Crystal structure and luminescence properties of 2-[(2′,6′-dimeth­oxy-2,3′-bipyridin-6-yl)­oxy]-9-(pyridin-2-yl)-9H-carbazole

In the title com­pound, the dihedral angle between the planes of the bi­pyridine and carbazole moieties connected by an O atom is 68.45 (3)°. The bi­pyridine ring system, with two meth­oxy substituents, is approximately planar. The pyridine ring in the pyridyl-substituted carbazole fragment is tilted by 56.65 (4)° with respect to the mean plane of the carbazole moiety. The title com­pound exhibits a high energy gap and triplet energy.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.034
• wR factor = 0.084
• Data-to-parameter ratio = 15.8

checkCIF/PLATON results

No syntax errors found



Datablock: I


Alert level C
PLAT915_ALERT_3_C No Flack x Check Done: Low Friedel Pair Coverage         82 %

Alert level G
PLAT128_ALERT_4_G Alternate Setting for Input Space Group  Ia              Ic Note
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600          4 Note
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.         14 Info

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   1 ALERT level C = Check. Ensure it is not caused by an omission or oversight
   3 ALERT level G = General information/check it is not something unexpected

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: APEX2 (Bruker, 2014); cell refinement: SAINT (Bruker, 2014); data reduction: SAINT (Bruker, 2014); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: DIAMOND (Brandenburg, 2010); software used to prepare material for publication: SHELXTL (Sheldrick, 2008) and publCIF (Westrip, 2010).

2-[(2',6'-Dimethoxy-2,3'-bipyridin-6-yl)oxy]-9-(pyridin-2-yl)-9H-carbazole

Crystal data

C29H22N4O3	F(000) = 992
Mr = 474.50	Dx = 1.385 Mg m^−3
Monoclinic, Ia	Mo Kα radiation, λ = 0.71073 Å
a = 9.6979 (1) Å	Cell parameters from 6053 reflections
b = 23.6702 (3) Å	θ = 2.2–28.3°
c = 9.9229 (2) Å	µ = 0.09 mm^−1
β = 92.9125 (5)°	T = 173 K
V = 2274.87 (6) Å^3	Block, colourless
Z = 4	0.53 × 0.46 × 0.12 mm

Data collection

Bruker APEXII CCD diffractometer	4943 reflections with I > 2σ(I)
φ and ω scans	Rint = 0.020
Absorption correction: multi-scan (SADABS; Bruker, 2014)	θmax = 28.4°, θmin = 1.7°
Tmin = 0.710, Tmax = 0.746	h = −12→12
10918 measured reflections	k = −31→31
5179 independent reflections	l = −13→12

