Crystal structure and Hirshfeld surface analysis of ethyl 2-[9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,8-dioxo-2,3,4,4a,5,6,7,8a,9,9a,10,10a-dodeca­hydro­acridin-10-yl]acetate

The mol­ecular conformation is stabilized by an intra­molecular O—H...O hydrogen bond between the hy­droxy substituent on the benzene ring and one of the carbonyl groups of the acridinedione unit.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.002 Å
• Disorder in main residue
• R factor = 0.045
• wR factor = 0.126
• Data-to-parameter ratio = 14.8

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT410_ALERT_2_C Short Intra H...H Contact  H12A     ..H14A     .       1.97 Ang.
                                                      x,y,z  =      1_555 Check
PLAT480_ALERT_4_C Long H...A H-Bond Reported H14B     ..O2       .       2.66 Ang.
PLAT911_ALERT_3_C Missing FCF Refl Between Thmin & STh/L=    0.600          3 Report

Alert level G
PLAT007_ALERT_5_G Number of Unrefined Donor-H Atoms ..............          1 Report
PLAT171_ALERT_4_G The CIF-Embedded .res File Contains EADP Records          2 Report
PLAT230_ALERT_2_G Hirshfeld Test Diff for    O3A      --C15      .       12.5 s.u.
PLAT230_ALERT_2_G Hirshfeld Test Diff for    C16      --C17A     .       11.5 s.u.
PLAT301_ALERT_3_G Main Residue  Disorder ..............(Resd  1  )         6% Note
PLAT367_ALERT_2_G Long?  C(sp?)-C(sp?) Bond  C14      - C15      .       1.51 Ang.
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600         81 Note
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.         19 Info

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   3 ALERT level C = Check. Ensure it is not caused by an omission or oversight
   8 ALERT level G = General information/check it is not something unexpected

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion
   1 ALERT type 5 Informative message, check


checkCIF publication errors

Alert level A
PUBL024_ALERT_1_A The number of authors is greater than 5.
              Please specify the role of each of the co-authors
              for your paper.

   1 ALERT level A = Data missing that is essential or data in wrong format
   0 ALERT level G = General alerts. Data that may be required is missing

---

Computing details

Data collection: CrysAlis PRO (Rigaku OD, 2015); cell refinement: CrysAlis PRO (Rigaku OD, 2015); data reduction: CrysAlis PRO (Rigaku OD, 2015); program(s) used to solve structure: ShelXT (Sheldrick, 2015b); program(s) used to refine structure: SHELXL (Sheldrick, 2015a); molecular graphics: OLEX2 (Dolomanov et al., 2009); software used to prepare material for publication: OLEX2 (Dolomanov et al., 2009).

Ethyl 2-[9-(2-hydroxyphenyl)-3,3,6,6-tetramethyl-1,8-dioxo-2,3,4,4a,5,6,7,8a,9,9a,10,10a-dodecahydroacridin-10-yl]acetate

Crystal data

C27H33NO5	F(000) = 968
Mr = 451.54	Dx = 1.229 Mg m^−3
Monoclinic, P21/n	Cu Kα radiation, λ = 1.54184 Å
a = 9.5289 (2) Å	Cell parameters from 3784 reflections
b = 18.6653 (5) Å	θ = 4.0–71.4°
c = 13.8046 (3) Å	µ = 0.68 mm^−1
β = 96.410 (2)°	T = 173 K
V = 2439.93 (10) Å^3	Plate, yellow
Z = 4	0.48 × 0.22 × 0.08 mm

Data collection

Rigaku Oxford Diffraction EOS diffractometer	4648 independent reflections
Radiation source: fine-focus sealed X-ray tube, Enhance (Cu) X-ray Source	3949 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.029
Detector resolution: 16.0416 pixels mm^-1	θmax = 71.2°, θmin = 4.0°
ω scans	h = −11→11
Absorption correction: multi-scan (CrysalisPro; Rigaku OD, 2015)	k = −22→14
Tmin = 0.861, Tmax = 1.000	l = −16→16
9527 measured reflections

