(1Z,2Z)-1,2-Bis{2-[3,5-bis­(tri­fluoro­meth­yl)phen­yl]hydrazinyl­idene}-1,2-bis­(4-meth­oxy­phen­yl)ethane including an unknown solvate

The complete mol­ecule of the title compound, C₃₂H₂₂F₁₂N₄O₂, is generated by a crystallographic twofold axis aligned parallel to [010]. The F atoms of one of the CF₃ groups are disordered over three orientations in a 0.6: 0.2: 0.2 ratio. In the crystal, mol­ecules are linked by N—H...O hydrogen bonds, forming zigzag chains propagating along the a-axis direction. In addition, weak C—H...O and C—H...F bonds are observed. The contribution of the disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18] of PLATON. The solvent contribution is not included in the reported mol­ecular weight and density.

Key indicators

• Single-crystal synchrotron study
• T = 100 K
• Mean [sigma](C-C) = 0.005 Å
• Disorder in main residue
• R factor = 0.079
• wR factor = 0.215
• Data-to-parameter ratio = 16.8

checkCIF/PLATON results

No syntax errors found



Datablock: I


Alert level C
PLAT340_ALERT_3_C Low Bond Precision on  C-C Bonds ...............    0.00475 Ang.
PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ......      3.430 Check
PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ......      2.065 Check
PLAT911_ALERT_3_C Missing FCF Refl Between Thmin & STh/L=    0.600         23 Report
PLAT913_ALERT_3_C Missing # of Very Strong Reflections in FCF ....          5 Note
PLAT978_ALERT_2_C Number C-C Bonds with Positive Residual Density.          0 Info

Alert level G
ABSMU01_ALERT_1_G  Calculation of _exptl_absorpt_correction_mu
                not performed for this radiation type.
PLAT002_ALERT_2_G Number of Distance or Angle Restraints on AtSite         10 Note
PLAT014_ALERT_1_G N.O.K.   _shelx_fab_checksum Found in CIF ......     Please Check
PLAT092_ALERT_4_G Check: Wavelength Given is not Cu,Ga,Mo,Ag,In Ka    0.78790 Ang.
PLAT171_ALERT_4_G The CIF-Embedded .res File Contains EADP Records          1 Report
PLAT172_ALERT_4_G The CIF-Embedded .res File Contains DFIX Records          4 Report
PLAT230_ALERT_2_G Hirshfeld Test Diff for    F1       --C15      .        6.0 s.u.
PLAT230_ALERT_2_G Hirshfeld Test Diff for    F3       --C15      .        6.7 s.u.
PLAT230_ALERT_2_G Hirshfeld Test Diff for    F3'      --C15      .        9.7 s.u.
PLAT230_ALERT_2_G Hirshfeld Test Diff for    F3"      --C15      .        6.0 s.u.
PLAT242_ALERT_2_G Low    'MainMol' Ueq as Compared to Neighbors of        C15 Check
PLAT242_ALERT_2_G Low    'MainMol' Ueq as Compared to Neighbors of        C16 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F1         Constrained at        0.6 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F2         Constrained at        0.6 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F3         Constrained at        0.6 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F1'        Constrained at        0.2 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F1"        Constrained at        0.2 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F2'        Constrained at        0.2 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F2"        Constrained at        0.2 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F3'        Constrained at        0.2 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F3"        Constrained at        0.2 Check
PLAT301_ALERT_3_G Main Residue  Disorder ..............(Resd  1  )        12% Note
PLAT434_ALERT_2_G Short Inter HL..HL Contact F5       ..F3'              2.75 Ang.
                                              3/2-x,1/2+y,z  =      8_765 Check
PLAT434_ALERT_2_G Short Inter HL..HL Contact F5       ..F2'              2.82 Ang.
                                           -1/2+x,3/2-y,1-z  =      4_466 Check
PLAT434_ALERT_2_G Short Inter HL..HL Contact F6       ..F2"              2.72 Ang.
                                           -1/2+x,3/2-y,1-z  =      4_466 Check
PLAT605_ALERT_4_G Largest Solvent Accessible VOID in the Structure         95 A   3  
PLAT802_ALERT_4_G CIF Input Record(s) with more than 80 Characters          1 Info
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............         18 Note
PLAT869_ALERT_4_G ALERTS Related to the Use of SQUEEZE Suppressed           ! Info
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600          9 Note
PLAT933_ALERT_2_G Number of OMIT Records in Embedded .res File ...         15 Note

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   6 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  31 ALERT level G = General information/check it is not something unexpected

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  12 ALERT type 2 Indicator that the structure model may be wrong or deficient
   7 ALERT type 3 Indicator that the structure quality may be low
  16 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check


checkCIF publication errors

Alert level A
PUBL024_ALERT_1_A The number of authors is greater than 5.
              Please specify the role of each of the co-authors
              for your paper.