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.034	H-atom parameters constrained
wR(F^2) = 0.084	w = 1/[σ^2(Fo^2) + (0.0404P)^2 + 0.7038P] where P = (Fo^2 + 2Fc^2)/3
S = 1.06	(Δ/σ)max < 0.001
5179 reflections	Δρmax = 0.21 e Å^−3
328 parameters	Δρmin = −0.19 e Å^−3
2 restraints	Extinction correction: SHELXL2014 (Sheldrick, 2015), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0062 (6)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
O1	0.16676 (16)	0.24337 (6)	0.28067 (15)	0.0285 (3)
O2	−0.27313 (17)	0.33138 (6)	0.70330 (18)	0.0382 (4)
O3	−0.43670 (17)	0.15756 (6)	0.82051 (17)	0.0358 (4)
N1	0.3339 (2)	0.06572 (7)	0.02064 (19)	0.0287 (4)
N2	0.30895 (18)	0.04679 (7)	0.24867 (18)	0.0270 (4)
N3	−0.00057 (17)	0.25161 (7)	0.43700 (18)	0.0244 (3)
N4	−0.35398 (18)	0.24417 (7)	0.75714 (19)	0.0273 (4)
C1	0.3152 (3)	0.05001 (10)	−0.1083 (2)	0.0344 (5)
H1	0.3516	0.0737	−0.1752	0.041*
C2	0.2465 (3)	0.00167 (10)	−0.1504 (2)	0.0360 (5)
H2	0.2399	−0.0086	−0.2431	0.043*
C3	0.1874 (3)	−0.03137 (10)	−0.0545 (3)	0.0379 (5)
H3	0.1378	−0.0646	−0.0801	0.045*
C4	0.2016 (3)	−0.01536 (9)	0.0794 (2)	0.0353 (5)
H4	0.1594	−0.0365	0.1475	0.042*
C5	0.2793 (2)	0.03247 (8)	0.1115 (2)	0.0246 (4)
C6	0.3774 (2)	0.01129 (8)	0.3428 (2)	0.0261 (4)
C7	0.4216 (2)	−0.04424 (9)	0.3285 (2)	0.0305 (4)
H7	0.4050	−0.0642	0.2462	0.037*
C8	0.4904 (2)	−0.06934 (9)	0.4381 (2)	0.0331 (5)
H8	0.5208	−0.1073	0.4311	0.040*
C9	0.5164 (3)	−0.04006 (10)	0.5592 (2)	0.0356 (5)
H9	0.5633	−0.0584	0.6333	0.043*
C10	0.4742 (2)	0.01540 (9)	0.5717 (2)	0.0319 (5)
H10	0.4937	0.0355	0.6534	0.038*
C11	0.4030 (2)	0.04161 (8)	0.4635 (2)	0.0253 (4)
C12	0.3469 (2)	0.09767 (8)	0.44159 (19)	0.0231 (4)
C13	0.3371 (2)	0.14504 (8)	0.5239 (2)	0.0259 (4)
H13	0.3741	0.1443	0.6144	0.031*
C14	0.2730 (2)	0.19313 (8)	0.4724 (2)	0.0263 (4)
H14	0.2648	0.2256	0.5277	0.032*
C15	0.2203 (2)	0.19380 (8)	0.3386 (2)	0.0243 (4)
C16	0.2283 (2)	0.14802 (8)	0.2536 (2)	0.0240 (4)
H16	0.1920	0.1493	0.1629	0.029*
C17	0.2923 (2)	0.09974 (8)	0.3073 (2)	0.0232 (4)
C18	0.0820 (2)	0.27662 (8)	0.3548 (2)	0.0239 (4)
C19	0.0883 (2)	0.33456 (9)	0.3325 (2)	0.0309 (5)
H19	0.1491	0.3506	0.2708	0.037*
C20	0.0015 (2)	0.36732 (9)	0.4049 (2)	0.0347 (5)
H20	0.0019	0.4072	0.3941	0.042*
C21	−0.0865 (2)	0.34265 (9)	0.4935 (2)	0.0299 (5)
H21	−0.1461	0.3653	0.5440	0.036*
C22	−0.0865 (2)	0.28402 (8)	0.5075 (2)	0.0238 (4)
C23	−0.1789 (2)	0.25192 (8)	0.5941 (2)	0.0251 (4)
C24	−0.2697 (2)	0.27479 (8)	0.6851 (2)	0.0261 (4)
C25	−0.3517 (2)	0.18857 (9)	0.7446 (2)	0.0301 (4)
C26	−0.2677 (3)	0.16054 (10)	0.6591 (3)	0.0431 (6)
H26	−0.2689	0.1205	0.6519	0.052*
C27	−0.1815 (3)	0.19309 (9)	0.5844 (3)	0.0374 (5)
H27	−0.1222	0.1749	0.5245	0.045*
C28	−0.3786 (3)	0.35291 (10)	0.7870 (3)	0.0458 (6)
H28A	−0.3613	0.3930	0.8061	0.069*
H28B	−0.3770	0.3317	0.8719	0.069*
H28C	−0.4693	0.3486	0.7398	0.069*
