Acetatobis(2,2′-bipyridyl)­zinc(II) hexafluorophosphate monohydrate

Rodrigues, B.L.

doi:10.1107/S1600536804017489

Acetatobis(2,2'-bipyridyl)zinc(II) hexafluorophosphate monohydrate

The title compound, [Zn(C₂H₃O₂)(bipy)₂]PF₆·H₂O, where bipy is 2,2'-bipyridyl (C₁₀H₈N₂), crystallizes in the triclinic space group P $\overline 1$ with one independent molecule in a general position. The Zn atom is coordinated by one acetate and two bipyridine ligands in an approximate mm2 point-group symmetry. The two Zn-O bond distances are similar to each other, as are the Zn-N bond distances.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804017489/cv6342sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536804017489/cv6342Isup2.hkl Contains datablock I

CCDC reference: 248751

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.006 Å
R factor = 0.052
wR factor = 0.153
Data-to-parameter ratio = 12.9

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given .......          ?
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Zn1    -   O1      ..       6.01 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Zn1    -   O2      ..       5.90 su
PLAT244_ALERT_4_C Low  Solvent U(eq) as Compared to Neighbors  for         P1
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          2
PLAT751_ALERT_4_C Bond    Calc     0.85154, Rep    0.851(4) ......  Senseless su
              O3   -H1O3    1.555   1.555
PLAT751_ALERT_4_C Bond    Calc     0.86150, Rep    0.861(4) ......  Senseless su
              O3   -H2O3    1.555   1.555
PLAT752_ALERT_4_C Angle   Calc      106.57, Rep    106.6(5) ......  Senseless su
              H1O3 -O3   -H2O3    1.555   1.555   1.555
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          3
              H2 O

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  10 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   7 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: COLLECT (Nonius, 1999); cell refinement: COLLECT; data reduction: COLLECT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

acetatobis(2,2'-bipyridil)znic(II) hexafluorphosphate monohydrate top

Crystal data top

[Zn(C₂H₃O₂)(C₁₀H₈N₂)₂]PF₆·H₂O	F(000) = 608
M_r = 599.79	D_x = 1.616 Mg m⁻³
Triclinic, P1	Melting point: not measured K
a = 8.4489 (4) Å	Mo Kα radiation, λ = 0.71073 Å
b = 10.0482 (5) Å	Cell parameters from 11273 reflections
c = 14.9191 (8) Å	θ = 0.4–27.1°
α = 77.264 (3)°	µ = 1.14 mm⁻¹
β = 87.306 (3)°	T = 293 K
γ = 86.554 (3)°	Prism, colorless
V = 1232.44 (11) Å³	0.15 × 0.13 × 0.09 mm
Z = 2

