Download citation
Download citation
link to html
The title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(di­methyl­amino)­ethyl­amino]quinoline ligand and another chloride ion to form a distorted fac-CdN3Cl3 octa­hedron. The ethanol mol­ecule is both an acceptor of an N—H...O and a donor of an O—H...Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314621001504/hb4375sup1.cif
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2414314621001504/hb4375Isup2.hkl
Contains datablock I

CCDC reference: 2062006

Key indicators

  • Single-crystal X-ray study
  • T = 296 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.036
  • wR factor = 0.086
  • Data-to-parameter ratio = 22.3

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT242_ALERT_2_C Low 'MainMol' Ueq as Compared to Neighbors of N4 Check PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors of C28 Check PLAT414_ALERT_2_C Short Intra D-H..H-X H1 ..H28A 1.95 Ang. x,y,z = 1_555 Check PLAT417_ALERT_2_C Short Inter D-H..H-D H1 ..H5 . 2.11 Ang. x,y,z = 1_555 Check PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ...... 2.450 Check
Alert level G PLAT007_ALERT_5_G Number of Unrefined Donor-H Atoms .............. 3 Report PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Cd1 --Cl3 . 8.2 s.u. PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Cd2 --Cl2 . 8.4 s.u. PLAT793_ALERT_4_G Model has Chirality at N2 (Centro SPGR) R Verify PLAT793_ALERT_4_G Model has Chirality at N5 (Centro SPGR) R Verify PLAT794_ALERT_5_G Tentative Bond Valency for Cd1 (II) . 1.97 Info PLAT794_ALERT_5_G Tentative Bond Valency for Cd2 (II) . 1.97 Info PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L= 0.600 1203 Note PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density. 1 Info
0 ALERT level A = Most likely a serious problem - resolve or explain 0 ALERT level B = A potentially serious problem, consider carefully 5 ALERT level C = Check. Ensure it is not caused by an omission or oversight 9 ALERT level G = General information/check it is not something unexpected 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 4 ALERT type 4 Improvement, methodology, query or suggestion 3 ALERT type 5 Informative message, check

Computing details top

