii—Au7—Y2 | 90.0 |
Au4viii—Au2—Au2vii | 58.731 (14) | Au6—Au7—Y2 | 90.0 |
Au4vii—Au2—Au2vii | 107.084 (13) | Au3xxiv—Au7—Y2 | 63.81 (3) |
Au1ix—Au2—Au2vii | 61.863 (16) | Au3xxi—Au7—Y2 | 150.919 (10) |
Au2v—Au2—Au2vii | 120.0 | Au3i—Au7—Y2 | 63.81 (3) |
Au3—Au2—Y3 | 172.47 (3) | Au3xii—Au7—Y2 | 150.919 (10) |
Au5vi—Au2—Y3 | 66.54 (5) | Au3xvii—Au7—Y2 | 64.37 (3) |
Au5vii—Au2—Y3 | 65.57 (5) | Au3v—Au7—Y2 | 64.37 (3) |
Au4viii—Au2—Y3 | 66.46 (4) | Au6xxiii—Au7—Y2xxiii | 90.0 |
Au4vii—Au2—Y3 | 66.37 (4) | Au6—Au7—Y2xxiii | 90.0 |
Au1ix—Au2—Y3 | 113.56 (3) | Au3xxiv—Au7—Y2xxiii | 64.37 (3) |
Au2v—Au2—Y3 | 60.718 (6) | Au3xxi—Au7—Y2xxiii | 63.81 (3) |
Au2vii—Au2—Y3 | 60.718 (6) | Au3i—Au7—Y2xxiii | 64.37 (3) |
Au3—Au2—Au1vii | 76.470 (16) | Au3xii—Au7—Y2xxiii | 63.81 (3) |
Au5vi—Au2—Au1vii | 135.48 (3) | Au3xvii—Au7—Y2xxiii | 150.919 (10) |
Au5vii—Au2—Au1vii | 102.99 (3) | Au3v—Au7—Y2xxiii | 150.919 (10) |
Au4viii—Au2—Au1vii | 103.33 (2) | Y2—Au7—Y2xxiii | 120.000 (1) |
Au4vii—Au2—Au1vii | 55.682 (15) | Au6xxiii—Au7—Y2xxv | 90.0 |
Au1ix—Au2—Au1vii | 112.921 (16) | Au6—Au7—Y2xxv | 90.0 |
Au2v—Au2—Au1vii | 58.850 (15) | Au3xxiv—Au7—Y2xxv | 150.919 (10) |
Au2vii—Au2—Au1vii | 161.742 (11) | Au3xxi—Au7—Y2xxv | 64.37 (3) |
Y3—Au2—Au1vii | 111.02 (2) | Au3i—Au7—Y2xxv | 150.919 (10) |
Au3—Au2—Y2vii | 66.83 (3) | Au3xii—Au7—Y2xxv | 64.37 (3) |
Au5vi—Au2—Y2vii | 78.88 (4) | Au3xvii—Au7—Y2xxv | 63.81 (3) |
Au5vii—Au2—Y2vii | 56.50 (4) | Au3v—Au7—Y2xxv | 63.81 (3) |
Au4viii—Au2—Y2vii | 165.07 (3) | Y2—Au7—Y2xxv | 120.0 |
Au4vii—Au2—Y2vii | 110.19 (3) | Y2xxiii—Au7—Y2xxv | 120.0 |
Au1ix—Au2—Y2vii | 128.42 (3) | Au6xxii—Y1—Au6x | 70.09 (4) |
Au2v—Au2—Y2vii | 64.87 (3) | Au6xxii—Y1—Au1ix | 152.94 (5) |
Au2vii—Au2—Y2vii | 135.92 (2) | Au6x—Y1—Au1ix | 108.96 (2) |
Y3—Au2—Y2vii | 115.52 (5) | Au6xxii—Y1—Au1viii | 108.96 (2) |
Au1vii—Au2—Y2vii | 61.84 (3) | Au6x—Y1—Au1viii | 152.94 (5) |
Au3—Au2—Y2vi | 62.06 (3) | Au1ix—Y1—Au1viii | 59.00 (3) |
Au5vi—Au2—Y2vi | 54.92 (4) | Au6xxii—Y1—Au1xxvi | 56.41 (2) |
