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The title compound, [Sn(C6H5)3(C6H4NO3)], possesses an infinite chain structure. The SnO2C3 centre has distorted trigonal–bipyramidal geometry with the O atoms in the apical positions. A strong inter­molecular N—H...O hydrogen bond results in the formation of double chains.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806006726/hb2011sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806006726/hb2011Isup2.hkl
Contains datablock I

CCDC reference: 287798

Key indicators

  • Single-crystal X-ray study
  • T = 298 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.027
  • wR factor = 0.071
  • Data-to-parameter ratio = 14.3

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.95 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.13 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C9
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 3 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.

catena-Poly[[triphenyltin(IV)]-µ-6-hydroxypyridine-3-carboxylato] top
Crystal data top
[Sn(C6H5)3(C6H4NO3)]F(000) = 976
Mr = 488.09Dx = 1.518 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 5143 reflections
a = 9.5629 (17) Åθ = 2.2–27.8°
b = 10.6579 (19) ŵ = 1.22 mm1
c = 21.353 (4) ÅT = 298 K
β = 101.155 (3)°Block, colourless
V = 2135.2 (7) Å30.49 × 0.46 × 0.41 mm
Z = 4
Data collection top
Bruker SMART CCD
diffractometer
3755 independent reflections
Radiation source: fine-focus sealed tube3053 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.041
φ and ω scansθmax = 25.0°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 1998)
h = 911
Tmin = 0.586, Tmax = 0.635k = 1212
10839 measured reflectionsl = 2425
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.027Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.071H-atom parameters constrained
S = 1.00 w = 1/[σ2(Fo2) + (0.034P)2 + 0.6145P]
where P = (Fo2 + 2Fc2)/3
3755 reflections(Δ/σ)max = 0.001
262 parametersΔρmax = 0.52 e Å3
0 restraintsΔρmin = 0.47 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.38463 (2)0.22844 (2)0.371584 (10)0.03163 (9)
N10.4684 (3)0.8383 (2)0.31816 (13)0.0412 (7)
H10.50200.88540.29190.049*
O10.3573 (2)0.4286 (2)0.37293 (10)0.0406 (6)
O20.4407 (3)0.4558 (2)0.28338 (11)0.0516 (7)
O30.4339 (3)1.0117 (2)0.37454 (12)0.0543 (6)
C10.4027 (3)0.4975 (3)0.33130 (15)0.0370 (7)
C20.4619 (4)0.7144 (3)0.30654 (15)0.0385 (8)
H20.49400.68320.27120.046*
C30.4092 (3)0.6339 (3)0.34543 (14)0.0311 (7)
C40.3660 (3)0.6863 (3)0.39925 (15)0.0379 (8)
H40.33070.63380.42730.045*
C50.3746 (4)0.8110 (3)0.41112 (16)0.0425 (8)
H50.34670.84190.44750.051*
C60.4251 (4)0.8959 (3)0.36931 (15)0.0395 (8)
C70.2975 (3)0.2123 (3)0.45612 (15)0.0366 (8)
C80.2362 (4)0.1009 (4)0.4700 (2)0.0675 (13)
H80.23060.03390.44180.081*
