Tris[tri­phenyl­anti­mony(V)]hexa(μ-oxido)­tellurium(VI): a mol­ecular complex with six Te—O—Sb bridges

Domasevitch, K.V.; Senchyk, G.A.

doi:10.1107/S2056989021011294

Tris[triphenylantimony(V)]hexa(μ-oxido)tellurium(VI): a molecular complex with six Te—O—Sb bridges

The structure of (C₁₈H₁₅Sb)₃TeO₆, contains a [TeO₆] octahedral unit linked to three trigonal–bipyramidal [SbC₃O₂] units via pairs of bridging O atoms to form a discrete molecular unit. The packing of the units is dominated by C—H

O hydrogen bonding and weak dispersion forces, with a minor contribution from C—H

π bonds and π–π stacking interactions.

Keywords: crystal structure; triorganoantimony(V); hexaoxidotellurate(VI); polyoxoanions; oxide clusters; Hirshfeld surface.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2056989021011294/cq2048sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S2056989021011294/cq2048Isup2.hkl Contains datablock I

CCDC reference: 2118082

checkCIF report

Key indicators

Single-crystal X-ray study
T = 173 K
Mean (C-C) = 0.009 Å
R factor = 0.038
wR factor = 0.096
Data-to-parameter ratio = 18.6

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT220_ALERT_2_C NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range        3.2 Ratio
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of        C29 Check
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of        C39 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        C25 Check
PLAT342_ALERT_3_C Low Bond Precision on  C-C Bonds ...............    0.00867 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H21      ..O4       .       2.75 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H46      ..O6       .       2.67 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H47      ..O6       .       2.73 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H47      ..O2       .       2.70 Ang.
PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ......      3.831 Check
PLAT911_ALERT_3_C Missing FCF Refl Between Thmin & STh/L=    0.600         18 Report
PLAT978_ALERT_2_C Number C-C Bonds with Positive Residual Density.          0 Info

Alert level G
PLAT128_ALERT_4_G Alternate Setting for Input Space Group     C2/c       I2/a Note
PLAT910_ALERT_3_G Missing # of FCF Reflection(s) Below Theta(Min).          4 Note
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600         61 Note

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
  12 ALERT level C = Check. Ensure it is not caused by an omission or oversight
   3 ALERT level G = General information/check it is not something unexpected

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   6 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: IPDS Software (Stoe & Cie, 2000); cell refinement: IPDS Software (Stoe & Cie, 2000); data reduction: IPDS Software (Stoe & Cie, 2000); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2018/1 (Sheldrick, 2015); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: WinGX (Farrugia, 2012).

Hexa-µ-oxido-1:2κ⁴O:O;1:3κ⁴O:O;1:4κ⁴O:O-nonaphenyl-2κ³C,3κ³C,4κ³C-triantimony(V)tellurium(VI) top

Crystal data top

[Sb₃Te(C₆H₅)₉O₆]	F(000) = 4976
M_r = 1282.75	D_x = 1.762 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
a = 47.714 (2) Å	Cell parameters from 8000 reflections
b = 9.1176 (4) Å	θ = 2.2–27.2°
c = 22.9324 (10) Å	µ = 2.31 mm⁻¹
β = 104.168 (4)°	T = 173 K
V = 9672.9 (8) Å³	Prism, colorless
Z = 8	0.28 × 0.22 × 0.21 mm