Au5vii—Au2—Y2vi | 81.85 (4) | Au6x—Y1—Au1xxvi | 90.67 (4) |
Au4viii—Au2—Y2vi | 105.59 (3) | Au1ix—Y1—Au1xxvi | 148.61 (6) |
Au4vii—Au2—Y2vi | 161.51 (3) | Au1viii—Y1—Au1xxvi | 111.67 (3) |
Au1ix—Au2—Y2vi | 60.68 (3) | Au6xxii—Y1—Au1vii | 90.67 (4) |
Au2v—Au2—Y2vi | 137.48 (2) | Au6x—Y1—Au1vii | 56.41 (2) |
Au2vii—Au2—Y2vi | 58.83 (3) | Au1ix—Y1—Au1vii | 111.67 (3) |
Y3—Au2—Y2vi | 110.51 (4) | Au1viii—Y1—Au1vii | 148.61 (6) |
Au1vii—Au2—Y2vi | 136.12 (3) | Au1xxvi—Y1—Au1vii | 58.92 (3) |
Y2vii—Au2—Y2vi | 87.798 (17) | Au6xxii—Y1—Au1xxvii | 55.79 (2) |
Au2—Au3—Au1x | 125.00 (2) | Au6x—Y1—Au1xxvii | 89.52 (4) |
Au2—Au3—Au3xi | 105.707 (13) | Au1ix—Y1—Au1xxvii | 97.53 (4) |
Au1x—Au3—Au3xi | 127.803 (14) | Au1viii—Y1—Au1xxvii | 69.88 (3) |
Au2—Au3—Au7xii | 122.101 (18) | Au1xxvi—Y1—Au1xxvii | 107.15 (3) |
Au1x—Au3—Au7xii | 96.937 (17) | Au1vii—Y1—Au1xxvii | 140.29 (5) |
Au3xi—Au3—Au7xii | 60.921 (10) | Au6xxii—Y1—Au1x | 89.52 (4) |
Au2—Au3—Au6x | 105.008 (18) | Au6x—Y1—Au1x | 55.79 (2) |
Au1x—Au3—Au6x | 61.068 (14) | Au1ix—Y1—Au1x | 69.88 (3) |
Au3xi—Au3—Au6x | 120.237 (16) | Au1viii—Y1—Au1x | 97.53 (4) |
Au7xii—Au3—Au6x | 59.317 (18) | Au1xxvi—Y1—Au1x | 140.29 (5) |
Au2—Au3—Au1ix | 62.702 (15) | Au1vii—Y1—Au1x | 107.15 (3) |
Au1x—Au3—Au1ix | 75.78 (2) | Au1xxvii—Y1—Au1x | 57.66 (3) |
Au3xi—Au3—Au1ix | 124.659 (13) | Au6xxii—Y1—Au4vii | 109.98 (4) |
Au7xii—Au3—Au1ix | 172.590 (18) | Au6x—Y1—Au4vii | 109.98 (4) |
Au6x—Au3—Au1ix | 114.88 (2) | Au1ix—Y1—Au4vii | 95.91 (4) |
Au2—Au3—Au3xiii | 112.16 (2) | Au1viii—Y1—Au4vii | 95.91 (4) |
Au1x—Au3—Au3xiii | 61.909 (15) | Au1xxvi—Y1—Au4vii | 53.57 (3) |
Au3xi—Au3—Au3xiii | 90.0 | Au1vii—Y1—Au4vii | 53.57 (3) |
Au7xii—Au3—Au3xiii | 123.004 (19) | Au1xxvii—Y1—Au4vii | 151.146 (16) |
Au6x—Au3—Au3xiii | 122.580 (19) | Au1x—Y1—Au4vii | 151.146 (16) |
Au1ix—Au3—Au3xiii | 54.935 (14) | Au6xxii—Y1—Au4viii | 142.36 (3) |
Au2—Au3—Y2vi | 67.15 (3) | Au6x—Y1—Au4viii | 142.36 (3) |
Au1x—Au3—Y2vi | 123.00 (3) | Au1ix—Y1—Au4viii | 52.94 (3) |
