Phosphoramides bearing isoxazole derivative: spectroscopic and structural characterization, study of hydrogen-bonding interactions and two lanthanide complexes (Ln^III = Ce and Eu)

In this study, the synthesis and spectroscopic characterization of new phosphoramides based on 3-amino-5-methylisoxazole with the formula R₂P(O)[NH–C₄H₄NO], R = C₆H₅O (1), C₆H₅ (2), RP(O)[NH—C₄H₄NO]₂, R = C₆H₅O (3), CH₃—C₆H₄O (4), C₆H₅NH (5), (C₆H₅)ClP(O)[NH–C₄H₄NO] (6) and two lanthanide complexes [Ln(2)₂(NO₃)₃(EtOH)]·EtOH, Ln^III = Ce (7) and Eu (8), have been reported. The structural study of (3) shows the presence of two conformers (crystallographically independent molecules) in the crystalline lattice, caused by different orientations of the phenyl and isoxazole rings. For (3), the intermolecular interactions have been studied by Hirshfeld surface analysis and fingerprint plots. Furthermore, the electronic and energy aspects of hydrogen bonds between molecules of (3) have been explored by density functional theory (DFT) calculations. X-ray crystallography of complexes (7) and (8) reveals that two phosphoramide ligands take part in coordination to the metal, one as monodentate from O_phosphoryl, and the other one as chelate through O_phosphoryl and N_ring. The complexes are also composed of two conformers in the solid-state structure. Quantum theory of atoms in molecules (QTAIM) analysis discloses the electrostatic nature of the Ln–ligand interaction.

S1. Experimental

S1.1. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1. Crystals of C14H15N4O4P were twins with several disoriented domains. The Cell_Now program (Bruker (2005)) indexing allowed decribing the twinning as superposition of two components that are rotated by approximately 179.9 degrees against each other. The H atoms of NH groups were located from Fourier difference maps and refined in isotropic appoximation with the NH distances constrained at 0.91 %A. The positions of H(C) atoms were calculated and refined within riging model, with the Uiso(H) parameters equal to 1.2 Ueq(Ci), where U(Ci) are the equivalent thermal parameters of the carbon atoms to which the corresponding H atoms are bonded The model of the best possible quality was obtained during the structure refinement using standard HKLF4 instruction (Fo² data for only one domain); at that the weighting scheme was varied manually.

S2. Experimental

S2.1. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1. The H atoms of the NH and OH groups were localized in the difference Fourier-syntheses and refined isotropically. The H(C) atoms were placed in calculated positions and included in the refinement within riding model with fixed isotropic displacement parameters Uiso(H) = 1.2Ueq(C) and Uiso(H) = 1.5Ueq(C) for the methyl groups.

S3. Experimental

S3.1. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1. The H atoms of the NH and OH groups were localized in the difference Fourier-syntheses and refined isotropically. The H(C) atoms were placed in calculated positions and included in the refinement within riding model with fixed isotropic displacement parameters Uiso(H) = 1.2Ueq(C) and Uiso(H) = 1.5Ueq(C) for the methyl groups.

Computing details

Data collection: Bruker APEX II for m71; APEX2 (Bruker, 2005) for IGCN, IGE. Cell refinement: Bruker SAINT for m71; SAINTPlus, v. 6.2 (Bruker, 2001) for IGCN, IGE. Data reduction: Bruker SAINT for m71; SAINTPlus, v. 6.2 (Bruker, 2001) for IGCN, IGE. Program(s) used to solve structure: SHELXS97 (Sheldrick, 1997) for m71; SHELXTL (Sheldrick, 2008) for IGCN, IGE. Program(s) used to refine structure: SHELXL97 (Sheldrick, 1997) for m71; SHELXTL (Sheldrick, 2008) for IGCN, IGE. Molecular graphics: Bruker SHELXTL for m71; SHELXTL (Sheldrick, 2008) for IGCN, IGE. Software used to prepare material for publication: Bruker SHELXTL for m71; SHELXTL (Sheldrick, 2008) for IGCN, IGE.

Figures

(m71)

Crystal data

C14H15N4O4P	Z = 4
Mr = 334.27	F(000) = 696
Triclinic, P1	Dx = 1.469 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.2849 (19) Å	Cell parameters from 1098 reflections
b = 10.835 (2) Å	θ = 3–28°
c = 15.295 (3) Å	µ = 0.21 mm^−1
α = 89.96 (4)°	T = 100 K
β = 84.78 (3)°	Needle, colorless
γ = 80.54 (2)°	0.33 × 0.13 × 0.07 mm
V = 1511.4 (5) Å^3

Data collection

Bruker APEX II CCD area detector diffractometer	7171 independent reflections
Radiation source: fine-focus sealed tube	4896 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.065
ω scans	θmax = 28.0°, θmin = 1.3°
Absorption correction: multi-scan TWINABS	h = −12→12
Tmin = 0.934, Tmax = 0.986	k = −14→14
7171 measured reflections	l = 0→20

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.098	Hydrogen site location: mixed
wR(F^2) = 0.195	H-atom parameters constrained
S = 1.09	w = 1/[σ^2(Fo^2) + (0.010P)^2 + 11.7247P] where P = (Fo^2 + 2Fc^2)/3
7171 reflections	(Δ/σ)max < 0.001
423 parameters	Δρmax = 1.16 e Å^−3
12 restraints	Δρmin = −0.65 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
P1	0.11291 (13)	0.94793 (11)	0.78152 (8)	0.0110 (2)
P2	0.12521 (13)	0.45070 (11)	0.71535 (8)	0.0113 (2)
O1	0.1509 (4)	1.0574 (3)	0.7323 (2)	0.0148 (7)
O1A	0.1527 (4)	0.5625 (3)	0.7612 (2)	0.0151 (7)
O2	0.2331 (3)	0.8756 (3)	0.8384 (2)	0.0141 (7)
O2A	0.2579 (4)	0.3794 (3)	0.6539 (2)	0.0154 (7)
O3	−0.1734 (4)	0.7672 (3)	0.9800 (2)	0.0193 (7)
O3A	−0.1791 (4)	0.3037 (3)	0.9516 (2)	0.0163 (7)
O4	−0.1429 (4)	0.7990 (3)	0.5553 (2)	0.0165 (7)
O4A	−0.1702 (4)	0.2642 (3)	0.5575 (2)	0.0178 (7)
N1	−0.0242 (4)	0.9941 (4)	0.8531 (3)	0.0142 (8)
H1N	−0.0484	1.0789	0.8552	0.038 (18)*
N1A	0.0837 (4)	0.3358 (3)	0.7802 (2)	0.0126 (8)
H1NA	0.0968	0.2570	0.7571	0.033 (17)*
N2	−0.0717 (5)	0.8003 (4)	0.9130 (3)	0.0186 (9)
N2A	−0.0819 (4)	0.2579 (4)	0.8791 (3)	0.0156 (8)
N3	0.0797 (4)	0.8327 (3)	0.7202 (2)	0.0117 (8)
H3N	0.0988	0.7536	0.7412	0.032 (17)*
N3A	−0.0032 (4)	0.4925 (4)	0.6504 (2)	0.0131 (8)
H3NA	−0.0162	0.5758	0.6386	0.033 (17)*
N4	−0.0504 (4)	0.7523 (4)	0.6191 (3)	0.0151 (8)
N4A	−0.0664 (4)	0.2979 (4)	0.6119 (3)	0.0146 (8)
C1	−0.1008 (5)	0.9232 (4)	0.9104 (3)	0.0140 (9)
C1A	−0.0217 (5)	0.3537 (4)	0.8502 (3)	0.0127 (9)
C2	−0.2159 (5)	0.9740 (5)	0.9727 (3)	0.0178 (10)
H2A	−0.2555	1.0597	0.9835	0.021*
C2A	−0.0769 (5)	0.4648 (4)	0.8999 (3)	0.0127 (9)
H2AA	−0.0528	0.5461	0.8913	0.015*
C3	−0.2576 (5)	0.8732 (5)	1.0136 (3)	0.0177 (10)
C3A	−0.1717 (5)	0.4269 (4)	0.9624 (3)	0.0134 (9)
C4	−0.3696 (6)	0.8569 (5)	1.0854 (3)	0.0253 (12)
H4A	−0.4286	0.9384	1.1020	0.038*
H4B	−0.3215	0.8208	1.1361	0.038*
H4C	−0.4332	0.8008	1.0657	0.038*
C4A	−0.2644 (5)	0.4900 (4)	1.0382 (3)	0.0168 (10)
H4AA	−0.2421	0.4439	1.0918	0.025*
H4AB	−0.3680	0.4924	1.0291	0.025*
H4AC	−0.2448	0.5756	1.0440	0.025*
C5	−0.0129 (5)	0.8509 (4)	0.6547 (3)	0.0118 (9)
C5A	−0.0817 (5)	0.4207 (4)	0.6049 (3)	0.0125 (9)
C6	−0.0790 (5)	0.9645 (4)	0.6176 (3)	0.0148 (9)
H6A	−0.0693	1.0477	0.6324	0.018*
C6A	−0.1891 (5)	0.4711 (4)	0.5491 (3)	0.0150 (9)
H6AA	−0.2188	0.5560	0.5343	0.018*
C7	−0.1579 (5)	0.9266 (4)	0.5568 (3)	0.0150 (9)
C7A	−0.2391 (5)	0.3692 (4)	0.5220 (3)	0.0158 (10)
C8	−0.2553 (6)	0.9912 (5)	0.4931 (3)	0.0209 (11)
H8A	−0.2616	1.0820	0.4998	0.031*
H8B	−0.3534	0.9690	0.5044	0.031*
H8C	−0.2152	0.9654	0.4332	0.031*
C8A	−0.3516 (6)	0.3516 (5)	0.4626 (3)	0.0209 (11)
H8AA	−0.3970	0.4333	0.4420	0.031*
H8AB	−0.4268	0.3106	0.4943	0.031*
H8AC	−0.3054	0.2993	0.4122	0.031*
C9	0.3740 (5)	0.8192 (4)	0.8088 (3)	0.0132 (9)
C9A	0.3917 (5)	0.3273 (5)	0.6881 (3)	0.0162 (10)
C10	0.4527 (6)	0.7528 (4)	0.8705 (3)	0.0178 (10)
H10A	0.4094	0.7470	0.9288	0.021*
C10A	0.4747 (6)	0.4042 (5)	0.7255 (3)	0.0201 (10)
H10B	0.4428	0.4919	0.7308	0.024*
C11	0.5941 (6)	0.6948 (5)	0.8474 (4)	0.0246 (12)
H11A	0.6494	0.6493	0.8898	0.030*
C11A	0.6066 (6)	0.3484 (5)	0.7548 (4)	0.0239 (11)
H11B	0.6662	0.3986	0.7810	0.029*
C12	0.6553 (6)	0.7028 (5)	0.7628 (4)	0.0260 (12)
H12A	0.7531	0.6628	0.7467	0.031*
C12A	0.6526 (6)	0.2201 (5)	0.7465 (3)	0.0218 (11)
H12B	0.7435	0.1833	0.7665	0.026*
C13	0.5752 (6)	0.7690 (5)	0.7010 (4)	0.0260 (12)
H13A	0.6176	0.7730	0.6424	0.031*
C13A	0.5661 (6)	0.1459 (5)	0.7091 (3)	0.0219 (11)
H13B	0.5973	0.0579	0.7042	0.026*
C14	0.4334 (6)	0.8293 (5)	0.7241 (3)	0.0187 (10)
H14A	0.3786	0.8765	0.6824	0.022*
C14A	0.4352 (5)	0.1989 (5)	0.6791 (3)	0.0178 (10)
H14B	0.3758	0.1486	0.6528	0.021*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
P1	0.0138 (6)	0.0083 (5)	0.0111 (5)	0.0009 (4)	−0.0072 (4)	0.0015 (4)
P2	0.0147 (6)	0.0089 (5)	0.0104 (5)	0.0003 (4)	−0.0061 (4)	0.0016 (4)
O1	0.0221 (18)	0.0101 (15)	0.0126 (16)	−0.0011 (13)	−0.0057 (13)	0.0007 (12)
O1A	0.0187 (17)	0.0110 (16)	0.0160 (17)	−0.0015 (13)	−0.0062 (13)	0.0001 (13)
O2	0.0140 (16)	0.0153 (16)	0.0110 (15)	0.0060 (13)	−0.0060 (13)	0.0006 (12)
O2A	0.0188 (17)	0.0141 (16)	0.0132 (16)	−0.0011 (13)	−0.0042 (13)	0.0009 (13)
O3	0.0200 (18)	0.0135 (17)	0.0233 (19)	−0.0012 (14)	0.0012 (15)	0.0035 (14)
O3A	0.0223 (18)	0.0099 (16)	0.0167 (17)	−0.0023 (13)	−0.0022 (14)	0.0004 (13)
O4	0.0203 (17)	0.0146 (17)	0.0166 (17)	−0.0037 (13)	−0.0116 (14)	0.0027 (13)
O4A	0.0268 (19)	0.0122 (16)	0.0169 (17)	−0.0051 (14)	−0.0110 (14)	0.0022 (13)
N1	0.020 (2)	0.0063 (18)	0.016 (2)	−0.0001 (15)	−0.0030 (16)	0.0003 (15)
N1A	0.020 (2)	0.0062 (18)	0.0103 (18)	0.0015 (15)	−0.0033 (15)	0.0003 (14)
N2	0.023 (2)	0.013 (2)	0.019 (2)	−0.0004 (17)	−0.0005 (17)	0.0053 (16)
N2A	0.018 (2)	0.0130 (19)	0.015 (2)	−0.0004 (16)	−0.0020 (16)	0.0000 (15)
N3	0.0172 (19)	0.0066 (18)	0.0119 (18)	0.0002 (15)	−0.0089 (15)	0.0033 (14)
N3A	0.0167 (19)	0.0094 (18)	0.0139 (19)	−0.0008 (15)	−0.0082 (15)	0.0022 (15)
N4	0.019 (2)	0.0110 (19)	0.016 (2)	0.0014 (16)	−0.0102 (16)	0.0026 (15)
N4A	0.019 (2)	0.0108 (19)	0.016 (2)	−0.0030 (15)	−0.0124 (16)	0.0008 (15)
C1	0.016 (2)	0.010 (2)	0.015 (2)	0.0019 (17)	−0.0069 (18)	0.0015 (17)
C1A	0.015 (2)	0.011 (2)	0.013 (2)	0.0014 (17)	−0.0102 (17)	0.0029 (16)
C2	0.022 (3)	0.015 (2)	0.015 (2)	−0.0001 (19)	−0.0011 (19)	−0.0011 (18)
C2A	0.015 (2)	0.010 (2)	0.013 (2)	0.0029 (17)	−0.0081 (18)	−0.0003 (17)
C3	0.019 (2)	0.017 (2)	0.017 (2)	−0.0019 (19)	−0.0042 (19)	−0.0019 (19)
C3A	0.013 (2)	0.010 (2)	0.018 (2)	0.0019 (17)	−0.0113 (18)	0.0020 (17)
C4	0.032 (3)	0.025 (3)	0.018 (3)	−0.003 (2)	−0.001 (2)	0.006 (2)
C4A	0.020 (2)	0.013 (2)	0.017 (2)	−0.0014 (19)	−0.0035 (19)	0.0022 (18)
C5	0.012 (2)	0.009 (2)	0.013 (2)	0.0014 (16)	−0.0016 (17)	0.0020 (17)
C5A	0.012 (2)	0.015 (2)	0.010 (2)	0.0003 (17)	−0.0045 (17)	0.0010 (17)
C6	0.019 (2)	0.010 (2)	0.016 (2)	0.0005 (18)	−0.0086 (19)	0.0026 (17)
C6A	0.018 (2)	0.013 (2)	0.013 (2)	0.0010 (18)	−0.0025 (18)	0.0018 (17)
C7	0.018 (2)	0.013 (2)	0.014 (2)	−0.0004 (18)	−0.0057 (19)	0.0011 (17)
C7A	0.020 (2)	0.017 (2)	0.010 (2)	−0.0007 (19)	−0.0068 (18)	0.0017 (17)
C8	0.026 (3)	0.016 (2)	0.022 (3)	0.000 (2)	−0.017 (2)	0.002 (2)
C8A	0.025 (3)	0.017 (2)	0.022 (3)	−0.004 (2)	−0.010 (2)	0.002 (2)
C9	0.008 (2)	0.012 (2)	0.020 (2)	−0.0001 (17)	−0.0093 (18)	−0.0011 (18)
C9A	0.016 (2)	0.018 (2)	0.013 (2)	−0.0002 (19)	−0.0017 (18)	0.0000 (18)
C10	0.024 (3)	0.016 (2)	0.015 (2)	−0.0032 (19)	−0.008 (2)	0.0027 (18)
C10A	0.025 (3)	0.017 (2)	0.019 (2)	−0.005 (2)	−0.006 (2)	−0.0016 (19)
C11	0.021 (3)	0.022 (3)	0.030 (3)	0.002 (2)	−0.010 (2)	0.006 (2)
C11A	0.020 (3)	0.029 (3)	0.026 (3)	−0.007 (2)	−0.011 (2)	−0.003 (2)
C12	0.021 (3)	0.019 (3)	0.037 (3)	0.001 (2)	−0.005 (2)	0.000 (2)
C12A	0.015 (2)	0.026 (3)	0.023 (3)	0.000 (2)	−0.005 (2)	0.003 (2)
C13	0.026 (3)	0.027 (3)	0.024 (3)	−0.005 (2)	0.003 (2)	0.002 (2)
C13A	0.021 (3)	0.020 (3)	0.024 (3)	0.001 (2)	−0.005 (2)	0.000 (2)
C14	0.022 (3)	0.018 (2)	0.017 (2)	−0.002 (2)	−0.006 (2)	0.0032 (19)
C14A	0.017 (2)	0.020 (2)	0.017 (2)	−0.0060 (19)	0.0009 (19)	−0.0036 (19)

Geometric parameters (Å, º)

P1—O1	1.479 (3)	C4—H4C	0.9800
P1—O2	1.583 (3)	C4A—H4AA	0.9800
P1—N1	1.615 (4)	C4A—H4AB	0.9800
P1—N3	1.647 (4)	C4A—H4AC	0.9800
P2—O1A	1.470 (3)	C5—C6	1.424 (6)
P2—O2A	1.574 (4)	C5A—C6A	1.413 (6)
P2—N3A	1.628 (4)	C6—C7	1.339 (7)
P2—N1A	1.664 (4)	C6—H6A	0.9500
O2—C9	1.385 (5)	C6A—C7A	1.344 (7)
O2A—C9A	1.422 (6)	C6A—H6AA	0.9500
O3—C3	1.351 (6)	C7—C8	1.485 (6)
O3—N2	1.416 (5)	C7A—C8A	1.480 (7)
O3A—C3A	1.359 (5)	C8—H8A	0.9800
O3A—N2A	1.400 (5)	C8—H8B	0.9800
O4—C7	1.366 (6)	C8—H8C	0.9800
O4—N4	1.399 (5)	C8A—H8AA	0.9800
O4A—C7A	1.350 (5)	C8A—H8AB	0.9800
O4A—N4A	1.420 (5)	C8A—H8AC	0.9800
N1—C1	1.389 (6)	C9—C14	1.373 (7)
N1—H1N	0.9100	C9—C10	1.376 (6)
N1A—C1A	1.375 (6)	C9A—C10A	1.381 (7)
N1A—H1NA	0.9099	C9A—C14A	1.387 (7)
N2—C1	1.316 (6)	C10—C11	1.375 (7)
N2A—C1A	1.315 (6)	C10—H10A	0.9500
N3—C5	1.372 (6)	C10A—C11A	1.386 (7)
N3—H3N	0.9099	C10A—H10B	0.9500
N3A—C5A	1.379 (6)	C11—C12	1.374 (8)
N3A—H3NA	0.9100	C11—H11A	0.9500
N4—C5	1.310 (6)	C11A—C12A	1.387 (7)
N4A—C5A	1.321 (6)	C11A—H11B	0.9500
C1—C2	1.405 (7)	C12—C13	1.383 (8)
C1A—C2A	1.420 (6)	C12—H12A	0.9500
C2—C3	1.352 (7)	C12A—C13A	1.384 (7)
C2—H2A	0.9500	C12A—H12B	0.9500
C2A—C3A	1.349 (7)	C13—C14	1.385 (7)
C2A—H2AA	0.9500	C13—H13A	0.9500
C3—C4	1.474 (7)	C13A—C14A	1.374 (7)
C3A—C4A	1.477 (7)	C13A—H13B	0.9500
C4—H4A	0.9800	C14—H14A	0.9500
C4—H4B	0.9800	C14A—H14B	0.9500
O1—P1—O2	117.1 (2)	N4—C5—C6	112.2 (4)
O1—P1—N1	109.0 (2)	N3—C5—C6	129.6 (4)
O2—P1—N1	103.46 (19)	N4A—C5A—N3A	122.7 (4)
O1—P1—N3	114.91 (19)	N4A—C5A—C6A	113.7 (4)
O2—P1—N3	100.85 (18)	N3A—C5A—C6A	123.6 (4)
N1—P1—N3	110.8 (2)	C7—C6—C5	103.8 (4)
O1A—P2—O2A	116.0 (2)	C7—C6—H6A	128.1
O1A—P2—N3A	108.7 (2)	C5—C6—H6A	128.1
O2A—P2—N3A	104.71 (19)	C7A—C6A—C5A	103.0 (4)
O1A—P2—N1A	115.2 (2)	C7A—C6A—H6AA	128.5
O2A—P2—N1A	101.09 (19)	C5A—C6A—H6AA	128.5
N3A—P2—N1A	110.5 (2)	C6—C7—O4	110.3 (4)
C9—O2—P1	127.1 (3)	C6—C7—C8	134.6 (5)
C9A—O2A—P2	121.1 (3)	O4—C7—C8	115.1 (4)
C3—O3—N2	108.4 (4)	C6A—C7A—O4A	111.2 (4)
C3A—O3A—N2A	107.9 (3)	C6A—C7A—C8A	132.8 (4)
C7—O4—N4	108.3 (3)	O4A—C7A—C8A	115.9 (4)
C7A—O4A—N4A	108.5 (3)	C7—C8—H8A	109.5
C1—N1—P1	129.0 (3)	C7—C8—H8B	109.5
C1—N1—H1N	119.2	H8A—C8—H8B	109.5
P1—N1—H1N	111.8	C7—C8—H8C	109.5
C1A—N1A—P2	123.4 (3)	H8A—C8—H8C	109.5
C1A—N1A—H1NA	112.6	H8B—C8—H8C	109.5
P2—N1A—H1NA	118.3	C7A—C8A—H8AA	109.5
C1—N2—O3	104.8 (4)	C7A—C8A—H8AB	109.5
C1A—N2A—O3A	105.5 (4)	H8AA—C8A—H8AB	109.5
C5—N3—P1	122.9 (3)	C7A—C8A—H8AC	109.5
C5—N3—H3N	116.5	H8AA—C8A—H8AC	109.5
P1—N3—H3N	117.8	H8AB—C8A—H8AC	109.5
C5A—N3A—P2	130.2 (3)	C14—C9—C10	121.5 (4)
C5A—N3A—H3NA	116.6	C14—C9—O2	122.9 (4)
P2—N3A—H3NA	112.9	C10—C9—O2	115.6 (4)
C5—N4—O4	105.4 (3)	C10A—C9A—C14A	122.7 (5)
C5A—N4A—O4A	103.6 (3)	C10A—C9A—O2A	120.2 (4)
N2—C1—N1	123.3 (4)	C14A—C9A—O2A	117.1 (4)
N2—C1—C2	112.5 (4)	C11—C10—C9	119.7 (5)
N1—C1—C2	124.2 (4)	C11—C10—H10A	120.2
N2A—C1A—N1A	118.9 (4)	C9—C10—H10A	120.2
N2A—C1A—C2A	112.4 (4)	C9A—C10A—C11A	117.5 (5)
N1A—C1A—C2A	128.8 (4)	C9A—C10A—H10B	121.3
C3—C2—C1	104.3 (4)	C11A—C10A—H10B	121.3
C3—C2—H2A	127.8	C12—C11—C10	119.7 (5)
C1—C2—H2A	127.8	C12—C11—H11A	120.1
C3A—C2A—C1A	103.2 (4)	C10—C11—H11A	120.1
C3A—C2A—H2AA	128.4	C10A—C11A—C12A	120.9 (5)
C1A—C2A—H2AA	128.4	C10A—C11A—H11B	119.6
O3—C3—C2	110.0 (4)	C12A—C11A—H11B	119.6
O3—C3—C4	116.1 (4)	C11—C12—C13	120.3 (5)
C2—C3—C4	133.9 (5)	C11—C12—H12A	119.9
C2A—C3A—O3A	110.9 (4)	C13—C12—H12A	119.9
C2A—C3A—C4A	133.7 (4)	C13A—C12A—C11A	120.1 (5)
O3A—C3A—C4A	115.4 (4)	C13A—C12A—H12B	119.9
C3—C4—H4A	109.5	C11A—C12A—H12B	119.9
C3—C4—H4B	109.5	C12—C13—C14	120.3 (5)
H4A—C4—H4B	109.5	C12—C13—H13A	119.8
C3—C4—H4C	109.5	C14—C13—H13A	119.8
H4A—C4—H4C	109.5	C14A—C13A—C12A	120.2 (5)
H4B—C4—H4C	109.5	C14A—C13A—H13B	119.9
C3A—C4A—H4AA	109.5	C12A—C13A—H13B	119.9
C3A—C4A—H4AB	109.5	C9—C14—C13	118.4 (5)
H4AA—C4A—H4AB	109.5	C9—C14—H14A	120.8
C3A—C4A—H4AC	109.5	C13—C14—H14A	120.8
H4AA—C4A—H4AC	109.5	C13A—C14A—C9A	118.7 (5)
H4AB—C4A—H4AC	109.5	C13A—C14A—H14B	120.7
N4—C5—N3	118.2 (4)	C9A—C14A—H14B	120.7
O1—P1—O2—C9	−58.7 (4)	N2A—O3A—C3A—C4A	−178.2 (4)
N1—P1—O2—C9	−178.6 (4)	O4—N4—C5—N3	−179.6 (4)
N3—P1—O2—C9	66.7 (4)	O4—N4—C5—C6	0.7 (5)
O1A—P2—O2A—C9A	60.7 (4)	P1—N3—C5—N4	−169.3 (3)
N3A—P2—O2A—C9A	−179.5 (3)	P1—N3—C5—C6	10.2 (7)
N1A—P2—O2A—C9A	−64.7 (4)	O4A—N4A—C5A—N3A	177.8 (4)
O1—P1—N1—C1	176.5 (4)	O4A—N4A—C5A—C6A	−0.1 (5)
O2—P1—N1—C1	−58.2 (5)	P2—N3A—C5A—N4A	3.5 (7)
N3—P1—N1—C1	49.1 (5)	P2—N3A—C5A—C6A	−178.8 (4)
O1A—P2—N1A—C1A	49.7 (4)	N4—C5—C6—C7	−0.4 (6)
O2A—P2—N1A—C1A	175.5 (4)	N3—C5—C6—C7	−180.0 (5)
N3A—P2—N1A—C1A	−74.0 (4)	N4A—C5A—C6A—C7A	0.0 (6)
C3—O3—N2—C1	0.0 (5)	N3A—C5A—C6A—C7A	−178.0 (4)
C3A—O3A—N2A—C1A	0.1 (5)	C5—C6—C7—O4	−0.1 (5)
O1—P1—N3—C5	−48.8 (4)	C5—C6—C7—C8	179.5 (6)
O2—P1—N3—C5	−175.7 (4)	N4—O4—C7—C6	0.6 (5)
N1—P1—N3—C5	75.3 (4)	N4—O4—C7—C8	−179.2 (4)
O1A—P2—N3A—C5A	−168.7 (4)	C5A—C6A—C7A—O4A	0.2 (5)
O2A—P2—N3A—C5A	66.8 (5)	C5A—C6A—C7A—C8A	−179.8 (5)
N1A—P2—N3A—C5A	−41.3 (5)	N4A—O4A—C7A—C6A	−0.2 (5)
C7—O4—N4—C5	−0.8 (5)	N4A—O4A—C7A—C8A	179.7 (4)
C7A—O4A—N4A—C5A	0.2 (5)	P1—O2—C9—C14	6.2 (7)
O3—N2—C1—N1	179.6 (4)	P1—O2—C9—C10	−174.5 (3)
O3—N2—C1—C2	0.5 (5)	P2—O2A—C9A—C10A	−63.1 (6)
P1—N1—C1—N2	−1.5 (7)	P2—O2A—C9A—C14A	119.0 (4)
P1—N1—C1—C2	177.5 (4)	C14—C9—C10—C11	0.0 (8)
O3A—N2A—C1A—N1A	177.8 (4)	O2—C9—C10—C11	−179.3 (5)
O3A—N2A—C1A—C2A	−1.1 (5)	C14A—C9A—C10A—C11A	−0.1 (8)
P2—N1A—C1A—N2A	157.4 (3)	O2A—C9A—C10A—C11A	−177.8 (4)
P2—N1A—C1A—C2A	−23.9 (7)	C9—C10—C11—C12	−0.5 (8)
N2—C1—C2—C3	−0.7 (6)	C9A—C10A—C11A—C12A	0.2 (8)
N1—C1—C2—C3	−179.9 (5)	C10—C11—C12—C13	0.0 (9)
N2A—C1A—C2A—C3A	1.7 (5)	C10A—C11A—C12A—C13A	−0.5 (8)
N1A—C1A—C2A—C3A	−177.0 (4)	C11—C12—C13—C14	1.0 (9)
N2—O3—C3—C2	−0.5 (5)	C11A—C12A—C13A—C14A	0.8 (8)
N2—O3—C3—C4	−179.4 (4)	C10—C9—C14—C13	1.0 (8)
C1—C2—C3—O3	0.7 (6)	O2—C9—C14—C13	−179.8 (5)
C1—C2—C3—C4	179.4 (6)	C12—C13—C14—C9	−1.5 (8)
C1A—C2A—C3A—O3A	−1.6 (5)	C12A—C13A—C14A—C9A	−0.7 (8)
C1A—C2A—C3A—C4A	177.4 (5)	C10A—C9A—C14A—C13A	0.3 (8)
N2A—O3A—C3A—C2A	1.1 (5)	O2A—C9A—C14A—C13A	178.1 (4)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N1A—H1NA···O1^i	0.91	2.16	3.054 (5)	166
N1—H1N···N2A^ii	0.91	1.94	2.842 (6)	170
N3A—H3NA···N4	0.91	1.91	2.824 (6)	177
N3—H3N···O1A	0.91	2.08	2.974 (5)	168

Symmetry codes: (i) x, y−1, z; (ii) x, y+1, z.