C29	−0.5206 (3)	0.18868 (10)	0.9090 (3)	0.0366 (5)
H29A	−0.5724	0.1623	0.9634	0.055*
H29B	−0.5854	0.2125	0.8555	0.055*
H29C	−0.4616	0.2125	0.9686	0.055*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
O1	0.0366 (8)	0.0230 (7)	0.0266 (7)	0.0077 (6)	0.0087 (6)	0.0039 (6)
O2	0.0429 (9)	0.0230 (7)	0.0510 (10)	−0.0008 (6)	0.0243 (8)	−0.0039 (7)
O3	0.0361 (8)	0.0275 (8)	0.0446 (10)	−0.0009 (6)	0.0100 (8)	0.0102 (7)
N1	0.0347 (9)	0.0247 (8)	0.0272 (9)	−0.0012 (7)	0.0062 (7)	−0.0023 (7)
N2	0.0367 (10)	0.0195 (8)	0.0249 (9)	0.0020 (7)	0.0032 (7)	−0.0003 (6)
N3	0.0248 (8)	0.0212 (8)	0.0275 (8)	0.0015 (6)	0.0032 (7)	0.0005 (6)
N4	0.0247 (9)	0.0268 (8)	0.0306 (9)	0.0009 (7)	0.0032 (7)	0.0034 (7)
C1	0.0435 (13)	0.0330 (11)	0.0272 (11)	0.0016 (10)	0.0085 (9)	−0.0003 (9)
C2	0.0410 (13)	0.0362 (12)	0.0303 (11)	0.0063 (10)	−0.0024 (10)	−0.0106 (9)
C3	0.0409 (13)	0.0272 (11)	0.0448 (14)	−0.0027 (9)	−0.0062 (11)	−0.0101 (9)
C4	0.0420 (13)	0.0277 (11)	0.0364 (12)	−0.0074 (9)	0.0034 (10)	−0.0005 (9)
C5	0.0278 (10)	0.0206 (9)	0.0254 (10)	0.0023 (7)	0.0025 (8)	−0.0029 (7)
C6	0.0282 (10)	0.0245 (9)	0.0262 (10)	0.0008 (8)	0.0072 (8)	0.0032 (7)
C7	0.0367 (11)	0.0240 (9)	0.0314 (11)	0.0010 (8)	0.0094 (9)	−0.0002 (8)
C8	0.0342 (11)	0.0248 (10)	0.0413 (12)	0.0050 (8)	0.0116 (9)	0.0054 (9)
C9	0.0386 (12)	0.0349 (11)	0.0337 (12)	0.0095 (9)	0.0047 (10)	0.0104 (9)
C10	0.0346 (11)	0.0351 (11)	0.0265 (10)	0.0070 (9)	0.0055 (9)	0.0045 (8)
C11	0.0247 (10)	0.0254 (9)	0.0264 (10)	0.0022 (7)	0.0078 (8)	0.0023 (8)
C12	0.0227 (9)	0.0248 (9)	0.0222 (9)	0.0009 (7)	0.0048 (7)	0.0019 (7)
C13	0.0276 (9)	0.0288 (10)	0.0215 (9)	0.0012 (8)	0.0034 (7)	−0.0012 (8)
C14	0.0291 (10)	0.0236 (9)	0.0268 (10)	0.0007 (8)	0.0064 (8)	−0.0039 (8)
C15	0.0238 (9)	0.0217 (9)	0.0283 (10)	0.0009 (7)	0.0088 (8)	0.0019 (7)
C16	0.0249 (9)	0.0243 (9)	0.0231 (9)	−0.0010 (7)	0.0043 (7)	0.0006 (7)
C17	0.0248 (9)	0.0220 (9)	0.0233 (9)	−0.0024 (7)	0.0058 (8)	−0.0015 (7)
C18	0.0256 (9)	0.0227 (9)	0.0235 (9)	0.0039 (8)	0.0016 (8)	−0.0004 (7)
C19	0.0330 (11)	0.0242 (10)	0.0364 (12)	0.0018 (8)	0.0099 (9)	0.0067 (8)
C20	0.0398 (12)	0.0203 (9)	0.0448 (13)	0.0048 (9)	0.0109 (10)	0.0036 (9)
C21	0.0297 (10)	0.0243 (10)	0.0364 (12)	0.0059 (8)	0.0096 (9)	−0.0003 (8)
C22	0.0223 (9)	0.0221 (9)	0.0269 (10)	0.0016 (7)	−0.0002 (8)	0.0006 (7)
C23	0.0226 (9)	0.0228 (9)	0.0300 (10)	0.0025 (7)	0.0018 (8)	0.0030 (8)
C24	0.0246 (9)	0.0242 (9)	0.0294 (10)	0.0011 (7)	0.0014 (8)	0.0016 (8)
C25	0.0270 (10)	0.0275 (10)	0.0359 (11)	−0.0003 (8)	0.0025 (9)	0.0070 (9)
C26	0.0481 (15)	0.0218 (10)	0.0613 (17)	0.0015 (10)	0.0208 (13)	0.0050 (10)
C27	0.0407 (12)	0.0241 (10)	0.0489 (14)	0.0037 (9)	0.0182 (11)	0.0004 (9)
C28	0.0540 (15)	0.0298 (11)	0.0565 (16)	0.0028 (11)	0.0298 (13)	−0.0055 (11)
C29	0.0359 (12)	0.0377 (12)	0.0370 (12)	−0.0085 (10)	0.0090 (10)	0.0034 (10)