Au3xi—Au3—Y2vi | 63.624 (16) | Au1viii—Y1—Au4viii | 52.94 (3) |
Au7xii—Au3—Y2vi | 124.05 (2) | Au1xxvi—Y1—Au4viii | 96.62 (4) |
Au6x—Au3—Y2vi | 172.15 (3) | Au1vii—Y1—Au4viii | 96.62 (4) |
Au1ix—Au3—Y2vi | 62.36 (2) | Au1xxvii—Y1—Au4viii | 122.77 (4) |
Au3xiii—Au3—Y2vi | 62.70 (3) | Au1x—Y1—Au4viii | 122.77 (4) |
Au2—Au3—Y2x | 166.16 (3) | Au4vii—Y1—Au4viii | 50.61 (3) |
Au1x—Au3—Y2x | 63.65 (2) | Au6xxii—Y1—Au3 | 123.52 (5) |
Au3xi—Au3—Y2x | 64.234 (16) | Au6x—Y1—Au3 | 54.720 (18) |
Au7xii—Au3—Y2x | 62.81 (3) | Au1ix—Y1—Au3 | 56.346 (17) |
Au6x—Au3—Y2x | 88.63 (3) | Au1viii—Y1—Au3 | 114.50 (4) |
Au1ix—Au3—Y2x | 114.00 (3) | Au1xxvi—Y1—Au3 | 128.51 (4) |
Au3xiii—Au3—Y2x | 60.40 (3) | Au1vii—Y1—Au3 | 69.815 (18) |
Y2vi—Au3—Y2x | 99.21 (4) | Au1xxvii—Y1—Au3 | 108.99 (4) |
Au2—Au3—Y2vii | 61.64 (3) | Au1x—Y1—Au3 | 51.435 (17) |
Au1x—Au3—Y2vii | 149.16 (3) | Au4vii—Y1—Au3 | 99.72 (3) |
Au3xi—Au3—Y2vii | 64.444 (15) | Au4viii—Y1—Au3 | 93.46 (3) |
Au7xii—Au3—Y2vii | 62.48 (3) | Au6xxii—Y1—Au3iii | 54.720 (18) |
Au6x—Au3—Y2vii | 88.15 (3) | Au6x—Y1—Au3iii | 123.52 (5) |
Au1ix—Au3—Y2vii | 123.51 (3) | Au1ix—Y1—Au3iii | 114.50 (4) |
Au3xiii—Au3—Y2vii | 148.03 (3) | Au1viii—Y1—Au3iii | 56.346 (17) |
Y2vi—Au3—Y2vii | 87.78 (5) | Au1xxvi—Y1—Au3iii | 69.815 (18) |
Y2x—Au3—Y2vii | 117.55 (5) | Au1vii—Y1—Au3iii | 128.51 (4) |
Au2—Au3—Y1 | 66.14 (3) | Au1xxvii—Y1—Au3iii | 51.435 (17) |
Au1x—Au3—Y1 | 61.78 (3) | Au1x—Y1—Au3iii | 108.99 (4) |
Au3xi—Au3—Y1 | 169.67 (3) | Au4vii—Y1—Au3iii | 99.72 (3) |
Au7xii—Au3—Y1 | 117.06 (3) | Au4viii—Y1—Au3iii | 93.46 (3) |
Au6x—Au3—Y1 | 58.78 (3) | Au3—Y1—Au3iii | 159.33 (5) |
Au1ix—Au3—Y1 | 58.46 (3) | Au5—Y2—Au2xvii | 57.25 (3) |
Au3xiii—Au3—Y1 | 98.93 (3) | Au5—Y2—Au2v | 57.25 (3) |
Y2vi—Au3—Y1 | 116.05 (3) | Au2xvii—Y2—Au2v | 87.50 (5) |
Y2x—Au3—Y1 | 124.89 (3) | Au5—Y2—Au3xvi | 96.61 (5) |
Y2vii—Au3—Y1 | 105.37 (3) | Au2xvii—Y2—Au3xvi | 100.39 (3) |
Au4v—Au4—Au4vii | 120.000 (1) | Au2v—Y2—Au3xvi | 142.63 (6) |
Au4v—Au4—Au1 | 113.38 (2) | Au5—Y2—Au3ii | 96.61 (5) |