(IGCN)

Crystal data

C34H36CeN7O14P2·C2H6O	F(000) = 4120
Mr = 1014.83	Dx = 1.557 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 14.8817 (5) Å	Cell parameters from 9920 reflections
b = 15.9332 (5) Å	θ = 2.3–30.5°
c = 36.7289 (12) Å	µ = 1.20 mm^−1
β = 96.133 (1)°	T = 100 K
V = 8659.1 (5) Å^3	Prism, colourless
Z = 8	0.17 × 0.12 × 0.10 mm

Data collection

Bruker APEX-II CCD diffractometer	20861 independent reflections
Radiation source: fine-focus sealed tube	14486 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.081
ϕ and ω scans	θmax = 28.0°, θmin = 1.7°
Absorption correction: multi-scan SADABS (Sheldrick, 2003)	h = −19→19
Tmin = 0.741, Tmax = 0.889	k = −21→21
98260 measured reflections	l = −48→48

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.046	Hydrogen site location: mixed
wR(F^2) = 0.090	H atoms treated by a mixture of independent and constrained refinement
S = 1.05	w = 1/[σ^2(Fo^2) + (0.0251P)^2 + 14.9859P] where P = (Fo^2 + 2Fc^2)/3
20861 reflections	(Δ/σ)max = 0.002
1157 parameters	Δρmax = 1.08 e Å^−3
0 restraints	Δρmin = −1.34 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ce1A	0.269159 (14)	0.481741 (14)	0.123985 (5)	0.01154 (5)
P1A	0.48040 (7)	0.36220 (6)	0.12083 (3)	0.0138 (2)
P2A	0.03072 (7)	0.37417 (6)	0.12068 (3)	0.0146 (2)
O1A	0.2353 (2)	0.47363 (18)	0.19169 (7)	0.0222 (6)
O2A	0.3526 (2)	0.54571 (19)	0.18160 (8)	0.0240 (7)
O3A	0.3019 (2)	0.55200 (19)	0.23494 (8)	0.0341 (8)
O4A	0.1686 (2)	0.60666 (19)	0.14478 (8)	0.0264 (7)
O5A	0.1623 (2)	0.58623 (18)	0.08617 (8)	0.0226 (7)
O6A	0.0764 (3)	0.6798 (2)	0.10756 (11)	0.0494 (10)
O7A	0.33430 (19)	0.54397 (16)	0.06335 (7)	0.0181 (6)
O8A	0.35937 (19)	0.61651 (16)	0.11349 (7)	0.0163 (6)
O9A	0.4310 (2)	0.64657 (18)	0.06643 (8)	0.0242 (7)
O10A	0.2399 (2)	0.3843 (2)	0.07019 (8)	0.0203 (7)
H10V	0.216 (4)	0.347 (4)	0.0751 (17)	0.06 (2)*
O11A	0.42547 (18)	0.44113 (17)	0.11888 (8)	0.0171 (6)
O12A	0.12034 (18)	0.41706 (17)	0.12574 (7)	0.0169 (6)
O13A	0.24718 (18)	0.28949 (17)	0.17459 (7)	0.0185 (6)
O14A	0.1901 (2)	0.16903 (18)	0.07754 (8)	0.0221 (6)
N1A	0.2967 (2)	0.5240 (2)	0.20367 (9)	0.0221 (8)
N2A	0.1349 (2)	0.6255 (2)	0.11251 (11)	0.0243 (8)
N3A	0.3757 (2)	0.6034 (2)	0.08087 (9)	0.0163 (7)
N4A	0.3061 (2)	0.3258 (2)	0.15124 (8)	0.0150 (7)
N5A	0.4167 (2)	0.2770 (2)	0.11596 (9)	0.0152 (7)
H5A	0.432 (3)	0.240 (3)	0.1033 (13)	0.023 (13)*
N6A	0.1458 (2)	0.2420 (2)	0.08856 (9)	0.0181 (7)
N7A	0.0333 (2)	0.2715 (2)	0.12680 (10)	0.0172 (7)
H7A	0.005 (3)	0.253 (3)	0.1421 (12)	0.018 (12)*
C1A	0.2781 (4)	0.3661 (4)	0.03635 (14)	0.0246 (12)	0.82
H1AA	0.3359	0.3357	0.0422	0.030*	0.82
H1AB	0.2916	0.4197	0.0244	0.030*	0.82
C2A	0.2180 (4)	0.3151 (4)	0.01022 (14)	0.0302 (13)	0.82
H2AA	0.2432	0.3125	−0.0133	0.045*	0.82
H2AB	0.1579	0.3410	0.0067	0.045*	0.82
H2AC	0.2130	0.2582	0.0200	0.045*	0.82
C1'A	0.229 (2)	0.3814 (18)	0.0323 (7)	0.028 (6)*	0.18
H1'A	0.2572	0.4311	0.0221	0.034*	0.18
H1'B	0.1636	0.3815	0.0233	0.034*	0.18
C2'A	0.2736 (19)	0.3002 (16)	0.0199 (7)	0.025 (5)*	0.18
H2'A	0.2811	0.3042	−0.0063	0.037*	0.18
H2'B	0.2353	0.2519	0.0240	0.037*	0.18
H2'C	0.3329	0.2931	0.0339	0.037*	0.18
C3A	0.3503 (3)	0.2623 (2)	0.13921 (10)	0.0142 (8)
C4A	0.3238 (3)	0.1851 (2)	0.15310 (11)	0.0181 (8)
H4AA	0.3463	0.1309	0.1483	0.022*
C5A	0.2591 (3)	0.2054 (2)	0.17487 (11)	0.0189 (9)
C6A	0.2038 (4)	0.1572 (3)	0.19818 (12)	0.0318 (11)
H6AA	0.1399	0.1717	0.1921	0.048*
H6AB	0.2221	0.1706	0.2239	0.048*
H6AC	0.2123	0.0971	0.1941	0.048*
C7A	0.0872 (3)	0.2148 (2)	0.10990 (11)	0.0165 (8)
C8A	0.0888 (3)	0.1267 (3)	0.11385 (11)	0.0223 (9)
H8AA	0.0522	0.0929	0.1276	0.027*
C9A	0.1541 (3)	0.1018 (3)	0.09364 (12)	0.0247 (10)
C10A	0.1958 (4)	0.0193 (3)	0.08638 (14)	0.0459 (14)
H10A	0.2350	0.0014	0.1082	0.069*
H10B	0.2318	0.0248	0.0657	0.069*
H10C	0.1482	−0.0225	0.0806	0.069*
C11A	0.5455 (3)	0.3545 (3)	0.16491 (11)	0.0161 (8)
C12A	0.5589 (3)	0.4270 (3)	0.18640 (11)	0.0199 (9)
H12A	0.5352	0.4794	0.1775	0.024*
C13A	0.6072 (3)	0.4214 (3)	0.22093 (12)	0.0234 (9)
H13A	0.6173	0.4704	0.2355	0.028*
C14A	0.6407 (3)	0.3451 (3)	0.23411 (12)	0.0262 (10)
H14A	0.6733	0.3418	0.2578	0.031*
C15A	0.6268 (3)	0.2730 (3)	0.21281 (12)	0.0243 (10)
H15A	0.6501	0.2207	0.2220	0.029*
C16A	0.5792 (3)	0.2772 (3)	0.17821 (11)	0.0186 (8)
H16A	0.5696	0.2280	0.1637	0.022*
C17A	0.5473 (3)	0.3531 (2)	0.08322 (11)	0.0149 (8)
C18A	0.6195 (3)	0.2976 (2)	0.08366 (11)	0.0178 (8)
H18A	0.6390	0.2668	0.1052	0.021*
C19A	0.6628 (3)	0.2877 (3)	0.05240 (11)	0.0210 (9)
H19A	0.7123	0.2500	0.0526	0.025*
C20A	0.6343 (3)	0.3325 (3)	0.02067 (12)	0.0208 (9)
H20A	0.6634	0.3248	−0.0009	0.025*
C21A	0.5630 (3)	0.3886 (3)	0.02091 (11)	0.0209 (9)
H21A	0.5439	0.4198	−0.0006	0.025*
C22A	0.5195 (3)	0.3997 (3)	0.05184 (11)	0.0185 (9)
H22A	0.4711	0.4386	0.0518	0.022*
C23A	−0.0426 (3)	0.4048 (2)	0.15384 (11)	0.0188 (9)
C24A	−0.1327 (3)	0.3777 (3)	0.14954 (12)	0.0212 (9)
H24A	−0.1553	0.3467	0.1284	0.025*
C25A	−0.1885 (3)	0.3964 (3)	0.17613 (12)	0.0258 (10)
H25A	−0.2495	0.3778	0.1735	0.031*
C26A	−0.1556 (3)	0.4421 (3)	0.20662 (12)	0.0270 (10)
H26A	−0.1942	0.4552	0.2248	0.032*
C27A	−0.0666 (3)	0.4688 (3)	0.21077 (13)	0.0313 (11)
H27A	−0.0443	0.4997	0.2319	0.038*
C28A	−0.0097 (3)	0.4508 (3)	0.18433 (12)	0.0248 (10)
H28A	0.0511	0.4698	0.1871	0.030*
C29A	−0.0268 (3)	0.3951 (3)	0.07624 (11)	0.0177 (8)
C30A	−0.0771 (3)	0.3355 (3)	0.05568 (11)	0.0211 (9)
H30A	−0.0786	0.2793	0.0643	0.025*
C31A	−0.1254 (3)	0.3571 (3)	0.02266 (12)	0.0248 (10)
H31A	−0.1591	0.3155	0.0086	0.030*
C32A	−0.1249 (3)	0.4385 (3)	0.01004 (14)	0.0380 (12)
H32A	−0.1590	0.4532	−0.0124	0.046*
C33A	−0.0745 (4)	0.4986 (3)	0.03023 (17)	0.0541 (18)
H33A	−0.0735	0.5547	0.0216	0.065*
C34A	−0.0255 (4)	0.4770 (3)	0.06313 (15)	0.0431 (14)
H34A	0.0093	0.5184	0.0768	0.052*
Ce1B	0.650088 (13)	0.982188 (14)	0.118436 (5)	0.01131 (5)
P1B	0.43786 (7)	0.86463 (6)	0.11988 (3)	0.0125 (2)
P2B	0.88136 (7)	0.86881 (6)	0.11375 (3)	0.0151 (2)
O1B	0.73256 (18)	0.97982 (18)	0.18473 (7)	0.0203 (6)
O2B	0.6100 (2)	1.05394 (19)	0.17740 (8)	0.0235 (7)
O3B	0.6987 (2)	1.06294 (18)	0.22852 (8)	0.0268 (7)
O4B	0.73500 (19)	1.07334 (17)	0.07385 (8)	0.0201 (6)
O5B	0.7678 (2)	1.10678 (18)	0.13069 (8)	0.0212 (6)
O6B	0.8481 (2)	1.1570 (2)	0.08944 (10)	0.0385 (9)
O7B	0.54330 (19)	1.04173 (16)	0.05960 (7)	0.0178 (6)
O8B	0.55431 (18)	1.11633 (16)	0.10929 (7)	0.0167 (6)
O9B	0.4434 (2)	1.13829 (19)	0.06652 (8)	0.0254 (7)
O10B	0.6431 (2)	0.87789 (19)	0.06688 (8)	0.0187 (6)
H10W	0.674 (3)	0.845 (3)	0.0723 (14)	0.029 (16)*
O11B	0.49135 (18)	0.94331 (16)	0.11855 (7)	0.0160 (6)
O12B	0.79850 (18)	0.91878 (16)	0.11778 (7)	0.0158 (6)
O13B	0.69995 (18)	0.79078 (17)	0.17323 (7)	0.0176 (6)
O14B	0.70596 (19)	0.65563 (17)	0.07603 (8)	0.0200 (6)
N1B	0.6806 (2)	1.0330 (2)	0.19788 (9)	0.0190 (8)
N2B	0.7850 (2)	1.1137 (2)	0.09755 (10)	0.0206 (8)
N3B	0.5125 (2)	1.0993 (2)	0.07790 (9)	0.0169 (7)
N4B	0.6306 (2)	0.8270 (2)	0.14906 (9)	0.0145 (7)
N5B	0.4987 (2)	0.7792 (2)	0.11496 (9)	0.0139 (7)
H5B	0.479 (4)	0.736 (3)	0.1018 (15)	0.048 (17)*
N6B	0.7480 (2)	0.7321 (2)	0.08778 (9)	0.0165 (7)
N7B	0.8770 (2)	0.7695 (2)	0.12639 (10)	0.0183 (8)
H7B	0.912 (3)	0.755 (3)	0.1417 (13)	0.023 (13)*
C1B	0.6148 (3)	0.8699 (3)	0.02800 (11)	0.0219 (9)
H1BA	0.6688	0.8681	0.0145	0.026*
H1BB	0.5786	0.9197	0.0195	0.026*
C2B	0.5593 (3)	0.7917 (3)	0.01954 (12)	0.0259 (10)
H2BA	0.5441	0.7868	−0.0070	0.039*
H2BB	0.5036	0.7951	0.0315	0.039*
H2BC	0.5941	0.7424	0.0286	0.039*
C3B	0.5765 (3)	0.7642 (2)	0.13841 (10)	0.0134 (8)
C4B	0.6073 (3)	0.6865 (3)	0.15389 (11)	0.0183 (8)
H4BA	0.5804	0.6327	0.1503	0.022*
C5B	0.6838 (3)	0.7074 (3)	0.17494 (11)	0.0202 (9)
C6B	0.7494 (3)	0.6586 (3)	0.20042 (13)	0.0324 (11)
H6BA	0.8111	0.6705	0.1949	0.049*
H6BB	0.7370	0.5985	0.1973	0.049*
H6BC	0.7429	0.6748	0.2258	0.049*
C7B	0.8188 (3)	0.7097 (2)	0.10992 (11)	0.0181 (8)
C8B	0.8272 (3)	0.6218 (3)	0.11423 (13)	0.0276 (10)
H8BA	0.8725	0.5911	0.1288	0.033*
C9B	0.7548 (3)	0.5921 (3)	0.09241 (14)	0.0308 (11)
C10B	0.7205 (4)	0.5058 (3)	0.08298 (18)	0.0554 (18)
H10D	0.7129	0.4990	0.0563	0.083*
H10E	0.6622	0.4976	0.0926	0.083*
H10F	0.7639	0.4642	0.0938	0.083*
C11B	0.3510 (3)	0.8569 (2)	0.08228 (11)	0.0150 (8)
C12B	0.2739 (3)	0.8067 (2)	0.08315 (11)	0.0163 (8)
H12B	0.2643	0.7766	0.1047	0.020*
C13B	0.2117 (3)	0.8011 (3)	0.05240 (11)	0.0206 (9)
H13B	0.1592	0.7674	0.0529	0.025*
C14B	0.2261 (3)	0.8448 (3)	0.02075 (12)	0.0206 (9)
H14B	0.1832	0.8408	−0.0003	0.025*
C15B	0.3021 (3)	0.8939 (3)	0.01954 (11)	0.0217 (9)
H15B	0.3117	0.9230	−0.0023	0.026*
C16B	0.3645 (3)	0.9008 (3)	0.05024 (11)	0.0176 (8)
H16B	0.4164	0.9353	0.0496	0.021*
C17B	0.3937 (2)	0.8571 (2)	0.16338 (10)	0.0130 (8)
C18B	0.3908 (3)	0.9286 (3)	0.18508 (11)	0.0182 (9)
H18B	0.4112	0.9809	0.1767	0.022*
C19B	0.3581 (3)	0.9233 (3)	0.21900 (11)	0.0204 (9)
H19B	0.3553	0.9722	0.2336	0.024*
C20B	0.3293 (3)	0.8463 (3)	0.23169 (11)	0.0230 (9)
H20B	0.3073	0.8427	0.2550	0.028*
C21B	0.3331 (3)	0.7749 (3)	0.21013 (11)	0.0229 (9)
H21B	0.3137	0.7224	0.2188	0.027*
C22B	0.3650 (3)	0.7796 (3)	0.17612 (11)	0.0173 (8)
H22B	0.3674	0.7306	0.1615	0.021*
C23B	0.9073 (3)	0.8692 (3)	0.06684 (11)	0.0186 (9)
C24B	0.8850 (3)	0.9384 (3)	0.04515 (12)	0.0297 (11)
H24B	0.8539	0.9843	0.0546	0.036*
C25B	0.9083 (4)	0.9408 (4)	0.00939 (13)	0.0417 (14)
H25B	0.8935	0.9887	−0.0055	0.050*
C26B	0.9527 (3)	0.8740 (3)	−0.00455 (13)	0.0351 (12)
H26B	0.9689	0.8758	−0.0289	0.042*
C27B	0.9732 (3)	0.8046 (3)	0.01710 (12)	0.0317 (11)
H27B	1.0032	0.7584	0.0074	0.038*
C28B	0.9510 (3)	0.8006 (3)	0.05264 (12)	0.0229 (9)
H28B	0.9651	0.7522	0.0672	0.027*
C29B	0.9759 (3)	0.9054 (2)	0.14367 (11)	0.0163 (8)
C30B	1.0627 (3)	0.8777 (3)	0.13925 (12)	0.0223 (9)
H30B	1.0734	0.8442	0.1187	0.027*
C31B	1.1338 (3)	0.8995 (3)	0.16526 (12)	0.0242 (10)
H31B	1.1933	0.8809	0.1625	0.029*
C32B	1.1184 (3)	0.9479 (3)	0.19500 (12)	0.0241 (9)
H32B	1.1669	0.9614	0.2130	0.029*
C33B	1.0316 (3)	0.9773 (3)	0.19876 (12)	0.0236 (9)
H33B	1.0214	1.0120	0.2189	0.028*
C34B	0.9605 (3)	0.9558 (3)	0.17328 (11)	0.0203 (9)
H34B	0.9012	0.9754	0.1759	0.024*
O1S	−0.0719 (2)	0.1775 (2)	0.17235 (9)	0.0271 (7)
H1S	−0.108 (4)	0.154 (4)	0.1574 (15)	0.048 (18)*
C1S	−0.1070 (3)	0.1835 (3)	0.20704 (12)	0.0326 (11)
H1SA	−0.1256	0.1273	0.2150	0.039*
H1SB	−0.1608	0.2206	0.2049	0.039*
C2S	−0.0361 (4)	0.2183 (4)	0.23430 (14)	0.0432 (13)
H2SA	−0.0617	0.2289	0.2574	0.065*
H2SB	−0.0134	0.2711	0.2250	0.065*
H2SC	0.0137	0.1781	0.2385	0.065*
O2S	0.9991 (3)	0.6876 (2)	0.17914 (10)	0.0361 (9)
H2S	1.044 (4)	0.680 (4)	0.1683 (17)	0.06 (2)*
C3S	1.0337 (7)	0.7285 (5)	0.2130 (2)	0.044 (2)	0.70
H3SA	1.0799	0.7703	0.2078	0.053*	0.70
H3SB	0.9838	0.7590	0.2230	0.053*	0.70
C4S	1.0733 (9)	0.6700 (6)	0.2403 (3)	0.088 (4)	0.70
H4SA	1.0989	0.7010	0.2620	0.131*	0.70
H4SB	1.1213	0.6381	0.2302	0.131*	0.70
H4SC	1.0267	0.6313	0.2471	0.131*	0.70
C3S'	1.0253 (18)	0.6785 (18)	0.2187 (7)	0.065 (7)*	0.30
H3SC	0.9695	0.6752	0.2311	0.078*	0.30
H3SD	1.0578	0.6246	0.2230	0.078*	0.30
C4S'	1.0783 (17)	0.7410 (16)	0.2347 (7)	0.069 (7)*	0.30
H4SD	1.0896	0.7306	0.2611	0.104*	0.30
H4SE	1.0474	0.7950	0.2305	0.104*	0.30
H4SF	1.1359	0.7424	0.2241	0.104*	0.30

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ce1A	0.01315 (11)	0.01008 (10)	0.01141 (10)	0.00028 (9)	0.00146 (8)	−0.00101 (9)
P1A	0.0127 (5)	0.0124 (5)	0.0165 (5)	0.0011 (4)	0.0025 (4)	−0.0003 (4)
P2A	0.0127 (5)	0.0117 (5)	0.0195 (5)	0.0000 (4)	0.0019 (4)	−0.0021 (4)
O1A	0.0303 (17)	0.0208 (16)	0.0164 (14)	−0.0020 (14)	0.0064 (12)	−0.0007 (12)
O2A	0.0273 (17)	0.0289 (17)	0.0158 (15)	−0.0066 (13)	0.0020 (12)	−0.0036 (12)
O3A	0.067 (3)	0.0244 (17)	0.0112 (15)	−0.0051 (17)	0.0061 (15)	−0.0063 (12)
O4A	0.0351 (18)	0.0232 (17)	0.0212 (16)	0.0077 (14)	0.0049 (14)	−0.0018 (13)
O5A	0.0214 (16)	0.0214 (16)	0.0241 (17)	0.0037 (13)	−0.0019 (13)	0.0012 (12)
O6A	0.047 (2)	0.039 (2)	0.063 (3)	0.0267 (19)	0.005 (2)	0.0051 (19)
O7A	0.0259 (16)	0.0119 (14)	0.0159 (14)	−0.0041 (12)	−0.0009 (12)	−0.0036 (11)
O8A	0.0269 (16)	0.0148 (14)	0.0084 (13)	−0.0027 (12)	0.0070 (11)	−0.0020 (10)
O9A	0.0337 (18)	0.0234 (16)	0.0168 (15)	−0.0138 (14)	0.0093 (13)	−0.0017 (12)
O10A	0.0253 (17)	0.0184 (16)	0.0182 (15)	−0.0085 (14)	0.0073 (12)	−0.0048 (12)
O11A	0.0168 (15)	0.0123 (14)	0.0227 (15)	0.0014 (11)	0.0043 (12)	0.0017 (11)
O12A	0.0131 (14)	0.0162 (15)	0.0216 (15)	0.0008 (11)	0.0029 (11)	−0.0024 (11)
O13A	0.0199 (15)	0.0183 (15)	0.0188 (15)	−0.0020 (12)	0.0097 (12)	0.0034 (11)
O14A	0.0255 (16)	0.0190 (15)	0.0231 (16)	0.0070 (13)	0.0082 (13)	−0.0035 (12)
N1A	0.036 (2)	0.0185 (18)	0.0122 (16)	0.0072 (17)	0.0026 (15)	−0.0017 (15)
N2A	0.024 (2)	0.0140 (18)	0.034 (2)	0.0034 (15)	0.0020 (17)	0.0037 (16)
N3A	0.0231 (19)	0.0095 (16)	0.0165 (17)	−0.0011 (14)	0.0031 (14)	−0.0014 (13)
N4A	0.0165 (17)	0.0161 (17)	0.0128 (16)	−0.0011 (13)	0.0039 (13)	0.0033 (13)
N5A	0.0205 (18)	0.0102 (17)	0.0160 (17)	−0.0005 (14)	0.0073 (14)	−0.0018 (13)
N6A	0.0190 (18)	0.0132 (17)	0.0227 (19)	0.0031 (14)	0.0055 (14)	−0.0037 (14)
N7A	0.0183 (18)	0.0139 (18)	0.0206 (19)	0.0029 (14)	0.0075 (15)	−0.0016 (14)
C1A	0.029 (3)	0.027 (3)	0.019 (3)	−0.008 (3)	0.010 (2)	−0.009 (2)
C2A	0.041 (4)	0.034 (3)	0.015 (3)	−0.003 (3)	0.001 (2)	−0.004 (2)
C3A	0.0133 (19)	0.0108 (18)	0.018 (2)	−0.0003 (15)	−0.0005 (15)	0.0001 (15)
C4A	0.023 (2)	0.014 (2)	0.017 (2)	0.0015 (17)	−0.0004 (16)	0.0033 (15)
C5A	0.026 (2)	0.015 (2)	0.015 (2)	−0.0055 (17)	−0.0009 (17)	0.0034 (15)
C6A	0.050 (3)	0.025 (3)	0.023 (2)	−0.009 (2)	0.017 (2)	0.0050 (19)
C7A	0.021 (2)	0.0135 (19)	0.015 (2)	0.0011 (16)	0.0022 (16)	0.0000 (15)
C8A	0.035 (3)	0.014 (2)	0.019 (2)	0.0000 (18)	0.0083 (18)	−0.0010 (16)
C9A	0.041 (3)	0.014 (2)	0.019 (2)	0.0058 (19)	0.0057 (19)	0.0034 (17)
C10A	0.080 (4)	0.024 (2)	0.037 (3)	0.024 (3)	0.022 (3)	0.003 (2)
C11A	0.0134 (19)	0.020 (2)	0.016 (2)	−0.0002 (16)	0.0057 (15)	−0.0004 (16)
C12A	0.019 (2)	0.020 (2)	0.023 (2)	−0.0019 (17)	0.0081 (17)	−0.0028 (17)
C13A	0.023 (2)	0.022 (2)	0.026 (2)	−0.0031 (18)	0.0080 (18)	−0.0087 (18)
C14A	0.020 (2)	0.041 (3)	0.019 (2)	−0.001 (2)	0.0033 (17)	0.0007 (19)
C15A	0.025 (2)	0.026 (2)	0.022 (2)	0.0050 (19)	0.0051 (18)	0.0068 (18)
C16A	0.015 (2)	0.019 (2)	0.021 (2)	−0.0015 (16)	0.0033 (16)	0.0009 (16)
C17A	0.0098 (19)	0.016 (2)	0.019 (2)	−0.0008 (15)	0.0034 (15)	−0.0021 (15)
C18A	0.018 (2)	0.016 (2)	0.021 (2)	0.0002 (16)	0.0055 (16)	0.0054 (16)
C19A	0.017 (2)	0.021 (2)	0.025 (2)	0.0066 (17)	0.0055 (17)	−0.0017 (17)
C20A	0.018 (2)	0.024 (2)	0.021 (2)	−0.0013 (18)	0.0031 (17)	−0.0058 (17)
C21A	0.023 (2)	0.021 (2)	0.018 (2)	0.0017 (18)	−0.0035 (17)	−0.0015 (17)
C22A	0.017 (2)	0.017 (2)	0.021 (2)	0.0043 (17)	0.0022 (16)	−0.0028 (16)
C23A	0.019 (2)	0.014 (2)	0.025 (2)	0.0019 (16)	0.0075 (17)	−0.0022 (16)
C24A	0.018 (2)	0.024 (2)	0.023 (2)	−0.0007 (17)	0.0018 (17)	−0.0063 (17)
C25A	0.017 (2)	0.033 (3)	0.028 (2)	−0.0005 (19)	0.0078 (18)	−0.0018 (19)
C26A	0.025 (2)	0.028 (2)	0.030 (3)	0.005 (2)	0.0110 (19)	−0.0068 (19)
C27A	0.031 (3)	0.037 (3)	0.027 (2)	−0.004 (2)	0.0034 (19)	−0.014 (2)
C28A	0.015 (2)	0.027 (2)	0.032 (3)	−0.0018 (18)	0.0024 (18)	−0.0110 (19)
C29A	0.015 (2)	0.018 (2)	0.020 (2)	0.0005 (16)	0.0024 (16)	−0.0010 (16)
C30A	0.021 (2)	0.019 (2)	0.024 (2)	−0.0005 (17)	0.0059 (17)	−0.0030 (17)
C31A	0.021 (2)	0.033 (3)	0.020 (2)	−0.0057 (19)	0.0031 (17)	−0.0121 (19)
C32A	0.033 (3)	0.047 (3)	0.031 (3)	0.002 (2)	−0.009 (2)	0.009 (2)
C33A	0.067 (4)	0.025 (3)	0.061 (4)	−0.014 (3)	−0.034 (3)	0.020 (2)
C34A	0.051 (3)	0.019 (2)	0.053 (3)	−0.011 (2)	−0.025 (3)	0.003 (2)
Ce1B	0.01223 (11)	0.00969 (10)	0.01193 (10)	−0.00061 (9)	0.00083 (8)	−0.00124 (9)
P1B	0.0123 (5)	0.0121 (5)	0.0128 (5)	−0.0002 (4)	0.0003 (4)	−0.0008 (4)
P2B	0.0138 (5)	0.0123 (5)	0.0188 (5)	−0.0004 (4)	−0.0001 (4)	−0.0015 (4)
O1B	0.0241 (15)	0.0197 (14)	0.0166 (14)	0.0000 (13)	−0.0005 (11)	−0.0041 (12)
O2B	0.0260 (17)	0.0271 (16)	0.0171 (15)	0.0069 (13)	0.0004 (13)	−0.0022 (12)
O3B	0.046 (2)	0.0219 (16)	0.0115 (15)	−0.0044 (14)	0.0003 (13)	−0.0039 (12)
O4B	0.0201 (16)	0.0187 (15)	0.0210 (15)	−0.0025 (12)	0.0001 (12)	0.0037 (12)
O5B	0.0246 (16)	0.0189 (15)	0.0200 (16)	−0.0050 (13)	0.0017 (12)	0.0000 (12)
O6B	0.0305 (19)	0.039 (2)	0.045 (2)	−0.0193 (16)	0.0022 (16)	0.0156 (16)
O7B	0.0235 (16)	0.0143 (14)	0.0157 (14)	0.0028 (12)	0.0027 (12)	−0.0030 (11)
O8B	0.0198 (15)	0.0142 (14)	0.0149 (14)	0.0037 (11)	−0.0033 (11)	−0.0013 (11)
O9B	0.0250 (17)	0.0257 (17)	0.0241 (16)	0.0124 (13)	−0.0045 (13)	0.0016 (13)
O10B	0.0228 (16)	0.0157 (16)	0.0163 (15)	0.0060 (13)	−0.0039 (12)	−0.0033 (12)
O11B	0.0160 (14)	0.0127 (14)	0.0188 (15)	0.0001 (11)	0.0000 (11)	−0.0007 (11)
O12B	0.0148 (14)	0.0151 (14)	0.0170 (15)	0.0013 (11)	−0.0012 (11)	−0.0014 (11)
O13B	0.0190 (15)	0.0152 (14)	0.0171 (14)	−0.0014 (12)	−0.0048 (11)	0.0027 (11)
O14B	0.0217 (15)	0.0152 (15)	0.0219 (15)	−0.0032 (12)	−0.0023 (12)	−0.0052 (11)
N1B	0.030 (2)	0.0129 (18)	0.0141 (17)	−0.0077 (14)	0.0035 (14)	−0.0003 (13)
N2B	0.0227 (19)	0.0140 (18)	0.025 (2)	−0.0023 (15)	0.0029 (15)	0.0037 (14)
N3B	0.0222 (19)	0.0113 (16)	0.0172 (17)	0.0017 (14)	0.0026 (14)	0.0009 (13)
N4B	0.0121 (16)	0.0155 (17)	0.0149 (17)	0.0001 (13)	−0.0037 (13)	0.0030 (13)
N5B	0.0153 (17)	0.0106 (16)	0.0153 (17)	−0.0021 (13)	−0.0002 (13)	−0.0023 (13)
N6B	0.0173 (17)	0.0113 (17)	0.0201 (18)	−0.0036 (13)	−0.0016 (14)	−0.0046 (13)
N7B	0.0153 (18)	0.0169 (18)	0.0211 (19)	0.0027 (14)	−0.0054 (15)	−0.0011 (14)
C1B	0.030 (2)	0.019 (2)	0.017 (2)	−0.0014 (18)	0.0015 (18)	−0.0034 (16)
C2B	0.034 (3)	0.025 (2)	0.018 (2)	−0.007 (2)	−0.0037 (19)	−0.0027 (17)
C3B	0.0146 (19)	0.0131 (19)	0.0130 (19)	−0.0006 (15)	0.0044 (15)	−0.0010 (14)
C4B	0.023 (2)	0.015 (2)	0.017 (2)	−0.0034 (17)	0.0029 (16)	0.0027 (15)
C5B	0.030 (2)	0.014 (2)	0.016 (2)	0.0010 (18)	0.0009 (17)	0.0054 (16)
C6B	0.038 (3)	0.022 (2)	0.034 (3)	0.005 (2)	−0.014 (2)	0.009 (2)
C7B	0.019 (2)	0.013 (2)	0.022 (2)	0.0026 (16)	0.0035 (17)	−0.0021 (16)
C8B	0.030 (3)	0.016 (2)	0.035 (3)	0.0001 (19)	−0.008 (2)	0.0002 (19)
C9B	0.031 (3)	0.017 (2)	0.042 (3)	−0.001 (2)	−0.008 (2)	0.002 (2)
C10B	0.057 (4)	0.016 (3)	0.085 (5)	−0.009 (2)	−0.029 (3)	−0.003 (3)
C11B	0.0121 (19)	0.016 (2)	0.017 (2)	0.0011 (16)	0.0009 (15)	−0.0041 (15)
C12B	0.018 (2)	0.014 (2)	0.016 (2)	−0.0005 (16)	0.0041 (16)	−0.0001 (15)
C13B	0.016 (2)	0.020 (2)	0.024 (2)	−0.0029 (17)	−0.0041 (17)	−0.0066 (17)
C14B	0.018 (2)	0.020 (2)	0.022 (2)	0.0039 (17)	−0.0057 (17)	−0.0061 (17)
C15B	0.029 (2)	0.021 (2)	0.014 (2)	0.0013 (19)	−0.0006 (17)	−0.0024 (16)
C16B	0.017 (2)	0.018 (2)	0.017 (2)	0.0014 (17)	0.0003 (16)	−0.0010 (16)
C17B	0.0098 (18)	0.018 (2)	0.0106 (18)	0.0012 (15)	−0.0010 (14)	−0.0008 (15)
C18B	0.013 (2)	0.020 (2)	0.020 (2)	−0.0015 (16)	−0.0011 (16)	−0.0046 (16)
C19B	0.016 (2)	0.023 (2)	0.022 (2)	0.0042 (17)	0.0010 (17)	−0.0067 (17)
C20B	0.024 (2)	0.034 (3)	0.012 (2)	0.0024 (19)	0.0048 (17)	0.0014 (17)
C21B	0.026 (2)	0.020 (2)	0.022 (2)	0.0000 (18)	0.0037 (18)	0.0050 (17)
C22B	0.017 (2)	0.018 (2)	0.017 (2)	−0.0011 (16)	0.0018 (16)	−0.0030 (16)
C23B	0.014 (2)	0.021 (2)	0.021 (2)	0.0010 (17)	0.0006 (16)	−0.0016 (17)
C24B	0.038 (3)	0.030 (3)	0.022 (2)	0.009 (2)	0.007 (2)	0.0032 (19)
C25B	0.052 (3)	0.050 (3)	0.024 (3)	0.016 (3)	0.012 (2)	0.015 (2)
C26B	0.026 (3)	0.060 (4)	0.021 (2)	0.005 (2)	0.0069 (19)	−0.001 (2)
C27B	0.019 (2)	0.050 (3)	0.025 (3)	0.005 (2)	−0.0027 (19)	−0.016 (2)
C28B	0.018 (2)	0.027 (2)	0.023 (2)	0.0048 (18)	−0.0019 (17)	−0.0045 (18)
C29B	0.016 (2)	0.0141 (19)	0.018 (2)	−0.0028 (16)	−0.0023 (16)	0.0008 (15)
C30B	0.019 (2)	0.023 (2)	0.024 (2)	0.0017 (18)	0.0016 (17)	−0.0058 (18)
C31B	0.014 (2)	0.021 (2)	0.036 (3)	0.0012 (18)	−0.0003 (18)	−0.0035 (19)
C32B	0.021 (2)	0.022 (2)	0.027 (2)	−0.0065 (18)	−0.0072 (18)	−0.0009 (18)
C33B	0.024 (2)	0.021 (2)	0.026 (2)	−0.0006 (19)	0.0019 (17)	−0.0039 (19)
C34B	0.015 (2)	0.023 (2)	0.024 (2)	0.0001 (17)	0.0026 (17)	−0.0015 (17)
O1S	0.0282 (18)	0.0293 (18)	0.0246 (18)	−0.0076 (15)	0.0064 (14)	−0.0002 (14)
C1S	0.032 (3)	0.041 (3)	0.027 (3)	0.000 (2)	0.011 (2)	0.004 (2)
C2S	0.044 (3)	0.057 (4)	0.029 (3)	−0.007 (3)	0.004 (2)	−0.007 (2)
O2S	0.034 (2)	0.044 (2)	0.030 (2)	0.0077 (17)	−0.0017 (16)	0.0040 (16)
C3S	0.078 (6)	0.033 (5)	0.020 (4)	0.007 (4)	−0.003 (4)	−0.003 (3)
C4S	0.129 (10)	0.051 (6)	0.067 (7)	0.022 (6)	−0.067 (7)	−0.008 (5)

