trans-[2,3-Bis(methylthio)hexane-S,S']dichlorozinc(II), trans-[1,2-Bis(methylthio)cyclohexane-S,S']dichlorozinc(II) and cis-[5,6-Bis(methylthio)-1,3-cycloheptadiene-S,S']dichlorozinc(II)

The crystal structures of trans-[2,3-bis(methylthio)hexane-S,S']dichlorozinc(II), [ZnCl₂(C₈H₁₈S₂)], trans-[1,2-bis(methylthio)cyclohexane-S,S']dichlorozinc(II), [ZnCl₂(C₈H₁₆S₂)], and cis-[1,2-bis(methylthio)-3,5-cycloheptadiene-S,S']dichlorozinc(II), [ZnCl₂(C₉H₁₄S₂)], contain distorted tetrahedral Zn atoms coordinated to two Cl and two S atoms with Zn-Cl and Zn-S distances in the ranges 2.190 (2)-2.222 (2) and 2.369 (2)-2.475 (1) Å, respectively. The Cl-Zn-Cl and S-Zn-S angles in the three compounds are in the ranges 117.35 (4)-122.63 (4) and 88.11 (5)-91.12 (6)°, respectively.

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