Refinement

Refinement on F^2	Primary atom site location: dual
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.045	H-atom parameters constrained
wR(F^2) = 0.126	w = 1/[σ^2(Fo^2) + (0.0643P)^2 + 0.6477P] where P = (Fo^2 + 2Fc^2)/3
S = 1.04	(Δ/σ)max < 0.001
4648 reflections	Δρmax = 0.27 e Å^−3
313 parameters	Δρmin = −0.23 e Å^−3
0 restraints

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
O1	0.65518 (12)	0.22713 (7)	0.50403 (8)	0.0373 (3)
O2	0.21715 (14)	0.36821 (7)	0.51857 (8)	0.0426 (3)
O3	0.3445 (5)	0.11473 (19)	0.83632 (16)	0.0636 (11)	0.777 (9)
O3A	0.2813 (17)	0.1388 (6)	0.8394 (7)	0.0636 (11)	0.223 (9)
O4	0.35606 (14)	0.14006 (6)	0.99586 (9)	0.0406 (3)
O5	0.41985 (13)	0.19489 (7)	0.39430 (8)	0.0389 (3)
H5	0.4887	0.2122	0.4300	0.058*
N1	0.44568 (13)	0.24991 (6)	0.79603 (8)	0.0236 (2)
C1	0.54686 (14)	0.22154 (7)	0.74277 (10)	0.0228 (3)
C2	0.66871 (16)	0.18305 (8)	0.79873 (11)	0.0292 (3)
H2A	0.6309	0.1464	0.8407	0.035*
H2B	0.7234	0.2179	0.8419	0.035*
C3	0.76892 (16)	0.14645 (9)	0.73461 (12)	0.0328 (3)
C4	0.79512 (16)	0.19849 (9)	0.65285 (12)	0.0356 (4)
H4A	0.8424	0.2421	0.6814	0.043*
H4B	0.8587	0.1758	0.6098	0.043*
C5	0.65908 (16)	0.21917 (8)	0.59366 (11)	0.0286 (3)
C6	0.53718 (15)	0.23162 (8)	0.64433 (10)	0.0245 (3)
C7	0.40195 (15)	0.25806 (8)	0.58758 (10)	0.0244 (3)
H7	0.4283	0.2880	0.5323	0.029*
C8	0.32755 (14)	0.30588 (7)	0.65354 (10)	0.0237 (3)
C9	0.22950 (16)	0.35939 (8)	0.60657 (11)	0.0291 (3)
C10	0.14223 (16)	0.40152 (9)	0.67124 (12)	0.0323 (3)
H10A	0.0581	0.3731	0.6833	0.039*
H10B	0.1091	0.4463	0.6376	0.039*
C11	0.22671 (16)	0.42010 (8)	0.76873 (11)	0.0280 (3)
C12	0.27846 (15)	0.34965 (8)	0.81805 (10)	0.0263 (3)
H12A	0.3461	0.3608	0.8758	0.032*
H12B	0.1970	0.3245	0.8411	0.032*
C13	0.34886 (14)	0.30040 (7)	0.75185 (10)	0.0222 (3)
C14	0.43949 (15)	0.22835 (8)	0.89738 (10)	0.0256 (3)
H14A	0.3858	0.2646	0.9304	0.031*
H14B	0.5365	0.2265	0.9315	0.031*
C15	0.37019 (19)	0.15605 (9)	0.90423 (12)	0.0368 (4)
C16	0.2856 (3)	0.07304 (12)	1.01388 (17)	0.0641 (7)
H16A	0.3553	0.0335	1.0218	0.077*	0.725 (5)