Geometric parameters (Å, º)

Ce1A—O11A	2.441 (3)	Ce1B—O7B	2.713 (3)
Ce1A—O12A	2.450 (3)	Ce1B—N4B	2.744 (3)
Ce1A—O10A	2.514 (3)	Ce1B—N1B	3.016 (3)
Ce1A—O2A	2.549 (3)	P1B—O11B	1.489 (3)
Ce1A—O8A	2.583 (3)	P1B—N5B	1.655 (3)
Ce1A—O1A	2.593 (3)	P1B—C11B	1.792 (4)
Ce1A—O5A	2.599 (3)	P1B—C17B	1.795 (4)
Ce1A—O4A	2.651 (3)	P2B—O12B	1.488 (3)
Ce1A—O7A	2.710 (3)	P2B—N7B	1.653 (4)
Ce1A—N4A	2.712 (3)	P2B—C29B	1.788 (4)
Ce1A—N1A	2.988 (3)	P2B—C23B	1.806 (4)
P1A—O11A	1.498 (3)	O1B—N1B	1.276 (4)
P1A—N5A	1.655 (3)	O2B—N1B	1.270 (4)
P1A—C17A	1.793 (4)	O3B—N1B	1.225 (4)
P1A—C11A	1.800 (4)	O4B—N2B	1.259 (4)
P2A—O12A	1.492 (3)	O5B—N2B	1.275 (4)
P2A—N7A	1.651 (4)	O6B—N2B	1.228 (4)
P2A—C23A	1.788 (4)	O7B—N3B	1.253 (4)
P2A—C29A	1.792 (4)	O8B—N3B	1.279 (4)
O1A—N1A	1.260 (4)	O9B—N3B	1.235 (4)
O2A—N1A	1.269 (4)	O10B—C1B	1.451 (5)
O3A—N1A	1.227 (4)	O10B—H10W	0.71 (5)
O4A—N2A	1.272 (5)	O13B—C5B	1.352 (5)
O5A—N2A	1.256 (5)	O13B—N4B	1.411 (4)
O6A—N2A	1.227 (5)	O14B—C9B	1.350 (5)
O7A—N3A	1.266 (4)	O14B—N6B	1.416 (4)
O8A—N3A	1.265 (4)	N4B—C3B	1.317 (5)
O9A—N3A	1.235 (4)	N5B—C3B	1.388 (5)
O10A—C1'A	1.38 (3)	N5B—H5B	0.87 (5)
O10A—C1A	1.450 (6)	N6B—C7B	1.310 (5)
O10A—H10V	0.73 (6)	N7B—C7B	1.382 (5)
O13A—C5A	1.351 (5)	N7B—H7B	0.76 (5)
O13A—N4A	1.415 (4)	C1B—C2B	1.508 (6)
O14A—C9A	1.360 (5)	C1B—H1BA	0.9900
O14A—N6A	1.417 (4)	C1B—H1BB	0.9900
N4A—C3A	1.310 (5)	C2B—H2BA	0.9800
N5A—C3A	1.393 (5)	C2B—H2BB	0.9800
N5A—H5A	0.80 (5)	C2B—H2BC	0.9800
N6A—C7A	1.307 (5)	C3B—C4B	1.418 (5)
N7A—C7A	1.397 (5)	C4B—C5B	1.348 (6)
N7A—H7A	0.80 (4)	C4B—H4BA	0.9500
C1A—C2A	1.482 (7)	C5B—C6B	1.497 (6)
C1A—H1AA	0.9900	C6B—H6BA	0.9800
C1A—H1AB	0.9900	C6B—H6BB	0.9800
C2A—H2AA	0.9800	C6B—H6BC	0.9800
C2A—H2AB	0.9800	C7B—C8B	1.413 (6)
C2A—H2AC	0.9800	C8B—C9B	1.358 (6)
C1'A—C2'A	1.55 (4)	C8B—H8BA	0.9500
C1'A—H1'A	0.9900	C9B—C10B	1.495 (6)
C1'A—H1'B	0.9900	C10B—H10D	0.9800
C2'A—H2'A	0.9800	C10B—H10E	0.9800
C2'A—H2'B	0.9800	C10B—H10F	0.9800
C2'A—H2'C	0.9800	C11B—C16B	1.402 (5)
C3A—C4A	1.403 (5)	C11B—C12B	1.403 (5)
C4A—C5A	1.355 (6)	C12B—C13B	1.384 (5)
C4A—H4AA	0.9500	C12B—H12B	0.9500
C5A—C6A	1.467 (6)	C13B—C14B	1.391 (6)
C6A—H6AA	0.9800	C13B—H13B	0.9500
C6A—H6AB	0.9800	C14B—C15B	1.380 (6)
C6A—H6AC	0.9800	C14B—H14B	0.9500
C7A—C8A	1.410 (5)	C15B—C16B	1.386 (5)
C8A—C9A	1.345 (6)	C15B—H15B	0.9500
C8A—H8AA	0.9500	C16B—H16B	0.9500
C9A—C10A	1.490 (6)	C17B—C18B	1.393 (5)
C10A—H10A	0.9800	C17B—C22B	1.404 (5)
C10A—H10B	0.9800	C18B—C19B	1.388 (6)
C10A—H10C	0.9800	C18B—H18B	0.9500
C11A—C16A	1.399 (6)	C19B—C20B	1.395 (6)
C11A—C12A	1.401 (5)	C19B—H19B	0.9500
C12A—C13A	1.393 (6)	C20B—C21B	1.391 (6)
C12A—H12A	0.9500	C20B—H20B	0.9500
C13A—C14A	1.381 (6)	C21B—C22B	1.385 (6)
C13A—H13A	0.9500	C21B—H21B	0.9500
C14A—C15A	1.393 (6)	C22B—H22B	0.9500
C14A—H14A	0.9500	C23B—C24B	1.379 (6)
C15A—C16A	1.389 (6)	C23B—C28B	1.400 (6)
C15A—H15A	0.9500	C24B—C25B	1.394 (6)
C16A—H16A	0.9500	C24B—H24B	0.9500
C17A—C18A	1.390 (5)	C25B—C26B	1.380 (7)
C17A—C22A	1.396 (6)	C25B—H25B	0.9500
C18A—C19A	1.384 (6)	C26B—C27B	1.377 (7)
C18A—H18A	0.9500	C26B—H26B	0.9500
C19A—C20A	1.393 (6)	C27B—C28B	1.382 (6)
C19A—H19A	0.9500	C27B—H27B	0.9500
C20A—C21A	1.388 (6)	C28B—H28B	0.9500
C20A—H20A	0.9500	C29B—C30B	1.391 (6)
C21A—C22A	1.377 (6)	C29B—C34B	1.391 (6)
C21A—H21A	0.9500	C30B—C31B	1.392 (6)
C22A—H22A	0.9500	C30B—H30B	0.9500
C23A—C28A	1.383 (6)	C31B—C32B	1.376 (6)
C23A—C24A	1.401 (6)	C31B—H31B	0.9500
C24A—C25A	1.379 (6)	C32B—C33B	1.394 (6)
C24A—H24A	0.9500	C32B—H32B	0.9500
C25A—C26A	1.380 (6)	C33B—C34B	1.378 (6)
C25A—H25A	0.9500	C33B—H33B	0.9500
C26A—C27A	1.384 (6)	C34B—H34B	0.9500
C26A—H26A	0.9500	O1S—C1S	1.432 (5)
C27A—C28A	1.384 (6)	O1S—H1S	0.82 (6)
C27A—H27A	0.9500	C1S—C2S	1.483 (7)
C28A—H28A	0.9500	C1S—H1SA	0.9900
C29A—C30A	1.383 (6)	C1S—H1SB	0.9900
C29A—C34A	1.391 (6)	C2S—H2SA	0.9800
C30A—C31A	1.385 (6)	C2S—H2SB	0.9800
C30A—H30A	0.9500	C2S—H2SC	0.9800
C31A—C32A	1.378 (7)	O2S—C3S	1.449 (8)
C31A—H31A	0.9500	O2S—C3S'	1.47 (3)
C32A—C33A	1.382 (7)	O2S—H2S	0.83 (6)
C32A—H32A	0.9500	C3S—C4S	1.447 (11)
C33A—C34A	1.387 (7)	C3S—H3SA	0.9900
C33A—H33A	0.9500	C3S—H3SB	0.9900
C34A—H34A	0.9500	C4S—H4SA	0.9800
Ce1B—O12B	2.431 (3)	C4S—H4SB	0.9800
Ce1B—O11B	2.443 (3)	C4S—H4SC	0.9800
Ce1B—O10B	2.513 (3)	C3S'—C4S'	1.36 (3)
Ce1B—O8B	2.571 (3)	C3S'—H3SC	0.9900
Ce1B—O2B	2.574 (3)	C3S'—H3SD	0.9900
Ce1B—O1B	2.607 (3)	C4S'—H4SD	0.9800
Ce1B—O4B	2.613 (3)	C4S'—H4SE	0.9800
Ce1B—O5B	2.654 (3)	C4S'—H4SF	0.9800
O11A—Ce1A—O12A	139.65 (9)	O8B—Ce1B—O1B	109.46 (9)
O11A—Ce1A—O10A	82.09 (10)	O2B—Ce1B—O1B	49.38 (9)
O12A—Ce1A—O10A	71.31 (9)	O12B—Ce1B—O4B	73.99 (9)
O11A—Ce1A—O2A	77.65 (9)	O11B—Ce1B—O4B	132.41 (9)
O12A—Ce1A—O2A	120.53 (9)	O10B—Ce1B—O4B	83.07 (9)
O10A—Ce1A—O2A	158.06 (10)	O8B—Ce1B—O4B	75.79 (9)
O11A—Ce1A—O8A	72.19 (9)	O2B—Ce1B—O4B	116.82 (9)
O12A—Ce1A—O8A	147.07 (9)	O1B—Ce1B—O4B	112.48 (9)
O10A—Ce1A—O8A	116.45 (9)	O12B—Ce1B—O5B	74.27 (9)
O2A—Ce1A—O8A	64.95 (9)	O11B—Ce1B—O5B	144.12 (9)
O11A—Ce1A—O1A	110.19 (9)	O10B—Ce1B—O5B	126.59 (10)
O12A—Ce1A—O1A	71.63 (9)	O8B—Ce1B—O5B	75.33 (9)
O10A—Ce1A—O1A	133.45 (10)	O2B—Ce1B—O5B	74.51 (9)
O2A—Ce1A—O1A	49.55 (9)	O1B—Ce1B—O5B	67.43 (9)
O8A—Ce1A—O1A	110.00 (8)	O4B—Ce1B—O5B	48.40 (9)
O11A—Ce1A—O5A	131.46 (9)	O12B—Ce1B—O7B	126.36 (9)
O12A—Ce1A—O5A	77.32 (9)	O11B—Ce1B—O7B	66.78 (9)
O10A—Ce1A—O5A	86.04 (10)	O10B—Ce1B—O7B	69.96 (9)
O2A—Ce1A—O5A	113.79 (9)	O8B—Ce1B—O7B	48.39 (8)
O8A—Ce1A—O5A	71.68 (9)	O2B—Ce1B—O7B	110.25 (9)
O1A—Ce1A—O5A	111.95 (9)	O1B—Ce1B—O7B	157.83 (8)
O11A—Ce1A—O4A	142.48 (9)	O4B—Ce1B—O7B	65.67 (9)
O12A—Ce1A—O4A	76.62 (9)	O5B—Ce1B—O7B	101.14 (9)
O10A—Ce1A—O4A	129.36 (10)	O12B—Ce1B—N4B	76.43 (9)
O2A—Ce1A—O4A	72.58 (10)	O11B—Ce1B—N4B	68.07 (9)
O8A—Ce1A—O4A	74.77 (9)	O10B—Ce1B—N4B	73.47 (10)
O1A—Ce1A—O4A	65.64 (9)	O8B—Ce1B—N4B	136.15 (9)
O5A—Ce1A—O4A	48.79 (9)	O2B—Ce1B—N4B	90.64 (10)
O11A—Ce1A—O7A	66.82 (9)	O1B—Ce1B—N4B	70.36 (9)
O12A—Ce1A—O7A	125.40 (9)	O4B—Ce1B—N4B	146.80 (9)
O10A—Ce1A—O7A	68.12 (9)	O5B—Ce1B—N4B	134.51 (9)
O2A—Ce1A—O7A	110.52 (9)	O7B—Ce1B—N4B	124.27 (9)
O8A—Ce1A—O7A	48.39 (8)	O12B—Ce1B—N1B	94.47 (9)
O1A—Ce1A—O7A	158.39 (9)	O11B—Ce1B—N1B	96.45 (9)
O5A—Ce1A—O7A	65.07 (9)	O10B—Ce1B—N1B	153.70 (9)
O4A—Ce1A—O7A	102.97 (9)	O8B—Ce1B—N1B	85.83 (9)
O11A—Ce1A—N4A	68.17 (9)	O2B—Ce1B—N1B	24.67 (9)
O12A—Ce1A—N4A	75.72 (9)	O1B—Ce1B—N1B	24.90 (9)
O10A—Ce1A—N4A	74.67 (10)	O4B—Ce1B—N1B	115.09 (9)
O2A—Ce1A—N4A	89.90 (10)	O5B—Ce1B—N1B	66.82 (9)
O8A—Ce1A—N4A	136.73 (9)	O7B—Ce1B—N1B	133.76 (9)
O1A—Ce1A—N4A	69.70 (9)	N4B—Ce1B—N1B	81.77 (9)
O5A—Ce1A—N4A	150.71 (9)	O11B—P1B—N5B	112.82 (16)
O4A—Ce1A—N4A	132.82 (9)	O11B—P1B—C11B	112.14 (17)
O7A—Ce1A—N4A	124.20 (9)	N5B—P1B—C11B	102.55 (17)
O11A—Ce1A—N1A	95.90 (9)	O11B—P1B—C17B	109.45 (17)
O12A—Ce1A—N1A	95.68 (10)	N5B—P1B—C17B	107.40 (18)
O10A—Ce1A—N1A	154.55 (10)	C11B—P1B—C17B	112.27 (18)
O2A—Ce1A—N1A	24.92 (9)	O12B—P2B—N7B	115.23 (17)
O8A—Ce1A—N1A	86.54 (9)	O12B—P2B—C29B	111.74 (17)
O1A—Ce1A—N1A	24.83 (9)	N7B—P2B—C29B	101.03 (18)
O5A—Ce1A—N1A	113.03 (9)	O12B—P2B—C23B	110.94 (17)
O4A—Ce1A—N1A	64.63 (9)	N7B—P2B—C23B	106.88 (19)
O7A—Ce1A—N1A	134.31 (9)	C29B—P2B—C23B	110.53 (19)
N4A—Ce1A—N1A	81.01 (10)	N1B—O1B—Ce1B	95.8 (2)
O11A—P1A—N5A	112.36 (17)	N1B—O2B—Ce1B	97.5 (2)
O11A—P1A—C17A	112.12 (17)	N2B—O4B—Ce1B	98.0 (2)
N5A—P1A—C17A	102.06 (18)	N2B—O5B—Ce1B	95.7 (2)
O11A—P1A—C11A	109.80 (18)	N3B—O7B—Ce1B	92.6 (2)
N5A—P1A—C11A	106.78 (18)	N3B—O8B—Ce1B	98.7 (2)
C17A—P1A—C11A	113.43 (18)	C1B—O10B—Ce1B	141.7 (2)
O12A—P2A—N7A	115.42 (17)	C1B—O10B—H10W	109 (4)
O12A—P2A—C23A	113.13 (18)	Ce1B—O10B—H10W	107 (4)
N7A—P2A—C23A	100.66 (19)	P1B—O11B—Ce1B	137.24 (16)
O12A—P2A—C29A	111.20 (18)	P2B—O12B—Ce1B	170.54 (17)
N7A—P2A—C29A	108.09 (19)	C5B—O13B—N4B	108.0 (3)
C23A—P2A—C29A	107.61 (19)	C9B—O14B—N6B	108.1 (3)
N1A—O1A—Ce1A	95.4 (2)	O3B—N1B—O2B	121.9 (4)
N1A—O2A—Ce1A	97.3 (2)	O3B—N1B—O1B	121.6 (3)
N2A—O4A—Ce1A	95.0 (2)	O2B—N1B—O1B	116.5 (3)
N2A—O5A—Ce1A	97.9 (2)	O3B—N1B—Ce1B	171.4 (3)
N3A—O7A—Ce1A	93.0 (2)	O2B—N1B—Ce1B	57.82 (18)
N3A—O8A—Ce1A	99.1 (2)	O1B—N1B—Ce1B	59.34 (18)
C1'A—O10A—C1A	31.5 (12)	O6B—N2B—O4B	122.0 (4)
C1'A—O10A—Ce1A	143.4 (12)	O6B—N2B—O5B	121.1 (4)
C1A—O10A—Ce1A	138.3 (3)	O4B—N2B—O5B	116.9 (3)
C1'A—O10A—H10V	102 (5)	O9B—N3B—O7B	121.7 (3)
C1A—O10A—H10V	107 (5)	O9B—N3B—O8B	120.4 (3)
Ce1A—O10A—H10V	111 (5)	O7B—N3B—O8B	117.9 (3)
P1A—O11A—Ce1A	137.63 (16)	C3B—N4B—O13B	105.0 (3)
P2A—O12A—Ce1A	171.02 (17)	C3B—N4B—Ce1B	130.6 (2)
C5A—O13A—N4A	108.7 (3)	O13B—N4B—Ce1B	121.7 (2)
C9A—O14A—N6A	107.8 (3)	C3B—N5B—P1B	120.3 (3)
O3A—N1A—O1A	121.9 (4)	C3B—N5B—H5B	114 (4)
O3A—N1A—O2A	121.3 (4)	P1B—N5B—H5B	124 (4)
O1A—N1A—O2A	116.8 (3)	C7B—N6B—O14B	104.7 (3)
O3A—N1A—Ce1A	170.8 (3)	C7B—N7B—P2B	125.4 (3)
O1A—N1A—Ce1A	59.74 (17)	C7B—N7B—H7B	117 (4)
O2A—N1A—Ce1A	57.78 (18)	P2B—N7B—H7B	117 (4)
O6A—N2A—O5A	121.4 (4)	O10B—C1B—C2B	111.7 (3)
O6A—N2A—O4A	120.4 (4)	O10B—C1B—H1BA	109.3
O5A—N2A—O4A	118.2 (3)	C2B—C1B—H1BA	109.3
O9A—N3A—O8A	121.2 (3)	O10B—C1B—H1BB	109.3
O9A—N3A—O7A	120.6 (3)	C2B—C1B—H1BB	109.3
O8A—N3A—O7A	118.2 (3)	H1BA—C1B—H1BB	107.9
C3A—N4A—O13A	104.7 (3)	C1B—C2B—H2BA	109.5
C3A—N4A—Ce1A	132.3 (2)	C1B—C2B—H2BB	109.5
O13A—N4A—Ce1A	119.0 (2)	H2BA—C2B—H2BB	109.5
C3A—N5A—P1A	120.5 (3)	C1B—C2B—H2BC	109.5
C3A—N5A—H5A	120 (3)	H2BA—C2B—H2BC	109.5
P1A—N5A—H5A	118 (3)	H2BB—C2B—H2BC	109.5
C7A—N6A—O14A	105.0 (3)	N4B—C3B—N5B	119.7 (3)
C7A—N7A—P2A	125.9 (3)	N4B—C3B—C4B	112.6 (3)
C7A—N7A—H7A	117 (3)	N5B—C3B—C4B	127.7 (3)
P2A—N7A—H7A	117 (3)	C5B—C4B—C3B	103.3 (4)
O10A—C1A—C2A	113.6 (5)	C5B—C4B—H4BA	128.3
O10A—C1A—H1AA	108.9	C3B—C4B—H4BA	128.3
C2A—C1A—H1AA	108.9	C4B—C5B—O13B	111.1 (3)
O10A—C1A—H1AB	108.9	C4B—C5B—C6B	133.2 (4)
C2A—C1A—H1AB	108.9	O13B—C5B—C6B	115.6 (4)
H1AA—C1A—H1AB	107.7	C5B—C6B—H6BA	109.5
O10A—C1'A—C2'A	108 (2)	C5B—C6B—H6BB	109.5
O10A—C1'A—H1'A	110.0	H6BA—C6B—H6BB	109.5
C2'A—C1'A—H1'A	110.0	C5B—C6B—H6BC	109.5
O10A—C1'A—H1'B	110.0	H6BA—C6B—H6BC	109.5
C2'A—C1'A—H1'B	110.0	H6BB—C6B—H6BC	109.5
H1'A—C1'A—H1'B	108.4	N6B—C7B—N7B	120.5 (4)
C1'A—C2'A—H2'A	109.5	N6B—C7B—C8B	113.3 (4)
C1'A—C2'A—H2'B	109.5	N7B—C7B—C8B	126.1 (4)
H2'A—C2'A—H2'B	109.5	C9B—C8B—C7B	103.0 (4)
C1'A—C2'A—H2'C	109.5	C9B—C8B—H8BA	128.5
H2'A—C2'A—H2'C	109.5	C7B—C8B—H8BA	128.5
H2'B—C2'A—H2'C	109.5	O14B—C9B—C8B	110.9 (4)
N4A—C3A—N5A	119.4 (3)	O14B—C9B—C10B	115.6 (4)
N4A—C3A—C4A	112.6 (3)	C8B—C9B—C10B	133.5 (4)
N5A—C3A—C4A	128.0 (4)	C9B—C10B—H10D	109.5
C5A—C4A—C3A	104.5 (4)	C9B—C10B—H10E	109.5
C5A—C4A—H4AA	127.8	H10D—C10B—H10E	109.5
C3A—C4A—H4AA	127.8	C9B—C10B—H10F	109.5
O13A—C5A—C4A	109.4 (3)	H10D—C10B—H10F	109.5
O13A—C5A—C6A	116.3 (4)	H10E—C10B—H10F	109.5
C4A—C5A—C6A	134.3 (4)	C16B—C11B—C12B	119.7 (4)
C5A—C6A—H6AA	109.5	C16B—C11B—P1B	117.2 (3)
C5A—C6A—H6AB	109.5	C12B—C11B—P1B	123.1 (3)
H6AA—C6A—H6AB	109.5	C13B—C12B—C11B	119.7 (4)
C5A—C6A—H6AC	109.5	C13B—C12B—H12B	120.2
H6AA—C6A—H6AC	109.5	C11B—C12B—H12B	120.2
H6AB—C6A—H6AC	109.5	C12B—C13B—C14B	120.0 (4)
N6A—C7A—N7A	120.2 (4)	C12B—C13B—H13B	120.0
N6A—C7A—C8A	112.8 (4)	C14B—C13B—H13B	120.0
N7A—C7A—C8A	127.0 (4)	C15B—C14B—C13B	120.7 (4)
C9A—C8A—C7A	104.0 (4)	C15B—C14B—H14B	119.6
C9A—C8A—H8AA	128.0	C13B—C14B—H14B	119.6
C7A—C8A—H8AA	128.0	C14B—C15B—C16B	119.9 (4)
C8A—C9A—O14A	110.4 (4)	C14B—C15B—H15B	120.0
C8A—C9A—C10A	134.3 (4)	C16B—C15B—H15B	120.0
O14A—C9A—C10A	115.2 (4)	C15B—C16B—C11B	120.0 (4)
C9A—C10A—H10A	109.5	C15B—C16B—H16B	120.0
C9A—C10A—H10B	109.5	C11B—C16B—H16B	120.0
H10A—C10A—H10B	109.5	C18B—C17B—C22B	119.9 (4)
C9A—C10A—H10C	109.5	C18B—C17B—P1B	119.4 (3)
H10A—C10A—H10C	109.5	C22B—C17B—P1B	120.6 (3)
H10B—C10A—H10C	109.5	C19B—C18B—C17B	120.0 (4)
C16A—C11A—C12A	120.4 (4)	C19B—C18B—H18B	120.0
C16A—C11A—P1A	120.8 (3)	C17B—C18B—H18B	120.0
C12A—C11A—P1A	118.7 (3)	C18B—C19B—C20B	120.2 (4)
C13A—C12A—C11A	119.2 (4)	C18B—C19B—H19B	119.9
C13A—C12A—H12A	120.4	C20B—C19B—H19B	119.9
C11A—C12A—H12A	120.4	C21B—C20B—C19B	119.8 (4)
C14A—C13A—C12A	120.5 (4)	C21B—C20B—H20B	120.1
C14A—C13A—H13A	119.7	C19B—C20B—H20B	120.1
C12A—C13A—H13A	119.7	C22B—C21B—C20B	120.5 (4)
C13A—C14A—C15A	120.2 (4)	C22B—C21B—H21B	119.7
C13A—C14A—H14A	119.9	C20B—C21B—H21B	119.7
C15A—C14A—H14A	119.9	C21B—C22B—C17B	119.6 (4)
C16A—C15A—C14A	120.3 (4)	C21B—C22B—H22B	120.2
C16A—C15A—H15A	119.8	C17B—C22B—H22B	120.2
C14A—C15A—H15A	119.8	C24B—C23B—C28B	120.1 (4)
C15A—C16A—C11A	119.4 (4)	C24B—C23B—P2B	119.4 (3)
C15A—C16A—H16A	120.3	C28B—C23B—P2B	120.5 (3)
C11A—C16A—H16A	120.3	C23B—C24B—C25B	119.8 (4)
C18A—C17A—C22A	120.5 (4)	C23B—C24B—H24B	120.1
C18A—C17A—P1A	122.4 (3)	C25B—C24B—H24B	120.1
C22A—C17A—P1A	116.9 (3)	C26B—C25B—C24B	120.4 (5)
C19A—C18A—C17A	119.4 (4)	C26B—C25B—H25B	119.8
C19A—C18A—H18A	120.3	C24B—C25B—H25B	119.8
C17A—C18A—H18A	120.3	C27B—C26B—C25B	119.4 (4)
C18A—C19A—C20A	120.6 (4)	C27B—C26B—H26B	120.3
C18A—C19A—H19A	119.7	C25B—C26B—H26B	120.3
C20A—C19A—H19A	119.7	C26B—C27B—C28B	121.4 (4)
C21A—C20A—C19A	119.3 (4)	C26B—C27B—H27B	119.3
C21A—C20A—H20A	120.4	C28B—C27B—H27B	119.3
C19A—C20A—H20A	120.4	C27B—C28B—C23B	118.9 (4)
C22A—C21A—C20A	121.0 (4)	C27B—C28B—H28B	120.5
C22A—C21A—H21A	119.5	C23B—C28B—H28B	120.5
C20A—C21A—H21A	119.5	C30B—C29B—C34B	120.5 (4)
C21A—C22A—C17A	119.3 (4)	C30B—C29B—P2B	120.3 (3)
C21A—C22A—H22A	120.4	C34B—C29B—P2B	118.9 (3)
C17A—C22A—H22A	120.4	C29B—C30B—C31B	119.2 (4)
C28A—C23A—C24A	120.4 (4)	C29B—C30B—H30B	120.4
C28A—C23A—P2A	120.5 (3)	C31B—C30B—H30B	120.4
C24A—C23A—P2A	119.0 (3)	C32B—C31B—C30B	120.4 (4)
C25A—C24A—C23A	119.6 (4)	C32B—C31B—H31B	119.8
C25A—C24A—H24A	120.2	C30B—C31B—H31B	119.8
C23A—C24A—H24A	120.2	C31B—C32B—C33B	120.1 (4)
C24A—C25A—C26A	120.0 (4)	C31B—C32B—H32B	120.0
C24A—C25A—H25A	120.0	C33B—C32B—H32B	120.0
C26A—C25A—H25A	120.0	C34B—C33B—C32B	120.1 (4)
C25A—C26A—C27A	120.2 (4)	C34B—C33B—H33B	119.9
C25A—C26A—H26A	119.9	C32B—C33B—H33B	119.9
C27A—C26A—H26A	119.9	C33B—C34B—C29B	119.7 (4)
C28A—C27A—C26A	120.6 (4)	C33B—C34B—H34B	120.2
C28A—C27A—H27A	119.7	C29B—C34B—H34B	120.2
C26A—C27A—H27A	119.7	C1S—O1S—H1S	110 (4)
C23A—C28A—C27A	119.2 (4)	O1S—C1S—C2S	108.9 (4)
C23A—C28A—H28A	120.4	O1S—C1S—H1SA	109.9
C27A—C28A—H28A	120.4	C2S—C1S—H1SA	109.9
C30A—C29A—C34A	118.8 (4)	O1S—C1S—H1SB	109.9
C30A—C29A—P2A	123.2 (3)	C2S—C1S—H1SB	109.9
C34A—C29A—P2A	117.8 (3)	H1SA—C1S—H1SB	108.3
C29A—C30A—C31A	120.5 (4)	C1S—C2S—H2SA	109.5
C29A—C30A—H30A	119.8	C1S—C2S—H2SB	109.5
C31A—C30A—H30A	119.8	H2SA—C2S—H2SB	109.5
C32A—C31A—C30A	120.5 (4)	C1S—C2S—H2SC	109.5
C32A—C31A—H31A	119.8	H2SA—C2S—H2SC	109.5
C30A—C31A—H31A	119.8	H2SB—C2S—H2SC	109.5
C31A—C32A—C33A	119.6 (4)	C3S—O2S—C3S'	33.3 (10)
C31A—C32A—H32A	120.2	C3S—O2S—H2S	104 (4)
C33A—C32A—H32A	120.2	C3S'—O2S—H2S	108 (4)
C32A—C33A—C34A	120.0 (5)	C4S—C3S—O2S	112.7 (7)
C32A—C33A—H33A	120.0	C4S—C3S—H3SA	109.1
C34A—C33A—H33A	120.0	O2S—C3S—H3SA	109.1
C33A—C34A—C29A	120.6 (4)	C4S—C3S—H3SB	109.1
C33A—C34A—H34A	119.7	O2S—C3S—H3SB	109.1
C29A—C34A—H34A	119.7	H3SA—C3S—H3SB	107.8
O12B—Ce1B—O11B	140.75 (9)	C4S'—C3S'—O2S	116 (2)
O12B—Ce1B—O10B	71.49 (9)	C4S'—C3S'—H3SC	108.3
O11B—Ce1B—O10B	82.60 (9)	O2S—C3S'—H3SC	108.3
O12B—Ce1B—O8B	146.69 (9)	C4S'—C3S'—H3SD	108.3
O11B—Ce1B—O8B	71.84 (9)	O2S—C3S'—H3SD	108.3