Data collection: CrysAlis PRO (Rigaku OD, 2019); cell refinement: CrysAlis PRO (Rigaku OD, 2019); data reduction: CrysAlis PRO (Rigaku OD, 2019); program(s) used to solve structure: SHELXS (Sheldrick, 2008); program(s) used to refine structure: SHELXL (Sheldrick, 2015); molecular graphics: Mercury (Macrae et al., 2020); software used to prepare material for publication: WinGX (Farrugia, 2012).

Di-µ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate top
Crystal data top
[Cd2Cl4(C13H17N3)2]·C2H6OF(000) = 1688
Mr = 843.26Dx = 1.679 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 11.9747 (6) ÅCell parameters from 7578 reflections
b = 15.6483 (7) Åθ = 3.7–29.2°
c = 17.8804 (8) ŵ = 1.63 mm1
β = 95.292 (4)°T = 296 K
V = 3336.2 (3) Å3Block, colourless
Z = 40.16 × 0.13 × 0.10 mm
Data collection top
Rigaku Oxford Diffraction SuperNova, Dual, Cu at home/near, Atlas
diffractometer
5798 reflections with I > 2σ(I)
ω scansRint = 0.033
Absorption correction: gaussian
(CrysAlisPro (Rigaku OD, 2019)
θmax = 29.9°, θmin = 1.7°
Tmin = 0.897, Tmax = 1.000h = 1615
29581 measured reflectionsk = 2120
8400 independent reflectionsl = 2324
Refinement top
Refinement on F20 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.036H-atom parameters constrained
wR(F2) = 0.086 w = 1/[σ2(Fo2) + (0.0253P)2 + 3.3741P]
where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max = 0.002
8400 reflectionsΔρmax = 0.58 e Å3
376 parametersΔρmin = 0.86 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. The H atoms were positioned geometrically and refined using a riding model with Uiso(H) = 1.2Ueq(carrier) or 1.5Ueq(methyl C). The methyl groups were allowd to rotate, but not to tip, to best fit the electron density.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.5109 (3)0.4794 (3)0.09136 (19)0.0610 (11)
H1A0.4681660.5313600.0912530.092*
H1B0.4661520.4353550.0661150.092*
H1C0.5769270.4886980.0658370.092*
C20.6062 (4)0.3720 (3)0.1695 (3)0.0719 (13)
H2A0.6737190.3801470.1453200.108*
H2B0.5606830.3292610.1429970.108*
H2C0.6248540.3538910.2203850.108*
C30.6125 (3)0.5191 (3)0.2093 (2)0.0579 (11)
H3A0.6612880.5448470.1751990.069*
H3B0.6595580.4925500.2499000.069*
C40.5426 (3)0.5879 (2)0.2411 (2)0.0531 (10)
H4A0.5912260.6319400.2642660.064*
H4B0.4942310.6139840.2009420.064*
C50.5393 (3)0.5251 (2)0.36625 (17)0.0358 (7)
C60.6046 (3)0.5815 (3)0.40930 (19)0.0453 (9)
H60.6091770.6380540.3938750.054*
C70.6649 (3)0.5551 (3)0.4766 (2)0.0516 (10)
H70.7098230.5941590.5047510.062*
C80.6582 (3)0.4734 (3)0.50079 (19)0.0486 (9)
H80.6976950.4568320.5456880.058*
C90.5915 (3)0.4130 (2)0.45811 (18)0.0432 (9)