Data collection top

Nonius KappaCCD diffractometer	3411 reflections with I > 2σ(I)
Radiation source: fine focus sealed tube, nonius	R_int = 0.053
Horizonally mounted graphite crystal monochromator	θ_max = 25°, θ_min = 1.4°
Detector resolution: 9 pixels mm^-1	h = −8→10
CCD scans	k = −11→11
13542 measured reflections	l = −17→17
4308 independent reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.052	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.153	H atoms treated by a mixture of independent and constrained refinement
S = 1.05	w = 1/[σ²(F_o²) + (0.0986P)² + 0.1996P] where P = (F_o² + 2F_c²)/3
4308 reflections	(Δ/σ)_max < 0.001
334 parameters	Δρ_max = 0.55 e Å⁻³
0 restraints	Δρ_min = −0.50 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
O3	−0.2582 (6)	0.1279 (4)	0.4022 (3)	0.1155 (16)
H1O3	−0.2574	0.2123	0.3762	0.076*
H2O3	−0.3288	0.0933	0.3756	0.076*
Zn1	0.02308 (5)	0.48059 (4)	0.24915 (3)	0.04602 (19)
N2	0.0280 (4)	0.6352 (3)	0.3257 (2)	0.0480 (7)
N3	0.0496 (4)	0.3315 (3)	0.1664 (2)	0.0472 (7)
O2	−0.2047 (3)	0.5592 (3)	0.19285 (18)	0.0558 (7)
N1	0.1706 (4)	0.3873 (3)	0.3595 (2)	0.0465 (7)
O1	−0.2020 (3)	0.4006 (3)	0.31807 (19)	0.0593 (7)
N4	0.1729 (4)	0.5749 (3)	0.1380 (2)	0.0463 (7)
C5	0.1978 (4)	0.4652 (4)	0.4186 (2)	0.0470 (9)
C21	−0.2765 (5)	0.4814 (4)	0.2556 (3)	0.0504 (9)
C6	0.1214 (4)	0.6058 (4)	0.3981 (2)	0.0471 (9)
C15	0.1339 (4)	0.3693 (4)	0.0873 (3)	0.0468 (9)
C16	0.2028 (4)	0.5060 (4)	0.0711 (2)	0.0465 (9)
C14	0.1543 (6)	0.2866 (4)	0.0246 (3)	0.0590 (10)
H14	0.2118	0.3151	−0.0303	0.071*
C20	0.2345 (5)	0.6992 (4)	0.1274 (3)	0.0561 (10)
H20	0.2141	0.7478	0.1734	0.067*
C1	0.2343 (5)	0.2598 (4)	0.3744 (3)	0.0599 (10)
H1	0.2155	0.2056	0.3333	0.072*
C4	0.2888 (5)	0.4162 (5)	0.4945 (3)	0.0629 (11)
H4	0.3056	0.4713	0.5354	0.075*
C17	0.2917 (5)	0.5593 (4)	−0.0068 (3)	0.0604 (11)
H17	0.3095	0.5105	−0.0528	0.073*
C11	−0.0176 (6)	0.2111 (4)	0.1839 (3)	0.0606 (11)
H11	−0.0777	0.1856	0.2381	0.073*
C2	0.3270 (6)	0.2057 (5)	0.4485 (3)	0.0718 (13)
H2	0.37	0.1166	0.4572	0.086*
C19	0.3251 (6)	0.7561 (5)	0.0522 (3)	0.0661 (12)
H19	0.3664	0.8411	0.0475	0.079*
C9	−0.0329 (6)	0.8563 (5)	0.3551 (3)	0.0667 (12)
H9	−0.0886	0.9405	0.3399	0.08*
C12	−0.0014 (6)	0.1237 (5)	0.1252 (3)	0.0695 (13)
H12	−0.0501	0.0407	0.1394	0.083*
C7	0.1410 (6)	0.7011 (5)	0.4508 (3)	0.0667 (12)
H7	0.205	0.6791	0.5016	0.08*
C18	0.3543 (6)	0.6858 (5)	−0.0163 (3)	0.0699 (13)
H18	0.4153	0.7226	−0.0684	0.084*
C10	−0.0484 (5)	0.7582 (4)	0.3047 (3)	0.0586 (10)
H10	−0.114	0.7781	0.2546	0.07*
C22	−0.4547 (5)	0.4850 (5)	0.2577 (4)	0.0800 (15)
H22A	−0.492	0.4182	0.3096	0.12*
H22B	−0.4899	0.4649	0.2021	0.12*
H22C	−0.4962	0.5742	0.2629	0.12*
C13	0.0876 (6)	0.1601 (5)	0.0450 (3)	0.0719 (13)
H13	0.1029	0.1009	0.005	0.086*
C8	0.0656 (7)	0.8278 (5)	0.4277 (4)	0.0746 (14)
H8	0.0813	0.8937	0.461	0.09*
C3	0.3548 (6)	0.2842 (6)	0.5089 (3)	0.0765 (14)
H3	0.4174	0.2497	0.5593	0.092*
P1	0.48833 (15)	0.98960 (12)	0.22912 (9)	0.0653 (3)