Au4vii—Au4—Au1 | 116.43 (2) | Au2xvii—Y2—Au3ii | 142.63 (6) |
Au4v—Au4—Au1iii | 113.38 (2) | Au2v—Y2—Au3ii | 100.39 (3) |
Au4vii—Au4—Au1iii | 116.43 (2) | Au3xvi—Y2—Au3ii | 52.75 (3) |
Au1—Au4—Au1iii | 65.23 (2) | Au5—Y2—Au1 | 101.33 (3) |
Au4v—Au4—Au2ii | 62.122 (16) | Au2xvii—Y2—Au1 | 146.31 (5) |
Au4vii—Au4—Au2ii | 115.570 (12) | Au2v—Y2—Au1 | 58.949 (16) |
Au1—Au4—Au2ii | 63.616 (15) | Au3xvi—Y2—Au1 | 108.31 (4) |
Au1iii—Au4—Au2ii | 118.43 (2) | Au3ii—Y2—Au1 | 56.516 (19) |
Au4v—Au4—Au2iv | 62.122 (16) | Au5—Y2—Au1xi | 101.33 (3) |
Au4vii—Au4—Au2iv | 115.570 (12) | Au2xvii—Y2—Au1xi | 58.950 (16) |
Au1—Au4—Au2iv | 118.43 (2) | Au2v—Y2—Au1xi | 146.31 (5) |
Au1iii—Au4—Au2iv | 63.615 (15) | Au3xvi—Y2—Au1xi | 56.515 (19) |
Au2ii—Au4—Au2iv | 117.28 (3) | Au3ii—Y2—Au1xi | 108.31 (4) |
Au4v—Au4—Au2xiv | 115.680 (12) | Au1—Y2—Au1xi | 154.07 (6) |
Au4vii—Au4—Au2xiv | 61.827 (16) | Au5—Y2—Au7 | 150.05 (6) |
Au1—Au4—Au2xiv | 120.41 (2) | Au2xvii—Y2—Au7 | 103.29 (4) |
Au1iii—Au4—Au2xiv | 65.686 (15) | Au2v—Y2—Au7 | 103.29 (4) |
Au2ii—Au4—Au2xiv | 175.71 (3) | Au3xvi—Y2—Au7 | 110.11 (5) |
Au2iv—Au4—Au2xiv | 62.795 (16) | Au3ii—Y2—Au7 | 110.11 (5) |
Au4v—Au4—Au2v | 115.680 (13) | Au1—Y2—Au7 | 83.33 (3) |
Au4vii—Au4—Au2v | 61.827 (16) | Au1xi—Y2—Au7 | 83.33 (3) |
Au1—Au4—Au2v | 65.685 (15) | Au5—Y2—Au3i | 148.61 (4) |
Au1iii—Au4—Au2v | 120.41 (2) | Au2xvii—Y2—Au3i | 154.12 (5) |
Au2ii—Au4—Au2v | 62.795 (16) | Au2v—Y2—Au3i | 107.37 (2) |
Au2iv—Au4—Au2v | 175.71 (3) | Au3xvi—Y2—Au3i | 80.79 (4) |
Au2xiv—Au4—Au2v | 116.77 (3) | Au3ii—Y2—Au3i | 56.89 (3) |
Au4v—Au4—Y1v | 174.03 (3) | Au1—Y2—Au3i | 51.51 (2) |
Au4vii—Au4—Y1v | 65.97 (3) | Au1xi—Y2—Au3i | 102.99 (5) |
Au1—Au4—Y1v | 61.84 (3) | Au7—Y2—Au3i | 53.38 (3) |
Au1iii—Au4—Y1v | 61.84 (3) | Au5—Y2—Au3xxiv | 148.61 (4) |
Au2ii—Au4—Y1v | 116.188 (17) | Au2xvii—Y2—Au3xxiv | 107.37 (2) |
Au2iv—Au4—Y1v | 116.188 (17) | Au2v—Y2—Au3xxiv | 154.12 (5) |
Au2xiv—Au4—Y1v | 66.401 (18) | Au3xvi—Y2—Au3xxiv | 56.89 (3) |
Au2v—Au4—Y1v | 66.401 (18) | Au3ii—Y2—Au3xxiv | 80.79 (4) |