O10B—Ce1B—O8B	118.25 (9)	H3SC—C3S'—H3SD	107.4
O12B—Ce1B—O2B	119.01 (9)	C3S'—C4S'—H4SD	109.5
O11B—Ce1B—O2B	78.48 (9)	C3S'—C4S'—H4SE	109.5
O10B—Ce1B—O2B	158.86 (10)	H4SD—C4S'—H4SE	109.5
O8B—Ce1B—O2B	64.27 (9)	C3S'—C4S'—H4SF	109.5
O12B—Ce1B—O1B	70.47 (9)	H4SD—C4S'—H4SF	109.5
O11B—Ce1B—O1B	110.71 (9)	H4SE—C4S'—H4SF	109.5
O10B—Ce1B—O1B	132.19 (10)
O11A—Ce1A—O1A—N1A	57.7 (2)	C30A—C31A—C32A—C33A	1.2 (8)
O12A—Ce1A—O1A—N1A	−165.1 (2)	C31A—C32A—C33A—C34A	−0.6 (9)
O10A—Ce1A—O1A—N1A	156.1 (2)	C32A—C33A—C34A—C29A	−0.4 (10)
O2A—Ce1A—O1A—N1A	5.5 (2)	C30A—C29A—C34A—C33A	0.7 (8)
O8A—Ce1A—O1A—N1A	−20.0 (2)	P2A—C29A—C34A—C33A	−175.0 (5)
O5A—Ce1A—O1A—N1A	−97.7 (2)	O12B—Ce1B—O1B—N1B	163.8 (2)
O4A—Ce1A—O1A—N1A	−81.9 (2)	O11B—Ce1B—O1B—N1B	−58.0 (2)
O7A—Ce1A—O1A—N1A	−20.1 (4)	O10B—Ce1B—O1B—N1B	−157.1 (2)
N4A—Ce1A—O1A—N1A	113.8 (2)	O8B—Ce1B—O1B—N1B	19.2 (2)
O11A—Ce1A—O2A—N1A	−136.1 (2)	O2B—Ce1B—O1B—N1B	−5.30 (19)
O12A—Ce1A—O2A—N1A	4.8 (3)	O4B—Ce1B—O1B—N1B	101.5 (2)
O10A—Ce1A—O2A—N1A	−113.1 (3)	O5B—Ce1B—O1B—N1B	83.3 (2)
O8A—Ce1A—O2A—N1A	148.0 (3)	O7B—Ce1B—O1B—N1B	21.0 (4)
O1A—Ce1A—O2A—N1A	−5.5 (2)	N4B—Ce1B—O1B—N1B	−114.1 (2)
O5A—Ce1A—O2A—N1A	93.8 (2)	O12B—Ce1B—O2B—N1B	−6.4 (2)
O4A—Ce1A—O2A—N1A	67.0 (2)	O11B—Ce1B—O2B—N1B	135.9 (2)
O7A—Ce1A—O2A—N1A	164.7 (2)	O10B—Ce1B—O2B—N1B	109.0 (3)
N4A—Ce1A—O2A—N1A	−68.5 (2)	O8B—Ce1B—O2B—N1B	−148.9 (2)
O11A—Ce1A—O4A—N2A	109.8 (2)	O1B—Ce1B—O2B—N1B	5.35 (19)
O12A—Ce1A—O4A—N2A	−82.7 (2)	O4B—Ce1B—O2B—N1B	−92.2 (2)
O10A—Ce1A—O4A—N2A	−31.1 (3)	O5B—Ce1B—O2B—N1B	−68.0 (2)
O2A—Ce1A—O4A—N2A	148.8 (2)	O7B—Ce1B—O2B—N1B	−164.4 (2)
O8A—Ce1A—O4A—N2A	80.8 (2)	N4B—Ce1B—O2B—N1B	68.4 (2)
O1A—Ce1A—O4A—N2A	−158.3 (3)	O12B—Ce1B—O4B—N2B	−77.1 (2)
O5A—Ce1A—O4A—N2A	2.0 (2)	O11B—Ce1B—O4B—N2B	136.9 (2)
O7A—Ce1A—O4A—N2A	41.1 (2)	O10B—Ce1B—O4B—N2B	−149.7 (2)
N4A—Ce1A—O4A—N2A	−138.2 (2)	O8B—Ce1B—O4B—N2B	88.7 (2)
N1A—Ce1A—O4A—N2A	174.3 (3)	O2B—Ce1B—O4B—N2B	37.8 (2)
O11A—Ce1A—O5A—N2A	−131.4 (2)	O1B—Ce1B—O4B—N2B	−16.8 (2)
O12A—Ce1A—O5A—N2A	81.1 (2)	O5B—Ce1B—O4B—N2B	5.9 (2)
O10A—Ce1A—O5A—N2A	152.8 (2)	O7B—Ce1B—O4B—N2B	139.1 (2)
O2A—Ce1A—O5A—N2A	−36.9 (3)	N4B—Ce1B—O4B—N2B	−104.9 (2)
O8A—Ce1A—O5A—N2A	−87.6 (2)	N1B—Ce1B—O4B—N2B	10.4 (2)
O1A—Ce1A—O5A—N2A	17.2 (3)	O12B—Ce1B—O5B—N2B	76.6 (2)
O4A—Ce1A—O5A—N2A	−2.1 (2)	O11B—Ce1B—O5B—N2B	−113.9 (2)
O7A—Ce1A—O5A—N2A	−139.5 (2)	O10B—Ce1B—O5B—N2B	24.9 (3)
N4A—Ce1A—O5A—N2A	104.5 (3)	O8B—Ce1B—O5B—N2B	−89.7 (2)
N1A—Ce1A—O5A—N2A	−9.7 (3)	O2B—Ce1B—O5B—N2B	−156.5 (2)
O11A—Ce1A—O7A—N3A	−80.1 (2)	O1B—Ce1B—O5B—N2B	151.5 (2)
O12A—Ce1A—O7A—N3A	144.4 (2)	O4B—Ce1B—O5B—N2B	−5.8 (2)
O10A—Ce1A—O7A—N3A	−170.7 (2)	O7B—Ce1B—O5B—N2B	−48.3 (2)
O2A—Ce1A—O7A—N3A	−14.3 (2)	N4B—Ce1B—O5B—N2B	128.3 (2)
O8A—Ce1A—O7A—N3A	6.17 (19)	N1B—Ce1B—O5B—N2B	178.6 (2)
O1A—Ce1A—O7A—N3A	6.3 (4)	O12B—Ce1B—O7B—N3B	−146.1 (2)
O5A—Ce1A—O7A—N3A	93.3 (2)	O11B—Ce1B—O7B—N3B	77.0 (2)
O4A—Ce1A—O7A—N3A	61.8 (2)	O10B—Ce1B—O7B—N3B	167.4 (2)
N4A—Ce1A—O7A—N3A	−118.9 (2)	O8B—Ce1B—O7B—N3B	−8.85 (19)
N1A—Ce1A—O7A—N3A	−5.3 (3)	O2B—Ce1B—O7B—N3B	9.9 (2)
O11A—Ce1A—O8A—N3A	68.2 (2)	O1B—Ce1B—O7B—N3B	−11.1 (4)
O12A—Ce1A—O8A—N3A	−99.3 (2)	O4B—Ce1B—O7B—N3B	−101.2 (2)
O10A—Ce1A—O8A—N3A	−3.0 (2)	O5B—Ce1B—O7B—N3B	−67.5 (2)
O2A—Ce1A—O8A—N3A	152.6 (2)	N4B—Ce1B—O7B—N3B	115.4 (2)
O1A—Ce1A—O8A—N3A	173.8 (2)	N1B—Ce1B—O7B—N3B	1.0 (3)
O5A—Ce1A—O8A—N3A	−78.8 (2)	O12B—Ce1B—O8B—N3B	104.1 (2)
O4A—Ce1A—O8A—N3A	−129.8 (2)	O11B—Ce1B—O8B—N3B	−66.0 (2)
O7A—Ce1A—O8A—N3A	−6.2 (2)	O10B—Ce1B—O8B—N3B	4.8 (2)
N4A—Ce1A—O8A—N3A	92.6 (2)	O2B—Ce1B—O8B—N3B	−151.7 (2)
N1A—Ce1A—O8A—N3A	165.6 (2)	O1B—Ce1B—O8B—N3B	−172.1 (2)
O11A—Ce1A—O10A—C1'A	−94 (2)	O4B—Ce1B—O8B—N3B	78.7 (2)
O12A—Ce1A—O10A—C1'A	117 (2)	O5B—Ce1B—O8B—N3B	128.7 (2)
O2A—Ce1A—O10A—C1'A	−116 (2)	O7B—Ce1B—O8B—N3B	8.76 (19)
O8A—Ce1A—O10A—C1'A	−28 (2)	N4B—Ce1B—O8B—N3B	−90.6 (2)
O1A—Ce1A—O10A—C1'A	156 (2)	N1B—Ce1B—O8B—N3B	−164.1 (2)
O5A—Ce1A—O10A—C1'A	39 (2)	O12B—Ce1B—O10B—C1B	−129.1 (4)
O4A—Ce1A—O10A—C1'A	64 (2)	O11B—Ce1B—O10B—C1B	80.8 (4)
O7A—Ce1A—O10A—C1'A	−25 (2)	O8B—Ce1B—O10B—C1B	16.0 (4)
N4A—Ce1A—O10A—C1'A	−163 (2)	O2B—Ce1B—O10B—C1B	107.4 (4)
N1A—Ce1A—O10A—C1'A	179 (2)	O1B—Ce1B—O10B—C1B	−167.9 (4)
O11A—Ce1A—O10A—C1A	−43.2 (5)	O4B—Ce1B—O10B—C1B	−53.7 (4)
O12A—Ce1A—O10A—C1A	167.5 (5)	O5B—Ce1B—O10B—C1B	−76.3 (4)
O2A—Ce1A—O10A—C1A	−65.9 (6)	O7B—Ce1B—O10B—C1B	12.9 (4)
O8A—Ce1A—O10A—C1A	22.3 (5)	N4B—Ce1B—O10B—C1B	150.0 (4)
O1A—Ce1A—O10A—C1A	−153.6 (5)	N1B—Ce1B—O10B—C1B	170.4 (4)
O5A—Ce1A—O10A—C1A	89.6 (5)	N5B—P1B—O11B—Ce1B	−9.4 (3)
O4A—Ce1A—O10A—C1A	113.9 (5)	C11B—P1B—O11B—Ce1B	−124.6 (2)
O7A—Ce1A—O10A—C1A	24.9 (5)	C17B—P1B—O11B—Ce1B	110.1 (2)
N4A—Ce1A—O10A—C1A	−112.7 (5)	O12B—Ce1B—O11B—P1B	3.4 (3)
N1A—Ce1A—O10A—C1A	−130.4 (5)	O10B—Ce1B—O11B—P1B	51.7 (2)
N5A—P1A—O11A—Ce1A	17.4 (3)	O8B—Ce1B—O11B—P1B	174.8 (3)
C17A—P1A—O11A—Ce1A	131.6 (2)	O2B—Ce1B—O11B—P1B	−118.8 (2)
C11A—P1A—O11A—Ce1A	−101.3 (3)	O1B—Ce1B—O11B—P1B	−80.7 (2)
O12A—Ce1A—O11A—P1A	−11.8 (3)	O4B—Ce1B—O11B—P1B	125.3 (2)
O10A—Ce1A—O11A—P1A	−60.2 (2)	O5B—Ce1B—O11B—P1B	−160.49 (18)
O2A—Ce1A—O11A—P1A	111.3 (3)	O7B—Ce1B—O11B—P1B	123.1 (2)
O8A—Ce1A—O11A—P1A	178.7 (3)	N4B—Ce1B—O11B—P1B	−23.4 (2)
O1A—Ce1A—O11A—P1A	73.3 (3)	N1B—Ce1B—O11B—P1B	−101.8 (2)
O5A—Ce1A—O11A—P1A	−137.8 (2)	N7B—P2B—O12B—Ce1B	−53.5 (11)
O4A—Ce1A—O11A—P1A	149.3 (2)	C29B—P2B—O12B—Ce1B	−168.0 (10)
O7A—Ce1A—O11A—P1A	−129.7 (3)	C23B—P2B—O12B—Ce1B	68.1 (11)
N4A—Ce1A—O11A—P1A	16.4 (2)	O11B—Ce1B—O12B—P2B	32.4 (11)
N1A—Ce1A—O11A—P1A	94.2 (2)	O10B—Ce1B—O12B—P2B	−18.9 (11)
N7A—P2A—O12A—Ce1A	85.3 (11)	O8B—Ce1B—O12B—P2B	−132.5 (10)
C23A—P2A—O12A—Ce1A	−159.5 (11)	O2B—Ce1B—O12B—P2B	141.0 (10)
C29A—P2A—O12A—Ce1A	−38.3 (11)	O1B—Ce1B—O12B—P2B	131.6 (11)
O11A—Ce1A—O12A—P2A	−68.3 (11)	O4B—Ce1B—O12B—P2B	−106.8 (11)
O10A—Ce1A—O12A—P2A	−16.8 (11)	O5B—Ce1B—O12B—P2B	−157.3 (11)
O2A—Ce1A—O12A—P2A	−176.4 (11)	O7B—Ce1B—O12B—P2B	−64.9 (11)
O8A—Ce1A—O12A—P2A	93.2 (11)	N4B—Ce1B—O12B—P2B	57.9 (11)
O1A—Ce1A—O12A—P2A	−168.1 (11)	N1B—Ce1B—O12B—P2B	138.3 (11)
O5A—Ce1A—O12A—P2A	73.3 (11)	Ce1B—O2B—N1B—O3B	169.9 (3)
O4A—Ce1A—O12A—P2A	123.4 (11)	Ce1B—O2B—N1B—O1B	−9.3 (3)
O7A—Ce1A—O12A—P2A	26.9 (11)	Ce1B—O1B—N1B—O3B	−170.0 (3)
N4A—Ce1A—O12A—P2A	−95.2 (11)	Ce1B—O1B—N1B—O2B	9.1 (3)
N1A—Ce1A—O12A—P2A	−174.4 (11)	O12B—Ce1B—N1B—O3B	83.3 (19)
Ce1A—O1A—N1A—O3A	169.4 (3)	O11B—Ce1B—N1B—O3B	−134.4 (19)
Ce1A—O1A—N1A—O2A	−9.5 (4)	O10B—Ce1B—N1B—O3B	139.2 (19)
Ce1A—O2A—N1A—O3A	−169.2 (3)	O8B—Ce1B—N1B—O3B	−63.3 (19)
Ce1A—O2A—N1A—O1A	9.7 (4)	O2B—Ce1B—N1B—O3B	−91.1 (19)
O11A—Ce1A—N1A—O3A	129.9 (19)	O1B—Ce1B—N1B—O3B	99 (2)
O12A—Ce1A—N1A—O3A	−88.8 (19)	O4B—Ce1B—N1B—O3B	9 (2)
O10A—Ce1A—N1A—O3A	−146.1 (18)	O5B—Ce1B—N1B—O3B	12.6 (19)
O2A—Ce1A—N1A—O3A	87.0 (19)	O7B—Ce1B—N1B—O3B	−71 (2)
O8A—Ce1A—N1A—O3A	58.2 (19)	N4B—Ce1B—N1B—O3B	158.9 (19)
O1A—Ce1A—N1A—O3A	−103.0 (19)	O12B—Ce1B—N1B—O2B	174.4 (2)
O5A—Ce1A—N1A—O3A	−10.2 (19)	O11B—Ce1B—N1B—O2B	−43.3 (2)
O4A—Ce1A—N1A—O3A	−16.6 (19)	O10B—Ce1B—N1B—O2B	−129.7 (3)
O7A—Ce1A—N1A—O3A	66.8 (19)	O8B—Ce1B—N1B—O2B	27.8 (2)
N4A—Ce1A—N1A—O3A	−163.4 (19)	O1B—Ce1B—N1B—O2B	−170.3 (3)
O11A—Ce1A—N1A—O1A	−127.1 (2)	O4B—Ce1B—N1B—O2B	100.0 (2)
O12A—Ce1A—N1A—O1A	14.2 (2)	O5B—Ce1B—N1B—O2B	103.7 (2)
O10A—Ce1A—N1A—O1A	−43.1 (4)	O7B—Ce1B—N1B—O2B	20.5 (3)
O2A—Ce1A—N1A—O1A	−170.0 (4)	N4B—Ce1B—N1B—O2B	−110.0 (2)
O8A—Ce1A—N1A—O1A	161.2 (2)	O12B—Ce1B—N1B—O1B	−15.2 (2)
O5A—Ce1A—N1A—O1A	92.8 (2)	O11B—Ce1B—N1B—O1B	127.0 (2)
O4A—Ce1A—N1A—O1A	86.4 (2)	O10B—Ce1B—N1B—O1B	40.7 (3)
O7A—Ce1A—N1A—O1A	169.8 (2)	O8B—Ce1B—N1B—O1B	−161.8 (2)
N4A—Ce1A—N1A—O1A	−60.4 (2)	O2B—Ce1B—N1B—O1B	170.3 (3)
O11A—Ce1A—N1A—O2A	42.9 (2)	O4B—Ce1B—N1B—O1B	−89.6 (2)
O12A—Ce1A—N1A—O2A	−175.8 (2)	O5B—Ce1B—N1B—O1B	−86.0 (2)
O10A—Ce1A—N1A—O2A	126.9 (3)	O7B—Ce1B—N1B—O1B	−169.19 (19)
O8A—Ce1A—N1A—O2A	−28.8 (2)	N4B—Ce1B—N1B—O1B	60.3 (2)
O1A—Ce1A—N1A—O2A	170.0 (4)	Ce1B—O4B—N2B—O6B	168.9 (3)
O5A—Ce1A—N1A—O2A	−97.2 (2)	Ce1B—O4B—N2B—O5B	−10.3 (3)
O4A—Ce1A—N1A—O2A	−103.6 (2)	Ce1B—O5B—N2B—O6B	−169.1 (3)
O7A—Ce1A—N1A—O2A	−20.2 (3)	Ce1B—O5B—N2B—O4B	10.1 (3)
N4A—Ce1A—N1A—O2A	109.7 (2)	Ce1B—O7B—N3B—O9B	−164.0 (3)
Ce1A—O5A—N2A—O6A	−175.2 (4)	Ce1B—O7B—N3B—O8B	15.2 (3)
Ce1A—O5A—N2A—O4A	3.7 (4)	Ce1B—O8B—N3B—O9B	163.0 (3)
Ce1A—O4A—N2A—O6A	175.3 (4)	Ce1B—O8B—N3B—O7B	−16.2 (3)
Ce1A—O4A—N2A—O5A	−3.6 (4)	C5B—O13B—N4B—C3B	1.2 (4)
Ce1A—O8A—N3A—O9A	−167.9 (3)	C5B—O13B—N4B—Ce1B	−161.7 (2)
Ce1A—O8A—N3A—O7A	11.4 (3)	O12B—Ce1B—N4B—C3B	−119.3 (3)
Ce1A—O7A—N3A—O9A	168.6 (3)	O11B—Ce1B—N4B—C3B	43.7 (3)
Ce1A—O7A—N3A—O8A	−10.7 (3)	O10B—Ce1B—N4B—C3B	−44.9 (3)
C5A—O13A—N4A—C3A	−0.6 (4)	O8B—Ce1B—N4B—C3B	68.9 (4)
C5A—O13A—N4A—Ce1A	159.6 (2)	O2B—Ce1B—N4B—C3B	121.0 (3)
O11A—Ce1A—N4A—C3A	−43.6 (3)	O1B—Ce1B—N4B—C3B	166.9 (4)
O12A—Ce1A—N4A—C3A	118.1 (4)	O4B—Ce1B—N4B—C3B	−91.8 (4)
O10A—Ce1A—N4A—C3A	43.9 (3)	O5B—Ce1B—N4B—C3B	−170.3 (3)
O2A—Ce1A—N4A—C3A	−120.3 (3)	O7B—Ce1B—N4B—C3B	5.7 (4)
O8A—Ce1A—N4A—C3A	−68.6 (4)	N1B—Ce1B—N4B—C3B	144.1 (3)
O1A—Ce1A—N4A—C3A	−166.6 (4)	O12B—Ce1B—N4B—O13B	38.8 (2)
O5A—Ce1A—N4A—C3A	94.5 (4)	O11B—Ce1B—N4B—O13B	−158.3 (3)
O4A—Ce1A—N4A—C3A	173.9 (3)	O10B—Ce1B—N4B—O13B	113.2 (3)
O7A—Ce1A—N4A—C3A	−5.3 (4)	O8B—Ce1B—N4B—O13B	−133.0 (2)
N1A—Ce1A—N4A—C3A	−143.7 (4)	O2B—Ce1B—N4B—O13B	−80.9 (2)
O11A—Ce1A—N4A—O13A	162.8 (3)	O1B—Ce1B—N4B—O13B	−35.0 (2)
O12A—Ce1A—N4A—O13A	−35.6 (2)	O4B—Ce1B—N4B—O13B	66.3 (3)
O10A—Ce1A—N4A—O13A	−109.7 (2)	O5B—Ce1B—N4B—O13B	−12.3 (3)
O2A—Ce1A—N4A—O13A	86.1 (2)	O7B—Ce1B—N4B—O13B	163.8 (2)
O8A—Ce1A—N4A—O13A	137.8 (2)	N1B—Ce1B—N4B—O13B	−57.8 (2)
O1A—Ce1A—N4A—O13A	39.8 (2)	O11B—P1B—N5B—C3B	56.1 (3)
O5A—Ce1A—N4A—O13A	−59.1 (3)	C11B—P1B—N5B—C3B	177.0 (3)
O4A—Ce1A—N4A—O13A	20.3 (3)	C17B—P1B—N5B—C3B	−64.5 (3)
O7A—Ce1A—N4A—O13A	−158.9 (2)	C9B—O14B—N6B—C7B	0.5 (4)
N1A—Ce1A—N4A—O13A	62.7 (2)	O12B—P2B—N7B—C7B	64.2 (4)
O11A—P1A—N5A—C3A	−56.3 (3)	C29B—P2B—N7B—C7B	−175.2 (4)
C17A—P1A—N5A—C3A	−176.6 (3)	C23B—P2B—N7B—C7B	−59.6 (4)
C11A—P1A—N5A—C3A	64.1 (3)	Ce1B—O10B—C1B—C2B	−132.4 (4)
C9A—O14A—N6A—C7A	−0.3 (4)	O13B—N4B—C3B—N5B	178.0 (3)
O12A—P2A—N7A—C7A	−52.2 (4)	Ce1B—N4B—C3B—N5B	−21.2 (5)
C23A—P2A—N7A—C7A	−174.3 (3)	O13B—N4B—C3B—C4B	−1.0 (4)
C29A—P2A—N7A—C7A	73.0 (4)	Ce1B—N4B—C3B—C4B	159.8 (3)
C1'A—O10A—C1A—C2A	−47 (2)	P1B—N5B—C3B—N4B	−39.0 (5)
Ce1A—O10A—C1A—C2A	−165.5 (4)	P1B—N5B—C3B—C4B	139.9 (4)
C1A—O10A—C1'A—C2'A	41.4 (18)	N4B—C3B—C4B—C5B	0.5 (5)
Ce1A—O10A—C1'A—C2'A	142.8 (14)	N5B—C3B—C4B—C5B	−178.5 (4)
O13A—N4A—C3A—N5A	−178.2 (3)	C3B—C4B—C5B—O13B	0.4 (5)
Ce1A—N4A—C3A—N5A	25.5 (5)	C3B—C4B—C5B—C6B	176.8 (5)
O13A—N4A—C3A—C4A	0.3 (4)	N4B—O13B—C5B—C4B	−1.0 (4)
Ce1A—N4A—C3A—C4A	−156.0 (3)	N4B—O13B—C5B—C6B	−178.1 (4)
P1A—N5A—C3A—N4A	34.6 (5)	O14B—N6B—C7B—N7B	179.2 (3)
P1A—N5A—C3A—C4A	−143.6 (4)	O14B—N6B—C7B—C8B	−0.5 (5)
N4A—C3A—C4A—C5A	0.1 (5)	P2B—N7B—C7B—N6B	−15.6 (6)
N5A—C3A—C4A—C5A	178.4 (4)	P2B—N7B—C7B—C8B	164.1 (4)
N4A—O13A—C5A—C4A	0.7 (4)	N6B—C7B—C8B—C9B	0.3 (5)
N4A—O13A—C5A—C6A	179.3 (4)	N7B—C7B—C8B—C9B	−179.4 (4)
C3A—C4A—C5A—O13A	−0.5 (4)	N6B—O14B—C9B—C8B	−0.3 (5)
C3A—C4A—C5A—C6A	−178.7 (5)	N6B—O14B—C9B—C10B	−179.7 (5)
O14A—N6A—C7A—N7A	177.8 (3)	C7B—C8B—C9B—O14B	0.0 (5)
O14A—N6A—C7A—C8A	−0.4 (4)	C7B—C8B—C9B—C10B	179.2 (6)
P2A—N7A—C7A—N6A	4.0 (6)	O11B—P1B—C11B—C16B	25.3 (4)
P2A—N7A—C7A—C8A	−178.1 (3)	N5B—P1B—C11B—C16B	−96.0 (3)
N6A—C7A—C8A—C9A	0.9 (5)	C17B—P1B—C11B—C16B	149.0 (3)
N7A—C7A—C8A—C9A	−177.2 (4)	O11B—P1B—C11B—C12B	−157.6 (3)
C7A—C8A—C9A—O14A	−1.0 (5)	N5B—P1B—C11B—C12B	81.1 (4)
C7A—C8A—C9A—C10A	176.7 (5)	C17B—P1B—C11B—C12B	−33.8 (4)
N6A—O14A—C9A—C8A	0.8 (5)	C16B—C11B—C12B—C13B	−0.1 (6)
N6A—O14A—C9A—C10A	−177.4 (4)	P1B—C11B—C12B—C13B	−177.2 (3)
O11A—P1A—C11A—C16A	159.4 (3)	C11B—C12B—C13B—C14B	0.3 (6)
N5A—P1A—C11A—C16A	37.4 (4)	C12B—C13B—C14B—C15B	0.1 (6)
C17A—P1A—C11A—C16A	−74.2 (4)	C13B—C14B—C15B—C16B	−0.8 (6)
O11A—P1A—C11A—C12A	−18.0 (4)	C14B—C15B—C16B—C11B	1.0 (6)
N5A—P1A—C11A—C12A	−140.1 (3)	C12B—C11B—C16B—C15B	−0.6 (6)
C17A—P1A—C11A—C12A	108.3 (3)	P1B—C11B—C16B—C15B	176.7 (3)
C16A—C11A—C12A—C13A	1.0 (6)	O11B—P1B—C17B—C18B	17.4 (4)
P1A—C11A—C12A—C13A	178.4 (3)	N5B—P1B—C17B—C18B	140.2 (3)
C11A—C12A—C13A—C14A	−0.8 (6)	C11B—P1B—C17B—C18B	−107.8 (3)
C12A—C13A—C14A—C15A	0.4 (7)	O11B—P1B—C17B—C22B	−160.6 (3)
C13A—C14A—C15A—C16A	−0.1 (7)	N5B—P1B—C17B—C22B	−37.8 (4)
C14A—C15A—C16A—C11A	0.2 (6)	C11B—P1B—C17B—C22B	74.2 (4)
C12A—C11A—C16A—C15A	−0.6 (6)	C22B—C17B—C18B—C19B	−1.0 (6)
P1A—C11A—C16A—C15A	−178.0 (3)	P1B—C17B—C18B—C19B	−179.0 (3)
O11A—P1A—C17A—C18A	163.5 (3)	C17B—C18B—C19B—C20B	0.9 (6)
N5A—P1A—C17A—C18A	−76.1 (4)	C18B—C19B—C20B—C21B	−0.3 (6)
C11A—P1A—C17A—C18A	38.4 (4)	C19B—C20B—C21B—C22B	−0.2 (6)
O11A—P1A—C17A—C22A	−21.4 (4)	C20B—C21B—C22B—C17B	0.0 (6)
N5A—P1A—C17A—C22A	99.0 (3)	C18B—C17B—C22B—C21B	0.6 (6)
C11A—P1A—C17A—C22A	−146.5 (3)	P1B—C17B—C22B—C21B	178.5 (3)
C22A—C17A—C18A—C19A	−1.2 (6)	O12B—P2B—C23B—C24B	31.2 (4)
P1A—C17A—C18A—C19A	173.7 (3)	N7B—P2B—C23B—C24B	157.6 (4)
C17A—C18A—C19A—C20A	−0.2 (6)	C29B—P2B—C23B—C24B	−93.3 (4)
C18A—C19A—C20A—C21A	1.2 (6)	O12B—P2B—C23B—C28B	−149.8 (3)
C19A—C20A—C21A—C22A	−0.8 (6)	N7B—P2B—C23B—C28B	−23.4 (4)
C20A—C21A—C22A—C17A	−0.6 (6)	C29B—P2B—C23B—C28B	85.7 (4)
C18A—C17A—C22A—C21A	1.6 (6)	C28B—C23B—C24B—C25B	−1.8 (7)
P1A—C17A—C22A—C21A	−173.6 (3)	P2B—C23B—C24B—C25B	177.2 (4)
O12A—P2A—C23A—C28A	−11.6 (4)	C23B—C24B—C25B—C26B	0.7 (8)
N7A—P2A—C23A—C28A	112.2 (4)	C24B—C25B—C26B—C27B	0.5 (8)
C29A—P2A—C23A—C28A	−134.8 (4)	C25B—C26B—C27B—C28B	−0.6 (8)
O12A—P2A—C23A—C24A	171.9 (3)	C26B—C27B—C28B—C23B	−0.5 (7)
N7A—P2A—C23A—C24A	−64.4 (4)	C24B—C23B—C28B—C27B	1.7 (6)
C29A—P2A—C23A—C24A	48.7 (4)	P2B—C23B—C28B—C27B	−177.3 (3)
C28A—C23A—C24A—C25A	−0.7 (7)	O12B—P2B—C29B—C30B	−167.9 (3)
P2A—C23A—C24A—C25A	175.8 (3)	N7B—P2B—C29B—C30B	69.1 (4)
C23A—C24A—C25A—C26A	0.5 (7)	C23B—P2B—C29B—C30B	−43.8 (4)
C24A—C25A—C26A—C27A	−0.5 (7)	O12B—P2B—C29B—C34B	17.8 (4)
C25A—C26A—C27A—C28A	0.6 (7)	N7B—P2B—C29B—C34B	−105.3 (3)
C24A—C23A—C28A—C27A	0.8 (7)	C23B—P2B—C29B—C34B	141.8 (3)
P2A—C23A—C28A—C27A	−175.7 (4)	C34B—C29B—C30B—C31B	1.4 (6)
C26A—C27A—C28A—C23A	−0.8 (7)	P2B—C29B—C30B—C31B	−172.9 (3)
O12A—P2A—C29A—C30A	141.3 (3)	C29B—C30B—C31B—C32B	0.0 (7)
N7A—P2A—C29A—C30A	13.6 (4)	C30B—C31B—C32B—C33B	−1.7 (7)
C23A—P2A—C29A—C30A	−94.3 (4)	C31B—C32B—C33B—C34B	1.9 (7)
O12A—P2A—C29A—C34A	−43.2 (4)	C32B—C33B—C34B—C29B	−0.5 (7)
N7A—P2A—C29A—C34A	−170.9 (4)	C30B—C29B—C34B—C33B	−1.1 (6)
C23A—P2A—C29A—C34A	81.2 (4)	P2B—C29B—C34B—C33B	173.2 (3)
C34A—C29A—C30A—C31A	−0.1 (6)	C3S'—O2S—C3S—C4S	22 (2)
P2A—C29A—C30A—C31A	175.3 (3)	C3S—O2S—C3S'—C4S'	−17.5 (16)
C29A—C30A—C31A—C32A	−0.8 (7)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N5A—H5A···O9B^i	0.80 (5)	2.13 (5)	2.914 (4)	168 (5)
N5B—H5B···O9A	0.87 (5)	2.01 (5)	2.877 (4)	173 (6)
N7A—H7A···O1S	0.79 (4)	2.07 (5)	2.838 (5)	165 (5)
N7B—H7B···O2S	0.76 (5)	2.08 (5)	2.830 (5)	167 (5)
O10A—H10V···N6A	0.73 (6)	2.06 (6)	2.786 (4)	179 (9)
O10B—H10W···N6B	0.71 (5)	2.15 (5)	2.858 (4)	170 (5)
O1S—H1S···O5B^ii	0.82 (6)	2.14 (6)	2.919 (4)	161 (5)
O1S—H1S···O6B^ii	0.82 (6)	2.51 (6)	3.166 (5)	138 (5)
O2S—H2S···O4A^iii	0.82 (6)	2.43 (6)	3.209 (5)	159 (6)
O2S—H2S···O6A^iii	0.82 (6)	2.33 (6)	2.983 (6)	137 (5)