H16B	0.2146	0.0615	0.9581	0.077*	0.725 (5)
H16C	0.2872	0.0420	0.9559	0.077*	0.275 (5)
H16D	0.3405	0.0485	1.0693	0.077*	0.275 (5)
C17	0.2157 (4)	0.08124 (19)	1.1040 (3)	0.0665 (9)	0.725 (5)
H17A	0.2875	0.0880	1.1598	0.100*	0.725 (5)
H17B	0.1604	0.0381	1.1141	0.100*	0.725 (5)
H17C	0.1530	0.1230	1.0976	0.100*	0.725 (5)
C17A	0.1551 (11)	0.0790 (5)	1.0331 (8)	0.0665 (9)	0.275 (5)
H17D	0.1499	0.1142	1.0853	0.100*	0.275 (5)
H17E	0.1217	0.0324	1.0541	0.100*	0.275 (5)
H17F	0.0956	0.0947	0.9745	0.100*	0.275 (5)
C18	0.30828 (15)	0.19663 (8)	0.54418 (10)	0.0258 (3)
C19	0.32270 (16)	0.16932 (9)	0.45105 (11)	0.0307 (3)
C20	0.23375 (19)	0.11504 (10)	0.41156 (13)	0.0405 (4)
H20	0.2428	0.0976	0.3479	0.049*
C21	0.13242 (18)	0.08647 (9)	0.46441 (14)	0.0410 (4)
H21	0.0723	0.0493	0.4371	0.049*
C22	0.11833 (17)	0.11164 (9)	0.55659 (13)	0.0356 (4)
H22	0.0494	0.0916	0.5933	0.043*
C23	0.20564 (16)	0.16652 (8)	0.59556 (11)	0.0295 (3)
H23	0.1949	0.1839	0.6590	0.035*
C24	0.7045 (2)	0.07682 (10)	0.69143 (15)	0.0469 (4)
H24A	0.6894	0.0436	0.7443	0.070*
H24B	0.7688	0.0550	0.6493	0.070*
H24C	0.6139	0.0872	0.6531	0.070*
C25	0.9082 (2)	0.12973 (11)	0.79789 (14)	0.0468 (4)
H25A	0.9533	0.1746	0.8214	0.070*
H25B	0.9713	0.1036	0.7590	0.070*
H25C	0.8887	0.1003	0.8537	0.070*
C26	0.13320 (19)	0.45952 (9)	0.83469 (13)	0.0405 (4)
H26A	0.0495	0.4305	0.8424	0.061*
H26B	0.1038	0.5057	0.8052	0.061*
H26C	0.1864	0.4677	0.8987	0.061*
C27	0.35163 (17)	0.46822 (8)	0.75087 (12)	0.0340 (3)
H27A	0.4061	0.4799	0.8133	0.051*
H27B	0.3163	0.5125	0.7187	0.051*
H27C	0.4123	0.4431	0.7092	0.051*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
O1	0.0375 (6)	0.0503 (7)	0.0266 (6)	−0.0016 (5)	0.0144 (4)	−0.0032 (5)
O2	0.0548 (7)	0.0469 (7)	0.0249 (6)	0.0155 (6)	−0.0006 (5)	0.0006 (5)
O3	0.114 (3)	0.0437 (16)	0.0360 (8)	−0.0364 (17)	0.0192 (12)	−0.0122 (10)
O3A	0.114 (3)	0.0437 (16)	0.0360 (8)	−0.0364 (17)	0.0192 (12)	−0.0122 (10)
O4	0.0571 (7)	0.0352 (6)	0.0317 (6)	−0.0098 (5)	0.0158 (5)	0.0055 (5)
O5	0.0448 (6)	0.0485 (7)	0.0245 (5)	0.0025 (5)	0.0080 (5)	−0.0075 (5)