Data collection top

Stoe IPDS diffractometer	8356 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	R_int = 0.053
φ oscillation scans	θ_max = 27.2°, θ_min = 2.2°
Absorption correction: numerical [X-RED (Stoe & Cie, 2001) and X-SHAPE (Stoe & Cie, 1999)]	h = −61→61
T_min = 0.499, T_max = 0.572	k = −11→11
29796 measured reflections	l = −22→29
10754 independent reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.038	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.096	H-atom parameters constrained
S = 0.93	w = 1/[σ²(F_o²) + (0.0636P)²] where P = (F_o² + 2F_c²)/3
10754 reflections	(Δ/σ)_max = 0.001
577 parameters	Δρ_max = 1.00 e Å⁻³
0 restraints	Δρ_min = −1.24 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Te1	0.11716 (2)	0.68140 (3)	0.04796 (2)	0.02091 (7)
Sb1	0.07040 (2)	0.57473 (3)	−0.06047 (2)	0.02250 (7)
Sb2	0.17996 (2)	0.60629 (3)	0.04935 (2)	0.02511 (8)
Sb3	0.11281 (2)	0.81559 (3)	0.16789 (2)	0.02307 (8)
O1	0.10263 (7)	0.7188 (3)	−0.03781 (13)	0.0251 (6)
O2	0.08497 (7)	0.5513 (3)	0.03277 (13)	0.0242 (6)
O3	0.14157 (7)	0.5152 (3)	0.03645 (14)	0.0272 (7)
O4	0.15241 (7)	0.7840 (3)	0.04941 (14)	0.0259 (6)
O5	0.09873 (7)	0.8455 (3)	0.07399 (13)	0.0242 (6)
O6	0.12791 (7)	0.6419 (3)	0.13479 (13)	0.0256 (6)
C1	0.02873 (10)	0.6340 (5)	−0.0526 (2)	0.0283 (9)
C2	0.02482 (13)	0.7519 (6)	−0.0164 (3)	0.0481 (14)
H2	0.040997	0.806533	0.005257	0.058*
C3	−0.00268 (15)	0.7882 (7)	−0.0124 (3)	0.0578 (17)
H3	−0.005373	0.870350	0.011127	0.069*
C4	−0.02669 (13)	0.7065 (7)	−0.0423 (3)	0.0523 (16)
H4	−0.045521	0.731029	−0.038595	0.063*
C5	−0.02249 (12)	0.5895 (7)	−0.0773 (3)	0.0491 (14)
H5	−0.038624	0.533456	−0.098183	0.059*
C6	0.00518 (11)	0.5525 (6)	−0.0826 (2)	0.0392 (12)
H6	0.007804	0.471373	−0.106653	0.047*
C7	0.06772 (10)	0.6452 (5)	−0.15228 (19)	0.0279 (9)
C8	0.04299 (14)	0.7081 (8)	−0.1870 (3)	0.0572 (17)
H8	0.026270	0.718276	−0.171824	0.069*
C9	0.04280 (16)	0.7567 (10)	−0.2448 (3)	0.075 (2)
H9	0.025760	0.799698	−0.269074	0.090*
C10	0.06683 (17)	0.7434 (9)	−0.2672 (3)	0.065 (2)
H10	0.066485	0.775560	−0.306753	0.078*
C11	0.09166 (15)	0.6821 (7)	−0.2310 (3)	0.0541 (16)
H11	0.108536	0.673533	−0.245738	0.065*
C12	0.09213 (13)	0.6338 (7)	−0.1741 (2)	0.0453 (13)
H12	0.109299	0.592438	−0.149739	0.054*
C13	0.07579 (10)	0.3464 (5)	−0.0738 (2)	0.0253 (9)
C14	0.06436 (11)	0.2885 (5)	−0.1306 (2)	0.0332 (11)
H14	0.055396	0.351604	−0.162692	0.040*
C15	0.06591 (12)	0.1384 (5)	−0.1409 (2)	0.0381 (12)
H15	0.057839	0.098566	−0.179658	0.046*
C16	0.07947 (13)	0.0479 (5)	−0.0935 (3)	0.0418 (13)