Symmetry codes: (i) x, y−1, z; (ii) x−1, y−1, z; (iii) x+1, y, z.

(IGE)

Crystal data

C34H36EuN7O14P2·C2H6O	F(000) = 4160
Mr = 1026.67	Dx = 1.590 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 954 reflections
a = 14.8395 (5) Å	θ = 3–29°
b = 15.8178 (5) Å	µ = 1.61 mm^−1
c = 36.7471 (11) Å	T = 100 K
β = 96.168 (1)°	Prism, colourless
V = 8575.6 (5) Å^3	0.17 × 0.12 × 0.10 mm
Z = 8

Data collection

Bruker APEX II CCD area detector' diffractometer	22773 independent reflections
Radiation source: fine-focus sealed tube	18894 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.036
ω scans	θmax = 29.0°, θmin = 1.7°
Absorption correction: multi-scan SADABS (Sheldrick, 2003)	h = −20→20
Tmin = 0.771, Tmax = 0.855	k = −21→21
104605 measured reflections	l = −50→50

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.029	Hydrogen site location: mixed
wR(F^2) = 0.062	H atoms treated by a mixture of independent and constrained refinement
S = 1.01	w = 1/[σ^2(Fo^2) + (0.0191P)^2 + 13.8245P] where P = (Fo^2 + 2Fc^2)/3
22773 reflections	(Δ/σ)max = 0.004
1176 parameters	Δρmax = 0.93 e Å^−3
0 restraints	Δρmin = −1.44 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Eu1A	0.731265 (7)	0.521073 (7)	0.875513 (3)	0.01089 (3)
P1A	0.52326 (4)	0.63898 (4)	0.879285 (16)	0.01315 (11)
P2A	0.96823 (4)	0.62481 (4)	0.878464 (16)	0.01363 (11)
O1A	0.76565 (12)	0.52959 (11)	0.80942 (4)	0.0204 (3)
O2A	0.64615 (12)	0.45960 (11)	0.81978 (5)	0.0210 (4)
O3A	0.69597 (15)	0.45132 (12)	0.76627 (5)	0.0298 (4)
O4A	0.82543 (12)	0.39673 (11)	0.85542 (5)	0.0229 (4)
O5A	0.83595 (12)	0.42192 (11)	0.91352 (5)	0.0206 (4)
O6A	0.91879 (15)	0.32354 (13)	0.89296 (7)	0.0427 (6)
O7A	0.66773 (11)	0.46032 (10)	0.93622 (4)	0.0177 (3)
O8A	0.64547 (11)	0.38770 (10)	0.88616 (4)	0.0157 (3)
O9A	0.57258 (12)	0.35503 (11)	0.93268 (5)	0.0224 (4)
O11A	0.57892 (11)	0.56003 (10)	0.88092 (5)	0.0160 (3)
O12A	0.87849 (11)	0.58178 (10)	0.87358 (4)	0.0160 (3)
O13A	0.75721 (11)	0.70998 (10)	0.82566 (4)	0.0174 (3)
O14A	0.81385 (12)	0.83531 (11)	0.92168 (5)	0.0215 (4)
N1A	0.70249 (14)	0.47955 (13)	0.79743 (5)	0.0193 (4)
N2A	0.86113 (14)	0.37940 (13)	0.88759 (6)	0.0220 (4)
N3A	0.62811 (13)	0.40057 (12)	0.91891 (5)	0.0145 (4)
N4A	0.69863 (13)	0.67453 (12)	0.84935 (5)	0.0143 (4)
N5A	0.58677 (13)	0.72548 (12)	0.88385 (6)	0.0149 (4)
H5A	0.571 (2)	0.7636 (19)	0.8949 (8)	0.022 (8)*
N6A	0.85515 (13)	0.76069 (12)	0.91034 (6)	0.0180 (4)
N7A	0.96629 (13)	0.72868 (12)	0.87176 (5)	0.0162 (4)
C3A	0.65285 (15)	0.73918 (14)	0.86072 (6)	0.0133 (4)
C4A	0.68014 (16)	0.81689 (15)	0.84625 (6)	0.0174 (5)
H4AA	0.6581	0.8719	0.8506	0.021*
C5A	0.74482 (17)	0.79473 (15)	0.82486 (6)	0.0182 (5)
C6A	0.8007 (2)	0.84253 (17)	0.80083 (7)	0.0290 (6)
H6AA	0.8647	0.8282	0.8071	0.044*
H6AB	0.7920	0.9033	0.8043	0.044*
H6AC	0.7822	0.8277	0.7752	0.044*
C7A	0.91485 (16)	0.78613 (15)	0.88888 (6)	0.0164 (4)
C8A	0.91674 (18)	0.87557 (15)	0.88552 (7)	0.0218 (5)
H8AA	0.9547	0.9089	0.8720	0.026*
C9A	0.8523 (2)	0.90215 (16)	0.90593 (7)	0.0255 (5)
C10A	0.8142 (3)	0.98638 (19)	0.91392 (9)	0.0471 (9)
H10A	0.7749	1.0062	0.8925	0.071*
H10B	0.8639	1.0267	0.9196	0.071*
H10C	0.7789	0.9817	0.9349	0.071*
C11A	0.45720 (15)	0.64622 (15)	0.83550 (6)	0.0160 (4)
C12A	0.44376 (16)	0.57329 (15)	0.81390 (7)	0.0191 (5)
H12A	0.4677	0.5206	0.8228	0.023*
C13A	0.39503 (17)	0.57856 (17)	0.77938 (7)	0.0230 (5)
H13A	0.3854	0.5292	0.7648	0.028*
C14A	0.36048 (17)	0.65564 (18)	0.76626 (7)	0.0247 (5)
H14A	0.3272	0.6588	0.7427	0.030*
C15A	0.37440 (17)	0.72814 (17)	0.78746 (7)	0.0229 (5)
H15A	0.3509	0.7808	0.7783	0.028*
C16A	0.42257 (16)	0.72400 (15)	0.82205 (7)	0.0184 (5)
H16A	0.4320	0.7736	0.8365	0.022*
C17A	0.45667 (15)	0.64776 (14)	0.91680 (6)	0.0153 (4)
C18A	0.38316 (16)	0.70277 (15)	0.91627 (7)	0.0179 (5)
H18A	0.3628	0.7329	0.8946	0.021*
C19A	0.33970 (16)	0.71333 (16)	0.94783 (7)	0.0202 (5)
H19A	0.2896	0.7508	0.9477	0.024*
C20A	0.36976 (17)	0.66908 (16)	0.97949 (7)	0.0208 (5)
H20A	0.3406	0.6769	1.0010	0.025*
C21A	0.44213 (17)	0.61359 (16)	0.97977 (7)	0.0218 (5)
H21A	0.4620	0.5831	1.0014	0.026*
C22A	0.48558 (16)	0.60237 (16)	0.94862 (7)	0.0196 (5)
H22A	0.5349	0.5640	0.9488	0.023*
C23A	1.04230 (15)	0.59356 (14)	0.84562 (6)	0.0164 (4)
C24A	1.13273 (16)	0.62031 (16)	0.85021 (7)	0.0202 (5)
H24A	1.1553	0.6509	0.8715	0.024*
C25A	1.18910 (17)	0.60196 (17)	0.82358 (7)	0.0227 (5)
H25A	1.2504	0.6202	0.8265	0.027*
C26A	1.15602 (18)	0.55697 (18)	0.79259 (7)	0.0255 (5)
H26A	1.1947	0.5448	0.7743	0.031*
C27A	1.06664 (18)	0.52974 (18)	0.78827 (8)	0.0286 (6)
H27A	1.0446	0.4986	0.7670	0.034*
C28A	1.00911 (17)	0.54755 (17)	0.81471 (7)	0.0231 (5)
H28A	0.9480	0.5286	0.8118	0.028*
C29A	1.02631 (15)	0.60557 (15)	0.92308 (6)	0.0165 (4)
C30A	1.07679 (16)	0.66720 (16)	0.94296 (7)	0.0199 (5)
H30A	1.0779	0.7234	0.9339	0.024*
C31A	1.12583 (17)	0.64672 (18)	0.97626 (7)	0.0240 (5)
H31A	1.1600	0.6892	0.9898	0.029*
C32A	1.1253 (2)	0.5659 (2)	0.98970 (8)	0.0346 (7)
H32A	1.1590	0.5525	1.0124	0.042*
C33A	1.0753 (3)	0.5039 (2)	0.96995 (10)	0.0510 (10)
H33A	1.0749	0.4478	0.9791	0.061*
C34A	1.0259 (2)	0.52355 (18)	0.93683 (9)	0.0369 (7)
H34A	0.9916	0.4809	0.9235	0.044*
Eu1B	0.649778 (7)	0.979599 (7)	0.118723 (3)	0.01061 (3)
P1B	0.43904 (4)	0.86475 (4)	0.119313 (15)	0.01189 (10)
P2B	0.87874 (4)	0.86760 (4)	0.114352 (16)	0.01318 (11)
O1B	0.73087 (11)	0.97595 (11)	0.18335 (4)	0.0184 (3)
O2B	0.60662 (12)	1.04801 (11)	0.17602 (5)	0.0207 (4)
O3B	0.69626 (13)	1.05970 (11)	0.22696 (5)	0.0250 (4)
O4B	0.73168 (11)	1.06776 (10)	0.07496 (4)	0.0181 (3)
O5B	0.76262 (12)	1.10238 (11)	0.13176 (5)	0.0204 (4)
O6B	0.84147 (13)	1.15625 (13)	0.09074 (6)	0.0350 (5)
O7B	0.54537 (11)	1.03847 (10)	0.06002 (4)	0.0171 (3)
O8B	0.55928 (11)	1.11290 (10)	0.10970 (4)	0.0156 (3)
O9B	0.44789 (12)	1.13850 (11)	0.06734 (5)	0.0232 (4)
O10B	0.64226 (11)	0.87801 (10)	0.06875 (4)	0.0159 (3)
O11B	0.49474 (10)	0.94327 (10)	0.11825 (4)	0.0148 (3)
O12B	0.79539 (10)	0.91804 (10)	0.11809 (4)	0.0151 (3)
O13B	0.70094 (11)	0.79116 (10)	0.17277 (4)	0.0168 (3)
O14B	0.70413 (12)	0.65373 (10)	0.07544 (5)	0.0204 (4)
N1B	0.67841 (14)	1.02871 (12)	0.19654 (5)	0.0170 (4)
N2B	0.78004 (14)	1.10984 (13)	0.09872 (6)	0.0200 (4)
N3B	0.51640 (13)	1.09721 (12)	0.07853 (5)	0.0158 (4)
N4B	0.63180 (12)	0.82686 (12)	0.14813 (5)	0.0142 (4)
N5B	0.49878 (13)	0.77773 (12)	0.11457 (5)	0.0133 (4)
H5B	0.4772 (19)	0.7394 (18)	0.1028 (8)	0.017 (7)*
N6B	0.74606 (13)	0.73052 (12)	0.08773 (5)	0.0167 (4)
N7B	0.87501 (14)	0.76751 (12)	0.12691 (6)	0.0173 (4)
H7B	0.908 (2)	0.750 (2)	0.1426 (8)	0.026 (8)*
C1B	0.61661 (17)	0.87192 (16)	0.02955 (6)	0.0203 (5)
H1BA	0.6719	0.8696	0.0167	0.024*
H1BB	0.5818	0.9229	0.0210	0.024*
C2B	0.55985 (19)	0.79418 (17)	0.02014 (7)	0.0267 (6)
H2BA	0.5462	0.7901	−0.0065	0.040*
H2BB	0.5032	0.7982	0.0315	0.040*
H2BC	0.5934	0.7438	0.0293	0.040*
C3B	0.57679 (15)	0.76330 (14)	0.13794 (6)	0.0130 (4)
C4B	0.60782 (16)	0.68582 (15)	0.15420 (6)	0.0177 (5)
H4BA	0.5809	0.6315	0.1509	0.021*
C5B	0.68446 (17)	0.70727 (15)	0.17540 (6)	0.0185 (5)
C6B	0.74975 (19)	0.65909 (18)	0.20105 (8)	0.0292 (6)
H6BA	0.8116	0.6704	0.1954	0.044*
H6BB	0.7370	0.5985	0.1984	0.044*
H6BC	0.7436	0.6766	0.2262	0.044*
C7B	0.81683 (16)	0.70755 (14)	0.11004 (6)	0.0159 (4)
C8B	0.82454 (18)	0.61846 (15)	0.11382 (8)	0.0243 (5)
H8BA	0.8692	0.5871	0.1286	0.029*
C9B	0.75367 (19)	0.58879 (16)	0.09149 (8)	0.0280 (6)
C10B	0.7194 (3)	0.50267 (18)	0.08138 (12)	0.0537 (11)
H10D	0.6990	0.5009	0.0551	0.081*
H10E	0.6685	0.4891	0.0953	0.081*
H10F	0.7680	0.4613	0.0871	0.081*
C11B	0.35181 (15)	0.85824 (14)	0.08173 (6)	0.0141 (4)
C12B	0.27516 (15)	0.80745 (15)	0.08262 (6)	0.0166 (4)
H12B	0.2661	0.7769	0.1042	0.020*
C13B	0.21219 (16)	0.80180 (15)	0.05185 (7)	0.0197 (5)
H13B	0.1598	0.7675	0.0524	0.024*
C14B	0.22596 (17)	0.84654 (16)	0.02030 (7)	0.0209 (5)
H14B	0.1828	0.8425	−0.0007	0.025*
C15B	0.30188 (17)	0.89677 (16)	0.01918 (7)	0.0212 (5)
H15B	0.3109	0.9268	−0.0025	0.025*
C16B	0.36497 (16)	0.90327 (15)	0.04987 (6)	0.0180 (5)
H16B	0.4169	0.9382	0.0493	0.022*
C17B	0.39465 (15)	0.85706 (14)	0.16274 (6)	0.0135 (4)
C18B	0.39156 (15)	0.92941 (15)	0.18448 (6)	0.0175 (5)
H18B	0.4115	0.9822	0.1760	0.021*
C19B	0.35910 (16)	0.92387 (17)	0.21863 (7)	0.0211 (5)
H19B	0.3567	0.9730	0.2334	0.025*
C20B	0.33033 (17)	0.84670 (17)	0.23110 (7)	0.0228 (5)
H20B	0.3080	0.8431	0.2543	0.027*
C21B	0.33409 (17)	0.77453 (17)	0.20962 (7)	0.0222 (5)
H21B	0.3145	0.7218	0.2183	0.027*
C22B	0.36626 (16)	0.77938 (15)	0.17561 (6)	0.0181 (5)
H22B	0.3690	0.7300	0.1611	0.022*
C23B	0.90561 (15)	0.86713 (15)	0.06782 (6)	0.0177 (5)
C24B	0.8849 (2)	0.93786 (18)	0.04589 (7)	0.0286 (6)
H24B	0.8545	0.9847	0.0552	0.034*
C25B	0.9091 (2)	0.9397 (2)	0.01015 (8)	0.0399 (8)
H25B	0.8955	0.9881	−0.0048	0.048*
C26B	0.9526 (2)	0.8714 (2)	−0.00347 (8)	0.0364 (7)
H26B	0.9696	0.8731	−0.0277	0.044*
C27B	0.97164 (18)	0.8008 (2)	0.01790 (8)	0.0305 (6)
H27B	1.0006	0.7535	0.0082	0.037*
C28B	0.94879 (16)	0.79807 (17)	0.05352 (7)	0.0226 (5)
H28B	0.9625	0.7493	0.0682	0.027*
C29B	0.97375 (15)	0.90382 (14)	0.14429 (6)	0.0156 (4)
C30B	1.06084 (16)	0.87498 (16)	0.14014 (7)	0.0207 (5)
H30B	1.0714	0.8414	0.1196	0.025*
C31B	1.13231 (17)	0.89586 (17)	0.16636 (7)	0.0255 (6)
H31B	1.1917	0.8760	0.1638	0.031*
C32B	1.11686 (17)	0.94545 (17)	0.19613 (7)	0.0238 (5)
H32B	1.1656	0.9585	0.2142	0.029*
C33B	1.03076 (17)	0.97626 (16)	0.19977 (7)	0.0220 (5)
H33B	1.0211	1.0118	0.2198	0.026*
C34B	0.95867 (16)	0.95506 (15)	0.17409 (7)	0.0183 (5)
H34B	0.8994	0.9752	0.1768	0.022*
O10A	0.75961 (11)	0.61770 (10)	0.92720 (4)	0.0188 (3)
C2A	0.7839 (4)	0.6857 (3)	0.98813 (13)	0.0302 (11)	0.60
H2AA	0.7608	0.6871	1.0121	0.045*	0.60
H2AB	0.7854	0.7433	0.9783	0.045*	0.60
H2AC	0.8453	0.6620	0.9907	0.045*	0.60
C1A	0.7239 (4)	0.6325 (3)	0.96279 (13)	0.0291 (11)	0.60
H1AA	0.6639	0.6601	0.9583	0.035*	0.60
H1AB	0.7152	0.5773	0.9746	0.035*	0.60
C1'A	0.7755 (6)	0.6186 (4)	0.96435 (17)	0.0218 (13)	0.40
H1'A	0.8417	0.6190	0.9716	0.026*	0.40
H1'B	0.7503	0.5665	0.9743	0.026*	0.40
C2'A	0.7323 (6)	0.6965 (6)	0.9807 (2)	0.0339 (18)	0.40
H2'A	0.7427	0.6941	1.0075	0.051*	0.40
H2'B	0.6670	0.6970	0.9731	0.051*	0.40
H2'C	0.7597	0.7481	0.9720	0.051*	0.40
O1S	0.07558 (12)	0.82275 (12)	0.82735 (5)	0.0235 (4)
C1S	0.11108 (18)	0.81660 (19)	0.79263 (7)	0.0282 (6)
H1SA	0.1647	0.7790	0.7947	0.034*
H1SB	0.1300	0.8732	0.7848	0.034*
O2S	−0.00007 (14)	0.68435 (13)	0.17818 (5)	0.0321 (4)
C2S	0.0388 (2)	0.7816 (2)	0.76495 (8)	0.0376 (7)
H2SA	0.0636	0.7740	0.7415	0.056*
H2SB	−0.0124	0.8209	0.7618	0.056*
H2SC	0.0182	0.7269	0.7735	0.056*
C3S	0.0142 (8)	0.7128 (8)	0.2133 (4)	0.032 (2)	0.45
H3SA	−0.0360	0.6934	0.2269	0.039*	0.45
H3SB	0.0139	0.7753	0.2133	0.039*	0.45
C4S	0.1010 (6)	0.6826 (8)	0.2323 (3)	0.051 (3)	0.45
H4SA	0.1082	0.7043	0.2575	0.077*	0.45
H4SB	0.1512	0.7029	0.2194	0.077*	0.45
H4SC	0.1013	0.6207	0.2328	0.077*	0.45
C4'S	0.0646 (9)	0.6664 (8)	0.2426 (3)	0.040 (3)	0.35
H4'A	0.0888	0.6958	0.2651	0.060*	0.35
H4'B	0.1092	0.6252	0.2359	0.060*	0.35
H4'C	0.0085	0.6371	0.2468	0.060*	0.35
C3'S	0.0452 (9)	0.7302 (9)	0.2119 (4)	0.027 (3)	0.35
H3'A	0.1024	0.7569	0.2062	0.033*	0.35
H3'B	0.0047	0.7752	0.2195	0.033*	0.35
C4RS	0.0746 (15)	0.7455 (14)	0.2357 (5)	0.051 (5)	0.20
H4RA	0.0948	0.7336	0.2614	0.077*	0.20
H4RB	0.0343	0.7947	0.2340	0.077*	0.20
H4RC	0.1273	0.7572	0.2225	0.077*	0.20
C3RS	0.0273 (9)	0.6743 (9)	0.2197 (3)	0.044 (5)	0.20
H3RA	−0.0280	0.6651	0.2321	0.053*	0.20
H3RB	0.0660	0.6235	0.2239	0.053*	0.20
H7A	0.9970	0.7477	0.8555	0.053*
H1OB	0.6765	0.8393	0.0731	0.053*
H1S	0.1163	0.8378	0.8453	0.053*
H2S	0.0429	0.6757	0.1662	0.053*
H1OA	0.7929	0.6602	0.9224	0.053*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Eu1A	0.01217 (5)	0.00948 (5)	0.01108 (5)	0.00055 (4)	0.00155 (4)	−0.00111 (4)
P1A	0.0115 (3)	0.0116 (3)	0.0165 (3)	0.0006 (2)	0.0021 (2)	−0.0007 (2)
P2A	0.0122 (3)	0.0114 (3)	0.0175 (3)	0.0003 (2)	0.0027 (2)	−0.0021 (2)
O1A	0.0275 (9)	0.0186 (8)	0.0157 (8)	−0.0017 (7)	0.0051 (7)	−0.0007 (7)
O2A	0.0221 (9)	0.0252 (9)	0.0154 (8)	−0.0038 (7)	0.0006 (7)	−0.0025 (7)
O3A	0.0530 (13)	0.0253 (10)	0.0114 (8)	−0.0021 (9)	0.0043 (8)	−0.0059 (7)
O4A	0.0284 (9)	0.0174 (8)	0.0233 (9)	0.0039 (7)	0.0042 (7)	−0.0020 (7)
O5A	0.0204 (9)	0.0203 (9)	0.0206 (9)	0.0015 (7)	0.0001 (7)	0.0027 (7)
O6A	0.0380 (12)	0.0294 (11)	0.0596 (15)	0.0235 (10)	0.0003 (11)	0.0036 (10)
O7A	0.0220 (8)	0.0135 (8)	0.0174 (8)	−0.0041 (6)	0.0003 (7)	−0.0044 (6)
O8A	0.0218 (8)	0.0133 (7)	0.0127 (7)	−0.0024 (6)	0.0044 (6)	−0.0020 (6)
O9A	0.0288 (9)	0.0219 (9)	0.0178 (8)	−0.0112 (7)	0.0086 (7)	−0.0024 (7)
O11A	0.0136 (8)	0.0127 (7)	0.0222 (8)	0.0017 (6)	0.0036 (6)	−0.0007 (6)
O12A	0.0131 (8)	0.0152 (8)	0.0200 (8)	−0.0003 (6)	0.0033 (6)	−0.0019 (6)
O13A	0.0206 (8)	0.0155 (8)	0.0174 (8)	−0.0006 (6)	0.0079 (7)	0.0032 (6)
O14A	0.0272 (9)	0.0175 (8)	0.0206 (9)	0.0074 (7)	0.0066 (7)	−0.0029 (7)
N1A	0.0288 (11)	0.0155 (9)	0.0136 (9)	0.0041 (9)	0.0024 (8)	0.0015 (8)
N2A	0.0188 (10)	0.0160 (10)	0.0313 (12)	0.0022 (8)	0.0025 (9)	0.0004 (9)
N3A	0.0159 (9)	0.0119 (9)	0.0155 (9)	−0.0005 (7)	0.0006 (7)	0.0003 (7)
N4A	0.0141 (9)	0.0145 (9)	0.0147 (9)	−0.0004 (7)	0.0034 (7)	0.0021 (7)
N5A	0.0137 (9)	0.0115 (9)	0.0201 (10)	0.0011 (7)	0.0040 (8)	−0.0023 (8)
N6A	0.0190 (10)	0.0136 (9)	0.0218 (10)	0.0053 (8)	0.0049 (8)	−0.0034 (8)
N7A	0.0190 (9)	0.0117 (9)	0.0188 (10)	0.0010 (7)	0.0065 (8)	−0.0011 (7)
C3A	0.0133 (10)	0.0134 (10)	0.0125 (10)	0.0005 (8)	−0.0015 (8)	0.0010 (8)
C4A	0.0218 (11)	0.0124 (10)	0.0178 (11)	0.0018 (9)	0.0018 (9)	0.0012 (9)
C5A	0.0258 (12)	0.0142 (11)	0.0145 (11)	−0.0009 (9)	0.0012 (9)	0.0037 (9)
C6A	0.0417 (16)	0.0239 (13)	0.0234 (13)	−0.0064 (12)	0.0122 (12)	0.0053 (11)
C7A	0.0176 (11)	0.0146 (11)	0.0168 (11)	0.0022 (9)	0.0015 (9)	−0.0005 (9)
C8A	0.0337 (14)	0.0128 (11)	0.0192 (12)	0.0025 (10)	0.0044 (10)	0.0007 (9)
C9A	0.0394 (15)	0.0160 (12)	0.0214 (12)	0.0075 (11)	0.0045 (11)	0.0005 (10)
C10A	0.083 (3)	0.0210 (14)	0.0411 (18)	0.0228 (16)	0.0234 (18)	0.0035 (13)
C11A	0.0123 (10)	0.0187 (11)	0.0175 (11)	−0.0009 (8)	0.0034 (8)	0.0005 (9)
C12A	0.0170 (11)	0.0180 (11)	0.0229 (12)	0.0007 (9)	0.0050 (9)	−0.0031 (9)
C13A	0.0214 (12)	0.0279 (13)	0.0206 (12)	−0.0028 (10)	0.0053 (10)	−0.0083 (10)
C14A	0.0208 (12)	0.0372 (15)	0.0161 (11)	0.0003 (11)	0.0023 (9)	0.0013 (11)
C15A	0.0216 (12)	0.0266 (13)	0.0205 (12)	0.0027 (10)	0.0018 (10)	0.0039 (10)
C16A	0.0181 (11)	0.0181 (11)	0.0191 (11)	0.0006 (9)	0.0026 (9)	−0.0003 (9)
C17A	0.0156 (10)	0.0144 (10)	0.0161 (11)	−0.0031 (8)	0.0035 (8)	−0.0021 (8)
C18A	0.0171 (11)	0.0161 (11)	0.0208 (12)	0.0004 (9)	0.0038 (9)	0.0029 (9)
C19A	0.0170 (11)	0.0198 (12)	0.0247 (12)	0.0032 (9)	0.0063 (9)	0.0005 (10)
C20A	0.0203 (12)	0.0237 (12)	0.0191 (12)	−0.0009 (10)	0.0057 (9)	−0.0045 (10)
C21A	0.0251 (13)	0.0253 (13)	0.0148 (11)	0.0038 (10)	0.0012 (9)	−0.0016 (10)
C22A	0.0178 (11)	0.0220 (12)	0.0187 (11)	0.0051 (9)	0.0010 (9)	−0.0017 (9)
C23A	0.0154 (11)	0.0142 (10)	0.0199 (11)	0.0027 (8)	0.0037 (9)	−0.0014 (9)
C24A	0.0157 (11)	0.0231 (12)	0.0219 (12)	−0.0006 (9)	0.0030 (9)	−0.0038 (10)
C25A	0.0158 (11)	0.0274 (13)	0.0259 (13)	−0.0002 (10)	0.0062 (10)	−0.0022 (10)
C26A	0.0238 (13)	0.0293 (14)	0.0248 (13)	0.0037 (11)	0.0089 (10)	−0.0062 (11)
C27A	0.0252 (13)	0.0348 (15)	0.0261 (13)	−0.0012 (11)	0.0050 (11)	−0.0140 (12)
C28A	0.0168 (11)	0.0258 (13)	0.0269 (13)	−0.0002 (10)	0.0031 (10)	−0.0087 (10)
C29A	0.0130 (10)	0.0172 (11)	0.0194 (11)	0.0003 (8)	0.0026 (8)	−0.0001 (9)
C30A	0.0181 (11)	0.0198 (12)	0.0221 (12)	−0.0004 (9)	0.0034 (9)	−0.0037 (10)
C31A	0.0182 (12)	0.0327 (14)	0.0210 (12)	−0.0024 (10)	0.0015 (9)	−0.0110 (11)
C32A	0.0292 (15)	0.0436 (18)	0.0285 (15)	−0.0020 (13)	−0.0088 (12)	0.0063 (13)
C33A	0.059 (2)	0.0314 (17)	0.055 (2)	−0.0126 (15)	−0.0306 (18)	0.0207 (15)
C34A	0.0420 (17)	0.0206 (13)	0.0427 (17)	−0.0113 (12)	−0.0209 (14)	0.0074 (13)
Eu1B	0.01103 (5)	0.00919 (5)	0.01141 (5)	−0.00034 (4)	0.00030 (4)	−0.00111 (4)
P1B	0.0115 (2)	0.0116 (3)	0.0125 (3)	−0.0005 (2)	0.0004 (2)	−0.0008 (2)
P2B	0.0121 (3)	0.0116 (3)	0.0155 (3)	0.0008 (2)	−0.0002 (2)	−0.0013 (2)
O1B	0.0209 (8)	0.0174 (8)	0.0164 (8)	0.0013 (7)	0.0001 (6)	−0.0018 (7)
O2B	0.0215 (9)	0.0243 (9)	0.0159 (8)	0.0041 (7)	−0.0004 (7)	−0.0025 (7)
O3B	0.0408 (11)	0.0221 (9)	0.0114 (8)	−0.0044 (8)	−0.0004 (7)	−0.0038 (7)
O4B	0.0174 (8)	0.0183 (8)	0.0183 (8)	−0.0003 (6)	0.0004 (6)	0.0031 (7)
O5B	0.0223 (9)	0.0170 (8)	0.0217 (9)	−0.0047 (7)	0.0012 (7)	−0.0016 (7)
O6B	0.0271 (10)	0.0347 (11)	0.0429 (12)	−0.0176 (9)	0.0030 (9)	0.0107 (9)
O7B	0.0213 (8)	0.0132 (8)	0.0169 (8)	0.0016 (6)	0.0029 (6)	−0.0045 (6)
O8B	0.0187 (8)	0.0130 (7)	0.0141 (8)	0.0017 (6)	−0.0027 (6)	−0.0022 (6)
O9B	0.0240 (9)	0.0215 (9)	0.0225 (9)	0.0116 (7)	−0.0046 (7)	−0.0017 (7)
O10B	0.0188 (8)	0.0138 (8)	0.0143 (8)	0.0036 (6)	−0.0023 (6)	−0.0028 (6)
O11B	0.0141 (7)	0.0119 (7)	0.0182 (8)	−0.0013 (6)	0.0005 (6)	−0.0002 (6)
O12B	0.0126 (7)	0.0129 (7)	0.0195 (8)	0.0015 (6)	0.0000 (6)	−0.0023 (6)
O13B	0.0162 (8)	0.0159 (8)	0.0170 (8)	0.0009 (6)	−0.0042 (6)	0.0027 (6)
O14B	0.0218 (9)	0.0133 (8)	0.0251 (9)	−0.0030 (7)	−0.0024 (7)	−0.0024 (7)
N1B	0.0242 (10)	0.0131 (9)	0.0137 (9)	−0.0040 (8)	0.0019 (8)	0.0008 (7)
N2B	0.0165 (10)	0.0169 (10)	0.0261 (11)	0.0001 (8)	0.0005 (8)	0.0050 (8)
N3B	0.0197 (10)	0.0111 (9)	0.0167 (9)	0.0006 (7)	0.0019 (8)	0.0005 (7)
N4B	0.0134 (9)	0.0148 (9)	0.0133 (9)	0.0015 (7)	−0.0031 (7)	0.0023 (7)
N5B	0.0135 (9)	0.0110 (9)	0.0148 (9)	−0.0019 (7)	−0.0011 (7)	−0.0024 (7)
N6B	0.0183 (9)	0.0116 (9)	0.0198 (10)	−0.0026 (7)	0.0002 (8)	−0.0039 (7)
N7B	0.0176 (10)	0.0112 (9)	0.0219 (10)	0.0011 (8)	−0.0044 (8)	0.0005 (8)
C1B	0.0267 (13)	0.0210 (12)	0.0132 (11)	0.0004 (10)	0.0016 (9)	−0.0021 (9)
C2B	0.0318 (14)	0.0239 (13)	0.0225 (13)	−0.0031 (11)	−0.0050 (11)	−0.0035 (10)
C3B	0.0133 (10)	0.0143 (10)	0.0118 (10)	0.0016 (8)	0.0035 (8)	−0.0001 (8)
C4B	0.0205 (11)	0.0127 (10)	0.0198 (11)	0.0006 (9)	0.0011 (9)	0.0041 (9)
C5B	0.0225 (12)	0.0153 (11)	0.0172 (11)	0.0022 (9)	0.0003 (9)	0.0036 (9)
C6B	0.0320 (15)	0.0253 (13)	0.0277 (14)	0.0051 (11)	−0.0087 (11)	0.0092 (11)
C7B	0.0177 (11)	0.0121 (10)	0.0180 (11)	0.0007 (8)	0.0028 (9)	0.0002 (8)
C8B	0.0258 (13)	0.0118 (11)	0.0333 (14)	0.0019 (9)	−0.0065 (11)	0.0010 (10)
C9B	0.0294 (14)	0.0144 (12)	0.0384 (16)	−0.0010 (10)	−0.0056 (12)	0.0007 (11)
C10B	0.055 (2)	0.0151 (14)	0.083 (3)	−0.0061 (13)	−0.028 (2)	−0.0041 (15)
C11B	0.0120 (10)	0.0140 (10)	0.0159 (10)	0.0019 (8)	−0.0009 (8)	−0.0018 (8)
C12B	0.0154 (10)	0.0157 (11)	0.0182 (11)	0.0006 (8)	−0.0002 (9)	−0.0020 (9)
C13B	0.0158 (11)	0.0187 (11)	0.0235 (12)	−0.0014 (9)	−0.0025 (9)	−0.0049 (9)
C14B	0.0203 (12)	0.0209 (12)	0.0197 (12)	0.0035 (9)	−0.0062 (9)	−0.0064 (10)
C15B	0.0251 (12)	0.0234 (12)	0.0145 (11)	0.0029 (10)	−0.0010 (9)	−0.0001 (9)
C16B	0.0165 (11)	0.0205 (11)	0.0168 (11)	−0.0003 (9)	0.0010 (9)	−0.0005 (9)
C17B	0.0124 (10)	0.0160 (10)	0.0115 (10)	0.0004 (8)	−0.0006 (8)	−0.0007 (8)
C18B	0.0147 (11)	0.0185 (11)	0.0188 (11)	0.0006 (9)	−0.0004 (9)	−0.0028 (9)
C19B	0.0182 (11)	0.0262 (13)	0.0184 (11)	0.0033 (9)	−0.0011 (9)	−0.0073 (10)
C20B	0.0196 (12)	0.0338 (14)	0.0152 (11)	0.0026 (10)	0.0026 (9)	−0.0012 (10)
C21B	0.0261 (13)	0.0230 (12)	0.0179 (12)	−0.0004 (10)	0.0037 (10)	0.0041 (10)
C22B	0.0187 (11)	0.0180 (11)	0.0176 (11)	−0.0007 (9)	0.0023 (9)	−0.0008 (9)
C23B	0.0123 (10)	0.0218 (12)	0.0186 (11)	0.0015 (9)	0.0003 (8)	−0.0018 (9)
C24B	0.0345 (15)	0.0284 (14)	0.0240 (13)	0.0095 (12)	0.0090 (11)	0.0025 (11)
C25B	0.0462 (19)	0.0484 (19)	0.0270 (15)	0.0175 (15)	0.0129 (13)	0.0144 (14)
C26B	0.0290 (15)	0.063 (2)	0.0182 (13)	0.0102 (14)	0.0052 (11)	−0.0006 (13)
C27B	0.0211 (13)	0.0434 (17)	0.0264 (14)	0.0101 (12)	0.0004 (11)	−0.0103 (12)
C28B	0.0184 (11)	0.0267 (13)	0.0220 (12)	0.0051 (10)	−0.0012 (9)	−0.0053 (10)
C29B	0.0149 (10)	0.0142 (10)	0.0168 (11)	−0.0006 (8)	−0.0016 (8)	−0.0005 (8)
C30B	0.0163 (11)	0.0209 (12)	0.0244 (12)	0.0025 (9)	−0.0006 (9)	−0.0055 (10)
C31B	0.0130 (11)	0.0301 (14)	0.0318 (14)	0.0032 (10)	−0.0045 (10)	−0.0066 (11)
C32B	0.0194 (12)	0.0231 (12)	0.0269 (13)	−0.0013 (10)	−0.0065 (10)	−0.0034 (10)
C33B	0.0218 (12)	0.0205 (12)	0.0233 (12)	−0.0023 (10)	0.0003 (9)	−0.0067 (10)
C34B	0.0145 (11)	0.0175 (11)	0.0227 (12)	−0.0003 (9)	0.0018 (9)	−0.0042 (9)
O10A	0.0228 (9)	0.0171 (8)	0.0177 (8)	−0.0065 (7)	0.0070 (7)	−0.0077 (7)
C2A	0.042 (3)	0.033 (3)	0.015 (2)	−0.006 (3)	0.004 (2)	−0.0041 (19)
C1A	0.033 (3)	0.035 (3)	0.021 (2)	−0.013 (2)	0.012 (2)	−0.012 (2)
C1'A	0.030 (4)	0.020 (3)	0.015 (3)	−0.009 (3)	−0.001 (3)	0.002 (2)
C2'A	0.035 (4)	0.046 (5)	0.022 (4)	−0.011 (4)	0.010 (3)	−0.010 (3)
O1S	0.0245 (9)	0.0259 (9)	0.0203 (9)	−0.0052 (7)	0.0026 (7)	0.0005 (7)
C1S	0.0244 (13)	0.0349 (15)	0.0264 (14)	−0.0024 (11)	0.0076 (11)	0.0033 (12)
O2S	0.0333 (11)	0.0353 (11)	0.0266 (10)	0.0071 (9)	−0.0022 (8)	0.0042 (9)
C2S	0.0369 (16)	0.0488 (19)	0.0274 (15)	−0.0087 (14)	0.0049 (13)	−0.0074 (14)
C3S	0.035 (6)	0.033 (7)	0.030 (5)	−0.001 (5)	0.006 (5)	0.010 (4)
C4S	0.036 (5)	0.073 (8)	0.042 (6)	0.000 (5)	−0.012 (4)	−0.001 (5)
C4'S	0.050 (7)	0.036 (5)	0.032 (6)	−0.003 (5)	−0.011 (5)	0.009 (4)
C3'S	0.040 (8)	0.022 (6)	0.020 (5)	−0.007 (5)	0.003 (6)	0.001 (4)
C4RS	0.067 (13)	0.061 (13)	0.024 (9)	0.004 (11)	0.000 (9)	−0.004 (9)
C3RS	0.063 (14)	0.037 (11)	0.029 (10)	−0.004 (10)	−0.008 (9)	0.025 (8)

