Iodo­tris(tri-p-tolyl­phosphine)silver(I)

In the title compound, [AgI(C₂₁H₂₁P)₃], important bond distances are: Ag-P = 2.5346 (9), 2.5562 (9) and 2.5617 (9) Å, and Ag-I = 2.8683 (5) Å. The Ag^I atom is in a distorted tetra­hedral environment and all bond angles are close to the ideal values.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.006 Å
• Disorder in main residue
• R factor = 0.040
• wR factor = 0.094
• Data-to-parameter ratio = 19.6

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.98
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C13
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C15
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C93
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for       C93B
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C11
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C14
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C84
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C91
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C94
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C94B
PLAT301_ALERT_3_C Main Residue  Disorder .........................       8.00 Perc.

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  12 ALERT level C = Check and explain
   2 ALERT level G = General alerts; check

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  10 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: SMART-NT (Bruker, 1999); cell refinement: SAINT-Plus (Bruker, 1999); data reduction: SAINT-Plus and XPREP (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

Iodotris(tri-p-tolylphosphine)silver(I)

Crystal data

[AgI(C21H21P)3]	Z = 2
Mr = 1147.81	F(000) = 1172
Triclinic, P1	Dx = 1.36 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 11.0426 (13) Å	Cell parameters from 891 reflections
b = 11.5665 (14) Å	θ = 6.1–51.2°
c = 23.243 (3) Å	µ = 1.03 mm^−1
α = 99.292 (3)°	T = 293 K
β = 92.174 (2)°	Cuboid, colourless
γ = 106.196 (2)°	0.3 × 0.26 × 0.15 mm
V = 2802.7 (6) Å^3

Data collection

Bruker SMART 1K CCD area-detector diffractometer	13246 independent reflections
Radiation source: fine-focus sealed tube	8623 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.022
Detector resolution: 512 pixels mm^-1	θmax = 28°, θmin = 0.9°
ω scans	h = −14→14
Absorption correction: multi-scan (SADABS; Bruker, 2004)	k = −15→11
Tmin = 0.747, Tmax = 0.860	l = −30→28
19391 measured reflections

Refinement

Refinement on F^2	6 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.040	w = 1/[σ^2(Fo^2) + (0.0327P)^2 + 1.1965P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.094	(Δ/σ)max < 0.001
S = 1.01	Δρmax = 0.57 e Å^−3
13246 reflections	Δρmin = −0.54 e Å^−3
677 parameters