H16	0.080622	−0.054577	−0.100017	0.050*
C17	0.09124 (13)	0.1054 (5)	−0.0373 (2)	0.0392 (12)
H17	0.100771	0.042865	−0.005505	0.047*
C18	0.08920 (12)	0.2546 (5)	−0.0271 (2)	0.0351 (11)
H18	0.097003	0.293822	0.011831	0.042*
C19	0.19842 (11)	0.3885 (5)	0.0503 (2)	0.0339 (11)
C20	0.17987 (13)	0.2677 (5)	0.0376 (2)	0.0398 (12)
H20	0.159550	0.282526	0.028564	0.048*
C21	0.19088 (16)	0.1249 (7)	0.0382 (3)	0.0596 (18)
H21	0.178264	0.042909	0.029335	0.071*
C22	0.22051 (19)	0.1063 (7)	0.0519 (4)	0.074 (2)
H22	0.228237	0.010132	0.052558	0.089*
C23	0.23914 (15)	0.2243 (8)	0.0646 (3)	0.0610 (19)
H23	0.259449	0.209139	0.073495	0.073*
C24	0.22796 (13)	0.3664 (7)	0.0644 (3)	0.0454 (13)
H24	0.240714	0.447647	0.074062	0.054*
C25	0.19205 (10)	0.7018 (5)	−0.0260 (2)	0.0296 (10)
C26	0.21692 (14)	0.6580 (8)	−0.0415 (3)	0.0564 (17)
H26	0.228689	0.583115	−0.019206	0.068*
C27	0.22468 (14)	0.7237 (9)	−0.0897 (3)	0.0628 (19)
H27	0.242017	0.694453	−0.099821	0.075*
C28	0.20786 (15)	0.8293 (7)	−0.1229 (3)	0.0537 (16)
H28	0.213614	0.875525	−0.155249	0.064*
C29	0.18223 (19)	0.8685 (9)	−0.1089 (3)	0.073 (2)
H29	0.169940	0.939138	−0.132870	0.088*
C30	0.17436 (15)	0.8053 (7)	−0.0601 (3)	0.0571 (17)
H30	0.156880	0.833491	−0.050383	0.068*
C31	0.20271 (10)	0.6711 (6)	0.1384 (2)	0.0324 (10)
C32	0.21543 (12)	0.5654 (7)	0.1800 (2)	0.0436 (13)
H32	0.215506	0.465302	0.168523	0.052*
C33	0.22812 (15)	0.6083 (9)	0.2390 (3)	0.0637 (19)
H33	0.237072	0.537143	0.267874	0.076*
C34	0.22770 (15)	0.7527 (10)	0.2555 (3)	0.071 (2)
H34	0.236135	0.780978	0.295823	0.085*
C35	0.21508 (13)	0.8571 (8)	0.2136 (3)	0.0560 (16)
H35	0.215294	0.957248	0.225207	0.067*
C36	0.20219 (12)	0.8174 (6)	0.1554 (3)	0.0425 (13)
H36	0.193028	0.889105	0.127008	0.051*
C37	0.13421 (11)	0.7432 (5)	0.2576 (2)	0.0302 (10)
C38	0.15596 (16)	0.6418 (7)	0.2671 (3)	0.0572 (18)
H38	0.162176	0.601976	0.234131	0.069*
C39	0.1691 (2)	0.5966 (8)	0.3264 (3)	0.079 (3)
H39	0.183498	0.522309	0.332976	0.095*
C40	0.16135 (16)	0.6588 (8)	0.3746 (3)	0.0568 (17)
H40	0.170279	0.628873	0.414496	0.068*
C41	0.14045 (14)	0.7650 (7)	0.3639 (2)	0.0484 (14)
H41	0.135249	0.810505	0.397014	0.058*
C42	0.12681 (13)	0.8076 (6)	0.3065 (2)	0.0428 (13)
H42	0.112290	0.881184	0.300325	0.051*
C43	0.12967 (10)	1.0318 (5)	0.1727 (2)	0.0273 (9)
C44	0.15430 (12)	1.0674 (5)	0.2163 (3)	0.0393 (12)
H44	0.163334	0.996960	0.245419	0.047*
C45	0.16574 (14)	1.2099 (6)	0.2169 (3)	0.0506 (15)
H45	0.183074	1.235275	0.245520	0.061*
C46	0.15185 (13)	1.3118 (6)	0.1761 (3)	0.0442 (13)
H46	0.160002	1.406821	0.176095	0.053*