C90.1831 (6)0.0879 (5)0.5256 (3)0.0968 (19)
H90.14350.01190.53480.116*
C100.1886 (6)0.1860 (6)0.5668 (2)0.0900 (17)
H100.15390.17660.60430.108*
C110.2440 (5)0.2965 (5)0.5536 (2)0.0733 (14)
H110.24540.36400.58130.088*
C120.2991 (4)0.3099 (4)0.49839 (17)0.0536 (10)
H120.33790.38650.48980.064*
C130.2302 (3)0.1953 (3)0.28674 (15)0.0376 (8)
C140.2259 (4)0.0894 (3)0.24924 (17)0.0528 (9)
H140.29890.03070.25860.063*
C150.1152 (5)0.0684 (4)0.19798 (19)0.0695 (12)
H150.11470.00350.17330.083*
C160.0067 (5)0.1534 (6)0.1837 (2)0.0863 (16)
H160.06820.13910.14960.104*
C170.0087 (5)0.2593 (5)0.2196 (2)0.0890 (17)
H170.06470.31750.20980.107*
C180.1192 (4)0.2807 (4)0.27052 (19)0.0612 (11)
H180.11940.35370.29440.073*
C190.6108 (3)0.2454 (3)0.38611 (15)0.0382 (8)
C200.6747 (4)0.3350 (4)0.42928 (17)0.0531 (9)
H200.61780.38720.44870.064*
C210.8207 (5)0.3483 (5)0.4441 (2)0.0785 (14)
H210.86270.40620.47460.094*
C220.9026 (5)0.2745 (5)0.4130 (3)0.0827 (16)
H221.00110.28480.42170.099*
C230.8441 (5)0.1876 (5)0.3704 (2)0.0763 (14)
H230.90210.13920.34960.092*
C240.6973 (4)0.1696 (4)0.35701 (18)0.0539 (10)
H240.65740.10710.32870.065*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.03997 (14)0.02032 (14)0.03523 (13)0.00202 (9)0.00883 (10)0.00077 (9)
N10.0582 (18)0.0239 (16)0.0461 (17)0.0021 (13)0.0214 (14)0.0053 (13)
O10.0616 (15)0.0190 (12)0.0444 (13)0.0018 (10)0.0183 (12)0.0007 (10)
O20.0845 (18)0.0317 (14)0.0465 (14)0.0005 (12)0.0325 (13)0.0098 (11)
O30.0843 (18)0.0149 (13)0.0638 (16)0.0025 (12)0.0149 (13)0.0018 (11)
C10.0432 (19)0.0241 (18)0.044 (2)0.0001 (14)0.0088 (15)0.0005 (15)
C20.055 (2)0.026 (2)0.0373 (18)0.0025 (15)0.0169 (16)0.0022 (14)
C30.0409 (17)0.0211 (17)0.0313 (16)0.0016 (13)0.0074 (14)0.0001 (13)
C40.053 (2)0.0275 (18)0.0359 (17)0.0011 (15)0.0164 (15)0.0021 (14)
C50.063 (2)0.0272 (19)0.0408 (19)0.0038 (17)0.0177 (17)0.0025 (15)
C60.051 (2)0.025 (2)0.0397 (19)0.0037 (15)0.0016 (16)0.0001 (14)
C70.0373 (18)0.036 (2)0.0374 (17)0.0049 (14)0.0093 (14)0.0082 (14)
C80.088 (3)0.037 (2)0.091 (3)0.012 (2)0.050 (3)0.019 (2)
C90.126 (4)0.064 (3)0.123 (5)0.024 (3)0.081 (4)0.050 (3)
C100.101 (4)0.118 (5)0.064 (3)0.035 (4)0.049 (3)0.039 (3)
C110.069 (3)0.109 (4)0.046 (2)0.004 (3)0.019 (2)0.015 (3)
C120.055 (2)0.061 (3)0.046 (2)0.007 (2)0.0134 (18)0.0083 (19)
C130.0410 (18)0.036 (2)0.0371 (18)0.0057 (15)0.0094 (14)0.0007 (15)
C140.066 (2)0.043 (2)0.046 (2)0.0071 (19)0.0045 (19)0.0033 (17)
C150.080 (3)0.072 (3)0.053 (3)0.025 (3)0.004 (2)0.018 (2)
C160.059 (3)0.138 (5)0.056 (3)0.015 (3)0.005 (2)0.013 (3)
C170.057 (3)0.127 (5)0.075 (3)0.028 (3)0.008 (2)0.007 (3)
C180.056 (2)0.069 (3)0.055 (2)0.015 (2)0.0026 (19)0.011 (2)
C190.0349 (18)0.039 (2)0.0415 (19)0.0014 (15)0.0082 (15)0.0077 (15)
C200.048 (2)0.057 (3)0.052 (2)0.0094 (19)0.0042 (18)0.0028 (19)