   1 ALERT level A = Data missing that is essential or data in wrong format
   0 ALERT level G = General alerts. Data that may be required is missing

---

Computing details

Data collection: Marccd (Doyle, 2011); cell refinement: iMosflm (Battye et al., 2011); data reduction: iMosflm (Battye et al., 2011); program(s) used to solve structure: SHELXT2016/6 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2016/6 (Sheldrick, 2015b); molecular graphics: ORTEP3for Windows (Farrugia, 2012); software used to prepare material for publication: PLATON (Spek, 2009).

(1Z,2Z)-1,2-Bis{2-[3,5-bis(trifluoromethyl)phenyl]hydrazinylidene}-1,2-bis(4-methoxyphenyl)ethane

Crystal data

C32H22F12N4O2	Dx = 1.408 Mg m^−3
Mr = 722.54	Synchrotron radiation, λ = 0.78790 Å
Orthorhombic, Pbcn	Cell parameters from 600 reflections
a = 13.479 (3) Å	θ = 2.0–30.0°
b = 11.213 (2) Å	µ = 0.17 mm^−1
c = 22.552 (5) Å	T = 100 K
V = 3408.5 (12) Å^3	Prism, colourless
Z = 4	0.18 × 0.12 × 0.10 mm
F(000) = 1464

Data collection

Rayonix SX165 CCD diffractometer	2478 reflections with I > 2σ(I)
/f scan	Rint = 0.062
Absorption correction: multi-scan (SCALA; Evans, 2006)	θmax = 31.0°, θmin = 2.0°
Tmin = 0.954, Tmax = 0.972	h = −17→17
34331 measured reflections	k = −14→14
3971 independent reflections	l = −29→29