C47	0.12629 (14)	1.2793 (5)	0.1352 (2)	0.0421 (13)
H47	0.116082	1.353112	0.109215	0.050*
C48	0.11567 (12)	1.1371 (5)	0.1323 (2)	0.0341 (11)
H48	0.098727	1.111817	0.102554	0.041*
C49	0.06918 (10)	0.8064 (5)	0.1725 (2)	0.0313 (10)
C50	0.04935 (12)	0.9103 (6)	0.1435 (3)	0.0455 (13)
H50	0.055228	0.985429	0.120348	0.055*
C51	0.02094 (13)	0.9043 (8)	0.1483 (3)	0.0571 (17)
H51	0.007406	0.975992	0.128787	0.069*
C52	0.01240 (14)	0.7942 (9)	0.1813 (3)	0.0604 (19)
H52	−0.006883	0.791890	0.185752	0.072*
C53	0.03177 (14)	0.6876 (8)	0.2080 (3)	0.0540 (17)
H53	0.025482	0.608218	0.228399	0.065*
C54	0.06031 (13)	0.6957 (6)	0.2051 (2)	0.0416 (12)
H54	0.073856	0.625189	0.225552	0.050*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Te1	0.02428 (14)	0.01463 (12)	0.02401 (14)	0.00024 (9)	0.00627 (11)	0.00027 (9)
Sb1	0.02552 (14)	0.01608 (13)	0.02517 (15)	0.00021 (10)	0.00482 (11)	0.00089 (10)
Sb2	0.02550 (15)	0.02110 (14)	0.02942 (16)	0.00203 (10)	0.00803 (12)	0.00078 (11)
Sb3	0.02859 (15)	0.01667 (13)	0.02517 (15)	−0.00063 (10)	0.00892 (11)	0.00024 (10)
O1	0.0306 (16)	0.0175 (13)	0.0268 (15)	−0.0019 (12)	0.0061 (12)	0.0028 (12)
O2	0.0329 (16)	0.0194 (14)	0.0204 (14)	−0.0021 (12)	0.0070 (12)	0.0023 (11)
O3	0.0292 (16)	0.0177 (14)	0.0353 (17)	0.0009 (12)	0.0088 (13)	−0.0024 (12)
O4	0.0295 (16)	0.0148 (13)	0.0338 (17)	−0.0025 (12)	0.0084 (13)	−0.0003 (12)
O5	0.0320 (16)	0.0166 (13)	0.0258 (15)	0.0045 (12)	0.0104 (13)	−0.0015 (11)
O6	0.0323 (17)	0.0184 (14)	0.0259 (15)	0.0011 (12)	0.0068 (13)	−0.0033 (12)
C1	0.030 (2)	0.023 (2)	0.032 (2)	0.0038 (18)	0.0075 (19)	0.0069 (18)
C2	0.042 (3)	0.036 (3)	0.069 (4)	0.005 (2)	0.019 (3)	−0.013 (3)
C3	0.054 (4)	0.049 (3)	0.078 (5)	0.017 (3)	0.031 (3)	−0.002 (3)
C4	0.037 (3)	0.065 (4)	0.061 (4)	0.015 (3)	0.023 (3)	0.020 (3)
C5	0.029 (3)	0.068 (4)	0.050 (3)	−0.006 (3)	0.009 (2)	0.008 (3)
C6	0.032 (3)	0.047 (3)	0.038 (3)	−0.006 (2)	0.008 (2)	−0.003 (2)
C7	0.037 (3)	0.026 (2)	0.020 (2)	−0.0048 (18)	0.0071 (18)	0.0057 (17)
C8	0.045 (3)	0.075 (4)	0.048 (3)	0.000 (3)	0.002 (3)	0.030 (3)
C9	0.056 (4)	0.108 (6)	0.051 (4)	−0.005 (4)	−0.003 (3)	0.042 (4)
C10	0.078 (5)	0.076 (5)	0.039 (3)	−0.011 (4)	0.010 (3)	0.023 (3)
C11	0.063 (4)	0.064 (4)	0.043 (3)	−0.006 (3)	0.028 (3)	0.007 (3)
C12	0.049 (3)	0.055 (3)	0.034 (3)	0.007 (3)	0.015 (2)	0.010 (3)
C13	0.030 (2)	0.0191 (19)	0.027 (2)	0.0001 (16)	0.0080 (18)	−0.0004 (17)
C14	0.035 (3)	0.023 (2)	0.039 (3)	0.0023 (19)	0.003 (2)	−0.0012 (19)
C15	0.049 (3)	0.025 (2)	0.037 (3)	−0.001 (2)	0.003 (2)	−0.006 (2)
C16	0.060 (3)	0.017 (2)	0.052 (3)	0.001 (2)	0.020 (3)	−0.003 (2)