Geometric parameters (Å, º)

O1—C18	1.378 (2)	C10—H10	0.9500
O1—C15	1.395 (2)	C11—C12	1.446 (3)
O2—C24	1.352 (2)	C12—C13	1.393 (3)
O2—C28	1.443 (3)	C12—C17	1.409 (3)
O3—C25	1.360 (3)	C13—C14	1.383 (3)
O3—C29	1.431 (3)	C13—H13	0.9500
N1—C5	1.327 (3)	C14—C15	1.398 (3)
N1—C1	1.335 (3)	C14—H14	0.9500
N2—C17	1.395 (2)	C15—C16	1.378 (3)
N2—C6	1.399 (3)	C16—C17	1.393 (3)
N2—C5	1.417 (3)	C16—H16	0.9500
N3—C18	1.312 (3)	C18—C19	1.391 (3)
N3—C22	1.353 (3)	C19—C20	1.373 (3)
N4—C25	1.322 (3)	C19—H19	0.9500
N4—C24	1.328 (3)	C20—C21	1.386 (3)
C1—C2	1.379 (3)	C20—H20	0.9500
C1—H1	0.9500	C21—C22	1.395 (3)
C2—C3	1.379 (4)	C21—H21	0.9500
C2—H2	0.9500	C22—C23	1.482 (3)
C3—C4	1.382 (3)	C23—C27	1.396 (3)
C3—H3	0.9500	C23—C24	1.402 (3)
C4—C5	1.388 (3)	C25—C26	1.377 (3)
C4—H4	0.9500	C26—C27	1.380 (3)
C6—C7	1.392 (3)	C26—H26	0.9500
C6—C11	1.407 (3)	C27—H27	0.9500
C7—C8	1.380 (3)	C28—H28A	0.9800
C7—H7	0.9500	C28—H28B	0.9800
C8—C9	1.399 (3)	C28—H28C	0.9800
C8—H8	0.9500	C29—H29A	0.9800
C9—C10	1.382 (3)	C29—H29B	0.9800
C9—H9	0.9500	C29—H29C	0.9800
C10—C11	1.393 (3)
C18—O1—C15	118.70 (15)	C16—C15—O1	116.16 (18)
C24—O2—C28	116.72 (17)	C16—C15—C14	122.88 (18)
C25—O3—C29	116.20 (17)	O1—C15—C14	120.73 (17)
C5—N1—C1	116.50 (19)	C15—C16—C17	116.67 (18)
C17—N2—C6	108.79 (16)	C15—C16—H16	121.7
C17—N2—C5	126.41 (16)	C17—C16—H16	121.7
C6—N2—C5	124.30 (16)	C16—C17—N2	129.49 (18)
C18—N3—C22	118.47 (17)	C16—C17—C12	121.93 (18)
C25—N4—C24	118.63 (19)	N2—C17—C12	108.51 (16)
N1—C1—C2	124.2 (2)	N3—C18—O1	118.27 (17)
N1—C1—H1	117.9	N3—C18—C19	125.21 (19)
C2—C1—H1	117.9	O1—C18—C19	116.49 (19)
C3—C2—C1	118.2 (2)	C20—C19—C18	116.1 (2)
C3—C2—H2	120.9	C20—C19—H19	121.9
C1—C2—H2	120.9	C18—C19—H19	121.9
C2—C3—C4	118.9 (2)	C19—C20—C21	120.5 (2)
C2—C3—H3	120.5	C19—C20—H20	119.7
C4—C3—H3	120.5	C21—C20—H20	119.7
C3—C4—C5	118.1 (2)	C20—C21—C22	119.04 (19)
C3—C4—H4	120.9	C20—C21—H21	120.5