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: mixed
R[F^2 > 2σ(F^2)] = 0.079	H atoms treated by a mixture of independent and constrained refinement
wR(F^2) = 0.215	w = 1/[σ^2(Fo^2) + (0.08P)^2 + 4P] where P = (Fo^2 + 2Fc^2)/3
S = 1.02	(Δ/σ)max < 0.001
3971 reflections	Δρmax = 0.52 e Å^−3
237 parameters	Δρmin = −0.56 e Å^−3
18 restraints	Extinction correction: SHELXL-2018/1 (Sheldrick 2015b), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: difference Fourier map	Extinction coefficient: 0.0077 (7)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. The H atoms of aromatic and methyl groups were placed in calculated positions (C—H = 0.95 and 0.98 Å, respectively) and refined using a riding model withU_iso= 1.2U_eq(C-aromatic) and 1.5U_eq(C-methyl).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
F1	0.8573 (3)	0.6496 (2)	0.57941 (18)	0.0832 (7)	0.6
F2	0.8431 (3)	0.5107 (4)	0.51521 (11)	0.0832 (7)	0.6
F3	0.8715 (3)	0.4684 (3)	0.60651 (16)	0.0832 (7)	0.6
F1'	0.8618 (8)	0.6207 (7)	0.6062 (4)	0.0832 (7)	0.2
F2'	0.8426 (8)	0.5731 (9)	0.5152 (2)	0.0832 (7)	0.2
F3'	0.8670 (8)	0.4374 (5)	0.5803 (5)	0.0832 (7)	0.2
F1"	0.8783 (8)	0.5085 (9)	0.6148 (4)	0.0832 (7)	0.2
F2"	0.8552 (7)	0.6378 (6)	0.5458 (5)	0.0832 (7)	0.2
F3"	0.8270 (8)	0.4531 (7)	0.5295 (4)	0.0832 (7)	0.2
F4	0.38927 (16)	0.6493 (2)	0.52250 (11)	0.0811 (7)
F5	0.47074 (18)	0.79502 (19)	0.55878 (11)	0.0837 (7)
F6	0.51490 (18)	0.7197 (2)	0.47565 (11)	0.0857 (7)
O1	0.80893 (17)	−0.1149 (2)	0.84552 (11)	0.0618 (6)
N1	0.59184 (19)	0.2977 (2)	0.70406 (12)	0.0541 (6)
N2	0.5315 (2)	0.3763 (2)	0.67618 (14)	0.0586 (7)
H2	0.474 (3)	0.370 (4)	0.6825 (17)	0.070*
C1	0.5545 (2)	0.2249 (3)	0.74170 (15)	0.0513 (7)
C2	0.6199 (2)	0.1371 (3)	0.77029 (15)	0.0543 (8)
C3	0.5875 (3)	0.0684 (3)	0.81721 (16)	0.0603 (8)
H3	0.5219	0.0796	0.8317	0.072*
C4	0.6476 (3)	−0.0165 (3)	0.84393 (17)	0.0627 (9)
H4	0.6235	−0.0628	0.8761	0.075*
C5	0.7433 (2)	−0.0327 (3)	0.82289 (15)	0.0558 (8)
C6	0.7778 (2)	0.0366 (3)	0.77612 (15)	0.0581 (8)
H6	0.8437	0.0263	0.7621	0.070*
C7	0.7173 (2)	0.1194 (3)	0.75029 (16)	0.0567 (8)
H7	0.7417	0.1659	0.7182	0.068*
C8	0.7725 (3)	−0.1975 (3)	0.88859 (17)	0.0694 (10)
H8A	0.7180	−0.2439	0.8714	0.104*
H8B	0.7485	−0.1538	0.9234	0.104*
H8C	0.8261	−0.2515	0.9005	0.104*
C9	0.5710 (2)	0.4527 (3)	0.63442 (15)	0.0564 (8)
C10	0.6731 (2)	0.4553 (3)	0.62320 (15)	0.0580 (8)
H10	0.7165	0.4028	0.6436	0.070*
C11	0.7098 (3)	0.5348 (3)	0.58237 (16)	0.0610 (8)
C12	0.6496 (3)	0.6129 (3)	0.55145 (16)	0.0627 (9)
H12	0.6768	0.6684	0.5241	0.075*
C13	0.5475 (3)	0.6076 (3)	0.56162 (16)	0.0595 (8)
C14	0.5086 (3)	0.5286 (3)	0.60240 (16)	0.0600 (8)
H14	0.4389	0.5259	0.6088	0.072*
C15	0.8195 (2)	0.5397 (2)	0.57040 (12)	0.0723 (10)
C16	0.4815 (3)	0.6924 (3)	0.52972 (18)	0.0669 (9)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
F1	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F2	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F3	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F1'	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F2'	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F3'	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F1"	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F2"	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F3"	0.0625 (9)	0.0989 (17)	0.0883 (16)	−0.0094 (12)	0.0081 (11)	0.0227 (13)
F4	0.0686 (13)	0.0683 (13)	0.1064 (17)	0.0058 (11)	−0.0214 (12)	0.0126 (12)
F5	0.0879 (15)	0.0552 (12)	0.1079 (17)	0.0166 (11)	−0.0122 (13)	−0.0034 (12)
F6	0.0849 (15)	0.0845 (16)	0.0877 (16)	0.0244 (13)	0.0063 (13)	0.0265 (12)
O1	0.0574 (13)	0.0502 (12)	0.0779 (15)	0.0070 (10)	−0.0006 (12)	0.0084 (11)
N1	0.0492 (13)	0.0475 (13)	0.0655 (16)	0.0000 (11)	0.0017 (12)	0.0036 (12)
N2	0.0458 (14)	0.0519 (15)	0.0781 (19)	0.0036 (12)	0.0052 (13)	0.0136 (13)
C1	0.0476 (15)	0.0424 (15)	0.0638 (18)	−0.0013 (13)	0.0054 (14)	−0.0024 (13)
C2	0.0501 (16)	0.0450 (15)	0.0677 (19)	−0.0006 (13)	0.0067 (15)	−0.0014 (14)
C3	0.0507 (17)	0.0526 (17)	0.078 (2)	0.0018 (14)	0.0086 (16)	0.0090 (16)
C4	0.0589 (19)	0.0563 (19)	0.073 (2)	0.0023 (16)	0.0088 (17)	0.0146 (16)
C5	0.0529 (17)	0.0455 (16)	0.0691 (19)	0.0036 (13)	−0.0009 (15)	0.0008 (15)
C6	0.0500 (17)	0.0546 (18)	0.070 (2)	0.0044 (14)	0.0083 (15)	0.0011 (16)
C7	0.0509 (17)	0.0499 (16)	0.0692 (19)	0.0015 (14)	0.0098 (15)	0.0064 (15)
C8	0.075 (2)	0.0582 (19)	0.075 (2)	0.0094 (18)	−0.0009 (19)	0.0113 (18)
C9	0.0537 (17)	0.0478 (16)	0.068 (2)	0.0013 (14)	0.0037 (15)	0.0055 (15)
C10	0.0511 (17)	0.0511 (17)	0.072 (2)	−0.0008 (14)	0.0014 (15)	0.0075 (15)
C11	0.0525 (17)	0.0577 (19)	0.073 (2)	−0.0002 (15)	0.0010 (16)	0.0095 (16)
C12	0.063 (2)	0.0541 (18)	0.070 (2)	−0.0006 (16)	0.0032 (17)	0.0106 (16)
C13	0.0610 (19)	0.0474 (16)	0.070 (2)	0.0041 (15)	−0.0047 (17)	0.0054 (15)
C14	0.0524 (17)	0.0525 (18)	0.075 (2)	0.0046 (14)	0.0000 (16)	0.0029 (16)
C15	0.063 (2)	0.071 (2)	0.083 (3)	−0.0008 (18)	0.0034 (19)	0.022 (2)
C16	0.065 (2)	0.0529 (18)	0.083 (3)	0.0053 (16)	−0.0003 (19)	0.0067 (18)

