Octabenzyl­di-μ3-oxo-bis­(μ-2,3,4,5-tetra­fluoro­benzoato-κ2O:O′)bis(2,3,4,5-tetra­fluoro­benzoato-κO)tetratin(IV)

Sun, J.; Qiu, L.; Zhang, R.; Ma, C.

doi:10.1107/S1600536806051397

Octabenzyldi-μ₃-oxo-bis(μ-2,3,4,5-tetrafluorobenzoato-κ²O:O′)bis(2,3,4,5-tetrafluorobenzoato-κO)tetratin(IV)

The structure of the title compound, [Sn₄(C₇H₇)₈(C₇HF₄O₂)₄O₂], features a central Sn₂O₂ unit with two additional Sn atoms linked by the μ₃-oxo atoms. Two pairs of Sn atoms are bridged by two bidentate 2,3,4,5-tetrafluorobenzoate ligands. Two of the Sn atoms are also each coordinated by a monodentate 2,3,4,5-tetrafluorobenzoate ligand. The geometry around each five-coordinated Sn center is distorted trigonal bipyramidal.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806051397/hy2028sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806051397/hy2028Isup2.hkl Contains datablock I

CCDC reference: 633891

checkCIF report

Key indicators

Single-crystal X-ray study
T = 295 K
Mean (C-C) = 0.009 Å
R factor = 0.040
wR factor = 0.096
Data-to-parameter ratio = 13.9

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000)         200 Deg.
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.04 Ratio
PLAT230_ALERT_2_C Hirshfeld Test Diff for    F9     -   C73     ..       6.93 su
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O1
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C25
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C32
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C39
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C23
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C30
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C37
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C51
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C83
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C23    -C28           1.36 Ang.
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C30    -C35           1.36 Ang.
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          9

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  15 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  13 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.

(I) top

Crystal data top

C₈₄H₆₀F₁₆O₁₀Sn₄	Z = 2
M_r = 2008.08	F(000) = 1976
Triclinic, P1	D_x = 1.720 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 11.9014 (9) Å	Cell parameters from 7092 reflections
b = 12.122 (1) Å	θ = 2.3–25.7°
c = 29.070 (2) Å	µ = 1.37 mm⁻¹
α = 99.171 (2)°	T = 295 K
β = 91.623 (2)°	Block, colorless
γ = 109.922 (2)°	0.27 × 0.13 × 0.08 mm
V = 3877.2 (5) Å³

Data collection top

Bruker 1000 CCD area detector diffractometer	14288 independent reflections
Radiation source: fine-focus sealed tube	9736 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.031
φ and ω scans	θ_max = 25.5°, θ_min = 1.4°
Absorption correction: multi-scan SADABS (Sheldrick, 1996)	h = −14→14
T_min = 0.708, T_max = 0.898	k = −14→14
29322 measured reflections	l = −35→35