C17	0.064 (4)	0.023 (2)	0.031 (3)	0.011 (2)	0.014 (2)	0.0077 (19)
C18	0.050 (3)	0.026 (2)	0.029 (2)	0.006 (2)	0.011 (2)	0.0035 (19)
C19	0.043 (3)	0.025 (2)	0.039 (3)	0.014 (2)	0.020 (2)	0.0072 (19)
C20	0.050 (3)	0.026 (2)	0.047 (3)	0.011 (2)	0.020 (2)	0.006 (2)
C21	0.077 (5)	0.028 (3)	0.081 (5)	0.020 (3)	0.032 (4)	0.008 (3)
C22	0.099 (6)	0.036 (3)	0.102 (6)	0.032 (4)	0.053 (5)	0.025 (4)
C23	0.055 (4)	0.066 (4)	0.072 (4)	0.037 (3)	0.035 (3)	0.022 (4)
C24	0.045 (3)	0.047 (3)	0.048 (3)	0.019 (3)	0.016 (3)	0.006 (3)
C25	0.031 (2)	0.029 (2)	0.031 (2)	−0.0031 (18)	0.0125 (19)	−0.0010 (18)
C26	0.046 (3)	0.075 (4)	0.057 (4)	0.023 (3)	0.030 (3)	0.027 (3)
C27	0.042 (3)	0.097 (5)	0.056 (4)	0.010 (3)	0.024 (3)	0.025 (4)
C28	0.058 (4)	0.064 (4)	0.046 (3)	−0.010 (3)	0.026 (3)	0.007 (3)
C29	0.095 (6)	0.082 (5)	0.054 (4)	0.036 (5)	0.043 (4)	0.034 (4)
C30	0.063 (4)	0.059 (4)	0.058 (4)	0.025 (3)	0.032 (3)	0.024 (3)
C31	0.023 (2)	0.043 (3)	0.028 (2)	−0.0029 (19)	0.0010 (18)	−0.004 (2)
C32	0.041 (3)	0.053 (3)	0.034 (3)	0.010 (2)	0.003 (2)	0.004 (2)
C33	0.058 (4)	0.091 (5)	0.034 (3)	0.020 (4)	−0.005 (3)	0.005 (3)
C34	0.051 (4)	0.105 (6)	0.045 (4)	0.005 (4)	−0.009 (3)	−0.027 (4)
C35	0.039 (3)	0.066 (4)	0.057 (4)	−0.004 (3)	0.000 (3)	−0.023 (3)
C36	0.033 (3)	0.042 (3)	0.051 (3)	−0.006 (2)	0.007 (2)	−0.012 (2)
C37	0.039 (3)	0.027 (2)	0.022 (2)	−0.0041 (19)	0.0024 (19)	0.0011 (17)
C38	0.080 (5)	0.051 (3)	0.029 (3)	0.032 (3)	−0.007 (3)	−0.005 (2)
C39	0.113 (7)	0.065 (5)	0.046 (4)	0.048 (5)	−0.009 (4)	0.000 (3)
C40	0.077 (5)	0.057 (4)	0.032 (3)	0.004 (3)	0.005 (3)	0.010 (3)
C41	0.056 (4)	0.059 (4)	0.030 (3)	0.002 (3)	0.010 (2)	0.000 (3)
C42	0.046 (3)	0.051 (3)	0.033 (3)	0.005 (3)	0.012 (2)	0.000 (2)
C43	0.033 (2)	0.019 (2)	0.032 (2)	−0.0050 (17)	0.0105 (19)	−0.0021 (17)
C44	0.040 (3)	0.025 (2)	0.048 (3)	−0.004 (2)	0.002 (2)	0.003 (2)
C45	0.052 (3)	0.034 (3)	0.056 (4)	−0.013 (2)	−0.006 (3)	0.002 (3)
C46	0.057 (4)	0.029 (3)	0.046 (3)	−0.015 (2)	0.011 (3)	−0.001 (2)
C47	0.071 (4)	0.023 (2)	0.031 (3)	−0.007 (2)	0.010 (2)	0.0050 (19)
C48	0.049 (3)	0.021 (2)	0.032 (2)	−0.001 (2)	0.009 (2)	0.0022 (18)
C49	0.029 (2)	0.032 (2)	0.034 (2)	−0.0050 (18)	0.0103 (19)	−0.0072 (19)
C50	0.040 (3)	0.045 (3)	0.055 (3)	0.009 (2)	0.017 (3)	0.008 (3)
C51	0.037 (3)	0.072 (4)	0.063 (4)	0.010 (3)	0.013 (3)	−0.010 (3)
C52	0.038 (3)	0.103 (6)	0.043 (3)	−0.024 (4)	0.016 (3)	−0.023 (4)
C53	0.046 (3)	0.079 (5)	0.039 (3)	−0.028 (3)	0.013 (3)	−0.001 (3)
C54	0.045 (3)	0.048 (3)	0.033 (3)	−0.009 (2)	0.010 (2)	0.003 (2)