F3	0.4901 (8)	1.0101 (5)	0.1225 (3)	0.159 (2)
F5	0.4594 (7)	1.1469 (3)	0.2179 (3)	0.1439 (18)
F6	0.4846 (7)	0.9753 (4)	0.3352 (3)	0.1494 (19)
F4	0.6660 (5)	1.0158 (7)	0.2222 (5)	0.201 (3)
F2	0.5147 (9)	0.8324 (4)	0.2430 (4)	0.178 (2)
F1	0.3120 (6)	0.9666 (7)	0.2319 (4)	0.195 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
O3	0.155 (4)	0.082 (3)	0.115 (3)	−0.015 (3)	−0.036 (3)	−0.024 (2)
Zn1	0.0471 (3)	0.0504 (3)	0.0415 (3)	−0.00399 (19)	−0.00228 (18)	−0.01163 (19)
N2	0.0512 (18)	0.0508 (18)	0.0412 (17)	−0.0024 (15)	−0.0027 (14)	−0.0085 (13)
N3	0.0505 (17)	0.0477 (17)	0.0436 (17)	−0.0046 (14)	−0.0013 (14)	−0.0096 (13)
O2	0.0533 (16)	0.0693 (18)	0.0448 (15)	−0.0071 (14)	0.0015 (12)	−0.0121 (13)
N1	0.0442 (17)	0.0529 (18)	0.0421 (17)	0.0003 (14)	0.0028 (13)	−0.0115 (14)
O1	0.0561 (17)	0.0657 (17)	0.0540 (17)	−0.0076 (14)	−0.0085 (13)	−0.0061 (14)
N4	0.0476 (17)	0.0485 (17)	0.0436 (17)	−0.0056 (14)	−0.0031 (13)	−0.0106 (13)
C5	0.0398 (19)	0.060 (2)	0.040 (2)	−0.0041 (17)	0.0031 (15)	−0.0079 (17)
C21	0.047 (2)	0.061 (2)	0.047 (2)	−0.0028 (18)	−0.0023 (17)	−0.0200 (19)
C6	0.047 (2)	0.055 (2)	0.041 (2)	−0.0084 (17)	0.0050 (16)	−0.0150 (16)
C15	0.046 (2)	0.051 (2)	0.043 (2)	0.0011 (17)	−0.0080 (16)	−0.0103 (16)
C16	0.045 (2)	0.054 (2)	0.042 (2)	−0.0046 (17)	−0.0076 (16)	−0.0100 (16)
C14	0.076 (3)	0.061 (2)	0.042 (2)	−0.009 (2)	−0.0001 (19)	−0.0159 (18)
C20	0.063 (2)	0.055 (2)	0.052 (2)	−0.016 (2)	−0.0025 (19)	−0.0136 (18)
C1	0.064 (3)	0.055 (2)	0.056 (3)	0.007 (2)	0.005 (2)	−0.0072 (19)
C4	0.066 (3)	0.079 (3)	0.043 (2)	−0.001 (2)	−0.0110 (19)	−0.011 (2)
C17	0.071 (3)	0.067 (3)	0.044 (2)	−0.012 (2)	0.0066 (19)	−0.0146 (19)
C11	0.073 (3)	0.052 (2)	0.056 (2)	−0.015 (2)	0.004 (2)	−0.0071 (19)
C2	0.076 (3)	0.066 (3)	0.064 (3)	0.016 (2)	−0.002 (2)	−0.001 (2)
C19	0.072 (3)	0.062 (3)	0.063 (3)	−0.022 (2)	−0.001 (2)	−0.005 (2)
C9	0.083 (3)	0.052 (2)	0.065 (3)	0.002 (2)	0.006 (2)	−0.017 (2)
C12	0.089 (3)	0.051 (2)	0.072 (3)	−0.019 (2)	−0.003 (3)	−0.017 (2)
C7	0.079 (3)	0.071 (3)	0.057 (3)	−0.009 (2)	−0.007 (2)	−0.026 (2)
C18	0.080 (3)	0.072 (3)	0.054 (3)	−0.022 (3)	0.012 (2)	−0.005 (2)
C10	0.065 (3)	0.053 (2)	0.057 (3)	0.006 (2)	−0.002 (2)	−0.0118 (19)
C22	0.048 (3)	0.102 (4)	0.085 (4)	−0.004 (3)	0.002 (2)	−0.012 (3)
C13	0.095 (4)	0.064 (3)	0.065 (3)	−0.008 (3)	−0.004 (3)	−0.030 (2)
C8	0.099 (4)	0.063 (3)	0.071 (3)	−0.012 (3)	0.001 (3)	−0.034 (2)
C3	0.071 (3)	0.093 (4)	0.055 (3)	0.016 (3)	−0.012 (2)	0.003 (3)
P1	0.0671 (7)	0.0562 (7)	0.0733 (8)	−0.0084 (6)	−0.0117 (6)	−0.0125 (6)
F3	0.279 (7)	0.128 (3)	0.082 (3)	−0.057 (4)	−0.010 (3)	−0.033 (2)
F5	0.251 (6)	0.063 (2)	0.109 (3)	0.003 (3)	0.031 (3)	−0.0100 (19)
F6	0.267 (6)	0.103 (3)	0.076 (2)	−0.032 (3)	−0.011 (3)	−0.006 (2)
F4	0.073 (3)	0.272 (7)	0.264 (7)	−0.032 (4)	−0.006 (4)	−0.064 (6)
F2	0.290 (7)	0.066 (2)	0.178 (5)	0.014 (3)	−0.013 (5)	−0.033 (3)
F1	0.086 (3)	0.235 (6)	0.237 (6)	−0.054 (4)	−0.023 (3)	0.023 (5)