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.096	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.041P)² + 0.1235P] where P = (F_o² + 2F_c²)/3
14288 reflections	(Δ/σ)_max = 0.002
1027 parameters	Δρ_max = 0.72 e Å⁻³
1632 restraints	Δρ_min = −0.64 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Sn1	0.17251 (3)	0.91428 (3)	0.686589 (10)	0.03794 (9)
Sn2	0.37089 (3)	1.23796 (3)	0.711324 (10)	0.04049 (9)
Sn3	0.29903 (3)	1.03004 (3)	0.794951 (10)	0.03853 (9)
Sn4	0.10001 (3)	0.71028 (3)	0.772533 (10)	0.04047 (9)
F1	0.0924 (3)	0.8919 (3)	0.53375 (10)	0.0803 (9)
F2	0.0718 (3)	0.9251 (3)	0.44655 (11)	0.1013 (12)
F3	0.1897 (4)	1.1370 (4)	0.42226 (11)	0.1222 (14)
F4	0.3332 (4)	1.3187 (4)	0.48727 (13)	0.1346 (16)
F5	0.4791 (3)	1.2250 (3)	0.87171 (10)	0.0870 (10)
F6	0.5544 (3)	1.3120 (3)	0.96108 (11)	0.1032 (12)
F7	0.6326 (3)	1.5473 (3)	0.99348 (10)	0.0979 (11)
F8	0.6343 (4)	1.6990 (3)	0.93557 (12)	0.1378 (18)
F9	0.0349 (3)	0.6976 (3)	0.60773 (10)	0.0865 (10)
F10	−0.0604 (3)	0.6087 (3)	0.52208 (10)	0.0929 (11)
F11	−0.1902 (3)	0.3754 (3)	0.49676 (11)	0.1106 (13)
F12	−0.2288 (3)	0.2308 (3)	0.56093 (13)	0.1110 (13)
F13	0.3960 (3)	1.0591 (3)	0.94366 (10)	0.0914 (11)
F14	0.4076 (4)	1.0403 (3)	1.03267 (11)	0.1143 (14)
F15	0.2641 (4)	0.8447 (3)	1.06282 (10)	0.1134 (13)
F16	0.1061 (4)	0.6649 (3)	1.00158 (11)	0.1219 (16)
O1	0.3221 (3)	1.1651 (3)	0.63443 (10)	0.0596 (9)
O2	0.1703 (3)	0.9928 (3)	0.62270 (10)	0.0554 (9)
O3	0.4188 (3)	1.2699 (3)	0.78690 (10)	0.0508 (8)
O4	0.5006 (4)	1.4572 (3)	0.77816 (12)	0.0753 (11)
O5	0.2773 (2)	1.0747 (2)	0.72494 (9)	0.0396 (7)
O6	0.1832 (2)	0.8746 (2)	0.75681 (9)	0.0403 (7)
O7	0.0611 (3)	0.6656 (3)	0.69680 (9)	0.0483 (8)
O8	−0.0228 (3)	0.4825 (3)	0.71039 (11)	0.0660 (10)
O9	0.1391 (3)	0.7956 (3)	0.84817 (10)	0.0535 (8)
O10	0.3093 (3)	0.9508 (3)	0.85664 (10)	0.0524 (8)
C1	0.5514 (4)	1.2716 (4)	0.69374 (17)	0.0569 (13)
H1A	0.6040	1.2916	0.7223	0.068*
H1B	0.5567	1.1995	0.6755	0.068*
C2	0.5937 (4)	1.3714 (5)	0.66634 (18)	0.0579 (13)
C3	0.5746 (5)	1.3475 (6)	0.6180 (2)	0.0755 (16)
H3	0.5388	1.2694	0.6022	0.091*
C4	0.6095 (6)	1.4419 (7)	0.5929 (2)	0.097 (2)
H4	0.5951	1.4270	0.5605	0.116*
C5	0.6644 (6)	1.5551 (7)	0.6165 (3)	0.099 (2)
H5	0.6877	1.6174	0.5998	0.118*
C6	0.6860 (5)	1.5796 (6)	0.6634 (3)	0.093 (2)
H6	0.7244	1.6578	0.6787	0.112*
C7	0.6506 (5)	1.4875 (5)	0.6889 (2)	0.0732 (16)
H7	0.6655	1.5043	0.7213	0.088*
C8	0.2529 (5)	1.3361 (4)	0.71068 (16)	0.0571 (13)
H8A	0.1709	1.2811	0.7088	0.069*
H8B	0.2678	1.3916	0.7401	0.069*
C9	0.2648 (5)	1.4037 (5)	0.67163 (18)	0.0576 (13)
C10	0.1824 (5)	1.3631 (5)	0.6326 (2)	0.0742 (16)
H10	0.1174	1.2926	0.6311	0.089*
C11	0.1950 (7)	1.4253 (7)	0.5957 (2)	0.095 (2)
H11	0.1383	1.3979	0.5700	0.114*
C12	0.2916 (8)	1.5273 (8)	0.5979 (3)	0.104 (2)
H12	0.3015	1.5686	0.5731	0.124*
C13	0.3739 (7)	1.5697 (6)	0.6357 (3)	0.097 (2)
H13	0.4393	1.6395	0.6366	0.116*
C14	0.3600 (5)	1.5086 (5)	0.6727 (2)	0.0769 (17)
H14	0.4157	1.5388	0.6988	0.092*
C15	0.2927 (4)	0.8259 (4)	0.66145 (15)	0.0488 (12)
H15A	0.3387	0.8200	0.6884	0.059*
H15B	0.2445	0.7452	0.6467	0.059*
C16	0.3799 (4)	0.8786 (4)	0.62764 (15)	0.0463 (11)
C17	0.4977 (5)	0.9461 (5)	0.64169 (18)	0.0646 (14)
H17	0.5248	0.9622	0.6732	0.077*
C18	0.5777 (5)	0.9911 (5)	0.6092 (2)	0.0853 (19)
H18	0.6564	1.0401	0.6192	0.102*
C19	0.5402 (6)	0.9630 (6)	0.5634 (2)	0.0840 (19)
H19	0.5941	0.9900	0.5416	0.101*
C20	0.4242 (6)	0.8954 (6)	0.54861 (19)	0.0793 (17)
H20	0.3986	0.8779	0.5169	0.095*
C21	0.3449 (5)	0.8531 (4)	0.58034 (16)	0.0606 (14)
H21	0.2658	0.8062	0.5698	0.073*
C22	−0.0164 (4)	0.8801 (4)	0.68131 (16)	0.0531 (12)
H22A	−0.0454	0.8572	0.6484	0.064*
H22B	−0.0549	0.8121	0.6961	0.064*
C23	−0.0568 (4)	0.9795 (4)	0.70212 (17)	0.0511 (12)
C24	−0.0419 (6)	1.0753 (6)	0.6811 (2)	0.090 (2)
H24	−0.0065	1.0791	0.6530	0.108*
C25	−0.0784 (7)	1.1665 (6)	0.7008 (3)	0.119 (3)
H25	−0.0650	1.2325	0.6863	0.142*