C100.5328 (3)0.4391 (2)0.38922 (17)0.0360 (7)
C110.5772 (4)0.3284 (3)0.4815 (2)0.0594 (11)
H110.6137260.3095280.5266410.071*
C120.5104 (4)0.2742 (3)0.4385 (2)0.0670 (12)
H120.4989950.2184740.4542220.080*
C130.4587 (3)0.3039 (3)0.3697 (2)0.0562 (10)
H130.4152850.2657680.3395540.067*
C140.0799 (4)0.4866 (3)0.3591 (3)0.0781 (14)
H14A0.0239020.4501260.3841800.117*
H14B0.1034800.4634560.3104560.117*
H14C0.1431770.4901970.3882440.117*
C150.0095 (4)0.6041 (4)0.4240 (2)0.0832 (15)
H15A0.0392180.6605680.4190810.125*
H15B0.0677100.5668750.4453840.125*
H15C0.0504150.6057410.4561120.125*
C160.1216 (3)0.6266 (3)0.3123 (3)0.0659 (12)
H16A0.1661480.5921890.2755860.079*
H16B0.1706640.6459490.3491160.079*
C170.0792 (3)0.7015 (3)0.2743 (2)0.0576 (10)
H17A0.0337430.7358320.3106020.069*
H17B0.1419750.7361120.2540280.069*
C180.0760 (3)0.6499 (2)0.14515 (19)0.0409 (8)
C190.1360 (3)0.7065 (3)0.0994 (2)0.0609 (11)
H190.1374000.7638650.1128890.073*
C200.1960 (4)0.6794 (3)0.0321 (2)0.0741 (14)
H200.2362050.7190860.0017620.089*
C210.1958 (4)0.5963 (3)0.0110 (2)0.0626 (12)
H210.2352480.5793640.0337620.075*
C220.1355 (3)0.5352 (2)0.05715 (19)0.0434 (8)
C230.0746 (3)0.5624 (2)0.12458 (18)0.0370 (7)
C240.1319 (4)0.4480 (3)0.0387 (2)0.0594 (11)
H240.1711480.4278850.0051020.071*
C250.0715 (4)0.3937 (3)0.0846 (3)0.0722 (13)
H250.0695240.3357040.0733340.087*
C260.0121 (4)0.4254 (3)0.1492 (2)0.0655 (12)
H260.0305610.3872450.1797470.079*
C270.1593 (5)0.7698 (4)0.0786 (3)0.112 (2)
H27A0.1277080.7137940.0822930.168*
H27B0.2071180.7708680.0383320.168*
H27C0.1000970.8108050.0687620.168*
C280.2249 (4)0.7913 (3)0.1491 (3)0.0789 (14)
H28A0.2779260.7455790.1620220.095*
H28B0.2674140.8428900.1419810.095*
N10.5435 (2)0.4533 (2)0.16910 (16)0.0465 (7)
N20.4735 (2)0.55133 (17)0.29757 (14)0.0367 (6)
H20.4193750.5946630.3103940.044*
N30.4685 (2)0.38266 (18)0.34557 (15)0.0415 (7)
N40.0328 (3)0.5724 (2)0.35048 (17)0.0490 (8)
N50.0111 (2)0.67654 (17)0.21276 (15)0.0393 (6)
H50.0339350.7260580.2006030.047*
N60.0127 (2)0.50655 (18)0.16967 (16)0.0434 (7)
Cd10.37193 (2)0.43475 (2)0.23492 (2)0.03457 (7)
Cd20.11394 (2)0.56817 (2)0.26458 (2)0.03612 (8)
Cl10.32762 (8)0.30005 (6)0.16560 (5)0.0542 (2)
Cl20.25905 (7)0.55385 (6)0.15909 (5)0.0450 (2)
Cl30.19490 (7)0.42895 (6)0.32090 (5)0.0450 (2)
Cl40.24434 (8)0.67656 (6)0.33611 (5)0.0487 (2)
O10.1615 (3)0.8033 (2)0.20690 (19)0.0813 (9)
H10.1895220.7777560.2440200.122*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.056 (2)0.094 (3)0.032 (2)0.003 (2)0.0001 (17)0.005 (2)