Au4v—Au4—Y1iv | 63.42 (3) | Au1—Y2—Au3xxiv | 102.99 (5) |
Au4vii—Au4—Y1iv | 176.58 (3) | Au1xi—Y2—Au3xxiv | 51.51 (2) |
Au1—Au4—Y1iv | 60.86 (3) | Au7—Y2—Au3xxiv | 53.38 (3) |
Au1iii—Au4—Y1iv | 60.86 (3) | Au3i—Y2—Au3xxiv | 51.53 (3) |
Au2ii—Au4—Y1iv | 65.576 (17) | Au5—Y2—Au3v | 100.55 (5) |
Au2iv—Au4—Y1iv | 65.576 (17) | Au2xvii—Y2—Au3v | 88.54 (4) |
Au2xiv—Au4—Y1iv | 117.239 (17) | Au2v—Y2—Au3v | 51.53 (2) |
Au2v—Au4—Y1iv | 117.239 (17) | Au3xvi—Y2—Au3v | 162.83 (6) |
Y1v—Au4—Y1iv | 110.61 (3) | Au3ii—Y2—Au3v | 124.90 (2) |
Au4v—Au4—Y3 | 65.483 (12) | Au1—Y2—Au3v | 68.85 (2) |
Au4vii—Au4—Y3 | 65.483 (12) | Au1xi—Y2—Au3v | 118.69 (4) |
Au1—Au4—Y3 | 113.46 (4) | Au7—Y2—Au3v | 53.15 (3) |
Au1iii—Au4—Y3 | 177.95 (3) | Au3i—Y2—Au3v | 84.81 (4) |
Au2ii—Au4—Y3 | 59.59 (3) | Au3xxiv—Y2—Au3v | 106.53 (5) |
Au2iv—Au4—Y3 | 116.52 (4) | Au5—Y2—Au3xvii | 100.55 (5) |
Au2xiv—Au4—Y3 | 116.29 (4) | Au2xvii—Y2—Au3xvii | 51.53 (2) |
Au2v—Au4—Y3 | 59.52 (3) | Au2v—Y2—Au3xvii | 88.54 (4) |
Y1v—Au4—Y3 | 119.17 (3) | Au3xvi—Y2—Au3xvii | 124.90 (2) |
Y1iv—Au4—Y3 | 117.20 (3) | Au3ii—Y2—Au3xvii | 162.83 (6) |
Au4v—Au4—Y3xv | 65.483 (12) | Au1—Y2—Au3xvii | 118.69 (4) |
Au4vii—Au4—Y3xv | 65.483 (12) | Au1xi—Y2—Au3xvii | 68.85 (2) |
Au1—Au4—Y3xv | 177.95 (3) | Au7—Y2—Au3xvii | 53.15 (3) |
Au1iii—Au4—Y3xv | 113.45 (4) | Au3i—Y2—Au3xvii | 106.53 (5) |
Au2ii—Au4—Y3xv | 116.52 (4) | Au3xxiv—Y2—Au3xvii | 84.81 (4) |
Au2iv—Au4—Y3xv | 59.59 (3) | Au3v—Y2—Au3xvii | 51.11 (3) |
Au2xiv—Au4—Y3xv | 59.52 (3) | Au2—Y3—Au2ix | 115.81 (3) |
Au2v—Au4—Y3xv | 116.29 (4) | Au2—Y3—Au2xxviii | 156.04 (9) |
Y1v—Au4—Y3xv | 119.17 (3) | Au2ix—Y3—Au2xxviii | 58.564 (11) |
Y1iv—Au4—Y3xv | 117.20 (3) | Au2—Y3—Au2v | 58.564 (11) |
Y3—Au4—Y3xv | 67.82 (8) | Au2ix—Y3—Au2v | 156.04 (9) |
Au5vii—Au5—Au5v | 120.0 | Au2xxviii—Y3—Au2v | 115.81 (3) |
Au5vii—Au5—Au2xvi | 128.67 (3) | Au2—Y3—Au2vii | 58.565 (11) |
Au5v—Au5—Au2xvi | 76.23 (5) | Au2ix—Y3—Au2vii | 58.564 (11) |
Au5vii—Au5—Au2ii | 128.67 (3) | Au2xxviii—Y3—Au2vii | 115.81 (3) |