C26	−0.1331 (6)	1.1620 (6)	0.7404 (3)	0.116 (3)
H26	−0.1587	1.2239	0.7530	0.140*
C27	−0.1510 (6)	1.0673 (7)	0.7621 (3)	0.109 (2)
H27	−0.1891	1.0631	0.7896	0.131*
C28	−0.1114 (5)	0.9764 (5)	0.7423 (2)	0.0775 (17)
H28	−0.1228	0.9115	0.7572	0.093*
C29	0.1851 (4)	1.1219 (4)	0.82406 (16)	0.0566 (13)
H29A	0.2297	1.2066	0.8270	0.068*
H29B	0.1177	1.1030	0.8010	0.068*
C30	0.1352 (5)	1.1030 (4)	0.86945 (17)	0.0533 (12)
C31	0.1962 (6)	1.1712 (6)	0.9105 (2)	0.0890 (19)
H31	0.2725	1.2264	0.9097	0.107*
C32	0.1497 (8)	1.1615 (7)	0.9527 (2)	0.123 (3)
H32	0.1946	1.2083	0.9800	0.147*
C33	0.0413 (8)	1.0859 (8)	0.9545 (3)	0.114 (3)
H33	0.0079	1.0835	0.9830	0.137*
C34	−0.0229 (7)	1.0114 (7)	0.9158 (3)	0.113 (2)
H34	−0.0973	0.9543	0.9179	0.136*
C35	0.0244 (6)	1.0215 (6)	0.8724 (2)	0.0895 (19)
H35	−0.0200	0.9722	0.8454	0.107*
C36	0.4794 (4)	1.0406 (4)	0.78316 (16)	0.0518 (12)
H36A	0.4863	1.0374	0.7498	0.062*
H36B	0.5319	1.1192	0.7985	0.062*
C37	0.5301 (4)	0.9530 (4)	0.79752 (16)	0.0475 (12)
C38	0.5810 (5)	0.9694 (5)	0.84199 (19)	0.0748 (16)
H38	0.5757	1.0309	0.8645	0.090*
C39	0.6398 (6)	0.8970 (7)	0.8542 (2)	0.100 (2)
H39	0.6744	0.9109	0.8846	0.119*
C40	0.6480 (6)	0.8064 (6)	0.8227 (3)	0.089 (2)
H40	0.6905	0.7597	0.8309	0.106*
C41	0.5936 (5)	0.7837 (5)	0.7789 (2)	0.0797 (17)
H41	0.5953	0.7188	0.7574	0.096*
C42	0.5357 (5)	0.8570 (5)	0.76616 (19)	0.0659 (14)
H42	0.4999	0.8414	0.7359	0.079*
C43	−0.0830 (4)	0.6732 (4)	0.78753 (16)	0.0541 (13)
H43A	−0.0936	0.7475	0.8005	0.065*
H43B	−0.1343	0.6400	0.7585	0.065*
C44	−0.1223 (4)	0.5885 (5)	0.82096 (19)	0.0617 (14)
C45	−0.1680 (5)	0.4664 (5)	0.8045 (2)	0.0844 (18)
H45	−0.1791	0.4367	0.7725	0.101*
C46	−0.1973 (6)	0.3887 (7)	0.8364 (3)	0.110 (2)
H46	−0.2285	0.3067	0.8258	0.132*
C47	−0.1806 (7)	0.4322 (9)	0.8826 (3)	0.117 (3)
H47	−0.1985	0.3788	0.9033	0.141*
C48	−0.1389 (6)	0.5504 (8)	0.9001 (3)	0.111 (3)
H48	−0.1287	0.5781	0.9322	0.134*
C49	−0.1110 (5)	0.6311 (6)	0.8683 (2)	0.0879 (19)
H49	−0.0851	0.7128	0.8794	0.106*
C50	0.2284 (4)	0.6257 (4)	0.77912 (17)	0.0591 (13)
H50A	0.2157	0.5635	0.7519	0.071*
H50B	0.3080	0.6839	0.7790	0.071*
C51	0.2245 (5)	0.5725 (5)	0.8215 (2)	0.0651 (15)
C52	0.3083 (6)	0.6294 (7)	0.8594 (2)	0.097 (2)
H52	0.3695	0.7004	0.8574	0.117*
C53	0.3031 (8)	0.5826 (9)	0.9007 (3)	0.128 (3)
H53	0.3588	0.6203	0.9265	0.154*
C54	0.2135 (10)	0.4811 (10)	0.9006 (3)	0.131 (3)
H54	0.2061	0.4524	0.9286	0.157*
C55	0.1295 (8)	0.4126 (8)	0.8640 (4)	0.130 (3)
H55	0.0731	0.3387	0.8660	0.156*
C56	0.1364 (6)	0.4640 (6)	0.8234 (3)	0.101 (2)
H56	0.0812	0.4246	0.7976	0.121*
C57	0.2413 (4)	1.0828 (4)	0.60923 (15)	0.0430 (11)
C58	0.2273 (4)	1.0911 (4)	0.55843 (16)	0.0485 (12)
C59	0.1541 (5)	0.9986 (5)	0.52448 (17)	0.0576 (13)
C60	0.1429 (5)	1.0147 (6)	0.47873 (18)	0.0679 (15)
C61	0.2030 (6)	1.1219 (6)	0.46689 (19)	0.0782 (18)
C62	0.2751 (6)	1.2131 (6)	0.5003 (2)	0.0805 (18)
C63	0.2881 (5)	1.1989 (5)	0.54554 (17)	0.0654 (15)
H63	0.3381	1.2620	0.5677	0.078*
C64	0.4762 (4)	1.3808 (4)	0.80271 (16)	0.0483 (12)
C65	0.5141 (4)	1.4179 (4)	0.85439 (16)	0.0479 (12)
C66	0.5137 (4)	1.3438 (4)	0.88521 (16)	0.0539 (13)
C67	0.5519 (5)	1.3859 (5)	0.93199 (17)	0.0628 (14)
C68	0.5923 (5)	1.5045 (5)	0.94843 (17)	0.0680 (15)
C69	0.5927 (6)	1.5812 (5)	0.9185 (2)	0.0760 (17)
C70	0.5545 (5)	1.5391 (5)	0.87208 (17)	0.0677 (15)
H70	0.5558	1.5925	0.8522	0.081*
C71	−0.0012 (4)	0.5531 (4)	0.68336 (16)	0.0488 (12)
C72	−0.0478 (4)	0.5098 (4)	0.63303 (15)	0.0474 (12)
C73	−0.0290 (4)	0.5798 (4)	0.59914 (17)	0.0520 (12)
C74	−0.0766 (5)	0.5365 (5)	0.55340 (17)	0.0629 (14)
C75	−0.1427 (5)	0.4183 (5)	0.54113 (19)	0.0709 (16)
C76	−0.1612 (5)	0.3474 (5)	0.5738 (2)	0.0704 (16)
C77	−0.1158 (4)	0.3893 (4)	0.61933 (18)	0.0596 (14)
H77	−0.1300	0.3382	0.6409	0.072*
C78	0.2281 (4)	0.8715 (4)	0.87218 (15)	0.0464 (11)
C79	0.2397 (4)	0.8698 (4)	0.92380 (15)	0.0495 (12)
C80	0.3206 (5)	0.9592 (5)	0.95547 (17)	0.0623 (14)
C81	0.3281 (5)	0.9515 (5)	1.00224 (18)	0.0741 (17)