Special details

Experimental. The intensity data were collected on a Siemens SMART 1 K CCD diffractometer using an exposure time of 10 s/frame. A total of 1315 frames were collected with a frame width of 0.3° covering up to θ = 28.0° with 97.9% completeness accomplished. The first 50 frames were recollected at the end of each data collection to check for decay; none was found.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag	0.14515 (2)	0.21085 (2)	0.248917 (11)	0.04531 (8)
I	0.40509 (2)	0.21196 (2)	0.247552 (11)	0.06297 (9)
P1	0.12590 (8)	0.27580 (7)	0.35685 (4)	0.04108 (19)
P2	0.15045 (8)	0.38249 (8)	0.19135 (4)	0.0472 (2)
P3	−0.00408 (8)	0.00545 (7)	0.19679 (4)	0.04207 (19)
C11	0.1621 (3)	0.1794 (3)	0.40646 (14)	0.0435 (7)
C12	0.2345 (5)	0.1032 (4)	0.38875 (19)	0.0811 (13)
H12	0.2676	0.1042	0.3526	0.097*
C13	0.2593 (5)	0.0244 (4)	0.4242 (2)	0.0924 (15)
H13	0.308	−0.0266	0.4109	0.111*
C14	0.2148 (4)	0.0203 (3)	0.47693 (18)	0.0626 (10)
C15	0.1478 (4)	0.0983 (4)	0.49495 (19)	0.0850 (14)
H15	0.1185	0.0996	0.532	0.102*
C16	0.1203 (4)	0.1773 (4)	0.46037 (17)	0.0752 (12)
H16	0.0728	0.229	0.4745	0.09*
C17	0.2417 (5)	−0.0665 (4)	0.5153 (2)	0.0952 (16)
H17A	0.2143	−0.0473	0.5534	0.143*
H17B	0.3309	−0.0574	0.5186	0.143*
H17C	0.1968	−0.1493	0.4978	0.143*
C21	0.2325 (3)	0.4264 (3)	0.38682 (13)	0.0417 (7)
C22	0.3472 (3)	0.4409 (3)	0.41686 (17)	0.0601 (10)
H22	0.3672	0.3726	0.4259	0.072*
C23	0.4334 (3)	0.5560 (4)	0.43390 (18)	0.0678 (11)
H23	0.5107	0.5632	0.4537	0.081*
C24	0.4069 (4)	0.6590 (3)	0.42223 (16)	0.0602 (10)
C25	0.2919 (4)	0.6451 (3)	0.39367 (16)	0.0612 (10)
H25	0.2709	0.7142	0.3864	0.073*
C26	0.2064 (3)	0.5317 (3)	0.37541 (16)	0.0572 (9)
H26	0.1299	0.5253	0.3551	0.069*
C27	0.5046 (4)	0.7819 (4)	0.4402 (2)	0.0934 (15)
H27A	0.5528	0.8015	0.4078	0.14*
H27B	0.5602	0.7788	0.4723	0.14*
H27C	0.463	0.8434	0.452	0.14*
C31	−0.0296 (3)	0.2887 (3)	0.37501 (13)	0.0410 (7)
C32	−0.0505 (3)	0.3634 (3)	0.42458 (14)	0.0498 (8)
H32	0.0176	0.4114	0.4506	0.06*
C33	−0.1719 (3)	0.3667 (3)	0.43537 (15)	0.0550 (9)
H33	−0.1841	0.417	0.4688	0.066*
C34	−0.2746 (3)	0.2974 (3)	0.39783 (16)	0.0554 (9)
C35	−0.2543 (3)	0.2242 (3)	0.34844 (15)	0.0596 (10)
H35	−0.3227	0.1774	0.3222	0.072*
C36	−0.1336 (3)	0.2196 (3)	0.33751 (15)	0.0527 (8)
H36	−0.1222	0.1688	0.3041	0.063*
C37	−0.4065 (4)	0.3021 (5)	0.4093 (2)	0.0953 (16)
H37A	−0.4028	0.3633	0.4431	0.143*
H37B	−0.4559	0.2238	0.4162	0.143*
H37C	−0.4448	0.3221	0.3759	0.143*
C41	−0.0020 (3)	0.4039 (3)	0.17181 (14)	0.0475 (8)
C42	−0.0224 (3)	0.4734 (3)	0.13047 (16)	0.0596 (9)
H42	0.0445	0.5104	0.1103	0.072*
C43	−0.1403 (4)	0.4880 (4)	0.11916 (16)	0.0643 (10)
H43	−0.1508	0.5359	0.0919	0.077*
C44	−0.2425 (3)	0.4333 (3)	0.14718 (17)	0.0590 (9)
C45	−0.2239 (4)	0.3639 (3)	0.18798 (19)	0.0656 (10)
H45	−0.2917	0.3255	0.2073	0.079*
C46	−0.1051 (3)	0.3511 (3)	0.20029 (16)	0.0561 (9)
H46	−0.0944	0.3055	0.2286	0.067*
C47	−0.3720 (4)	0.4486 (4)	0.1339 (2)	0.0909 (14)
H47A	−0.4313	0.4042	0.1574	0.136*	0.5
H47B	−0.3993	0.4174	0.0932	0.136*	0.5
H47C	−0.3675	0.5338	0.1426	0.136*	0.5
H47D	−0.3675	0.4994	0.1047	0.136*	0.5
H47E	−0.3994	0.4862	0.1689	0.136*	0.5
H47F	−0.4313	0.3698	0.1196	0.136*	0.5
C51	0.2184 (3)	0.3535 (3)	0.12181 (14)	0.0445 (7)
C52	0.2115 (3)	0.2342 (3)	0.09761 (15)	0.0489 (8)
H52	0.1734	0.1715	0.1173	0.059*
C53	0.2597 (3)	0.2055 (3)	0.04478 (15)	0.0515 (8)
H53	0.2524	0.1242	0.0295	0.062*
C54	0.3190 (3)	0.2967 (3)	0.01431 (15)	0.0484 (8)
C55	0.3264 (3)	0.4164 (3)	0.03887 (16)	0.0570 (9)
H55	0.3654	0.4793	0.0194	0.068*
C56	0.2776 (3)	0.4445 (3)	0.09114 (15)	0.0543 (9)
H56	0.2842	0.5258	0.1062	0.065*
C57	0.3754 (4)	0.2666 (4)	−0.04213 (17)	0.0675 (10)
H57A	0.3089	0.2315	−0.0731	0.101*
H57B	0.4219	0.2091	−0.0381	0.101*
H57C	0.4314	0.34	−0.0512	0.101*
C61	0.2469 (3)	0.5374 (3)	0.22309 (14)	0.0494 (8)
C62	0.3751 (4)	0.5575 (4)	0.23764 (19)	0.0726 (11)
H62	0.4096	0.4923	0.2317	0.087*
C63	0.4523 (4)	0.6742 (4)	0.2610 (2)	0.0811 (13)
H63	0.5383	0.6859	0.2694	0.097*
C64	0.4052 (5)	0.7723 (4)	0.27180 (18)	0.0734 (12)
C65	0.2785 (5)	0.7523 (4)	0.25944 (18)	0.0755 (12)