Au5v—Au5—Au2ii | 76.23 (5) | Au2v—Y3—Au2vii | 115.81 (3) |
Au2xvi—Au5—Au2ii | 101.79 (5) | Au2—Y3—Au2ii | 115.81 (3) |
Au5vii—Au5—Au5vi | 30.0 | Au2ix—Y3—Au2ii | 115.81 (3) |
Au5v—Au5—Au5vi | 90.0 | Au2xxviii—Y3—Au2ii | 58.564 (11) |
Au2xvi—Au5—Au5vi | 125.74 (2) | Au2v—Y3—Au2ii | 58.564 (11) |
Au2ii—Au5—Au5vi | 125.74 (2) | Au2vii—Y3—Au2ii | 156.04 (9) |
Au5vii—Au5—Au5xvi | 90.000 (1) | Au2—Y3—Au5xvi | 103.44 (7) |
Au5v—Au5—Au5xvi | 30.0 | Au2ix—Y3—Au5xvi | 51.98 (3) |
Au2xvi—Au5—Au5xvi | 94.93 (5) | Au2xxviii—Y3—Au5xvi | 53.72 (3) |
Au2ii—Au5—Au5xvi | 94.93 (5) | Au2v—Y3—Au5xvi | 104.88 (7) |
Au5vi—Au5—Au5xvi | 60.0 | Au2vii—Y3—Au5xvi | 78.24 (5) |
Au5vii—Au5—Y2 | 111.68 (8) | Au2ii—Y3—Au5xvi | 81.06 (5) |
Au5v—Au5—Y2 | 128.32 (8) | Au2—Y3—Au5xviii | 78.24 (5) |
Au2xvi—Au5—Y2 | 71.90 (3) | Au2ix—Y3—Au5xviii | 53.72 (3) |
Au2ii—Au5—Y2 | 71.90 (3) | Au2xxviii—Y3—Au5xviii | 81.06 (5) |
Au5vi—Au5—Y2 | 141.68 (8) | Au2v—Y3—Au5xviii | 103.44 (7) |
Au5xvi—Au5—Y2 | 158.32 (8) | Au2vii—Y3—Au5xviii | 51.98 (3) |
Au5vii—Au5—Au2v | 70.41 (5) | Au2ii—Y3—Au5xviii | 104.88 (7) |
Au5v—Au5—Au2v | 131.18 (2) | Au5xvi—Y3—Au5xviii | 29.03 (3) |
Au2xvi—Au5—Au2v | 138.15 (5) | Au2—Y3—Au5v | 104.88 (7) |
Au2ii—Au5—Au2v | 64.963 (16) | Au2ix—Y3—Au5v | 78.24 (5) |
Au5vi—Au5—Au2v | 89.59 (5) | Au2xxviii—Y3—Au5v | 51.98 (3) |
Au5xvi—Au5—Au2v | 124.51 (3) | Au2v—Y3—Au5v | 81.06 (5) |
Y2—Au5—Au2v | 66.25 (3) | Au2vii—Y3—Au5v | 103.44 (7) |
Au5vii—Au5—Au2xvii | 70.41 (5) | Au2ii—Y3—Au5v | 53.72 (3) |
Au5v—Au5—Au2xvii | 131.18 (2) | Au5xvi—Y3—Au5v | 29.03 (3) |
Au2xvi—Au5—Au2xvii | 64.963 (17) | Au5xviii—Y3—Au5v | 51.46 (5) |
Au2ii—Au5—Au2xvii | 138.15 (5) | Au2—Y3—Au5vi | 51.98 (3) |
Au5vi—Au5—Au2xvii | 89.59 (5) | Au2ix—Y3—Au5vi | 81.06 (5) |
Au5xvi—Au5—Au2xvii | 124.51 (3) | Au2xxviii—Y3—Au5vi | 104.88 (7) |
Y2—Au5—Au2xvii | 66.25 (3) | Au2v—Y3—Au5vi | 78.24 (5) |
Au2v—Au5—Au2xvii | 97.64 (4) | Au2vii—Y3—Au5vi | 53.72 (3) |
Au5vii—Au5—Y3xviii | 75.483 (13) | Au2ii—Y3—Au5vi | 103.44 (7) |
Au5v—Au5—Y3xviii | 75.483 (13) | Au5xvi—Y3—Au5vi | 51.46 (5) |