C20.052 (3)0.088 (4)0.076 (3)0.021 (2)0.012 (2)0.004 (3)
C30.040 (2)0.096 (3)0.037 (2)0.020 (2)0.0032 (16)0.006 (2)
C40.064 (3)0.053 (2)0.039 (2)0.024 (2)0.0120 (17)0.0115 (18)
C50.0321 (17)0.046 (2)0.0283 (16)0.0012 (15)0.0003 (13)0.0006 (15)
C60.044 (2)0.053 (2)0.0384 (19)0.0063 (17)0.0016 (15)0.0013 (17)
C70.043 (2)0.074 (3)0.037 (2)0.0076 (19)0.0017 (15)0.0125 (19)
C80.039 (2)0.074 (3)0.0306 (18)0.0038 (19)0.0061 (14)0.0032 (19)
C90.0387 (19)0.058 (2)0.0330 (18)0.0123 (17)0.0006 (14)0.0030 (17)
C100.0304 (16)0.045 (2)0.0320 (17)0.0055 (15)0.0006 (12)0.0019 (15)
C110.069 (3)0.064 (3)0.043 (2)0.014 (2)0.0100 (18)0.014 (2)
C120.091 (3)0.050 (3)0.058 (3)0.005 (2)0.006 (2)0.018 (2)
C130.066 (3)0.044 (2)0.056 (2)0.000 (2)0.0108 (19)0.0013 (19)
C140.074 (3)0.073 (3)0.091 (4)0.016 (3)0.030 (3)0.008 (3)
C150.083 (3)0.113 (4)0.054 (3)0.012 (3)0.012 (2)0.012 (3)
C160.051 (2)0.075 (3)0.073 (3)0.013 (2)0.014 (2)0.003 (2)
C170.063 (3)0.049 (2)0.061 (2)0.016 (2)0.008 (2)0.008 (2)
C180.0350 (18)0.039 (2)0.047 (2)0.0029 (15)0.0057 (15)0.0014 (16)
C190.069 (3)0.041 (2)0.067 (3)0.012 (2)0.020 (2)0.004 (2)
C200.085 (3)0.066 (3)0.064 (3)0.024 (3)0.032 (2)0.005 (2)
C210.067 (3)0.066 (3)0.050 (2)0.009 (2)0.0244 (19)0.002 (2)
C220.0394 (19)0.048 (2)0.0405 (19)0.0004 (16)0.0075 (15)0.0035 (17)
C230.0293 (16)0.042 (2)0.0380 (18)0.0012 (14)0.0040 (13)0.0002 (15)
C240.070 (3)0.055 (3)0.049 (2)0.006 (2)0.0152 (19)0.014 (2)
C250.098 (4)0.041 (2)0.072 (3)0.003 (2)0.029 (3)0.015 (2)
C260.085 (3)0.040 (2)0.066 (3)0.008 (2)0.025 (2)0.005 (2)
C270.116 (5)0.124 (6)0.096 (4)0.015 (4)0.008 (4)0.006 (4)
C280.080 (3)0.079 (4)0.077 (3)0.006 (3)0.005 (3)0.008 (3)
N10.0359 (16)0.064 (2)0.0386 (16)0.0012 (14)0.0001 (12)0.0056 (15)
N20.0389 (15)0.0333 (15)0.0370 (15)0.0010 (12)0.0011 (11)0.0032 (12)
N30.0457 (17)0.0372 (17)0.0401 (16)0.0039 (13)0.0053 (12)0.0035 (13)
N40.0506 (18)0.051 (2)0.0455 (18)0.0058 (15)0.0060 (14)0.0003 (15)
N50.0423 (16)0.0299 (15)0.0442 (16)0.0006 (12)0.0046 (12)0.0035 (13)
N60.0494 (18)0.0318 (16)0.0458 (17)0.0027 (13)0.0123 (13)0.0022 (13)
Cd10.03461 (13)0.03321 (14)0.03431 (13)0.00004 (10)0.00531 (9)0.00115 (10)
Cd20.03520 (14)0.03407 (14)0.03719 (14)0.00278 (10)0.00686 (10)0.00189 (11)
Cl10.0645 (6)0.0397 (5)0.0574 (6)0.0067 (4)0.0004 (4)0.0091 (4)
Cl20.0485 (5)0.0479 (5)0.0370 (4)0.0107 (4)0.0046 (4)0.0047 (4)
Cl30.0452 (5)0.0395 (5)0.0501 (5)0.0074 (4)0.0039 (4)0.0100 (4)