H65	0.2441	0.8173	0.2674	0.091*
C66	0.1997 (4)	0.6368 (3)	0.23513 (17)	0.0656 (10)
H66	0.1139	0.6261	0.2268	0.079*
C67	0.4925 (5)	0.8998 (4)	0.2983 (2)	0.0988 (17)
H67A	0.4918	0.955	0.2716	0.148*
H67B	0.5772	0.8953	0.3052	0.148*
H67C	0.4632	0.9291	0.3346	0.148*
C71	−0.1473 (3)	0.0207 (3)	0.16081 (14)	0.0439 (7)
C72	−0.2609 (3)	−0.0009 (3)	0.18623 (15)	0.0566 (9)
H72	−0.2674	−0.0316	0.2209	0.068*
C73	−0.3650 (4)	0.0224 (4)	0.16094 (16)	0.0653 (10)
H73	−0.4397	0.0083	0.1793	0.078*
C74	−0.3604 (3)	0.0660 (3)	0.10907 (16)	0.0555 (9)
C75	−0.2479 (3)	0.0867 (3)	0.08341 (17)	0.0598 (9)
H75	−0.2427	0.1149	0.048	0.072*
C76	−0.1422 (3)	0.0664 (3)	0.10909 (16)	0.0540 (9)
H76	−0.0667	0.0837	0.0914	0.065*
C77	−0.4755 (4)	0.0909 (4)	0.08200 (19)	0.0804 (13)
H77A	−0.539	0.0148	0.0676	0.121*
H77B	−0.4517	0.1339	0.0502	0.121*
H77C	−0.5087	0.1399	0.111	0.121*
C81	0.0597 (3)	−0.0827 (3)	0.13968 (14)	0.0434 (7)
C82	−0.0075 (4)	−0.1510 (3)	0.08838 (16)	0.0614 (10)
H82	−0.0895	−0.1487	0.0796	0.074*
C83	0.0458 (4)	−0.2235 (4)	0.04947 (16)	0.0681 (11)
H83	−0.0007	−0.2674	0.0147	0.082*
C84	0.1648 (4)	−0.2314 (3)	0.06145 (16)	0.0611 (10)
C85	0.2318 (4)	−0.1630 (4)	0.11189 (19)	0.0704 (11)
H85	0.3135	−0.1664	0.1206	0.085*
C86	0.1812 (3)	−0.0881 (3)	0.15071 (16)	0.0604 (9)
H86	0.2298	−0.0413	0.1844	0.072*
C87	0.2194 (5)	−0.3142 (4)	0.01950 (19)	0.0956 (16)
H87A	0.1779	−0.3981	0.0215	0.143*
H87B	0.3084	−0.2964	0.0301	0.143*
H87C	0.2066	−0.3005	−0.0196	0.143*
C91	−0.0626 (3)	−0.1085 (3)	0.24329 (14)	0.0445 (7)
C92	−0.0089 (11)	−0.0844 (7)	0.3002 (3)	0.069 (3)	0.648 (17)
H92	0.05	−0.0093	0.3149	0.083*	0.648 (17)
C93	−0.0426 (12)	−0.1719 (8)	0.3354 (3)	0.085 (4)	0.648 (17)
H93	−0.0065	−0.1514	0.3739	0.102*	0.648 (17)
C94	−0.1230 (18)	−0.283 (2)	0.3184 (10)	0.069 (4)	0.648 (17)
C95	−0.1826 (17)	−0.3059 (19)	0.2601 (11)	0.074 (4)	0.648 (17)
H95	−0.2461	−0.3786	0.2467	0.088*	0.648 (17)
C96	−0.1469 (10)	−0.2212 (12)	0.2232 (6)	0.064 (3)	0.648 (17)
H96	−0.1807	−0.2412	0.1844	0.076*	0.648 (17)
C97	−0.1539 (14)	−0.3725 (12)	0.3593 (6)	0.095 (4)	0.648 (17)
H97A	−0.2391	−0.3822	0.3696	0.143*	0.648 (17)
H97B	−0.0965	−0.3424	0.3941	0.143*	0.648 (17)
H97C	−0.146	−0.45	0.3407	0.143*	0.648 (17)
C92B	−0.087 (2)	−0.0716 (12)	0.2991 (6)	0.071 (5)	0.352 (17)
H92B	−0.0688	0.0118	0.3134	0.086*	0.352 (17)
C93B	−0.138 (3)	−0.1556 (13)	0.3365 (6)	0.088 (7)	0.352 (17)
H93B	−0.1545	−0.1291	0.3746	0.106*	0.352 (17)
C94B	−0.162 (3)	−0.274 (4)	0.3143 (18)	0.061 (6)	0.352 (17)
C95B	−0.134 (3)	−0.314 (3)	0.261 (2)	0.083 (10)	0.352 (17)
H95B	−0.1446	−0.3966	0.2483	0.1*	0.352 (17)
C96B	−0.089 (3)	−0.229 (2)	0.2255 (11)	0.076 (7)	0.352 (17)
H96B	−0.0769	−0.2582	0.1871	0.091*	0.352 (17)
C97B	−0.222 (2)	−0.380 (3)	0.3510 (12)	0.099 (8)	0.352 (17)
H97D	−0.1936	−0.3516	0.3917	0.149*	0.352 (17)
H97E	−0.1962	−0.4512	0.3368	0.149*	0.352 (17)
H97F	−0.3131	−0.4007	0.3463	0.149*	0.352 (17)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ag	0.04831 (14)	0.04667 (15)	0.04342 (14)	0.01687 (11)	0.00701 (11)	0.00893 (11)
I	0.04693 (13)	0.08375 (19)	0.06328 (16)	0.02666 (12)	0.00769 (11)	0.01324 (13)
P1	0.0410 (4)	0.0427 (5)	0.0399 (4)	0.0145 (4)	0.0049 (3)	0.0041 (4)
P2	0.0533 (5)	0.0455 (5)	0.0485 (5)	0.0189 (4)	0.0103 (4)	0.0147 (4)
P3	0.0458 (4)	0.0396 (5)	0.0411 (5)	0.0143 (4)	0.0027 (4)	0.0046 (4)
C11	0.0402 (17)	0.0421 (18)	0.0478 (19)	0.0102 (14)	0.0038 (14)	0.0100 (15)
C12	0.124 (4)	0.072 (3)	0.074 (3)	0.059 (3)	0.044 (3)	0.029 (2)
C13	0.137 (4)	0.079 (3)	0.097 (4)	0.072 (3)	0.045 (3)	0.039 (3)
C14	0.059 (2)	0.057 (2)	0.077 (3)	0.0144 (19)	0.004 (2)	0.030 (2)
C15	0.102 (3)	0.115 (4)	0.066 (3)	0.054 (3)	0.034 (3)	0.046 (3)
C16	0.099 (3)	0.096 (3)	0.058 (2)	0.063 (3)	0.024 (2)	0.029 (2)
C17	0.104 (4)	0.087 (3)	0.111 (4)	0.030 (3)	0.011 (3)	0.059 (3)
C21	0.0407 (16)	0.0447 (18)	0.0408 (17)	0.0134 (14)	0.0061 (14)	0.0082 (14)
C22	0.0446 (19)	0.053 (2)	0.084 (3)	0.0142 (17)	−0.0025 (18)	0.017 (2)
C23	0.046 (2)	0.064 (3)	0.084 (3)	0.0023 (19)	−0.0123 (19)	0.013 (2)
C24	0.066 (2)	0.052 (2)	0.055 (2)	0.0043 (19)	0.0059 (19)	0.0118 (18)