Geometric parameters (Å, º) top

Zn1—O1	2.226 (3)	C19—C18	1.371 (7)
Zn1—O2	2.170 (3)	C9—C8	1.366 (7)
Zn1—N1	2.125 (3)	C9—C10	1.381 (6)
Zn1—N2	2.124 (3)	C12—C13	1.374 (7)
Zn1—N3	2.136 (3)	C7—C8	1.369 (7)
Zn1—N4	2.122 (3)	P1—F1	1.518 (4)
Zn1—C21	2.528 (4)	P1—F4	1.535 (5)
N2—C6	1.337 (5)	P1—F2	1.551 (4)
N2—C10	1.339 (5)	P1—F6	1.556 (4)
N3—C11	1.336 (5)	P1—F3	1.558 (4)
N3—C15	1.342 (5)	P1—F5	1.558 (4)
O2—C21	1.239 (5)	O3—H1O3	0.851 (4)
N1—C1	1.335 (5)	O3—H2O3	0.861 (4)
N1—C5	1.337 (5)	C14—H14	0.9300
O1—C21	1.259 (5)	C20—H20	0.9300
N4—C16	1.342 (5)	C1—H1	0.9300
N4—C20	1.356 (5)	C4—H4	0.9300
C5—C4	1.380 (5)	C17—H17	0.9300
C5—C6	1.492 (6)	C11—H11	0.9300
C21—C22	1.503 (6)	C2—H2	0.9300
C6—C7	1.389 (6)	C19—H19	0.9300
C15—C14	1.381 (6)	C9—H9	0.9300
C15—C16	1.490 (5)	C7—H7	0.9300
C16—C17	1.376 (5)	C18—H18	0.9300
C14—C13	1.388 (6)	C10—H10	0.9300
C20—C19	1.364 (6)	C22—H22A	0.9600
C1—C2	1.377 (6)	C22—H22B	0.9600
C4—C3	1.383 (7)	C22—H22C	0.9600
C17—C18	1.381 (6)	C13—H13	0.9300
C11—C12	1.367 (6)	C8—H8	0.9300
C2—C3	1.358 (7)	C3—H3	0.9300