Cl40.0523 (5)0.0419 (5)0.0483 (5)0.0069 (4)0.0145 (4)0.0010 (4)
O10.080 (2)0.079 (2)0.082 (2)0.0113 (19)0.0056 (18)0.0220 (19)
Geometric parameters (Å, º) top
C1—N11.467 (4)C16—H16B0.9700
C1—H1A0.9600C17—N51.481 (4)
C1—H1B0.9600C17—H17A0.9700
C1—H1C0.9600C17—H17B0.9700
C2—N11.476 (5)C18—C191.364 (5)
C2—H2A0.9600C18—C231.418 (5)
C2—H2B0.9600C18—N51.437 (4)
C2—H2C0.9600C19—C201.409 (5)
C3—N11.467 (5)C19—H190.9300
C3—C41.508 (6)C20—C211.354 (6)
C3—H3A0.9700C20—H200.9300
C3—H3B0.9700C21—C221.417 (5)
C4—N21.478 (4)C21—H210.9300
C4—H4A0.9700C22—C241.405 (5)
C4—H4B0.9700C22—C231.416 (4)
C5—C61.368 (5)C23—N61.361 (4)
C5—C101.412 (5)C24—C251.345 (6)
C5—N21.455 (4)C24—H240.9300
C6—C71.407 (5)C25—C261.390 (5)
C6—H60.9300C25—H250.9300
C7—C81.356 (6)C26—N61.322 (5)
C7—H70.9300C26—H260.9300
C8—C91.414 (5)C27—C281.462 (7)
C8—H80.9300C27—H27A0.9600
C9—C111.404 (5)C27—H27B0.9600
C9—C101.421 (4)C27—H27C0.9600
C10—N31.368 (4)C28—O11.350 (5)
C11—C121.356 (6)C28—H28A0.9700
C11—H110.9300C28—H28B0.9700
C12—C131.404 (5)N1—Cd12.477 (3)
C12—H120.9300N2—Cd12.411 (3)
C13—N31.315 (5)N2—H20.9800
C13—H130.9300N3—Cd12.344 (3)
C14—N41.469 (5)N4—Cd22.439 (3)
C14—H14A0.9600N5—Cd22.392 (3)
C14—H14B0.9600N5—H50.9800
C14—H14C0.9600N6—Cd22.374 (3)
C15—N41.452 (5)Cd1—Cl12.4777 (9)
C15—H15A0.9600Cd1—Cl22.6079 (9)
C15—H15B0.9600Cd1—Cl32.7326 (9)
C15—H15C0.9600Cd2—Cl32.5535 (9)
C16—C171.468 (6)Cd2—Cl42.5656 (9)
C16—N41.478 (5)Cd2—Cl22.6893 (9)
C16—H16A0.9700O1—H10.8200
N1—C1—H1A109.5C23—C22—C21119.1 (3)
N1—C1—H1B109.5N6—C23—C22121.3 (3)
H1A—C1—H1B109.5N6—C23—C18119.0 (3)
N1—C1—H1C109.5C22—C23—C18119.6 (3)
H1A—C1—H1C109.5C25—C24—C22119.8 (4)
H1B—C1—H1C109.5C25—C24—H24120.1
N1—C2—H2A109.5C22—C24—H24120.1
N1—C2—H2B109.5C24—C25—C26119.1 (4)
H2A—C2—H2B109.5C24—C25—H25120.5
N1—C2—H2C109.5C26—C25—H25120.5
H2A—C2—H2C109.5N6—C26—C25123.9 (4)
H2B—C2—H2C109.5N6—C26—H26118.1
N1—C3—C4112.3 (3)C25—C26—H26118.1
N1—C3—H3A109.2C28—C27—H27A109.5
C4—C3—H3A109.2C28—C27—H27B109.5
N1—C3—H3B109.2H27A—C27—H27B109.5
C4—C3—H3B109.2C28—C27—H27C109.5
H3A—C3—H3B107.9H27A—C27—H27C109.5
N2—C4—C3110.3 (3)H27B—C27—H27C109.5
N2—C4—H4A109.6O1—C28—C27113.4 (5)
C3—C4—H4A109.6O1—C28—H28A108.9
N2—C4—H4B109.6C27—C28—H28A108.9
C3—C4—H4B109.6O1—C28—H28B108.9
H4A—C4—H4B108.1C27—C28—H28B108.9
C6—C5—C10119.7 (3)H28A—C28—H28B107.7
C6—C5—N2122.0 (3)C3—N1—C1110.9 (3)
C10—C5—N2118.3 (3)C3—N1—C2109.8 (3)
C5—C6—C7120.9 (4)C1—N1—C2109.6 (3)
C5—C6—H6119.5C3—N1—Cd1107.7 (2)