C25	0.077 (3)	0.045 (2)	0.062 (2)	0.0178 (19)	−0.001 (2)	0.0123 (18)
C26	0.058 (2)	0.054 (2)	0.060 (2)	0.0161 (18)	−0.0067 (18)	0.0124 (18)
C27	0.097 (3)	0.058 (3)	0.104 (4)	−0.010 (2)	−0.010 (3)	0.015 (2)
C31	0.0381 (16)	0.0445 (18)	0.0401 (17)	0.0121 (14)	0.0029 (13)	0.0069 (14)
C32	0.0446 (18)	0.059 (2)	0.0450 (19)	0.0187 (16)	−0.0003 (15)	0.0011 (16)
C33	0.059 (2)	0.065 (2)	0.047 (2)	0.0312 (19)	0.0094 (17)	0.0057 (17)
C34	0.0467 (19)	0.077 (3)	0.052 (2)	0.0274 (18)	0.0097 (17)	0.0204 (19)
C35	0.0395 (18)	0.080 (3)	0.050 (2)	0.0060 (18)	−0.0022 (16)	0.0054 (19)
C36	0.0448 (18)	0.061 (2)	0.0461 (19)	0.0080 (16)	0.0047 (15)	0.0029 (16)
C37	0.054 (2)	0.158 (5)	0.077 (3)	0.041 (3)	0.011 (2)	0.009 (3)
C41	0.0525 (19)	0.0466 (19)	0.0471 (19)	0.0177 (16)	0.0092 (15)	0.0116 (15)
C42	0.058 (2)	0.073 (3)	0.056 (2)	0.0216 (19)	0.0120 (18)	0.0264 (19)
C43	0.073 (3)	0.071 (3)	0.059 (2)	0.034 (2)	0.002 (2)	0.019 (2)
C44	0.052 (2)	0.055 (2)	0.072 (3)	0.0235 (18)	0.0031 (19)	0.0025 (19)
C45	0.057 (2)	0.056 (2)	0.092 (3)	0.0204 (19)	0.027 (2)	0.023 (2)
C46	0.058 (2)	0.053 (2)	0.067 (2)	0.0239 (17)	0.0174 (18)	0.0226 (18)
C47	0.067 (3)	0.094 (3)	0.120 (4)	0.037 (3)	0.003 (3)	0.020 (3)
C51	0.0443 (17)	0.0455 (19)	0.0476 (19)	0.0163 (15)	0.0056 (15)	0.0131 (15)
C52	0.0495 (19)	0.0430 (19)	0.055 (2)	0.0113 (15)	0.0078 (16)	0.0146 (16)
C53	0.0518 (19)	0.047 (2)	0.055 (2)	0.0173 (16)	0.0019 (16)	0.0023 (16)
C54	0.0412 (17)	0.055 (2)	0.051 (2)	0.0174 (16)	0.0049 (15)	0.0091 (16)
C55	0.064 (2)	0.052 (2)	0.061 (2)	0.0188 (18)	0.0196 (18)	0.0202 (18)
C56	0.069 (2)	0.0404 (19)	0.059 (2)	0.0210 (17)	0.0183 (18)	0.0124 (16)
C57	0.065 (2)	0.072 (3)	0.065 (3)	0.022 (2)	0.023 (2)	0.008 (2)
C61	0.059 (2)	0.0463 (19)	0.0461 (19)	0.0168 (16)	0.0114 (16)	0.0133 (15)
C62	0.063 (2)	0.060 (3)	0.091 (3)	0.018 (2)	0.012 (2)	0.001 (2)
C63	0.056 (2)	0.083 (3)	0.092 (3)	0.007 (2)	0.015 (2)	0.001 (3)
C64	0.096 (3)	0.057 (3)	0.065 (3)	0.012 (2)	0.024 (2)	0.016 (2)
C65	0.108 (4)	0.050 (2)	0.073 (3)	0.031 (2)	−0.001 (3)	0.011 (2)
C66	0.083 (3)	0.054 (2)	0.065 (2)	0.030 (2)	−0.005 (2)	0.0113 (19)
C67	0.124 (4)	0.062 (3)	0.085 (3)	−0.011 (3)	0.014 (3)	0.008 (2)
C71	0.0483 (18)	0.0390 (17)	0.0444 (18)	0.0163 (14)	0.0021 (15)	0.0017 (14)
C72	0.056 (2)	0.074 (3)	0.047 (2)	0.0266 (19)	0.0068 (17)	0.0142 (18)
C73	0.056 (2)	0.090 (3)	0.058 (2)	0.033 (2)	0.0144 (18)	0.013 (2)
C74	0.058 (2)	0.058 (2)	0.053 (2)	0.0279 (18)	0.0007 (18)	0.0013 (17)
C75	0.065 (2)	0.059 (2)	0.061 (2)	0.0201 (19)	0.0017 (19)	0.0225 (19)
C76	0.053 (2)	0.052 (2)	0.061 (2)	0.0167 (17)	0.0100 (17)	0.0191 (17)
C77	0.076 (3)	0.103 (3)	0.077 (3)	0.052 (3)	−0.002 (2)	0.014 (3)
C81	0.0484 (18)	0.0401 (18)	0.0444 (18)	0.0171 (14)	0.0043 (15)	0.0074 (14)
C82	0.059 (2)	0.071 (3)	0.055 (2)	0.0265 (19)	−0.0015 (18)	0.0000 (19)
C83	0.087 (3)	0.072 (3)	0.045 (2)	0.032 (2)	0.001 (2)	−0.0043 (19)
C84	0.090 (3)	0.057 (2)	0.052 (2)	0.039 (2)	0.026 (2)	0.0209 (19)
C85	0.062 (2)	0.079 (3)	0.085 (3)	0.042 (2)	0.013 (2)	0.017 (2)
C86	0.064 (2)	0.061 (2)	0.058 (2)	0.0293 (19)	−0.0036 (18)	−0.0021 (18)
C87	0.153 (5)	0.098 (3)	0.071 (3)	0.083 (3)	0.045 (3)	0.026 (3)
C91	0.0513 (19)	0.0409 (19)	0.0424 (18)	0.0156 (15)	0.0062 (15)	0.0060 (14)
C92	0.093 (7)	0.049 (4)	0.055 (4)	0.005 (4)	−0.010 (4)	0.011 (3)
C93	0.122 (9)	0.071 (5)	0.051 (4)	0.003 (5)	−0.007 (5)	0.023 (4)
C94	0.098 (11)	0.055 (6)	0.067 (7)	0.039 (7)	0.001 (7)	0.020 (5)
C95	0.084 (9)	0.046 (7)	0.085 (9)	0.004 (5)	0.013 (8)	0.018 (6)
C96	0.071 (6)	0.051 (5)	0.057 (5)	0.001 (5)	−0.002 (5)	0.009 (4)
C97	0.122 (11)	0.065 (6)	0.095 (7)	0.007 (7)	0.005 (8)	0.042 (5)
C92B	0.130 (17)	0.038 (6)	0.047 (7)	0.029 (8)	−0.005 (9)	0.005 (5)
C93B	0.16 (2)	0.061 (9)	0.045 (7)	0.033 (10)	0.017 (9)	0.021 (6)
C94B	0.084 (16)	0.055 (11)	0.062 (12)	0.031 (11)	0.013 (13)	0.038 (9)
C95B	0.12 (3)	0.033 (8)	0.089 (19)	0.017 (16)	0.05 (2)	0.004 (9)
C96B	0.118 (19)	0.059 (9)	0.055 (10)	0.030 (13)	0.038 (13)	0.005 (7)
C97B	0.092 (14)	0.112 (14)	0.086 (13)	−0.003 (14)	−0.008 (13)	0.058 (11)