Geometric parameters (Å, º)

Eu1A—O11A	2.3721 (16)	O8B—N3B	1.274 (2)
Eu1A—O12A	2.3945 (16)	O9B—N3B	1.241 (2)
Eu1A—O10A	2.4391 (16)	O10B—C1B	1.453 (3)
Eu1A—O2A	2.4859 (17)	O10B—H1OB	0.8002
Eu1A—O8A	2.5163 (16)	O13B—C5B	1.355 (3)
Eu1A—O5A	2.5214 (17)	O13B—N4B	1.411 (2)
Eu1A—O1A	2.5386 (16)	O14B—C9B	1.360 (3)
Eu1A—O4A	2.5666 (17)	O14B—N6B	1.416 (2)
Eu1A—N4A	2.6364 (19)	N4B—C3B	1.323 (3)
Eu1A—O7A	2.6910 (17)	N5B—C3B	1.384 (3)
Eu1A—N1A	2.9296 (19)	N5B—H5B	0.79 (3)
Eu1A—N2A	2.958 (2)	N6B—C7B	1.312 (3)
P1A—O11A	1.4949 (16)	N7B—C7B	1.383 (3)
P1A—N5A	1.660 (2)	N7B—H7B	0.77 (3)
P1A—C17A	1.786 (2)	C1B—C2B	1.509 (3)
P1A—C11A	1.796 (2)	C1B—H1BA	0.9900
P2A—O12A	1.4892 (17)	C1B—H1BB	0.9900
P2A—N7A	1.661 (2)	C2B—H2BA	0.9800
P2A—C23A	1.787 (2)	C2B—H2BB	0.9800
P2A—C29A	1.794 (2)	C2B—H2BC	0.9800
O1A—N1A	1.269 (3)	C3B—C4B	1.418 (3)
O2A—N1A	1.273 (3)	C4B—C5B	1.351 (3)
O3A—N1A	1.223 (3)	C4B—H4BA	0.9500
O4A—N2A	1.272 (3)	C5B—C6B	1.487 (3)
O5A—N2A	1.255 (3)	C6B—H6BA	0.9800
O6A—N2A	1.231 (3)	C6B—H6BB	0.9800
O7A—N3A	1.250 (2)	C6B—H6BC	0.9800
O8A—N3A	1.274 (2)	C7B—C8B	1.419 (3)
O9A—N3A	1.242 (2)	C8B—C9B	1.347 (4)
O13A—C5A	1.353 (3)	C8B—H8BA	0.9500
O13A—N4A	1.411 (2)	C9B—C10B	1.487 (4)
O14A—C9A	1.360 (3)	C10B—H10D	0.9800
O14A—N6A	1.413 (2)	C10B—H10E	0.9800
N4A—C3A	1.320 (3)	C10B—H10F	0.9800
N5A—C3A	1.382 (3)	C11B—C12B	1.396 (3)
N5A—H5A	0.78 (3)	C11B—C16B	1.402 (3)
N6A—C7A	1.311 (3)	C12B—C13B	1.390 (3)
N7A—C7A	1.381 (3)	C12B—H12B	0.9500
N7A—H7A	0.8453	C13B—C14B	1.392 (4)
C3A—C4A	1.416 (3)	C13B—H13B	0.9500
C4A—C5A	1.351 (3)	C14B—C15B	1.383 (4)
C4A—H4AA	0.9500	C14B—H14B	0.9500
C5A—C6A	1.482 (3)	C15B—C16B	1.390 (3)
C6A—H6AA	0.9800	C15B—H15B	0.9500
C6A—H6AB	0.9800	C16B—H16B	0.9500
C6A—H6AC	0.9800	C17B—C22B	1.398 (3)
C7A—C8A	1.421 (3)	C17B—C18B	1.399 (3)
C8A—C9A	1.345 (4)	C18B—C19B	1.394 (3)
C8A—H8AA	0.9500	C18B—H18B	0.9500
C9A—C10A	1.488 (4)	C19B—C20B	1.387 (4)
C10A—H10A	0.9800	C19B—H19B	0.9500
C10A—H10B	0.9800	C20B—C21B	1.392 (4)
C10A—H10C	0.9800	C20B—H20B	0.9500
C11A—C12A	1.402 (3)	C21B—C22B	1.387 (3)
C11A—C16A	1.403 (3)	C21B—H21B	0.9500
C12A—C13A	1.394 (3)	C22B—H22B	0.9500
C12A—H12A	0.9500	C23B—C24B	1.394 (4)
C13A—C14A	1.389 (4)	C23B—C28B	1.397 (3)
C13A—H13A	0.9500	C24B—C25B	1.398 (4)
C14A—C15A	1.389 (4)	C24B—H24B	0.9500
C14A—H14A	0.9500	C25B—C26B	1.381 (4)
C15A—C16A	1.391 (3)	C25B—H25B	0.9500
C15A—H15A	0.9500	C26B—C27B	1.377 (4)
C16A—H16A	0.9500	C26B—H26B	0.9500
C17A—C18A	1.394 (3)	C27B—C28B	1.388 (4)
C17A—C22A	1.400 (3)	C27B—H27B	0.9500
C18A—C19A	1.396 (3)	C28B—H28B	0.9500
C18A—H18A	0.9500	C29B—C30B	1.394 (3)
C19A—C20A	1.390 (3)	C29B—C34B	1.400 (3)
C19A—H19A	0.9500	C30B—C31B	1.394 (3)
C20A—C21A	1.386 (3)	C30B—H30B	0.9500
C20A—H20A	0.9500	C31B—C32B	1.385 (4)
C21A—C22A	1.384 (3)	C31B—H31B	0.9500
C21A—H21A	0.9500	C32B—C33B	1.387 (4)
C22A—H22A	0.9500	C32B—H32B	0.9500
C23A—C28A	1.394 (3)	C33B—C34B	1.389 (3)
C23A—C24A	1.400 (3)	C33B—H33B	0.9500
C24A—C25A	1.385 (3)	C34B—H34B	0.9500
C24A—H24A	0.9500	O10A—C1'A	1.360 (6)
C25A—C26A	1.387 (4)	O10A—C1A	1.481 (5)
C25A—H25A	0.9500	O10A—H1OA	0.8643
C26A—C27A	1.387 (4)	C2A—C1A	1.480 (7)
C26A—H26A	0.9500	C2A—H2AA	0.9800
C27A—C28A	1.390 (4)	C2A—H2AB	0.9800
C27A—H27A	0.9500	C2A—H2AC	0.9800
C28A—H28A	0.9500	C1A—H1AA	0.9900
C29A—C30A	1.388 (3)	C1A—H1AB	0.9900
C29A—C34A	1.393 (4)	C1'A—C2'A	1.542 (11)
C30A—C31A	1.393 (4)	C1'A—H1'A	0.9900
C30A—H30A	0.9500	C1'A—H1'B	0.9900
C31A—C32A	1.370 (4)	C2'A—H2'A	0.9800
C31A—H31A	0.9500	C2'A—H2'B	0.9800
C32A—C33A	1.387 (4)	C2'A—H2'C	0.9800
C32A—H32A	0.9500	O1S—C1S	1.435 (3)
C33A—C34A	1.387 (4)	O1S—H1S	0.8783
C33A—H33A	0.9500	C1S—C2S	1.502 (4)
C34A—H34A	0.9500	C1S—H1SA	0.9900
Eu1B—O11B	2.3697 (15)	C1S—H1SB	0.9900
Eu1B—O12B	2.3724 (15)	O2S—C3S	1.362 (13)
Eu1B—O10B	2.4338 (16)	O2S—C3'S	1.529 (14)
Eu1B—O8B	2.5027 (16)	O2S—C3RS	1.545 (13)
Eu1B—O2B	2.5106 (17)	O2S—H2S	0.8249
Eu1B—O4B	2.5353 (16)	C2S—H2SA	0.9800
Eu1B—O1B	2.5449 (16)	C2S—H2SB	0.9800
Eu1B—O5B	2.5755 (17)	C2S—H2SC	0.9800
Eu1B—N4B	2.6716 (19)	C3S—C4S	1.477 (16)
Eu1B—O7B	2.6839 (16)	C3S—H3SA	0.9900
Eu1B—N1B	2.9494 (19)	C3S—H3SB	0.9900
Eu1B—N2B	2.971 (2)	C4S—H4SA	0.9800
P1B—O11B	1.4947 (16)	C4S—H4SB	0.9800
P1B—N5B	1.657 (2)	C4S—H4SC	0.9800
P1B—C11B	1.791 (2)	C4'S—C3'S	1.519 (18)
P1B—C17B	1.795 (2)	C4'S—H4'A	0.9800
P2B—O12B	1.4906 (16)	C4'S—H4'B	0.9800
P2B—N7B	1.652 (2)	C4'S—H4'C	0.9800
P2B—C29B	1.787 (2)	C3'S—H3'A	0.9900
P2B—C23B	1.797 (2)	C3'S—H3'B	0.9900
O1B—N1B	1.272 (3)	C4RS—C3RS	1.42 (2)
O2B—N1B	1.274 (3)	C4RS—H4RA	0.9800
O3B—N1B	1.223 (2)	C4RS—H4RB	0.9800
O4B—N2B	1.259 (3)	C4RS—H4RC	0.9800
O5B—N2B	1.274 (3)	C3RS—H3RA	0.9900
O6B—N2B	1.230 (3)	C3RS—H3RB	0.9900
O7B—N3B	1.254 (2)
O11A—Eu1A—O12A	141.18 (5)	O4B—Eu1B—O7B	64.79 (5)
O11A—Eu1A—O10A	81.84 (6)	O1B—Eu1B—O7B	158.77 (5)
O12A—Eu1A—O10A	71.96 (5)	O5B—Eu1B—O7B	101.28 (5)
O11A—Eu1A—O2A	76.48 (6)	N4B—Eu1B—O7B	124.38 (5)
O12A—Eu1A—O2A	121.12 (6)	O11B—Eu1B—N1B	96.30 (5)
O10A—Eu1A—O2A	156.43 (6)	O12B—Eu1B—N1B	94.65 (6)
O11A—Eu1A—O8A	72.67 (5)	O10B—Eu1B—N1B	153.59 (5)
O12A—Eu1A—O8A	145.02 (5)	O8B—Eu1B—N1B	85.75 (5)
O10A—Eu1A—O8A	116.88 (5)	O2B—Eu1B—N1B	25.40 (5)
O2A—Eu1A—O8A	65.13 (5)	O4B—Eu1B—N1B	116.17 (5)
O11A—Eu1A—O5A	130.63 (6)	O1B—Eu1B—N1B	25.43 (5)
O12A—Eu1A—O5A	75.88 (6)	O5B—Eu1B—N1B	66.29 (5)
O10A—Eu1A—O5A	85.07 (6)	N4B—Eu1B—N1B	81.74 (5)
O2A—Eu1A—O5A	116.19 (6)	O7B—Eu1B—N1B	134.30 (5)
O8A—Eu1A—O5A	71.60 (5)	O11B—Eu1B—N2B	145.42 (5)
O11A—Eu1A—O1A	110.96 (6)	O12B—Eu1B—N2B	70.41 (5)
O12A—Eu1A—O1A	70.88 (6)	O10B—Eu1B—N2B	104.44 (6)
O10A—Eu1A—O1A	132.55 (6)	O8B—Eu1B—N2B	74.76 (5)
O2A—Eu1A—O1A	50.88 (6)	O2B—Eu1B—N2B	98.05 (6)
O8A—Eu1A—O1A	110.51 (5)	O4B—Eu1B—N2B	24.86 (5)
O5A—Eu1A—O1A	112.81 (6)	O1B—Eu1B—N2B	89.52 (6)
O11A—Eu1A—O4A	140.93 (6)	O5B—Eu1B—N2B	25.29 (5)
O12A—Eu1A—O4A	76.82 (6)	N4B—Eu1B—N2B	145.39 (6)
O10A—Eu1A—O4A	130.58 (6)	O7B—Eu1B—N2B	83.99 (5)
O2A—Eu1A—O4A	72.99 (6)	N1B—Eu1B—N2B	91.58 (6)
O8A—Eu1A—O4A	72.69 (6)	O11B—P1B—N5B	112.58 (10)
O5A—Eu1A—O4A	50.25 (6)	O11B—P1B—C11B	112.54 (10)
O1A—Eu1A—O4A	66.04 (6)	N5B—P1B—C11B	102.81 (10)
O11A—Eu1A—N4A	69.64 (6)	O11B—P1B—C17B	109.66 (10)
O12A—Eu1A—N4A	75.67 (6)	N5B—P1B—C17B	106.79 (10)
O10A—Eu1A—N4A	73.54 (6)	C11B—P1B—C17B	112.20 (10)
O2A—Eu1A—N4A	90.14 (6)	O12B—P2B—N7B	115.74 (10)
O8A—Eu1A—N4A	138.80 (6)	O12B—P2B—C29B	112.29 (10)
O5A—Eu1A—N4A	148.52 (6)	N7B—P2B—C29B	100.56 (11)
O1A—Eu1A—N4A	69.52 (6)	O12B—P2B—C23B	111.16 (10)
O4A—Eu1A—N4A	133.23 (6)	N7B—P2B—C23B	106.22 (11)
O11A—Eu1A—O7A	66.50 (5)	C29B—P2B—C23B	110.25 (11)
O12A—Eu1A—O7A	124.74 (5)	N1B—O1B—Eu1B	95.36 (12)
O10A—Eu1A—O7A	67.95 (5)	N1B—O2B—Eu1B	96.92 (13)
O2A—Eu1A—O7A	110.55 (5)	N2B—O4B—Eu1B	97.32 (13)
O8A—Eu1A—O7A	48.97 (5)	N2B—O5B—Eu1B	94.99 (13)
O5A—Eu1A—O7A	64.44 (5)	N3B—O7B—Eu1B	91.32 (12)
O1A—Eu1A—O7A	159.47 (5)	N3B—O8B—Eu1B	99.44 (12)
O4A—Eu1A—O7A	102.41 (5)	C1B—O10B—Eu1B	141.05 (14)
N4A—Eu1A—O7A	124.34 (5)	C1B—O10B—H1OB	103.9
O11A—Eu1A—N1A	95.76 (6)	Eu1B—O10B—H1OB	112.2
O12A—Eu1A—N1A	95.64 (6)	P1B—O11B—Eu1B	137.77 (9)
O10A—Eu1A—N1A	153.89 (6)	P2B—O12B—Eu1B	170.49 (10)
O2A—Eu1A—N1A	25.54 (6)	C5B—O13B—N4B	108.27 (17)
O8A—Eu1A—N1A	86.64 (5)	C9B—O14B—N6B	108.12 (18)
O5A—Eu1A—N1A	114.79 (6)	O3B—N1B—O1B	122.0 (2)
O1A—Eu1A—N1A	25.58 (6)	O3B—N1B—O2B	122.0 (2)
O4A—Eu1A—N1A	64.73 (6)	O1B—N1B—O2B	116.01 (18)
N4A—Eu1A—N1A	81.23 (6)	O3B—N1B—Eu1B	170.39 (15)
O7A—Eu1A—N1A	134.80 (5)	O1B—N1B—Eu1B	59.21 (10)
O11A—Eu1A—N2A	142.72 (6)	O2B—N1B—Eu1B	57.67 (11)
O12A—Eu1A—N2A	74.12 (6)	O6B—N2B—O4B	122.1 (2)
O10A—Eu1A—N2A	107.62 (6)	O6B—N2B—O5B	120.9 (2)
O2A—Eu1A—N2A	95.31 (6)	O4B—N2B—O5B	116.93 (19)
O8A—Eu1A—N2A	70.97 (6)	O6B—N2B—Eu1B	172.43 (17)
O5A—Eu1A—N2A	24.89 (6)	O4B—N2B—Eu1B	57.82 (11)
O1A—Eu1A—N2A	89.38 (6)	O5B—N2B—Eu1B	59.72 (11)
O4A—Eu1A—N2A	25.38 (6)	O9B—N3B—O7B	121.79 (19)
N4A—Eu1A—N2A	147.51 (6)	O9B—N3B—O8B	120.51 (19)
O7A—Eu1A—N2A	83.43 (6)	O7B—N3B—O8B	117.70 (18)
N1A—Eu1A—N2A	90.07 (6)	O9B—N3B—Eu1B	165.24 (16)
O11A—P1A—N5A	112.30 (10)	O7B—N3B—Eu1B	63.87 (11)
O11A—P1A—C17A	112.52 (10)	O8B—N3B—Eu1B	55.70 (10)
N5A—P1A—C17A	102.32 (10)	C3B—N4B—O13B	105.14 (17)
O11A—P1A—C11A	109.60 (10)	C3B—N4B—Eu1B	131.15 (14)
N5A—P1A—C11A	106.70 (11)	O13B—N4B—Eu1B	121.61 (12)
C17A—P1A—C11A	113.12 (11)	C3B—N5B—P1B	119.55 (16)
O12A—P2A—N7A	115.67 (10)	C3B—N5B—H5B	118 (2)
O12A—P2A—C23A	113.52 (10)	P1B—N5B—H5B	120 (2)
N7A—P2A—C23A	100.11 (10)	C7B—N6B—O14B	104.85 (18)
O12A—P2A—C29A	111.60 (10)	C7B—N7B—P2B	124.75 (17)
N7A—P2A—C29A	107.59 (11)	C7B—N7B—H7B	114 (2)
C23A—P2A—C29A	107.47 (11)	P2B—N7B—H7B	121 (2)
N1A—O1A—Eu1A	94.70 (12)	O10B—C1B—C2B	111.2 (2)
N1A—O2A—Eu1A	97.10 (13)	O10B—C1B—H1BA	109.4
N2A—O4A—Eu1A	94.76 (13)	C2B—C1B—H1BA	109.4
N2A—O5A—Eu1A	97.40 (13)	O10B—C1B—H1BB	109.4
N3A—O7A—Eu1A	92.04 (12)	C2B—C1B—H1BB	109.4
N3A—O8A—Eu1A	99.78 (12)	H1BA—C1B—H1BB	108.0
P1A—O11A—Eu1A	137.82 (10)	C1B—C2B—H2BA	109.5
P2A—O12A—Eu1A	170.64 (10)	C1B—C2B—H2BB	109.5
C5A—O13A—N4A	108.42 (17)	H2BA—C2B—H2BB	109.5
C9A—O14A—N6A	107.98 (18)	C1B—C2B—H2BC	109.5
O3A—N1A—O1A	122.3 (2)	H2BA—C2B—H2BC	109.5
O3A—N1A—O2A	121.5 (2)	H2BB—C2B—H2BC	109.5
O1A—N1A—O2A	116.27 (18)	N4B—C3B—N5B	120.0 (2)
O3A—N1A—Eu1A	170.83 (16)	N4B—C3B—C4B	112.0 (2)
O1A—N1A—Eu1A	59.72 (11)	N5B—C3B—C4B	128.0 (2)
O2A—N1A—Eu1A	57.35 (11)	C5B—C4B—C3B	103.9 (2)
O6A—N2A—O5A	121.4 (2)	C5B—C4B—H4BA	128.0
O6A—N2A—O4A	121.1 (2)	C3B—C4B—H4BA	128.0
O5A—N2A—O4A	117.48 (19)	C4B—C5B—O13B	110.6 (2)
O6A—N2A—Eu1A	176.62 (18)	C4B—C5B—C6B	133.4 (2)
O5A—N2A—Eu1A	57.71 (11)	O13B—C5B—C6B	115.9 (2)
O4A—N2A—Eu1A	59.85 (11)	C5B—C6B—H6BA	109.5
O9A—N3A—O7A	121.84 (19)	C5B—C6B—H6BB	109.5
O9A—N3A—O8A	120.14 (18)	H6BA—C6B—H6BB	109.5
O7A—N3A—O8A	118.02 (18)	C5B—C6B—H6BC	109.5
O9A—N3A—Eu1A	168.84 (15)	H6BA—C6B—H6BC	109.5
O7A—N3A—Eu1A	63.41 (11)	H6BB—C6B—H6BC	109.5
O8A—N3A—Eu1A	55.54 (10)	N6B—C7B—N7B	120.6 (2)
C3A—N4A—O13A	105.04 (17)	N6B—C7B—C8B	112.7 (2)
C3A—N4A—Eu1A	132.72 (15)	N7B—C7B—C8B	126.7 (2)
O13A—N4A—Eu1A	119.32 (12)	C9B—C8B—C7B	103.7 (2)
C3A—N5A—P1A	120.00 (16)	C9B—C8B—H8BA	128.1
C3A—N5A—H5A	118 (2)	C7B—C8B—H8BA	128.1
P1A—N5A—H5A	119 (2)	C8B—C9B—O14B	110.6 (2)
C7A—N6A—O14A	105.29 (18)	C8B—C9B—C10B	134.0 (3)
C7A—N7A—P2A	125.80 (16)	O14B—C9B—C10B	115.4 (2)
C7A—N7A—H7A	117.0	C9B—C10B—H10D	109.5
P2A—N7A—H7A	117.1	C9B—C10B—H10E	109.5
N4A—C3A—N5A	119.8 (2)	H10D—C10B—H10E	109.5
N4A—C3A—C4A	112.1 (2)	C9B—C10B—H10F	109.5
N5A—C3A—C4A	128.1 (2)	H10D—C10B—H10F	109.5
C5A—C4A—C3A	104.1 (2)	H10E—C10B—H10F	109.5
C5A—C4A—H4AA	128.0	C12B—C11B—C16B	119.9 (2)
C3A—C4A—H4AA	128.0	C12B—C11B—P1B	122.55 (18)
C4A—C5A—O13A	110.4 (2)	C16B—C11B—P1B	117.43 (17)
C4A—C5A—C6A	133.8 (2)	C13B—C12B—C11B	119.8 (2)
O13A—C5A—C6A	115.8 (2)	C13B—C12B—H12B	120.1
C5A—C6A—H6AA	109.5	C11B—C12B—H12B	120.1
C5A—C6A—H6AB	109.5	C12B—C13B—C14B	119.9 (2)
H6AA—C6A—H6AB	109.5	C12B—C13B—H13B	120.0
C5A—C6A—H6AC	109.5	C14B—C13B—H13B	120.0
H6AA—C6A—H6AC	109.5	C15B—C14B—C13B	120.6 (2)
H6AB—C6A—H6AC	109.5	C15B—C14B—H14B	119.7
N6A—C7A—N7A	121.0 (2)	C13B—C14B—H14B	119.7
N6A—C7A—C8A	112.3 (2)	C14B—C15B—C16B	119.9 (2)
N7A—C7A—C8A	126.8 (2)	C14B—C15B—H15B	120.1
C9A—C8A—C7A	104.0 (2)	C16B—C15B—H15B	120.1
C9A—C8A—H8AA	128.0	C15B—C16B—C11B	119.9 (2)
C7A—C8A—H8AA	128.0	C15B—C16B—H16B	120.1
C8A—C9A—O14A	110.5 (2)	C11B—C16B—H16B	120.1
C8A—C9A—C10A	134.2 (3)	C22B—C17B—C18B	119.8 (2)
O14A—C9A—C10A	115.2 (2)	C22B—C17B—P1B	120.88 (17)
C9A—C10A—H10A	109.5	C18B—C17B—P1B	119.33 (18)
C9A—C10A—H10B	109.5	C19B—C18B—C17B	119.9 (2)
H10A—C10A—H10B	109.5	C19B—C18B—H18B	120.1
C9A—C10A—H10C	109.5	C17B—C18B—H18B	120.1
H10A—C10A—H10C	109.5	C20B—C19B—C18B	120.1 (2)
H10B—C10A—H10C	109.5	C20B—C19B—H19B	120.0
C12A—C11A—C16A	119.9 (2)	C18B—C19B—H19B	120.0
C12A—C11A—P1A	119.04 (18)	C19B—C20B—C21B	120.1 (2)
C16A—C11A—P1A	121.04 (18)	C19B—C20B—H20B	120.0
C13A—C12A—C11A	119.6 (2)	C21B—C20B—H20B	120.0
C13A—C12A—H12A	120.2	C22B—C21B—C20B	120.3 (2)
C11A—C12A—H12A	120.2	C22B—C21B—H21B	119.9
C14A—C13A—C12A	120.3 (2)	C20B—C21B—H21B	119.9
C14A—C13A—H13A	119.9	C21B—C22B—C17B	119.9 (2)
C12A—C13A—H13A	119.9	C21B—C22B—H22B	120.0
C13A—C14A—C15A	120.2 (2)	C17B—C22B—H22B	120.0
C13A—C14A—H14A	119.9	C24B—C23B—C28B	119.5 (2)
C15A—C14A—H14A	119.9	C24B—C23B—P2B	119.29 (19)
C14A—C15A—C16A	120.3 (2)	C28B—C23B—P2B	121.24 (19)