Geometric parameters (Å, º) top

Te1—O2	1.904 (3)	C22—C23	1.380 (11)
Te1—O5	1.904 (3)	C22—H22	0.9500
Te1—O4	1.918 (3)	C23—C24	1.401 (8)
Te1—O1	1.949 (3)	C23—H23	0.9500
Te1—O6	1.964 (3)	C24—H24	0.9500
Te1—O3	1.968 (3)	C25—C30	1.376 (7)
Sb1—O1	1.992 (3)	C25—C26	1.378 (8)
Sb1—O2	2.091 (3)	C26—C27	1.386 (9)
Sb1—C1	2.110 (5)	C26—H26	0.9500
Sb1—C13	2.128 (4)	C27—C28	1.361 (9)
Sb1—C7	2.175 (4)	C27—H27	0.9500
Sb2—O3	1.966 (3)	C28—C29	1.385 (10)
Sb2—O4	2.087 (3)	C28—H28	0.9500
Sb2—C25	2.136 (5)	C29—C30	1.390 (9)
Sb2—C31	2.147 (5)	C29—H29	0.9500
Sb2—C19	2.170 (4)	C30—H30	0.9500
Sb3—O6	1.967 (3)	C31—C32	1.387 (7)
Sb3—O5	2.110 (3)	C31—C36	1.392 (7)
Sb3—C49	2.112 (5)	C32—C33	1.397 (8)
Sb3—C43	2.122 (4)	C32—H32	0.9500
Sb3—C37	2.165 (4)	C33—C34	1.371 (11)
C1—C6	1.381 (7)	C33—H33	0.9500
C1—C2	1.399 (7)	C34—C35	1.381 (11)
C2—C3	1.378 (8)	C34—H34	0.9500
C2—H2	0.9500	C35—C36	1.376 (8)
C3—C4	1.398 (10)	C35—H35	0.9500
C3—H3	0.9500	C36—H36	0.9500
C4—C5	1.379 (9)	C37—C38	1.367 (8)
C4—H4	0.9500	C37—C42	1.385 (7)
C5—C6	1.396 (8)	C38—C39	1.412 (8)
C5—H5	0.9500	C38—H38	0.9500
C6—H6	0.9500	C39—C40	1.371 (10)
C7—C8	1.377 (7)	C39—H39	0.9500
C7—C12	1.380 (8)	C40—C41	1.368 (9)
C8—C9	1.396 (9)	C40—H40	0.9500
C8—H8	0.9500	C41—C42	1.374 (8)
C9—C10	1.371 (11)	C41—H41	0.9500
C9—H9	0.9500	C42—H42	0.9500
C10—C11	1.387 (10)	C43—C44	1.383 (7)
C10—H10	0.9500	C43—C48	1.387 (7)
C11—C12	1.371 (8)	C44—C45	1.408 (7)
C11—H11	0.9500	C44—H44	0.9500
C12—H12	0.9500	C45—C46	1.368 (8)
C13—C18	1.386 (6)	C45—H45	0.9500
C13—C14	1.387 (7)	C46—C47	1.377 (8)
C14—C15	1.394 (7)	C46—H46	0.9500
C14—H14	0.9500	C47—C48	1.387 (7)
C15—C16	1.391 (7)	C47—H47	0.9500
C15—H15	0.9500	C48—H48	0.9500
C16—C17	1.377 (8)	C49—C54	1.382 (7)
C16—H16	0.9500	C49—C50	1.388 (7)
C17—C18	1.388 (7)	C50—C51	1.387 (8)
C17—H17	0.9500	C50—H50	0.9500
C18—H18	0.9500	C51—C52	1.379 (10)
C19—C24	1.382 (8)	C51—H51	0.9500
C19—C20	1.398 (8)	C52—C53	1.377 (10)
C20—C21	1.403 (7)	C52—H52	0.9500
C20—H20	0.9500	C53—C54	1.382 (8)
C21—C22	1.381 (11)	C53—H53	0.9500
C21—H21	0.9500	C54—H54	0.9500