C82	0.2555 (6)	0.8530 (6)	1.01751 (18)	0.0767 (17)
C83	0.1759 (5)	0.7640 (5)	0.98606 (18)	0.0722 (16)
C84	0.1663 (5)	0.7706 (5)	0.93989 (17)	0.0661 (15)
H84	0.1104	0.7085	0.9191	0.079*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.04338 (19)	0.03929 (18)	0.02841 (17)	0.01017 (15)	0.00150 (13)	0.00821 (13)
Sn2	0.0497 (2)	0.03717 (18)	0.03388 (17)	0.01157 (15)	0.00317 (14)	0.01254 (14)
Sn3	0.04608 (19)	0.03953 (18)	0.02818 (17)	0.01166 (15)	0.00268 (14)	0.00848 (13)
Sn4	0.0499 (2)	0.03812 (18)	0.03187 (17)	0.01066 (15)	0.00574 (14)	0.01224 (13)
F1	0.098 (2)	0.071 (2)	0.0544 (19)	0.0118 (19)	−0.0127 (17)	0.0059 (16)
F2	0.113 (3)	0.135 (3)	0.048 (2)	0.043 (3)	−0.0190 (19)	−0.003 (2)
F3	0.152 (3)	0.190 (4)	0.042 (2)	0.067 (3)	0.009 (2)	0.055 (2)
F4	0.177 (4)	0.132 (4)	0.087 (3)	0.018 (3)	0.014 (3)	0.074 (3)
F5	0.134 (3)	0.0538 (19)	0.058 (2)	0.014 (2)	−0.0156 (19)	0.0138 (15)
F6	0.150 (3)	0.090 (3)	0.052 (2)	0.015 (2)	−0.014 (2)	0.0245 (18)
F7	0.130 (3)	0.100 (3)	0.0435 (19)	0.026 (2)	−0.0151 (19)	−0.0091 (17)
F8	0.243 (5)	0.067 (2)	0.080 (3)	0.043 (3)	−0.040 (3)	−0.022 (2)
F9	0.119 (3)	0.070 (2)	0.0500 (19)	0.007 (2)	−0.0014 (18)	0.0125 (16)
F10	0.117 (3)	0.110 (3)	0.0442 (19)	0.025 (2)	−0.0004 (18)	0.0246 (18)
F11	0.120 (3)	0.119 (3)	0.060 (2)	0.021 (2)	−0.031 (2)	−0.021 (2)
F12	0.120 (3)	0.057 (2)	0.117 (3)	0.002 (2)	−0.035 (2)	−0.021 (2)
F13	0.114 (3)	0.068 (2)	0.059 (2)	−0.013 (2)	−0.0090 (19)	0.0217 (17)
F14	0.145 (3)	0.107 (3)	0.048 (2)	−0.003 (3)	−0.027 (2)	0.0034 (19)
F15	0.155 (4)	0.130 (3)	0.0405 (19)	0.023 (3)	0.002 (2)	0.032 (2)
F16	0.160 (4)	0.104 (3)	0.065 (2)	−0.016 (3)	0.012 (2)	0.049 (2)
O1	0.079 (2)	0.058 (2)	0.0318 (18)	0.010 (2)	0.0058 (17)	0.0116 (16)
O2	0.062 (2)	0.060 (2)	0.0394 (19)	0.0098 (18)	−0.0024 (16)	0.0207 (16)
O3	0.065 (2)	0.0456 (19)	0.0339 (17)	0.0088 (17)	−0.0001 (15)	0.0088 (15)
O4	0.112 (3)	0.050 (2)	0.053 (2)	0.011 (2)	0.001 (2)	0.0177 (18)
O5	0.0470 (18)	0.0312 (16)	0.0333 (16)	0.0030 (14)	0.0016 (13)	0.0095 (13)
O6	0.0529 (19)	0.0365 (16)	0.0273 (15)	0.0088 (14)	0.0002 (13)	0.0096 (13)
O7	0.063 (2)	0.0444 (19)	0.0299 (17)	0.0088 (16)	0.0039 (15)	0.0077 (14)
O8	0.096 (3)	0.045 (2)	0.048 (2)	0.0094 (19)	0.0061 (19)	0.0173 (17)
O9	0.061 (2)	0.059 (2)	0.0324 (18)	0.0109 (18)	0.0014 (16)	0.0080 (15)
O10	0.057 (2)	0.060 (2)	0.0403 (18)	0.0149 (18)	0.0006 (16)	0.0240 (16)
C1	0.048 (3)	0.062 (3)	0.063 (3)	0.018 (3)	0.008 (2)	0.024 (3)
C2	0.038 (3)	0.078 (4)	0.063 (3)	0.019 (3)	0.013 (2)	0.028 (3)
C3	0.064 (4)	0.104 (5)	0.063 (4)	0.026 (3)	0.021 (3)	0.031 (3)
C4	0.068 (4)	0.152 (6)	0.085 (5)	0.037 (5)	0.024 (4)	0.062 (5)
C5	0.071 (5)	0.128 (6)	0.116 (6)	0.031 (4)	0.035 (4)	0.081 (5)
C6	0.068 (4)	0.087 (5)	0.122 (6)	0.010 (3)	0.020 (4)	0.047 (4)
C7	0.056 (3)	0.074 (4)	0.085 (4)	0.007 (3)	0.015 (3)	0.038 (3)
C8	0.071 (3)	0.061 (3)	0.048 (3)	0.033 (3)	0.008 (3)	0.014 (2)
C9	0.072 (4)	0.063 (3)	0.055 (3)	0.042 (3)	0.012 (3)	0.019 (3)
C10	0.076 (4)	0.092 (4)	0.071 (4)	0.046 (3)	0.006 (3)	0.027 (3)
C11	0.113 (5)	0.131 (6)	0.077 (4)	0.081 (5)	0.006 (4)	0.035 (4)
C12	0.139 (7)	0.131 (6)	0.097 (5)	0.095 (6)	0.051 (5)	0.068 (5)
C13	0.109 (5)	0.072 (4)	0.138 (6)	0.052 (4)	0.048 (5)	0.052 (4)
C14	0.091 (4)	0.059 (4)	0.093 (4)	0.036 (3)	0.015 (3)	0.029 (3)
C15	0.055 (3)	0.045 (3)	0.049 (3)	0.020 (2)	0.010 (2)	0.013 (2)
C16	0.055 (3)	0.044 (3)	0.038 (3)	0.016 (2)	0.008 (2)	0.004 (2)
C17	0.063 (4)	0.074 (4)	0.051 (3)	0.018 (3)	0.006 (3)	0.007 (3)
C18	0.057 (4)	0.086 (4)	0.093 (5)	0.003 (3)	0.019 (4)	0.004 (4)
C19	0.096 (5)	0.090 (5)	0.072 (4)	0.031 (4)	0.040 (4)	0.031 (4)
C20	0.091 (5)	0.104 (5)	0.049 (3)	0.037 (4)	0.021 (3)	0.023 (3)
C21	0.066 (3)	0.062 (3)	0.044 (3)	0.014 (3)	0.007 (3)	0.002 (3)
C22	0.043 (3)	0.054 (3)	0.054 (3)	0.007 (2)	−0.004 (2)	0.009 (2)
C23	0.044 (3)	0.061 (3)	0.051 (3)	0.017 (2)	0.001 (2)	0.022 (3)
C24	0.099 (5)	0.093 (5)	0.112 (5)	0.056 (4)	0.046 (4)	0.058 (4)
