Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ²P,P′]ruthenium(II)

In the title compound, [RuCl₂(C₁₆H₃₂P₂)₂], the Ru^II ion is situated on a twofold rotation axis, so the asymmetric unit contains one half-mol­ecule. The slightly distorted octa­hedral environment of the Ru center is formed by four P atoms [Ru—P = 2.4417 (6) and 2.4544 (6) Å] from two different (1S,1S′,2R,2R′)-TangPhos ligands [(1S,1S′,2R,2R′)-TangPhos = (1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane] and two Cl atoms [Ru—Cl = 2.4267 (5) Å].

Key indicators

• Single-crystal X-ray study
• T = 108 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.024
• wR factor = 0.058
• Data-to-parameter ratio = 22.8

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.88
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.82 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.62 Ratio
PLAT850_ALERT_2_C Check Flack Parameter Exact Value 0.00 and su ..       0.02

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           28.29
           From the CIF: _reflns_number_total               4164
           Count of symmetry unique reflns         2406
           Completeness (_total/calc)            173.07%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      1758
           Fraction of Friedel pairs measured     0.731
           Are heavy atom types Z>Si present        yes
PLAT791_ALERT_1_G Confirm the Absolute Configuration of C8     ...          R
PLAT791_ALERT_1_G Confirm the Absolute Configuration of C9     ...          R

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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S1. Comment

Recently, some chiral diphosphino ruthenium complexes have been synthesized and used as catalysts for the asymmetric reactions (Stoop et al., 1999; James et al., 1993). Herein, we report the synthesis and crystal structure of the title compound - the ruthenium(II) complex containing the chiral TangPhos ligand.

As shown in Fig. 1, the crystals of the title complex contain discrete [RuCl₂(TangPhos)₂] units with the metal center in a slightly distorted octahedral environment. The trans-axial positions of Ru^II environment are occupied by Cl1 and Cl1ⁱ atoms, and the equatorial positions are occupied by P1, P2, P1ⁱ, P2ⁱ atoms, respectively [symmetry code: (i) -x, y, -z + 1/2], from two different TangPhos ligands, resulting in two chelate rings, which assume a half-chair conformation with the tert-butyl in the less hindered equatorial positions. Similar conformations were found in previously reported related structures (Stoop et al., 1999; Ikariya et al., 1985).

Related literature

For related literature, see: Ikariya et al. (1985); James & Fogg (1993); Stoop et al. (1999).

S2. Experimental

To a solution of [RuCl₂(PPh)₃] (96 mg, 0.1 mmol) in 2 ml of deoxygenated CH₂Cl₂ was added dropwise a solution of (1S,1S',2R,2R')-TangPhos, (56 mg, 0.2 mmol) in CH₂Cl₂ (1 ml). The resulting mixture was stirred at ambient temperature for 6 h. Deoxygenated ether (12 ml) was added into the vigorously stirring solution and kept for 6 h at room temperature. The resulting light brown precipitate was filtered, washed with ether (3 times with 10 ml), and dried under vacuum. Yield: 45 mg (56%). Crystals suitable for X-ray diffraction were obtained by diffusion of hexane into a CD₂Cl₂ solution of the above compound at room temperature.

S3. Refinement

All H atoms were positioned geometrically (C—H 0.98–1.00 Å), and treated as riding, with U_iso(H) = 1.2–1.5U_eq (C).

Computing details

Data collection: SMART (Bruker, 1997); cell refinement: SMART (Bruker, 1997); data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures

Fig. 1. View of the title compound with the atomic numbering and 40% probability displacement ellipsoids [symmetry code: (i) -x, y, -z + 1/2]. H atoms are omitted for clarity.

Dichloridobis[(1S,1S',2R,2R')-(+)-1,1'-di-tert-butyl-2,2'- diphospholane-κ²P,P']ruthenium(II)

Crystal data

[RuCl2(C16H32P2)2]	F(000) = 1576
Mr = 744.72	Dx = 1.418 Mg m^−3
Orthorhombic, C2221	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: C 2c 2	Cell parameters from 5992 reflections
a = 11.8640 (14) Å	θ = 2.4–28.2°
b = 20.669 (3) Å	µ = 0.81 mm^−1
c = 14.2274 (17) Å	T = 108 K
V = 3488.8 (8) Å^3	Brick, orange
Z = 4	0.24 × 0.15 × 0.10 mm

Data collection

Bruker SMART CCD area-detector diffractometer	4164 independent reflections
Radiation source: fine-focus sealed tube	4018 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.025
phi and ω scans	θmax = 28.3°, θmin = 2.0°
Absorption correction: multi-scan (SADABS; Bruker, 2001)	h = −14→15
Tmin = 0.863, Tmax = 0.921	k = −17→27
11542 measured reflections	l = −18→18