N1—Zn1—O1	95.68 (11)	C11—C12—C13	119.2 (4)
N1—Zn1—O2	152.55 (12)	C8—C7—C6	119.6 (4)
N1—Zn1—N2	77.38 (12)	C19—C18—C17	118.9 (4)
N1—Zn1—N3	100.36 (12)	N2—C10—C9	122.1 (4)
N1—Zn1—N4	107.45 (12)	C12—C13—C14	118.9 (4)
N2—Zn1—O1	93.42 (11)	C9—C8—C7	119.3 (4)
N2—Zn1—O2	92.27 (12)	C2—C3—C4	119.1 (4)
N2—Zn1—N3	172.44 (12)	F1—P1—F4	177.7 (4)
N2—Zn1—N4	96.52 (11)	F1—P1—F2	86.6 (4)
N3—Zn1—O1	93.98 (11)	F4—P1—F2	94.3 (4)
N3—Zn1—O2	92.81 (12)	F1—P1—F6	90.8 (3)
N3—Zn1—N4	77.18 (11)	F4—P1—F6	91.3 (4)
N4—Zn1—O1	156.31 (11)	F2—P1—F6	89.8 (3)
N4—Zn1—O2	98.87 (11)	F1—P1—F3	89.0 (3)
O1—Zn1—O2	59.19 (10)	F4—P1—F3	88.8 (3)
N4—Zn1—C21	127.68 (12)	F2—P1—F3	92.4 (3)
N2—Zn1—C21	93.41 (12)	F6—P1—F3	177.7 (3)
N1—Zn1—C21	124.84 (12)	F1—P1—F5	92.7 (4)
N3—Zn1—C21	93.76 (12)	F4—P1—F5	86.4 (3)
O2—Zn1—C21	29.33 (11)	F2—P1—F5	178.4 (3)
O1—Zn1—C21	29.86 (11)	F6—P1—F5	88.7 (2)
C6—N2—C10	119.2 (4)	F3—P1—F5	89.0 (2)
C6—N2—Zn1	115.4 (3)	H1O3—O3—H2O3	106.6 (5)
C10—N2—Zn1	125.4 (3)	C15—C14—H14	120.6
C11—N3—C15	118.6 (3)	C13—C14—H14	120.6
C11—N3—Zn1	126.0 (3)	N4—C20—H20	118.6
C15—N3—Zn1	115.2 (2)	C19—C20—H20	118.6
C21—O2—Zn1	91.5 (2)	N1—C1—H1	118.9
C1—N1—C5	118.8 (3)	C2—C1—H1	118.9
C1—N1—Zn1	125.7 (3)	C5—C4—H4	120.4
C5—N1—Zn1	115.5 (2)	C3—C4—H4	120.4
C21—O1—Zn1	88.5 (2)	C16—C17—H17	120.2
C16—N4—C20	118.0 (3)	C18—C17—H17	120.2
C16—N4—Zn1	115.9 (2)	N3—C11—H11	118.7
C20—N4—Zn1	126.0 (3)	C12—C11—H11	118.7
N1—C5—C4	121.5 (4)	C3—C2—H2	120.4
N1—C5—C6	115.8 (3)	C1—C2—H2	120.4
C4—C5—C6	122.7 (4)	C20—C19—H19	120.5
O2—C21—O1	120.8 (4)	C18—C19—H19	120.5
O2—C21—C22	119.6 (4)	C8—C9—H9	120.6
O1—C21—C22	119.6 (4)	C10—C9—H9	120.6
O2—C21—Zn1	59.1 (2)	C11—C12—H12	120.4
O1—C21—Zn1	61.7 (2)	C13—C12—H12	120.4
C22—C21—Zn1	178.7 (3)	C8—C7—H7	120.2
N2—C6—C7	120.9 (4)	C6—C7—H7	120.2
N2—C6—C5	115.8 (3)	C19—C18—H18	120.5
C7—C6—C5	123.3 (4)	C17—C18—H18	120.5
N3—C15—C14	121.8 (3)	N2—C10—H10	119.0
N3—C15—C16	115.9 (3)	C9—C10—H10	119.0
C14—C15—C16	122.2 (4)	C21—C22—H22A	109.5
N4—C16—C17	121.6 (3)	C21—C22—H22B	109.5
N4—C16—C15	115.5 (3)	H22A—C22—H22B	109.5
C17—C16—C15	122.9 (4)	C21—C22—H22C	109.5
C15—C14—C13	118.8 (4)	H22A—C22—H22C	109.5
N4—C20—C19	122.8 (4)	H22B—C22—H22C	109.5
N1—C1—C2	122.3 (4)	C12—C13—H13	120.6
C5—C4—C3	119.1 (4)	C14—C13—H13	120.6
C16—C17—C18	119.7 (4)	C9—C8—H8	120.4
N3—C11—C12	122.7 (4)	C7—C8—H8	120.4
C3—C2—C1	119.1 (5)	C2—C3—H3	120.4
C20—C19—C18	119.0 (4)	C4—C3—H3	120.4
C8—C9—C10	118.9 (4)