C25	0.114 (6)	0.093 (5)	0.183 (8)	0.054 (5)	0.051 (5)	0.072 (5)
C26	0.094 (5)	0.075 (5)	0.186 (8)	0.043 (4)	0.038 (5)	0.005 (5)
C27	0.101 (5)	0.118 (6)	0.117 (6)	0.050 (5)	0.040 (4)	0.012 (5)
C28	0.078 (4)	0.084 (4)	0.085 (4)	0.037 (3)	0.027 (3)	0.032 (3)
C29	0.068 (3)	0.064 (3)	0.052 (3)	0.036 (3)	0.017 (3)	0.017 (3)
C30	0.067 (3)	0.053 (3)	0.045 (3)	0.026 (3)	0.020 (3)	0.010 (2)
C31	0.104 (5)	0.090 (4)	0.061 (4)	0.020 (4)	0.021 (4)	0.007 (3)
C32	0.152 (7)	0.147 (7)	0.066 (5)	0.052 (6)	0.023 (5)	0.012 (5)
C33	0.144 (7)	0.143 (7)	0.076 (5)	0.063 (6)	0.049 (5)	0.042 (5)
C34	0.094 (5)	0.128 (6)	0.126 (6)	0.033 (5)	0.054 (5)	0.049 (5)
C35	0.079 (4)	0.102 (5)	0.080 (4)	0.022 (4)	0.024 (4)	0.014 (4)
C36	0.048 (3)	0.061 (3)	0.050 (3)	0.020 (3)	0.009 (2)	0.018 (2)
C37	0.040 (3)	0.051 (3)	0.046 (3)	0.007 (2)	0.002 (2)	0.011 (2)
C38	0.077 (4)	0.104 (5)	0.052 (3)	0.049 (4)	−0.007 (3)	0.005 (3)
C39	0.097 (5)	0.155 (6)	0.073 (5)	0.070 (5)	0.000 (4)	0.038 (4)
C40	0.083 (5)	0.095 (5)	0.114 (6)	0.048 (4)	0.018 (4)	0.051 (4)
C41	0.076 (4)	0.063 (4)	0.100 (5)	0.032 (3)	0.007 (4)	−0.001 (3)
C42	0.065 (4)	0.066 (4)	0.067 (4)	0.027 (3)	−0.003 (3)	0.005 (3)
C43	0.045 (3)	0.060 (3)	0.059 (3)	0.016 (2)	0.006 (2)	0.021 (3)
C44	0.043 (3)	0.081 (4)	0.067 (4)	0.019 (3)	0.014 (3)	0.034 (3)
C45	0.077 (4)	0.078 (4)	0.106 (5)	0.021 (3)	0.040 (4)	0.048 (4)
C46	0.099 (5)	0.108 (5)	0.145 (7)	0.040 (4)	0.060 (5)	0.073 (5)
C47	0.085 (5)	0.173 (8)	0.125 (7)	0.048 (6)	0.041 (5)	0.104 (7)
C48	0.067 (4)	0.175 (7)	0.081 (5)	0.013 (5)	0.012 (4)	0.056 (5)
C49	0.061 (4)	0.128 (5)	0.068 (4)	0.015 (4)	0.019 (3)	0.039 (4)
C50	0.066 (3)	0.063 (3)	0.058 (3)	0.033 (3)	0.016 (3)	0.013 (3)
C51	0.073 (4)	0.080 (4)	0.066 (4)	0.052 (3)	0.013 (3)	0.026 (3)
C52	0.107 (5)	0.129 (5)	0.085 (5)	0.079 (4)	0.003 (4)	0.021 (4)
C53	0.142 (7)	0.177 (8)	0.100 (6)	0.111 (6)	−0.015 (5)	0.008 (6)
C54	0.167 (9)	0.182 (9)	0.098 (6)	0.117 (7)	0.024 (6)	0.053 (6)
C55	0.145 (7)	0.117 (6)	0.172 (8)	0.074 (6)	0.065 (6)	0.081 (6)
C56	0.114 (5)	0.099 (5)	0.121 (6)	0.055 (4)	0.035 (4)	0.063 (4)
C57	0.048 (3)	0.054 (3)	0.032 (3)	0.023 (2)	0.007 (2)	0.009 (2)
C58	0.055 (3)	0.061 (3)	0.038 (3)	0.026 (3)	0.007 (2)	0.019 (2)
C59	0.069 (4)	0.067 (4)	0.042 (3)	0.028 (3)	0.005 (3)	0.014 (3)
C60	0.077 (4)	0.094 (4)	0.039 (3)	0.041 (4)	−0.004 (3)	0.005 (3)
C61	0.097 (5)	0.112 (5)	0.039 (3)	0.046 (4)	0.011 (3)	0.028 (3)
C62	0.100 (5)	0.091 (5)	0.057 (4)	0.027 (4)	0.016 (3)	0.042 (3)
C63	0.079 (4)	0.075 (4)	0.042 (3)	0.022 (3)	0.008 (3)	0.025 (3)
C64	0.049 (3)	0.048 (3)	0.042 (3)	0.010 (2)	0.008 (2)	0.007 (2)
C65	0.050 (3)	0.048 (3)	0.041 (3)	0.012 (2)	0.003 (2)	0.006 (2)
C66	0.067 (3)	0.043 (3)	0.040 (3)	0.007 (3)	0.006 (2)	0.001 (2)
C67	0.070 (4)	0.073 (4)	0.040 (3)	0.016 (3)	0.003 (3)	0.018 (3)
C68	0.076 (4)	0.079 (4)	0.035 (3)	0.017 (3)	−0.003 (3)	−0.006 (3)
C69	0.108 (5)	0.057 (4)	0.052 (3)	0.024 (3)	−0.010 (3)	−0.008 (3)
C70	0.094 (4)	0.058 (3)	0.047 (3)	0.024 (3)	−0.005 (3)	0.006 (3)
C71	0.059 (3)	0.043 (3)	0.041 (3)	0.012 (2)	0.012 (2)	0.007 (2)
C72	0.050 (3)	0.051 (3)	0.036 (3)	0.013 (2)	0.003 (2)	0.002 (2)
C73	0.053 (3)	0.042 (3)	0.049 (3)	0.006 (2)	0.004 (2)	−0.002 (2)
C74	0.063 (4)	0.080 (4)	0.040 (3)	0.019 (3)	0.006 (3)	0.011 (3)
C75	0.071 (4)	0.078 (4)	0.046 (3)	0.017 (3)	−0.010 (3)	−0.017 (3)
C76	0.061 (4)	0.053 (3)	0.079 (4)	0.009 (3)	−0.011 (3)	−0.012 (3)
C77	0.056 (3)	0.054 (3)	0.064 (4)	0.017 (3)	−0.002 (3)	0.002 (3)
C78	0.058 (3)	0.057 (3)	0.034 (3)	0.030 (3)	0.012 (2)	0.014 (2)
C79	0.068 (3)	0.059 (3)	0.026 (2)	0.026 (3)	0.003 (2)	0.015 (2)
C80	0.076 (4)	0.071 (4)	0.038 (3)	0.018 (3)	0.004 (3)	0.021 (3)
C81	0.091 (4)	0.077 (4)	0.036 (3)	0.010 (3)	−0.010 (3)	0.007 (3)
C82	0.102 (5)	0.090 (4)	0.034 (3)	0.025 (4)	0.007 (3)	0.019 (3)
C83	0.099 (4)	0.073 (4)	0.042 (3)	0.017 (3)	0.013 (3)	0.029 (3)
C84	0.081 (4)	0.072 (4)	0.040 (3)	0.018 (3)	0.005 (3)	0.013 (3)