C5—C4—H4	120.9	C22—C21—H21	120.5
N1—C5—C4	123.9 (2)	N3—C22—C21	120.63 (19)
N1—C5—N2	116.24 (18)	N3—C22—C23	114.54 (16)
C4—C5—N2	119.80 (19)	C21—C22—C23	124.80 (18)
C7—C6—N2	129.6 (2)	C27—C23—C24	114.82 (19)
C7—C6—C11	121.8 (2)	C27—C23—C22	118.74 (19)
N2—C6—C11	108.61 (17)	C24—C23—C22	126.41 (18)
C8—C7—C6	117.7 (2)	N4—C24—O2	116.67 (18)
C8—C7—H7	121.1	N4—C24—C23	124.05 (18)
C6—C7—H7	121.1	O2—C24—C23	119.27 (18)
C7—C8—C9	121.5 (2)	N4—C25—O3	118.2 (2)
C7—C8—H8	119.3	N4—C25—C26	123.4 (2)
C9—C8—H8	119.3	O3—C25—C26	118.41 (19)
C10—C9—C8	120.4 (2)	C25—C26—C27	117.1 (2)
C10—C9—H9	119.8	C25—C26—H26	121.4
C8—C9—H9	119.8	C27—C26—H26	121.4
C9—C10—C11	119.4 (2)	C26—C27—C23	121.9 (2)
C9—C10—H10	120.3	C26—C27—H27	119.0
C11—C10—H10	120.3	C23—C27—H27	119.0
C10—C11—C6	119.22 (19)	O2—C28—H28A	109.5
C10—C11—C12	133.8 (2)	O2—C28—H28B	109.5
C6—C11—C12	106.95 (17)	H28A—C28—H28B	109.5
C13—C12—C17	119.52 (18)	O2—C28—H28C	109.5
C13—C12—C11	133.37 (18)	H28A—C28—H28C	109.5
C17—C12—C11	107.10 (17)	H28B—C28—H28C	109.5
C14—C13—C12	119.24 (19)	O3—C29—H29A	109.5
C14—C13—H13	120.4	O3—C29—H29B	109.5
C12—C13—H13	120.4	H29A—C29—H29B	109.5
C13—C14—C15	119.76 (18)	O3—C29—H29C	109.5
C13—C14—H14	120.1	H29A—C29—H29C	109.5
C15—C14—H14	120.1	H29B—C29—H29C	109.5
C5—N1—C1—C2	−1.4 (3)	C6—N2—C17—C16	−178.7 (2)
N1—C1—C2—C3	3.2 (4)	C5—N2—C17—C16	9.2 (3)
C1—C2—C3—C4	−1.1 (4)	C6—N2—C17—C12	−1.7 (2)
C2—C3—C4—C5	−2.3 (4)	C5—N2—C17—C12	−173.88 (18)
C1—N1—C5—C4	−2.4 (3)	C13—C12—C17—C16	0.0 (3)
C1—N1—C5—N2	175.06 (19)	C11—C12—C17—C16	179.17 (18)
C3—C4—C5—N1	4.3 (3)	C13—C12—C17—N2	−177.21 (18)
C3—C4—C5—N2	−173.1 (2)	C11—C12—C17—N2	2.0 (2)
C17—N2—C5—N1	51.1 (3)	C22—N3—C18—O1	−178.41 (17)
C6—N2—C5—N1	−119.9 (2)	C22—N3—C18—C19	−0.6 (3)
C17—N2—C5—C4	−131.3 (2)	C15—O1—C18—N3	−34.5 (3)
C6—N2—C5—C4	57.7 (3)	C15—O1—C18—C19	147.49 (19)
C17—N2—C6—C7	−177.0 (2)	N3—C18—C19—C20	0.9 (3)