C14A—C15A—H15A	119.9	C23B—C24B—C25B	119.8 (3)
C16A—C15A—H15A	119.9	C23B—C24B—H24B	120.1
C15A—C16A—C11A	119.7 (2)	C25B—C24B—H24B	120.1
C15A—C16A—H16A	120.1	C26B—C25B—C24B	120.1 (3)
C11A—C16A—H16A	120.1	C26B—C25B—H25B	120.0
C18A—C17A—C22A	120.1 (2)	C24B—C25B—H25B	120.0
C18A—C17A—P1A	122.33 (18)	C27B—C26B—C25B	120.2 (3)
C22A—C17A—P1A	117.36 (18)	C27B—C26B—H26B	119.9
C17A—C18A—C19A	119.6 (2)	C25B—C26B—H26B	119.9
C17A—C18A—H18A	120.2	C26B—C27B—C28B	120.5 (3)
C19A—C18A—H18A	120.2	C26B—C27B—H27B	119.8
C20A—C19A—C18A	120.0 (2)	C28B—C27B—H27B	119.8
C20A—C19A—H19A	120.0	C27B—C28B—C23B	119.9 (3)
C18A—C19A—H19A	120.0	C27B—C28B—H28B	120.0
C21A—C20A—C19A	120.3 (2)	C23B—C28B—H28B	120.0
C21A—C20A—H20A	119.9	C30B—C29B—C34B	120.2 (2)
C19A—C20A—H20A	119.9	C30B—C29B—P2B	120.46 (18)
C22A—C21A—C20A	120.3 (2)	C34B—C29B—P2B	119.05 (17)
C22A—C21A—H21A	119.9	C31B—C30B—C29B	119.5 (2)
C20A—C21A—H21A	119.9	C31B—C30B—H30B	120.3
C21A—C22A—C17A	119.8 (2)	C29B—C30B—H30B	120.3
C21A—C22A—H22A	120.1	C32B—C31B—C30B	120.1 (2)
C17A—C22A—H22A	120.1	C32B—C31B—H31B	119.9
C28A—C23A—C24A	120.4 (2)	C30B—C31B—H31B	119.9
C28A—C23A—P2A	120.37 (18)	C31B—C32B—C33B	120.5 (2)
C24A—C23A—P2A	119.09 (18)	C31B—C32B—H32B	119.8
C25A—C24A—C23A	119.7 (2)	C33B—C32B—H32B	119.8
C25A—C24A—H24A	120.1	C32B—C33B—C34B	120.0 (2)
C23A—C24A—H24A	120.1	C32B—C33B—H33B	120.0
C24A—C25A—C26A	120.0 (2)	C34B—C33B—H33B	120.0
C24A—C25A—H25A	120.0	C33B—C34B—C29B	119.7 (2)
C26A—C25A—H25A	120.0	C33B—C34B—H34B	120.2
C25A—C26A—C27A	120.2 (2)	C29B—C34B—H34B	120.2
C25A—C26A—H26A	119.9	C1'A—O10A—C1A	32.0 (3)
C27A—C26A—H26A	119.9	C1'A—O10A—Eu1A	141.7 (3)
C26A—C27A—C28A	120.6 (2)	C1A—O10A—Eu1A	137.6 (2)
C26A—C27A—H27A	119.7	C1'A—O10A—H1OA	99.0
C28A—C27A—H27A	119.7	C1A—O10A—H1OA	108.9
C27A—C28A—C23A	119.1 (2)	Eu1A—O10A—H1OA	112.5
C27A—C28A—H28A	120.5	C2A—C1A—O10A	113.4 (4)
C23A—C28A—H28A	120.5	C2A—C1A—H1AA	108.9
C30A—C29A—C34A	119.1 (2)	O10A—C1A—H1AA	108.9
C30A—C29A—P2A	122.73 (19)	C2A—C1A—H1AB	108.9
C34A—C29A—P2A	117.97 (19)	O10A—C1A—H1AB	108.9
C29A—C30A—C31A	120.0 (2)	H1AA—C1A—H1AB	107.7
C29A—C30A—H30A	120.0	O10A—C1'A—C2'A	111.4 (6)
C31A—C30A—H30A	120.0	O10A—C1'A—H1'A	109.3
C32A—C31A—C30A	120.7 (2)	C2'A—C1'A—H1'A	109.3
C32A—C31A—H31A	119.6	O10A—C1'A—H1'B	109.3
C30A—C31A—H31A	119.6	C2'A—C1'A—H1'B	109.3
C31A—C32A—C33A	119.6 (3)	H1'A—C1'A—H1'B	108.0
C31A—C32A—H32A	120.2	C1'A—C2'A—H2'A	109.5
C33A—C32A—H32A	120.2	C1'A—C2'A—H2'B	109.5
C32A—C33A—C34A	120.2 (3)	H2'A—C2'A—H2'B	109.5
C32A—C33A—H33A	119.9	C1'A—C2'A—H2'C	109.5
C34A—C33A—H33A	119.9	H2'A—C2'A—H2'C	109.5
C33A—C34A—C29A	120.3 (3)	H2'B—C2'A—H2'C	109.5
C33A—C34A—H34A	119.9	C1S—O1S—H1S	113.4
C29A—C34A—H34A	119.9	O1S—C1S—C2S	108.9 (2)
O11B—Eu1B—O12B	141.72 (5)	O1S—C1S—H1SA	109.9
O11B—Eu1B—O10B	82.45 (5)	C2S—C1S—H1SA	109.9
O12B—Eu1B—O10B	71.91 (5)	O1S—C1S—H1SB	109.9
O11B—Eu1B—O8B	72.34 (5)	C2S—C1S—H1SB	109.9
O12B—Eu1B—O8B	145.17 (5)	H1SA—C1S—H1SB	108.3
O10B—Eu1B—O8B	118.42 (5)	C3S—O2S—C3'S	20.6 (5)
O11B—Eu1B—O2B	77.04 (6)	C3S—O2S—C3RS	25.8 (7)
O12B—Eu1B—O2B	119.99 (5)	C3'S—O2S—C3RS	37.0 (7)
O10B—Eu1B—O2B	157.25 (6)	C3S—O2S—H2S	120.7
O8B—Eu1B—O2B	64.30 (5)	C3'S—O2S—H2S	102.4
O11B—Eu1B—O4B	131.30 (5)	C3RS—O2S—H2S	112.0
O12B—Eu1B—O4B	73.76 (5)	C1S—C2S—H2SA	109.5
O10B—Eu1B—O4B	82.58 (5)	C1S—C2S—H2SB	109.5
O8B—Eu1B—O4B	74.90 (5)	H2SA—C2S—H2SB	109.5
O2B—Eu1B—O4B	118.53 (6)	C1S—C2S—H2SC	109.5
O11B—Eu1B—O1B	111.27 (5)	H2SA—C2S—H2SC	109.5
O12B—Eu1B—O1B	70.12 (5)	H2SB—C2S—H2SC	109.5
O10B—Eu1B—O1B	131.91 (5)	O2S—C3S—C4S	112.4 (10)
O8B—Eu1B—O1B	109.63 (5)	O2S—C3S—H3SA	109.1
O2B—Eu1B—O1B	50.58 (5)	C4S—C3S—H3SA	109.1
O4B—Eu1B—O1B	113.17 (5)	O2S—C3S—H3SB	109.1
O11B—Eu1B—O5B	142.71 (5)	C4S—C3S—H3SB	109.1
O12B—Eu1B—O5B	74.73 (5)	H3SA—C3S—H3SB	107.8
O10B—Eu1B—O5B	127.91 (6)	C3'S—C4'S—H4'A	109.5
O8B—Eu1B—O5B	73.63 (5)	C3'S—C4'S—H4'B	109.5
O2B—Eu1B—O5B	74.83 (6)	H4'A—C4'S—H4'B	109.5
O4B—Eu1B—O5B	49.97 (5)	C3'S—C4'S—H4'C	109.5
O1B—Eu1B—O5B	67.09 (5)	H4'A—C4'S—H4'C	109.5
O11B—Eu1B—N4B	69.18 (5)	H4'B—C4'S—H4'C	109.5
O12B—Eu1B—N4B	76.31 (6)	C4'S—C3'S—O2S	108.6 (9)
O10B—Eu1B—N4B	73.12 (6)	C4'S—C3'S—H3'A	110.0
O8B—Eu1B—N4B	137.73 (6)	O2S—C3'S—H3'A	110.0
O2B—Eu1B—N4B	90.29 (6)	C4'S—C3'S—H3'B	110.0
O4B—Eu1B—N4B	146.04 (6)	O2S—C3'S—H3'B	110.0
O1B—Eu1B—N4B	70.11 (5)	H3'A—C3'S—H3'B	108.3
O5B—Eu1B—N4B	134.25 (5)	C4RS—C3RS—O2S	113.0 (12)
O11B—Eu1B—O7B	66.55 (5)	C4RS—C3RS—H3RA	109.0
O12B—Eu1B—O7B	125.61 (5)	O2S—C3RS—H3RA	109.0
O10B—Eu1B—O7B	69.32 (5)	C4RS—C3RS—H3RB	109.0
O8B—Eu1B—O7B	49.16 (5)	O2S—C3RS—H3RB	109.0
O2B—Eu1B—O7B	110.32 (5)	H3RA—C3RS—H3RB	107.8
O11A—Eu1A—O1A—N1A	−56.53 (14)	O10B—Eu1B—O4B—N2B	−151.60 (13)
O12A—Eu1A—O1A—N1A	164.86 (14)	O8B—Eu1B—O4B—N2B	86.25 (13)
O10A—Eu1A—O1A—N1A	−154.89 (12)	O2B—Eu1B—O4B—N2B	37.39 (14)
O2A—Eu1A—O1A—N1A	−5.90 (12)	O1B—Eu1B—O4B—N2B	−19.00 (14)
O8A—Eu1A—O1A—N1A	22.09 (14)	O5B—Eu1B—O4B—N2B	5.14 (12)
O5A—Eu1A—O1A—N1A	100.07 (13)	N4B—Eu1B—O4B—N2B	−107.46 (15)
O4A—Eu1A—O1A—N1A	81.17 (13)	O7B—Eu1B—O4B—N2B	137.81 (14)
N4A—Eu1A—O1A—N1A	−113.78 (14)	N1B—Eu1B—O4B—N2B	8.85 (14)
O7A—Eu1A—O1A—N1A	22.3 (2)	O11B—Eu1B—O5B—N2B	−113.69 (14)
N2A—Eu1A—O1A—N1A	91.46 (13)	O12B—Eu1B—O5B—N2B	76.36 (13)
O11A—Eu1A—O2A—N1A	137.96 (14)	O10B—Eu1B—O5B—N2B	24.71 (15)
O12A—Eu1A—O2A—N1A	−4.31 (15)	O8B—Eu1B—O5B—N2B	−88.86 (13)
O10A—Eu1A—O2A—N1A	114.32 (17)	O2B—Eu1B—O5B—N2B	−155.99 (14)
O8A—Eu1A—O2A—N1A	−145.12 (14)	O4B—Eu1B—O5B—N2B	−5.06 (12)
O5A—Eu1A—O2A—N1A	−93.13 (13)	O1B—Eu1B—O5B—N2B	150.86 (14)
O1A—Eu1A—O2A—N1A	5.90 (12)	N4B—Eu1B—O5B—N2B	128.89 (13)
O4A—Eu1A—O2A—N1A	−66.72 (13)	O7B—Eu1B—O5B—N2B	−47.77 (13)
N4A—Eu1A—O2A—N1A	68.97 (13)	N1B—Eu1B—O5B—N2B	178.58 (14)
O7A—Eu1A—O2A—N1A	−163.92 (12)	O11B—Eu1B—O7B—N3B	77.65 (12)
N2A—Eu1A—O2A—N1A	−78.95 (13)	O12B—Eu1B—O7B—N3B	−144.47 (12)
O11A—Eu1A—O4A—N2A	−110.41 (14)	O10B—Eu1B—O7B—N3B	168.25 (13)
O12A—Eu1A—O4A—N2A	80.68 (14)	O8B—Eu1B—O7B—N3B	−8.79 (11)
O10A—Eu1A—O4A—N2A	28.94 (16)	O2B—Eu1B—O7B—N3B	12.56 (13)
O2A—Eu1A—O4A—N2A	−150.51 (14)	O4B—Eu1B—O7B—N3B	−100.31 (13)
O8A—Eu1A—O4A—N2A	−81.94 (14)	O1B—Eu1B—O7B—N3B	−10.9 (2)
O5A—Eu1A—O4A—N2A	−1.79 (12)	O5B—Eu1B—O7B—N3B	−65.27 (13)
O1A—Eu1A—O4A—N2A	155.36 (15)	N4B—Eu1B—O7B—N3B	117.63 (12)
N4A—Eu1A—O4A—N2A	135.99 (13)	N1B—Eu1B—O7B—N3B	2.50 (15)
O7A—Eu1A—O4A—N2A	−42.54 (14)	N2B—Eu1B—O7B—N3B	−83.82 (12)
N1A—Eu1A—O4A—N2A	−176.49 (15)	O11B—Eu1B—O8B—N3B	−65.15 (13)
O11A—Eu1A—O5A—N2A	129.92 (13)	O12B—Eu1B—O8B—N3B	104.81 (14)
O12A—Eu1A—O5A—N2A	−82.64 (14)	O10B—Eu1B—O8B—N3B	5.63 (14)
O10A—Eu1A—O5A—N2A	−155.26 (14)	O2B—Eu1B—O8B—N3B	−148.96 (14)
O2A—Eu1A—O5A—N2A	35.41 (15)	O4B—Eu1B—O8B—N3B	78.29 (13)
O8A—Eu1A—O5A—N2A	84.29 (14)	O1B—Eu1B—O8B—N3B	−172.05 (12)
O1A—Eu1A—O5A—N2A	−20.82 (15)	O5B—Eu1B—O8B—N3B	130.33 (13)
O4A—Eu1A—O5A—N2A	1.82 (12)	N4B—Eu1B—O8B—N3B	−90.36 (14)
N4A—Eu1A—O5A—N2A	−108.54 (15)	O7B—Eu1B—O8B—N3B	8.77 (11)
O7A—Eu1A—O5A—N2A	136.85 (14)	N1B—Eu1B—O8B—N3B	−163.15 (13)
N1A—Eu1A—O5A—N2A	7.10 (15)	N2B—Eu1B—O8B—N3B	104.05 (13)
O11A—Eu1A—O7A—N3A	80.76 (12)	O11B—Eu1B—O10B—C1B	83.4 (2)
O12A—Eu1A—O7A—N3A	−142.15 (12)	O12B—Eu1B—O10B—C1B	−125.4 (2)
O10A—Eu1A—O7A—N3A	171.29 (14)	O8B—Eu1B—O10B—C1B	18.2 (2)
O2A—Eu1A—O7A—N3A	16.56 (13)	O2B—Eu1B—O10B—C1B	109.1 (2)
O8A—Eu1A—O7A—N3A	−6.24 (11)	O4B—Eu1B—O10B—C1B	−50.2 (2)
O5A—Eu1A—O7A—N3A	−93.50 (13)	O1B—Eu1B—O10B—C1B	−164.7 (2)
O1A—Eu1A—O7A—N3A	−6.5 (2)	O5B—Eu1B—O10B—C1B	−72.7 (2)
O4A—Eu1A—O7A—N3A	−59.70 (13)	N4B—Eu1B—O10B—C1B	153.8 (2)
N4A—Eu1A—O7A—N3A	121.60 (12)	O7B—Eu1B—O10B—C1B	15.6 (2)
N1A—Eu1A—O7A—N3A	6.87 (15)	N1B—Eu1B—O10B—C1B	172.3 (2)
N2A—Eu1A—O7A—N3A	−76.66 (12)	N2B—Eu1B—O10B—C1B	−62.1 (2)
O11A—Eu1A—O8A—N3A	−67.41 (12)	N5B—P1B—O11B—Eu1B	−9.39 (17)
O12A—Eu1A—O8A—N3A	100.45 (14)	C11B—P1B—O11B—Eu1B	−125.03 (14)
O10A—Eu1A—O8A—N3A	3.63 (14)	C17B—P1B—O11B—Eu1B	109.34 (14)
O2A—Eu1A—O8A—N3A	−150.22 (14)	O12B—Eu1B—O11B—P1B	4.12 (19)
O5A—Eu1A—O8A—N3A	77.96 (13)	O10B—Eu1B—O11B—P1B	51.78 (14)
O1A—Eu1A—O8A—N3A	−173.88 (12)	O8B—Eu1B—O11B—P1B	174.87 (15)
O4A—Eu1A—O8A—N3A	130.93 (13)	O2B—Eu1B—O11B—P1B	−118.31 (15)
N4A—Eu1A—O8A—N3A	−91.91 (14)	O4B—Eu1B—O11B—P1B	124.93 (13)
O7A—Eu1A—O8A—N3A	6.21 (11)	O1B—Eu1B—O11B—P1B	−80.39 (15)
N1A—Eu1A—O8A—N3A	−164.52 (13)	O5B—Eu1B—O11B—P1B	−160.12 (11)
N2A—Eu1A—O8A—N3A	104.25 (13)	N4B—Eu1B—O11B—P1B	−22.97 (13)
N5A—P1A—O11A—Eu1A	−16.88 (18)	O7B—Eu1B—O11B—P1B	122.46 (15)
C17A—P1A—O11A—Eu1A	−131.69 (14)	N1B—Eu1B—O11B—P1B	−101.64 (14)
C11A—P1A—O11A—Eu1A	101.52 (15)	N2B—Eu1B—O11B—P1B	156.31 (12)
O12A—Eu1A—O11A—P1A	12.0 (2)	N7B—P2B—O12B—Eu1B	−50.1 (7)
O10A—Eu1A—O11A—P1A	59.37 (15)	C29B—P2B—O12B—Eu1B	−164.7 (6)
O2A—Eu1A—O11A—P1A	−111.31 (15)	C23B—P2B—O12B—Eu1B	71.2 (7)
O8A—Eu1A—O11A—P1A	−179.09 (16)	O11B—Eu1B—O12B—P2B	28.4 (7)
O5A—Eu1A—O11A—P1A	135.63 (13)	O10B—Eu1B—O12B—P2B	−22.1 (6)
O1A—Eu1A—O11A—P1A	−73.22 (15)	O8B—Eu1B—O12B—P2B	−136.1 (6)
O4A—Eu1A—O11A—P1A	−150.62 (12)	O2B—Eu1B—O12B—P2B	136.6 (6)
N4A—Eu1A—O11A—P1A	−16.03 (14)	O4B—Eu1B—O12B—P2B	−109.4 (6)
O7A—Eu1A—O11A—P1A	128.81 (16)	O1B—Eu1B—O12B—P2B	127.8 (7)
N1A—Eu1A—O11A—P1A	−94.44 (15)	O5B—Eu1B—O12B—P2B	−161.5 (7)
N2A—Eu1A—O11A—P1A	167.83 (12)	N4B—Eu1B—O12B—P2B	54.3 (6)
N7A—P2A—O12A—Eu1A	−79.1 (7)	O7B—Eu1B—O12B—P2B	−68.4 (7)
C23A—P2A—O12A—Eu1A	166.0 (6)	N1B—Eu1B—O12B—P2B	134.7 (6)
C29A—P2A—O12A—Eu1A	44.3 (7)	N2B—Eu1B—O12B—P2B	−135.3 (7)
O11A—Eu1A—O12A—P2A	60.9 (7)	Eu1B—O1B—N1B—O3B	−168.83 (18)
O10A—Eu1A—O12A—P2A	10.9 (6)	Eu1B—O1B—N1B—O2B	10.48 (19)
O2A—Eu1A—O12A—P2A	169.2 (6)	Eu1B—O2B—N1B—O3B	168.65 (18)
O8A—Eu1A—O12A—P2A	−100.5 (6)	Eu1B—O2B—N1B—O1B	−10.65 (19)
O5A—Eu1A—O12A—P2A	−78.5 (6)	O11B—Eu1B—N1B—O3B	−131.7 (10)
O1A—Eu1A—O12A—P2A	160.8 (7)	O12B—Eu1B—N1B—O3B	85.0 (10)
O4A—Eu1A—O12A—P2A	−130.3 (6)	O10B—Eu1B—N1B—O3B	142.6 (10)
N4A—Eu1A—O12A—P2A	87.9 (6)	O8B—Eu1B—N1B—O3B	−60.1 (10)
O7A—Eu1A—O12A—P2A	−34.2 (7)	O2B—Eu1B—N1B—O3B	−91.0 (10)
N1A—Eu1A—O12A—P2A	167.3 (6)	O4B—Eu1B—N1B—O3B	10.8 (10)
N2A—Eu1A—O12A—P2A	−104.2 (6)	O1B—Eu1B—N1B—O3B	100.1 (10)
Eu1A—O1A—N1A—O3A	−169.5 (2)	O5B—Eu1B—N1B—O3B	13.9 (10)
Eu1A—O1A—N1A—O2A	10.0 (2)	N4B—Eu1B—N1B—O3B	160.4 (10)
Eu1A—O2A—N1A—O3A	169.27 (19)	O7B—Eu1B—N1B—O3B	−68.6 (10)
Eu1A—O2A—N1A—O1A	−10.3 (2)	N2B—Eu1B—N1B—O3B	14.5 (10)
O11A—Eu1A—N1A—O3A	−126.4 (11)	O11B—Eu1B—N1B—O1B	128.16 (12)
O12A—Eu1A—N1A—O3A	90.8 (11)	O12B—Eu1B—N1B—O1B	−15.10 (13)
O10A—Eu1A—N1A—O3A	150.4 (11)	O10B—Eu1B—N1B—O1B	42.47 (19)
O2A—Eu1A—N1A—O3A	−85.5 (11)	O8B—Eu1B—N1B—O1B	−160.16 (13)
O8A—Eu1A—N1A—O3A	−54.2 (11)	O2B—Eu1B—N1B—O1B	168.8 (2)
O5A—Eu1A—N1A—O3A	13.8 (11)	O4B—Eu1B—N1B—O1B	−89.28 (13)
O1A—Eu1A—N1A—O3A	105.1 (11)	O5B—Eu1B—N1B—O1B	−86.18 (13)
O4A—Eu1A—N1A—O3A	18.2 (11)	N4B—Eu1B—N1B—O1B	60.32 (12)
N4A—Eu1A—N1A—O3A	165.3 (11)	O7B—Eu1B—N1B—O1B	−168.70 (11)
O7A—Eu1A—N1A—O3A	−64.1 (11)	N2B—Eu1B—N1B—O1B	−85.57 (12)
N2A—Eu1A—N1A—O3A	16.7 (11)	O11B—Eu1B—N1B—O2B	−40.69 (13)
O11A—Eu1A—N1A—O1A	128.47 (13)	O12B—Eu1B—N1B—O2B	176.05 (13)
O12A—Eu1A—N1A—O1A	−14.36 (13)	O10B—Eu1B—N1B—O2B	−126.38 (15)
O10A—Eu1A—N1A—O1A	45.3 (2)	O8B—Eu1B—N1B—O2B	30.99 (13)
O2A—Eu1A—N1A—O1A	169.3 (2)	O4B—Eu1B—N1B—O2B	101.87 (13)
O8A—Eu1A—N1A—O1A	−159.34 (13)	O1B—Eu1B—N1B—O2B	−168.8 (2)
O5A—Eu1A—N1A—O1A	−91.39 (13)	O5B—Eu1B—N1B—O2B	104.98 (14)
O4A—Eu1A—N1A—O1A	−86.91 (13)	N4B—Eu1B—N1B—O2B	−108.52 (13)
N4A—Eu1A—N1A—O1A	60.16 (13)	O7B—Eu1B—N1B—O2B	22.45 (16)
O7A—Eu1A—N1A—O1A	−169.21 (11)	N2B—Eu1B—N1B—O2B	105.58 (13)
N2A—Eu1A—N1A—O1A	−88.41 (13)	Eu1B—O4B—N2B—O6B	171.1 (2)
O11A—Eu1A—N1A—O2A	−40.87 (13)	Eu1B—O4B—N2B—O5B	−8.9 (2)
O12A—Eu1A—N1A—O2A	176.29 (13)	Eu1B—O5B—N2B—O6B	−171.2 (2)
O10A—Eu1A—N1A—O2A	−124.09 (15)	Eu1B—O5B—N2B—O4B	8.8 (2)
O8A—Eu1A—N1A—O2A	31.31 (13)	O11B—Eu1B—N2B—O6B	−160.7 (13)
O5A—Eu1A—N1A—O2A	99.26 (13)	O12B—Eu1B—N2B—O6B	1.4 (13)
O1A—Eu1A—N1A—O2A	−169.3 (2)	O10B—Eu1B—N2B—O6B	−63.0 (13)
O4A—Eu1A—N1A—O2A	103.75 (14)	O8B—Eu1B—N2B—O6B	−179 (100)
N4A—Eu1A—N1A—O2A	−109.19 (14)	O2B—Eu1B—N2B—O6B	120.5 (13)
O7A—Eu1A—N1A—O2A	21.45 (16)	O4B—Eu1B—N2B—O6B	−92.1 (14)
N2A—Eu1A—N1A—O2A	102.24 (13)	O1B—Eu1B—N2B—O6B	70.5 (13)
Eu1A—O5A—N2A—O6A	176.1 (2)	O5B—Eu1B—N2B—O6B	97.1 (13)
Eu1A—O5A—N2A—O4A	−3.2 (2)	N4B—Eu1B—N2B—O6B	18.1 (14)
Eu1A—O4A—N2A—O6A	−176.2 (2)	O7B—Eu1B—N2B—O6B	−129.8 (13)
Eu1A—O4A—N2A—O5A	3.1 (2)	N1B—Eu1B—N2B—O6B	95.8 (13)