Geometric parameters (Å, º) top

Sn1—O5	2.039 (3)	C25—C26	1.339 (9)
Sn1—C22	2.139 (4)	C25—H25	0.9300
Sn1—C15	2.140 (4)	C26—C27	1.353 (9)
Sn1—O6	2.181 (2)	C26—H26	0.9300
Sn1—O2	2.221 (3)	C27—C28	1.391 (8)
Sn2—O5	2.022 (3)	C27—H27	0.9300
Sn2—C8	2.129 (4)	C28—H28	0.9300
Sn2—C1	2.139 (4)	C29—C30	1.482 (6)
Sn2—O3	2.193 (3)	C29—H29A	0.9700
Sn2—O1	2.250 (3)	C29—H29B	0.9700
Sn2—O4	2.934 (4)	C30—C31	1.364 (7)
Sn3—O6	2.040 (3)	C30—C35	1.366 (7)
Sn3—C29	2.142 (4)	C31—C32	1.365 (8)
Sn3—C36	2.147 (4)	C31—H31	0.9300
Sn3—O10	2.184 (3)	C32—C33	1.312 (9)
Sn3—O5	2.217 (3)	C32—H32	0.9300
Sn4—O6	2.031 (3)	C33—C34	1.349 (9)
Sn4—C50	2.130 (4)	C33—H33	0.9300
Sn4—C43	2.142 (4)	C34—C35	1.402 (8)
Sn4—O7	2.179 (3)	C34—H34	0.9300
Sn4—O8	2.922 (3)	C35—H35	0.9300
Sn4—O9	2.238 (3)	C36—C37	1.492 (6)
F1—C59	1.327 (6)	C36—H36A	0.9700
F2—C60	1.333 (6)	C36—H36B	0.9700
F3—C61	1.351 (6)	C37—C38	1.367 (6)
F4—C62	1.351 (6)	C37—C42	1.382 (6)
F5—C66	1.343 (5)	C38—C39	1.375 (7)
F6—C67	1.333 (5)	C38—H38	0.9300
F7—C68	1.339 (5)	C39—C40	1.346 (8)
F8—C69	1.345 (6)	C39—H39	0.9300
F9—C73	1.347 (5)	C40—C41	1.354 (8)
F10—C74	1.335 (6)	C40—H40	0.9300
F11—C75	1.341 (5)	C41—C42	1.382 (7)
F12—C76	1.351 (6)	C41—H41	0.9300
F13—C80	1.341 (6)	C42—H42	0.9300
F14—C81	1.339 (6)	C43—C44	1.495 (6)
F15—C82	1.341 (5)	C43—H43A	0.9700
F16—C83	1.360 (6)	C43—H43B	0.9700
O1—C57	1.237 (5)	C44—C49	1.376 (7)
O2—C57	1.260 (5)	C44—C45	1.388 (7)
O3—C64	1.282 (5)	C45—C46	1.395 (8)
O4—C64	1.221 (5)	C45—H45	0.9300
O7—C71	1.299 (5)	C46—C47	1.343 (10)
O8—C71	1.222 (5)	C46—H46	0.9300
O9—C78	1.243 (5)	C47—C48	1.353 (10)
O10—C78	1.262 (5)	C47—H47	0.9300
C1—C2	1.506 (6)	C48—C49	1.416 (8)
C1—H1A	0.9700	C48—H48	0.9300
C1—H1B	0.9700	C49—H49	0.9300
C2—C7	1.378 (7)	C50—C51	1.474 (6)
C2—C3	1.385 (7)	C50—H50A	0.9700
C3—C4	1.404 (8)	C50—H50B	0.9700
C3—H3	0.9300	C51—C52	1.381 (8)
C4—C5	1.358 (9)	C51—C56	1.385 (8)
C4—H4	0.9300	C52—C53	1.404 (9)
C5—C6	1.348 (9)	C52—H52	0.9300
C5—H5	0.9300	C53—C54	1.325 (11)
C6—C7	1.390 (7)	C53—H53	0.9300
C6—H6	0.9300	C54—C55	1.383 (11)
C7—H7	0.9300	C54—H54	0.9300
C8—C9	1.486 (6)	C55—C56	1.414 (9)
C8—H8A	0.9700	C55—H55	0.9300
C8—H8B	0.9700	C56—H56	0.9300
C9—C14	1.380 (7)	C57—C58	1.504 (6)
C9—C10	1.385 (7)	C58—C63	1.378 (6)
C10—C11	1.391 (8)	C58—C59	1.386 (7)
C10—H10	0.9300	C59—C60	1.384 (6)
C11—C12	1.363 (9)	C60—C61	1.357 (8)
C11—H11	0.9300	C61—C62	1.366 (8)
C12—C13	1.358 (9)	C62—C63	1.365 (7)
C12—H12	0.9300	C63—H63	0.9300
C13—C14	1.384 (8)	C64—C65	1.507 (6)
C13—H13	0.9300	C65—C66	1.366 (6)
C14—H14	0.9300	C65—C70	1.385 (6)
C15—C16	1.503 (6)	C66—C67	1.379 (6)
C15—H15A	0.9700	C67—C68	1.350 (7)
C15—H15B	0.9700	C68—C69	1.369 (7)
C16—C17	1.371 (6)	C69—C70	1.371 (7)
C16—C21	1.380 (6)	C70—H70	0.9300
C17—C18	1.398 (7)	C71—C72	1.495 (6)
C17—H17	0.9300	C72—C73	1.375 (6)
C18—C19	1.345 (8)	C72—C77	1.392 (6)
C18—H18	0.9300	C73—C74	1.377 (6)
C19—C20	1.358 (8)	C74—C75	1.361 (7)
C19—H19	0.9300	C75—C76	1.355 (8)
C20—C21	1.370 (7)	C76—C77	1.363 (7)
C20—H20	0.9300	C77—H77	0.9300
C21—H21	0.9300	C78—C79	1.507 (6)
C22—C23	1.492 (6)	C79—C80	1.368 (7)
C22—H22A	0.9700	C79—C84	1.383 (6)
C22—H22B	0.9700	C80—C81	1.380 (6)
C23—C28	1.353 (7)	C81—C82	1.363 (7)
C23—C24	1.359 (7)	C82—C83	1.356 (7)
C24—C25	1.370 (8)	C83—C84	1.361 (6)
C24—H24	0.9300	C84—H84	0.9300