C210.066 (3)0.086 (4)0.073 (3)0.021 (3)0.012 (2)0.010 (3)
C220.048 (3)0.087 (4)0.113 (4)0.006 (3)0.018 (3)0.040 (3)
C230.057 (3)0.082 (4)0.096 (4)0.019 (3)0.029 (3)0.032 (3)
C240.055 (2)0.044 (2)0.064 (2)0.0082 (19)0.0164 (19)0.0053 (19)
Geometric parameters (Å, º) top
Sn1—C192.133 (3)C10—H100.9300
Sn1—C132.134 (3)C11—C121.388 (5)
Sn1—C72.137 (3)C11—H110.9300
Sn1—O12.150 (2)C12—H120.9300
Sn1—O3i2.356 (2)C13—C141.380 (5)
N1—C21.343 (4)C13—C181.391 (5)
N1—C61.385 (4)C14—C151.385 (5)
N1—H10.8600C14—H140.9300
C1—O11.292 (4)C15—C161.367 (6)
C1—O21.233 (4)C15—H150.9300
O3—C61.240 (4)C16—C171.363 (7)
O3—Sn1ii2.356 (2)C16—H160.9300
C1—C31.483 (4)C17—C181.380 (6)
C2—C31.357 (4)C17—H170.9300
C2—H20.9300C18—H180.9300
C3—C41.410 (4)C19—C201.384 (5)
C4—C51.353 (5)C19—C241.386 (4)
C4—H40.9300C20—C211.378 (5)
C5—C61.420 (5)C20—H200.9300
C5—H50.9300C21—C221.369 (7)
C7—C121.375 (5)C21—H210.9300
C7—C81.382 (5)C22—C231.343 (7)
C8—C91.385 (6)C22—H220.9300
C8—H80.9300C23—C241.391 (5)
C9—C101.361 (7)C23—H230.9300
C9—H90.9300C24—H240.9300
C10—C111.344 (7)
C19—Sn1—C13130.80 (12)C9—C10—H10119.8
C19—Sn1—C7115.76 (12)C10—C11—C12119.9 (5)
C13—Sn1—C7112.63 (12)C10—C11—H11120.1
C19—Sn1—O192.09 (10)C12—C11—H11120.1
C13—Sn1—O196.30 (11)C7—C12—C11121.5 (4)
C7—Sn1—O190.01 (10)C7—C12—H12119.3
C19—Sn1—O3i83.52 (11)C11—C12—H12119.3
C13—Sn1—O3i87.84 (11)C14—C13—C18117.1 (3)
C7—Sn1—O3i90.42 (10)C14—C13—Sn1124.5 (3)
O1—Sn1—O3i175.31 (9)C18—C13—Sn1118.2 (3)
C2—N1—C6124.9 (3)C13—C14—C15121.5 (4)
C2—N1—H1117.6C13—C14—H14119.2
C6—N1—H1117.6C15—C14—H14119.2
C1—O1—Sn1119.82 (19)C16—C15—C14120.0 (4)
C6—O3—Sn1ii164.4 (3)C16—C15—H15120.0
O2—C1—O1123.9 (3)C14—C15—H15120.0
O2—C1—C3121.0 (3)C17—C16—C15119.7 (4)
O1—C1—C3115.1 (3)C17—C16—H16120.1
N1—C2—C3121.2 (3)C15—C16—H16120.1
N1—C2—H2119.4C16—C17—C18120.4 (5)
C3—C2—H2119.4C16—C17—H17119.8
C2—C3—C4116.7 (3)C18—C17—H17119.8
C2—C3—C1120.1 (3)C17—C18—C13121.3 (4)
C4—C3—C1123.2 (3)C17—C18—H18119.4
C5—C4—C3121.7 (3)C13—C18—H18119.4
C5—C4—H4119.1C20—C19—C24118.4 (3)
C3—C4—H4119.1C20—C19—Sn1117.4 (2)
C4—C5—C6121.6 (3)C24—C19—Sn1124.2 (3)
C4—C5—H5119.2C21—C20—C19121.4 (4)
C6—C5—H5119.2C21—C20—H20119.3
O3—C6—N1119.1 (3)C19—C20—H20119.3
O3—C6—C5127.1 (3)C22—C21—C20118.6 (5)
N1—C6—C5113.8 (3)C22—C21—H21120.7
C12—C7—C8117.4 (3)C20—C21—H21120.7
C12—C7—Sn1122.5 (3)C23—C22—C21121.5 (5)
C8—C7—Sn1120.1 (3)C23—C22—H22119.2
C7—C8—C9120.8 (4)C21—C22—H22119.2
C7—C8—H8119.6C22—C23—C24120.4 (5)
C9—C8—H8119.6C22—C23—H23119.8
C10—C9—C8120.1 (5)C24—C23—H23119.8
C10—C9—H9119.9C19—C24—C23119.6 (4)
C8—C9—H9119.9C19—C24—H24120.2
C11—C10—C9120.3 (4)C23—C24—H24120.2
C11—C10—H10119.8
Symmetry codes: (i) x, y1, z; (ii) x, y+1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1···O2iii0.861.952.785 (4)165
Symmetry code: (iii) x+1, y+1/2, z+1/2.
 

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