Au2xvi—Au5—Y3xviii | 61.48 (2) | Au5xviii—Y3—Au5vi | 29.03 (3) |
Au2ii—Au5—Y3xviii | 149.93 (5) | Au5v—Y3—Au5vi | 60.18 (6) |
Au5vi—Au5—Y3xviii | 64.27 (2) | Au2—Y3—Au5vii | 53.72 (3) |
Au5xvi—Au5—Y3xviii | 64.27 (3) | Au2ix—Y3—Au5vii | 104.88 (7) |
Y2—Au5—Y3xviii | 119.74 (3) | Au2xxviii—Y3—Au5vii | 103.44 (7) |
Au2v—Au5—Y3xviii | 144.41 (5) | Au2v—Y3—Au5vii | 51.98 (3) |
Au2xvii—Au5—Y3xviii | 60.71 (2) | Au2vii—Y3—Au5vii | 81.06 (5) |
Au5vii—Au5—Y3 | 75.483 (13) | Au2ii—Y3—Au5vii | 78.24 (5) |
Au5v—Au5—Y3 | 75.483 (13) | Au5xvi—Y3—Au5vii | 60.18 (6) |
Au2xvi—Au5—Y3 | 149.93 (5) | Au5xviii—Y3—Au5vii | 51.46 (5) |
Au2ii—Au5—Y3 | 61.48 (2) | Au5v—Y3—Au5vii | 51.46 (5) |
Au5vi—Au5—Y3 | 64.27 (2) | Au5vi—Y3—Au5vii | 29.03 (3) |
Au5xvi—Au5—Y3 | 64.27 (2) | Au2—Y3—Au5 | 81.06 (5) |
Y2—Au5—Y3 | 119.74 (3) | Au2ix—Y3—Au5 | 103.44 (7) |
Au2v—Au5—Y3 | 60.71 (2) | Au2xxviii—Y3—Au5 | 78.24 (5) |
Au2xvii—Au5—Y3 | 144.41 (5) | Au2v—Y3—Au5 | 53.72 (3) |
Y3xviii—Au5—Y3 | 119.82 (6) | Au2vii—Y3—Au5 | 104.87 (7) |
Au5vii—Au5—Au5xviii | 60.0 | Au2ii—Y3—Au5 | 51.98 (3) |
Au5v—Au5—Au5xviii | 60.0 | Au5xvi—Y3—Au5 | 51.46 (5) |
Au2xvi—Au5—Au5xviii | 112.76 (4) | Au5xviii—Y3—Au5 | 60.18 (6) |
Au2ii—Au5—Au5xviii | 112.76 (4) | Au5v—Y3—Au5 | 29.03 (3) |
Au5vi—Au5—Au5xviii | 30.0 | Au5vi—Y3—Au5 | 51.46 (5) |
Au5xvi—Au5—Au5xviii | 30.0 | Au5vii—Y3—Au5 | 29.03 (3) |
Symmetry codes: (i) y, −x+y+1, z; (ii) −y, x−y, z; (iii) x, y, −z+1; (iv) −y, x−y, −z+1; (v) x−y, x, z; (vi) −x+y, −x, −z; (vii) y, −x+y, z; (viii) −x+y, −x, −z+1; (ix) −x+y, −x, z; (x) x−y+1, x, z; (xi) x, y, −z; (xii) −x+1, −y+1, −z; (xiii) −x+1, −y, z; (xiv) x−y, x, −z+1; (xv) −x, −y, −z+1; (xvi) −y, x−y, −z; (xvii) x−y, x, −z; (xviii) −x, −y, −z; (xix) −y+1, x−y+1, z; (xx) −x+y, −x+1, z; (xxi) −x+1, −y+1, z; (xxii) −x+1, −y+1, −z+1; (xxiii) −x+y, −x+1, −z; (xxiv) y, −x+y+1, −z; (xxv) −y+1, x−y+1, −z; (xxvi) y, −x+y, −z+1; (xxvii) x−y+1, x, −z+1; (xxviii) −x, −y, z. |
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