Geometric parameters (Å, º)

Ag—P1	2.5346 (9)	C54—C55	1.388 (5)
Ag—P2	2.5562 (9)	C54—C57	1.505 (5)
Ag—P3	2.5617 (9)	C55—C56	1.375 (5)
Ag—I	2.8683 (5)	C55—H55	0.93
P1—C21	1.819 (3)	C56—H56	0.93
P1—C31	1.824 (3)	C57—H57A	0.96
P1—C11	1.833 (3)	C57—H57B	0.96
P2—C41	1.820 (3)	C57—H57C	0.96
P2—C61	1.827 (3)	C61—C66	1.383 (5)
P2—C51	1.829 (3)	C61—C62	1.388 (5)
P3—C81	1.825 (3)	C62—C63	1.389 (5)
P3—C71	1.826 (3)	C62—H62	0.93
P3—C91	1.833 (3)	C63—C64	1.367 (6)
C11—C16	1.353 (5)	C63—H63	0.93
C11—C12	1.373 (5)	C64—C65	1.364 (6)
C12—C13	1.396 (5)	C64—C67	1.534 (6)
C12—H12	0.93	C65—C66	1.390 (5)
C13—C14	1.340 (6)	C65—H65	0.93
C13—H13	0.93	C66—H66	0.93
C14—C15	1.346 (5)	C67—H67A	0.96
C14—C17	1.524 (5)	C67—H67B	0.96
C15—C16	1.395 (5)	C67—H67C	0.96
C15—H15	0.93	C71—C72	1.384 (4)
C16—H16	0.93	C71—C76	1.386 (4)
C17—H17A	0.96	C72—C73	1.382 (5)
C17—H17B	0.96	C72—H72	0.93
C17—H17C	0.96	C73—C74	1.378 (5)
C21—C22	1.377 (4)	C73—H73	0.93
C21—C26	1.389 (4)	C74—C75	1.376 (5)
C22—C23	1.389 (5)	C74—C77	1.515 (5)
C22—H22	0.93	C75—C76	1.385 (5)
C23—C24	1.368 (5)	C75—H75	0.93
C23—H23	0.93	C76—H76	0.93
C24—C25	1.366 (5)	C77—H77A	0.96
C24—C27	1.509 (5)	C77—H77B	0.96
C25—C26	1.376 (5)	C77—H77C	0.96
C25—H25	0.93	C81—C86	1.377 (4)
C26—H26	0.93	C81—C82	1.378 (5)
C27—H27A	0.96	C82—C83	1.392 (5)
C27—H27B	0.96	C82—H82	0.93
C27—H27C	0.96	C83—C84	1.364 (5)
C31—C36	1.381 (4)	C83—H83	0.93
C31—C32	1.392 (4)	C84—C85	1.363 (5)
C32—C33	1.382 (4)	C84—C87	1.515 (5)
C32—H32	0.93	C85—C86	1.390 (5)
C33—C34	1.373 (5)	C85—H85	0.93
C33—H33	0.93	C86—H86	0.93
C34—C35	1.377 (5)	C87—H87A	0.96
C34—C37	1.504 (5)	C87—H87B	0.96
C35—C36	1.380 (5)	C87—H87C	0.96
C35—H35	0.93	C91—C96B	1.34 (2)
C36—H36	0.93	C91—C92B	1.359 (15)
C37—H37A	0.96	C91—C96	1.370 (13)
C37—H37B	0.96	C91—C92	1.382 (9)
C37—H37C	0.96	C92—C93	1.383 (10)
C41—C46	1.381 (4)	C92—H92	0.93
C41—C42	1.398 (4)	C93—C94	1.33 (2)
C42—C43	1.379 (5)	C93—H93	0.93
C42—H42	0.93	C94—C95	1.44 (3)
C43—C44	1.374 (5)	C94—C97	1.49 (2)
C43—H43	0.93	C95—C96	1.39 (3)
C44—C45	1.382 (5)	C95—H95	0.93
C44—C47	1.516 (5)	C96—H96	0.93
C45—C46	1.385 (5)	C97—H97A	0.96
C45—H45	0.93	C97—H97B	0.96
C46—H46	0.93	C97—H97C	0.96
C47—H47A	0.96	C92B—C93B	1.423 (19)
C47—H47B	0.96	C92B—H92B	0.93
C47—H47C	0.96	C93B—C94B	1.33 (4)
C47—H47D	0.96	C93B—H93B	0.93
C47—H47E	0.96	C94B—C95B	1.33 (6)
C47—H47F	0.96	C94B—C97B	1.62 (4)
C51—C52	1.384 (4)	C95B—C96B	1.38 (5)
C51—C56	1.392 (4)	C95B—H95B	0.93
C52—C53	1.385 (4)	C96B—H96B	0.93
C52—H52	0.93	C97B—H97D	0.96
C53—C54	1.390 (4)	C97B—H97E	0.96
C53—H53	0.93	C97B—H97F	0.96
P1—Ag—P2	112.04 (3)	C56—C51—P2	124.1 (3)
P1—Ag—P3	117.65 (3)	C51—C52—C53	121.8 (3)
P2—Ag—P3	111.94 (3)	C51—C52—H52	119.1
P1—Ag—I	102.35 (2)	C53—C52—H52	119.1
P2—Ag—I	99.38 (2)	C52—C53—C54	120.9 (3)
P3—Ag—I	111.51 (2)	C52—C53—H53	119.5
C21—P1—C31	103.78 (14)	C54—C53—H53	119.5
C21—P1—C11	103.15 (14)	C55—C54—C53	117.2 (3)
C31—P1—C11	103.84 (14)	C55—C54—C57	121.6 (3)
C21—P1—Ag	112.53 (10)	C53—C54—C57	121.2 (3)
C31—P1—Ag	115.08 (10)	C56—C55—C54	121.8 (3)
C11—P1—Ag	116.91 (11)	C56—C55—H55	119.1
C41—P2—C61	103.04 (15)	C54—C55—H55	119.1
C41—P2—C51	105.19 (14)	C55—C56—C51	121.2 (3)
C61—P2—C51	102.39 (15)	C55—C56—H56	119.4
C41—P2—Ag	116.04 (11)	C51—C56—H56	119.4
C61—P2—Ag	118.32 (11)	C54—C57—H57A	109.5
C51—P2—Ag	110.25 (10)	C54—C57—H57B	109.5