O2—Te1—O5	97.67 (13)	C20—C19—Sb2	118.9 (4)
O2—Te1—O4	166.37 (13)	C19—C20—C21	120.8 (6)
O5—Te1—O4	94.67 (13)	C19—C20—H20	119.6
O2—Te1—O1	81.53 (12)	C21—C20—H20	119.6
O5—Te1—O1	95.83 (13)	C22—C21—C20	118.4 (7)
O4—Te1—O1	91.49 (13)	C22—C21—H21	120.8
O2—Te1—O6	94.01 (13)	C20—C21—H21	120.8
O5—Te1—O6	81.51 (12)	C23—C22—C21	121.5 (6)
O4—Te1—O6	93.53 (13)	C23—C22—H22	119.2
O1—Te1—O6	174.49 (13)	C21—C22—H22	119.2
O2—Te1—O3	88.47 (13)	C22—C23—C24	119.7 (6)
O5—Te1—O3	168.81 (13)	C22—C23—H23	120.2
O4—Te1—O3	80.35 (12)	C24—C23—H23	120.2
O1—Te1—O3	94.32 (13)	C19—C24—C23	120.1 (6)
O6—Te1—O3	88.77 (13)	C19—C24—H24	119.9
O1—Sb1—O2	76.01 (12)	C23—C24—H24	119.9
O1—Sb1—C1	119.50 (15)	C30—C25—C26	119.9 (5)
O2—Sb1—C1	91.35 (15)	C30—C25—Sb2	119.3 (4)
O1—Sb1—C13	124.71 (15)	C26—C25—Sb2	120.7 (4)
O2—Sb1—C13	91.45 (14)	C25—C26—C27	119.7 (6)
C1—Sb1—C13	114.34 (17)	C25—C26—H26	120.1
O1—Sb1—C7	85.22 (15)	C27—C26—H26	120.1
O2—Sb1—C7	161.09 (15)	C28—C27—C26	121.1 (6)
C1—Sb1—C7	99.99 (18)	C28—C27—H27	119.5
C13—Sb1—C7	97.49 (17)	C26—C27—H27	119.5
O3—Sb2—O4	76.38 (12)	C27—C28—C29	119.1 (6)
O3—Sb2—C25	118.46 (16)	C27—C28—H28	120.4
O4—Sb2—C25	88.80 (15)	C29—C28—H28	120.4
O3—Sb2—C31	119.67 (17)	C28—C29—C30	120.5 (6)
O4—Sb2—C31	87.58 (16)	C28—C29—H29	119.7
C25—Sb2—C31	118.87 (19)	C30—C29—H29	119.7
O3—Sb2—C19	88.62 (17)	C25—C30—C29	119.6 (6)
O4—Sb2—C19	164.73 (16)	C25—C30—H30	120.2
C25—Sb2—C19	101.04 (18)	C29—C30—H30	120.2
C31—Sb2—C19	97.6 (2)	C32—C31—C36	120.5 (5)
O6—Sb3—O5	76.45 (12)	C32—C31—Sb2	119.8 (4)
O6—Sb3—C49	116.47 (16)	C36—C31—Sb2	119.4 (4)
O5—Sb3—C49	89.13 (16)	C31—C32—C33	119.0 (6)
O6—Sb3—C43	126.74 (16)	C31—C32—H32	120.5
O5—Sb3—C43	87.41 (15)	C33—C32—H32	120.5
C49—Sb3—C43	113.58 (18)	C34—C33—C32	120.2 (6)
O6—Sb3—C37	89.39 (16)	C34—C33—H33	119.9
O5—Sb3—C37	165.43 (16)	C32—C33—H33	119.9
C49—Sb3—C37	100.46 (19)	C33—C34—C35	120.3 (6)
C43—Sb3—C37	98.58 (17)	C33—C34—H34	119.9
Te1—O1—Sb1	102.08 (13)	C35—C34—H34	119.9
Te1—O2—Sb1	100.07 (13)	C36—C35—C34	120.5 (6)
Sb2—O3—Te1	102.41 (13)	C36—C35—H35	119.7
Te1—O4—Sb2	99.85 (12)	C34—C35—H35	119.7
Te1—O5—Sb3	99.33 (13)	C35—C36—C31	119.4 (6)
Te1—O6—Sb3	102.36 (14)	C35—C36—H36	120.3
C6—C1—C2	119.8 (5)	C31—C36—H36	120.3
C6—C1—Sb1	119.3 (4)	C38—C37—C42	119.4 (5)
C2—C1—Sb1	120.8 (4)	C38—C37—Sb3	121.4 (4)
C3—C2—C1	119.4 (6)	C42—C37—Sb3	119.1 (4)
C3—C2—H2	120.3	C37—C38—C39	119.5 (6)
C1—C2—H2	120.3	C37—C38—H38	120.3
C2—C3—C4	121.2 (6)	C39—C38—H38	120.3
C2—C3—H3	119.4	C40—C39—C38	120.8 (6)
C4—C3—H3	119.4	C40—C39—H39	119.6
C5—C4—C3	118.7 (6)	C38—C39—H39	119.6
C5—C4—H4	120.7	C41—C40—C39	118.5 (5)
C3—C4—H4	120.7	C41—C40—H40	120.8
C4—C5—C6	120.8 (5)	C39—C40—H40	120.8
C4—C5—H5	119.6	C40—C41—C42	121.7 (6)
C6—C5—H5	119.6	C40—C41—H41	119.2
C1—C6—C5	119.9 (5)	C42—C41—H41	119.2
C1—C6—H6	120.0	C41—C42—C37	120.0 (5)
C5—C6—H6	120.0	C41—C42—H42	120.0
C8—C7—C12	120.1 (5)	C37—C42—H42	120.0
C8—C7—Sb1	121.5 (4)	C44—C43—C48	120.4 (4)
C12—C7—Sb1	118.3 (4)	C44—C43—Sb3	120.0 (3)
C7—C8—C9	119.2 (6)	C48—C43—Sb3	119.6 (3)
C7—C8—H8	120.4	C43—C44—C45	118.8 (5)
C9—C8—H8	120.4	C43—C44—H44	120.6
C10—C9—C8	121.0 (6)	C45—C44—H44	120.6
C10—C9—H9	119.5	C46—C45—C44	119.9 (5)
C8—C9—H9	119.5	C46—C45—H45	120.1
C9—C10—C11	118.8 (6)	C44—C45—H45	120.1
C9—C10—H10	120.6	C45—C46—C47	121.3 (5)
C11—C10—H10	120.6	C45—C46—H46	119.3
C12—C11—C10	120.8 (6)	C47—C46—H46	119.3
C12—C11—H11	119.6	C46—C47—C48	119.0 (5)
C10—C11—H11	119.6	C46—C47—H47	120.5
C11—C12—C7	120.2 (5)	C48—C47—H47	120.5
C11—C12—H12	119.9	C43—C48—C47	120.3 (5)
C7—C12—H12	119.9	C43—C48—H48	119.8
C18—C13—C14	119.7 (4)	C47—C48—H48	119.8
C18—C13—Sb1	122.0 (3)	C54—C49—C50	119.6 (5)
C14—C13—Sb1	118.3 (3)	C54—C49—Sb3	119.5 (4)
C13—C14—C15	120.6 (4)	C50—C49—Sb3	120.9 (4)
C13—C14—H14	119.7	C51—C50—C49	120.0 (6)
C15—C14—H14	119.7	C51—C50—H50	120.0
C16—C15—C14	118.9 (5)	C49—C50—H50	120.0
C16—C15—H15	120.5	C52—C51—C50	119.9 (6)
C14—C15—H15	120.5	C52—C51—H51	120.1
C17—C16—C15	120.7 (4)	C50—C51—H51	120.1
C17—C16—H16	119.7	C53—C52—C51	120.1 (6)
C15—C16—H16	119.7	C53—C52—H52	120.0
C16—C17—C18	120.1 (5)	C51—C52—H52	120.0
C16—C17—H17	120.0	C52—C53—C54	120.3 (6)
C18—C17—H17	120.0	C52—C53—H53	119.9
C13—C18—C17	120.0 (5)	C54—C53—H53	119.9
C13—C18—H18	120.0	C53—C54—C49	120.0 (6)
C17—C18—H18	120.0	C53—C54—H54	120.0
C24—C19—C20	119.4 (5)	C49—C54—H54	120.0
C24—C19—Sb2	121.6 (4)