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.024	H-atom parameters not refined
wR(F^2) = 0.057	w = 1/[σ^2(Fo^2) + (0.0315P)^2 + 0.2939P] where P = (Fo^2 + 2Fc^2)/3
S = 1.06	(Δ/σ)max = 0.003
4164 reflections	Δρmax = 0.83 e Å^−3
183 parameters	Δρmin = −0.29 e Å^−3
0 restraints	Absolute structure: Flack (1983), 1750 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.00 (2)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.02414 (19)	0.16346 (11)	−0.00952 (15)	0.0256 (5)
H1A	−0.0059	0.1290	−0.0497	0.038*
H1B	0.0806	0.1883	−0.0445	0.038*
H1C	−0.0373	0.1922	0.0098	0.038*
C2	−0.0038 (3)	0.08613 (11)	0.12059 (16)	0.0353 (6)
H2A	−0.0740	0.1086	0.1364	0.053*
H2B	0.0291	0.0677	0.1778	0.053*
H2C	−0.0198	0.0514	0.0756	0.053*
C3	0.1820 (2)	0.09489 (11)	0.04344 (16)	0.0257 (5)
H3A	0.2177	0.0737	0.0973	0.039*
H3B	0.2361	0.1243	0.0136	0.039*
H3C	0.1580	0.0621	−0.0021	0.039*
C4	0.07852 (18)	0.13369 (11)	0.07717 (15)	0.0188 (4)
C5	0.21860 (15)	0.15194 (10)	0.24348 (17)	0.0185 (4)
H5A	0.2097	0.1649	0.3100	0.022*
H5B	0.2031	0.1050	0.2384	0.022*
C6	0.33823 (17)	0.16652 (12)	0.21003 (18)	0.0262 (5)
H6A	0.3927	0.1616	0.2622	0.031*
H6B	0.3601	0.1369	0.1584	0.031*
C7	0.33514 (17)	0.23639 (12)	0.17560 (17)	0.0261 (5)
H7A	0.4066	0.2474	0.1434	0.031*
H7B	0.3250	0.2663	0.2293	0.031*
C8	0.23545 (18)	0.24229 (10)	0.10707 (15)	0.0179 (4)
H8	0.2549	0.2176	0.0489	0.021*
C9	0.20454 (18)	0.31083 (11)	0.07802 (15)	0.0185 (4)
H9	0.2760	0.3358	0.0695	0.022*
C10	0.13653 (19)	0.31551 (11)	−0.01378 (14)	0.0220 (5)
H10A	0.1839	0.3027	−0.0680	0.026*
H10B	0.0702	0.2865	−0.0112	0.026*
C11	0.09906 (19)	0.38550 (11)	−0.02376 (15)	0.0237 (5)
H11A	0.0465	0.3904	−0.0773	0.028*
H11B	0.1647	0.4142	−0.0338	0.028*
C12	0.04012 (19)	0.40157 (10)	0.06914 (15)	0.0203 (5)
H12A	−0.0402	0.3887	0.0663	0.024*
H12B	0.0442	0.4486	0.0817	0.024*
C13	0.2153 (2)	0.42001 (11)	0.21194 (17)	0.0261 (5)
C14	0.3123 (2)	0.39022 (14)	0.26745 (19)	0.0414 (7)
H14A	0.3582	0.4247	0.2951	0.062*
H14B	0.3590	0.3640	0.2253	0.062*
H14C	0.2819	0.3628	0.3176	0.062*