Geometric parameters (Å, º)

F1—C15	1.349 (3)	C3—C4	1.388 (5)
F2—C15	1.325 (3)	C3—H3	0.9500
F3—C15	1.339 (3)	C4—C5	1.386 (5)
F1'—C15	1.342 (3)	C4—H4	0.9500
F2'—C15	1.336 (3)	C5—C6	1.391 (5)
F3'—C15	1.333 (3)	C6—C7	1.366 (4)
F1"—C15	1.324 (3)	C6—H6	0.9500
F2"—C15	1.323 (3)	C7—H7	0.9500
F3"—C15	1.343 (3)	C8—H8A	0.9800
F4—C16	1.344 (4)	C8—H8B	0.9800
F5—C16	1.332 (4)	C8—H8C	0.9800
F6—C16	1.335 (4)	C9—C14	1.398 (5)
O1—C5	1.375 (4)	C9—C10	1.399 (4)
O1—C8	1.429 (4)	C10—C11	1.373 (5)
N1—C1	1.280 (4)	C10—H10	0.9500
N1—N2	1.355 (4)	C11—C12	1.383 (5)
N2—C9	1.380 (4)	C11—C15	1.504 (4)
N2—H2	0.79 (4)	C12—C13	1.396 (5)
C1—C2	1.471 (4)	C12—H12	0.9500
C1—C1^i	1.516 (6)	C13—C14	1.380 (5)
C2—C3	1.380 (4)	C13—C16	1.488 (5)
C2—C7	1.403 (4)	C14—H14	0.9500
C5—O1—C8	117.7 (3)	C9—C10—H10	120.3
C1—N1—N2	119.1 (3)	C10—C11—C12	122.5 (3)
N1—N2—C9	119.3 (3)	C10—C11—C15	119.9 (3)
N1—N2—H2	116 (3)	C12—C11—C15	117.6 (3)
C9—N2—H2	124 (3)	C11—C12—C13	118.0 (3)
N1—C1—C2	118.8 (3)	C11—C12—H12	121.0
N1—C1—C1^i	123.0 (3)	C13—C12—H12	121.0
C2—C1—C1^i	118.2 (3)	C14—C13—C12	120.7 (3)
C3—C2—C7	117.7 (3)	C14—C13—C16	120.4 (3)
C3—C2—C1	121.3 (3)	C12—C13—C16	118.8 (3)
C7—C2—C1	121.0 (3)	C13—C14—C9	120.4 (3)
C2—C3—C4	122.1 (3)	C13—C14—H14	119.8
C2—C3—H3	119.0	C9—C14—H14	119.8
C4—C3—H3	119.0	F2"—C15—F1"	108.6 (3)
C5—C4—C3	119.0 (3)	F3'—C15—F2'	106.6 (3)
C5—C4—H4	120.5	F2—C15—F3	107.4 (3)
C3—C4—H4	120.5	F3'—C15—F1'	106.1 (3)
O1—C5—C4	124.0 (3)	F2'—C15—F1'	105.7 (3)
O1—C5—C6	116.1 (3)	F2"—C15—F3"	106.6 (3)
C4—C5—C6	119.8 (3)	F1"—C15—F3"	106.5 (3)
C7—C6—C5	120.3 (3)	F2—C15—F1	106.0 (2)
C7—C6—H6	119.9	F3—C15—F1	104.8 (2)
C5—C6—H6	119.9	F2"—C15—C11	117.6 (5)
C6—C7—C2	121.2 (3)	F1"—C15—C11	116.3 (6)
C6—C7—H7	119.4	F2—C15—C11	113.3 (3)
C2—C7—H7	119.4	F3'—C15—C11	114.2 (5)
O1—C8—H8A	109.5	F2'—C15—C11	114.0 (5)
O1—C8—H8B	109.5	F3—C15—C11	112.5 (3)
H8A—C8—H8B	109.5	F1'—C15—C11	109.6 (5)
O1—C8—H8C	109.5	F3"—C15—C11	99.8 (5)
H8A—C8—H8C	109.5	F1—C15—C11	112.2 (3)
H8B—C8—H8C	109.5	F6—C16—F5	106.8 (3)