C81—P3—C71	104.34 (14)	H57A—C57—H57B	109.5
C81—P3—C91	100.96 (14)	C54—C57—H57C	109.5
C71—P3—C91	104.35 (15)	H57A—C57—H57C	109.5
C81—P3—Ag	116.80 (11)	H57B—C57—H57C	109.5
C71—P3—Ag	112.91 (10)	C66—C61—C62	117.2 (3)
C91—P3—Ag	115.84 (11)	C66—C61—P2	124.1 (3)
C16—C11—C12	116.9 (3)	C62—C61—P2	118.7 (3)
C16—C11—P1	123.8 (3)	C61—C62—C63	120.6 (4)
C12—C11—P1	119.4 (3)	C61—C62—H62	119.7
C11—C12—C13	121.0 (4)	C63—C62—H62	119.7
C11—C12—H12	119.5	C64—C63—C62	121.8 (4)
C13—C12—H12	119.5	C64—C63—H63	119.1
C14—C13—C12	121.9 (4)	C62—C63—H63	119.1
C14—C13—H13	119.1	C65—C64—C63	117.8 (4)
C12—C13—H13	119.1	C65—C64—C67	121.5 (4)
C13—C14—C15	116.8 (4)	C63—C64—C67	120.6 (5)
C13—C14—C17	121.5 (4)	C64—C65—C66	121.4 (4)
C15—C14—C17	121.6 (4)	C64—C65—H65	119.3
C14—C15—C16	122.7 (4)	C66—C65—H65	119.3
C14—C15—H15	118.6	C61—C66—C65	121.1 (4)
C16—C15—H15	118.6	C61—C66—H66	119.4
C11—C16—C15	120.6 (4)	C65—C66—H66	119.4
C11—C16—H16	119.7	C64—C67—H67A	109.5
C15—C16—H16	119.7	C64—C67—H67B	109.5
C14—C17—H17A	109.5	H67A—C67—H67B	109.5
C14—C17—H17B	109.5	C64—C67—H67C	109.5
H17A—C17—H17B	109.5	H67A—C67—H67C	109.5
C14—C17—H17C	109.5	H67B—C67—H67C	109.5
H17A—C17—H17C	109.5	C72—C71—C76	117.4 (3)
H17B—C17—H17C	109.5	C72—C71—P3	122.1 (3)
C22—C21—C26	117.1 (3)	C76—C71—P3	120.3 (3)
C22—C21—P1	121.8 (2)	C73—C72—C71	121.1 (3)
C26—C21—P1	120.8 (2)	C73—C72—H72	119.4
C21—C22—C23	121.0 (3)	C71—C72—H72	119.4
C21—C22—H22	119.5	C74—C73—C72	121.5 (3)
C23—C22—H22	119.5	C74—C73—H73	119.3
C24—C23—C22	121.4 (3)	C72—C73—H73	119.3
C24—C23—H23	119.3	C75—C74—C73	117.6 (3)
C22—C23—H23	119.3	C75—C74—C77	121.7 (4)
C25—C24—C23	117.7 (3)	C73—C74—C77	120.7 (3)
C25—C24—C27	122.7 (4)	C74—C75—C76	121.4 (3)
C23—C24—C27	119.6 (4)	C74—C75—H75	119.3
C24—C25—C26	121.7 (3)	C76—C75—H75	119.3
C24—C25—H25	119.1	C75—C76—C71	121.0 (3)
C26—C25—H25	119.1	C75—C76—H76	119.5
C25—C26—C21	121.0 (3)	C71—C76—H76	119.5
C25—C26—H26	119.5	C74—C77—H77A	109.5
C21—C26—H26	119.5	C74—C77—H77B	109.5
C24—C27—H27A	109.5	H77A—C77—H77B	109.5
C24—C27—H27B	109.5	C74—C77—H77C	109.5
H27A—C27—H27B	109.5	H77A—C77—H77C	109.5
C24—C27—H27C	109.5	H77B—C77—H77C	109.5
H27A—C27—H27C	109.5	C86—C81—C82	117.6 (3)
H27B—C27—H27C	109.5	C86—C81—P3	117.3 (3)
C36—C31—C32	117.6 (3)	C82—C81—P3	124.9 (3)
C36—C31—P1	118.1 (2)	C81—C82—C83	120.9 (3)
C32—C31—P1	124.2 (2)	C81—C82—H82	119.5
C33—C32—C31	120.5 (3)	C83—C82—H82	119.5
C33—C32—H32	119.7	C84—C83—C82	121.2 (4)
C31—C32—H32	119.7	C84—C83—H83	119.4
C34—C33—C32	121.4 (3)	C82—C83—H83	119.4
C34—C33—H33	119.3	C85—C84—C83	117.9 (3)
C32—C33—H33	119.3	C85—C84—C87	121.7 (4)
C33—C34—C35	118.4 (3)	C83—C84—C87	120.4 (4)
C33—C34—C37	121.3 (3)	C84—C85—C86	121.7 (4)
C35—C34—C37	120.3 (3)	C84—C85—H85	119.2
C34—C35—C36	120.7 (3)	C86—C85—H85	119.2
C34—C35—H35	119.7	C81—C86—C85	120.6 (4)
C36—C35—H35	119.7	C81—C86—H86	119.7
C35—C36—C31	121.5 (3)	C85—C86—H86	119.7
C35—C36—H36	119.3	C84—C87—H87A	109.5
C31—C36—H36	119.3	C84—C87—H87B	109.5
C34—C37—H37A	109.5	H87A—C87—H87B	109.5
C34—C37—H37B	109.5	C84—C87—H87C	109.5
H37A—C37—H37B	109.5	H87A—C87—H87C	109.5
C34—C37—H37C	109.5	H87B—C87—H87C	109.5
H37A—C37—H37C	109.5	C96B—C91—C92B	115.8 (12)
H37B—C37—H37C	109.5	C96—C91—C92	117.9 (7)
C46—C41—C42	116.8 (3)	C96B—C91—P3	124.4 (11)
C46—C41—P2	118.7 (3)	C92B—C91—P3	119.7 (6)