C15	0.2678 (2)	0.46048 (11)	0.13264 (17)	0.0291 (5)
H15A	0.2078	0.4806	0.0954	0.044*
H15B	0.3134	0.4324	0.0921	0.044*
H15C	0.3158	0.4943	0.1598	0.044*
C16	0.1502 (3)	0.46594 (13)	0.2754 (2)	0.0505 (9)
H16A	0.1180	0.4417	0.3281	0.076*
H16B	0.0895	0.4864	0.2394	0.076*
H16C	0.2013	0.4993	0.2995	0.076*
Cl1	−0.13351 (4)	0.27771 (3)	0.12078 (3)	0.01700 (10)
P1	0.11419 (5)	0.35562 (3)	0.16379 (4)	0.01581 (11)
P2	0.11916 (4)	0.19819 (3)	0.16823 (4)	0.01347 (11)
Ru1	0.0000	0.277275 (10)	0.2500	0.01108 (6)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.0294 (13)	0.0265 (11)	0.0207 (11)	0.0048 (10)	−0.0060 (9)	−0.0074 (9)
C2	0.0464 (14)	0.0316 (12)	0.0279 (12)	−0.0175 (14)	0.0162 (14)	−0.0125 (10)
C3	0.0352 (13)	0.0209 (11)	0.0209 (11)	0.0099 (10)	0.0033 (10)	−0.0011 (9)
C4	0.0241 (11)	0.0182 (10)	0.0142 (10)	0.0018 (9)	0.0029 (8)	−0.0020 (8)
C5	0.0201 (10)	0.0212 (9)	0.0141 (9)	0.0048 (8)	0.0021 (9)	0.0025 (10)
C6	0.0168 (11)	0.0359 (14)	0.0260 (11)	0.0088 (10)	0.0036 (9)	0.0107 (10)
C7	0.0132 (10)	0.0342 (15)	0.0310 (12)	−0.0006 (9)	0.0012 (9)	0.0117 (10)
C8	0.0166 (10)	0.0211 (11)	0.0159 (9)	0.0012 (8)	0.0046 (8)	0.0031 (8)
C9	0.0181 (10)	0.0208 (11)	0.0166 (10)	0.0011 (8)	0.0045 (8)	0.0041 (9)
C10	0.0285 (12)	0.0242 (12)	0.0133 (10)	0.0052 (10)	0.0058 (9)	0.0023 (8)
C11	0.0304 (13)	0.0240 (12)	0.0166 (11)	0.0015 (10)	0.0039 (9)	0.0061 (9)
C12	0.0247 (11)	0.0162 (10)	0.0199 (11)	0.0009 (9)	0.0015 (8)	0.0037 (9)
C13	0.0326 (13)	0.0224 (12)	0.0234 (11)	−0.0126 (10)	0.0024 (10)	−0.0004 (10)
C14	0.0485 (16)	0.0439 (15)	0.0317 (17)	−0.0285 (13)	−0.0166 (12)	0.0120 (12)
C15	0.0348 (13)	0.0212 (11)	0.0315 (13)	−0.0111 (11)	0.0056 (11)	0.0024 (10)
C16	0.0582 (19)	0.0429 (17)	0.050 (2)	−0.0304 (15)	0.0255 (15)	−0.0289 (14)
Cl1	0.0168 (2)	0.0205 (2)	0.0137 (2)	0.0003 (2)	−0.00355 (16)	0.0000 (2)
P1	0.0188 (3)	0.0144 (3)	0.0143 (3)	−0.0034 (2)	0.0013 (2)	0.0013 (2)
P2	0.0146 (3)	0.0147 (2)	0.0111 (2)	0.0011 (2)	0.0020 (2)	0.0013 (2)
Ru1	0.01224 (10)	0.01165 (10)	0.00935 (9)	0.000	0.00015 (8)	0.000