N2—C9—C14	119.9 (3)	F6—C16—F4	106.5 (3)
N2—C9—C10	121.1 (3)	F5—C16—F4	105.6 (3)
C14—C9—C10	119.0 (3)	F6—C16—C13	112.7 (3)
C11—C10—C9	119.3 (3)	F5—C16—C13	112.3 (3)
C11—C10—H10	120.3	F4—C16—C13	112.4 (3)
C1—N1—N2—C9	−178.3 (3)	C12—C13—C14—C9	0.2 (5)
N2—N1—C1—C2	177.9 (3)	C16—C13—C14—C9	−177.0 (3)
N2—N1—C1—C1^i	−2.0 (5)	N2—C9—C14—C13	178.3 (3)
N1—C1—C2—C3	170.4 (3)	C10—C9—C14—C13	−1.9 (5)
C1^i—C1—C2—C3	−9.6 (5)	C10—C11—C15—F2"	−159.7 (6)
N1—C1—C2—C7	−10.2 (5)	C12—C11—C15—F2"	19.7 (7)
C1^i—C1—C2—C7	169.7 (3)	C10—C11—C15—F1"	−28.4 (6)
C7—C2—C3—C4	−0.6 (5)	C12—C11—C15—F1"	151.0 (6)
C1—C2—C3—C4	178.7 (3)	C10—C11—C15—F2	116.9 (4)
C2—C3—C4—C5	0.1 (6)	C12—C11—C15—F2	−63.7 (4)
C8—O1—C5—C4	7.5 (5)	C10—C11—C15—F3'	27.3 (6)
C8—O1—C5—C6	−172.5 (3)	C12—C11—C15—F3'	−153.3 (6)
C3—C4—C5—O1	−179.4 (3)	C10—C11—C15—F2'	150.2 (6)
C3—C4—C5—C6	0.7 (5)	C12—C11—C15—F2'	−30.4 (6)
O1—C5—C6—C7	179.1 (3)	C10—C11—C15—F3	−5.2 (5)
C4—C5—C6—C7	−0.9 (5)	C12—C11—C15—F3	174.2 (3)
C5—C6—C7—C2	0.4 (5)	C10—C11—C15—F1'	−91.5 (6)
C3—C2—C7—C6	0.4 (5)	C12—C11—C15—F1'	87.9 (6)
C1—C2—C7—C6	−179.0 (3)	C10—C11—C15—F3"	85.6 (6)
N1—N2—C9—C14	175.6 (3)	C12—C11—C15—F3"	−95.0 (6)
N1—N2—C9—C10	−4.1 (5)	C10—C11—C15—F1	−123.2 (4)
N2—C9—C10—C11	−178.3 (3)	C12—C11—C15—F1	56.2 (4)
C14—C9—C10—C11	1.9 (5)	C14—C13—C16—F6	−149.8 (3)
C9—C10—C11—C12	−0.1 (6)	C12—C13—C16—F6	32.9 (5)
C9—C10—C11—C15	179.2 (3)	C14—C13—C16—F5	89.5 (4)
C10—C11—C12—C13	−1.6 (6)	C12—C13—C16—F5	−87.8 (4)
C15—C11—C12—C13	179.0 (3)	C14—C13—C16—F4	−29.5 (5)
C11—C12—C13—C14	1.6 (5)	C12—C13—C16—F4	153.3 (3)
C11—C12—C13—C16	178.8 (3)

Symmetry code: (i) −x+1, y, −z+3/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2···O1^ii	0.79 (4)	2.32 (4)	3.041 (4)	152 (4)
C3—H3···F1"^iii	0.95	2.42	3.279 (11)	151
C4—H4···F5^iv	0.95	2.51	3.439 (4)	165
C10—H10···F3	0.95	2.37	2.705 (5)	100
C14—H14···O1^ii	0.95	2.57	3.348 (5)	139

Symmetry codes: (ii) x−1/2, y+1/2, −z+3/2; (iii) x−1/2, y−1/2, −z+3/2; (iv) −x+1, y−1, −z+3/2.