O5—Sn1—C22	116.10 (15)	C33—C32—H32	120.2
O5—Sn1—C15	106.07 (15)	C31—C32—H32	120.2
C22—Sn1—C15	137.83 (18)	C32—C33—C34	121.4 (7)
O5—Sn1—O6	77.06 (10)	C32—C33—H33	119.3
C22—Sn1—O6	96.11 (14)	C34—C33—H33	119.3
C15—Sn1—O6	93.70 (14)	C33—C34—C35	118.9 (7)
O5—Sn1—O2	92.13 (11)	C33—C34—H34	120.6
C22—Sn1—O2	84.47 (15)	C35—C34—H34	120.6
C15—Sn1—O2	93.68 (14)	C30—C35—C34	120.6 (6)
O6—Sn1—O2	168.27 (11)	C30—C35—H35	119.7
O5—Sn2—C8	108.43 (16)	C34—C35—H35	119.7
O5—Sn2—C1	117.91 (15)	C37—C36—Sn3	121.6 (3)
C8—Sn2—C1	133.25 (18)	C37—C36—H36A	106.9
O5—Sn2—O3	80.51 (10)	Sn3—C36—H36A	106.9
C8—Sn2—O3	99.29 (15)	C37—C36—H36B	106.9
C1—Sn2—O3	94.16 (16)	Sn3—C36—H36B	106.9
O5—Sn2—O1	89.12 (11)	H36A—C36—H36B	106.7
C8—Sn2—O1	90.59 (16)	C38—C37—C42	116.8 (5)
C1—Sn2—O1	84.48 (16)	C38—C37—C36	120.9 (5)
O3—Sn2—O1	167.48 (11)	C42—C37—C36	122.1 (4)
O5—Sn2—O4	128.24 (10)	C37—C38—C39	121.4 (6)
C8—Sn2—O4	77.79 (16)	C37—C38—H38	119.3
C1—Sn2—O4	78.59 (16)	C39—C38—H38	119.3
O3—Sn2—O4	48.30 (10)	C40—C39—C38	121.0 (6)
O1—Sn2—O4	142.63 (10)	C40—C39—H39	119.5
O6—Sn3—C29	104.24 (17)	C38—C39—H39	119.5
O6—Sn3—C36	108.76 (15)	C39—C40—C41	119.4 (6)
C29—Sn3—C36	146.5 (2)	C39—C40—H40	120.3
O6—Sn3—O10	93.56 (11)	C41—C40—H40	120.3
C29—Sn3—O10	94.06 (15)	C40—C41—C42	120.1 (6)
C36—Sn3—O10	89.69 (14)	C40—C41—H41	120.0
O6—Sn3—O5	76.21 (10)	C42—C41—H41	120.0
C29—Sn3—O5	92.48 (14)	C41—C42—C37	121.3 (5)
C36—Sn3—O5	89.76 (14)	C41—C42—H42	119.3
O10—Sn3—O5	168.97 (11)	C37—C42—H42	119.3
O6—Sn4—C50	109.30 (16)	C44—C43—Sn4	113.5 (3)
O6—Sn4—C43	114.90 (15)	C44—C43—H43A	108.9
C50—Sn4—C43	135.14 (18)	Sn4—C43—H43A	108.9
O6—Sn4—O7	81.15 (10)	C44—C43—H43B	108.9
C50—Sn4—O7	98.64 (15)	Sn4—C43—H43B	108.9
C43—Sn4—O7	95.31 (15)	H43A—C43—H43B	107.7
O6—Sn4—O9	87.84 (11)	C49—C44—C45	119.7 (5)
C50—Sn4—O9	90.91 (16)	C49—C44—C43	120.1 (6)
C43—Sn4—O9	83.58 (15)	C45—C44—C43	120.1 (5)
O7—Sn4—O9	167.32 (11)	C44—C45—C46	119.2 (7)
C57—O1—Sn2	137.7 (3)	C44—C45—H45	120.4
C57—O2—Sn1	132.9 (3)	C46—C45—H45	120.4
C64—O3—Sn2	111.3 (3)	C47—C46—C45	120.1 (8)
C64—O4—Sn2	77.0 (3)	C47—C46—H46	120.0
Sn2—O5—Sn1	136.03 (13)	C45—C46—H46	120.0
Sn2—O5—Sn3	120.80 (12)	C46—C47—C48	122.6 (8)
Sn1—O5—Sn3	102.57 (10)	C46—C47—H47	118.7
Sn4—O6—Sn3	132.74 (13)	C48—C47—H47	118.7
Sn4—O6—Sn1	123.25 (13)	C47—C48—C49	118.3 (8)
Sn3—O6—Sn1	103.84 (11)	C47—C48—H48	120.9
C71—O7—Sn4	111.3 (3)	C49—C48—H48	120.9
C78—O9—Sn4	134.4 (3)	C44—C49—C48	120.0 (7)
C78—O10—Sn3	128.9 (3)	C44—C49—H49	120.0
C2—C1—Sn2	112.5 (3)	C48—C49—H49	120.0
C2—C1—H1A	109.1	C51—C50—Sn4	114.7 (3)
Sn2—C1—H1A	109.1	C51—C50—H50A	108.6
C2—C1—H1B	109.1	Sn4—C50—H50A	108.6
Sn2—C1—H1B	109.1	C51—C50—H50B	108.6
H1A—C1—H1B	107.8	Sn4—C50—H50B	108.6
C7—C2—C3	119.2 (5)	H50A—C50—H50B	107.6
C7—C2—C1	120.7 (5)	C52—C51—C56	119.6 (6)
C3—C2—C1	120.1 (5)	C52—C51—C50	120.7 (6)
C2—C3—C4	119.7 (6)	C56—C51—C50	119.7 (6)
C2—C3—H3	120.2	C51—C52—C53	121.5 (8)
C4—C3—H3	120.2	C51—C52—H52	119.3
C5—C4—C3	119.3 (7)	C53—C52—H52	119.3
C5—C4—H4	120.3	C54—C53—C52	115.5 (9)
C3—C4—H4	120.3	C54—C53—H53	122.3
C6—C5—C4	121.7 (7)	C52—C53—H53	122.3
C6—C5—H5	119.1	C53—C54—C55	128.0 (10)
C4—C5—H5	119.1	C53—C54—H54	116.0
C5—C6—C7	119.8 (7)	C55—C54—H54	116.0
C5—C6—H6	120.1	C54—C55—C56	114.5 (9)
C7—C6—H6	120.1	C54—C55—H55	122.7
C2—C7—C6	120.3 (6)	C56—C55—H55	122.7
C2—C7—H7	119.8	C51—C56—C55	120.6 (8)
C6—C7—H7	119.8	C51—C56—H56	119.7
C9—C8—Sn2	114.4 (3)	C55—C56—H56	119.7
C9—C8—H8A	108.7	O1—C57—O2	125.2 (4)
Sn2—C8—H8A	108.7	O1—C57—C58	117.3 (4)
C9—C8—H8B	108.7	O2—C57—C58	117.5 (4)
Sn2—C8—H8B	108.7	C63—C58—C59	118.5 (4)
H8A—C8—H8B	107.6	C63—C58—C57	117.4 (5)
C14—C9—C10	117.7 (5)	C59—C58—C57	124.0 (4)