Geometric parameters (Å, º)

C1—C4	1.522 (3)	C10—C11	1.520 (3)
C1—H1A	0.9800	C10—H10A	0.9900
C1—H1B	0.9800	C10—H10B	0.9900
C1—H1C	0.9800	C11—C12	1.532 (3)
C2—C4	1.517 (3)	C11—H11A	0.9900
C2—H2A	0.9800	C11—H11B	0.9900
C2—H2B	0.9800	C12—P1	1.868 (2)
C2—H2C	0.9800	C12—H12A	0.9900
C3—C4	1.543 (3)	C12—H12B	0.9900
C3—H3A	0.9800	C13—C16	1.520 (4)
C3—H3B	0.9800	C13—C14	1.525 (3)
C3—H3C	0.9800	C13—C15	1.537 (3)
C4—P2	1.920 (2)	C13—P1	1.918 (2)
C5—C6	1.527 (3)	C14—H14A	0.9800
C5—P2	1.858 (2)	C14—H14B	0.9800
C5—H5A	0.9900	C14—H14C	0.9800
C5—H5B	0.9900	C15—H15A	0.9800
C6—C7	1.525 (3)	C15—H15B	0.9800
C6—H6A	0.9900	C15—H15C	0.9800
C6—H6B	0.9900	C16—H16A	0.9800
C7—C8	1.538 (3)	C16—H16B	0.9800
C7—H7A	0.9900	C16—H16C	0.9800
C7—H7B	0.9900	Cl1—Ru1	2.4267 (5)
C8—C9	1.521 (3)	P1—Ru1	2.4417 (6)
C8—P2	1.869 (2)	P2—Ru1	2.4544 (6)
C8—H8	1.0000	Ru1—Cl1^i	2.4267 (5)
C9—C10	1.538 (3)	Ru1—P1^i	2.4417 (6)
C9—P1	1.870 (2)	Ru1—P2^i	2.4544 (6)
C9—H9	1.0000
C4—C1—H1A	109.5	C12—C11—H11A	110.7
C4—C1—H1B	109.5	C10—C11—H11B	110.7
H1A—C1—H1B	109.5	C12—C11—H11B	110.7
C4—C1—H1C	109.5	H11A—C11—H11B	108.8
H1A—C1—H1C	109.5	C11—C12—P1	107.29 (15)
H1B—C1—H1C	109.5	C11—C12—H12A	110.3
C4—C2—H2A	109.5	P1—C12—H12A	110.3
C4—C2—H2B	109.5	C11—C12—H12B	110.3
H2A—C2—H2B	109.5	P1—C12—H12B	110.3
C4—C2—H2C	109.5	H12A—C12—H12B	108.5
H2A—C2—H2C	109.5	C16—C13—C14	109.1 (2)
H2B—C2—H2C	109.5	C16—C13—C15	107.6 (2)
C4—C3—H3A	109.5	C14—C13—C15	107.1 (2)
C4—C3—H3B	109.5	C16—C13—P1	109.12 (17)
H3A—C3—H3B	109.5	C14—C13—P1	112.12 (17)
C4—C3—H3C	109.5	C15—C13—P1	111.66 (16)
H3A—C3—H3C	109.5	C13—C14—H14A	109.5
H3B—C3—H3C	109.5	C13—C14—H14B	109.5
C2—C4—C1	108.6 (2)	H14A—C14—H14B	109.5
C2—C4—C3	107.60 (19)	C13—C14—H14C	109.5
C1—C4—C3	107.18 (17)	H14A—C14—H14C	109.5
C2—C4—P2	109.67 (14)	H14B—C14—H14C	109.5
C1—C4—P2	111.87 (15)	C13—C15—H15A	109.5
C3—C4—P2	111.76 (15)	C13—C15—H15B	109.5
C6—C5—P2	108.00 (15)	H15A—C15—H15B	109.5
C6—C5—H5A	110.1	C13—C15—H15C	109.5
P2—C5—H5A	110.1	H15A—C15—H15C	109.5
C6—C5—H5B	110.1	H15B—C15—H15C	109.5
P2—C5—H5B	110.1	C13—C16—H16A	109.5
H5A—C5—H5B	108.4	C13—C16—H16B	109.5
C7—C6—C5	105.35 (17)	H16A—C16—H16B	109.5
C7—C6—H6A	110.7	C13—C16—H16C	109.5
C5—C6—H6A	110.7	H16A—C16—H16C	109.5
C7—C6—H6B	110.7	H16B—C16—H16C	109.5
C5—C6—H6B	110.7	C12—P1—C9	92.92 (10)
H6A—C6—H6B	108.8	C12—P1—C13	101.48 (10)
C6—C7—C8	107.28 (19)	C9—P1—C13	102.59 (10)
C6—C7—H7A	110.3	C12—P1—Ru1	116.00 (7)
C8—C7—H7A	110.3	C9—P1—Ru1	108.52 (7)
C6—C7—H7B	110.3	C13—P1—Ru1	128.89 (8)
C8—C7—H7B	110.3	C5—P2—C8	92.89 (9)
H7A—C7—H7B	108.5	C5—P2—C4	101.01 (10)
C9—C8—C7	115.57 (18)	C8—P2—C4	102.11 (9)