N1	0.0288 (6)	0.0242 (6)	0.0189 (5)	0.0020 (5)	0.0069 (4)	−0.0005 (4)
C1	0.0248 (6)	0.0203 (6)	0.0241 (7)	−0.0020 (5)	0.0064 (5)	−0.0023 (5)
C2	0.0305 (7)	0.0316 (7)	0.0257 (7)	0.0041 (6)	0.0035 (6)	−0.0014 (6)
C3	0.0324 (8)	0.0323 (8)	0.0344 (8)	0.0071 (6)	0.0065 (6)	−0.0027 (6)
C4	0.0290 (8)	0.0417 (9)	0.0382 (9)	0.0041 (6)	0.0125 (6)	−0.0014 (7)
C5	0.0309 (7)	0.0280 (7)	0.0287 (7)	−0.0025 (6)	0.0109 (6)	−0.0038 (6)
C6	0.0269 (7)	0.0244 (7)	0.0233 (7)	−0.0005 (5)	0.0073 (5)	−0.0025 (5)
C7	0.0303 (7)	0.0246 (7)	0.0190 (6)	0.0010 (6)	0.0065 (5)	−0.0012 (5)
C8	0.0260 (6)	0.0226 (7)	0.0233 (7)	−0.0010 (5)	0.0059 (5)	−0.0021 (5)
C9	0.0312 (7)	0.0294 (7)	0.0261 (7)	0.0006 (6)	0.0010 (6)	−0.0025 (6)
C10	0.0304 (7)	0.0318 (8)	0.0345 (8)	0.0063 (6)	0.0028 (6)	−0.0016 (6)
C11	0.0327 (7)	0.0243 (7)	0.0277 (7)	0.0043 (6)	0.0072 (6)	−0.0017 (6)
C12	0.0323 (7)	0.0241 (7)	0.0236 (7)	0.0020 (6)	0.0088 (5)	−0.0016 (5)
C13	0.0245 (6)	0.0195 (6)	0.0232 (7)	−0.0018 (5)	0.0064 (5)	−0.0010 (5)
C14	0.0325 (7)	0.0267 (7)	0.0187 (6)	0.0019 (6)	0.0068 (5)	0.0003 (5)
C15	0.0492 (9)	0.0353 (8)	0.0269 (8)	−0.0090 (7)	0.0085 (6)	0.0001 (6)
C16	0.0987 (18)	0.0460 (12)	0.0520 (12)	−0.0294 (12)	0.0280 (12)	0.0052 (9)
C17	0.082 (2)	0.0543 (16)	0.070 (2)	−0.0088 (15)	0.0384 (17)	0.0188 (17)
C17A	0.082 (2)	0.0543 (16)	0.070 (2)	−0.0088 (15)	0.0384 (17)	0.0188 (17)
C18	0.0286 (7)	0.0242 (7)	0.0239 (7)	0.0051 (5)	−0.0003 (5)	−0.0014 (5)
C19	0.0338 (8)	0.0323 (8)	0.0256 (7)	0.0080 (6)	0.0015 (6)	−0.0029 (6)
C20	0.0479 (9)	0.0391 (9)	0.0326 (8)	0.0063 (7)	−0.0039 (7)	−0.0137 (7)
C21	0.0388 (9)	0.0307 (8)	0.0503 (10)	0.0005 (7)	−0.0097 (7)	−0.0093 (7)
C22	0.0344 (8)	0.0281 (8)	0.0434 (9)	0.0008 (6)	−0.0001 (7)	0.0019 (7)
C23	0.0328 (7)	0.0274 (7)	0.0280 (7)	0.0026 (6)	0.0021 (6)	−0.0002 (6)
C24	0.0588 (11)	0.0312 (9)	0.0514 (11)	0.0062 (8)	0.0094 (8)	−0.0059 (8)
C25	0.0405 (10)	0.0533 (11)	0.0463 (10)	0.0185 (8)	0.0037 (8)	−0.0019 (8)
C26	0.0469 (10)	0.0344 (8)	0.0418 (9)	0.0118 (7)	0.0124 (7)	−0.0053 (7)
C27	0.0409 (8)	0.0247 (7)	0.0363 (8)	−0.0019 (6)	0.0034 (6)	0.0005 (6)