C42—C41—P2	124.5 (3)	C96—C91—P3	123.7 (6)
C43—C42—C41	121.1 (3)	C92—C91—P3	118.0 (4)
C43—C42—H42	119.5	C91—C92—C93	120.0 (7)
C41—C42—H42	119.5	C91—C92—H92	120
C44—C43—C42	121.5 (3)	C93—C92—H92	120
C44—C43—H43	119.2	C94—C93—C92	124.9 (11)
C42—C43—H43	119.2	C94—C93—H93	117.6
C43—C44—C45	118.1 (3)	C92—C93—H93	117.6
C43—C44—C47	121.1 (4)	C93—C94—C95	114.8 (16)
C45—C44—C47	120.8 (4)	C93—C94—C97	121.3 (17)
C44—C45—C46	120.5 (3)	C95—C94—C97	123.7 (19)
C44—C45—H45	119.7	C96—C95—C94	121.1 (18)
C46—C45—H45	119.7	C96—C95—H95	119.4
C41—C46—C45	122.0 (3)	C94—C95—H95	119.4
C41—C46—H46	119	C91—C96—C95	120.9 (14)
C45—C46—H46	119	C91—C96—H96	119.5
C44—C47—H47A	109.5	C95—C96—H96	119.5
C44—C47—H47B	109.5	C91—C92B—C93B	122.5 (11)
H47A—C47—H47B	109.5	C91—C92B—H92B	118.7
C44—C47—H47C	109.5	C93B—C92B—H92B	118.7
H47A—C47—H47C	109.5	C94B—C93B—C92B	116.7 (19)
H47B—C47—H47C	109.5	C94B—C93B—H93B	121.6
C44—C47—H47D	109.5	C92B—C93B—H93B	121.6
H47A—C47—H47D	141.1	C93B—C94B—C95B	123 (3)
H47B—C47—H47D	56.3	C93B—C94B—C97B	123 (3)
H47C—C47—H47D	56.3	C95B—C94B—C97B	114 (3)
C44—C47—H47E	109.5	C94B—C95B—C96B	118 (3)
H47A—C47—H47E	56.3	C94B—C95B—H95B	120.9
H47B—C47—H47E	141.1	C96B—C95B—H95B	120.9
H47C—C47—H47E	56.3	C91—C96B—C95B	123 (2)
H47D—C47—H47E	109.5	C91—C96B—H96B	118.3
C44—C47—H47F	109.5	C95B—C96B—H96B	118.3
H47A—C47—H47F	56.3	C94B—C97B—H97D	109.5
H47B—C47—H47F	56.3	C94B—C97B—H97E	109.5
H47C—C47—H47F	141.1	H97D—C97B—H97E	109.5
H47D—C47—H47F	109.5	C94B—C97B—H97F	109.5
H47E—C47—H47F	109.5	H97D—C97B—H97F	109.5
C52—C51—C56	117.2 (3)	H97E—C97B—H97F	109.5
C52—C51—P2	118.7 (2)
P2—Ag—P1—C21	−45.40 (11)	P2—C51—C52—C53	179.3 (3)
P3—Ag—P1—C21	−177.24 (11)	C51—C52—C53—C54	0.9 (5)
I—Ag—P1—C21	60.19 (11)	C52—C53—C54—C55	−0.6 (5)
P2—Ag—P1—C31	73.21 (11)	C52—C53—C54—C57	178.0 (3)
P3—Ag—P1—C31	−58.63 (11)	C53—C54—C55—C56	0.1 (5)
I—Ag—P1—C31	178.80 (11)	C57—C54—C55—C56	−178.4 (3)
P2—Ag—P1—C11	−164.53 (11)	C54—C55—C56—C51	0.0 (6)
P3—Ag—P1—C11	63.63 (12)	C52—C51—C56—C55	0.3 (5)
I—Ag—P1—C11	−58.94 (11)	P2—C51—C56—C55	−179.8 (3)
P1—Ag—P2—C41	−80.36 (12)	C41—P2—C61—C66	8.3 (3)
P3—Ag—P2—C41	54.29 (13)	C51—P2—C61—C66	117.3 (3)
I—Ag—P2—C41	172.13 (12)	Ag—P2—C61—C66	−121.3 (3)
P1—Ag—P2—C61	42.91 (13)	C41—P2—C61—C62	−173.4 (3)
P3—Ag—P2—C61	177.56 (13)	C51—P2—C61—C62	−64.4 (3)
I—Ag—P2—C61	−64.59 (13)	Ag—P2—C61—C62	57.0 (3)
P1—Ag—P2—C51	160.22 (11)	C66—C61—C62—C63	−2.7 (6)
P3—Ag—P2—C51	−65.14 (12)	P2—C61—C62—C63	178.9 (3)
I—Ag—P2—C51	52.71 (11)	C61—C62—C63—C64	1.7 (7)
P1—Ag—P3—C81	−144.81 (11)	C62—C63—C64—C65	0.5 (7)
P2—Ag—P3—C81	83.31 (12)	C62—C63—C64—C67	179.2 (4)
I—Ag—P3—C81	−27.03 (12)	C63—C64—C65—C66	−1.7 (6)
P1—Ag—P3—C71	94.22 (12)	C67—C64—C65—C66	179.6 (4)
P2—Ag—P3—C71	−37.67 (12)	C62—C61—C66—C65	1.6 (6)
I—Ag—P3—C71	−148.01 (11)	P2—C61—C66—C65	179.9 (3)
P1—Ag—P3—C91	−26.03 (12)	C64—C65—C66—C61	0.6 (6)
P2—Ag—P3—C91	−157.91 (11)	C81—P3—C71—C72	133.4 (3)
I—Ag—P3—C91	91.75 (12)	C91—P3—C71—C72	27.8 (3)
C21—P1—C11—C16	77.3 (3)	Ag—P3—C71—C72	−98.8 (3)
C31—P1—C11—C16	−30.7 (4)	C81—P3—C71—C76	−53.0 (3)
Ag—P1—C11—C16	−158.6 (3)	C91—P3—C71—C76	−158.5 (3)
C21—P1—C11—C12	−103.3 (3)	Ag—P3—C71—C76	74.8 (3)
C31—P1—C11—C12	148.7 (3)	C76—C71—C72—C73	−0.1 (5)
Ag—P1—C11—C12	20.7 (3)	P3—C71—C72—C73	173.8 (3)
C16—C11—C12—C13	2.3 (7)	C71—C72—C73—C74	1.1 (6)