C14—C9—C8	120.9 (5)	F1—C59—C60	117.0 (5)
C10—C9—C8	121.4 (5)	F1—C59—C58	122.6 (4)
C9—C10—C11	121.3 (6)	C60—C59—C58	120.5 (5)
C9—C10—H10	119.3	F2—C60—C61	120.2 (5)
C11—C10—H10	119.3	F2—C60—C59	119.7 (6)
C12—C11—C10	118.9 (7)	C61—C60—C59	120.0 (6)
C12—C11—H11	120.5	F3—C61—C60	119.4 (6)
C10—C11—H11	120.5	F3—C61—C62	121.0 (6)
C13—C12—C11	121.2 (7)	C60—C61—C62	119.6 (5)
C13—C12—H12	119.4	F4—C62—C63	120.7 (6)
C11—C12—H12	119.4	F4—C62—C61	117.9 (5)
C12—C13—C14	119.7 (7)	C63—C62—C61	121.3 (6)
C12—C13—H13	120.1	C62—C63—C58	120.1 (5)
C14—C13—H13	120.1	C62—C63—H63	120.0
C9—C14—C13	121.1 (6)	C58—C63—H63	120.0
C9—C14—H14	119.5	O4—C64—O3	123.4 (4)
C13—C14—H14	119.5	O4—C64—C65	118.8 (4)
C16—C15—Sn1	118.9 (3)	O3—C64—C65	117.8 (4)
C16—C15—H15A	107.6	C66—C65—C70	117.1 (4)
Sn1—C15—H15A	107.6	C66—C65—C64	126.3 (4)
C16—C15—H15B	107.6	C70—C65—C64	116.6 (4)
Sn1—C15—H15B	107.6	F5—C66—C65	122.2 (4)
H15A—C15—H15B	107.0	F5—C66—C67	115.5 (5)
C17—C16—C21	117.6 (4)	C65—C66—C67	122.3 (5)
C17—C16—C15	122.1 (4)	F6—C67—C68	119.1 (5)
C21—C16—C15	120.1 (4)	F6—C67—C66	121.2 (5)
C16—C17—C18	120.8 (5)	C68—C67—C66	119.7 (5)
C16—C17—H17	119.6	F7—C68—C67	120.6 (5)
C18—C17—H17	119.6	F7—C68—C69	120.0 (5)
C19—C18—C17	119.6 (6)	C67—C68—C69	119.5 (5)
C19—C18—H18	120.2	F8—C69—C68	118.5 (5)
C17—C18—H18	120.2	F8—C69—C70	120.7 (5)
C18—C19—C20	120.5 (6)	C68—C69—C70	120.8 (5)
C18—C19—H19	119.7	C69—C70—C65	120.6 (5)
C20—C19—H19	119.7	C69—C70—H70	119.7
C19—C20—C21	120.1 (6)	C65—C70—H70	119.7
C19—C20—H20	119.9	O8—C71—O7	122.2 (4)
C21—C20—H20	119.9	O8—C71—C72	119.4 (4)
C20—C21—C16	121.2 (5)	O7—C71—C72	118.3 (4)
C20—C21—H21	119.4	C73—C72—C77	117.4 (4)
C16—C21—H21	119.4	C73—C72—C71	125.1 (4)
C23—C22—Sn1	117.0 (3)	C77—C72—C71	117.6 (4)
C23—C22—H22A	108.0	F9—C73—C72	123.3 (4)
Sn1—C22—H22A	108.0	F9—C73—C74	113.7 (5)
C23—C22—H22B	108.0	C72—C73—C74	122.9 (5)
Sn1—C22—H22B	108.0	F10—C74—C75	120.8 (5)
H22A—C22—H22B	107.3	F10—C74—C73	121.0 (5)
C28—C23—C24	117.5 (5)	C75—C74—C73	118.2 (5)
C28—C23—C22	121.1 (5)	F11—C75—C76	121.6 (6)
C24—C23—C22	121.4 (5)	F11—C75—C74	118.7 (6)
C23—C24—C25	120.9 (6)	C76—C75—C74	119.8 (5)
C23—C24—H24	119.5	F12—C76—C75	118.6 (5)
C25—C24—H24	119.5	F12—C76—C77	118.8 (6)
C26—C25—C24	120.9 (7)	C75—C76—C77	122.6 (5)
C26—C25—H25	119.5	C76—C77—C72	119.0 (5)
C24—C25—H25	119.5	C76—C77—H77	120.5
C25—C26—C27	119.9 (7)	C72—C77—H77	120.5
C25—C26—H26	120.0	O9—C78—O10	124.9 (4)
C27—C26—H26	120.0	O9—C78—C79	117.8 (4)
C26—C27—C28	118.6 (7)	O10—C78—C79	117.4 (4)
C26—C27—H27	120.7	C80—C79—C84	118.1 (4)
C28—C27—H27	120.7	C80—C79—C78	123.8 (4)
C23—C28—C27	122.1 (6)	C84—C79—C78	118.1 (5)
C23—C28—H28	119.0	F13—C80—C79	123.0 (4)
C27—C28—H28	119.0	F13—C80—C81	115.9 (5)
C30—C29—Sn3	121.3 (3)	C79—C80—C81	121.0 (5)
C30—C29—H29A	107.0	F14—C81—C82	119.8 (5)
Sn3—C29—H29A	107.0	F14—C81—C80	120.1 (5)
C30—C29—H29B	107.0	C82—C81—C80	120.1 (5)
Sn3—C29—H29B	107.0	F15—C82—C83	121.0 (5)
H29A—C29—H29B	106.7	F15—C82—C81	120.1 (6)
C31—C30—C35	116.7 (5)	C83—C82—C81	118.8 (5)
C31—C30—C29	120.9 (5)	C82—C83—F16	118.2 (5)
C35—C30—C29	122.3 (5)	C82—C83—C84	121.9 (5)
C30—C31—C32	122.6 (7)	F16—C83—C84	120.0 (5)
C30—C31—H31	118.7	C83—C84—C79	120.0 (5)
C32—C31—H31	118.7	C83—C84—H84	120.0
C33—C32—C31	119.7 (8)	C79—C84—H84	120.0

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Octabenzyl­di-μ3-oxo-bis­(μ-2,3,4,5-tetra­fluoro­benzoato-κ2O:O′)bis(2,3,4,5-tetra­fluoro­benzoato-κO)tetratin(IV)

Supporting information

Key indicators

checkCIF/PLATON results

Octabenzyldi-μ₃-oxo-bis(μ-2,3,4,5-tetrafluorobenzoato-κ²O:O′)bis(2,3,4,5-tetrafluorobenzoato-κO)tetratin(IV)