Geometric parameters (Å, º)

O1—C5	1.2426 (19)	C12—C13	1.5057 (18)
O2—C9	1.2185 (19)	C14—H14A	0.9900
O3—C15	1.217 (3)	C14—H14B	0.9900
O3A—C15	1.205 (11)	C14—C15	1.510 (2)
O4—C15	1.321 (2)	C16—H16A	0.9900
O4—C16	1.454 (2)	C16—H16B	0.9900
O5—H5	0.8400	C16—H16C	0.9900
O5—C19	1.364 (2)	C16—H16D	0.9900
N1—C1	1.3816 (18)	C16—C17	1.483 (4)
N1—C13	1.4091 (18)	C16—C17A	1.305 (9)
N1—C14	1.4633 (17)	C17—H17A	0.9800
C1—C2	1.504 (2)	C17—H17B	0.9800
C1—C6	1.365 (2)	C17—H17C	0.9800
C2—H2A	0.9900	C17A—H17D	0.9800
C2—H2B	0.9900	C17A—H17E	0.9800
C2—C3	1.533 (2)	C17A—H17F	0.9800
C3—C4	1.531 (2)	C18—C19	1.404 (2)
C3—C24	1.530 (2)	C18—C23	1.389 (2)
C3—C25	1.537 (2)	C19—C20	1.392 (2)
C4—H4A	0.9900	C20—H20	0.9500
C4—H4B	0.9900	C20—C21	1.381 (3)
C4—C5	1.504 (2)	C21—H21	0.9500
C5—C6	1.4401 (19)	C21—C22	1.377 (3)
C6—C7	1.514 (2)	C22—H22	0.9500
C7—H7	1.0000	C22—C23	1.390 (2)
C7—C8	1.5074 (18)	C23—H23	0.9500
C7—C18	1.5334 (19)	C24—H24A	0.9800
C8—C9	1.468 (2)	C24—H24B	0.9800
C8—C13	1.354 (2)	C24—H24C	0.9800
C9—C10	1.507 (2)	C25—H25A	0.9800
C10—H10A	0.9900	C25—H25B	0.9800
C10—H10B	0.9900	C25—H25C	0.9800
C10—C11	1.529 (2)	C26—H26A	0.9800
C11—C12	1.537 (2)	C26—H26B	0.9800
C11—C26	1.532 (2)	C26—H26C	0.9800
C11—C27	1.533 (2)	C27—H27A	0.9800
C12—H12A	0.9900	C27—H27B	0.9800
C12—H12B	0.9900	C27—H27C	0.9800
C15—O4—C16	117.16 (15)	O3—C15—O4	124.13 (18)
C19—O5—H5	109.5	O3—C15—C14	124.71 (17)
C1—N1—C13	119.22 (11)	O3A—C15—O4	120.8 (5)
C1—N1—C14	120.56 (12)	O3A—C15—C14	117.9 (5)
C13—N1—C14	120.23 (11)	O4—C15—C14	110.73 (13)
N1—C1—C2	117.03 (12)	O4—C16—H16A	110.0
C6—C1—N1	120.23 (13)	O4—C16—H16B	110.0
C6—C1—C2	122.68 (13)	O4—C16—H16C	108.4
C1—C2—H2A	108.7	O4—C16—H16D	108.4
C1—C2—H2B	108.7	O4—C16—C17	108.3 (2)
C1—C2—C3	114.28 (12)	H16A—C16—H16B	108.4
H2A—C2—H2B	107.6	H16C—C16—H16D	107.5
C3—C2—H2A	108.7	C17—C16—H16A	110.0
C3—C2—H2B	108.7	C17—C16—H16B	110.0
C2—C3—C25	108.42 (13)	C17A—C16—O4	115.5 (4)
C4—C3—C2	107.84 (13)	C17A—C16—H16C	108.4
C4—C3—C25	110.27 (14)	C17A—C16—H16D	108.4
C24—C3—C2	110.77 (14)	C16—C17—H17A	109.5
C24—C3—C4	110.08 (14)	C16—C17—H17B	109.5
C24—C3—C25	109.43 (15)	C16—C17—H17C	109.5
C3—C4—H4A	109.4	H17A—C17—H17B	109.5
C3—C4—H4B	109.4	H17A—C17—H17C	109.5
H4A—C4—H4B	108.0	H17B—C17—H17C	109.5
C5—C4—C3	111.22 (13)	C16—C17A—H17D	109.5
C5—C4—H4A	109.4	C16—C17A—H17E	109.5