C9—C8—P2	113.76 (15)	C5—P2—Ru1	115.80 (8)
C7—C8—P2	103.53 (14)	C8—P2—Ru1	108.73 (7)
C9—C8—H8	107.9	C4—P2—Ru1	129.60 (7)
C7—C8—H8	107.9	Cl1^i—Ru1—Cl1	179.58 (3)
P2—C8—H8	107.9	Cl1^i—Ru1—P1	90.913 (19)
C8—C9—C10	114.56 (18)	Cl1—Ru1—P1	88.806 (19)
C8—C9—P1	114.98 (15)	Cl1^i—Ru1—P1^i	88.806 (19)
C10—C9—P1	102.85 (14)	Cl1—Ru1—P1^i	90.913 (19)
C8—C9—H9	108.0	P1—Ru1—P1^i	96.91 (3)
C10—C9—H9	108.0	Cl1^i—Ru1—P2^i	91.107 (19)
P1—C9—H9	108.0	Cl1—Ru1—P2^i	89.175 (19)
C11—C10—C9	107.00 (18)	P1—Ru1—P2^i	177.969 (19)
C11—C10—H10A	110.3	P1^i—Ru1—P2^i	83.341 (18)
C9—C10—H10A	110.3	Cl1^i—Ru1—P2	89.175 (19)
C11—C10—H10B	110.3	Cl1—Ru1—P2	91.107 (19)
C9—C10—H10B	110.3	P1—Ru1—P2	83.341 (18)
H10A—C10—H10B	108.6	P1^i—Ru1—P2	177.969 (19)
C10—C11—C12	105.02 (17)	P2^i—Ru1—P2	96.48 (3)
C10—C11—H11A	110.7
P2—C5—C6—C7	33.0 (2)	C9—C8—P2—C4	110.84 (16)
C5—C6—C7—C8	−50.9 (2)	C7—C8—P2—C4	−122.93 (15)
C6—C7—C8—C9	169.48 (18)	C9—C8—P2—Ru1	−28.74 (16)
C6—C7—C8—P2	44.4 (2)	C7—C8—P2—Ru1	97.50 (14)
C7—C8—C9—C10	159.29 (18)	C2—C4—P2—C5	76.02 (19)
P2—C8—C9—C10	−81.1 (2)	C1—C4—P2—C5	−163.42 (15)
C7—C8—C9—P1	−81.9 (2)	C3—C4—P2—C5	−43.22 (17)
P2—C8—C9—P1	37.76 (19)	C2—C4—P2—C8	171.43 (17)
C8—C9—C10—C11	171.88 (18)	C1—C4—P2—C8	−68.01 (17)
P1—C9—C10—C11	46.39 (19)	C3—C4—P2—C8	52.19 (17)
C9—C10—C11—C12	−53.0 (2)	C2—C4—P2—Ru1	−61.4 (2)
C10—C11—C12—P1	33.8 (2)	C1—C4—P2—Ru1	59.14 (18)
C11—C12—P1—C9	−6.50 (16)	C3—C4—P2—Ru1	179.34 (11)
C11—C12—P1—C13	96.98 (16)	C12—P1—Ru1—Cl1^i	−160.02 (8)
C11—C12—P1—Ru1	−118.75 (14)	C9—P1—Ru1—Cl1^i	97.09 (7)
C8—C9—P1—C12	−147.28 (16)	C13—P1—Ru1—Cl1^i	−27.34 (10)
C10—C9—P1—C12	−22.07 (15)	C12—P1—Ru1—Cl1	19.66 (8)
C8—C9—P1—C13	110.27 (16)	C9—P1—Ru1—Cl1	−83.23 (7)
C10—C9—P1—C13	−124.52 (15)	C13—P1—Ru1—Cl1	152.34 (10)
C8—C9—P1—Ru1	−28.60 (16)	C12—P1—Ru1—P1^i	−71.11 (8)
C10—C9—P1—Ru1	96.61 (13)	C9—P1—Ru1—P1^i	−174.00 (8)
C16—C13—P1—C12	77.9 (2)	C13—P1—Ru1—P1^i	61.56 (10)
C14—C13—P1—C12	−161.05 (17)	C12—P1—Ru1—P2	110.92 (8)
C15—C13—P1—C12	−40.84 (19)	C9—P1—Ru1—P2	8.03 (7)
C16—C13—P1—C9	173.58 (18)	C13—P1—Ru1—P2	−116.41 (10)
C14—C13—P1—C9	−65.40 (19)	C5—P2—Ru1—Cl1^i	20.56 (7)
C15—C13—P1—C9	54.81 (19)	C8—P2—Ru1—Cl1^i	−82.33 (7)
C16—C13—P1—Ru1	−59.7 (2)	C4—P2—Ru1—Cl1^i	153.05 (9)
C14—C13—P1—Ru1	61.3 (2)	C5—P2—Ru1—Cl1	−159.76 (7)
C15—C13—P1—Ru1	−178.44 (13)	C8—P2—Ru1—Cl1	97.35 (7)
C6—C5—P2—C8	−6.72 (17)	C4—P2—Ru1—Cl1	−27.27 (9)
C6—C5—P2—C4	96.21 (17)	C8—P2—Ru1—P1	8.68 (7)
C6—C5—P2—Ru1	−119.15 (15)	C5—P2—Ru1—P2^i	−70.46 (7)
C9—C8—P2—C5	−147.25 (16)	C8—P2—Ru1—P2^i	−173.36 (8)
C7—C8—P2—C5	−21.02 (16)	C4—P2—Ru1—P2^i	62.03 (9)

Symmetry code: (i) −x, y, −z+1/2.