C7—C6—H6119.5C1—N1—Cd1108.8 (2)
C8—C7—C6120.6 (4)C2—N1—Cd1109.9 (2)
C8—C7—H7119.7C5—N2—C4113.1 (3)
C6—C7—H7119.7C5—N2—Cd1112.9 (2)
C7—C8—C9120.4 (3)C4—N2—Cd1105.4 (2)
C7—C8—H8119.8C5—N2—H2108.4
C9—C8—H8119.8C4—N2—H2108.4
C11—C9—C8123.2 (3)Cd1—N2—H2108.4
C11—C9—C10117.7 (3)C13—N3—C10118.7 (3)
C8—C9—C10119.1 (4)C13—N3—Cd1123.4 (2)
N3—C10—C5119.5 (3)C10—N3—Cd1117.7 (2)
N3—C10—C9121.1 (3)C15—N4—C14108.8 (4)
C5—C10—C9119.3 (3)C15—N4—C16113.4 (4)
C12—C11—C9120.2 (4)C14—N4—C16107.8 (3)
C12—C11—H11119.9C15—N4—Cd2111.6 (3)
C9—C11—H11119.9C14—N4—Cd2110.3 (2)
C11—C12—C13118.6 (4)C16—N4—Cd2104.7 (2)
C11—C12—H12120.7C18—N5—C17114.2 (3)
C13—C12—H12120.7C18—N5—Cd2113.0 (2)
N3—C13—C12123.5 (4)C17—N5—Cd2105.5 (2)
N3—C13—H13118.2C18—N5—H5108.0
C12—C13—H13118.2C17—N5—H5108.0
N4—C14—H14A109.5Cd2—N5—H5108.0
N4—C14—H14B109.5C26—N6—C23118.0 (3)
H14A—C14—H14B109.5C26—N6—Cd2124.7 (2)
N4—C14—H14C109.5C23—N6—Cd2116.1 (2)
H14A—C14—H14C109.5N3—Cd1—N271.48 (9)
H14B—C14—H14C109.5N3—Cd1—N194.32 (10)
N4—C15—H15A109.5N2—Cd1—N174.16 (10)
N4—C15—H15B109.5N3—Cd1—Cl1101.11 (7)
H15A—C15—H15B109.5N2—Cd1—Cl1162.14 (7)
N4—C15—H15C109.5N1—Cd1—Cl190.61 (8)
H15A—C15—H15C109.5N3—Cd1—Cl2151.53 (7)
H15B—C15—H15C109.5N2—Cd1—Cl285.18 (7)
C17—C16—N4114.0 (3)N1—Cd1—Cl294.71 (7)
C17—C16—H16A108.8Cl1—Cd1—Cl2105.73 (3)
N4—C16—H16A108.8N3—Cd1—Cl382.05 (7)
C17—C16—H16B108.8N2—Cd1—Cl398.52 (7)
N4—C16—H16B108.8N1—Cd1—Cl3172.59 (7)
H16A—C16—H16B107.6Cl1—Cd1—Cl396.41 (3)
C16—C17—N5111.8 (3)Cl2—Cd1—Cl385.67 (3)
C16—C17—H17A109.3N6—Cd2—N571.04 (9)
N5—C17—H17A109.3N6—Cd2—N490.64 (10)
C16—C17—H17B109.3N5—Cd2—N476.30 (10)
N5—C17—H17B109.3N6—Cd2—Cl397.45 (7)
H17A—C17—H17B107.9N5—Cd2—Cl3163.54 (7)
C19—C18—C23119.3 (3)N4—Cd2—Cl392.51 (8)
C19—C18—N5122.0 (3)N6—Cd2—Cl4160.78 (7)
C23—C18—N5118.7 (3)N5—Cd2—Cl493.15 (7)
C18—C19—C20121.0 (4)N4—Cd2—Cl496.26 (8)
C18—C19—H19119.5Cl3—Cd2—Cl4100.13 (3)
C20—C19—H19119.5N6—Cd2—Cl282.90 (8)
C21—C20—C19120.9 (4)N5—Cd2—Cl2102.09 (7)
C21—C20—H20119.5N4—Cd2—Cl2173.50 (8)
C19—C20—H20119.5Cl3—Cd2—Cl287.66 (3)
C20—C21—C22120.0 (4)Cl4—Cd2—Cl290.11 (3)
C20—C21—H21120.0Cd1—Cl2—Cd291.85 (3)
C22—C21—H21120.0Cd2—Cl3—Cd192.05 (3)
C24—C22—C23117.9 (3)C28—O1—H1109.5
C24—C22—C21123.0 (3)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N2—H2···Cl40.982.533.492 (3)166
N5—H5···O10.981.942.874 (4)158
O1—H1···Cl40.822.333.136 (3)166
 

Follow IUCrData
Sign up for e-alerts
Follow IUCrData on Twitter
Follow us on facebook
Sign up for RSS feeds