C5—C4—H4B	109.4	C16—C17A—H17F	109.5
O1—C5—C4	119.99 (13)	H17D—C17A—H17E	109.5
O1—C5—C6	121.89 (14)	H17D—C17A—H17F	109.5
C6—C5—C4	118.08 (13)	H17E—C17A—H17F	109.5
C1—C6—C5	119.53 (13)	C19—C18—C7	121.14 (13)
C1—C6—C7	121.28 (12)	C23—C18—C7	121.01 (13)
C5—C6—C7	119.16 (12)	C23—C18—C19	117.85 (14)
C6—C7—H7	107.8	O5—C19—C18	122.76 (14)
C6—C7—C18	112.53 (11)	O5—C19—C20	116.89 (14)
C8—C7—C6	108.12 (11)	C20—C19—C18	120.34 (15)
C8—C7—H7	107.8	C19—C20—H20	119.8
C8—C7—C18	112.73 (11)	C21—C20—C19	120.35 (15)
C18—C7—H7	107.8	C21—C20—H20	119.8
C9—C8—C7	117.07 (12)	C20—C21—H21	119.9
C13—C8—C7	122.19 (13)	C22—C21—C20	120.17 (15)
C13—C8—C9	120.73 (13)	C22—C21—H21	119.9
O2—C9—C8	121.20 (14)	C21—C22—H22	120.2
O2—C9—C10	121.44 (14)	C21—C22—C23	119.56 (16)
C8—C9—C10	117.34 (13)	C23—C22—H22	120.2
C9—C10—H10A	109.3	C18—C23—C22	121.71 (14)
C9—C10—H10B	109.3	C18—C23—H23	119.1
C9—C10—C11	111.62 (12)	C22—C23—H23	119.1
H10A—C10—H10B	108.0	C3—C24—H24A	109.5
C11—C10—H10A	109.3	C3—C24—H24B	109.5
C11—C10—H10B	109.3	C3—C24—H24C	109.5
C10—C11—C12	107.90 (12)	H24A—C24—H24B	109.5
C10—C11—C26	110.38 (13)	H24A—C24—H24C	109.5
C10—C11—C27	109.47 (13)	H24B—C24—H24C	109.5
C26—C11—C12	109.08 (12)	C3—C25—H25A	109.5
C26—C11—C27	109.14 (13)	C3—C25—H25B	109.5
C27—C11—C12	110.87 (12)	C3—C25—H25C	109.5
C11—C12—H12A	108.9	H25A—C25—H25B	109.5
C11—C12—H12B	108.9	H25A—C25—H25C	109.5
H12A—C12—H12B	107.7	H25B—C25—H25C	109.5
C13—C12—C11	113.34 (12)	C11—C26—H26A	109.5
C13—C12—H12A	108.9	C11—C26—H26B	109.5
C13—C12—H12B	108.9	C11—C26—H26C	109.5
N1—C13—C12	117.39 (12)	H26A—C26—H26B	109.5
C8—C13—N1	120.15 (12)	H26A—C26—H26C	109.5
C8—C13—C12	122.36 (13)	H26B—C26—H26C	109.5
N1—C14—H14A	109.3	C11—C27—H27A	109.5
N1—C14—H14B	109.3	C11—C27—H27B	109.5
N1—C14—C15	111.74 (12)	C11—C27—H27C	109.5
H14A—C14—H14B	107.9	H27A—C27—H27B	109.5
C15—C14—H14A	109.3	H27A—C27—H27C	109.5
C15—C14—H14B	109.3	H27B—C27—H27C	109.5

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O5—H5···O1	0.84	1.81	2.6319 (17)	166
C2—H2A···O2^i	0.99	2.52	3.1663 (19)	123
C2—H2B···O5^i	0.99	2.53	3.457 (2)	157
C12—H12B···O1^ii	0.99	2.52	3.2708 (17)	133
C14—H14A···O1^ii	0.99	2.53	3.3299 (18)	138
C14—H14B···O2^i	0.99	2.66	3.473 (2)	140
C27—H27B···O3^iii	0.98	2.51	3.452 (3)	161

Symmetry codes: (i) x+1/2, −y+1/2, z+1/2; (ii) x−1/2, −y+1/2, z+1/2; (iii) −x+1/2, y+1/2, −z+3/2.