O11A—Eu1A—N2A—O6A	−150 (3)	O11B—Eu1B—N2B—O4B	−68.58 (17)
O12A—Eu1A—N2A—O6A	14 (3)	O12B—Eu1B—N2B—O4B	93.56 (13)
O10A—Eu1A—N2A—O6A	−50 (3)	O10B—Eu1B—N2B—O4B	29.15 (14)
O2A—Eu1A—N2A—O6A	135 (3)	O8B—Eu1B—N2B—O4B	−86.90 (13)
O8A—Eu1A—N2A—O6A	−163 (3)	O2B—Eu1B—N2B—O4B	−147.40 (13)
O5A—Eu1A—N2A—O6A	−76 (3)	O1B—Eu1B—N2B—O4B	162.59 (13)
O1A—Eu1A—N2A—O6A	85 (3)	O5B—Eu1B—N2B—O4B	−170.8 (2)
O4A—Eu1A—N2A—O6A	107 (3)	N4B—Eu1B—N2B—O4B	110.25 (14)
N4A—Eu1A—N2A—O6A	36 (3)	O7B—Eu1B—N2B—O4B	−37.66 (13)
O7A—Eu1A—N2A—O6A	−115 (3)	N1B—Eu1B—N2B—O4B	−172.06 (13)
N1A—Eu1A—N2A—O6A	110 (3)	O11B—Eu1B—N2B—O5B	102.18 (15)
O11A—Eu1A—N2A—O5A	−73.93 (16)	O12B—Eu1B—N2B—O5B	−95.68 (13)
O12A—Eu1A—N2A—O5A	90.59 (14)	O10B—Eu1B—N2B—O5B	−160.09 (12)
O10A—Eu1A—N2A—O5A	25.95 (14)	O8B—Eu1B—N2B—O5B	83.86 (13)
O2A—Eu1A—N2A—O5A	−148.52 (13)	O2B—Eu1B—N2B—O5B	23.36 (13)
O8A—Eu1A—N2A—O5A	−87.14 (14)	O4B—Eu1B—N2B—O5B	170.8 (2)
O1A—Eu1A—N2A—O5A	160.87 (14)	O1B—Eu1B—N2B—O5B	−26.65 (13)
O4A—Eu1A—N2A—O5A	−176.7 (2)	N4B—Eu1B—N2B—O5B	−78.99 (16)
N4A—Eu1A—N2A—O5A	112.82 (15)	O7B—Eu1B—N2B—O5B	133.10 (13)
O7A—Eu1A—N2A—O5A	−38.39 (13)	N1B—Eu1B—N2B—O5B	−1.30 (13)
N1A—Eu1A—N2A—O5A	−173.56 (14)	Eu1B—O7B—N3B—O9B	−164.39 (19)
O11A—Eu1A—N2A—O4A	102.81 (15)	Eu1B—O7B—N3B—O8B	14.87 (19)
O12A—Eu1A—N2A—O4A	−92.67 (14)	Eu1B—O8B—N3B—O9B	163.07 (18)
O10A—Eu1A—N2A—O4A	−157.32 (13)	Eu1B—O8B—N3B—O7B	−16.2 (2)
O2A—Eu1A—N2A—O4A	28.21 (14)	O11B—Eu1B—N3B—O9B	25.4 (6)
O8A—Eu1A—N2A—O4A	89.60 (14)	O12B—Eu1B—N3B—O9B	169.1 (6)
O5A—Eu1A—N2A—O4A	176.7 (2)	O10B—Eu1B—N3B—O9B	105.2 (6)
O1A—Eu1A—N2A—O4A	−22.39 (14)	O8B—Eu1B—N3B—O9B	−79.8 (6)
N4A—Eu1A—N2A—O4A	−70.45 (18)	O2B—Eu1B—N3B—O9B	−52.0 (6)
O7A—Eu1A—N2A—O4A	138.35 (14)	O4B—Eu1B—N3B—O9B	−173.9 (6)
N1A—Eu1A—N2A—O4A	3.18 (14)	O1B—Eu1B—N3B—O9B	−69.3 (6)
Eu1A—O7A—N3A—O9A	−168.70 (19)	O5B—Eu1B—N3B—O9B	−126.8 (6)
Eu1A—O7A—N3A—O8A	10.57 (19)	N4B—Eu1B—N3B—O9B	34.7 (6)
Eu1A—O8A—N3A—O9A	167.81 (17)	O7B—Eu1B—N3B—O9B	116.2 (6)
Eu1A—O8A—N3A—O7A	−11.5 (2)	N1B—Eu1B—N3B—O9B	−61.9 (6)
O11A—Eu1A—N3A—O9A	32.7 (8)	N2B—Eu1B—N3B—O9B	−150.8 (6)
O12A—Eu1A—N3A—O9A	175.7 (7)	O11B—Eu1B—N3B—O7B	−90.71 (13)
O10A—Eu1A—N3A—O9A	112.6 (8)	O12B—Eu1B—N3B—O7B	52.98 (16)
O2A—Eu1A—N3A—O9A	−43.8 (8)	O10B—Eu1B—N3B—O7B	−11.00 (12)
O8A—Eu1A—N3A—O9A	−70.6 (8)	O8B—Eu1B—N3B—O7B	164.0 (2)
O5A—Eu1A—N3A—O9A	−163.6 (8)	O2B—Eu1B—N3B—O7B	−168.20 (13)
O1A—Eu1A—N3A—O9A	−62.5 (8)	O4B—Eu1B—N3B—O7B	69.90 (12)
O4A—Eu1A—N3A—O9A	−116.8 (8)	O1B—Eu1B—N3B—O7B	174.50 (11)
N4A—Eu1A—N3A—O9A	43.5 (8)	O5B—Eu1B—N3B—O7B	117.03 (12)
O7A—Eu1A—N3A—O9A	120.7 (8)	N4B—Eu1B—N3B—O7B	−81.41 (14)
N1A—Eu1A—N3A—O9A	−54.1 (8)	N1B—Eu1B—N3B—O7B	−178.10 (12)
N2A—Eu1A—N3A—O9A	−139.8 (8)	N2B—Eu1B—N3B—O7B	93.08 (12)
O11A—Eu1A—N3A—O7A	−87.99 (13)	O11B—Eu1B—N3B—O8B	105.25 (13)
O12A—Eu1A—N3A—O7A	54.97 (16)	O12B—Eu1B—N3B—O8B	−111.06 (14)
O10A—Eu1A—N3A—O7A	−8.08 (13)	O10B—Eu1B—N3B—O8B	−175.04 (13)
O2A—Eu1A—N3A—O7A	−164.49 (13)	O2B—Eu1B—N3B—O8B	27.76 (13)
O8A—Eu1A—N3A—O7A	168.7 (2)	O4B—Eu1B—N3B—O8B	−94.14 (13)
O5A—Eu1A—N3A—O7A	75.71 (12)	O1B—Eu1B—N3B—O8B	10.47 (16)
O1A—Eu1A—N3A—O7A	176.80 (11)	O5B—Eu1B—N3B—O8B	−47.01 (13)
O4A—Eu1A—N3A—O7A	122.51 (12)	N4B—Eu1B—N3B—O8B	114.55 (13)
N4A—Eu1A—N3A—O7A	−77.25 (14)	O7B—Eu1B—N3B—O8B	−164.0 (2)
N1A—Eu1A—N3A—O7A	−174.80 (12)	N1B—Eu1B—N3B—O8B	17.86 (14)
N2A—Eu1A—N3A—O7A	99.45 (13)	N2B—Eu1B—N3B—O8B	−70.95 (13)
O11A—Eu1A—N3A—O8A	103.33 (13)	C5B—O13B—N4B—C3B	1.3 (2)
O12A—Eu1A—N3A—O8A	−113.71 (13)	C5B—O13B—N4B—Eu1B	−163.92 (14)
O10A—Eu1A—N3A—O8A	−176.76 (13)	O11B—Eu1B—N4B—C3B	42.21 (19)
O2A—Eu1A—N3A—O8A	26.83 (13)	O12B—Eu1B—N4B—C3B	−120.9 (2)
O5A—Eu1A—N3A—O8A	−92.97 (13)	O10B—Eu1B—N4B—C3B	−45.98 (19)
O1A—Eu1A—N3A—O8A	8.12 (16)	O8B—Eu1B—N4B—C3B	67.9 (2)
O4A—Eu1A—N3A—O8A	−46.17 (13)	O2B—Eu1B—N4B—C3B	118.21 (19)
N4A—Eu1A—N3A—O8A	114.07 (13)	O4B—Eu1B—N4B—C3B	−92.2 (2)
O7A—Eu1A—N3A—O8A	−168.7 (2)	O1B—Eu1B—N4B—C3B	165.6 (2)
N1A—Eu1A—N3A—O8A	16.52 (14)	O5B—Eu1B—N4B—C3B	−172.91 (17)
N2A—Eu1A—N3A—O8A	−69.22 (13)	O7B—Eu1B—N4B—C3B	3.1 (2)
C5A—O13A—N4A—C3A	1.5 (2)	N1B—Eu1B—N4B—C3B	142.2 (2)
C5A—O13A—N4A—Eu1A	−161.54 (14)	N2B—Eu1B—N4B—C3B	−137.08 (18)
O11A—Eu1A—N4A—C3A	41.09 (19)	O11B—Eu1B—N4B—O13B	−156.89 (16)
O12A—Eu1A—N4A—C3A	−121.2 (2)	O12B—Eu1B—N4B—O13B	39.99 (14)
O10A—Eu1A—N4A—C3A	−46.2 (2)	O10B—Eu1B—N4B—O13B	114.92 (15)
O2A—Eu1A—N4A—C3A	116.6 (2)	O8B—Eu1B—N4B—O13B	−131.16 (13)
O8A—Eu1A—N4A—C3A	66.1 (2)	O2B—Eu1B—N4B—O13B	−80.89 (15)
O5A—Eu1A—N4A—C3A	−95.3 (2)	O4B—Eu1B—N4B—O13B	68.73 (18)
O1A—Eu1A—N4A—C3A	164.2 (2)	O1B—Eu1B—N4B—O13B	−33.51 (14)
O4A—Eu1A—N4A—C3A	−176.94 (18)	O5B—Eu1B—N4B—O13B	−12.01 (19)
O7A—Eu1A—N4A—C3A	1.3 (2)	O7B—Eu1B—N4B—O13B	164.01 (13)
N1A—Eu1A—N4A—C3A	140.6 (2)	N1B—Eu1B—N4B—O13B	−56.89 (15)
N2A—Eu1A—N4A—C3A	−143.26 (18)	N2B—Eu1B—N4B—O13B	23.8 (2)
O11A—Eu1A—N4A—O13A	−161.43 (16)	O11B—P1B—N5B—C3B	54.7 (2)
O12A—Eu1A—N4A—O13A	36.27 (14)	C11B—P1B—N5B—C3B	176.06 (17)
O10A—Eu1A—N4A—O13A	111.33 (15)	C17B—P1B—N5B—C3B	−65.69 (19)
O2A—Eu1A—N4A—O13A	−85.93 (14)	C9B—O14B—N6B—C7B	−0.1 (3)
O8A—Eu1A—N4A—O13A	−136.46 (13)	O12B—P2B—N7B—C7B	64.1 (2)
O5A—Eu1A—N4A—O13A	62.19 (19)	C29B—P2B—N7B—C7B	−174.7 (2)
O1A—Eu1A—N4A—O13A	−38.34 (13)	C23B—P2B—N7B—C7B	−59.8 (2)
O4A—Eu1A—N4A—O13A	−19.46 (18)	Eu1B—O10B—C1B—C2B	−134.2 (2)
O7A—Eu1A—N4A—O13A	158.80 (12)	O13B—N4B—C3B—N5B	177.42 (18)
N1A—Eu1A—N4A—O13A	−61.90 (14)	Eu1B—N4B—C3B—N5B	−19.4 (3)
N2A—Eu1A—N4A—O13A	14.2 (2)	O13B—N4B—C3B—C4B	−1.4 (2)
O11A—P1A—N5A—C3A	55.0 (2)	Eu1B—N4B—C3B—C4B	161.77 (15)
C17A—P1A—N5A—C3A	175.90 (18)	P1B—N5B—C3B—N4B	−38.9 (3)
C11A—P1A—N5A—C3A	−65.08 (19)	P1B—N5B—C3B—C4B	139.8 (2)
C9A—O14A—N6A—C7A	0.0 (2)	N4B—C3B—C4B—C5B	1.1 (3)
O12A—P2A—N7A—C7A	54.1 (2)	N5B—C3B—C4B—C5B	−177.7 (2)
C23A—P2A—N7A—C7A	176.5 (2)	C3B—C4B—C5B—O13B	−0.2 (3)
C29A—P2A—N7A—C7A	−71.4 (2)	C3B—C4B—C5B—C6B	177.3 (3)
O13A—N4A—C3A—N5A	178.07 (18)	N4B—O13B—C5B—C4B	−0.7 (3)
Eu1A—N4A—C3A—N5A	−22.2 (3)	N4B—O13B—C5B—C6B	−178.7 (2)
O13A—N4A—C3A—C4A	−1.5 (2)	O14B—N6B—C7B—N7B	179.0 (2)
Eu1A—N4A—C3A—C4A	158.30 (16)	O14B—N6B—C7B—C8B	−0.6 (3)
P1A—N5A—C3A—N4A	−35.4 (3)	P2B—N7B—C7B—N6B	−15.5 (3)
P1A—N5A—C3A—C4A	144.1 (2)	P2B—N7B—C7B—C8B	164.1 (2)
N4A—C3A—C4A—C5A	0.9 (3)	N6B—C7B—C8B—C9B	1.1 (3)
N5A—C3A—C4A—C5A	−178.6 (2)	N7B—C7B—C8B—C9B	−178.5 (3)
C3A—C4A—C5A—O13A	0.2 (3)	C7B—C8B—C9B—O14B	−1.1 (3)
C3A—C4A—C5A—C6A	178.1 (3)	C7B—C8B—C9B—C10B	179.4 (4)
N4A—O13A—C5A—C4A	−1.0 (3)	N6B—O14B—C9B—C8B	0.8 (3)
N4A—O13A—C5A—C6A	−179.4 (2)	N6B—O14B—C9B—C10B	−179.6 (3)
O14A—N6A—C7A—N7A	−177.9 (2)	O11B—P1B—C11B—C12B	−159.02 (18)
O14A—N6A—C7A—C8A	0.8 (3)	N5B—P1B—C11B—C12B	79.6 (2)
P2A—N7A—C7A—N6A	−6.2 (3)	C17B—P1B—C11B—C12B	−34.8 (2)
P2A—N7A—C7A—C8A	175.3 (2)	O11B—P1B—C11B—C16B	24.2 (2)
N6A—C7A—C8A—C9A	−1.3 (3)	N5B—P1B—C11B—C16B	−97.18 (19)
N7A—C7A—C8A—C9A	177.3 (2)	C17B—P1B—C11B—C16B	148.45 (18)
C7A—C8A—C9A—O14A	1.3 (3)	C16B—C11B—C12B—C13B	0.0 (3)
C7A—C8A—C9A—C10A	−177.2 (3)	P1B—C11B—C12B—C13B	−176.70 (18)
N6A—O14A—C9A—C8A	−0.9 (3)	C11B—C12B—C13B—C14B	0.2 (4)
N6A—O14A—C9A—C10A	177.9 (2)	C12B—C13B—C14B—C15B	0.0 (4)
O11A—P1A—C11A—C12A	18.1 (2)	C13B—C14B—C15B—C16B	−0.4 (4)
N5A—P1A—C11A—C12A	139.91 (18)	C14B—C15B—C16B—C11B	0.6 (4)
C17A—P1A—C11A—C12A	−108.36 (19)	C12B—C11B—C16B—C15B	−0.4 (3)
O11A—P1A—C11A—C16A	−159.08 (18)	P1B—C11B—C16B—C15B	176.46 (18)
N5A—P1A—C11A—C16A	−37.3 (2)	O11B—P1B—C17B—C22B	−158.95 (18)
C17A—P1A—C11A—C16A	74.5 (2)	N5B—P1B—C17B—C22B	−36.7 (2)
C16A—C11A—C12A—C13A	−0.8 (3)	C11B—P1B—C17B—C22B	75.2 (2)
P1A—C11A—C12A—C13A	−178.00 (18)	O11B—P1B—C17B—C18B	18.8 (2)
C11A—C12A—C13A—C14A	0.5 (4)	N5B—P1B—C17B—C18B	141.03 (18)
C12A—C13A—C14A—C15A	0.1 (4)	C11B—P1B—C17B—C18B	−107.06 (19)
C13A—C14A—C15A—C16A	−0.4 (4)	C22B—C17B—C18B—C19B	−0.8 (3)
C14A—C15A—C16A—C11A	0.0 (4)	P1B—C17B—C18B—C19B	−178.58 (18)
C12A—C11A—C16A—C15A	0.5 (4)	C17B—C18B—C19B—C20B	0.3 (4)
P1A—C11A—C16A—C15A	177.68 (18)	C18B—C19B—C20B—C21B	0.2 (4)
O11A—P1A—C17A—C18A	−162.75 (18)	C19B—C20B—C21B—C22B	−0.2 (4)
N5A—P1A—C17A—C18A	76.5 (2)	C20B—C21B—C22B—C17B	−0.3 (4)
C11A—P1A—C17A—C18A	−37.9 (2)	C18B—C17B—C22B—C21B	0.8 (3)
O11A—P1A—C17A—C22A	22.7 (2)	P1B—C17B—C22B—C21B	178.54 (18)
N5A—P1A—C17A—C22A	−98.0 (2)	O12B—P2B—C23B—C24B	32.4 (2)
C11A—P1A—C17A—C22A	147.61 (18)	N7B—P2B—C23B—C24B	159.1 (2)
C22A—C17A—C18A—C19A	1.1 (4)	C29B—P2B—C23B—C24B	−92.8 (2)
P1A—C17A—C18A—C19A	−173.27 (19)	O12B—P2B—C23B—C28B	−149.15 (19)
C17A—C18A—C19A—C20A	−0.1 (4)	N7B—P2B—C23B—C28B	−22.4 (2)
C18A—C19A—C20A—C21A	−0.8 (4)	C29B—P2B—C23B—C28B	85.7 (2)
C19A—C20A—C21A—C22A	0.6 (4)	C28B—C23B—C24B—C25B	−1.2 (4)
C20A—C21A—C22A—C17A	0.5 (4)	P2B—C23B—C24B—C25B	177.2 (2)
C18A—C17A—C22A—C21A	−1.3 (4)	C23B—C24B—C25B—C26B	0.5 (5)
P1A—C17A—C22A—C21A	173.34 (19)	C24B—C25B—C26B—C27B	0.7 (5)
O12A—P2A—C23A—C28A	12.6 (2)	C25B—C26B—C27B—C28B	−1.2 (5)
N7A—P2A—C23A—C28A	−111.3 (2)	C26B—C27B—C28B—C23B	0.5 (4)
C29A—P2A—C23A—C28A	136.5 (2)	C24B—C23B—C28B—C27B	0.7 (4)
O12A—P2A—C23A—C24A	−171.24 (18)	P2B—C23B—C28B—C27B	−177.7 (2)
N7A—P2A—C23A—C24A	64.9 (2)	O12B—P2B—C29B—C30B	−168.31 (19)
C29A—P2A—C23A—C24A	−47.3 (2)	N7B—P2B—C29B—C30B	68.1 (2)
C28A—C23A—C24A—C25A	1.0 (4)	C23B—P2B—C29B—C30B	−43.8 (2)
P2A—C23A—C24A—C25A	−175.2 (2)	O12B—P2B—C29B—C34B	17.8 (2)
C23A—C24A—C25A—C26A	−0.3 (4)	N7B—P2B—C29B—C34B	−105.8 (2)
C24A—C25A—C26A—C27A	−0.4 (4)	C23B—P2B—C29B—C34B	142.35 (19)
C25A—C26A—C27A—C28A	0.4 (4)	C34B—C29B—C30B—C31B	1.6 (4)
C26A—C27A—C28A—C23A	0.3 (4)	P2B—C29B—C30B—C31B	−172.3 (2)
C24A—C23A—C28A—C27A	−1.0 (4)	C29B—C30B—C31B—C32B	−0.5 (4)
P2A—C23A—C28A—C27A	175.1 (2)	C30B—C31B—C32B—C33B	−1.4 (4)
O12A—P2A—C29A—C30A	−141.29 (19)	C31B—C32B—C33B—C34B	2.2 (4)
N7A—P2A—C29A—C30A	−13.4 (2)	C32B—C33B—C34B—C29B	−1.1 (4)
C23A—P2A—C29A—C30A	93.6 (2)	C30B—C29B—C34B—C33B	−0.8 (4)
O12A—P2A—C29A—C34A	43.7 (2)	P2B—C29B—C34B—C33B	173.16 (19)
N7A—P2A—C29A—C34A	171.6 (2)	O11A—Eu1A—O10A—C1'A	98.3 (6)
C23A—P2A—C29A—C34A	−81.4 (2)	O12A—Eu1A—O10A—C1'A	−110.7 (6)
C34A—C29A—C30A—C31A	−0.3 (4)	O2A—Eu1A—O10A—C1'A	121.5 (6)
P2A—C29A—C30A—C31A	−175.22 (19)	O8A—Eu1A—O10A—C1'A	32.5 (6)
C29A—C30A—C31A—C32A	0.3 (4)	O5A—Eu1A—O10A—C1'A	−34.0 (6)
C30A—C31A—C32A—C33A	0.0 (5)	O1A—Eu1A—O10A—C1'A	−150.7 (6)
C31A—C32A—C33A—C34A	−0.2 (6)	O4A—Eu1A—O10A—C1'A	−57.2 (6)
C32A—C33A—C34A—C29A	0.2 (6)	N4A—Eu1A—O10A—C1'A	169.4 (6)
C30A—C29A—C34A—C33A	0.0 (5)	O7A—Eu1A—O10A—C1'A	30.4 (6)
P2A—C29A—C34A—C33A	175.2 (3)	N1A—Eu1A—O10A—C1'A	−175.2 (6)
O11B—Eu1B—O1B—N1B	−57.00 (13)	N2A—Eu1A—O10A—C1'A	−44.6 (6)
O12B—Eu1B—O1B—N1B	163.97 (13)	O11A—Eu1A—O10A—C1A	48.2 (4)
O10B—Eu1B—O1B—N1B	−156.20 (11)	O12A—Eu1A—O10A—C1A	−160.8 (4)
O8B—Eu1B—O1B—N1B	21.06 (13)	O2A—Eu1A—O10A—C1A	71.4 (4)
O2B—Eu1B—O1B—N1B	−6.17 (11)	O8A—Eu1A—O10A—C1A	−17.6 (4)
O4B—Eu1B—O1B—N1B	102.54 (12)	O5A—Eu1A—O10A—C1A	−84.1 (4)
O5B—Eu1B—O1B—N1B	82.67 (13)	O1A—Eu1A—O10A—C1A	159.3 (4)
N4B—Eu1B—O1B—N1B	−113.89 (13)	O4A—Eu1A—O10A—C1A	−107.3 (4)
O7B—Eu1B—O1B—N1B	22.8 (2)	N4A—Eu1A—O10A—C1A	119.3 (4)
N2B—Eu1B—O1B—N1B	94.68 (12)	O7A—Eu1A—O10A—C1A	−19.7 (4)
O11B—Eu1B—O2B—N1B	138.32 (13)	N1A—Eu1A—O10A—C1A	134.7 (4)
O12B—Eu1B—O2B—N1B	−4.54 (15)	N2A—Eu1A—O10A—C1A	−94.7 (4)
O10B—Eu1B—O2B—N1B	112.15 (16)	C1'A—O10A—C1A—C2A	47.7 (6)
O8B—Eu1B—O2B—N1B	−145.26 (14)	Eu1A—O10A—C1A—C2A	164.0 (3)
O4B—Eu1B—O2B—N1B	−91.46 (13)	C1A—O10A—C1'A—C2'A	−42.4 (7)
O1B—Eu1B—O2B—N1B	6.17 (11)	Eu1A—O10A—C1'A—C2'A	−145.3 (4)
O5B—Eu1B—O2B—N1B	−66.41 (13)	C3'S—O2S—C3S—C4S	−61 (3)
N4B—Eu1B—O2B—N1B	69.78 (13)	C3RS—O2S—C3S—C4S	45.8 (17)
O7B—Eu1B—O2B—N1B	−163.06 (12)	C3S—O2S—C3'S—C4'S	57 (3)
N2B—Eu1B—O2B—N1B	−76.52 (13)	C3RS—O2S—C3'S—C4'S	12.7 (10)
O11B—Eu1B—O4B—N2B	135.31 (12)	C3S—O2S—C3RS—C4RS	−37.0 (16)
O12B—Eu1B—O4B—N2B	−78.34 (13)	C3'S—O2S—C3RS—C4RS	−2.9 (14)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O1S—H1S···O5B^i	0.88	2.12	2.941 (3)	155
O1S—H1S···O6B^i	0.88	2.37	3.145 (3)	148
O2S—H2S···O4A^ii	0.82	2.47	3.252 (3)	159
O2S—H2S···O6A^ii	0.82	2.31	2.997 (3)	142
N5A—H5A···O9B^i	0.78 (3)	2.12 (3)	2.883 (3)	168 (3)
N5B—H5B···O9A^ii	0.79 (3)	2.07 (3)	2.855 (3)	174 (3)
N7A—H7A···O1S^iii	0.84	2.02	2.842 (3)	163
N7B—H7B···O2S^iii	0.77 (3)	2.07 (3)	2.822 (3)	169 (3)
O10B—H1OB···N6B	0.80	2.05	2.841 (2)	170
O10A—H1OA···N6A	0.86	1.91	2.775 (3)	174

Symmetry codes: (i) −x+1, −y+2, −z+1; (ii) −x+1, −y+1, −z+1; (iii) x+1, y, z.