C5—N2—C6—C7	−4.6 (3)	O1—C18—C19—C20	178.79 (19)
C17—N2—C6—C11	0.8 (2)	C18—C19—C20—C21	−0.4 (4)
C5—N2—C6—C11	173.16 (18)	C19—C20—C21—C22	−0.4 (4)
N2—C6—C7—C8	178.5 (2)	C18—N3—C22—C21	−0.3 (3)
C11—C6—C7—C8	1.0 (3)	C18—N3—C22—C23	178.03 (17)
C6—C7—C8—C9	−0.6 (3)	C20—C21—C22—N3	0.8 (3)
C7—C8—C9—C10	−0.5 (4)	C20—C21—C22—C23	−177.4 (2)
C8—C9—C10—C11	1.3 (4)	N3—C22—C23—C27	−7.2 (3)
C9—C10—C11—C6	−1.0 (3)	C21—C22—C23—C27	171.1 (2)
C9—C10—C11—C12	−179.1 (2)	N3—C22—C23—C24	174.66 (18)
C7—C6—C11—C10	−0.2 (3)	C21—C22—C23—C24	−7.0 (3)
N2—C6—C11—C10	−178.16 (18)	C25—N4—C24—O2	−178.53 (19)
C7—C6—C11—C12	178.39 (19)	C25—N4—C24—C23	1.0 (3)
N2—C6—C11—C12	0.4 (2)	C28—O2—C24—N4	−6.9 (3)
C10—C11—C12—C13	−4.2 (4)	C28—O2—C24—C23	173.6 (2)
C6—C11—C12—C13	177.6 (2)	C27—C23—C24—N4	−0.6 (3)
C10—C11—C12—C17	176.8 (2)	C22—C23—C24—N4	177.60 (19)
C6—C11—C12—C17	−1.4 (2)	C27—C23—C24—O2	178.9 (2)
C17—C12—C13—C14	0.4 (3)	C22—C23—C24—O2	−2.9 (3)
C11—C12—C13—C14	−178.5 (2)	C24—N4—C25—O3	178.91 (18)
C12—C13—C14—C15	−0.6 (3)	C24—N4—C25—C26	−1.0 (4)
C18—O1—C15—C16	141.73 (19)	C29—O3—C25—N4	−0.6 (3)
C18—O1—C15—C14	−43.6 (3)	C29—O3—C25—C26	179.2 (2)
C13—C14—C15—C16	0.3 (3)	N4—C25—C26—C27	0.5 (4)
C13—C14—C15—O1	−174.02 (18)	O3—C25—C26—C27	−179.4 (2)
O1—C15—C16—C17	174.71 (16)	C25—C26—C27—C23	−0.1 (4)
C14—C15—C16—C17	0.1 (3)	C24—C23—C27—C26	0.1 (4)
C15—C16—C17—N2	176.29 (19)	C22—C23—C27—C26	−178.2 (2)
C15—C16—C17—C12	−0.3 (3)

Hydrogen-bond geometry (Å, º)

Cg1 is the centroid of the C12–C17 ring.

D—H···A	D—H	H···A	D···A	D—H···A
C3—H3···O3^i	0.95	2.50	3.429 (3)	165
C21—H21···O2	0.95	2.20	2.839 (3)	123
C27—H27···N3	0.95	2.35	2.720 (3)	102
C29—H29A···N1^ii	0.98	2.54	3.442 (3)	154
C8—H8···Cg1^iii	0.95	2.76	3.426 (2)	128
C28—H28C···Cg1^iv	0.98	2.89	3.485 (3)	120

Symmetry codes: (i) x+1/2, −y, z−1; (ii) x−1, y, z+1; (iii) x+1/2, −y, z; (iv) x−1, −y+1/2, z+1/2.