Comparative bond lengths (Å) for [Zn(OXO)L₂]Y complexes top

compound	Zn—N1	Zn—N2	Zn—N3	Zn—N4	Zn—O1	Zn—O2
[Zn(ONO)(bipy)₂]NO₃^a	2.077 (9)	2.129 (9)	2.151 (9)	2.092 (9)	2.223 (8)	2.217 (9)
[Zn(ONO)(bipy)₂]ClO₄^b	2.090 (4)	2.129 (4)	2.135 (4)	2.085 (4)	2.216 (5)	2.197 (5)
[Zn(ac)(bipy)₂]Cl₄.H₂O^c	2,131 (4)	2.121 (5)	2.127 (4)	2.129 (4)	2.246 (4)	2.155 (4)
[Zn(ac)(bipy)₂][Mn(dca)₃(H₂O)]^d	2.115 (2)	2.137 (2)	2.121 (2)	2.107 (2)	2.347 (2)	2.120 (1)
[Zn(ac)(bipy)₂]PF₆.H₂O^e	2.125 (3)	2.124 (3)	2.136 (3)	2.122 (3)	2.226 (3)	2.170 (3)
[Zn(ac)(phen)₂]BF₄^f	2.091 (3)	2.151 (3)	2.148 (3)	2.119 (3)	2.293 (3)	2.149 (3)
[Zn(ac)(phen)₂]BF₄.2H₂O^g	2.116 (2)	2.147 (2)	2.147 (2)	2.116 (2)	2.184 (2)	2.184 (2)
[Zn(ac)(phen)₂]ClO₄^h	2.135 (6)	2.143 (6)	2.160 (5)	2.100 (5)	2.296 (5)	2.156 (5)

Notes: (a) Walsh et al. (1981); (b) Murphy et al. (2003); (c) Chen, Xu & Mak (1994); (d) Wang et al. (2003); (e) this work; (f) Rodrigues (2004) (g) Fitzgerald et al. (1985); (h) Chen, Xu, Yu & Mak (1994).

Comparative bond angles (°) for [Zn(OXO)L₂]Y complexes top

compound	N1—Zn—N2	N3—Zn—N4	O1—Zn—O2
[Zn(ONO)(bipy)₂]NO₃^a	77.94	78.53	56.5
[Zn(ONO)(bipy)₂]ClO₄^b	77.76 (16)	77.88 (17)	55.80 (18)
[Zn(ac)(bipy)₂]Cl₄.H₂O^c	77.2 (2)	77.8 (2)	59.0 (1)
[Zn(ac)(bipy)₂][Mn(dca)₃(H₂O)]^d	77.03 (6)	78.07 (6)	58.29 (5)
[Zn(ac)(bipy)₂]PF₆.H₂O)^e	77.38 (12)	77.18 (11)	59.19 (10)
[Zn(ac)(phen)₂]BF₄^f	78.94 (12)	77.92 (12)	58.12 (11)
[Zn(ac)(phen)₂]BF₄.2H₂O^g	78.47	78.47	57.2
[Zn(ac)(phen)₂]ClO₄^h	78.1 (2)	78.6 (2)	57.8 (2)

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Acetatobis(2,2'-bipyridyl)­zinc(II) hexafluorophosphate monohydrate

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Acetatobis(2,2'-bipyridyl)zinc(II) hexafluorophosphate monohydrate