C6—C1—C2—C3	−1.9 (9)	C27—C28—C29—C30	2.7 (12)
Sb1—C1—C2—C3	179.8 (5)	C26—C25—C30—C29	−2.1 (10)
C1—C2—C3—C4	2.1 (10)	Sb2—C25—C30—C29	179.6 (6)
C2—C3—C4—C5	−1.4 (10)	C28—C29—C30—C25	−0.8 (12)
C3—C4—C5—C6	0.5 (9)	C36—C31—C32—C33	−1.0 (9)
C2—C1—C6—C5	1.1 (8)	Sb2—C31—C32—C33	−174.9 (5)
Sb1—C1—C6—C5	179.4 (4)	C31—C32—C33—C34	0.6 (10)
C4—C5—C6—C1	−0.3 (9)	C32—C33—C34—C35	−0.9 (12)
C12—C7—C8—C9	1.5 (10)	C33—C34—C35—C36	1.5 (11)
Sb1—C7—C8—C9	177.5 (6)	C34—C35—C36—C31	−1.9 (10)
C7—C8—C9—C10	−0.4 (12)	C32—C31—C36—C35	1.6 (9)
C8—C9—C10—C11	−0.8 (13)	Sb2—C31—C36—C35	175.5 (5)
C9—C10—C11—C12	0.9 (11)	C42—C37—C38—C39	4.5 (10)
C10—C11—C12—C7	0.3 (10)	Sb3—C37—C38—C39	−179.4 (6)
C8—C7—C12—C11	−1.5 (9)	C37—C38—C39—C40	−3.4 (13)
Sb1—C7—C12—C11	−177.5 (5)	C38—C39—C40—C41	0.4 (13)
C18—C13—C14—C15	0.9 (8)	C39—C40—C41—C42	1.5 (11)
Sb1—C13—C14—C15	−176.5 (4)	C40—C41—C42—C37	−0.4 (10)
C13—C14—C15—C16	−0.9 (8)	C38—C37—C42—C41	−2.7 (9)
C14—C15—C16—C17	−0.1 (9)	Sb3—C37—C42—C41	−178.9 (5)
C15—C16—C17—C18	1.2 (9)	C48—C43—C44—C45	−3.4 (8)
C14—C13—C18—C17	0.2 (8)	Sb3—C43—C44—C45	177.3 (5)
Sb1—C13—C18—C17	177.5 (4)	C43—C44—C45—C46	2.5 (10)
C16—C17—C18—C13	−1.2 (9)	C44—C45—C46—C47	1.7 (10)
C24—C19—C20—C21	−1.1 (8)	C45—C46—C47—C48	−5.0 (10)
Sb2—C19—C20—C21	−179.5 (5)	C44—C43—C48—C47	0.2 (8)
C19—C20—C21—C22	0.4 (10)	Sb3—C43—C48—C47	179.5 (4)
C20—C21—C22—C23	−0.2 (12)	C46—C47—C48—C43	4.0 (9)
C21—C22—C23—C24	0.7 (12)	C54—C49—C50—C51	1.3 (9)
C20—C19—C24—C23	1.5 (9)	Sb3—C49—C50—C51	−178.4 (5)
Sb2—C19—C24—C23	180.0 (4)	C49—C50—C51—C52	−0.7 (10)
C22—C23—C24—C19	−1.4 (10)	C50—C51—C52—C53	−2.1 (10)
C30—C25—C26—C27	3.1 (10)	C51—C52—C53—C54	4.3 (9)
Sb2—C25—C26—C27	−178.6 (6)	C52—C53—C54—C49	−3.7 (9)
C25—C26—C27—C28	−1.2 (12)	C50—C49—C54—C53	0.9 (8)
C26—C27—C28—C29	−1.7 (12)	Sb3—C49—C54—C53	−179.3 (4)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C16—H16···O1ⁱ	0.95	2.58	3.342 (6)	137
C17—H17···O5ⁱ	0.95	2.58	3.437 (6)	150
C21—H21···O4ⁱ	0.95	2.75	3.651 (8)	158
C46—H46···O6ⁱⁱ	0.95	2.67	3.276 (6)	122
C47—H47···O6ⁱⁱ	0.95	2.73	3.307 (6)	120
C47—H47···O2ⁱⁱ	0.95	2.70	3.645 (6)	177

Symmetry codes: (i) x, y−1, z; (ii) x, y+1, z.

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Tris[tri­phenyl­anti­mony(V)]hexa(μ-oxido)­tellurium(VI): a mol­ecular complex with six Te—O—Sb bridges

Supporting information

Key indicators

checkCIF/PLATON results

Tris[triphenylantimony(V)]hexa(μ-oxido)tellurium(VI): a molecular complex with six Te—O—Sb bridges