P1—C11—C12—C13	−177.1 (4)	C72—C73—C74—C75	−0.5 (6)
C11—C12—C13—C14	−0.6 (8)	C72—C73—C74—C77	180.0 (4)
C12—C13—C14—C15	−1.8 (7)	C73—C74—C75—C76	−1.0 (6)
C12—C13—C14—C17	179.7 (4)	C77—C74—C75—C76	178.5 (3)
C13—C14—C15—C16	2.5 (7)	C74—C75—C76—C71	2.1 (6)
C17—C14—C15—C16	−179.0 (4)	C72—C71—C76—C75	−1.5 (5)
C12—C11—C16—C15	−1.7 (6)	P3—C71—C76—C75	−175.4 (3)
P1—C11—C16—C15	177.7 (3)	C71—P3—C81—C86	167.5 (3)
C14—C15—C16—C11	−0.7 (7)	C91—P3—C81—C86	−84.5 (3)
C31—P1—C21—C22	137.0 (3)	Ag—P3—C81—C86	42.1 (3)
C11—P1—C21—C22	28.9 (3)	C71—P3—C81—C82	−17.4 (3)
Ag—P1—C21—C22	−98.0 (3)	C91—P3—C81—C82	90.6 (3)
C31—P1—C21—C26	−49.2 (3)	Ag—P3—C81—C82	−142.8 (3)
C11—P1—C21—C26	−157.3 (3)	C86—C81—C82—C83	0.5 (5)
Ag—P1—C21—C26	75.8 (3)	P3—C81—C82—C83	−174.6 (3)
C26—C21—C22—C23	−1.1 (5)	C81—C82—C83—C84	1.5 (6)
P1—C21—C22—C23	172.9 (3)	C82—C83—C84—C85	−2.1 (6)
C21—C22—C23—C24	0.9 (6)	C82—C83—C84—C87	177.9 (4)
C22—C23—C24—C25	0.7 (6)	C83—C84—C85—C86	0.8 (6)
C22—C23—C24—C27	−178.5 (4)	C87—C84—C85—C86	−179.2 (4)
C23—C24—C25—C26	−2.0 (6)	C82—C81—C86—C85	−1.8 (5)
C27—C24—C25—C26	177.1 (4)	P3—C81—C86—C85	173.7 (3)
C24—C25—C26—C21	1.8 (6)	C84—C85—C86—C81	1.2 (6)
C22—C21—C26—C25	−0.2 (5)	C81—P3—C91—C96B	−20.8 (14)
P1—C21—C26—C25	−174.3 (3)	C71—P3—C91—C96B	87.3 (14)
C21—P1—C31—C36	149.1 (3)	Ag—P3—C91—C96B	−147.9 (14)
C11—P1—C31—C36	−103.3 (3)	C81—P3—C91—C92B	162.2 (12)
Ag—P1—C31—C36	25.7 (3)	C71—P3—C91—C92B	−89.8 (12)
C21—P1—C31—C32	−31.3 (3)	Ag—P3—C91—C92B	35.0 (12)
C11—P1—C31—C32	76.2 (3)	C81—P3—C91—C96	−55.5 (7)
Ag—P1—C31—C32	−154.7 (2)	C71—P3—C91—C96	52.5 (7)
C36—C31—C32—C33	0.3 (5)	Ag—P3—C91—C96	177.3 (6)
P1—C31—C32—C33	−179.3 (3)	C81—P3—C91—C92	117.6 (6)
C31—C32—C33—C34	−0.1 (5)	C71—P3—C91—C92	−134.4 (6)
C32—C33—C34—C35	−0.4 (5)	Ag—P3—C91—C92	−9.6 (6)
C32—C33—C34—C37	−179.4 (4)	C96B—C91—C92—C93	−29.6 (12)
C33—C34—C35—C36	0.9 (5)	C92B—C91—C92—C93	81.7 (13)
C37—C34—C35—C36	179.8 (4)	C96—C91—C92—C93	−1.3 (9)
C34—C35—C36—C31	−0.8 (5)	P3—C91—C92—C93	−174.8 (5)
C32—C31—C36—C35	0.2 (5)	C91—C92—C93—C94	2.0 (14)
P1—C31—C36—C35	179.8 (3)	C92—C93—C94—C95	−4.5 (19)
C61—P2—C41—C46	−114.9 (3)	C92—C93—C94—C97	179.8 (11)
C51—P2—C41—C46	138.1 (3)	C93—C94—C95—C96	7 (2)
Ag—P2—C41—C46	16.0 (3)	C97—C94—C95—C96	−177.8 (13)
C61—P2—C41—C42	63.4 (3)	C96B—C91—C96—C95	75 (3)
C51—P2—C41—C42	−43.5 (3)	C92B—C91—C96—C95	−37.1 (12)
Ag—P2—C41—C42	−165.7 (3)	C92—C91—C96—C95	3.6 (12)
C46—C41—C42—C43	0.1 (5)	P3—C91—C96—C95	176.6 (8)
P2—C41—C42—C43	−178.3 (3)	C94—C95—C96—C91	−6.4 (18)
C41—C42—C43—C44	−1.1 (6)	C96B—C91—C92B—C93B	−0.6 (13)
C42—C43—C44—C45	0.8 (6)	C96—C91—C92B—C93B	28.9 (12)
C42—C43—C44—C47	−179.2 (4)	C92—C91—C92B—C93B	−84.5 (13)
C43—C44—C45—C46	0.5 (6)	P3—C91—C92B—C93B	176.7 (8)
C47—C44—C45—C46	−179.5 (4)	C91—C92B—C93B—C94B	0.0 (18)
C42—C41—C46—C45	1.2 (5)	C92B—C93B—C94B—C95B	4 (3)
P2—C41—C46—C45	179.6 (3)	C92B—C93B—C94B—C97B	−179.4 (16)
C44—C45—C46—C41	−1.5 (6)	C93B—C94B—C95B—C96B	−6 (4)
C41—P2—C51—C52	−100.8 (3)	C97B—C94B—C95B—C96B	176 (2)
C61—P2—C51—C52	151.8 (3)	C92B—C91—C96B—C95B	−2 (2)
Ag—P2—C51—C52	25.0 (3)	C96—C91—C96B—C95B	−81 (3)
C41—P2—C51—C56	79.3 (3)	C92—C91—C96B—C95B	38 (2)
C61—P2—C51—C56	−28.1 (3)	P3—C91—C96B—C95B	−179.4 (17)
Ag—P2—C51—C56	−154.9 (3)	C94B—C95B—C96B—C91	6 (4)
C56—C51—C52—C53	−0.8 (5)